DAQ-2024-004884

1
DAQC-CI118840001-24
Site ID 11884 (B1)

MEMORANDUM

TO: FILE – WILLIAMSEN-GODWIN TRUCK BODY CO, LLC - Salt Lake Plant

THROUGH: Chad Gilgen, Minor Source Compliance Section Manager

FROM: Daniel Riddle, Environmental Scientist

DATE: February 12, 2024

SUBJECT: FULL COMPLIANCE EVALUATION, Minor, Salt Lake County

INSPECTION DATE: January 10, 2024

SOURCE LOCATION: 1925 West Indiana Avenue
Salt Lake City, UT 84104
SOURCE CONTACTS: Kevin Sorensen, Manager
801-973-9400 [e-mail]

OPERATING STATUS: Operating normally at the time of inspection.

PROCESS DESCRIPTION: Manufacture and repair of heavy-duty truck frames. Large truck
frames are fabricated from raw materials. The metal is primed
and painted. There are two paint booth coating units equipped
with paint arrester filters. The outdoor blasting unit has been
replaced by the new steel shot enclosed abrasive blasting unit
which is in a production line with two new powder coat booths
(one priming and one finish coat) and one new curing oven (two
4.0 MMBtu burners).

APPLICABLE REGULATIONS: Approval Order (AO) DAQE-AN118840001-17, dated July 18,
2017
MACT (Part 63) HHHHHH: National Emission Standards for
Hazardous Air Pollutants: Paint Stripping and Miscellaneous
Surface Coating Operations at Area Sources,

SOURCE EVALUATION:

Name of Permittee: Permitted Location:

Williamsen-Godwin Truck Body Co, LLC
Salt Lake Plant

1925 West Indiana Avenue 1925 West Indiana Avenue
Salt Lake City, UT 84104 Salt Lake City, UT 84104

2
SIC Code: 3713: (Truck & Bus Bodies)

Section I: GENERAL PROVISIONS

I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the
UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to
those rules. [R307-101]

I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401]

I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions
covered by this AO must be reviewed and approved. [R307-401-1]

I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by
the owner/operator, shall be made available to the Director or Director's representative upon
request, and the records shall include the two-year period prior to the date of the request. Unless
otherwise specified in this AO or in other applicable state and federal rules, records shall be kept
for a minimum of two (2) years. [R307-401-8]

I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall,
to the extent practicable, maintain and operate any equipment approved under this AO, including
associated air pollution control equipment, in a manner consistent with good air pollution control
practice for minimizing emissions. Determination of whether acceptable operating and
maintenance procedures are being used will be based on information available to the Director
which may include, but is not limited to, monitoring results, opacity observations, review of
operating and maintenance procedures, and inspection of the source. All maintenance performed
on equipment authorized by this AO shall be recorded. [R307-401-4]

I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns.
[R307-107]

I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150]

I.8 The owner/operator shall submit documentation of the status of construction or modification to
the Director within 18 months from the date of this AO. This AO may become invalid if
construction is not commenced within 18 months from the date of this AO or if construction is
discontinued for 18 months or more. To ensure proper credit when notifying the Director, send
the documentation to the Director, attn.: NSR Section. [R307-401-18]

Status: In Compliance. No limits set forth in this AO appear to have been exceeded. The
source stated that there have been no modifications to the equipment or processes. The
equipment appeared to be properly operated and maintained according to manufacturer
recommendations. Records are kept as required and were made available after the
inspection. No breakdowns have been reported since the previous inspection. This source
is not required to submit an emissions inventory at this time. See the construction status
update from 2017 attached below.

Section II: SPECIAL PROVISIONS

II.A The approved installations shall consist of the following equipment:

II.A.1 Williamsen-Godwin Truck Body Co, LLC
A truck bed manufacture and repair plant
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II.A.2 Abrasive Blasting Unit (New)
Media Type: Steel shot
Control: Baghouse
Baghouse Flow Rate: 13,000 acfm
Baghouse Pressure Drop Range: Between 2 and 4 inches of H2O

II.A.3 Two (2) Paint Booths
Control: Filters

II.A.4 Two (2) Powder Coat Paint Booths (New)
Control: Cartridge Filter System

II.A.5 One (1) Curing Oven (New)
Burner Capacity: 2-4.0 MMBtu/hr burners
Fuel: Natural Gas

II.A.6 Miscellaneous Equipment
Associated equipment and functions for the manufacture and repair of truck beds:
- Plasma cutting operations
- Welding operations
- Parts washers and gun cleaning station
- Natural gas-fired boilers and heaters less than 5.0 MMBtu/hr each

Status: In Compliance. No unapproved equipment was observed at the time of inspection.

II.B Requirements and Limitations

II.B.1 Site-Wide Requirements

II.B.1.a Visible emissions from the following emission points shall not exceed the following values:

A. Baghouses - 10% opacity

B. Paint booths - 10% opacity

C. Powder coating paint booths - 10% opacity

D. Curing ovens - 10% opacity

E. Any other stationary point or fugitive emissions associated with the source - 20% opacity.
[R307-401-8]

II.B.1.a.1 Opacity observations of emissions from stationary sources shall be conducted according to 40
CFR 60, Appendix A, Method 9. [R307-401-8]

Status: In Compliance. No visible emissions were observed from any point at the time of
inspection. Method 9 was utilized to verify opacity limits. See attached VEO form.

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II.B.1.b The owner/operator shall conduct all degreasing and solvent cleaning operations in accordance
with the requirements of R307-335. [R307-335]

Status: In Compliance. The parts washer has a lid that is easily operated by one hand. The
lid was closed during the inspection. No excess solvent appears to have splashed or leaked.

Solvent cleaning operations are applicable to R307-350-7(2). The main solvent used in
cleaning is the MS151 multi-purpose solvent. VOC composite pressure for this product is
0.295 mmHG at 20 degrees Celsius. See the attached SDS for this product, the Compliant
Brochure from Omni, and the email correspondence below (end of records).

II.B.1.c The plant-wide emissions of VOCs and HAPs from the paint booths, degreasers, contact cement
applicators, etc. and associated operations excluding incomplete combustion products shall not
exceed:

9.53 tons per rolling 12-month period for VOCs
8.46 tons per rolling 12-month period for combined HAPs

[R307-401-8]

II.B.1.c.1 Compliance with each limitation shall be determined on a rolling 12-month total. To determine
compliance with a rolling 12-month total, the owner/operator shall calculate a new 12-month
total by the twentieth day of each month using date from the previous 12 months.

VOC and HAP emissions shall be determined by maintaining a record of VOC- and HAP-
emitting materials used each month. The record shall include the following data for each material
used:

A. Name of the VOC- or HAPs-emitting material, such as: paint, adhesive, solvent,
thinner, reducers, chemical compounds, toxics, isocyanates, etc.

B. Density of each VOC- or HAPs-emitting material used (pounds per gallon)

C. Percent by weight of all VOC or HAP in each material used

D. Gallons of each VOC- or HAP-emitting material used

E. The amount of VOC or HAP emitted monthly from each material used. The amount of
VOC or HAP emitted monthly by each material used shall be calculated by the
following procedure:

VOC = (% VOC by Weight)/100 x [Density (lb/gal)] x (Gal Consumed) x (1 ton/2000 lb)

HAP = (% HAP by Weight)/100 x [Density (lb/gal)] x (Gal Consumed) x (1 ton/2000 lb)

F. The amount of VOC or HAP emitted monthly from all materials used

G. The amount of VOCs or HAPs reclaimed for the month shall be similarly quantified and
subtracted from the quantities calculated above to provide the monthly total VOC or
HAP emissions

[R307-401-8]

Status: In Compliance. For the rolling 12-month period from January 2023 - December
2023, 2.31 tons of VOCs were emitted, and 1.594 tons of combined HAPs were emitted. See
the attached summary below.

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II.B.2 Abrasive Blasting Unit Requirements

II.B.2.a The baghouse shall control the exhaust stream from the abrasive blasting unit. All exhaust air
from the abrasive blasting process shall be routed through the baghouse before being vented to
the atmosphere. [R307-401-8]

II.B.2.a.1 A manometer or magnehelic pressure gauge shall be installed to measure the pressure differential
across the fabric filters. The pressure drop range across the filter media shall be between two and
four inches of water column. The reading shall be accurate within plus or minus one inch. The
pressure gauge shall be located such that an inspector/operator can safely read the output at any
time. [R307-401-8]

II.B.2.a.2 The pressure drop reading from the pressure gauge shall be recorded for each day the abrasive
blasting unit is in operation. [R307-401-8]

Status: In Compliance. The pressure gauge is maintained between 2 and 4 inches of water
column. See the attached log for 2023.

II.B.3 Paint Booth Requirements

II.B.3.a Each paint spray booth shall be equipped with paint arrestor particulate filters, or equivalent, to
control particulate emissions. All air exiting the booths shall pass through this control system
before being vented to the atmosphere. Equivalency determinations, when requested by the
owner/operator, shall be submitted to the Director for approval. [R307-401-8]

Status: In Compliance. The paint spray booths were observed to be equipped with filters
at the time of inspection.

II.B.3.b The owner/operator shall conduct all painting operations in accordance with the requirements of
R307-350. [R307-350]

Status: In Compliance. All products are compliant. See attached SDS.

II.B.3.c Each paint spray booth shall vent vertically unrestricted to the atmosphere with a stack height of
no less than 35 feet above ground level. [R307-401-8, R307-410]

Status: In Compliance. Each paint spray booth stack was observed to be no less than 35
feet above ground level at the time of inspection.

II.B.4 Powder Coat Booth Requirements

II.B.4.a Each powder coat booth shall be equipped with a cartridge filter system, or equivalent, to control
particulate emissions. All air exiting the booths shall pass through this control system before
being vented to the atmosphere. Equivalency determinations, when requested by the
owner/operator, shall be submitted to the Director for approval. [R307-401-8]

Status: Not Applicable. Each powder coat booth is controlled with a two-stage, pulse-jet
filter system that vents internally.

Section III: APPLICABLE FEDERAL REQUIREMENTS

In addition to the requirements of this AO, all applicable provisions of the following federal programs
have been found to apply to this installation. This AO in no way releases the owner or operator from any
liability for compliance with all other applicable federal, state, and local regulations including UAC
R307.

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MACT (Part 63) HHHHHH: National Emission Standards for Hazardous Air Pollutants: Paint Stripping and
Miscellaneous Surface Coating Operations at Area Sources

Status: Not Applicable. The source does not emit any of the target HAPs listed in 40 CFR 63.11180.

AREA SOURCE RULES EVALUATION:

The following Area Source Rules were evaluated during this inspection:

Nonattainment and Maintenance Areas for PM10: Emission Standards [R307-305]

Status: In Compliance. The requirements of this area source rule are satisfied by compliance with
AO condition II.B.1.a. See status of AO condition II.B.1.a for additional information.

PM10 Nonattainment and Maintenance Areas: Abrasive Blasting [R307-306]

Status: In Compliance. The requirements of this area source rule are satisfied by use of an enclosed
abrasive blast unit that vents to a baghouse.

Ozone Nonattainment and Maintenance Areas: General Requirements [R307-325]

Status: In Compliance. No VOC containing materials were observed spilled, discarded, stored in
open containers or handled in any other way that would result in greater evaporation.

Degreasing [R307-335]

Status: In Compliance. The requirements of this area source rule are satisfied by compliance with
AO condition II.B.1.b. See status of AO condition II.B.1.b for additional information.

Miscellaneous Metal Parts and Products Coatings [R307-350]

Status: In Compliance. The requirements of this area source rule are satisfied by compliance with
AO condition II.B.3.b. See status of AO condition II.B.3.b for additional information.

EMISSION INVENTORY:

Listed before are the estimated total potential emissions (PTE) on AO: DAQE-AN118840001-17, dated
July 18, 2017. PTE are supplied for supplemental purposes only.

Criteria Pollutant PTE tons/yr
CO2 Equivalent 7452.00
Carbon Monoxide 5.18
Nitrogen Oxides 6.17
Particulate Matter - PM10 1.36
Particulate Matter - PM2.5 1.00
Sulfur Dioxide 0.04
Volatile Organic Compounds 9.87

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Hazardous Air Pollutant PTE lbs/yr
Cumene (CAS #98828) 1
Ethyl Benzene (CAS #100414) 760
Formaldehyde (CAS #50000) 9
Hexamethylene-1,6-Diisocyanate (CAS #822060) 40
Hexane (CAS #110543) 220
Methanol (CAS #67561) 5220
Methyl Isobutyl Ketone (Hexone) (CAS #108101) 4460
Toluene (CAS #108883) 15000
Xylenes (Isomers and Mixture) (CAS #1330207) 3700

PREVIOUS ENFORCEMENT
ACTIONS: No enforcement actions within the past five years.

COMPLIANCE STATUS &
RECOMMENDATIONS: In regards to Approval Order (AO) DAQE-AN118840001-17,
dated July 18, 2017: In compliance at the time of inspection.

HPV STATUS: Not Applicable.

RECOMMENDATION FOR
NEXT INSPECTION: Inspect at low frequency. Safety glasses are required for this
inspection. AO condition II.B.1.b needs to be updated to remove
“solvent cleaning operations” since those activities are addressed
under R307-350-7(2).

ATTACHMENTS: VEO form, construction status, pressure drops, VOC and HAP
emissions, SDS
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ϰͬϮϭͬϮϬϮϯ Ϯ͘ϳ
ϰͬϮϮͬϮϬϮϯ Ϯ͘ϳ
ϰͬϮϯͬϮϬϮϯ Ϯ͘ϳ
ϰͬϮϰͬϮϬϮϯ ϯ͘Ϯ
ϰͬϮϱͬϮϬϮϯ ϯ͘Ϯ
ϰͬϮϲͬϮϬϮϯ ϯ͘Ϯ
ϰͬϮϳͬϮϬϮϯ ϯ͘Ϯ
ϰͬϮϴͬϮϬϮϯ ϯ͘Ϯ
ϰͬϮϵͬϮϬϮϯ ϯ͘Ϯ
ϰͬϯϬͬϮϬϮϯ ϯ͘Ϯ
ϱͬϭͬϮϬϮϯ ϯ͘Ϯ
ϱͬϮͬϮϬϮϯ ϯ͘Ϯ
ϱͬϯͬϮϬϮϯ ϯ͘Ϯ
ϱͬϰͬϮϬϮϯ ϯ͘Ϯ
ϱͬϱͬϮϬϮϯ ϯ͘Ϯ
ϱͬϲͬϮϬϮϯ ϯ͘Ϯ
ϱͬϳͬϮϬϮϯ ϯ͘Ϯ
ϱͬϴͬϮϬϮϯ ϯ͘ϯ
ϱͬϵͬϮϬϮϯ ϯ͘ϯ
ϱͬϭϬͬϮϬϮϯ ϯ͘ϯ
ϱͬϭϭͬϮϬϮϯ ϯ͘ϯ
ϱͬϭϮͬϮϬϮϯ ϯ͘ϯ
ϱͬϭϯͬϮϬϮϯ ϯ͘ϯ
ϱͬϭϰͬϮϬϮϯ ϯ͘ϯ
ϱͬϭϱͬϮϬϮϯ ϯ
ϱͬϭϲͬϮϬϮϯ ϯ
ϱͬϭϳͬϮϬϮϯ ϯ
ϱͬϭϴͬϮϬϮϯ ϯ
ϱͬϭϵͬϮϬϮϯ ϯ
ϱͬϮϬͬϮϬϮϯ ϯ
ϱͬϮϭͬϮϬϮϯ ϯ
ϱͬϮϮͬϮϬϮϯ Ϯ͘ϳ
ϱͬϮϯͬϮϬϮϯ Ϯ͘ϳ
ϱͬϮϰͬϮϬϮϯ Ϯ͘ϳ
ϱͬϮϱͬϮϬϮϯ Ϯ͘ϳ
ϱͬϮϲͬϮϬϮϯ Ϯ͘ϳ
ϱͬϮϳͬϮϬϮϯ Ϯ͘ϳ
ϱͬϮϴͬϮϬϮϯ Ϯ͘ϳ
ϱͬϮϵͬϮϬϮϯ Ϯ͘ϳ
ϱͬϯϬͬϮϬϮϯ Ϯ͘ϳ
ϱͬϯϭͬϮϬϮϯ Ϯ͘ϳ
ϲͬϭͬϮϬϮϯ Ϯ͘ϳ
ϲͬϮͬϮϬϮϯ Ϯ͘ϳ
ϲͬϯͬϮϬϮϯ Ϯ͘ϳ
ϲͬϰͬϮϬϮϯ Ϯ͘ϳ
ϲͬϱͬϮϬϮϯ ϯ
ϲͬϲͬϮϬϮϯ ϯ
ϲͬϳͬϮϬϮϯ ϯ
ϲͬϴͬϮϬϮϯ ϯ
ϲͬϵͬϮϬϮϯ ϯ
ϲͬϭϬͬϮϬϮϯ ϯ
ϲͬϭϭͬϮϬϮϯ ϯ
ϲͬϭϮͬϮϬϮϯ ϯ͘ϱ
ϲͬϭϯͬϮϬϮϯ ϯ͘ϱ
ϲͬϭϰͬϮϬϮϯ ϯ͘ϱ
ϲͬϭϱͬϮϬϮϯ ϯ͘ϱ
ϲͬϭϲͬϮϬϮϯ ϯ͘ϱ
ϲͬϭϳͬϮϬϮϯ ϯ͘ϱ
ϲͬϭϴͬϮϬϮϯ ϯ͘ϱ
ϲͬϭϵͬϮϬϮϯ ϯ͘ϳ
ϲͬϮϬͬϮϬϮϯ ϯ͘ϳ
ϲͬϮϭͬϮϬϮϯ ϯ͘ϳ
ϲͬϮϮͬϮϬϮϯ ϯ͘ϳ
ϲͬϮϯͬϮϬϮϯ ϯ͘ϳ
ϲͬϮϰͬϮϬϮϯ ϯ͘ϳ
ϲͬϮϱͬϮϬϮϯ ϯ͘ϳ
ϲͬϮϲͬϮϬϮϯ ϯ͘ϳ
ϲͬϮϳͬϮϬϮϯ ϯ͘ϳ
ϲͬϮϴͬϮϬϮϯ ϯ͘ϳ
ϲͬϮϵͬϮϬϮϯ ϯ͘ϳ
ϲͬϯϬͬϮϬϮϯ ϯ͘ϳ
ϳͬϭͬϮϬϮϯ ϯ͘ϳ
ϳͬϮͬϮϬϮϯ ϯ͘ϳ
ϳͬϯͬϮϬϮϯ ϯ͘ϳ
ϳͬϰͬϮϬϮϯ ϯ͘ϳ
ϳͬϱͬϮϬϮϯ ϯ͘ϳ
ϳͬϲͬϮϬϮϯ ϯ͘ϳ
ϳͬϳͬϮϬϮϯ ϯ͘ϳ
ϳͬϴͬϮϬϮϯ ϯ͘ϳ
ϳͬϵͬϮϬϮϯ ϯ͘ϳ
ϳͬϭϬͬϮϬϮϯ ϯ͘ϳ
ϳͬϭϭͬϮϬϮϯ ϯ͘ϭ
ϳͬϭϮͬϮϬϮϯ ϯ͘ϭ
ϳͬϭϯͬϮϬϮϯ ϯ͘ϭ
ϳͬϭϰͬϮϬϮϯ ϯ͘ϭ
ϳͬϭϱͬϮϬϮϯ ϯ͘ϭ
ϳͬϭϲͬϮϬϮϯ ϯ͘ϭ
ϳͬϭϳͬϮϬϮϯ ϯ͘ϭ
ϳͬϭϴͬϮϬϮϯ ϯ͘ϭ
ϳͬϭϵͬϮϬϮϯ ϯ͘ϭ
ϳͬϮϬͬϮϬϮϯ ϯ͘ϭ
ϳͬϮϭͬϮϬϮϯ ϯ͘ϭ
ϳͬϮϮͬϮϬϮϯ ϯ͘ϭ
ϳͬϮϯͬϮϬϮϯ ϯ͘ϭ
ϳͬϮϰͬϮϬϮϯ ϯ͘Ϯ
ϳͬϮϱͬϮϬϮϯ ϯ͘Ϯ
ϳͬϮϲͬϮϬϮϯ ϯ͘Ϯ
ϳͬϮϳͬϮϬϮϯ ϯ͘Ϯ
ϳͬϮϴͬϮϬϮϯ ϯ͘Ϯ
ϳͬϮϵͬϮϬϮϯ ϯ͘Ϯ
ϳͬϯϬͬϮϬϮϯ ϯ͘Ϯ
ϳͬϯϭͬϮϬϮϯ ϯ͘Ϯ
ϴͬϭͬϮϬϮϯ ϯ͘Ϯ
ϴͬϮͬϮϬϮϯ ϯ͘Ϯ
ϴͬϯͬϮϬϮϯ ϯ͘Ϯ
ϴͬϰͬϮϬϮϯ ϯ͘Ϯ
ϴͬϱͬϮϬϮϯ ϯ͘Ϯ
ϴͬϲͬϮϬϮϯ ϯ͘Ϯ
ϴͬϳͬϮϬϮϯ ϯ͘Ϯ
ϴͬϴͬϮϬϮϯ ϯ͘Ϯ
ϴͬϵͬϮϬϮϯ ϯ͘Ϯ
ϴͬϭϬͬϮϬϮϯ ϯ͘Ϯ
ϴͬϭϭͬϮϬϮϯ ϯ͘Ϯ
ϴͬϭϮͬϮϬϮϯ ϯ͘Ϯ
ϴͬϭϯͬϮϬϮϯ ϯ͘Ϯ
ϴͬϭϰͬϮϬϮϯ ϯ͘Ϯ
ϴͬϭϱͬϮϬϮϯ ϯ͘Ϯ
ϴͬϭϲͬϮϬϮϯ ϯ͘Ϯ
ϴͬϭϳͬϮϬϮϯ ϯ͘Ϯ
ϴͬϭϴͬϮϬϮϯ ϯ͘Ϯ
ϴͬϭϵͬϮϬϮϯ ϯ͘Ϯ
ϴͬϮϬͬϮϬϮϯ ϯ͘Ϯ
ϴͬϮϭͬϮϬϮϯ ϯ͘Ϯ
ϴͬϮϮͬϮϬϮϯ ϯ͘Ϯ
ϴͬϮϯͬϮϬϮϯ ϯ͘Ϯ
ϴͬϮϰͬϮϬϮϯ ϯ͘Ϯ
ϴͬϮϱͬϮϬϮϯ ϯ͘Ϯ
ϴͬϮϲͬϮϬϮϯ ϯ͘Ϯ
ϴͬϮϳͬϮϬϮϯ ϯ͘Ϯ
ϴͬϮϴͬϮϬϮϯ ϯ
ϴͬϮϵͬϮϬϮϯ ϯ
ϴͬϯϬͬϮϬϮϯ ϯ
ϴͬϯϭͬϮϬϮϯ ϯ
ϵͬϭͬϮϬϮϯ ϯ
ϵͬϮͬϮϬϮϯ ϯ
ϵͬϯͬϮϬϮϯ ϯ
ϵͬϰͬϮϬϮϯ ϯ
ϵͬϱͬϮϬϮϯ ϯ
ϵͬϲͬϮϬϮϯ ϯ
ϵͬϳͬϮϬϮϯ ϯ
ϵͬϴͬϮϬϮϯ ϯ
ϵͬϵͬϮϬϮϯ ϯ
ϵͬϭϬͬϮϬϮϯ ϯ
ϵͬϭϭͬϮϬϮϯ ϯ
ϵͬϭϮͬϮϬϮϯ ϯ
ϵͬϭϯͬϮϬϮϯ ϯ
ϵͬϭϰͬϮϬϮϯ ϯ
ϵͬϭϱͬϮϬϮϯ ϯ
ϵͬϭϲͬϮϬϮϯ ϯ
ϵͬϭϳͬϮϬϮϯ ϯ
ϵͬϭϴͬϮϬϮϯ ϯ͘ϱ
ϵͬϭϵͬϮϬϮϯ ϯ͘ϱ
ϵͬϮϬͬϮϬϮϯ ϯ͘ϱ
ϵͬϮϭͬϮϬϮϯ ϯ͘ϱ
ϵͬϮϮͬϮϬϮϯ ϯ͘ϱ
ϵͬϮϯͬϮϬϮϯ ϯ͘ϱ
ϵͬϮϰͬϮϬϮϯ ϯ͘ϱ
ϵͬϮϱͬϮϬϮϯ ϯ͘ϱ
ϵͬϮϲͬϮϬϮϯ ϯ͘ϱ
ϵͬϮϳͬϮϬϮϯ ϯ͘ϱ
ϵͬϮϴͬϮϬϮϯ ϯ͘ϱ
ϵͬϮϵͬϮϬϮϯ ϯ͘ϱ
ϵͬϯϬͬϮϬϮϯ ϯ͘ϱ
ϭϬͬϭͬϮϬϮϯ ϯ͘ϱ
ϭϬͬϮͬϮϬϮϯ ϯ͘ϱ
ϭϬͬϯͬϮϬϮϯ ϯ͘ϱ
ϭϬͬϰͬϮϬϮϯ ϯ͘ϱ
ϭϬͬϱͬϮϬϮϯ ϯ͘ϱ
ϭϬͬϲͬϮϬϮϯ ϯ͘ϱ
ϭϬͬϳͬϮϬϮϯ ϯ͘ϱ
ϭϬͬϴͬϮϬϮϯ ϯ͘ϱ
ϭϬͬϵͬϮϬϮϯ ϯ͘ϴ
ϭϬͬϭϬͬϮϬϮϯ ϯ͘ϴ
ϭϬͬϭϭͬϮϬϮϯ ϯ͘ϴ
ϭϬͬϭϮͬϮϬϮϯ ϯ͘ϴ
ϭϬͬϭϯͬϮϬϮϯ ϯ͘ϴ
ϭϬͬϭϰͬϮϬϮϯ ϯ͘ϴ
ϭϬͬϭϱͬϮϬϮϯ ϯ͘ϴ
ϭϬͬϭϲͬϮϬϮϯ Ϯ͘ϵ
ϭϬͬϭϳͬϮϬϮϯ Ϯ͘ϵ
ϭϬͬϭϴͬϮϬϮϯ Ϯ͘ϵ
ϭϬͬϭϵͬϮϬϮϯ Ϯ͘ϵ
ϭϬͬϮϬͬϮϬϮϯ Ϯ͘ϵ
ϭϬͬϮϭͬϮϬϮϯ Ϯ͘ϵ
ϭϬͬϮϮͬϮϬϮϯ Ϯ͘ϵ
ϭϬͬϮϯͬϮϬϮϯ ϯ͘ϭ
ϭϬͬϮϰͬϮϬϮϯ ϯ͘ϭ
ϭϬͬϮϱͬϮϬϮϯ ϯ͘ϭ
ϭϬͬϮϲͬϮϬϮϯ ϯ͘ϭ
ϭϬͬϮϳͬϮϬϮϯ ϯ͘ϭ
ϭϬͬϮϴͬϮϬϮϯ ϯ͘ϭ
ϭϬͬϮϵͬϮϬϮϯ ϯ͘ϭ
ϭϬͬϯϬͬϮϬϮϯ ϯ͘ϭ
ϭϬͬϯϭͬϮϬϮϯ ϯ͘ϭ
ϭϭͬϭͬϮϬϮϯ ϯ͘ϭ
ϭϭͬϮͬϮϬϮϯ ϯ͘ϭ
ϭϭͬϯͬϮϬϮϯ ϯ͘ϭ
ϭϭͬϰͬϮϬϮϯ ϯ͘ϭ
ϭϭͬϱͬϮϬϮϯ ϯ͘ϭ
ϭϭͬϲͬϮϬϮϯ ϯ͘ϭ
ϭϭͬϳͬϮϬϮϯ ϯ͘ϭ
ϭϭͬϴͬϮϬϮϯ ϯ͘ϭ
ϭϭͬϵͬϮϬϮϯ ϯ͘ϭ
ϭϭͬϭϬͬϮϬϮϯ ϯ͘ϭ
ϭϭͬϭϭͬϮϬϮϯ ϯ͘ϭ
ϭϭͬϭϮͬϮϬϮϯ ϯ͘ϭ
ϭϭͬϭϯͬϮϬϮϯ ϯ͘ϯ
ϭϭͬϭϰͬϮϬϮϯ ϯ͘ϯ
ϭϭͬϭϱͬϮϬϮϯ ϯ͘ϯ
ϭϭͬϭϲͬϮϬϮϯ ϯ͘ϯ
ϭϭͬϭϳͬϮϬϮϯ ϯ͘ϯ
ϭϭͬϭϴͬϮϬϮϯ ϯ͘ϯ
ϭϭͬϭϵͬϮϬϮϯ ϯ͘ϯ
ϭϭͬϮϬͬϮϬϮϯ Ϯ͘ϵ
ϭϭͬϮϭͬϮϬϮϯ Ϯ͘ϵ
ϭϭͬϮϮͬϮϬϮϯ Ϯ͘ϵ
ϭϭͬϮϯͬϮϬϮϯ Ϯ͘ϵ
ϭϭͬϮϰͬϮϬϮϯ Ϯ͘ϵ
ϭϭͬϮϱͬϮϬϮϯ Ϯ͘ϵ
ϭϭͬϮϲͬϮϬϮϯ Ϯ͘ϵ
ϭϭͬϮϳͬϮϬϮϯ Ϯ͘ϴ
ϭϭͬϮϴͬϮϬϮϯ Ϯ͘ϴ
ϭϭͬϮϵͬϮϬϮϯ Ϯ͘ϴ
ϭϭͬϯϬͬϮϬϮϯ Ϯ͘ϴ
ϭϮͬϭͬϮϬϮϯ Ϯ͘ϴ
ϭϮͬϮͬϮϬϮϯ Ϯ͘ϴ
ϭϮͬϯͬϮϬϮϯ Ϯ͘ϴ
ϭϮͬϰͬϮϬϮϯ ϯ͘ϭ
ϭϮͬϱͬϮϬϮϯ ϯ͘ϭ
ϭϮͬϲͬϮϬϮϯ ϯ͘ϭ
ϭϮͬϳͬϮϬϮϯ ϯ͘ϭ
ϭϮͬϴͬϮϬϮϯ ϯ͘ϭ
ϭϮͬϵͬϮϬϮϯ ϯ͘ϭ
ϭϮͬϭϬͬϮϬϮϯ ϯ͘ϭ
ϭϮͬϭϭͬϮϬϮϯ ϯ͘ϭ
ϭϮͬϭϮͬϮϬϮϯ ϯ͘ϭ
ϭϮͬϭϯͬϮϬϮϯ ϯ͘ϭ
ϭϮͬϭϰͬϮϬϮϯ ϯ͘ϭ
ϭϮͬϭϱͬϮϬϮϯ ϯ͘ϭ
ϭϮͬϭϲͬϮϬϮϯ ϯ͘ϭ
ϭϮͬϭϳͬϮϬϮϯ ϯ͘ϭ
ϭϮͬϭϴͬϮϬϮϯ ϯ͘ϰ
ϭϮͬϭϵͬϮϬϮϯ ϯ͘ϰ
ϭϮͬϮϬͬϮϬϮϯ ϯ͘ϰ
ϭϮͬϮϭͬϮϬϮϯ ϯ͘ϰ
ϭϮͬϮϮͬϮϬϮϯ ϯ͘ϰ
ϭϮͬϮϯͬϮϬϮϯ ϯ͘ϰ
ϭϮͬϮϰͬϮϬϮϯ ϯ͘ϰ
ϭϮͬϮϱͬϮϬϮϯ Ϯ͘ϱ
ϭϮͬϮϲͬϮϬϮϯ Ϯ͘ϱ
ϭϮͬϮϳͬϮϬϮϯ Ϯ͘ϱ
ϭϮͬϮϴͬϮϬϮϯ Ϯ͘ϱ
ϭϮͬϮϵͬϮϬϮϯ Ϯ͘ϱ
ϭϮͬϯϬͬϮϬϮϯ Ϯ͘ϱ
ϭϮͬϯϭͬϮϬϮϯ Ϯ͘ϱ
ϭͬϭͬϮϬϮϰ
Summary of Monthly Throughputs Tracking Spreadsheet
Williamsen-Godwin
Salt Lake City, UT
Part #Nat Gas Nat Gas Nat Gas N/A N/A DX840GL CFX849 CRE-211H CRE-321 ESB800 ESH200 ESSS SS-1 ESX500 MS251 Q30 Q80
Description Main Building Old Paint Shop
New Paint
Shop
Abrasive
Blasting
Powder
Coating
Blending
Solvent
Super
Accelerator
2.1 Epoxy
Activator
2.1 Epoxy
Primer Grey
Clear Coat
Converter
Essentials
Hardener
Essentials
Colors Mixed
Package .75
Gal Each
Essentials
Colors
Activator
Multi
Purpose
Solvent
Acetone
Reducer for
Primer in the
Winter
Xylene Reducer
for Primer in
the Summer
Month [decatherms][decatherms][decatherms][hours][lbs][gal][gal][gal][gal][gal][gal][gal][gal][gal][gal][gal]
Nov-16
Dec-16
Jan-17
Feb-17
Mar-17
Apr-17
May-17
Jun-17 11.5 40.9
Jul-17 9.9 4.5 2.15 365 23 39 13 94.5 9.25 110 15 15
Aug-17 12.9 349.6 0.2 6.7 1615 3 20 6.75 42.75 6 55 10
Sep-17 26.5 353.4 158.6 6.83 1585 9
Oct-17 40 323.8 232.7 12.15 1550 2.375 12 1.375 55 5
Nov-17 442.2 533.3 364.4 1 165 5.25 7.5 5 55
Dec-17 940.8 547 642.7 8.3 1320 5.25 46.5 5.25 55
Jan-18 957.4 233.4 472.6 6.83 1250 9 16 1.5 13.5 2.75 25 10
Feb-18 1063.3 544.1 188.7 8.88 1590 1 8 17 4.75 20.25 4.75 10 5
Mar-18 693.8 436.8 9.6 15.27 2070 7 14 1.875 12.75 2.25 16.5 10
Apr-18 144.4 418.8 245.9 10.36 1485 1 0.125 7 14 2.75 18.75 2.875 29 10
May-18 21 48 190.7 8.84 1355 6 13 3.25 18.75 3.25 20 10
Jun-18 19.5 13 156.5 12 1305 6 10 2.875 17.25 1.25 7 10
Jul-18 11.3 2.4 195 16.18 2235 6 10 3.75 23.25 3.75 50 5
Aug-18 31.7 8.2 175.1 14.12 1505 6 12 3.125 16.5 3.125 10
Sep-18 14.7 100.5 198.7 6.62 1030 1 7 14 3.25 18.75 3.25 5
Oct-18 41.7 360.6 164.1 13.44 980 4 10 2.75 16.5 2.5 110 5
Nov-18 445.1 582.8 241.6 10.66 1350 1 8 17 2.125 11.25 2.125 10
Dec-18 2237.7 138.4 720.1 7.85 360 12 22 6 36 6 45 18
Jan-19 1080.6 82.9 618.7 21 38 5 30 5 110 25
Feb-19 1093.4 350.1 549.9 8.52 1395 1 4 8 4.75 28.5 4.75 10
Mar-19 387.4 396.6 338.4 16.18 1485 1 7 12 3.625 19.5 3.625 46 5
Apr-19 125.7 197.9 384.5 26.04 2685 5 12 3.75 22.5 2.625 10
May-19 29 239.2 196.8 12.78 2550 5 10 3.625 21.75 3.625 10
Jun-19 14.6 27.4 126.9 12.47 1720 1 6 14 4.625 27 4.5 5 10
Jul-19 22 9 164 11.04 1805 1 9 19 3.875 23.25 5 48 33
Aug-19 22 7 52 2.89 635 1 5 14 3.625 21.75 3.625 10
Sep-19 24 116 117 14.16 1170 8 17 8 48 8 110 20
Oct-19 418 474 171 13.4 1645 4 9 3.25 19.5 3.25 95 5
Nov-19 719 518 185 13.14 1550 2 4 8 2.875 17.25 2.875 5 5
Dec-19 1215 621 194 14.25 2220 1 6 12 3.625 21.75 3.625 35 10
Jan-20 1194 594 142 13.27 1610 1 6 9 5.5 33 5.5
Feb-20 1131 572 134 291.74 1025 2 7 9 0.5 6.75 40.5 6.75 5
Mar-20 442 545 149 14.26 815 1 7 12 2.25 7.375 40.5 6.375
Apr-20 194 326 140 10.99 865 2 4 7 4.625 27.75 4.625 40 10
May-20 26 109 123 9.14 360 2 4 8 4.5 24.75 4.5 41 5
Jun-20 23 63 67 7.25 650 4 2 4 6.25 37.5 6.25 40
Jul-20 27 3 123 12.4 450 3 4 8 2 12 2 10
Aug-20 27 105 11.23 920 1 4 6 1.75 17.25 2.875 55 45
Sep-20 27 43 78 3.84 580 4 2 3.75 22.5 3.75 5
Oct-20 387 227 138 10.21 1575 2 4 9 4.125 24 4.125 5
Nov-20 1058 389 107 8.19 1340 1 1 2 3.375 21 3.375
Dec-20 1467 542 105 3.34 665 4 4 8 6.125 36.75 6.125 50 10
Jan-21 1401 449 131 9.72 1050 1 2 4 1.625 9.75 1.625 5 5
Feb-21 1110 436 116 8.64 1560 2 4 8 3.25 19.5 3.25 5 5
Mar-21 870 398 147 8.29 2683 3 6 11 5.375 32.25 5.5 55 13
Apr-21 506 163 102 9.71 1225 3 3 6 3.125 18.75 3.125 45
May-21 95 59 131 10.61 2360 4 3 6 9.25 55.5 9.25 5 10
Jun-21 26 6 90 6.63 1355 5 5 8 4.375 26.25 4.375 51
Jul-21 26 3 7 2.58 250 2 4 8 5.25 31.5 5.5 50 5
Aug-21 27 102 16 6.47 1445 3 0.125 5 10 5 32.25 5.875 65 5 5
Sep-21 25 66 37 9.64 1170 1 4 8 3.125 18.75 3.125 50 10
Oct-21 486 153 151 9.82 1085 2 6 8 3.25 19.5 3.25 55 5
Nov-21 689 104 241 8.45 975 1 7 14 4.875 29.25 4.875 40 10
Dec-21 1355 128 423 4.94 450 1 1 2 3.5 21 3.5 5 5
Jan-22 1420 509 190 15.03 2355 2 1 2 2.375 14.25 2.375 56
Feb-22 1253 435 172 10.48 1470 1 3 6 1.75 10.5 1.75 10 5
Mar-22 854 332 56 1.74 450 1 3 6 4.25 25.5 4.25 45 10
Apr-22 525 178 53 5.02 950 2 5 10 4.75 28.5 4.75 25 10
May-22 203 97 36 6.34 200 4 11 22 6.5 38.25 6.5 65 10
Jun-22 28 36 49 4.76 710 3 4 8 5.375 32.25 5.5 40 5
Jul-22 27 4 45 6.12 1000 4 3 8 2.75 16.5 2.75 30 5
Aug-22 26 59 5.45 1000 1 3 6 3.875 23.25 3.875 5 5
Sep-22 27 19 4.48 2 7 14 4 24 4 50 5
Oct-22 184 157 2.93 250 1 9 18 4.625 27.75 4.625 55 5
Nov-22 1265 419 65 1.74 2.2 1 2 4 2.875 17.25 2.875 20 5 5
Dec-22 1430 445 72 1.27 2 3 6 2.625 15.75 2.625 45 5
Jan-23 1370 496 88 2.7 450 1 1 2 2.125 12.75 2.125
Feb-23 1392 475 82 1.94 360 2 3 6 3.375 20.25 3.375 27.5 5
Mar-23 1170 444 75 4.3 580 5 7 5.25 31.5 5.25 40 5
Apr-23 298 274 90 5.8 900 3 2.75 16.5 2.75 25 5
May-23 32 33 58 4.44 200 3 2 1 3 18 3 30 5
Jun-23 25 24 63 5.78 565 1 8 16 3.375 29.25 4.375 37 5 5
Jul-23 26 6 30 5.46 650 2 1 2 4.25 25.5 4.25 15
Aug-23 25 31 9 2.55 100 4 8 4 24 4 60 10
Sep-23 26 37 35 1.25 410 4 6 5.125 30.75 5.125 20 5 5
Oct-23 165 99 77 5.78 1250 3 3 6 6.75 40.5 6.5 50
Nov-23 858 352 75 6.68 665 2 3 6 3.25 19.5 3.25 40 5
Dec-23 1252 487 73 3.85 675 1 3 6 3.25 19.5 3.25 20 5
Jan-24
UB107 DV16(w)DV16(b)SCA400
3.5 VOC
Anti-Sag
Additive
16 Oz Aerosol
Spray Cans -
Color White
16 Oz Aerosol
Spray Cans -
Color Black
16 Oz Aerosol
Spray Cans -
Clear Coat
[gal][gal][gal][gal]
0.1875 0.046875
0.09375 0.0390625
1 0.1171875 0.015625
2 0.046875 0.1015625
0.0703125 0.0703125
0.0546875
0.09375 0.0078125
0.078125 0.0703125
0.0078125 0.03125
0.046875
0.09375 0.09375
0.09375 0.09375
0.09375 0.09375
0.09375
0.09375
0.1875 0.09375
0.09375 0.09375
0.09375 0.09375
1
0.09375
0.09375 0.09375
2
1
0.1875
0.09375 0.09375
0.09375 0.09375
2
0.09375 0.1875
0.09375
0.09375 0.09375
0.09375
0.09375
0.09375
0.09375
1
1
0.09375
1
0.09375
1 0.09375
1 0.09375
1
2 0.1875
1
0.09375
Summary of Permit Limits
Williamsen-Godwin
Salt Lake City, UT
VOC Emission Limit Permit Limit:9.53 tons per rolling 12-month period
Month
Rolling 12-Month
Emissions
[TPY]
Percent of
Permit Limit
Feb-23 2.53 26.6%
Mar-23 2.53 26.6%
Apr-23 2.48 26.1%
May-23 2.26 23.7%
Jun-23 2.27 23.8%
Jul-23 2.22 23.3%
Aug-23 2.41 25.3%
Sep-23 2.32 24.4%
Oct-23 2.32 24.4%
Nov-23 2.39 25.1%
Dec-23 2.31 24.2%
Jan-24 2.27 23.8%
Total HAPs Emission Limit Permit Limit:8.46 tons per rolling 12-month period
Month
Rolling 12-Month
Emissions
[TPY]
Percent of
Permit Limit
Feb-23 1.82 21.5%
Mar-23 1.80 21.3%
Apr-23 1.79 21.1%
May-23 1.62 19.1%
Jun-23 1.63 19.3%
Jul-23 1.56 18.5%
Aug-23 1.76 20.9%
Sep-23 1.66 19.6%
Oct-23 1.63 19.2%
Nov-23 1.69 19.9%
Dec-23 1.59 18.8%
Jan-24 1.58 18.7%
0.0%
10.0%
20.0%
30.0%
40.0%
50.0%
60.0%
70.0%
80.0%
90.0%
100.0%
Dec-22 Jan-23 Mar-23 May-23 Jun-23 Aug-23 Oct-23 Nov-23 Jan-24 Feb-24
Pe
r
c
e
n
t
a
g
e

o
f

P
e
r
m
i
t

L
i
m
i
t
Month
VOC Emissions (Expressed as percentage of permit limit)
0.0%
10.0%
20.0%
30.0%
40.0%
50.0%
60.0%
70.0%
80.0%
90.0%
100.0%
Dec-22 Jan-23 Mar-23 May-23 Jun-23 Aug-23 Oct-23 Nov-23 Jan-24 Feb-24
Pe
r
c
e
n
t
a
g
e

o
f

P
e
r
m
i
t

L
i
m
i
t
Month
Total HAP Emissions (Expressed as percentage of permit limit)
BLENDING SOLVENT
Not available.
Liquid.
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Section 1. Identification
:
:
:
Product code :CFX240
Date of issue/Date of revision 1 March 2022
Version 19.02
Relevant identified uses of the substance or mixture and uses advised against
Uses advised against Not applicable.
Product use :Industrial applications.
Use of the substance/
mixture
:Solvent.
:
Manufacturer PPG Industries, Inc.
One PPG Place,
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
SETIQ Interior de la República: 800-00-214-00 (México)
SETIQ Ciudad de México: (55) 5559-1588 (México)
Emergency telephone
number
:
:
Technical Phone Number :1-800-647-6050
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the
substance or mixture
:
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 4.1%
(oral), 9.2% (dermal), 13% (inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
United States Page: 1/17
BLENDING SOLVENTProduct name
19.02Product code Date of issue VersionCFX2401 March 2022
Section 2. Hazards identification
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
Harmful if inhaled.
May cause respiratory irritation.
May cause drowsiness or dizziness.
May cause cancer.
May cause damage to organs through prolonged or repeated exposure. (hearing organs)
Hazard pictograms :
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or
in a well-ventilated area. Do not breathe vapor. Wash thoroughly after handling.
Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water. IF ON SKIN: Wash with plenty of water. If skin irritation
occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If
eye irritation persists: Get medical advice or attention.
Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep
cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label
elements
:Repeated exposure to high vapor concentrations may cause irritation of the respiratory
system and permanent brain and nervous system damage. Inhalation of vapor/aerosol
concentrations above the recommended exposure limits causes headaches,
drowsiness and nausea and may lead to unconsciousness or death. Avoid contact with
skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated.
Hazards not otherwise
classified
:Prolonged or repeated contact may dry skin and cause irritation.
Section 3. Composition/information on ingredients
Substance/mixture :Mixture
Product name BLENDING SOLVENT:
United States Page: 2/17
BLENDING SOLVENTProduct name
19.02Product code Date of issue VersionCFX2401 March 2022
Section 3. Composition/information on ingredients
4-methylpentan-2-one ≥20 - ≤50 108-10-1
2-methoxy-1-methylethyl acetate ≥20 - ≤50 108-65-6
xylene ≥10 - ≤20 1330-20-7
Solvent naphtha (petroleum), light aromatic ≥5.0 - ≤10 64742-95-6
1,2,4-trimethylbenzene ≥5.0 - ≤9.3 95-63-6
ethylbenzene ≥1.0 - ≤5.0 100-41-4
n-butyl acetate ≥1.0 - ≤5.0 123-86-4
cumene <1.0 98-82-8
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
SUB codes represent substances without registered CAS Numbers.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :
:Ingestion
Skin contact :
:Eye contact
Over-exposure signs/symptoms
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids
apart for at least 10 minutes and seek immediate medical advice.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
Causes serious eye irritation.
Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
drowsiness or dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression.
Causes skin irritation. Defatting to the skin.
United States Page: 3/17
BLENDING SOLVENTProduct name
19.02Product code Date of issue VersionCFX2401 March 2022
Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
No specific data.
Adverse symptoms may include the following:
irritation
redness
dryness
cracking
:
:
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon oxides
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Vapors may
accumulate in low or confined areas or travel a considerable distance to a source of
ignition and flash back. Runoff to sewer may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
United States Page: 4/17
BLENDING SOLVENTProduct name
19.02Product code Date of issue VersionCFX2401 March 2022
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Store
and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Special precautions :Vapors may accumulate in low or confined areas or travel a considerable distance to a
source of ignition and flash back. Vapors are heavier than air and may spread along
floors. If this material is part of a multiple component system, read the Safety Data
Sheet(s) for the other component or components before blending as the resulting
mixture may have the hazards of all of its parts.
United States Page: 5/17
BLENDING SOLVENTProduct name
19.02Product code Date of issue VersionCFX2401 March 2022
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 50°C (122°F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
:
4-methylpentan-2-one ACGIH TLV (United States, 1/2021).
STEL: 75 ppm 15 minutes.
TWA: 20 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 410 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
2-methoxy-1-methylethyl acetate IPEL (-, 10/2017). Absorbed through skin.
TWA: 30 ppm
STEL: 90 ppm
xylene ACGIH TLV (United States, 1/2021).
STEL: 651 mg/m³ 15 minutes.
STEL: 150 ppm 15 minutes.
TWA: 434 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
Solvent naphtha (petroleum), light aromatic None.
1,2,4-trimethylbenzene ACGIH TLV (United States, 1/2021).
TWA: 123 mg/m³ 8 hours.
TWA: 25 ppm 8 hours.
ethylbenzene ACGIH TLV (United States, 1/2021).
TWA: 20 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
n-butyl acetate OSHA PEL (United States, 5/2018).
TWA: 710 mg/m³ 8 hours.
TWA: 150 ppm 8 hours.
ACGIH TLV (United States, 1/2021).
STEL: 150 ppm 15 minutes.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
United States Page: 6/17
BLENDING SOLVENTProduct name
19.02Product code Date of issue VersionCFX2401 March 2022
Section 8. Exposure controls/personal protection
TWA: 50 ppm 8 hours.
cumene ACGIH TLV (United States, 1/2021).
TWA: 5 ppm 8 hours.
OSHA PEL (United States, 5/2018).
Absorbed through skin.
TWA: 245 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Eye/face protection
:
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Recommended monitoring
procedures
:If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Chemical splash goggles.
Key to abbreviations
A Acceptable Maximum Peak=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
TD =Total dust
Consult local authorities for acceptable exposure limits.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
STEL =
=
Short term Exposure limit values
United States Page: 7/17
BLENDING SOLVENTProduct name
19.02Product code Date of issue VersionCFX2401 March 2022
Section 8. Exposure controls/personal protection
Respiratory protection :
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Other skin protection :
Gloves For prolonged or repeated handling, use the following type of gloves:
Recommended: butyl rubber, polyvinyl alcohol (PVA), Viton®
May be used: Chloroprene, nitrile rubber
:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.
The respiratory protection shall be in accordance to 29 CFR 1910.134.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
0.87
Not available.
Not available.
Partially soluble in the following materials: cold water.
Not available.Odor
pH
Clear.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 23.89°C (75°F)
Not applicable.
Not available.
Viscosity Kinematic (40°C (104°F)): >21 mm2/s (>21 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :>37.78°C (>100°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
Bulk Density (g/cm³):0.868
Density ( lbs / gal ):7.26
United States Page: 8/17
BLENDING SOLVENTProduct name
19.02Product code Date of issue VersionCFX2401 March 2022
Section 9. Physical and chemical properties
% Solid. (w/w):4.131
Volatility :97% (v/v), 95.869% (w/w)
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
The product is stable.Chemical stability :
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
When exposed to high temperatures may produce hazardous decomposition products.
Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
Refer to protective measures listed in sections 7 and 8.
Depending on conditions, decomposition products may include the following materials:
carbon oxides
Section 11. Toxicological information
Acute toxicity
4-methylpentan-2-one LC50 Inhalation Vapor Rat 12.3 mg/l 4 hours
LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 2.08 g/kg -
2-methoxy-1-methylethyl
acetate
LC50 Inhalation Vapor Rat 30 mg/l 4 hours
LD50 Dermal Rabbit >5 g/kg -
LD50 Oral Rat 6190 mg/kg -
xylene LD50 Dermal Rabbit 1.7 g/kg -
LD50 Oral Rat 4.3 g/kg -
Solvent naphtha (petroleum),
light aromatic
LD50 Dermal Rabbit 3.48 g/kg -
LD50 Oral Rat 8400 mg/kg -
1,2,4-trimethylbenzene LC50 Inhalation Vapor Rat 18000 mg/m³4 hours
LD50 Oral Rat 5 g/kg -
ethylbenzene LC50 Inhalation Vapor Rat 17.8 mg/l 4 hours
LD50 Dermal Rabbit 17.8 g/kg -
LD50 Oral Rat 3.5 g/kg -
n-butyl acetate LC50 Inhalation Vapor Rat >21.1 mg/l 4 hours
LC50 Inhalation Vapor Rat 2000 ppm 4 hours
LD50 Dermal Rabbit >17600 mg/kg -
LD50 Oral Rat 10.768 g/kg -
cumene LC50 Inhalation Vapor Rat 39000 mg/m³4 hours
LD50 Dermal Rabbit 12.3 g/kg -
Product/ingredient name Result Species Dose Exposure
Information on toxicological effects
United States Page: 9/17
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19.02Product code Date of issue VersionCFX2401 March 2022
Section 11. Toxicological information
LD50 Oral Rat 1400 mg/kg -
Conclusion/Summary :
Carcinogenicity
Conclusion/Summary :
Mutagenicity
Conclusion/Summary :
Teratogenicity
Conclusion/Summary :
Reproductive toxicity
Conclusion/Summary :
Irritation/Corrosion
xylene Skin - Moderate irritant Rabbit -24 hours 500
mg
-
Product/ingredient name Result Score Exposure Observation
Conclusion/Summary
Skin :
Eyes :
Respiratory :
Sensitization
Conclusion/Summary
Skin :
Respiratory :
Species
Specific target organ toxicity (single exposure)
Classification
4-methylpentan-2-one -2B -
xylene -3 -
ethylbenzene -2B -
cumene -2B Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Carcinogen Classification code:
IARC: 1, 2A, 2B, 3, 4
NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen
OSHA: +
Not listed/not regulated: -
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Name
4-methylpentan-2-one Category 3 -Respiratory tract
irritation
2-methoxy-1-methylethyl acetate Category 3 -Narcotic effects
xylene Category 3 -Respiratory tract
irritation
Solvent naphtha (petroleum), light aromatic Category 3 -Narcotic effects
1,2,4-trimethylbenzene Category 3 -Respiratory tract
Category Route of
exposure
Target organs
United States Page: 10/17
BLENDING SOLVENTProduct name
19.02Product code Date of issue VersionCFX2401 March 2022
Section 11. Toxicological information
Information on the likely routes of exposure
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (repeated exposure)
Aspiration hazard
Name Result
xylene ASPIRATION HAZARD - Category 1
Solvent naphtha (petroleum), light aromatic ASPIRATION HAZARD - Category 1
ethylbenzene ASPIRATION HAZARD - Category 1
cumene ASPIRATION HAZARD - Category 1
Potential acute health effects
Inhalation :Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
drowsiness or dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression.:Ingestion
Skin contact :Causes skin irritation. Defatting to the skin.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
No specific data.
Adverse symptoms may include the following:
irritation
redness
dryness
cracking
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Target organs :Contains material which causes damage to the following organs: brain, central nervous
system (CNS).
Contains material which may cause damage to the following organs: blood, kidneys,
lungs, the nervous system, liver, upper respiratory tract, skin, ears, eye, lens or cornea.
irritation
n-butyl acetate Category 3 -Narcotic effects
cumene Category 3 -Respiratory tract
irritation
Name Category
ethylbenzene Category 2 -hearing organs
cumene Category 2 --
Route of
exposure
Target organs
United States Page: 11/17
BLENDING SOLVENTProduct name
19.02Product code Date of issue VersionCFX2401 March 2022
Section 11. Toxicological information
Conclusion/Summary :
General :
Carcinogenicity :
Mutagenicity :
Reproductive toxicity :
Potential chronic health effects
Numerical measures of toxicity
Acute toxicity estimates
Potential immediate
effects
:
Short term exposure
Potential delayed effects :
Potential immediate
effects
:
Long term exposure
Potential delayed effects :
May cause cancer. Risk of cancer depends on duration and level of exposure.
There are no data available on the mixture itself. Exposure to component solvent vapor
concentrations in excess of the stated occupational exposure limit may result in adverse
health effects such as mucous membrane and respiratory system irritation and adverse
effects on the kidneys, liver and central nervous system. Symptoms and signs include
headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases,
loss of consciousness. Solvents may cause some of the above effects by absorption
through the skin. There is some evidence that repeated exposure to organic solvent
vapors in combination with constant loud noise can cause greater hearing loss than
expected from exposure to noise alone. If splashed in the eyes, the liquid may cause
irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic
effects of components from short-term and long-term exposure by oral, inhalation and
dermal routes of exposure and eye contact.
May cause damage to organs through prolonged or repeated exposure. Prolonged or
repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Product/ingredient name
BLENDING SOLVENT 4499.6 8136.5 N/A 18.3 2.2
4-methylpentan-2-one 2080 N/A N/A 12.3 1.5
2-methoxy-1-methylethyl acetate 6190 N/A N/A 30 N/A
xylene 4300 1700 N/A 11 1.5
Solvent naphtha (petroleum), light aromatic 8400 3480 N/A N/A N/A
1,2,4-trimethylbenzene 5000 N/A N/A 18 1.5
ethylbenzene 3500 17800 N/A 17.8 1.5
n-butyl acetate 10768 N/A N/A N/A N/A
cumene 1400 12300 N/A 39 N/A
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm)
Inhalation
(vapors)
(mg/l)
Inhalation
(dusts and
mists) (mg/
l)
United States Page: 12/17
BLENDING SOLVENTProduct name
19.02Product code Date of issue VersionCFX2401 March 2022
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
4-methylpentan-2-one 1.9 -low
2-methoxy-1-methylethyl
acetate
1.2 -low
xylene 3.12 7.4 to 18.5 low
1,2,4-trimethylbenzene 3.63 120.23 low
ethylbenzene 3.6 79.43 low
n-butyl acetate 2.3 -low
cumene 3.55 35.48 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
4-methylpentan-2-one --Readily
2-methoxy-1-methylethyl
acetate
--Readily
xylene --Readily
ethylbenzene --Readily
n-butyl acetate --Readily
Toxicity
4-methylpentan-2-one Acute LC50 >179 mg/l Fish 96 hours
2-methoxy-1-methylethyl
acetate
Acute LC50 134 mg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
Solvent naphtha (petroleum),
light aromatic
Acute LC50 8.2 mg/l Fish 96 hours
ethylbenzene Acute EC50 1.8 mg/l Fresh water Daphnia 48 hours
Chronic NOEC 1 mg/l Fresh water Daphnia - Ceriodaphnia dubia -
n-butyl acetate Acute LC50 18 mg/l Fish 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
4-methylpentan-2-one OECD 301F 83 % - Readily - 28 days --
2-methoxy-1-methylethyl
acetate
-83 % - Readily - 28 days --
ethylbenzene -79 % - Readily - 10 days --
n-butyl acetate TEPA and OECD
301D
83 % - Readily - 28 days --
Product/ingredient name Test DoseResult Inoculum
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
United States Page: 13/17
BLENDING SOLVENTProduct name
19.02Product code Date of issue VersionCFX2401 March 2022
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
14. Transport information
PAINT RELATED MATERIAL
3
III
PAINT RELATED MATERIAL
3
III
PAINT RELATED MATERIAL
UN1263
3
III
UN1263 UN1263
DOT IMDG IATA
UN number
UN proper shipping
name
Transport hazard class
(es)
Packing group
Environmental hazards No.No.No.
Marine pollutant
substances
Not applicable.Not applicable.
RQ substances
604.19
(xylene, 4-methylpentan-
2-one)
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
Package sizes shipped in quantities less than the product reportable quantity are not subject to the
RQ (reportable quantity) transportation requirements.
None identified.
DOT
IMDG
:
:
IATA :None identified.
Product RQ (lbs)
United States Page: 14/17
BLENDING SOLVENTProduct name
19.02Product code Date of issue VersionCFX2401 March 2022
14. Transport information
Transport in bulk according
to IMO instruments
:Not applicable.
Section 15. Regulatory information
SARA 302/304
SARA 304 RQ :Not applicable.
Composition/information on ingredients
All components are active or exempted.United States inventory (TSCA 8b):
United States
No products were found.
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
HNOC - Defatting irritant
4-methylpentan-2-one ≥20 - ≤50 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
HNOC - Defatting irritant
2-methoxy-1-methylethyl acetate ≥20 - ≤50 FLAMMABLE LIQUIDS - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
xylene ≥10 - ≤20 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
ASPIRATION HAZARD - Category 1
Solvent naphtha (petroleum),
light aromatic
≥5.0 - ≤10 FLAMMABLE LIQUIDS - Category 3
SKIN IRRITATION - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
ASPIRATION HAZARD - Category 1
Name %Classification
Composition/information on ingredients
United States Page: 15/17
BLENDING SOLVENTProduct name
19.02Product code Date of issue VersionCFX2401 March 2022
Section 15. Regulatory information
SARA 313
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
California Prop. 65
Supplier notification
Chemical name
:4-methylpentan-2-one 108-10-1 15 - 40
xylene 1330-20-7 10 - 30
1,2,4-trimethylbenzene 95-63-6 3 - 7
ethylbenzene 100-41-4 1 - 5
cumene 98-82-8 0.1 - 1
CAS number Concentration
HNOC - Defatting irritant
1,2,4-trimethylbenzene ≥5.0 - ≤9.3 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
HNOC - Defatting irritant
ethylbenzene ≥1.0 - ≤5.0 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
HNOC - Defatting irritant
n-butyl acetate ≥1.0 - ≤5.0 FLAMMABLE LIQUIDS - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
HNOC - Defatting irritant
cumene <1.0 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (oral) - Category 4
CARCINOGENICITY - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
HNOC - Defatting irritant
WARNING: Cancer and Reproductive Harm - www.P65Warnings.ca.gov.
United States Page: 16/17
BLENDING SOLVENTProduct name
19.02Product code Date of issue VersionCFX2401 March 2022
Section 16. Other information
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Hazardous Material Information System (U.S.A.)
3
03
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Date of previous issue 6/13/2021:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Indicates information that has changed from previously issued version.
Organization that prepared
the SDS
:EHS
:::
:::2 *
2
0
( * ) - Chronic effects
United States Page: 17/17
SUPER ACCELERATOR
Not available.
Liquid.
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Section 1. Identification
:
:
:
Product code :CFX849
Date of issue/Date of revision 9 November 2021
Version 14.02
Relevant identified uses of the substance or mixture and uses advised against
Coating. Paints. Painting-related materials.
Uses advised against Not applicable.
Product use :Industrial applications.
Use of the substance/
mixture
:
:
Manufacturer PPG Industries, Inc.
One PPG Place,
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
SETIQ Interior de la República: 800-00-214-00 (México)
SETIQ Ciudad de México: (55) 5559-1588 (México)
Emergency telephone
number
:
:
Technical Phone Number :1-800-647-6050
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (dermal) - Category 3
ACUTE TOXICITY (inhalation) - Category 3
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
GERM CELL MUTAGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1
Classification of the
substance or mixture
:
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 4.6%
(dermal), 4.6% (inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
United States Page: 1/14
SUPER ACCELERATORProduct name
14.02Product code Date of issue VersionCFX8499 November 2021
Section 2. Hazards identification
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Harmful if swallowed.
Toxic in contact with skin or if inhaled.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye damage.
Suspected of causing genetic defects.
May damage fertility or the unborn child.
Causes damage to organs. (thymus)
Causes damage to organs through prolonged or repeated exposure. (immune system)
Hazard pictograms :
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response :IF exposed: Call a POISON CENTER or doctor. IF INHALED: Remove person to fresh
air and keep comfortable for breathing. Call a POISON CENTER or doctor. IF
SWALLOWED: Call a POISON CENTER or doctor if you feel unwell. Rinse mouth. IF
ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
Wash contaminated clothing before reuse. IF ON SKIN: Call a POISON CENTER or
doctor if you feel unwell. Wash with plenty of water. If skin irritation or rash occurs: Get
medical advice or attention. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor.
Storage :Store locked up. Store in a well-ventilated place. Keep cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label
elements
:Repeated exposure to high vapor concentrations may cause irritation of the respiratory
system and permanent brain and nervous system damage. Inhalation of vapor/aerosol
concentrations above the recommended exposure limits causes headaches,
drowsiness and nausea and may lead to unconsciousness or death. Emits toxic fumes
when heated.
Hazards not otherwise
classified
:None known.
United States Page: 2/14
SUPER ACCELERATORProduct name
14.02Product code Date of issue VersionCFX8499 November 2021
Section 3. Composition/information on ingredients
pentane-2,4-dione ≥90 123-54-6
dibutyltin dilaurate ≥1.0 - <5.0 77-58-7
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Product name SUPER ACCELERATOR:
SUB codes represent substances without registered CAS Numbers.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :
:Ingestion
Skin contact :
:Eye contact
Over-exposure signs/symptoms
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
Eye contact :Adverse symptoms may include the following:
pain
watering
redness
Potential acute health effects
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Check for and remove any contact lenses. Immediately flush eyes with running water for
at least 15 minutes, keeping eyelids open. Seek immediate medical attention.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
Causes serious eye damage.
Toxic if inhaled.
Harmful if swallowed. Causes damage to organs following a single exposure if
swallowed.
Toxic in contact with skin. Causes damage to organs following a single exposure in
contact with skin. Causes skin irritation. May cause an allergic skin reaction.
United States Page: 3/14
SUPER ACCELERATORProduct name
14.02Product code Date of issue VersionCFX8499 November 2021
Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Skin contact
Ingestion Adverse symptoms may include the following:
stomach pains
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon oxides
metal oxide/oxides
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Runoff to sewer may
create fire or explosion hazard. Fire water contaminated with this material must be
contained and prevented from being discharged to any waterway, sewer or drain.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
United States Page: 4/14
SUPER ACCELERATORProduct name
14.02Product code Date of issue VersionCFX8499 November 2021
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities.
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not ingest. Avoid release to the environment. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas
and confined spaces unless adequately ventilated. Keep in the original container or an
approved alternative made from a compatible material, kept tightly closed when not in
use. Store and use away from heat, sparks, open flame or any other ignition source.
Use explosion-proof electrical (ventilating, lighting and material handling) equipment.
Use only non-sparking tools. Take precautionary measures against electrostatic
discharges. Empty containers retain product residue and can be hazardous. Do not
reuse container.
:
Precautions for safe handling
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SUPER ACCELERATORProduct name
14.02Product code Date of issue VersionCFX8499 November 2021
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store below the following temperature: 5°C (41°F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
:
Special precautions :If this material is part of a multiple component system, read the Safety Data Sheet(s) for
the other component or components before blending as the resulting mixture may have
the hazards of all of its parts.
pentane-2,4-dione ACGIH TLV (United States, 1/2021).
Absorbed through skin.
TWA: 25 ppm 8 hours.
dibutyltin dilaurate ACGIH TLV (United States, 1/2021).
Absorbed through skin.
STEL: 0.2 mg/m³, (as Sn) 15 minutes.
TWA: 0.1 mg/m³, (as Sn) 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 0.1 mg/m³, (as Sn) 8 hours.
OSHA PEL (United States).
TWA: 0.1 mg/m³, (as Sn)
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
Recommended monitoring
procedures
:If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Key to abbreviations
A Acceptable Maximum Peak=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
TD =Total dust
Consult local authorities for acceptable exposure limits.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
STEL =
=
Short term Exposure limit values
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SUPER ACCELERATORProduct name
14.02Product code Date of issue VersionCFX8499 November 2021
Section 8. Exposure controls/personal protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :
Chemical splash goggles and face shield.
Gloves butyl rubber:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.
The respiratory protection shall be in accordance to 29 CFR 1910.134.
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SUPER ACCELERATORProduct name
14.02Product code Date of issue VersionCFX8499 November 2021
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
0.98
Not available.
Not available.
Partially soluble in the following materials: cold water.
Not available.Odor
pH
Not available.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 35.56°C (96°F)
Not applicable.
Not available.
Viscosity Kinematic (40°C (104°F)): >21 mm2/s (>21 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :>37.78°C (>100°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
% Solid. (w/w):4.771
Density ( lbs / gal ):8.18
Volatility :96% (v/v), 95.229% (w/w)
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
The product is stable.Chemical stability :
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
When exposed to high temperatures may produce hazardous decomposition products.
Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
Refer to protective measures listed in sections 7 and 8.
Depending on conditions, decomposition products may include the following materials:
carbon oxides metal oxide/oxides
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SUPER ACCELERATORProduct name
14.02Product code Date of issue VersionCFX8499 November 2021
Section 11. Toxicological information
Acute toxicity
pentane-2,4-dione LC50 Inhalation Vapor Rat 5.1 mg/l 4 hours
LD50 Dermal Rat 790 mg/kg -
LD50 Oral Rat 570 mg/kg -
dibutyltin dilaurate LD50 Oral Rat 2071 mg/kg -
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary :
Carcinogenicity
Conclusion/Summary :
Mutagenicity
Conclusion/Summary :
Teratogenicity
Conclusion/Summary :
Reproductive toxicity
Conclusion/Summary :
Irritation/Corrosion
Conclusion/Summary
Skin :
Eyes :
Respiratory :
Sensitization
Conclusion/Summary
Skin :
Respiratory :
Specific target organ toxicity (single exposure)
Information on toxicological effects
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Specific target organ toxicity (repeated exposure)
Aspiration hazard
Not available.
Target organs :Contains material which causes damage to the following organs: mucous membranes,
brain, .
Contains material which may cause damage to the following organs: blood, kidneys, the
nervous system, liver, bladder, upper respiratory tract, immune system, skin, central
nervous system (CNS), eye, lens or cornea.
Name
dibutyltin dilaurate Category 1 -thymus
Category Route of
exposure
Target organs
Name Category
dibutyltin dilaurate Category 1 oral immune system
Route of
exposure
Target organs
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SUPER ACCELERATORProduct name
14.02Product code Date of issue VersionCFX8499 November 2021
Section 11. Toxicological information
Conclusion/Summary :
Information on the likely routes of exposure
Delayed and immediate effects and also chronic effects from short and long term exposure
Potential immediate
effects
:
Short term exposure
Potential delayed effects :
Potential immediate
effects
:
Long term exposure
Potential acute health effects
Inhalation :Toxic if inhaled.
Harmful if swallowed. Causes damage to organs following a single exposure if
swallowed.
:Ingestion
Skin contact :Toxic in contact with skin. Causes damage to organs following a single exposure in
contact with skin. Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye damage.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
stomach pains
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain
watering
redness
There are no data available on the mixture itself. Exposure to component solvent vapor
concentrations in excess of the stated occupational exposure limit may result in adverse
health effects such as mucous membrane and respiratory system irritation and adverse
effects on the kidneys, liver and central nervous system. Symptoms and signs include
headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases,
loss of consciousness. Solvents may cause some of the above effects by absorption
through the skin. There is some evidence that repeated exposure to organic solvent
vapors in combination with constant loud noise can cause greater hearing loss than
expected from exposure to noise alone. If splashed in the eyes, the liquid may cause
irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic
effects of components from short-term and long-term exposure by oral, inhalation and
dermal routes of exposure and eye contact.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
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SUPER ACCELERATORProduct name
14.02Product code Date of issue VersionCFX8499 November 2021
Section 11. Toxicological information
General :
Carcinogenicity :
Mutagenicity :
Reproductive toxicity :
Potential chronic health effects
Numerical measures of toxicity
Acute toxicity estimates
Potential delayed effects :
No known significant effects or critical hazards.
Causes damage to organs through prolonged or repeated exposure. Once sensitized, a
severe allergic reaction may occur when subsequently exposed to very low levels.
May damage fertility or the unborn child.
Suspected of causing genetic defects.
There are no data available on the mixture itself.
Product/ingredient name
SUPER ACCELERATOR 593.6 833.7 N/A 5.4 N/A
pentane-2,4-dione 570 790 N/A 5.1 N/A
dibutyltin dilaurate 2071 N/A N/A N/A N/A
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm)
Inhalation
(vapors)
(mg/l)
Inhalation
(dusts and
mists) (mg/
l)
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
pentane-2,4-dione 0.68 -low
dibutyltin dilaurate 4.44 -high
Toxicity
dibutyltin dilaurate EC50 0.463 mg/l Daphnia 48 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
United States Page: 11/14
SUPER ACCELERATORProduct name
14.02Product code Date of issue VersionCFX8499 November 2021
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
14. Transport information
PENTANE-2,4-DIONE
3 (6.1)
III
PENTANE-2,4-DIONE
3 (6.1)
III
PENTANE-2,4-DIONE
UN2310
3 (6.1)
III
UN2310 UN2310
DOT IMDG IATA
UN number
UN proper shipping
name
Transport hazard class
(es)
Packing group
Environmental hazards No.Yes.Yes. The environmentally
hazardous substance mark is
not required.
Marine pollutant
substances
Not applicable.(dibutyltin dilaurate)Not applicable.
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
None identified.
The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
DOT
IMDG
:
:
IATA :The environmentally hazardous substance mark may appear if required by other transportation
regulations.
Transport in bulk according
to IMO instruments
:Not applicable.
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SUPER ACCELERATORProduct name
14.02Product code Date of issue VersionCFX8499 November 2021
Section 15. Regulatory information
SARA 302/304
SARA 304 RQ :Not applicable.
Composition/information on ingredients
All components are active or exempted.United States inventory (TSCA 8b):
United States
United States - TSCA 12(b) - Chemical export notification:
pentane-2,4-dione One time notification
United States - TSCA 5(a)2 - Proposed significant new use rules:
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
No products were found.
pentane-2,4-dione Listed
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (dermal) - Category 3
ACUTE TOXICITY (inhalation) - Category 3
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
GERM CELL MUTAGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1
pentane-2,4-dione ≥90 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (dermal) - Category 3
ACUTE TOXICITY (inhalation) - Category 3
dibutyltin dilaurate ≥1.0 - <5.0 SKIN CORROSION - Category 1C
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
GERM CELL MUTAGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) -
Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 1
Name %Classification
Composition/information on ingredients
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SUPER ACCELERATORProduct name
14.02Product code Date of issue VersionCFX8499 November 2021
Section 16. Other information
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Hazardous Material Information System (U.S.A.)
3
03
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Date of previous issue 6/13/2021:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Indicates information that has changed from previously issued version.
Organization that prepared
the SDS
:EHS
:::
:::3 *
3
0
( * ) - Chronic effects
United States Page: 14/14
2.1 VOC CORROSION RESISTANT EPOXY PRIMER - WHITE
Not available.
Liquid.
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Section 1. Identification
:
:
:
Product code :CRE-121
Date of issue/Date of revision 21 November 2022
Version 23
Relevant identified uses of the substance or mixture and uses advised against
Coating. Paints. Painting-related materials.
Uses advised against Not applicable.
Product use :Industrial applications.
Use of the substance/
mixture
:
:
Manufacturer PPG Industries, Inc.
One PPG Place,
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
SETIQ Interior de la República: 800-00-214-00 (México)
SETIQ Ciudad de México: (55) 5559-1588 (México)
Emergency telephone
number
:
:
Technical Phone Number :1-800-647-6050
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 2
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 1A
TOXIC TO REPRODUCTION - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the
substance or mixture
:
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 1.1%
(oral), 26.4% (dermal), 28.5% (inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
United States Page: 1/18
2.1 VOC CORROSION RESISTANT EPOXY PRIMER - WHITEProduct name
23Product code Date of issue VersionCRE-121 21 November 2022
Section 2. Hazards identification
Signal word :Danger
Hazard statements :Highly flammable liquid and vapor.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye damage.
May cause cancer.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Hazard pictograms :
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Keep container
tightly closed. Do not breathe vapor. Wash thoroughly after handling. Contaminated
work clothing must not be allowed out of the workplace.
Response :IF exposed or concerned: Get medical advice or attention. IF ON SKIN (or hair): Take
off immediately all contaminated clothing. Rinse skin with water. Wash contaminated
clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash
occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor.
Storage :Store locked up. Store in a well-ventilated place. Keep cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
GHS label elements
Supplemental label
elements
:Sanding and grinding dusts may be harmful if inhaled. This product contains crystalline
silica which can cause lung cancer or silicosis. The risk of cancer depends on the
duration and level of exposure to dust from sanding surfaces or mist from spray
applications. Trimethoxysilanes are capable of forming methanol if hydrolyzed or
ingested. If swallowed, methanol may be harmful or fatal or cause blindness. Repeated
exposure to high vapor concentrations may cause irritation of the respiratory system
and permanent brain and nervous system damage. Inhalation of vapor/aerosol
concentrations above the recommended exposure limits causes headaches,
drowsiness and nausea and may lead to unconsciousness or death. This product either
contains formaldehyde or is capable of releasing formaldehyde above 0.5 ppm under
certain conditions. Formaldehyde is a known cancer hazard, a skin sensitizer and a
This product contains TiO2 which has been classified as a GHS Carcinogen Category 2
based on its IARC 2B classification. For many products, TiO2 is utilized as a raw
material in a liquid coating formulation. In this case, the TiO2 particles are bound in a
matrix with no meaningful potential for human exposure to unbound particles of TiO2
when the product is applied with a brush or roller. Sanding the coating surface or mist
from spray applications may be harmful depending on the duration and level of
exposure and require the use of appropriate personal protective equipment and/or
engineering controls (see Section 8).
United States Page: 2/18
2.1 VOC CORROSION RESISTANT EPOXY PRIMER - WHITEProduct name
23Product code Date of issue VersionCRE-121 21 November 2022
Section 2. Hazards identification
respiratory sensitizer. Avoid contact with skin and clothing. Wash thoroughly after
handling. Emits toxic fumes when heated.
Hazards not otherwise
classified
:Prolonged or repeated contact may dry skin and cause irritation.
Section 3. Composition/information on ingredients
bis-[4-(2,3-epoxipropoxi)phenyl]propane ≥20 - ≤50 1675-54-3
Limestone ≥10 - ≤20 1317-65-3
4-chloro-α,α,α-trifluorotoluene ≥10 - ≤14 98-56-6
titanium dioxide ≥10 - ≤20 13463-67-7
4-methylpentan-2-one ≥10 - ≤15 108-10-1
Talc , not containing asbestiform fibres ≥1.0 - ≤3.9 14807-96-6
[3-(2,3-epoxypropoxy)propyl]trimethoxysilane ≥1.0 - ≤5.0 2530-83-8
3-butoxypropan-2-ol ≥1.0 - ≤3.8 5131-66-8
acetone ≥0.10 - ≤2.4 67-64-1
toluene ≤1.9 108-88-3
Alpha, Alpha"-(1,3-Xylenediyl)Bis(12-Hydroxy-Octadecanamide)≤1.1 Not available.
crystalline silica, respirable powder (<10 microns)<1.0 14808-60-7
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Product name 2.1 VOC CORROSION RESISTANT EPOXY PRIMER - WHITE:
SUB codes represent substances without registered CAS Numbers.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Potential acute health effects
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Check for and remove any contact lenses. Immediately flush eyes with running water for
at least 15 minutes, keeping eyelids open. Seek immediate medical attention.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
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Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments :No specific treatment.
Inhalation :
:Ingestion
Skin contact :
:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
stomach pains
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain
watering
redness
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Causes serious eye damage.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.
Section 5. Fire-fighting measures
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon oxides
nitrogen oxides
phosphorus oxides
halogenated compounds
carbonyl halides
metal oxide/oxides
Formaldehyde.
Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur
and the container may burst, with the risk of a subsequent explosion. Vapors may
accumulate in low or confined areas or travel a considerable distance to a source of
ignition and flash back. Runoff to sewer may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
:
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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Section 6. Accidental release measures
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 50°C (122°F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Special precautions :Vapors may accumulate in low or confined areas or travel a considerable distance to a
source of ignition and flash back. Vapors are heavier than air and may spread along
floors. If this material is part of a multiple component system, read the Safety Data
Sheet(s) for the other component or components before blending as the resulting
mixture may have the hazards of all of its parts.
bis-[4-(2,3-epoxipropoxi)phenyl]propane None.
Limestone OSHA PEL (United States, 5/2018).
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
4-chloro-α,α,α-trifluorotoluene IPEL (-).
TWA: 0.57 ppm
STEL: 1.71 ppm
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Section 8. Exposure controls/personal protection
titanium dioxide OSHA PEL (United States, 5/2018).
TWA: 15 mg/m³ 8 hours. Form: Total dust
ACGIH TLV (United States, 1/2022).
TWA: 2.5 mg/m³ 8 hours. Form: respirable
fraction, finescale particles
4-methylpentan-2-one ACGIH TLV (United States, 1/2022).
STEL: 75 ppm 15 minutes.
TWA: 20 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 410 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
Talc , not containing asbestiform fibres ACGIH TLV (United States, 1/2022).
TWA: 2 mg/m³ 8 hours. Form: Respirable
OSHA PEL Z3 (United States).
TWA: 2 mg/m³
[3-(2,3-epoxypropoxy)propyl]trimethoxysilane None.
3-butoxypropan-2-ol IPEL (-).
TWA: 50 ppm
acetone ACGIH TLV (United States, 1/2022).
STEL: 500 ppm 15 minutes.
TWA: 250 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 2400 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.
toluene OSHA PEL Z2 (United States, 2/2013).
AMP: 500 ppm 10 minutes.
CEIL: 300 ppm
TWA: 200 ppm 8 hours.
ACGIH TLV (United States, 1/2022).
Ototoxicant.
TWA: 20 ppm 8 hours.
Alpha, Alpha"-(1,3-Xylenediyl)Bis(12-Hydroxy-Octadecanamide)None.
crystalline silica, respirable powder (<10 microns)ACGIH TLV (United States, 1/2022). [Silica,
crystalline]
TWA: 0.025 mg/m³ 8 hours. Form:
Respirable
OSHA PEL Z3 (United States, 6/2016).
TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form:
Respirable
TWA: 250 mppcf / (%SiO2+5) 8 hours. Form:
Respirable
OSHA PEL (United States, 5/2018). [Silica,
crystalline]
TWA: 50 µg/m³ 8 hours. Form: Respirable
dust
Key to abbreviations
A Acceptable Maximum Peak=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
TD =Total dust
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
STEL =
=
Short term Exposure limit values
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Section 8. Exposure controls/personal protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :
Recommended monitoring
procedures
:Reference should be made to appropriate monitoring standards. Reference to national
guidance documents for methods for the determination of hazardous substances will
also be required.
Chemical splash goggles and face shield.
Gloves butyl rubber:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.
Consult local authorities for acceptable exposure limits.
OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
The respiratory protection shall be in accordance to 29 CFR 1910.134.
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Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Liquid.
Not available.
1.47
Not available.
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 18.33°C (65°F)
Not applicable.
Not applicable.
Viscosity Kinematic (40°C (104°F)): >21 mm2/s (>21 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :>37.78°C (>100°F)
Flammability :Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
% Solid. (w/w):69.751
Density ( lbs / gal ):12.27
Volatility :44% (v/v), 30.249% (w/w)
Solubility(ies):Media Result
cold water Not soluble
Section 10. Stability and reactivity
Conditions to avoid
The product is stable.Chemical stability :
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
When exposed to high temperatures may produce hazardous decomposition products.
Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
Refer to protective measures listed in sections 7 and 8.
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Section 10. Stability and reactivity
Hazardous decomposition
products
:Depending on conditions, decomposition products may include the following materials:
carbon oxides nitrogen oxides phosphorus oxides halogenated compounds
Formaldehyde. carbonyl halides metal oxide/oxides
Section 11. Toxicological information
Acute toxicity
bis-[4-(2,3-epoxipropoxi)
phenyl]propane
LD50 Dermal Rabbit 23000 mg/kg -
LD50 Oral Rat 15000 mg/kg -
Limestone LD50 Oral Rat 6450 mg/kg -
4-chloro-α,α,α-trifluorotoluene LC50 Inhalation Vapor Rat 33080 mg/m³4 hours
LD50 Dermal Rabbit >2.7 g/kg -
LD50 Oral Rat 13 g/kg -
titanium dioxide LC50 Inhalation Dusts and mists Rat >6.82 mg/l 4 hours
LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
4-methylpentan-2-one LC50 Inhalation Vapor Rat 11 mg/l 4 hours
LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 2.08 g/kg -
[3-(2,3-epoxypropoxy)propyl]
trimethoxysilane
LC50 Inhalation Dusts and mists Rat >5300 mg/m³4 hours
LD50 Dermal Rabbit 4.3 g/kg -
LD50 Oral Rat 7.01 g/kg -
3-butoxypropan-2-ol LD50 Dermal Rabbit 3100 mg/kg -
LD50 Oral Rat 2.2 g/kg -
acetone LC50 Inhalation Vapor Rat 76000 mg/m³4 hours
LD50 Dermal Rabbit 15.8 g/kg -
LD50 Oral Rat 5800 mg/kg -
toluene LC50 Inhalation Vapor Rat 49 g/m³4 hours
LD50 Dermal Rabbit 8.39 g/kg -
LD50 Oral Rat 5580 mg/kg -
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary :
Irritation/Corrosion
bis-[4-(2,3-epoxipropoxi)
phenyl]propane
Eyes - Mild irritant Rabbit -24 hours -
Eyes - Redness of the
conjunctivae
Rabbit 0.4 24 hours -
Skin - Edema Rabbit 0.5 4 hours -
Skin - Erythema/Eschar Rabbit 0.8 4 hours -
Skin - Mild irritant Rabbit -4 hours -
[3-(2,3-epoxypropoxy)propyl]
trimethoxysilane
Eyes - Cornea opacity Rabbit 11.8 1 minutes 24 hours
Product/ingredient name Result Score Exposure Observation
Conclusion/Summary
Skin :
Eyes :
Species
Information on toxicological effects
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
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Section 11. Toxicological information
Carcinogenicity
Conclusion/Summary :
Mutagenicity
Conclusion/Summary :
Teratogenicity
Conclusion/Summary :
Reproductive toxicity
Conclusion/Summary :
Respiratory :
Sensitization
bis-[4-(2,3-epoxipropoxi)
phenyl]propane
skin Mouse Sensitizing
Product/ingredient name Route of
exposure
Species Result
Conclusion/Summary
Skin :
Respiratory :
Specific target organ toxicity (single exposure)
Classification
bis-[4-(2,3-epoxipropoxi)
phenyl]propane
-3 -
4-chloro-α,α,α-trifluorotoluene -2B -
titanium dioxide -2B -
4-methylpentan-2-one -2B -
toluene -3 -
crystalline silica, respirable
powder (<10 microns)
-1 Known to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Carcinogen Classification code:
IARC: 1, 2A, 2B, 3, 4
NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen
OSHA: +
Not listed/not regulated: -
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Name
4-chloro-α,α,α-trifluorotoluene Category 3 -Respiratory tract
irritation
4-methylpentan-2-one Category 3 -Narcotic effects
Talc , not containing asbestiform fibres Category 3 -Respiratory tract
irritation
acetone Category 3 -Narcotic effects
toluene Category 3 -Narcotic effects
Alpha, Alpha"-(1,3-Xylenediyl)Bis(12-Hydroxy-
Octadecanamide)
Category 3 -Respiratory tract
irritation
Category Route of
exposure
Target organs
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Section 11. Toxicological information
Information on the likely routes of exposure
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (repeated exposure)
Aspiration hazard
Name Result
toluene ASPIRATION HAZARD - Category 1
Potential acute health effects
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.
Causes serious eye damage.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
stomach pains
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain
watering
redness
Target organs :Contains material which causes damage to the following organs: brain, skin, central
nervous system (CNS).
Contains material which may cause damage to the following organs: blood, kidneys,
lungs, the reproductive system, liver, heart, gastrointestinal tract, cardiovascular system,
upper respiratory tract, adrenal, ears, eye, lens or cornea.
Name Category
toluene Category 2 --
crystalline silica, respirable powder (<10 microns)Category 1 inhalation -
Route of
exposure
Target organs
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Section 11. Toxicological information
Conclusion/Summary :
General :
Carcinogenicity :
Mutagenicity :
Reproductive toxicity :
Potential chronic health effects
Numerical measures of toxicity
Acute toxicity estimates
Potential immediate
effects
:
Short term exposure
Potential delayed effects :
Potential immediate
effects
:
Long term exposure
Potential delayed effects :
May cause cancer. Risk of cancer depends on duration and level of exposure.
There are no data available on the mixture itself. Trimethoxysilanes are capable of
forming methanol if hydrolyzed or ingested. If swallowed, methanol may be harmful or
fatal or cause blindness. This product either contains formaldehyde or is capable of
releasing formaldehyde above 0.5 ppm under certain conditions. Formaldehyde is a
known cancer hazard, a skin sensitizer and a respiratory sensitizer. This product
contains crystalline silica which can cause lung cancer or silicosis. The risk of cancer
depends on the duration and level of exposure to dust from sanding surfaces or mist
from spray applications. This product contains TiO2 which has been classified as a
GHS Carcinogen Category 2 based on its IARC 2B classification. For many products,
TiO2 is utilized as a raw material in a liquid coating formulation. In this case, the TiO2
particles are bound in a matrix with no meaningful potential for human exposure to
unbound particles of TiO2 when the product is applied with a brush or roller. Sanding
the coating surface or mist from spray applications may be harmful depending on the
duration and level of exposure and require the use of appropriate personal protective
equipment and/or engineering controls (see Section 8). Exposure to component solvent
vapor concentrations in excess of the stated occupational exposure limit may result in
adverse health effects such as mucous membrane and respiratory system irritation and
adverse effects on the kidneys, liver and central nervous system. Symptoms and signs
include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme
cases, loss of consciousness. Solvents may cause some of the above effects by
absorption through the skin. There is some evidence that repeated exposure to organic
solvent vapors in combination with constant loud noise can cause greater hearing loss
than expected from exposure to noise alone. If splashed in the eyes, the liquid may
cause irritation and reversible damage. Ingestion may cause nausea, diarrhea and
vomiting. This takes into account, where known, delayed and immediate effects and
also chronic effects of components from short-term and long-term exposure by oral,
inhalation and dermal routes of exposure and eye contact.
May cause damage to organs through prolonged or repeated exposure. Prolonged or
repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.
Suspected of damaging fertility or the unborn child.
No known significant effects or critical hazards.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
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Section 11. Toxicological information
Product/ingredient name
2.1 VOC CORROSION RESISTANT EPOXY
PRIMER - WHITE
17280.8 10579.4 N/A 76.1 10.4
bis-[4-(2,3-epoxipropoxi)phenyl]propane 15000 23000 N/A N/A N/A
Limestone 6450 N/A N/A N/A N/A
4-chloro-α,α,α-trifluorotoluene 13000 2500 N/A 33.08 N/A
4-methylpentan-2-one 2080 N/A N/A 11 1.5
[3-(2,3-epoxypropoxy)propyl]trimethoxysilane 7010 4300 N/A N/A N/A
3-butoxypropan-2-ol 2200 3100 N/A N/A N/A
acetone 5800 15800 N/A 76 N/A
toluene 5580 8390 N/A 49 N/A
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm)
Inhalation
(vapors)
(mg/l)
Inhalation
(dusts and
mists) (mg/
l)
Section 12. Ecological information
Bioaccumulative potential
Product/ingredient name Aquatic half-life Photolysis Biodegradability
bis-[4-(2,3-epoxipropoxi)
phenyl]propane
--Not readily
4-methylpentan-2-one --Readily
acetone --Readily
toluene --Readily
Toxicity
bis-[4-(2,3-epoxipropoxi)
phenyl]propane
Acute LC50 1.8 mg/l Fresh water Daphnia - daphnia magna 48 hours
Chronic NOEC 0.3 mg/l Daphnia 21 days
Limestone Acute LC50 >56000 mg/l Fish 96 hours
titanium dioxide Acute LC50 >100 mg/l Fresh water Daphnia - Daphnia magna 48 hours
4-methylpentan-2-one Acute LC50 >179 mg/l Fish 96 hours
[3-(2,3-epoxypropoxy)propyl]
trimethoxysilane
Acute LC50 324 mg/l Daphnia 48 hours
acetone Acute LC50 4.42589 ml/L Marine water Crustaceans - Acartia tonsa -
Copepodid
48 hours
Acute LC50 5540 mg/l Fish 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
4-methylpentan-2-one OECD 301F 83 % - Readily - 28 days --
acetone -90.9 % - Readily - 28 days --
Product/ingredient name Test DoseResult Inoculum
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Section 12. Ecological information
LogPow BCF PotentialProduct/ingredient name
4-methylpentan-2-one 1.9 -low
3-butoxypropan-2-ol 1.2 -low
acetone -0.23 3 low
toluene 2.73 8.32 low
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
14. Transport information
PAINT
3
II
PAINT
3
II
PAINT
UN1263
3
II
UN1263 UN1263
DOT IMDG IATA
UN number
UN proper shipping
name
Transport hazard class
(es)
Packing group
Environmental hazards No.Yes.Yes. The environmentally
hazardous substance mark is
not required.
Marine pollutant
substances
Not applicable.(bis-[4-(2,3-epoxipropoxi)
phenyl]propane, trizinc bis
(orthophosphate))
48376.4 Not applicable.Not applicable.
Not applicable.
Product RQ (lbs)
United States Page: 15/18
2.1 VOC CORROSION RESISTANT EPOXY PRIMER - WHITEProduct name
23Product code Date of issue VersionCRE-121 21 November 2022
14. Transport information
RQ substances (4-methylpentan-2-one)Not applicable.Not applicable.
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
Package sizes shipped in quantities less than the product reportable quantity are not subject to the
RQ (reportable quantity) transportation requirements.
The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
DOT
IMDG
:
:
IATA :The environmentally hazardous substance mark may appear if required by other transportation
regulations.
Transport in bulk according
to IMO instruments
:Not applicable.
Section 15. Regulatory information
SARA 302/304
SARA 304 RQ :Not applicable.
Composition/information on ingredients
All components are active or exempted.United States inventory (TSCA 8b):
United States
United States - TSCA 5(a)2 - Final significant new use rules:
No products were found.
4-chloro-α,α,α-trifluorotoluene Listed 40 CFR 799.5089
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 2
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 1A
TOXIC TO REPRODUCTION - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
HNOC - Defatting irritant
bis-[4-(2,3-epoxipropoxi)phenyl]
propane
≥20 - ≤50 SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1B
4-chloro-α,α,α-trifluorotoluene ≥10 - ≤14 FLAMMABLE LIQUIDS - Category 3
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
Name %Classification
Composition/information on ingredients
United States Page: 16/18
2.1 VOC CORROSION RESISTANT EPOXY PRIMER - WHITEProduct name
23Product code Date of issue VersionCRE-121 21 November 2022
Section 15. Regulatory information
SARA 313
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
California Prop. 65
Supplier notification
Chemical name
:4-methylpentan-2-one 108-10-1 7 - 13
trizinc bis(orthophosphate)7779-90-0 5 - 10
toluene 108-88-3 0.5 - 1.5
CAS number Concentration
HNOC - Defatting irritant
titanium dioxide ≥10 - ≤20 CARCINOGENICITY - Category 2
4-methylpentan-2-one ≥10 - ≤15 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
HNOC - Defatting irritant
Talc , not containing asbestiform
fibres
≥1.0 - ≤3.9 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
[3-(2,3-epoxypropoxy)propyl]
trimethoxysilane
≥1.0 - ≤5.0 SERIOUS EYE DAMAGE - Category 1
3-butoxypropan-2-ol ≥1.0 - ≤3.8 FLAMMABLE LIQUIDS - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
acetone ≥0.10 - ≤2.4 FLAMMABLE LIQUIDS - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
HNOC - Defatting irritant
toluene ≤1.9 FLAMMABLE LIQUIDS - Category 2
SKIN IRRITATION - Category 2
TOXIC TO REPRODUCTION - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
HNOC - Defatting irritant
Alpha, Alpha"-(1,3-Xylenediyl)Bis
(12-Hydroxy-Octadecanamide)
≤1.1 COMBUSTIBLE DUSTS
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
crystalline silica, respirable
powder (<10 microns)
<1.0 CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 1
WARNING: Cancer and Reproductive Harm - www.P65Warnings.ca.gov.
United States Page: 17/18
2.1 VOC CORROSION RESISTANT EPOXY PRIMER - WHITEProduct name
23Product code Date of issue VersionCRE-121 21 November 2022
Section 16. Other information
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Hazardous Material Information System (U.S.A.)
3
03
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Date of previous issue 6/20/2022:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Indicates information that has changed from previously issued version.
Organization that prepared
the SDS
:EHS
:::
:::3 *
3
0
( * ) - Chronic effects
United States Page: 18/18
CRE PRIMER CATALYST
Not available.
Liquid.
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Section 1. Identification
:
:
:
Product code :CRE-211H
Date of issue/Date of revision 21 September 2023
Version 16
Relevant identified uses of the substance or mixture and uses advised against
Coating. Paints. Painting-related materials.
Uses advised against Not applicable.
Product use :Industrial applications.
Use of the substance/
mixture
:
:
Manufacturer PPG Industries, Inc.
One PPG Place,
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
SETIQ Interior de la República: 800-00-214-00 (México)
SETIQ Ciudad de México: (55) 5559-1588 (México)
Emergency telephone
number
:
:
Technical Phone Number :1-800-647-6050
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 2
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
TOXIC TO REPRODUCTION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the
substance or mixture
:
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 10%
(oral), 65% (dermal), 75% (inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
United States Page: 1/15
CRE PRIMER CATALYSTProduct name
16Product code Date of issue VersionCRE-211H 21 September 2023
Section 2. Hazards identification
Signal word :Danger
Hazard statements :Highly flammable liquid and vapor.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye damage.
May damage fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Keep container
tightly closed. Do not breathe vapor. Wash thoroughly after handling. Contaminated
work clothing must not be allowed out of the workplace.
Response :IF exposed or concerned: Get medical advice or attention. IF ON SKIN (or hair): Take
off immediately all contaminated clothing. Rinse skin with water. Wash contaminated
clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash
occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor.
Storage :Store locked up. Store in a well-ventilated place. Keep cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label
elements
:Repeated exposure to high vapor concentrations may cause irritation of the respiratory
system and permanent brain and nervous system damage. Inhalation of vapor/aerosol
concentrations above the recommended exposure limits causes headaches,
drowsiness and nausea and may lead to unconsciousness or death. This product either
contains formaldehyde or is capable of releasing formaldehyde above 0.5 ppm under
certain conditions. Formaldehyde is a known cancer hazard, a skin sensitizer and a
respiratory sensitizer. Avoid contact with skin and clothing. Wash thoroughly after
handling. Emits toxic fumes when heated.
Hazards not otherwise
classified
:Prolonged or repeated contact may dry skin and cause irritation.
Section 3. Composition/information on ingredients
Isopropyl alcohol ≥5.0 - ≤10 67-63-0
bisphenol A ≥5.0 - ≤10 80-05-7
toluene ≥5.0 - ≤9.9 108-88-3
m-phenylenebis(methylamine)≥1.0 - <5.0 1477-55-0
Ingredient name CAS number%
Substance/mixture :Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Product name CRE PRIMER CATALYST:
SUB codes represent substances without registered CAS Numbers.
United States Page: 2/15
CRE PRIMER CATALYSTProduct name
16Product code Date of issue VersionCRE-211H 21 September 2023
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :
:Ingestion
Skin contact :
:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
stomach pains
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain
watering
redness
Potential acute health effects
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Check for and remove any contact lenses. Immediately flush eyes with running water for
at least 15 minutes, keeping eyelids open. Seek immediate medical attention.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
Causes serious eye damage.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.
United States Page: 3/15
CRE PRIMER CATALYSTProduct name
16Product code Date of issue VersionCRE-211H 21 September 2023
Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments :No specific treatment.
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon oxides
nitrogen oxides
Formaldehyde.
Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur
and the container may burst, with the risk of a subsequent explosion. Runoff to sewer
may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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CRE PRIMER CATALYSTProduct name
16Product code Date of issue VersionCRE-211H 21 September 2023
Section 6. Accidental release measures
Environmental precautions
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
Section 7. Handling and storage
Advice on general
occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Special precautions :If this material is part of a multiple component system, read the Safety Data Sheet(s) for
the other component or components before blending as the resulting mixture may have
the hazards of all of its parts.
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CRE PRIMER CATALYSTProduct name
16Product code Date of issue VersionCRE-211H 21 September 2023
Section 7. Handling and storage
Conditions for safe storage,
including any
incompatibilities
Do not store below the following temperature: 5°C (41°F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
Isopropyl alcohol ACGIH TLV (United States, 1/2022).
STEL: 400 ppm 15 minutes.
TWA: 200 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 980 mg/m³ 8 hours.
TWA: 400 ppm 8 hours.
bisphenol A IPEL (-).
STEL: 5 mg/m³
toluene OSHA PEL Z2 (United States, 2/2013).
AMP: 500 ppm 10 minutes.
CEIL: 300 ppm
TWA: 200 ppm 8 hours.
ACGIH TLV (United States, 1/2022).
Ototoxicant.
TWA: 20 ppm 8 hours.
m-phenylenebis(methylamine)ACGIH TLV (United States, 1/2022).
Absorbed through skin.
C: 0.018 ppm
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Control parameters
Occupational exposure limits
Recommended monitoring
procedures
:Reference should be made to appropriate monitoring standards. Reference to national
guidance documents for methods for the determination of hazardous substances will
also be required.
Key to abbreviations
A Acceptable Maximum Peak=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
TD =Total dust
Consult local authorities for acceptable exposure limits.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
STEL =
=
Short term Exposure limit values
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16Product code Date of issue VersionCRE-211H 21 September 2023
Section 8. Exposure controls/personal protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :
Chemical splash goggles and face shield.
Gloves butyl rubber:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.
The respiratory protection shall be in accordance to 29 CFR 1910.134.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Not available.Odor
pH
Clear.Color
Auto-ignition temperature
Flash point
Not available.
Closed cup: 15°C (59°F)
Not applicable.
Not available.Odor threshold
:
:
:
:
:
:
:
:
Appearance
Boiling point :>37.78°C (>100°F)
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CRE PRIMER CATALYSTProduct name
16Product code Date of issue VersionCRE-211H 21 September 2023
Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
1.02
Not available.
Not available.
Evaporation rate Not available.
Not applicable.
Viscosity Kinematic (40°C (104°F)): >21 mm2/s (>21 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
Flammability :Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
% Solid. (w/w):80.01
Density ( lbs / gal ):8.51
Volatility :25% (v/v), 19.99% (w/w)
Solubility(ies):
Media Result
cold water Not soluble
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
The product is stable.Chemical stability :
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
When exposed to high temperatures may produce hazardous decomposition products.
Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
Refer to protective measures listed in sections 7 and 8.
Depending on conditions, decomposition products may include the following materials:
carbon oxides nitrogen oxides Formaldehyde.
Section 11. Toxicological information
Acute toxicity
Information on toxicological effects
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Section 11. Toxicological information
Isopropyl alcohol LC50 Inhalation Vapor Rat 72600 mg/m³4 hours
LD50 Dermal Rabbit 12800 mg/kg -
LD50 Oral Rat 5045 mg/kg -
bisphenol A LD50 Dermal Rabbit 3600 mg/kg -
LD50 Oral Rat 3.25 g/kg -
toluene LC50 Inhalation Vapor Rat 49 g/m³4 hours
LD50 Dermal Rabbit 8.39 g/kg -
LD50 Oral Rat 5580 mg/kg -
m-phenylenebis
(methylamine)
LC50 Inhalation Gas.Rat 700 ppm 1 hours
LD50 Dermal Rat - Male,
Female
>3100 mg/kg -
LD50 Oral Rat 930 mg/kg -
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary :proprietary polymer: ORAL (LD50) >2000 mg/kg. There are no data available on the
mixture itself.
Carcinogenicity
Conclusion/Summary :
Mutagenicity
Conclusion/Summary :
Irritation/Corrosion
m-phenylenebis
(methylamine)
Skin - Severe irritant Rat -4 hours 4 hours
Product/ingredient name Result Score Exposure Observation
Conclusion/Summary
Skin :
Eyes :
Respiratory :
Sensitization
m-phenylenebis
(methylamine)
skin Mouse Sensitizing
Product/ingredient name Route of
exposure
Species Result
Conclusion/Summary
Skin :
Respiratory :
Species
Classification
Isopropyl alcohol -3 -
toluene -3 -
Product/ingredient name NTPIARCOSHA
Carcinogen Classification code:
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
United States Page: 9/15
CRE PRIMER CATALYSTProduct name
16Product code Date of issue VersionCRE-211H 21 September 2023
Section 11. Toxicological information
Teratogenicity
Conclusion/Summary :
Reproductive toxicity
Conclusion/Summary :
Specific target organ toxicity (single exposure)
IARC: 1, 2A, 2B, 3, 4
NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen
OSHA: +
Not listed/not regulated: -
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Information on the likely routes of exposure
Specific target organ toxicity (repeated exposure)
Aspiration hazard
Name Result
toluene ASPIRATION HAZARD - Category 1
Potential acute health effects
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.
Causes serious eye damage.:Eye contact
Over-exposure signs/symptoms
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
Eye contact :Adverse symptoms may include the following:
pain
watering
redness
Target organs :Contains material which causes damage to the following organs: brain.
Contains material which may cause damage to the following organs: blood, kidneys, the
reproductive system, liver, heart, spleen, gastrointestinal tract, upper respiratory tract,
skin, central nervous system (CNS), ears, eye, lens or cornea.
Name
Isopropyl alcohol Category 3 -Narcotic effects
bisphenol A Category 3 -Respiratory tract
irritation
toluene Category 3 -Narcotic effects
Category Route of
exposure
Target organs
Name Category
toluene Category 2 --
Route of
exposure
Target organs
United States Page: 10/15
CRE PRIMER CATALYSTProduct name
16Product code Date of issue VersionCRE-211H 21 September 2023
Section 11. Toxicological information
Conclusion/Summary :
General :
Carcinogenicity :
Mutagenicity :
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Potential immediate
effects
:
Short term exposure
Potential delayed effects :
Potential immediate
effects
:
Long term exposure
Potential delayed effects :
Skin contact
Ingestion Adverse symptoms may include the following:
stomach pains
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
No known significant effects or critical hazards.
There are no data available on the mixture itself. This product either contains
formaldehyde or is capable of releasing formaldehyde above 0.5 ppm under certain
conditions. Formaldehyde is a known cancer hazard, a skin sensitizer and a respiratory
sensitizer. Exposure to component solvent vapor concentrations in excess of the stated
occupational exposure limit may result in adverse health effects such as mucous
membrane and respiratory system irritation and adverse effects on the kidneys, liver
and central nervous system. Symptoms and signs include headache, dizziness, fatigue,
muscular weakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. There is
some evidence that repeated exposure to organic solvent vapors in combination with
constant loud noise can cause greater hearing loss than expected from exposure to
noise alone. If splashed in the eyes, the liquid may cause irritation and reversible
damage. Ingestion may cause nausea, diarrhea and vomiting. This takes into account,
where known, delayed and immediate effects and also chronic effects of components
from short-term and long-term exposure by oral, inhalation and dermal routes of
exposure and eye contact. Exposure to amine vapor has been reported to cause
transient corneal edema described as blue haze, halo effect, foggy or blurred vision for
several hours. This condition is typically temporary and does not cause permanent
visual effects. When the proper eye protection specified in Section 8 is worn, exposure
is significantly reduced and the condition has not been observed.
May cause damage to organs through prolonged or repeated exposure. Prolonged or
repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.
No known significant effects or critical hazards.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
United States Page: 11/15
CRE PRIMER CATALYSTProduct name
16Product code Date of issue VersionCRE-211H 21 September 2023
Section 11. Toxicological information
Reproductive toxicity :
Numerical measures of toxicity
Acute toxicity estimates
May damage fertility or the unborn child.
Product/ingredient name
CRE PRIMER CATALYST 3283.9 7329.7 22527.1 N/A N/A
Isopropyl alcohol 5045 12800 N/A 72.6 N/A
bisphenol A 3250 3600 N/A N/A N/A
toluene 5580 8390 N/A 49 N/A
m-phenylenebis(methylamine)930 2500 4500 N/A N/A
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm)
Inhalation
(vapors)
(mg/l)
Inhalation
(dusts and
mists) (mg/
l)
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
Isopropyl alcohol 0.05 -Low
bisphenol A 3.4 43.65 Low
toluene 2.73 8.32 Low
m-phenylenebis(methylamine)0.18 2.69 Low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
bisphenol A --Readily
toluene --Readily
Toxicity
Isopropyl alcohol Acute EC50 10100 mg/l Fresh water Daphnia - Daphnia magna 48 hours
bisphenol A Acute LC50 0.885 mg/l Fresh water Crustaceans 48 hours
Acute LC50 8.11 mg/l Fresh water Daphnia - Daphnia magna -
Neonate
48 hours
Acute LC50 4.6 mg/l Fresh water Fish 96 hours
Chronic NOEC 0.000174 mg/l Fresh
water
Fish 5 months
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
United States Page: 12/15
CRE PRIMER CATALYSTProduct name
16Product code Date of issue VersionCRE-211H 21 September 2023
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
14. Transport information
PAINT RELATED MATERIAL
3
II
PAINT RELATED MATERIAL
3
II
PAINT RELATED MATERIAL
UN1263
3
II
UN1263 UN1263
DOT IMDG IATA
UN number
UN proper shipping
name
Transport hazard class
(es)
Packing group
Environmental hazards No.Yes.Yes. The environmentally
hazardous substance mark is
not required.
Marine pollutant
substances
Not applicable.(bisphenol A)
RQ substances
10090.8
(toluene)
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
Package sizes shipped in quantities less than the product reportable quantity are not subject to the
RQ (reportable quantity) transportation requirements.
The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
DOT
IMDG
:
:
IATA :The environmentally hazardous substance mark may appear if required by other transportation
regulations.
Product RQ (lbs)
United States Page: 13/15
CRE PRIMER CATALYSTProduct name
16Product code Date of issue VersionCRE-211H 21 September 2023
14. Transport information
Transport in bulk according
to IMO instruments
:Not applicable.
Section 15. Regulatory information
SARA 313
SARA 302/304
SARA 304 RQ :Not applicable.
Composition/information on ingredients
All components are active or exempted.United States inventory (TSCA 8b):
United States
Chemical name CAS number Concentration
No products were found.
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 2
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
TOXIC TO REPRODUCTION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
HNOC - Defatting irritant
Isopropyl alcohol ≥5.0 - ≤10 FLAMMABLE LIQUIDS - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
bisphenol A ≥5.0 - ≤10 COMBUSTIBLE DUSTS
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1B
TOXIC TO REPRODUCTION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
toluene ≥5.0 - ≤9.9 FLAMMABLE LIQUIDS - Category 2
SKIN IRRITATION - Category 2
TOXIC TO REPRODUCTION - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
HNOC - Defatting irritant
m-phenylenebis(methylamine)≥1.0 - <5.0 ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION - Category 1B
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1B
Name %Classification
Composition/information on ingredients
United States Page: 14/15
CRE PRIMER CATALYSTProduct name
16Product code Date of issue VersionCRE-211H 21 September 2023
Section 15. Regulatory information
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
California Prop. 65
Supplier notification :bisphenol A 80-05-7 5 - 10
toluene 108-88-3 5 - 10
WARNING: Reproductive Harm - www.P65Warnings.ca.gov.
Section 16. Other information
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Hazardous Material Information System (U.S.A.)
3
03
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Date of previous issue 6/20/2022:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Indicates information that has changed from previously issued version.
Organization that prepared
the SDS
:EHS
:::
:::3 *
3
0
( * ) - Chronic effects
United States Page: 15/15
BASECOAT CONVERTER
Not available.
Liquid.
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Section 1. Identification
:
:
:
Product code :ESB800
Date of issue/Date of revision 1 July 2021
Version 23.02
Relevant identified uses of the substance or mixture and uses advised against
Coating. Paints. Painting-related materials.
Uses advised against Not applicable.
Product use :Industrial applications.
Use of the substance/
mixture
:
:
Manufacturer PPG Industries, Inc.
One PPG Place,
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
SETIQ Interior de la República: 800-00-214-00 (México)
SETIQ Ciudad de México: (55) 5559-1588 (México)
Emergency telephone
number
:
:
Technical Phone Number :1-800-647-6050
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 3
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
Classification of the
substance or mixture
:
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 9%
(oral), 9% (dermal), 9% (inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
United States Page: 1/18
BASECOAT CONVERTERProduct name
23.02Product code Date of issue VersionESB8001 July 2021
Section 2. Hazards identification
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
May cause respiratory irritation.
May cause drowsiness or dizziness.
Suspected of causing cancer.
May damage fertility or the unborn child.
Hazard pictograms :
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or
in a well-ventilated area. Avoid breathing vapor. Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF ON SKIN:
Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice or attention.
Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep
cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label
elements
:Repeated exposure to high vapor concentrations may cause irritation of the respiratory
system and permanent brain and nervous system damage. Inhalation of vapor/aerosol
concentrations above the recommended exposure limits causes headaches,
drowsiness and nausea and may lead to unconsciousness or death. Avoid contact with
skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated.
Hazards not otherwise
classified
:Prolonged or repeated contact may dry skin and cause irritation.
United States Page: 2/18
BASECOAT CONVERTERProduct name
23.02Product code Date of issue VersionESB8001 July 2021
Section 3. Composition/information on ingredients
4-chloro-α,α,α-trifluorotoluene ≥20 - ≤50 98-56-6
heptan-2-one ≥20 - ≤27 110-43-0
butanone ≥1.0 - ≤4.4 78-93-3
xylene ≥0.10 - ≤2.9 1330-20-7
2-methoxy-1-methylethyl acetate ≥1.0 - ≤5.0 108-65-6
ethylbenzene <1.0 100-41-4
dibutyltin dilaurate <1.0 77-58-7
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Product name BASECOAT CONVERTER:
SUB codes represent substances without registered CAS Numbers.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :
:Ingestion
Skin contact :
:Eye contact
Over-exposure signs/symptoms
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product,
contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Safety Data Sheet information
available. Never give anything by mouth to an unconscious or convulsing person.
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids
apart for at least 10 minutes and seek immediate medical advice.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
Causes serious eye irritation.
Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression.
Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.
United States Page: 3/18
BASECOAT CONVERTERProduct name
23.02Product code Date of issue VersionESB8001 July 2021
Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments :No specific treatment.
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
dryness
cracking
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Specific hazards arising
from the chemical
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Runoff to sewer may
create fire or explosion hazard.
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
United States Page: 4/18
BASECOAT CONVERTERProduct name
23.02Product code Date of issue VersionESB8001 July 2021
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Decomposition products may include the following materials:
carbon oxides
halogenated compounds
carbonyl halides
metal oxide/oxides
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
United States Page: 5/18
BASECOAT CONVERTERProduct name
23.02Product code Date of issue VersionESB8001 July 2021
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store below the following temperature: 5°C (41°F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid
breathing vapor or mist. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Store
and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Special precautions :If this material is part of a multiple component system, read the Safety Data Sheet(s) for
the other component or components before blending as the resulting mixture may have
the hazards of all of its parts.
4-chloro-α,α,α-trifluorotoluene IPEL (-).
TWA: 0.57 ppm
STEL: 1.71 ppm
heptan-2-one ACGIH TLV (United States, 3/2020).
TWA: 233 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 465 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
butanone ACGIH TLV (United States, 3/2020).
STEL: 885 mg/m³ 15 minutes.
STEL: 300 ppm 15 minutes.
TWA: 590 mg/m³ 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
United States Page: 6/18
BASECOAT CONVERTERProduct name
23.02Product code Date of issue VersionESB8001 July 2021
Section 8. Exposure controls/personal protection
TWA: 200 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 590 mg/m³ 8 hours.
TWA: 200 ppm 8 hours.
xylene ACGIH TLV (United States, 3/2020).
STEL: 651 mg/m³ 15 minutes.
STEL: 150 ppm 15 minutes.
TWA: 434 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
2-methoxy-1-methylethyl acetate IPEL (-, 10/2017). Absorbed through skin.
TWA: 30 ppm
STEL: 90 ppm
ethylbenzene ACGIH TLV (United States, 3/2020).
TWA: 20 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
dibutyltin dilaurate ACGIH TLV (United States, 3/2020).
Absorbed through skin.
STEL: 0.2 mg/m³, (as Sn) 15 minutes.
TWA: 0.1 mg/m³, (as Sn) 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 0.1 mg/m³, (as Sn) 8 hours.
OSHA PEL (United States).
TWA: 0.1 mg/m³, (as Sn)
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Recommended monitoring
procedures
:If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Key to abbreviations
A Acceptable Maximum Peak=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
TD =Total dust
Consult local authorities for acceptable exposure limits.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
STEL =
=
Short term Exposure limit values
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BASECOAT CONVERTERProduct name
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Section 8. Exposure controls/personal protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :
Chemical splash goggles.
Gloves For prolonged or repeated handling, use the following type of gloves:
Recommended: butyl rubber, polyvinyl alcohol (PVA), Viton®
May be used: Chloroprene, nitrile rubber
:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.
The respiratory protection shall be in accordance to 29 CFR 1910.134.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Not available.Odor
pH
Not available.Color
Not applicable.
Not available.Odor threshold
:
:
:
:
:
:
Appearance
United States Page: 8/18
BASECOAT CONVERTERProduct name
23.02Product code Date of issue VersionESB8001 July 2021
Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1.14
Not available.
Not available.
Insoluble in the following materials: cold water.
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 38°C (100.4°F)
Not applicable.
Viscosity Kinematic (40°C (104°F)): >21 mm2/s (>21 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
Boiling point :>37.78°C (>100°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
% Solid. (w/w):20.748
Density ( lbs / gal ):9.51
Volatility :84% (v/v), 79.252% (w/w)
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
The product is stable.Chemical stability :
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
When exposed to high temperatures may produce hazardous decomposition products.
Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
Refer to protective measures listed in sections 7 and 8.
Depending on conditions, decomposition products may include the following materials:
carbon oxides halogenated compounds carbonyl halides metal oxide/oxides
Section 11. Toxicological information
Acute toxicity
Information on toxicological effects
United States Page: 9/18
BASECOAT CONVERTERProduct name
23.02Product code Date of issue VersionESB8001 July 2021
Section 11. Toxicological information
4-chloro-α,α,α-trifluorotoluene LC50 Inhalation Vapor Rat 33080 mg/m³4 hours
LD50 Dermal Rabbit >2.7 g/kg -
LD50 Oral Rat 13 g/kg -
heptan-2-one LC50 Inhalation Vapor Rat 16.7 mg/l 4 hours
LD50 Dermal Rabbit 10.206 g/kg -
LD50 Oral Rat 1.6 g/kg -
butanone LD50 Dermal Rabbit 6480 mg/kg -
LD50 Oral Rat 2737 mg/kg -
xylene LD50 Dermal Rabbit 1.7 g/kg -
LD50 Oral Rat 4.3 g/kg -
2-methoxy-1-methylethyl
acetate
LC50 Inhalation Vapor Rat 30 mg/l 4 hours
LD50 Dermal Rabbit >5 g/kg -
LD50 Oral Rat 6190 mg/kg -
ethylbenzene LC50 Inhalation Vapor Rat 17.8 mg/l 4 hours
LD50 Dermal Rabbit 17.8 g/kg -
LD50 Oral Rat 3.5 g/kg -
dibutyltin dilaurate LD50 Oral Rat 2071 mg/kg -
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary :
Carcinogenicity
Conclusion/Summary :
Mutagenicity
Conclusion/Summary :
Irritation/Corrosion
xylene Skin - Moderate irritant Rabbit -24 hours 500
mg
-
Product/ingredient name Result Score Exposure Observation
Conclusion/Summary
Skin :
Eyes :
Respiratory :
Sensitization
Conclusion/Summary
Skin :
Respiratory :
Species
Classification
4-chloro-α,α,α-trifluorotoluene -2B -
xylene -3 -
ethylbenzene -2B -
Product/ingredient name NTPIARCOSHA
Carcinogen Classification code:
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
United States Page: 10/18
BASECOAT CONVERTERProduct name
23.02Product code Date of issue VersionESB8001 July 2021
Section 11. Toxicological information
Teratogenicity
Conclusion/Summary :
Reproductive toxicity
Conclusion/Summary :
Specific target organ toxicity (single exposure)
IARC: 1, 2A, 2B, 3, 4
NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen
OSHA: +
Not listed/not regulated: -
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Information on the likely routes of exposure
Specific target organ toxicity (repeated exposure)
Aspiration hazard
Name Result
xylene ASPIRATION HAZARD - Category 1
ethylbenzene ASPIRATION HAZARD - Category 1
Potential acute health effects
Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression.:Ingestion
Skin contact :Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Target organs :Contains material which causes damage to the following organs: brain, central nervous
system (CNS).
Contains material which may cause damage to the following organs: kidneys, lungs, the
nervous system, liver, peripheral nervous system, upper respiratory tract, immune
system, skin, adrenal, eye, lens or cornea.
Name
4-chloro-α,α,α-trifluorotoluene Category 3 -Respiratory tract
irritation
heptan-2-one Category 3 -Narcotic effects
butanone Category 3 -Narcotic effects
xylene Category 3 -Respiratory tract
irritation
2-methoxy-1-methylethyl acetate Category 3 -Narcotic effects
dibutyltin dilaurate Category 1 -thymus
Category Route of
exposure
Target organs
Name Category
ethylbenzene Category 2 -hearing organs
dibutyltin dilaurate Category 1 oral immune system
Route of
exposure
Target organs
United States Page: 11/18
BASECOAT CONVERTERProduct name
23.02Product code Date of issue VersionESB8001 July 2021
Section 11. Toxicological information
Conclusion/Summary :
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Potential immediate
effects
:
Short term exposure
Potential delayed effects :
Potential immediate
effects
:
Long term exposure
Potential delayed effects :
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
dryness
cracking
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
There are no data available on the mixture itself. Exposure to component solvent vapor
concentrations in excess of the stated occupational exposure limit may result in adverse
health effects such as mucous membrane and respiratory system irritation and adverse
effects on the kidneys, liver and central nervous system. Symptoms and signs include
headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases,
loss of consciousness. Solvents may cause some of the above effects by absorption
through the skin. There is some evidence that repeated exposure to organic solvent
vapors in combination with constant loud noise can cause greater hearing loss than
expected from exposure to noise alone. If splashed in the eyes, the liquid may cause
irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic
effects of components from short-term and long-term exposure by oral, inhalation and
dermal routes of exposure and eye contact.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
United States Page: 12/18
BASECOAT CONVERTERProduct name
23.02Product code Date of issue VersionESB8001 July 2021
Section 11. Toxicological information
General :
Carcinogenicity :
Mutagenicity :
Reproductive toxicity :
Numerical measures of toxicity
Acute toxicity estimates
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or
dermatitis. Once sensitized, a severe allergic reaction may occur when subsequently
exposed to very low levels.
May damage fertility or the unborn child.
No known significant effects or critical hazards.
Product/ingredient name
BASECOAT CONVERTER 6232.7 4855.6 N/A 63.3 6
4-chloro-α,α,α-trifluorotoluene 13000 2500 N/A 33.08 N/A
heptan-2-one 1600 10206 N/A 16.7 1.5
butanone 2737 6480 N/A N/A N/A
xylene 4300 1700 N/A 11 1.5
2-methoxy-1-methylethyl acetate 6190 N/A N/A 30 N/A
ethylbenzene 3500 17800 N/A 17.8 1.5
dibutyltin dilaurate 2071 N/A N/A N/A N/A
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm)
Inhalation
(vapors)
(mg/l)
Inhalation
(dusts and
mists) (mg/
l)
Section 12. Ecological information
Toxicity
heptan-2-one Acute LC50 131 mg/l Fish 96 hours
2-methoxy-1-methylethyl
acetate
Acute LC50 134 mg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
ethylbenzene Acute EC50 1.8 mg/l Fresh water Daphnia 48 hours
Acute LC50 150 to 200 mg/l Fresh water Fish 96 hours
Chronic NOEC 1 mg/l Fresh water Daphnia - Ceriodaphnia dubia -
dibutyltin dilaurate EC50 0.463 mg/l Daphnia 48 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
heptan-2-one OECD 310 69 % - Readily - 28 days --
2-methoxy-1-methylethyl
acetate
-83 % - Readily - 28 days --
ethylbenzene -79 % - Readily - 10 days --
Product/ingredient name Test DoseResult Inoculum
United States Page: 13/18
BASECOAT CONVERTERProduct name
23.02Product code Date of issue VersionESB8001 July 2021
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
heptan-2-one 2.26 -low
butanone 0.3 -low
xylene 3.12 7.4 to 18.5 low
2-methoxy-1-methylethyl
acetate
1.2 -low
ethylbenzene 3.6 79.43 low
dibutyltin dilaurate 4.44 -high
Product/ingredient name Aquatic half-life Photolysis Biodegradability
heptan-2-one --Readily
xylene --Readily
2-methoxy-1-methylethyl
acetate
--Readily
ethylbenzene --Readily
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
United States Page: 14/18
BASECOAT CONVERTERProduct name
23.02Product code Date of issue VersionESB8001 July 2021
14. Transport information
PAINT
3
III
PAINT
3
III
PAINT
UN1263
3
III
UN1263 UN1263
DOT IMDG IATA
UN number
UN proper shipping
name
Transport hazard class
(es)
Packing group
Environmental hazards No.No.No.
Marine pollutant
substances
Not applicable.Not applicable.
RQ substances
4060.2
(xylene)
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
This product may be re-classified as "Combustible Liquid," unless transported by vessel or aircraft.
Non-bulk packages (less than or equal to 119 gal) of combustible liquids are not regulated as
hazardous materials in package sizes less than the product reportable quantity.
None identified.
DOT
IMDG
:
:
IATA :None identified.
Product RQ (lbs)
Transport in bulk according
to IMO instruments
:Not applicable.
Section 15. Regulatory information
SARA 302/304
SARA 304 RQ :Not applicable.
Composition/information on ingredients
All components are active or exempted.United States inventory (TSCA 8b):
United States
United States - TSCA 5(a)2 - Final significant new use rules:
No products were found.
4-chloro-α,α,α-trifluorotoluene Listed 40 CFR 799.5089
SARA 311/312
United States Page: 15/18
BASECOAT CONVERTERProduct name
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Section 15. Regulatory information
Classification :FLAMMABLE LIQUIDS - Category 3
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
HNOC - Defatting irritant
4-chloro-α,α,α-trifluorotoluene ≥20 - ≤50 FLAMMABLE LIQUIDS - Category 3
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
HNOC - Defatting irritant
heptan-2-one ≥20 - ≤27 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
HNOC - Defatting irritant
butanone ≥1.0 - ≤4.4 FLAMMABLE LIQUIDS - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
HNOC - Defatting irritant
xylene ≥0.10 - ≤2.9 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
ASPIRATION HAZARD - Category 1
2-methoxy-1-methylethyl acetate ≥1.0 - ≤5.0 FLAMMABLE LIQUIDS - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
ethylbenzene <1.0 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
HNOC - Defatting irritant
dibutyltin dilaurate <1.0 SKIN CORROSION - Category 1C
SERIOUS EYE DAMAGE - Category 1
Name %Classification
Composition/information on ingredients
United States Page: 16/18
BASECOAT CONVERTERProduct name
23.02Product code Date of issue VersionESB8001 July 2021
Section 15. Regulatory information
SARA 313
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
California Prop. 65
Supplier notification
Chemical name
:xylene 1330-20-7 1 - 5
ethylbenzene 100-41-4 0.1 - 1
CAS number Concentration
SKIN SENSITIZATION - Category 1
GERM CELL MUTAGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) -
Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 1
WARNING: Cancer - www.P65Warnings.ca.gov.
Section 16. Other information
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Hazardous Material Information System (U.S.A.)
2
02
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Date of previous issue 6/13/2021:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Indicates information that has changed from previously issued version.
Organization that prepared
the SDS
:EHS
:::
:::2 *
2
0
( * ) - Chronic effects
United States Page: 17/18
BASECOAT CONVERTERProduct name
23.02Product code Date of issue VersionESB8001 July 2021
Section 16. Other information
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
United States Page: 18/18
SINGLE STAGE HARDENER
Not available.
Liquid.
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Section 1. Identification
:
:
:
Product code :ESH200
Date of issue/Date of revision 19 May 2021
Version 12
Relevant identified uses of the substance or mixture and uses advised against
Coating. Paints. Painting-related materials.
Uses advised against Not applicable.
Product use :Industrial applications.
Use of the substance/
mixture
:
:
Manufacturer PPG Industries, Inc.
One PPG Place,
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
SETIQ Interior de la República: 800-00-214-00 (México)
SETIQ Ciudad de México: (55) 5559-1588 (México)
Emergency telephone
number
:
:
Technical Phone Number :1-800-647-6050
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 4
ACUTE TOXICITY (inhalation) - Category 4
RESPIRATORY SENSITIZATION - Category 1
SKIN SENSITIZATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
United States Page: 1/14
SINGLE STAGE HARDENERProduct name
12Product code Date of issue VersionESH20019 May 2021
Section 2. Hazards identification
Hazard statements :Combustible liquid.
May cause an allergic skin reaction.
Harmful if inhaled.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause respiratory irritation.
Precautionary statements
Prevention :Wear protective gloves, protective clothing and eye or face protection. Wear respiratory
protection. Keep away from flames and hot surfaces. No smoking. Use only outdoors
or in a well-ventilated area. Avoid breathing vapor. Contaminated work clothing must
not be allowed out of the workplace.
Response :IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a
POISON CENTER or doctor if you feel unwell. If experiencing respiratory symptoms:
Call a POISON CENTER or doctor. Wash contaminated clothing before reuse. IF ON
SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or
attention.
Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep
cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label
elements
:Moisture-sensitive material. Skin contact to isocyanate monomer may lead to allergic
lung reaction. Based on the properties of the isocyanate components and considering
toxicological data on similar mixtures, this mixture may cause acute irritation and/or
sensitization of the respiratory system, leading to an asthmatic condition, wheezing and
tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms
when exposed to atmospheric concentrations well below the OEL. Repeated exposure
may lead to permanent respiratory disability. Persons with a history of skin sensitization
problems or asthma, allergies or chronic or recurrent respiratory disease should not be
employed in any process in which this product is used. Avoid contact with skin and
clothing. Wash thoroughly after handling. Emits toxic fumes when heated.
Hazards not otherwise
classified
:May form explosive peroxides. Hazardous reactions or instability may occur under
certain conditions of storage or use. Prolonged or repeated contact may dry skin and
cause irritation.
Section 3. Composition/information on ingredients
Hexamethylene diisocyanate, oligomers.≥75 - ≤90 28182-81-2
ethyl 3-ethoxypropionate ≥10 - ≤20 763-69-9
hexamethylene-di-isocyanate <1.0 822-06-0
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Substance/mixture :Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Product name SINGLE STAGE HARDENER:
SUB codes represent substances without registered CAS Numbers.
United States Page: 2/14
SINGLE STAGE HARDENERProduct name
12Product code Date of issue VersionESH20019 May 2021
Section 3. Composition/information on ingredients
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :
:Ingestion
Skin contact :
:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
wheezing and breathing difficulties
asthma
No specific data.
Adverse symptoms may include the following:
irritation
redness
dryness
cracking
:
:
:
Eye contact :No specific data.
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids
apart for at least 10 minutes and seek immediate medical advice.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
No known significant effects or critical hazards.
Harmful if inhaled. May cause respiratory irritation. May cause allergy or asthma
symptoms or breathing difficulties if inhaled.
No known significant effects or critical hazards.
Defatting to the skin. May cause skin dryness and irritation. May cause an allergic skin
reaction.
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Section 4. First aid measures
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon oxides
nitrogen oxides
Cyanate and isocyanate.
hydrogen cyanide
Combustible liquid. In a fire or if heated, a pressure increase will occur and the
container may burst, with the risk of a subsequent explosion. Runoff to sewer may
create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Large spill :
Special provisions :Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Place in a suitable container. The contaminated area
should be cleaned immediately with a suitable decontaminant. One possible (flammable)
decontaminant comprises (by volume): water (45 parts), ethanol or isopropyl alcohol (50
parts) and concentrated (d: 0,880) ammonia solution (5 parts). A non-flammable
alternative is sodium carbonate (5 parts) and water (95 parts). Add the same
decontaminant to the remnants and let stand for several days until no further reaction in
an unsealed container. Once this stage is reached, close container and dispose of
according to local regulations (see section 13). Do not allow to enter drains or
watercourses. If the product contaminates lakes, rivers, or sewers, inform the
appropriate authorities in accordance with local regulations.
Section 7. Handling and storage
Advice on general
occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems or asthma, allergies or chronic or recurrent
respiratory disease should not be employed in any process in which this product is used.
Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist.
Use only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from heat,
sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Special precautions :May form explosive peroxides. Keep away from combustible materials. Avoid shock
and friction. Avoid all possible sources of ignition (spark or flame). If this material is
part of a multiple component system, read the Safety Data Sheet(s) for the other
component or components before blending as the resulting mixture may have the
hazards of all of its parts.
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Section 7. Handling and storage
Conditions for safe storage,
including any
incompatibilities
Do not store below the following temperature: 5°C (41°F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
Precautions should be taken to minimize exposure to atmospheric humidity or water.
CO₂ will be formed, which, in closed containers, could result in pressurization.
Hexamethylene diisocyanate, oligomers.IPEL (-).
TWA: 0.5 mg/m³
STEL: 1 mg/m³
ethyl 3-ethoxypropionate IPEL (-).
TWA: 50 ppm
STEL: 100 ppm
hexamethylene-di-isocyanate ACGIH TLV (United States, 3/2020).
TWA: 0.03 mg/m³ 8 hours.
TWA: 0.005 ppm 8 hours.
OSHA PEL (United States, 5/2018).
Absorbed through skin.
TWA: 5 mg/m³, (as CN) 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Control parameters
Occupational exposure limits
Recommended monitoring
procedures
:If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Key to abbreviations
A Acceptable Maximum Peak=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
TD =Total dust
Consult local authorities for acceptable exposure limits.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
STEL =
=
Short term Exposure limit values
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Section 8. Exposure controls/personal protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :
Safety glasses with side shields.
Restrictions on use :Persons with a history of asthma, allergies or chronic or recurrent respiratory disease
should not be employed in any process in which this product is used.
Gloves butyl rubber:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Use an air-fed respirator unless a site-specific assessment determines that an air-fed
respirator is not necessary, in which case the results of the risk assessment should be
utilized to determine whether respiratory protection is necessary and what type of
protection is appropriate. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected
respirator.
The respiratory protection shall be in accordance to 29 CFR 1910.134.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Not available.Odor
pH
Clear.Color
Flash point Closed cup: 75.56°C (168°F)
Not applicable.
Not available.Odor threshold
:
:
:
:
:
:
:
Appearance
Boiling point :>37.78°C (>100°F)
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Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1.14
Not available.
Not available.
Insoluble in the following materials: cold water.
Evaporation rate Not available.
Auto-ignition temperature Not available.
Not applicable.
Viscosity Kinematic (40°C (104°F)): >21 mm2/s (>21 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
% Solid. (w/w):89.035
Density ( lbs / gal ):9.51
Volatility :13% (v/v), 10.965% (w/w)
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
The product is stable.Chemical stability :
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
In a fire, hazardous decomposition products may be produced.
Keep away from: oxidizing agents, strong alkalis, strong acids, amines, alcohols, water.
Uncontrolled exothermic reactions occur with amines and alcohols.
Refer to protective measures listed in sections 7 and 8.
Depending on conditions, decomposition products may include the following materials:
Cyanate and isocyanate. carbon oxides nitrogen oxides hydrogen cyanide
Section 11. Toxicological information
Acute toxicity
Information on toxicological effects
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Section 11. Toxicological information
Hexamethylene diisocyanate,
oligomers.
LD50 Dermal Rabbit >2000 mg/kg -
LD50 Oral Rat - Female >2500 mg/kg -
ethyl 3-ethoxypropionate LD50 Dermal Rabbit >5 g/kg -
LD50 Oral Rat 3200 mg/kg -
hexamethylene-di-isocyanate LC50 Inhalation Dusts and mists Rat 124 mg/m³4 hours
LC50 Inhalation Vapor Rat 151 mg/m³4 hours
LC50 Inhalation Vapor Rat 22 ppm 4 hours
LD50 Dermal Rabbit 0.57 g/kg -
LD50 Oral Rat 0.71 g/kg -
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary :
Carcinogenicity
Conclusion/Summary :
Mutagenicity
Conclusion/Summary :
Teratogenicity
Conclusion/Summary :
Reproductive toxicity
Conclusion/Summary :
Irritation/Corrosion
Conclusion/Summary
Skin :
Eyes :
Respiratory :
Sensitization
Conclusion/Summary
Skin :
Respiratory :
Specific target organ toxicity (single exposure)
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Specific target organ toxicity (repeated exposure)
Aspiration hazard
Not available.
Target organs :Contains material which may cause damage to the following organs: upper respiratory
tract, skin, central nervous system (CNS).
Name
Hexamethylene diisocyanate, oligomers.Category 3 -Respiratory tract
irritation
hexamethylene-di-isocyanate Category 3 -Respiratory tract
irritation
Category Route of
exposure
Target organs
Not available.
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Section 11. Toxicological information
Conclusion/Summary :
Information on the likely routes of exposure
General :
Carcinogenicity :
Mutagenicity :
Reproductive toxicity :
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Potential immediate
effects
:
Short term exposure
Potential delayed effects :
Potential immediate
effects
:
Long term exposure
Potential delayed effects :
Potential acute health effects
Inhalation :Harmful if inhaled. May cause respiratory irritation. May cause allergy or asthma
symptoms or breathing difficulties if inhaled.
No known significant effects or critical hazards.:Ingestion
Skin contact :Defatting to the skin. May cause skin dryness and irritation. May cause an allergic skin
reaction.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
wheezing and breathing difficulties
asthma
No specific data.
Adverse symptoms may include the following:
irritation
redness
dryness
cracking
:
:
:
Eye contact :No specific data.
No known significant effects or critical hazards.
There are no data available on the mixture itself. Skin contact to isocyanate monomer
may lead to allergic lung reaction. Based on the properties of the isocyanate
components and considering toxicological data on similar mixtures, this mixture may
cause acute irritation and/or sensitization of the respiratory system, leading to an
asthmatic condition, wheezing and tightness of the chest. Repeated exposure may lead
to permanent respiratory disability. If splashed in the eyes, the liquid may cause
irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic
effects of components from short-term and long-term exposure by oral, inhalation and
dermal routes of exposure and eye contact.
Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or
dermatitis. Once sensitized, a severe allergic reaction may occur when subsequently
exposed to very low levels.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
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Section 11. Toxicological information
Acute toxicity estimates
Product/ingredient name
SINGLE STAGE HARDENER 2811.7 2811.7 N/A 12.4 1.7
Hexamethylene diisocyanate, oligomers.2500 2500 N/A 11 1.5
ethyl 3-ethoxypropionate 3200 N/A N/A N/A N/A
hexamethylene-di-isocyanate 710 570 N/A 0.151 0.124
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm)
Inhalation
(vapors)
(mg/l)
Inhalation
(dusts and
mists) (mg/
l)
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
Hexamethylene diisocyanate,
oligomers.
5.54 3.2 low
ethyl 3-ethoxypropionate 1.47 -low
hexamethylene-di-isocyanate 0.02 -low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Hexamethylene diisocyanate,
oligomers.
--Not readily
ethyl 3-ethoxypropionate --Readily
Toxicity
Hexamethylene diisocyanate,
oligomers.
Acute EC50 >1000 mg/l Algae - scenedesmus
subspicatus
72 hours
Acute EC50 >100 mg/l Daphnia - daphnia magna 48 hours
Acute LC50 >100 mg/l Fish - Danio rerio (zebra fish)96 hours
ethyl 3-ethoxypropionate Acute LC50 60.9 mg/l Fish 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
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Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
14. Transport information
PAINT
Combustible liquid.
III
-
-
-
-
Not regulated.
-
-
UN1263 Not regulated.
DOT IMDG IATA
UN number
UN proper shipping
name
Transport hazard class
(es)
Packing group
Environmental hazards No.No.No.
Marine pollutant
substances
Not applicable.Not applicable.Not applicable.
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
Non-bulk packages (less than or equal to 119 gal) of combustible liquids are not regulated as
hazardous materials.
None identified.
DOT
IMDG
:
:
IATA :None identified.
Transport in bulk according
to IMO instruments
:Not applicable.
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Section 15. Regulatory information
SARA 302/304
SARA 304 RQ :Not applicable.
Composition/information on ingredients
All components are active or exempted.United States inventory (TSCA 8b):
United States
U.S. Federal regulations :
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
No products were found.
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 4
ACUTE TOXICITY (inhalation) - Category 4
RESPIRATORY SENSITIZATION - Category 1
SKIN SENSITIZATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
HNOC - Defatting irritant
HNOC - May form explosive peroxides.
Hexamethylene diisocyanate,
oligomers.
≥75 - ≤90 COMBUSTIBLE DUSTS
ACUTE TOXICITY (inhalation) - Category 4
SKIN SENSITIZATION - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
ethyl 3-ethoxypropionate ≥10 - ≤20 FLAMMABLE LIQUIDS - Category 3
HNOC - Defatting irritant
HNOC - May form explosive peroxides.
hexamethylene-di-isocyanate <1.0 ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (dermal) - Category 3
ACUTE TOXICITY (inhalation) - Category 1
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
RESPIRATORY SENSITIZATION - Category 1A
SKIN SENSITIZATION - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
Name %Classification
Composition/information on ingredients
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Section 16. Other information
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Hazardous Material Information System (U.S.A.)
2
12
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Date of previous issue 1/27/2021:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Indicates information that has changed from previously issued version.
Organization that prepared
the SDS
:EHS
:::
:::3 *
3
1
( * ) - Chronic effects
United States Page: 14/14
HS Polyurethane Single StageProduct name
Product and company identification
:
1 .
ESSS-1
PPG Industries, Inc.
One PPG Place,
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
01-800-00-21-400 (Mexico)
Supplier
Code
Emergency telephone
number
:
:
:
Technical Phone Number :[phone] (DELAWARE, OH) 8:00 a.m. - 5:00 p.m. EST
Material Safety Data Sheet
Date of issue 21 January 2014
Version 7
Emergency overview
Hazards identification
Potential acute health effects
May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and
cause damage.
Eyes
Skin
Inhalation
Ingestion
DANGER!:
:
:
:
:
Medical conditions
aggravated by over-
exposure
Pre-existing skin disorders and disorders involving any other target organs mentioned
in this MSDS as being at risk may be aggravated by over-exposure to this product.
:
2 .
Over-exposure signs/symptoms
Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and
nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes
headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated
exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than
expected from exposure to noise alone.
This material increases the risk of fire and may aid combustion. Keep away from heat,
sparks and flame. Keep away from flames, such as a pilot light, and any object that
sparks, such as an electric motor. Keep away from heat. Do not smoke. Keep away
from combustible material. Do not breathe vapor or mist. Do not swallow. Do not get
on skin or clothing. Avoid contact with eyes. Use only with adequate ventilation.
Keep container tightly closed and sealed until ready for use. Wash thoroughly after
handling.
FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT, EYE AND
SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY BE HARMFUL
IF INHALED, ABSORBED THROUGH SKIN OR SWALLOWED. SANDING AND
GRINDING DUSTS MAY BE HARMFUL IF INHALED. ASPIRATION HAZARD. CAN
ENTER LUNGS AND CAUSE DAMAGE. PROLONGED OR REPEATED CONTACT
MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS MATERIAL THAT CAN
CAUSE TARGET ORGAN DAMAGE. May form explosive peroxides. Risk of explosion
by shock, friction, fire or other sources of ignition. Add this product only to water.
Never add water to this product.
May be harmful if inhaled. Severely irritating to the respiratory system. Can irritate
eyes, nose, mouth and throat. Exposure to decomposition products may cause a
health hazard. Serious effects may be delayed following exposure.
Irritating to eyes.
Harmful in contact with skin. Irritating to skin. May cause an allergic skin reaction.
This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials
Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).
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Hazards identification2 .
See toxicological information (Section 11)
Composition/information on ingredients3 .
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
titanium dioxide 13463-67-7 40 - 70
acetone 67-64-1 10 - 30
n-butyl acetate 123-86-4 10 - 30
PARACHLOROBENZOTRIFLUORIDE 98-56-6 10 - 30
heptan-2-one 110-43-0 10 - 30
diiron trioxide 1309-37-1 10 - 30
silicon dioxide 7631-86-9 7 - 13
2-methoxy-1-methylethyl acetate 108-65-6 7 - 13
Aluminium powder (stabilized)7429-90-5 5 - 10
Mica-group minerals 12001-26-2 3 - 7
Talc , not containing asbestiform fibres 14807-96-6 3 - 7
polychloro copper phthalocyanine 1328-53-6 1 - 5
Solvent naphtha (petroleum), light aliph.64742-89-8 1 - 5
barium sulfate 7727-43-7 1 - 5
Solvent naphtha (petroleum), light aromatic 64742-95-6 1 - 5
Copper, [29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, brominated chlorinated 68512-13-0 1 - 5
29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32 copper 147-14-8 1 - 5
[trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper 29719-96-8 1 - 5
Naphtha (petroleum), hydrotreated heavy 64742-48-9 1 - 5
Cashew, nutshell liq., 2-hydroxyethyl ethers 232268-65-4 1 - 5
ethyl 3-ethoxypropionate 763-69-9 1 - 5
Isopropyl alcohol 67-63-0 1 - 5
aluminium hydroxide 21645-51-2 1 - 5
Stoddard solvent 8052-41-3 1 - 5
zinc sulphide 1314-98-3 1 - 5
1,2,4-trimethylbenzene 95-63-6 1 - 5
xylene 1330-20-7 0.5 - 1.5
carbon black respirable 1333-86-4 0.5 - 1.5
chromium (III) oxide 1308-38-9 0.5 - 1.5
2-(2H-benzotriazol-2-yl)-4,6-ditertpentylphenol 25973-55-1 0.5 - 1.5
Naphtha (petroleum), heavy alkylate 64741-65-7 0.1 - 1
ethylbenzene 100-41-4 0.1 - 1
mesitylene 108-67-8 0.1 - 1
Name CAS number %
First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
4 .
Check for and remove any contact lenses. Immediately flush eyes with running
water for at least 15 minutes, keeping eyelids open. Seek immediate medical
attention.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognized skin cleanser. Do NOT use solvents or thinners.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
If swallowed, seek medical advice immediately and show this container or label.
Keep person warm and at rest. Do NOT induce vomiting.
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this
product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
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First aid measures4 .
Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Use dry chemical, CO₂, water spray (fog) or foam.
Fire-fighting measures
Extinguishing media
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Flammable liquid. Risk of explosion by shock, friction, fire or other sources of ignition.
May form explosive peroxide. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Vapors may
accumulate in low or confined areas or travel a considerable distance to a source of
ignition and flash back. Runoff to sewer may create fire or explosion hazard. Avoid
shock and friction. Keep away from heat, sparks and flame.
Special protective
equipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
5 .
Special exposure hazards :
Do not use water jet.
Suitable :
Not suitable :
Hazardous combustion
products
:Decomposition products may include the following materials:
carbon oxides
nitrogen oxides
sulfur oxides
halogenated compounds
metal oxide/oxides
Flammability of the product :
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment (see Section 8).
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an effluent
treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13). Do
not absorb in sawdust or other combustible material. It may lead to a fire risk when it
dries out. Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
Environmental precautions
Accidental release measures
:Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Personal precautions :
Large spill :
6 .
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb
with an inert dry material and place in an appropriate waste disposal container. Do not
absorb in sawdust or other combustible material. It may lead to a fire risk when it dries
out. Dispose of via a licensed waste disposal contractor.
Small spill :
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Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-
ventilated area, away from incompatible materials (see Section 10) and food and drink.
Eliminate all ignition sources. Separate from oxidizing materials. Separate from
reducing agents and combustible materials. See NFPA 430, Code for the Storage of
Liquid and Solid Oxidizers. Keep container tightly closed and sealed until ready for
use. Containers that have been opened must be carefully resealed and kept upright to
prevent leakage. Do not store in unlabeled containers. Use appropriate containment
to avoid environmental contamination. Do not store above the following temperature:
120F / 49C.
Put on appropriate personal protective equipment (see Section 8). Eating, drinking
and smoking should be prohibited in areas where this material is handled, stored and
processed. Persons with a history of skin sensitization problems should not be
employed in any process in which this product is used. Do not breathe vapor or mist.
Do not swallow. Do not get in eyes or on skin or clothing. Avoid shock and friction.
Avoid all possible sources of ignition (spark or flame). Use only with adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter
storage areas and confined spaces unless adequately ventilated. Keep in the original
container or an approved alternative made from a compatible material, kept tightly
closed when not in use. Store and use away from heat, sparks, open flame or any
other ignition source. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use non-sparking tools. Take precautionary measures against
electrostatic discharges. Vapors are heavier than air and may spread along floors. To
avoid fire or explosion, dissipate static electricity during transfer by grounding and
bonding containers and equipment before transferring material. Keep away from
combustible material. Add this product only to water. Never add water to this product.
Empty containers retain product residue and can be hazardous. Do not reuse
container. If this material is part of a multiple component system, read the Material
Safety Data Sheet(s) for the other component or components before blending as the
resulting mixture may have the hazards of all of its parts.
Handling and storage
Handling
Storage
:
:
7 .
Exposure controls/personal protection8 .
titanium dioxide TWA 10 mg/m³15 mg/m³ TD 10 mg/m³ TD 10 mg/m³
(as Ti)
Not
established
STEL Not
established
Not
established
Not
established
20 mg/m³
(as Ti)
Not
established
______________________________________________________________________________________________
acetone TWA 500 ppm 1000 ppm 500 ppm 1000 ppm Not
established
STEL 750 ppm Not
established
750 ppm 1260 ppm Not
established
______________________________________________________________________________________________
n-butyl acetate TWA 150 ppm 150 ppm 150 ppm 150 ppm Not
established
STEL 200 ppm Not
established
200 ppm 200 ppm Not
established
______________________________________________________________________________________________
PARACHLOROBENZOTRIFLUORIDE TWA Not
established
Not
established
Not
established
Not
established
25 ppm
______________________________________________________________________________________________
heptan-2-one TWA 50 ppm 100 ppm 25 ppm 50 ppm Not
established
STEL Not
established
Not
established
Not
established
100 ppm Not
established
______________________________________________________________________________________________
diiron trioxide TWA 5 mg/m³ R 10 mg/m³5 mg/m³ R 5 mg/m³ (as Not
Name Result ACGIH OSHA Ontario Mexico PPG
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Exposure controls/personal protection8 .
Fe)established
STEL Not
established
Not
established
Not
established
10 mg/m³
(as Fe)
Not
established
______________________________________________________________________________________________
silicon dioxide TWA Not
established
Not
established
Not
established
10 mg/m³
3 mg/m³ R
Not
established
______________________________________________________________________________________________
2-methoxy-1-methylethyl acetate TWA Not
established
Not
established
50 ppm Not
established
50 ppm
______________________________________________________________________________________________
Aluminium powder (stabilized)TWA 1 mg/m³ R 15 mg/m³
(as Al) TD
5 mg/m³ (as
Al) R
1 mg/m³ R 5 mg/m³
5 mg/m³
Not
established
______________________________________________________________________________________________
Mica-group minerals TWA 3 mg/m³ R 20 mppcf Z 3 mg/m³ R 3 mg/m³Not
established
______________________________________________________________________________________________
Talc , not containing asbestiform
fibres
TWA Not
established
20 mppcf Z 2 mg/m³ R 2 mg/m³ R Not
established
______________________________________________________________________________________________
barium sulfate TWA 10 mg/m³15 mg/m³ TD
5 mg/m³ R
10 mg/m³ TD Not
established
Not
established
______________________________________________________________________________________________
ethyl 3-ethoxypropionate TWA Not
established
Not
established
50 ppm Not
established
50 ppm
STEL Not
established
Not
established
Not
established
Not
established
100 ppm
______________________________________________________________________________________________
Isopropyl alcohol TWA 200 ppm 400 ppm 200 ppm 400 ppm Not
established
STEL 400 ppm Not
established
400 ppm 500 ppm Not
established
______________________________________________________________________________________________
aluminium hydroxide TWA 1 mg/m³Not
established
Not
established
Not
established
Not
established
______________________________________________________________________________________________
Stoddard solvent TWA 100 ppm 500 ppm 100 ppm 100 ppm Not
established
STEL Not
established
Not
established
Not
established
200 ppm Not
established
______________________________________________________________________________________________
1,2,4-trimethylbenzene TWA 25 ppm Not
established
25 ppm 25 ppm Not
established
STEL Not
established
Not
established
Not
established
35 ppm Not
established
______________________________________________________________________________________________
xylene TWA 100 ppm 100 ppm 100 ppm 100 ppm Not
established
STEL 150 ppm Not
established
150 ppm 150 ppm Not
established
______________________________________________________________________________________________
carbon black respirable TWA 3 mg/m³3.5 mg/m³3 mg/m³3.5 mg/m³Not
established
STEL Not
established
Not
established
Not
established
7 mg/m³Not
established
______________________________________________________________________________________________
chromium (III) oxide TWA 0.5 mg/m³
(measured
as Cr)
0.5 mg/m3
0.5 mg/m³
(as Cr)
0.5 mg/m³
(as Cr)
0.5 mg/m³ ()Not
established
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Exposure controls/personal protection8 .
Acceptable Maximum PeakA=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
TD =Total dust
Key to abbreviations
If workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator
complying with an approved standard if a risk assessment indicates this is necessary.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator.
Safety glasses with side shields.
Personal protection
Eyes
Respiratory
Consult local authorities for acceptable exposure limits.
:
:
butyl rubberGloves:
Engineering measures :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation
or other engineering controls to keep worker exposure to airborne contaminants below
any recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Hygiene measures :Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Recommended monitoring
procedures
:If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Hands :Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
0.1 MG/M3 ()
TD
______________________________________________________________________________________________
ethylbenzene TWA 20 ppm 100 ppm 20 ppm 100 ppm Not
established
STEL Not
established
Not
established
Not
established
125 ppm Not
established
______________________________________________________________________________________________
mesitylene TWA 25 ppm Not
established
25 ppm 25 ppm Not
established
STEL Not
established
Not
established
Not
established
35 ppm Not
established
______________________________________________________________________________________________
STEL =
=
Short term Exposure limit values
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Exposure controls/personal protection8 .
Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist before
handling this product.
When there is a risk of ignition from static electricity, wear anti-static protective clothing.
For the greatest protection from static discharges, clothing should include anti-static
overalls, boots and gloves.
Skin :
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
>37.78°C (>100°F)
Liquid.
50% (v/v), 42% (w/w)
Not available.
Not available.
1.05
Not available.
Not available.
Not available.
Not available.
Boiling/condensation point
Melting/freezing point
Not available.
Physical and chemical properties
Physical state
pH
Specific gravity
Vapor pressure
Vapor density
Volatility
Evaporation rate
Odor
Color
:
:
:
:
:
:
:
:
:
:
:
Flash point :Closed cup: -10°C (14°F)
9 .
Partition coefficient: n-
octanol/water
:Not available.
% Solid. (w/w):58.4
Density ( lbs / gal ):8.76
Physical property values shown in this section are calculated averages. For specific product information, contact your
PPG Sales Representative.
The product may not be stable under certain conditions of storage or use.
Reactive or incompatible with the following materials:,water,combustible materials,
organic materials,metals,acids,alkalis,oxidizing materials,reducing materials
Under normal conditions of storage and use, hazardous polymerization will not occur.
Under normal conditions of storage and use, hazardous decomposition products
should not be produced.
Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Drying on
clothing or other combustible materials may cause fire. Avoid increased storage
temperature. Pressure hazard
Stability and reactivity
Stability
Conditions to avoid
Materials to avoid
Hazardous decomposition
products
Hazardous polymerization
:
:
:
:
:
10 .
11 .Toxicological information
Acute toxicity
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11 .Toxicological information
Conclusion/Summary :Not available.
Chronic toxicity
Conclusion/Summary :Not available.
titanium dioxide LD50 Oral Rat >10 g/kg -
acetone LD50 Oral Rat 1.8 g/kg -
LD50 Dermal Rabbit 20 g/kg -
LC50 Inhalation
Vapor
Rat 76000 mg/m3 4 hours
n-butyl acetate LD50 Oral Rat 10.768 g/kg -
LD50 Dermal Rabbit >17600 mg/kg -
LC50 Inhalation Rat >21.1 mg/l 4 hours
PARACHLOROBENZOTRIFLUORIDE LD50 Oral Rat 13 g/kg -
LD50 Dermal Rabbit >2.7 g/kg -
LC50 Inhalation
Vapor
Rat 33080 mg/m3 4 hours
heptan-2-one LD50 Oral Rat 1.6 g/kg -
LD50 Dermal Rabbit 10.206 g/kg -
diiron trioxide LD50 Oral Rat 10 g/kg -
2-methoxy-1-methylethyl acetate LD50 Oral Rat 8532 mg/kg -
LD50 Dermal Rabbit >5 g/kg -
polychloro copper phthalocyanine LD50 Oral Rat >5000 mg/kg -
Solvent naphtha (petroleum), light
aromatic
LD50 Oral Rat 8400 mg/kg -
LD50 Dermal Rabbit 3.48 g/kg -
Copper, [29H,31H-phthalocyaninato(2-)-
N29,N30,N31,N32]-, brominated
chlorinated
LD50 Oral Rat >5 g/kg -
29H,31H-phthalocyaninato(2-)-N29,N30,
N31,N32 copper
LD50 Oral Rat 5.1 g/kg -
Naphtha (petroleum), hydrotreated heavy LD50 Oral Rat >6 g/kg -
LC50 Inhalation Rat 8500 mg/m3 4 hours
ethyl 3-ethoxypropionate LD50 Oral Rat 3200 mg/kg -
LD50 Dermal Rabbit 10 mL/kg -
Isopropyl alcohol LD50 Oral Rat 4.396 g/kg -
LD50 Dermal Rabbit 12800 mg/kg -
LC50 Inhalation
Vapor
Rat 72600 mg/m3 4 hours
Stoddard solvent LD50 Oral Rat >5 g/kg -
1,2,4-trimethylbenzene LD50 Oral Rat 5 g/kg -
LC50 Inhalation Rat 18000 mg/m3 4 hours
xylene LD50 Oral Rat 4.3 g/kg -
LD50 Dermal Rabbit >1.7 g/kg -
LC50 Inhalation
Vapor
Rat 5000 ppm 4 hours
carbon black respirable LD50 Oral Rat >15400 mg/kg -
LD50 Dermal Rabbit >3 g/kg -
2-(2H-benzotriazol-2-yl)-4,
6-ditertpentylphenol
LD50 Oral Rat >2000 mg/kg -
LD50 Dermal Rabbit >2000 mg/kg -
ethylbenzene LD50 Oral Rat 3.5 g/kg -
LD50 Dermal Rabbit >5000 mg/kg -
LC50 Inhalation
Vapor
Rat 4000 ppm 4 hours
mesitylene LD50 Oral Rat 5000 mg/kg -
LC50 Inhalation Rat 24000 mg/m3 4 hours
Product/ingredient name Result Species Dose Exposure
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11 .Toxicological information
Carcinogenicity
Classification
Carcinogenicity :Contains material which may cause cancer, based on animal data. Risk of cancer
depends on duration and level of exposure.
Defatting irritant :Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or
dermatitis.
Target organs :Contains material which causes damage to the following organs: lungs, brain, central
nervous system (CNS), eye, lens or cornea.
Contains material which may cause damage to the following organs: blood, kidneys,
the nervous system, liver, spleen, peripheral nervous system, gastrointestinal tract,
cardiovascular system, upper respiratory tract, skin, testes.
Carcinogen Classification code:ACGIH: A1, A2, A3, A4, A5
IARC: 1, 2A, 2B, 3, 4
NTP: Proven, Possible
OSHA: +
Not listed or regulated as a carcinogen: -
Product/ingredient name
titanium dioxide A4 2B --
acetone A4 ---
diiron trioxide A4 3 --
silicon dioxide -3 --
Aluminium powder (stabilized)A4 ---
Isopropyl alcohol A4 3 --
aluminium hydroxide A4 ---
xylene A4 3 --
carbon black respirable A3 2B --
chromium (III) oxide A4 3 --
ethylbenzene A3 2B --
ACGIH NTP OSHAIARC
Ecological information
Environmental effects :No known significant effects or critical hazards.
12 .
Aquatic ecotoxicity
acetone Acute LC50 >100000 ug/L Fresh water Fish - Fathead minnow - Pimephales
promelas
96 hours
___________________________________________________________________________
Acute LC50 6900 mg/L Fresh water Daphnia - Water flea - Daphnia
magna
48 hours
___________________________________________________________________________
Acute EC50 7200000 ug/L Fresh water Algae - Green algae - Selenastrum
sp.
96 hours
_________________________________________________________________________________________________
n-butyl acetate Acute LC50 18000 to 19000 ug/L
Fresh water
Fish - Fathead minnow - Pimephales
promelas
96 hours
_________________________________________________________________________________________________
heptan-2-one Acute LC50 131000 to 137000 ug/L
Fresh water
Fish - Fathead minnow - Pimephales
promelas
96 hours
_________________________________________________________________________________________________
barium sulfate Acute EC50 32000 ug/L Fresh water Daphnia - Water flea - Daphnia
magna
48 hours
_________________________________________________________________________________________________
Isopropyl alcohol Acute LC50 >1400000 ug/L Fish - Bluegill - Lepomis macrochirus 96 hours
_________________________________________________________________________________________________
zinc sulphide Acute LC50 1826000 ug/L Fresh water Fish - Fathead minnow - Pimephales 96 hours
Product/ingredient
name
SpeciesResult Exposure
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Ecological information12 .
promelas
___________________________________________________________________________
Acute LC50 >30000 mg/L Fresh water Daphnia - Water flea - Daphnia
magna
48 hours
_________________________________________________________________________________________________
1,2,4-trimethylbenzene Acute LC50 7720 to 8280 ug/L Fresh
water
Fish - Fathead minnow - Pimephales
promelas
96 hours
_________________________________________________________________________________________________
xylene Acute LC50 3300 to 4093 ug/L Fresh
water
Fish - Rainbow trout,donaldson trout -
Oncorhynchus mykiss
96 hours
_________________________________________________________________________________________________
ethylbenzene Acute LC50 4200 ug/L Fresh water Fish - Rainbow trout,donaldson trout -
Oncorhynchus mykiss
96 hours
___________________________________________________________________________
Acute LC50 5100 to 5700 ug/L Marine
water
Fish - Atlantic silverside - Menidia
menidia
96 hours
___________________________________________________________________________
Acute EC50 2930 to 4400 ug/L Fresh
water
Daphnia - Water flea - Daphnia
magna
48 hours
___________________________________________________________________________
Chronic NOEC 3300 ug/L Marine water Fish - Atlantic silverside - Menidia
menidia
96 hours
___________________________________________________________________________
Chronic NOEC 6800 ug/L Fresh water Daphnia - Water flea - Daphnia
magna
48 hours
_________________________________________________________________________________________________
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated
to the sewer unless fully compliant with the requirements of all authorities with
jurisdiction. Waste packaging should be recycled. Incineration or landfill should only
be considered when recycling is not feasible. This material and its container must be
disposed of in a safe way. Care should be taken when handling emptied containers
that have not been cleaned or rinsed out. Empty containers or liners may retain some
product residues. Vapor from product residues may create a highly flammable or
explosive atmosphere inside the container. Do not cut, weld or grind used containers
unless they have been cleaned thoroughly internally. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers.
Waste disposal
Disposal considerations
Disposal should be in accordance with applicable regional, national and local laws and regulations.
:
13 .
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
14. Transport information
PAINT
3
II
PAINT
3
II
UN1263 UN1263
DOT Mexico
UN number
UN proper shipping
name
Transport hazard
class(es)
Packing group
TDG
UN1263
PAINT
3
II
IMDG
UN1263
PAINT
3
II
Page: 10/13United States - Canada - Mexico
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14. Transport information
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
Package sizes shipped in quantities less than the product reportable quantity are not subject to the
RQ (reportable quantity) transportation requirements.
None identified.
None identified.
DOT
TDG
Mexico
:
:
:
Environmental
hazards
No.No.No.
Marine pollutant
substances
IMDG :None identified.
No.
Not applicable.
7260.2
RQ substances (xylene, acetone)Not applicable.
Not applicable.Not applicable.
Not applicable.
Not applicable.
Not applicable.
Not applicable.Not applicable.
Product RQ (lbs)
Not applicable.
15 .Regulatory information
At least one component is not listed.
At least one component is not listed. Unlisted component(s) have been notified
and volumes are being tracked.
At least one component is not listed.
At least one component is not listed.
Not determined.
At least one component is not listed.
At least one component is not listed.
All components are listed or exempted.United States inventory (TSCA 8b):
Australia inventory (AICS)
Canada inventory ( DSL ):
China inventory (IECSC):
Japan inventory (ENCS):
Korea inventory (KECI):
New Zealand ( NZIoC ):
Philippines inventory (PICCS):
:
Europe inventory ( REACH ):Please contact your supplier for information on the inventory status of this
material.
United States
CERCLA: Hazardous substances.: [N,N,N',N',N'',N''-hexaethyl-29H,31H-phthalocyaninetrimethylaminato(2-)-N29,N30,
N31,N32]copper: No RQ is being assigned to the generic or broad class.; ethylbenzene: 1000 lbs. (454 kg); butanone:
5000 lbs. (2270 kg); 2-butoxyethanol: No RQ is being assigned to the generic or broad class.; Zinc Phosphate
Compound; chromium (III) oxide: No RQ is being assigned to the generic or broad class.; xylene: 100 lbs. (45.4 kg);
zinc sulphide: No RQ is being assigned to the generic or broad class.; [trichloro-29H,31H-phthalocyaninato(2-)-N29,
N30,N31,N32]copper: No RQ is being assigned to the generic or broad class.; 29H,31H-phthalocyaninato(2-)-N29,
N30,N31,N32 copper: No RQ is being assigned to the generic or broad class.; Copper, [29H,31H-phthalocyaninato(2-)-
N29,N30,N31,N32]-, brominated chlorinated: No RQ is being assigned to the generic or broad class.; polychloro
copper phthalocyanine: No RQ is being assigned to the generic or broad class.; n-butyl acetate: 5000 lbs. (2270 kg);
acetone: 5000 lbs. (2270 kg);
SARA 302/304: Formaldehyde; Hydrogen chloride; 1,4-dihydroxybenzene
SARA 311/312 SDS Distribution - Chemical Inventory - Hazard Identification:
titanium dioxide 13463-67-7 N Y N N N
acetone 67-64-1 Y N Y N N
n-butyl acetate 123-86-4 Y N Y N N
PARACHLOROBENZOTRIFLUORIDE 98-56-6 Y N Y N N
heptan-2-one 110-43-0 Y N Y N N
diiron trioxide 1309-37-1 N N N N N
silicon dioxide 7631-86-9 N N N N N
Chemical name CAS #Acute Chronic Fire Reactive Pressure
Page: 11/13United States - Canada - Mexico
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HS Polyurethane Single StageProduct name
7Product code Date of issue VersionESSS-1 21 January 2014
15 .Regulatory information
SARA 313 CAS number Concentration
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
Supplier notification bismuth vanadium tetraoxide 14059-33-7 10 - 30
Aluminium powder (stabilized)7429-90-5 5 - 10
Copper, [29H,31H-phthalocyaninato(2-)-N29,N30,
N31,N32]-, brominated chlorinated
68512-13-0 1 - 5
[trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,
N31,N32]copper
29719-96-8 1 - 5
Isopropyl alcohol 67-63-0 1 - 5
zinc sulphide 1314-98-3 1 - 5
1,2,4-trimethylbenzene 95-63-6 1 - 5
xylene 1330-20-7 0.5 - 1.5
chromium (III) oxide 1308-38-9 0.5 - 1.5
ethylbenzene 100-41-4 0.1 - 1
2-methoxy-1-methylethyl acetate 108-65-6 Y N Y N N
Aluminium powder (stabilized)7429-90-5 N N N Y N
Mica-group minerals 12001-26-2 N N N N N
Talc , not containing asbestiform
fibres
14807-96-6 Y N N N N
Solvent naphtha (petroleum), light
aliph.
64742-89-8 Y N N N N
barium sulfate 7727-43-7 N N N N N
Solvent naphtha (petroleum), light
aromatic
64742-95-6 Y N Y N N
Naphtha (petroleum), hydrotreated
heavy
64742-48-9 Y N Y N N
Cashew, nutshell liq.,
2-hydroxyethyl ethers
232268-65-4 Y N N N N
ethyl 3-ethoxypropionate 763-69-9 Y N Y Y N
Isopropyl alcohol 67-63-0 Y N Y N N
aluminium hydroxide 21645-51-2 N N N N N
Stoddard solvent 8052-41-3 Y N Y N N
zinc sulphide 1314-98-3 Y N N N N
1,2,4-trimethylbenzene 95-63-6 Y N Y N N
xylene 1330-20-7 Y N Y N N
carbon black respirable 1333-86-4 N Y N N N
chromium (III) oxide 1308-38-9 N N N N N
2-(2H-benzotriazol-2-yl)-4,
6-ditertpentylphenol
25973-55-1 N N N N N
Naphtha (petroleum), heavy alkylate 64741-65-7 Y N Y N N
ethylbenzene 100-41-4 Y Y Y N N
Product as-supplied :Y Y Y Y N
Chemical name
California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer.
WHMIS (Canada)Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-2A:
Material causing other toxic effects (Very toxic). Class D-2B: Material causing other
toxic effects (Toxic).
:
Canada
Mexico
3 2 1HealthFlammabilityReactivity
Classification
:::
Page: 12/13United States - Canada - Mexico
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7Product code Date of issue VersionESSS-1 21 January 2014
Other information
Hazardous Material Information System (U.S.A.)
3
13
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary
measures described in this data sheet or for any misuse of the products.
Date of previous issue 11/29/2013.:
16 .
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller [phone].
The customer is responsible for determining the PPE code for this material.
Indicates information that has changed from previously issued version.
Organization that prepared
the MSDS
:EHS
:::
:::2 *
2
1
( * ) - Chronic
effects
Page: 13/13United States - Canada - Mexico
Powered by IHS
HS Polyurethane Single StageProduct name
Product and company identification
:
1 .
ESSS-2
PPG Industries, Inc.
One PPG Place,
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
01-800-00-21-400 (Mexico)
Supplier
Code
Emergency telephone
number
:
:
:
Technical Phone Number :[phone] (DELAWARE, OH) 8:00 a.m. - 5:00 p.m. EST
Material Safety Data Sheet
Date of issue 3 August 2012
Version 4
Emergency overview
Hazards identification
Potential acute health effects
May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and
cause damage.
Eyes
Skin
Inhalation
Ingestion
DANGER!:
:
:
:
:
2 .
Over-exposure signs/symptoms
Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and
nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes
headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated
exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected
from exposure to noise alone. Contains Lead. Lead poisoning is characterized by a metallic taste in the mouth, loss of
apetite, indigestion, nausea, vomiting, constipation, abdominal cramps, disturbance of rest and sleep and weakness.
Dryness, itching, cracking, burning, redness and swelling are conditions associated with excessive skin contact.
Exposure to lead dust and fumes adversely affects blood and blood forming tissues, kidneys, liver, the central/peripheral
nervous systems and male/female reproductive organs. Lead exposure causes adverse developmental effects including
brain damage in children and unborn fetuses. NTP, IARC, and OSHA have classified chromium (+6) compounds as
This material increases the risk of fire and may aid combustion. Keep away from heat,
sparks and flame. Keep away from flames, such as a pilot light, and any object that
sparks, such as an electric motor. Keep away from heat. Do not smoke. Keep away
from combustible material. Do not breathe vapor or mist. Do not swallow. Do not get in
eyes or on skin or clothing. Use only with adequate ventilation. Keep container tightly
closed and sealed until ready for use. Wash thoroughly after handling.
FLAMMABLE LIQUID AND VAPOR. HARMFUL IF ABSORBED THROUGH SKIN.
CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY CAUSE
ALLERGIC RESPIRATORY AND SKIN REACTION. CONTAINS LEAD. DRIED FILM
OF THIS PAINT MAY BE HARMFUL IF EATEN OR CHEWED. MAY BE HARMFUL IF
INHALED OR SWALLOWED. SANDING AND GRINDING DUSTS MAY BE HARMFUL
IF INHALED. ASPIRATION HAZARD. CAN ENTER LUNGS AND CAUSE DAMAGE.
PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION.
CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. CANCER
HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE CANCER. May form
explosive peroxides. Risk of explosion by shock, friction, fire or other sources of ignition.
Add this product only to water. Never add water to this product.
May be harmful if inhaled. Severely irritating to the respiratory system. Can irritate eyes,
nose, mouth and throat. May cause sensitization by inhalation. Exposure to
decomposition products may cause a health hazard. Serious effects may be delayed
following exposure.
Irritating to eyes.
Toxic in contact with skin. Irritating to skin. May cause an allergic skin reaction.
Page: 1/15United States - Canada - Mexico
HS Polyurethane Single StageProduct name
4Product code Date of issue VersionESSS-2 3 August 2012
Hazards identification2 .
See toxicological information (Section 11)
Medical conditions
aggravated by over-
exposure
Pre-existing respiratory and skin disorders and disorders involving any other target
organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to
this product.
:
carcinogenic. OSHA considers all Cr+6 compounds as potential occupational carcinogens capable of causing lung
cancer above the recommended exposure limits.
This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials
Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Composition/information on ingredients3 .
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
titanium dioxide 13463-67-7 40 - 70
acetone 67-64-1 10 - 30
n-butyl acetate 123-86-4 10 - 30
PARACHLOROBENZOTRIFLUORIDE 98-56-6 10 - 30
heptan-2-one 110-43-0 10 - 30
diiron trioxide 1309-37-1 10 - 30
Lead sulfochromate yellow 1344-37-2 7 - 13
silicon dioxide 7631-86-9 7 - 13
2-methoxy-1-methylethyl acetate 108-65-6 7 - 13
Lead chromate molybdate sulfate red 12656-85-8 7 - 13
Aluminium powder (stabilized)7429-90-5 5 - 10
Mica-group minerals 12001-26-2 3 - 7
Talc , not containing asbestiform fibres 14807-96-6 3 - 7
Solvent naphtha (petroleum), light arom.64742-95-6 1 - 5
polychloro copper phthalocyanine 1328-53-6 1 - 5
Solvent naphtha (petroleum), light aliph.64742-89-8 1 - 5
barium sulfate 7727-43-7 1 - 5
Copper, [29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, brominated chlorinated 68512-13-0 1 - 5
29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32 copper 147-14-8 1 - 5
[trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper 29719-96-8 1 - 5
Naphtha (petroleum), hydrotreated heavy 64742-48-9 1 - 5
Cashew, nutshell liq., 2-hydroxyethyl ethers 232268-65-4 1 - 5
ethyl 3-ethoxypropionate 763-69-9 1 - 5
propan-2-ol 67-63-0 1 - 5
aluminium hydroxide 21645-51-2 1 - 5
Stoddard solvent 8052-41-3 1 - 5
1,2,4-trimethylbenzene 95-63-6 1 - 5
Decanedioic acid, 1,10-bis(2,2,6,6-tetramethyl-4-piperidinyl) ester, reaction products
with tert-Bu hydroperoxide and octane
129757-67-1 1 - 5
zinc sulphide 1314-98-3 1 - 5
xylene 1330-20-7 0.5 - 1.5
Carbon black 1333-86-4 0.5 - 1.5
chromium (III) oxide 1308-38-9 0.5 - 1.5
2-(2H-benzotriazol-2-yl)-4,6-ditertpentylphenol 25973-55-1 0.5 - 1.5
Naphtha (petroleum), heavy alkylate 64741-65-7 0.1 - 1
antimony trioxide 1309-64-4 0.1 - 1
Kaolin 1332-58-7 0.1 - 1
ethylbenzene 100-41-4 0.1 - 1
mesitylene 108-67-8 0.1 - 1
sodium fluoride 7681-49-4 0.1 - 1
lead 7439-92-1 < 0.1
Name CAS number %
Page: 2/15United States - Canada - Mexico
HS Polyurethane Single StageProduct name
4Product code Date of issue VersionESSS-2 3 August 2012
First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
Notes to physician
:
:
:
:
:
4 .
Check for and remove any contact lenses. Immediately flush eyes with running
water for at least 15 minutes, keeping eyelids open. Seek immediate medical
attention.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognized skin cleanser. Do NOT use solvents or thinners.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
If swallowed, seek medical advice immediately and show this container or label.
Keep person warm and at rest. Do NOT induce vomiting.
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this
product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Use dry chemical, CO₂, water spray (fog) or foam.
Fire-fighting measures
Extinguishing media
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool. Fire water contaminated with this material
must be contained and prevented from being discharged to any waterway, sewer or
drain.
Flammable liquid. Risk of explosion by shock, friction, fire or other sources of ignition.
May form explosive peroxide. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Vapors may
accumulate in low or confined areas or travel a considerable distance to a source of
ignition and flash back. Runoff to sewer may create fire or explosion hazard. Avoid
shock and friction. Keep away from heat, sparks and flame.
Special protective
equipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
5 .
Special exposure hazards :
Do not use water jet.
Suitable :
Not suitable :
Hazardous combustion
products
:Decomposition products may include the following materials:
carbon oxides
nitrogen oxides
sulfur oxides
oxides of lead
halogenated compounds
metal oxide/oxides
Flammability of the product :
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment (see Section 8).
Environmental precautions
Accidental release measures
:Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities.
Personal precautions :
6 .
Page: 3/15United States - Canada - Mexico
HS Polyurethane Single StageProduct name
4Product code Date of issue VersionESSS-2 3 August 2012
Accidental release measures6 .
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an effluent
treatment plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Do not absorb in
sawdust or other combustible material. It may lead to a fire risk when it dries out.
Dispose of via a licensed waste disposal contractor. Contaminated absorbent material
may pose the same hazard as the spilled product. Note: see Section 1 for emergency
contact information and Section 13 for waste disposal.
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb with
an inert dry material and place in an appropriate waste disposal container. Do not
absorb in sawdust or other combustible material. It may lead to a fire risk when it dries
out. Dispose of via a licensed waste disposal contractor.
Small spill :
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Eliminate
all ignition sources. Separate from oxidizing materials. Separate from reducing agents
and combustible materials. See NFPA 430, Code for the Storage of Liquid and Solid
Oxidizers. Keep container tightly closed and sealed until ready for use. Containers that
have been opened must be carefully resealed and kept upright to prevent leakage. Do
not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination. Do not store above the following temperature: 120F / 49C.
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Persons with a history of skin sensitization problems or asthma, allergies or
chronic or recurrent respiratory disease should not be employed in any process in which
this product is used. Do not breathe vapor or mist. Ingestion of product or cured
coating may be harmful. Do not swallow. Do not get in eyes or on skin or clothing.
Avoid shock and friction. Avoid all possible sources of ignition (spark or flame). Avoid
release to the environment. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Store
and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
non-sparking tools. Take precautionary measures against electrostatic discharges.
Vapors are heavier than air and may spread along floors. To avoid fire or explosion,
dissipate static electricity during transfer by grounding and bonding containers and
equipment before transferring material. Keep away from combustible material. Add this
product only to water. Never add water to this product. Empty containers retain product
residue and can be hazardous. Do not apply on toys and other children's articles,
furniture, or interior surfaces of any dwelling or facility which may be occupied or used
by children. Do not apply on exterior surfaces of dwelling units, such as window sills,
porches, stairs, or railings, to which children may be commonly exposed. Do not reuse
container. If this material is part of a multiple component system, read the Material
Safety Data Sheet(s) for the other component or components before blending as the
resulting mixture may have the hazards of all of its parts.
Handling and storage
Handling
Storage
:
:
7 .
Page: 4/15United States - Canada - Mexico
HS Polyurethane Single StageProduct name
4Product code Date of issue VersionESSS-2 3 August 2012
Exposure controls/personal protection8 .
titanium dioxide TWA 10 mg/m³15 mg/m³ TD 10 mg/m³ TD 10 mg/m³
(as Ti)
Not
established
STEL Not
established
Not
established
Not
established
20 mg/m³
(as Ti)
Not
established
______________________________________________________________________________________________
acetone TWA 500 ppm 1000 ppm 500 ppm 1000 ppm Not
established
STEL 750 ppm Not
established
750 ppm 1260 ppm Not
established
______________________________________________________________________________________________
n-butyl acetate TWA 150 ppm 150 ppm 150 ppm 150 ppm Not
established
STEL 200 ppm Not
established
200 ppm 200 ppm Not
established
______________________________________________________________________________________________
PARACHLOROBENZOTRIFLUORIDE TWA Not
established
Not
established
Not
established
Not
established
25 ppm
______________________________________________________________________________________________
heptan-2-one TWA 50 ppm 100 ppm 25 ppm 50 ppm Not
established
STEL Not
established
Not
established
Not
established
100 ppm Not
established
______________________________________________________________________________________________
diiron trioxide TWA 5 mg/m³ R 10 mg/m³5 mg/m³ R 5 mg/m³ (as
Fe)
Not
established
STEL Not
established
Not
established
Not
established
10 mg/m³
(as Fe)
Not
established
______________________________________________________________________________________________
Lead sulfochromate yellow TWA 0.05 mg/m³
(as Pb)
0.05 MG/M3
() TD
0.05 mg/m³
(measured
as Cr)
5 mg/m3
50 ug/m3
5 µg/m³
0.05 mg/m³
(as Cr)
0.05 mg/m³
(as Pb)
0.15 mg/m³
(as Pb)
0.005 mg/m³
STEL Not
established
0.1 mg/m³ C Not
established
Not
established
Not
established
______________________________________________________________________________________________
silicon dioxide TWA Not
established
Not
established
Not
established
10 mg/m³
3 mg/m³ R
Not
established
______________________________________________________________________________________________
2-methoxy-1-methylethyl acetate TWA Not
established
Not
established
50 ppm Not
established
50 ppm
______________________________________________________________________________________________
Lead chromate molybdate sulfate
red
TWA 0.05 mg/m³
(as Pb)
0.05 MG/M3
TD
3 MG/M3 R
0.05 mg/m³
(measured
as Cr)
5 µg/m³
10 mg/m3
5 mg/m3
50 ug/m3
0.05 mg/m³
(as Cr)
0.05 mg/m³
(as Pb)
0.15 mg/m³
(as Pb)
0.005 mg/m³
STEL Not
established
1 mg/10m³ Z
C
Not
established
Not
established
Not
established
______________________________________________________________________________________________
Aluminium powder (stabilized)TWA 1 mg/m³ R 5 mg/m³ (as
Al) R
15 mg/m³
(as Al) TD
1 mg/m³ R 5 mg/m³
5 mg/m³
Not
established
Name Result ACGIH OSHA Ontario Mexico PPG
Page: 5/15United States - Canada - Mexico
HS Polyurethane Single StageProduct name
4Product code Date of issue VersionESSS-2 3 August 2012
Exposure controls/personal protection8 .
______________________________________________________________________________________________
Mica-group minerals TWA 3 mg/m³ R 20 mppcf Z 3 mg/m³ R 3 mg/m³Not
established
______________________________________________________________________________________________
Talc , not containing asbestiform
fibres
TWA 2 mg/m³ R 20 mppcf Z 2 mg/m³ R 2 mg/m³ R Not
established
______________________________________________________________________________________________
barium sulfate TWA 10 mg/m³5 mg/m³ R
15 mg/m³ TD
10 mg/m³ TD Not
established
Not
established
______________________________________________________________________________________________
ethyl 3-ethoxypropionate TWA Not
established
Not
established
50 ppm Not
established
50 ppm
STEL Not
established
Not
established
Not
established
Not
established
100 ppm
______________________________________________________________________________________________
propan-2-ol TWA 200 ppm 400 ppm 200 ppm 400 ppm Not
established
STEL 400 ppm Not
established
400 ppm 500 ppm Not
established
______________________________________________________________________________________________
aluminium hydroxide TWA 1 mg/m³Not
established
Not
established
2 mg/m³Not
established
______________________________________________________________________________________________
Stoddard solvent TWA 100 ppm 500 ppm 100 ppm 100 ppm Not
established
STEL Not
established
Not
established
Not
established
200 ppm Not
established
______________________________________________________________________________________________
1,2,4-trimethylbenzene TWA 25 ppm Not
established
25 ppm 25 ppm Not
established
STEL Not
established
Not
established
Not
established
35 ppm Not
established
______________________________________________________________________________________________
xylene TWA 100 ppm 100 ppm 100 ppm 100 ppm Not
established
STEL 150 ppm Not
established
150 ppm 150 ppm Not
established
______________________________________________________________________________________________
Carbon black TWA 3 mg/m³3.5 mg/m³3.5 mg/m³3.5 mg/m³Not
established
STEL Not
established
Not
established
Not
established
7 mg/m³Not
established
______________________________________________________________________________________________
chromium (III) oxide TWA 0.5 mg/m³
(measured
as Cr)
0.1 MG/M3 ()
TD
0.5 mg/m3
0.5 mg/m³
(as Cr)
0.5 mg/m³
(as Cr)
0.5 mg/m³ ()Not
established
______________________________________________________________________________________________
antimony trioxide TWA 0.5 mg/m³
(as Sb)
0.5 mg/m³
(as Sb)
0.5 mg/m3
(as Sb)
0.5 mg/m³
(as Sb)
0.5 mg/m³
(as Sb)
1 mg/m³
Not
established
______________________________________________________________________________________________
Kaolin TWA 2 mg/m³ R 5 mg/m³ R
15 mg/m³ TD
2 mg/m³ R 10 mg/m³Not
established
STEL Not
established
Not
established
Not
established
20 mg/m³Not
established
______________________________________________________________________________________________
ethylbenzene TWA 20 ppm 100 ppm 100 ppm 100 ppm Not
established
STEL Not Not 125 ppm 125 ppm Not
Page: 6/15United States - Canada - Mexico
HS Polyurethane Single StageProduct name
4Product code Date of issue VersionESSS-2 3 August 2012
Exposure controls/personal protection8 .
Acceptable Maximum PeakA=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
TD =Total dust
Key to abbreviations
By spraying: air-fed respirator. By other operations than spraying, in well ventilated
areas, air-fed respirators could be replaced by a combination charcoal filter and
particulate filter mask. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected
respirator.
Safety glasses with side shields.
Personal protection
Eyes
Respiratory
Consult local authorities for acceptable exposure limits.
:
:
butyl rubberGloves:
Engineering measures :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Hygiene measures :Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Recommended monitoring
procedures
:If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Hands :Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
established established established
______________________________________________________________________________________________
mesitylene TWA 25 ppm Not
established
25 ppm 25 ppm Not
established
STEL Not
established
Not
established
Not
established
35 ppm Not
established
______________________________________________________________________________________________
sodium fluoride TWA 2.5 mg/m³
(as F)
2.5 mg/m³
(as F)
2.5 mg/m³
TD Z
2.5 mg/m³
(as F)
Not
established
Not
established
______________________________________________________________________________________________
lead TWA 0.05 mg/m³
(as Pb)
50 µg/m³ (as
Pb)
50 ug/m3
0.05 mg/m³
(as Pb)
Not
established
Not
established
______________________________________________________________________________________________
STEL =
=
Short term Exposure limit values
Page: 7/15United States - Canada - Mexico
HS Polyurethane Single StageProduct name
4Product code Date of issue VersionESSS-2 3 August 2012
Exposure controls/personal protection8 .
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
When there is a risk of ignition from static electricity, wear anti-static protective clothing.
For the greatest protection from static discharges, clothing should include anti-static
overalls, boots and gloves.
Skin :
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment will
be necessary to reduce emissions to acceptable levels.
>37.78°C (>100°F)
Liquid.
50% (v/v), 42% (w/w)
Not available.
Not available.
1.05
Not available.
Not available.
Not available.
Not available.
Boiling/condensation point
Melting/freezing point
Not available.
Physical and chemical properties
Physical state
pH
Specific gravity
Vapor pressure
Vapor density
Volatility
Evaporation rate
Odor
Color
:
:
:
:
:
:
:
:
:
:
:
Flash point :Closed cup: -10°C (14°F)
9 .
Partition coefficient: n-
octanol/water
:Not available.
% Solid. (w/w):58.4
Density ( lbs / gal ):8.76
Physical property values shown in this section are calculated averages. For specific product information, contact your PPG
Sales Representative.
The product may not be stable under certain conditions of storage or use.
Reactive or incompatible with the following materials:,water,combustible materials,
organic materials,metals,acids,alkalis,oxidizing materials,reducing materials
Under normal conditions of storage and use, hazardous polymerization will not occur.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Drying on
clothing or other combustible materials may cause fire. Avoid increased storage
temperature. Pressure hazard
Stability and reactivity
Stability
Conditions to avoid
Materials to avoid
Hazardous decomposition
products
Hazardous polymerization
:
:
:
:
:
10 .
11 .Toxicological information
Acute toxicity
Page: 8/15United States - Canada - Mexico
HS Polyurethane Single StageProduct name
4Product code Date of issue VersionESSS-2 3 August 2012
11 .Toxicological information
Conclusion/Summary :Not available.
Chronic toxicity
Conclusion/Summary :Not available.
titanium dioxide LD50 Oral Rat >10 g/kg -
acetone LD50 Oral Rat 1.8 g/kg -
LD50 Dermal Rabbit 20 g/kg -
LC50 Inhalation
Vapor
Rat 76000 mg/m3 4 hours
n-butyl acetate LD50 Oral Rat 10.768 g/kg -
LD50 Dermal Rabbit >17600 mg/kg -
LC50 Inhalation Rat >21.1 mg/l 4 hours
PARACHLOROBENZOTRIFLUORIDE LD50 Oral Rat 13 g/kg -
LD50 Dermal Rabbit >2.7 g/kg -
LC50 Inhalation
Vapor
Rat 33080 mg/m3 4 hours
heptan-2-one LD50 Oral Rat 1.6 g/kg -
LD50 Dermal Rabbit 10.206 g/kg -
diiron trioxide LD50 Oral Rat 10 g/kg -
Lead sulfochromate yellow LD50 Oral Rat 1.2 g/kg -
2-methoxy-1-methylethyl acetate LD50 Oral Rat 8532 mg/kg -
LD50 Dermal Rabbit >5 g/kg -
Solvent naphtha (petroleum), light arom.LD50 Oral Rat 8400 mg/kg -
LD50 Dermal Rabbit 3.48 g/kg -
polychloro copper phthalocyanine LD50 Oral Rat >5000 mg/kg -
Copper, [29H,31H-phthalocyaninato(2-)-
N29,N30,N31,N32]-, brominated
chlorinated
LD50 Oral Rat >5 g/kg -
29H,31H-phthalocyaninato(2-)-N29,N30,
N31,N32 copper
LD50 Oral Rat 5.1 g/kg -
Naphtha (petroleum), hydrotreated heavy LD50 Oral Rat >6 g/kg -
LC50 Inhalation Rat 8500 mg/m3 4 hours
ethyl 3-ethoxypropionate LD50 Oral Rat 3200 mg/kg -
LD50 Dermal Rabbit 10 mL/kg -
propan-2-ol LD50 Oral Rat 4.396 g/kg -
LD50 Dermal Rabbit 12800 mg/kg -
LC50 Inhalation
Vapor
Rat 72600 mg/m3 4 hours
Stoddard solvent LD50 Oral Rat >5 g/kg -
1,2,4-trimethylbenzene LD50 Oral Rat 5 g/kg -
LC50 Inhalation Rat 18000 mg/m3 4 hours
xylene LD50 Oral Rat 4.3 g/kg -
LD50 Dermal Rabbit >1.7 g/kg -
LC50 Inhalation
Vapor
Rat 5000 ppm 4 hours
Carbon black LD50 Oral Rat >15400 mg/kg -
LD50 Dermal Rabbit >3 g/kg -
2-(2H-benzotriazol-2-yl)-4,
6-ditertpentylphenol
LD50 Oral Rat >2000 mg/kg -
LD50 Dermal Rabbit >2000 mg/kg -
Kaolin LD50 Oral Rat >5000 mg/kg -
ethylbenzene LD50 Oral Rat 3.5 g/kg -
LD50 Dermal Rabbit >5000 mg/kg -
LC50 Inhalation
Vapor
Rat 4000 ppm 4 hours
mesitylene LD50 Oral Rat 5000 mg/kg -
LC50 Inhalation Rat 24000 mg/m3 4 hours
sodium fluoride LD50 Oral Rat 31 mg/kg -
Product/ingredient name Result Species Dose Exposure
Page: 9/15United States - Canada - Mexico
HS Polyurethane Single StageProduct name
4Product code Date of issue VersionESSS-2 3 August 2012
11 .Toxicological information
Carcinogenicity
Classification
Carcinogenicity :Contains material which can cause cancer. Risk of cancer depends on duration and
level of exposure.
Defatting irritant :Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or
dermatitis.
Target organs :Contains material which causes damage to the following organs: lungs, brain, central
nervous system (CNS), eye, lens or cornea.
Contains material which may cause damage to the following organs: blood, kidneys, the
nervous system, liver, spleen, peripheral nervous system, gastrointestinal tract,
cardiovascular system, upper respiratory tract, skin, nose/sinuses, testes, throat.
Teratogenicity
Reproductive toxicity
Carcinogen Classification code:ACGIH: A1, A2, A3, A4, A5
IARC: 1, 2A, 2B, 3, 4
NTP: Proven, Possible
OSHA: +
Not listed or regulated as a carcinogen: -
Product/ingredient name
titanium dioxide A4 2B --
acetone A4 ---
diiron trioxide A4 3 --
Lead sulfochromate yellow A1 1 Possible -
silicon dioxide -3 --
Lead chromate molybdate sulfate red A1 1 Possible -
Aluminium powder (stabilized)A4 ---
propan-2-ol A4 3 --
aluminium hydroxide A4 ---
xylene A4 3 --
Carbon black A3 2B --
chromium (III) oxide A4 3 --
antimony trioxide A2 2B --
ethylbenzene A3 2B --
sodium fluoride A4 3 --
ACGIH NTP OSHAIARC
Ecological information
Environmental effects :Water polluting material. May be harmful to the environment if released in large
quantities.
12 .
Aquatic ecotoxicity
acetone Acute LC50 >100000 ug/L Fresh water Fish - Fathead minnow - Pimephales
promelas
96 hours
___________________________________________________________________________
Acute LC50 10000 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours
___________________________________________________________________________
Acute EC50 7200000 ug/L Fresh water Algae - Green algae - Selenastrum sp.96 hours
_________________________________________________________________________________________________
n-butyl acetate Acute LC50 18000 to 19000 ug/L
Fresh water
Fish - Fathead minnow - Pimephales
promelas
96 hours
_________________________________________________________________________________________________
heptan-2-one Acute LC50 131000 to 137000 ug/L
Fresh water
Fish - Fathead minnow - Pimephales
promelas
96 hours
_________________________________________________________________________________________________
Aluminium powder
(stabilized)
Acute LC50 120 ug/L Fresh water Fish - Rainbow trout,donaldson trout -
Oncorhynchus mykiss
96 hours
Product/ingredient
name
SpeciesResult Exposure
Page: 10/15United States - Canada - Mexico
HS Polyurethane Single StageProduct name
4Product code Date of issue VersionESSS-2 3 August 2012
Ecological information12 .
_________________________________________________________________________________________________
barium sulfate Acute EC50 32000 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours
_________________________________________________________________________________________________
propan-2-ol Acute LC50 >1400000 ug/L Fish - Bluegill - Lepomis macrochirus 96 hours
_________________________________________________________________________________________________
1,2,4-trimethylbenzene Acute LC50 7720 to 8280 ug/L Fresh
water
Fish - Fathead minnow - Pimephales
promelas
96 hours
_________________________________________________________________________________________________
zinc sulphide Acute LC50 1826000 ug/L Fresh water Fish - Fathead minnow - Pimephales
promelas
96 hours
___________________________________________________________________________
Acute LC50 970 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours
_________________________________________________________________________________________________
xylene Acute LC50 3300 to 4093 ug/L Fresh
water
Fish - Rainbow trout,donaldson trout -
Oncorhynchus mykiss
96 hours
_________________________________________________________________________________________________
antimony trioxide Acute LC50 >80000 ug/L Fresh water Fish - Fathead minnow - Pimephales
promelas
96 hours
___________________________________________________________________________
Acute EC50 423450 to 496000 ug/L
Fresh water
Daphnia - Water flea - Daphnia magna 48 hours
_________________________________________________________________________________________________
ethylbenzene Acute LC50 4200 ug/L Fresh water Fish - Rainbow trout,donaldson trout -
Oncorhynchus mykiss
96 hours
___________________________________________________________________________
Acute LC50 5100 to 5700 ug/L Marine
water
Fish - Atlantic silverside - Menidia
menidia
96 hours
___________________________________________________________________________
Acute EC50 2930 to 4400 ug/L Fresh
water
Daphnia - Water flea - Daphnia magna 48 hours
___________________________________________________________________________
Chronic NOEC 3300 ug/L Marine water Fish - Atlantic silverside - Menidia
menidia
96 hours
___________________________________________________________________________
Chronic NOEC 6800 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours
_________________________________________________________________________________________________
sodium fluoride Acute LC50 51000 to 68000 ug/L
Fresh water
Fish - Rainbow trout,donaldson trout -
Oncorhynchus mykiss
96 hours
___________________________________________________________________________
Acute EC50 98000 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours
___________________________________________________________________________
Acute EC50 850000 ug/L Fresh water Algae - Green algae - Scenedesmus
subspicatus
72 hours
___________________________________________________________________________
Chronic NOEC 110000 ug/L Fresh
water
Daphnia - Water flea - Daphnia magna 48 hours
_________________________________________________________________________________________________
lead Acute LC50 0.44 ppm Fresh water Fish - common carp - Cyprinus carpio 96 hours
___________________________________________________________________________
Acute LC50 4400 to 5300 ug/L Fresh
water
Daphnia - Water flea - Daphnia magna 48 hours
_________________________________________________________________________________________________
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
Waste disposal
Disposal considerations
:
13 .
Page: 11/15United States - Canada - Mexico
HS Polyurethane Single StageProduct name
4Product code Date of issue VersionESSS-2 3 August 2012
Disposal considerations13 .
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
Transport information14 .
Regulation UN number Proper shipping name Classes PG*
UN 1263 PAINT 3 II
Additional information
-
IMDG 1263 PAINT. Marine pollutant (Lead
chromate molybdate sulfate red,
Lead sulfochromate yellow)
3 -II
DOT Reportable quantity
8.0226 lbs / 3.6422 kg [0.
1097 gal / 0.41526 L]
Package sizes shipped in
quantities less than the
product reportable quantity
are not subject to the RQ
(reportable quantity)
transportation requirements.
1263 3PAINT II
CERCLA: Hazardous substances.: sodium fluoride: 1000 lbs. (454 kg); [N,N,N',N',N'',N''-
hexaethyl-29H,31H-phthalocyaninetrimethylaminato(2-)-N29,N30,N31,N32]copper;
ethylbenzene: 1000 lbs. (454 kg); butanone: 5000 lbs. (2270 kg); 2-butoxyethanol; antimony
trioxide: 1000 lbs. (454 kg); Zinc Phosphate Compound; chromium (III) oxide: 1 lb. (0.454 kg);
xylene: 100 lbs. (45.4 kg); zinc sulphide; [trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,
N32]copper; 29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32 copper; Copper, [29H,31H-
phthalocyaninato(2-)-N29,N30,N31,N32]-, brominated chlorinated; polychloro copper
phthalocyanine; Lead chromate molybdate sulfate red: 1 lb. (0.454 kg); Lead sulfochromate
yellow: 1 lb. (0.454 kg); n-butyl acetate: 5000 lbs. (2270 kg); acetone: 5000 lbs. (2270 kg);
Reportable quantity RQ :
PG* : Packing group
15 .Regulatory information
At least one component is not listed.
At least one component is not listed. Unlisted component(s) have been notified and
volumes are being tracked.
At least one component is not listed.
Not determined.
Not determined.
At least one component is not listed.
At least one component is not listed.
All components are listed or exempted.United States inventory (TSCA 8b):
Australia inventory (AICS)
Canada inventory ( DSL ):
China inventory (IECSC):
Japan inventory (ENCS):
Korea inventory (KECI):
New Zealand ( NZIoC ):
Philippines inventory (PICCS):
:
Europe inventory ( REACH ):Please contact your supplier for information on the inventory status of this material.
United States
United States - TSCA 12(b) - Chemical export notification:
Lead sulfochromate yellow Annual notification
Lead chromate molybdate sulfate red One time notification
United States - TSCA 5(a)2 - Final significant new use rules:
Page: 12/15United States - Canada - Mexico
HS Polyurethane Single StageProduct name
4Product code Date of issue VersionESSS-2 3 August 2012
15 .Regulatory information
CERCLA: Hazardous substances.: sodium fluoride: 1000 lbs. (454 kg); [N,N,N',N',N'',N''-hexaethyl-29H,31H-
phthalocyaninetrimethylaminato(2-)-N29,N30,N31,N32]copper; ethylbenzene: 1000 lbs. (454 kg); butanone: 5000 lbs.
(2270 kg); 2-butoxyethanol; antimony trioxide: 1000 lbs. (454 kg); Zinc Phosphate Compound; chromium (III) oxide: 1 lb.
(0.454 kg); xylene: 100 lbs. (45.4 kg); zinc sulphide; [trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper;
29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32 copper; Copper, [29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-,
brominated chlorinated; polychloro copper phthalocyanine; Lead chromate molybdate sulfate red: 1 lb. (0.454 kg); Lead
sulfochromate yellow: 1 lb. (0.454 kg); n-butyl acetate: 5000 lbs. (2270 kg); acetone: 5000 lbs. (2270 kg);
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: chromium (III) oxide; Carbon black; xylene; 1,2,4-trimethylbenzene;
Stoddard solvent; aluminium hydroxide; propan-2-ol; barium sulfate; Talc , not containing asbestiform fibres; Mica-group
minerals; Aluminium powder (stabilized); 2-methoxy-1-methylethyl acetate; diiron trioxide; heptan-2-one; n-butyl acetate;
acetone; titanium dioxide
SARA 311/312 MSDS Distribution - Chemical Inventory - Hazard Identification:
titanium dioxide 13463-67-7 N Y N N N
acetone 67-64-1 Y N Y N N
n-butyl acetate 123-86-4 Y N Y N N
PARACHLOROBENZOTRIFLUORIDE 98-56-6 Y N Y N N
heptan-2-one 110-43-0 Y N Y N N
diiron trioxide 1309-37-1 N N N N N
Lead sulfochromate yellow 1344-37-2 Y Y N N N
silicon dioxide 7631-86-9 N N N N N
2-methoxy-1-methylethyl acetate 108-65-6 Y N Y N N
Lead chromate molybdate sulfate
red
12656-85-8 Y Y N N N
Aluminium powder (stabilized)7429-90-5 N N N Y N
Mica-group minerals 12001-26-2 N N N N N
Talc , not containing asbestiform
fibres
14807-96-6 Y N N N N
Solvent naphtha (petroleum), light
arom.
64742-95-6 Y N Y N N
Solvent naphtha (petroleum), light
aliph.
64742-89-8 Y N Y N N
barium sulfate 7727-43-7 N N N N N
Naphtha (petroleum), hydrotreated
heavy
64742-48-9 Y N Y N N
Cashew, nutshell liq.,
2-hydroxyethyl ethers
232268-65-4 Y N N N N
ethyl 3-ethoxypropionate 763-69-9 Y N Y Y N
propan-2-ol 67-63-0 Y N Y N N
aluminium hydroxide 21645-51-2 N N N N N
Stoddard solvent 8052-41-3 Y N Y N N
1,2,4-trimethylbenzene 95-63-6 Y N Y N N
Decanedioic acid, 1,10-bis(2,2,6,
6-tetramethyl-4-piperidinyl) ester,
reaction products with tert-Bu
hydroperoxide and octane
129757-67-1 N N N N N
zinc sulphide 1314-98-3 Y N N N N
xylene 1330-20-7 Y N Y N N
Carbon black 1333-86-4 N Y N N N
chromium (III) oxide 1308-38-9 N N N N N
2-(2H-benzotriazol-2-yl)-4,
6-ditertpentylphenol
25973-55-1 N N N N N
Naphtha (petroleum), heavy alkylate 64741-65-7 Y N Y N N
Chemical name CAS #Acute Chronic Fire Reactive Pressure
Lead chromate molybdate sulfate red Listed
United States - TSCA 5(a)2 - Proposed significant new use rules:
Lead chromate molybdate sulfate red Listed
Page: 13/15United States - Canada - Mexico
HS Polyurethane Single StageProduct name
4Product code Date of issue VersionESSS-2 3 August 2012
15 .Regulatory information
SARA 313 CAS number Concentration
Additional environmental information is contained on the Environmental Data Sheet for this product, which can
be obtained from your PPG representative.
Supplier notification bismuth vanadium tetraoxide 14059-33-7 10 - 30
Lead sulfochromate yellow 1344-37-2 7 - 13
Lead chromate molybdate sulfate red 12656-85-8 7 - 13
Aluminium powder (stabilized)7429-90-5 5 - 10
polychloro copper phthalocyanine 1328-53-6 1 - 5
Copper, [29H,31H-phthalocyaninato(2-)-N29,N30,
N31,N32]-, brominated chlorinated
68512-13-0 1 - 5
[trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,
N31,N32]copper
29719-96-8 1 - 5
propan-2-ol 67-63-0 1 - 5
1,2,4-trimethylbenzene 95-63-6 1 - 5
zinc sulphide 1314-98-3 1 - 5
xylene 1330-20-7 0.5 - 1.5
chromium (III) oxide 1308-38-9 0.5 - 1.5
antimony trioxide 1309-64-4 0.1 - 1
ethylbenzene 100-41-4 0.1 - 1
antimony trioxide 1309-64-4 Y Y N N N
ethylbenzene 100-41-4 Y Y Y N N
sodium fluoride 7681-49-4 Y Y N N N
Product as-supplied :Y Y Y Y N
Chemical name
California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other
reproductive harm.
WHMIS (Canada)Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-1B:
Material causing immediate and serious toxic effects (Toxic). Class D-2A: Material
causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects
(Toxic).
:
Canada
Mexico
3 3 1HealthFlammabilityReactivity
Classification
:::
Other information
Hazardous Material Information System (U.S.A.)
3
13
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Date of previous issue 7/7/2012.:
16 .
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller [phone].
The customer is responsible for determining the PPE code for this material.
Indicates information that has changed from previously issued version.
Organization that prepared
the MSDS
:EHS
:::
:::3 *
3
1
( * ) - Chronic
effects
Page: 14/15United States - Canada - Mexico
HS Polyurethane Single StageProduct name
4Product code Date of issue VersionESSS-2 3 August 2012
Other information16 .
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Page: 15/15United States - Canada - Mexico
FACTORY PACKAGE - BLACKProduct name
Product and company identification
:
1 .
ESSS9000SF
PPG Industries, Inc.
One PPG Place,
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
01-800-00-21-400 (Mexico)
Supplier
Code
Emergency telephone
number
:
:
:
Technical Phone Number :1-800-647-6050
Material Safety Data Sheet
Date of issue 15 March 2014
Version 8
Emergency overview
Hazards identification
Potential acute health effects
May be harmful if swallowed.
Eyes
Skin
Inhalation
Ingestion
See toxicological information (Section 11)
WARNING!:
:
:
:
:
Medical conditions
aggravated by over-
exposure
Pre-existing disorders involving any target organs mentioned in this MSDS as being at
risk may be aggravated by over-exposure to this product.
:
2 .
Over-exposure signs/symptoms
Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and
nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes
headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated
exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than
expected from exposure to noise alone.
Keep away from flames, such as a pilot light, and any object that sparks, such as an
electric motor. Keep away from heat. Do not smoke. Do not swallow. Avoid
breathing vapor or mist. Avoid contact with eyes, skin and clothing. Use only with
adequate ventilation. Keep container tightly closed and sealed until ready for use.
Wash thoroughly after handling.
FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT AND EYE
IRRITATION. MAY BE HARMFUL IF INHALED OR SWALLOWED. PROLONGED OR
REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS
MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.
May be harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose,
mouth and throat. Exposure to decomposition products may cause a health hazard.
Serious effects may be delayed following exposure.
Irritating to eyes.
Moderately irritating to the skin.
This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials
Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).
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Composition/information on ingredients3 .
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
acetone 67-64-1 10 - 30
n-butyl acetate 123-86-4 7 - 13
heptan-2-one 110-43-0 5 - 10
2-methoxy-1-methylethyl acetate 108-65-6 1 - 5
carbon black respirable 1333-86-4 0.5 - 1.5
2-(2H-benzotriazol-2-yl)-4,6-ditertpentylphenol 25973-55-1 0.5 - 1.5
xylene 1330-20-7 0.1 - 1
1,2,4-trimethylbenzene 95-63-6 0.1 - 1
Name CAS number %
First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
Notes to physician
:
:
:
:
:
4 .
Check for and remove any contact lenses. Immediately flush eyes with running
water for at least 15 minutes, keeping eyelids open. Seek immediate medical
attention.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognized skin cleanser. Do NOT use solvents or thinners.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
If swallowed, seek medical advice immediately and show this container or label.
Keep person warm and at rest. Do NOT induce vomiting.
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this
product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Use dry chemical, CO₂, water spray (fog) or foam.
Fire-fighting measures
Extinguishing media
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Flammable liquid. In a fire or if heated, a pressure increase will occur and the
container may burst, with the risk of a subsequent explosion. Vapors may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back. Runoff to sewer may create fire or explosion hazard.
Special protective
equipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
5 .
Special exposure hazards :
Do not use water jet.
Suitable :
Not suitable :
Hazardous combustion
products
:Decomposition products may include the following materials:
carbon oxides
nitrogen oxides
Flammability of the product :
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No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment (see Section 8).
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an effluent
treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent material
may pose the same hazard as the spilled product. Note: see Section 1 for emergency
contact information and Section 13 for waste disposal.
Environmental precautions
Accidental release measures
:Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Personal precautions :
Large spill :
6 .
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb
with an inert dry material and place in an appropriate waste disposal container.
Dispose of via a licensed waste disposal contractor.
Small spill :
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-
ventilated area, away from incompatible materials (see Section 10) and food and drink.
Eliminate all ignition sources. Separate from oxidizing materials. Keep container
tightly closed and sealed until ready for use. Containers that have been opened must
be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled
containers. Use appropriate containment to avoid environmental contamination. Do
not store above the following temperature: 120F / 49C.
Put on appropriate personal protective equipment (see Section 8). Eating, drinking
and smoking should be prohibited in areas where this material is handled, stored and
processed. Do not swallow. Do not get in eyes or on skin or clothing. Avoid breathing
vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use non-sparking
tools. Take precautionary measures against electrostatic discharges. Vapors are
heavier than air and may spread along floors. To avoid fire or explosion, dissipate
static electricity during transfer by grounding and bonding containers and equipment
before transferring material. Empty containers retain product residue and can be
hazardous. Do not reuse container. If this material is part of a multiple component
system, read the Material Safety Data Sheet(s) for the other component or
components before blending as the resulting mixture may have the hazards of all of its
parts.
Handling and storage
Handling
Storage
:
:
7 .
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Exposure controls/personal protection8 .
Acceptable Maximum PeakA=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
TD =Total dust
Key to abbreviations
Consult local authorities for acceptable exposure limits.
Engineering measures :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation
or other engineering controls to keep worker exposure to airborne contaminants below
any recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Recommended monitoring
procedures
:If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
acetone TWA 500 ppm 1000 ppm 500 ppm 1000 ppm Not
established
STEL 750 ppm Not
established
750 ppm 1260 ppm Not
established
______________________________________________________________________________________________
n-butyl acetate TWA 150 ppm 150 ppm 150 ppm 150 ppm Not
established
STEL 200 ppm Not
established
200 ppm 200 ppm Not
established
______________________________________________________________________________________________
heptan-2-one TWA 50 ppm 100 ppm 25 ppm 50 ppm Not
established
STEL Not
established
Not
established
Not
established
100 ppm Not
established
______________________________________________________________________________________________
2-methoxy-1-methylethyl acetate TWA Not
established
Not
established
50 ppm Not
established
50 ppm
______________________________________________________________________________________________
carbon black respirable TWA 3 mg/m³3.5 mg/m³3 mg/m³3.5 mg/m³Not
established
STEL Not
established
Not
established
Not
established
7 mg/m³Not
established
______________________________________________________________________________________________
xylene TWA 100 ppm 100 ppm 100 ppm 100 ppm Not
established
STEL 150 ppm Not
established
150 ppm 150 ppm Not
established
______________________________________________________________________________________________
1,2,4-trimethylbenzene TWA 25 ppm Not
established
25 ppm 25 ppm Not
established
STEL Not
established
Not
established
Not
established
35 ppm Not
established
______________________________________________________________________________________________
Name Result ACGIH OSHA Ontario Mexico PPG
STEL =
=
Short term Exposure limit values
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Exposure controls/personal protection8 .
If workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator
complying with an approved standard if a risk assessment indicates this is necessary.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator.
Safety glasses with side shields.
Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist before
handling this product.
When there is a risk of ignition from static electricity, wear anti-static protective clothing.
For the greatest protection from static discharges, clothing should include anti-static
overalls, boots and gloves.
Personal protection
Eyes
Skin
Respiratory
:
:
:
Hygiene measures :Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Hands :Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
>37.78°C (>100°F)
Liquid.
52% (v/v), 44.68% (w/w)
Not available.
Not available.
0.97
Not available.
18.2 kPa (136.7 mm Hg) [room temperature]
Not available.
Not available.
Boiling/condensation point
Melting/freezing point
5.1 (butyl acetate = 1)
Physical and chemical properties
Physical state
pH
Specific gravity
Vapor pressure
Vapor density
Volatility
Evaporation rate
Odor
Color
:
:
:
:
:
:
:
:
:
:
:
Flash point :Closed cup: -10°C (14°F)
Explosion limits :Lower: 2.1%
9 .
Partition coefficient: n-
octanol/water
:Not available.
% Solid. (w/w):55.32
Density ( lbs / gal ):8.1
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Stable under recommended storage and handling conditions (see Section 7).
Reactive or incompatible with the following materials:,oxidizing materials,strong acids,
strong alkalis
Under normal conditions of storage and use, hazardous polymerization will not occur.
Under normal conditions of storage and use, hazardous decomposition products
should not be produced.
Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Stability and reactivity
Stability
Conditions to avoid
Materials to avoid
Hazardous decomposition
products
Hazardous polymerization
:
:
:
:
:
10 .
11 .Toxicological information
Conclusion/Summary :Not available.
Chronic toxicity
Conclusion/Summary :Not available.
Carcinogenicity
Classification
Carcinogenicity :Contains material which may cause cancer, based on animal data. Risk of cancer
depends on duration and level of exposure.
Defatting irritant :Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or
dermatitis.
Target organs :Contains material which causes damage to the following organs: brain.
Contains material which may cause damage to the following organs: blood, kidneys,
lungs, peripheral nervous system, upper respiratory tract, skin, central nervous system
(CNS), eye, lens or cornea.
acetone LD50 Oral Rat 1.8 g/kg -
LD50 Dermal Rabbit 20 g/kg -
LC50 Inhalation
Vapor
Rat 76000 mg/m3 4 hours
n-butyl acetate LD50 Oral Rat 10.768 g/kg -
LD50 Dermal Rabbit >17600 mg/kg -
LC50 Inhalation Rat >21.1 mg/l 4 hours
heptan-2-one LD50 Oral Rat 1.6 g/kg -
LD50 Dermal Rabbit 10.206 g/kg -
2-methoxy-1-methylethyl acetate LD50 Oral Rat 8532 mg/kg -
LD50 Dermal Rabbit >5 g/kg -
carbon black respirable LD50 Oral Rat >15400 mg/kg -
LD50 Dermal Rabbit >3 g/kg -
2-(2H-benzotriazol-2-yl)-4,
6-ditertpentylphenol
LD50 Oral Rat >2000 mg/kg -
LD50 Dermal Rabbit >2000 mg/kg -
xylene LD50 Oral Rat 4.3 g/kg -
LD50 Dermal Rabbit >1.7 g/kg -
LC50 Inhalation
Vapor
Rat 5000 ppm 4 hours
1,2,4-trimethylbenzene LD50 Oral Rat 5 g/kg -
LC50 Inhalation Rat 18000 mg/m3 4 hours
Product/ingredient name Result Species Dose Exposure
Acute toxicity
Product/ingredient name
acetone A4 ---
carbon black respirable A3 ---
ACGIH NTP OSHAIARC
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11 .Toxicological information
Carcinogen Classification code:ACGIH: A1, A2, A3, A4, A5
IARC: 1, 2A, 2B, 3, 4
NTP: Proven, Possible
OSHA: +
Not listed or regulated as a carcinogen: -
Ecological information
Environmental effects :No known significant effects or critical hazards.
12 .
Aquatic ecotoxicity
acetone Acute LC50 >100000 ug/L Fresh water Fish - Fathead minnow - Pimephales
promelas
96 hours
___________________________________________________________________________
Acute LC50 6900 mg/L Fresh water Daphnia - Water flea - Daphnia
magna
48 hours
___________________________________________________________________________
Acute EC50 7200000 ug/L Fresh water Algae - Green algae - Selenastrum
sp.
96 hours
_________________________________________________________________________________________________
n-butyl acetate Acute LC50 18000 to 19000 ug/L
Fresh water
Fish - Fathead minnow - Pimephales
promelas
96 hours
_________________________________________________________________________________________________
heptan-2-one Acute LC50 131000 to 137000 ug/L
Fresh water
Fish - Fathead minnow - Pimephales
promelas
96 hours
_________________________________________________________________________________________________
xylene Acute LC50 3300 to 4093 ug/L Fresh
water
Fish - Rainbow trout,donaldson trout -
Oncorhynchus mykiss
96 hours
_________________________________________________________________________________________________
1,2,4-trimethylbenzene Acute LC50 7720 to 8280 ug/L Fresh
water
Fish - Fathead minnow - Pimephales
promelas
96 hours
_________________________________________________________________________________________________
Product/ingredient
name
SpeciesResult Exposure
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated
to the sewer unless fully compliant with the requirements of all authorities with
jurisdiction. Waste packaging should be recycled. Incineration or landfill should only
be considered when recycling is not feasible. This material and its container must be
disposed of in a safe way. Care should be taken when handling emptied containers
that have not been cleaned or rinsed out. Empty containers or liners may retain some
product residues. Vapor from product residues may create a highly flammable or
explosive atmosphere inside the container. Do not cut, weld or grind used containers
unless they have been cleaned thoroughly internally. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers.
Waste disposal
Disposal considerations
Disposal should be in accordance with applicable regional, national and local laws and regulations.
:
13 .
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
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14. Transport information
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
Package sizes shipped in quantities less than the product reportable quantity are not subject to the
RQ (reportable quantity) transportation requirements.
None identified.
None identified.
DOT
TDG
Mexico
:
:
:
PAINT
3
II
PAINT
3
II
UN1263 UN1263
DOT Mexico
UN number
UN proper shipping
name
Transport hazard
class(es)
Packing group
Environmental
hazards
No.No.
TDG
UN1263
PAINT
3
II
No.
Marine pollutant
substances
IMDG :None identified.
IMDG
UN1263
PAINT
3
II
No.
Not applicable.
22571.2
RQ substances (xylene, acetone)Not applicable.
Not applicable.Not applicable.
Not applicable.
Not applicable.
Not applicable.
Not applicable.Not applicable.
Product RQ (lbs)
Not applicable.
15 .Regulatory information
At least one component is not listed.
All components are listed or exempted.
All components are listed or exempted.
At least one component is not listed.
At least one component is not listed.
At least one component is not listed.
At least one component is not listed.
All components are listed or exempted.United States inventory (TSCA 8b):
Australia inventory (AICS)
Canada inventory ( DSL ):
China inventory (IECSC):
Japan inventory (ENCS):
Korea inventory (KECI):
New Zealand ( NZIoC ):
Philippines inventory (PICCS):
:
Europe inventory ( REACH ):Please contact your supplier for information on the inventory status of this
material.
United States
CERCLA: Hazardous substances.: xylene: 100 lbs. (45.4 kg); n-butyl acetate: 5000 lbs. (2270 kg); acetone: 5000 lbs.
(2270 kg);
SARA 302/304: No products were found.
SARA 311/312 SDS Distribution - Chemical Inventory - Hazard Identification:
Chemical name CAS #Acute Chronic Fire Reactive Pressure
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15 .Regulatory information
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
acetone 67-64-1 Y N Y N N
n-butyl acetate 123-86-4 Y N Y N N
heptan-2-one 110-43-0 Y N Y N N
2-methoxy-1-methylethyl acetate 108-65-6 Y N Y N N
carbon black respirable 1333-86-4 N Y N N N
2-(2H-benzotriazol-2-yl)-4,
6-ditertpentylphenol
25973-55-1 N N N N N
Product as-supplied :Y Y Y N N
California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer.
WHMIS (Canada)Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-2A:
Material causing other toxic effects (Very toxic). Class D-2B: Material causing other
toxic effects (Toxic).
:
Canada
Mexico
3 2 0HealthFlammabilityReactivity
Classification
:::
Other information
Hazardous Material Information System (U.S.A.)
3
03
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary
measures described in this data sheet or for any misuse of the products.
Date of previous issue 11/24/2013.:
16 .
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller [phone].
The customer is responsible for determining the PPE code for this material.
Indicates information that has changed from previously issued version.
Organization that prepared
the MSDS
:EHS
:::
:::2 *
2
0
( * ) - Chronic
effects
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STANDARD ACTIVATOR
Not available.
Liquid.
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Section 1. Identification
:
:
:
Product code :ESX510
Date of issue/Date of revision 13 June 2021
Version 16
Relevant identified uses of the substance or mixture and uses advised against
Coating. Paints. Painting-related materials.
Uses advised against Not applicable.
Product use :Industrial applications.
Use of the substance/
mixture
:
:
Manufacturer PPG Industries, Inc.
One PPG Place,
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
SETIQ Interior de la República: 800-00-214-00 (México)
SETIQ Ciudad de México: (55) 5559-1588 (México)
Emergency telephone
number
:
:
Technical Phone Number :1-800-647-6050
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (dermal) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Classification of the
substance or mixture
:
Hazard pictograms :
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
United States Page: 1/15
STANDARD ACTIVATORProduct name
16Product code Date of issue VersionESX51013 June 2021
Section 2. Hazards identification
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Harmful in contact with skin.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
May cause respiratory irritation.
Suspected of causing cancer.
May damage fertility or the unborn child.
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or
in a well-ventilated area. Avoid breathing vapor. Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF ON SKIN:
Call a POISON CENTER or doctor if you feel unwell. Wash with plenty of water. If skin
irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice or attention.
Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep
cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label
elements
:Repeated exposure to high vapor concentrations may cause irritation of the respiratory
system and permanent brain and nervous system damage. Inhalation of vapor/aerosol
concentrations above the recommended exposure limits causes headaches,
drowsiness and nausea and may lead to unconsciousness or death. Avoid contact with
skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated.
Hazards not otherwise
classified
:Prolonged or repeated contact may dry skin and cause irritation.
Section 3. Composition/information on ingredients
4-chloro-α,α,α-trifluorotoluene ≥50 - ≤75 98-56-6
pentane-2,4-dione ≥20 - ≤25 123-54-6
acetone ≥10 - <20 67-64-1
dibutyltin dilaurate <1.0 77-58-7
Ingredient name CAS number%
Substance/mixture :Mixture
Product name STANDARD ACTIVATOR:
SUB codes represent substances without registered CAS Numbers.
United States Page: 2/15
STANDARD ACTIVATORProduct name
16Product code Date of issue VersionESX51013 June 2021
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :
:Ingestion
Skin contact :
:Eye contact
Over-exposure signs/symptoms
Skin contact
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
dryness
cracking
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids
apart for at least 10 minutes and seek immediate medical advice.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
Causes serious eye irritation.
May cause respiratory irritation.
No known significant effects or critical hazards.
Harmful in contact with skin. Causes skin irritation. Defatting to the skin. May cause
an allergic skin reaction.
United States Page: 3/15
STANDARD ACTIVATORProduct name
16Product code Date of issue VersionESX51013 June 2021
Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments :No specific treatment.
Ingestion Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon oxides
halogenated compounds
carbonyl halides
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Runoff to sewer may
create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For non-emergency
personnel
United States Page: 4/15
STANDARD ACTIVATORProduct name
16Product code Date of issue VersionESX51013 June 2021
Section 6. Accidental release measures
Environmental precautions
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid
breathing vapor or mist. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Store
and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Special precautions :If this material is part of a multiple component system, read the Safety Data Sheet(s) for
the other component or components before blending as the resulting mixture may have
the hazards of all of its parts.
United States Page: 5/15
STANDARD ACTIVATORProduct name
16Product code Date of issue VersionESX51013 June 2021
Section 7. Handling and storage
Conditions for safe storage,
including any
incompatibilities
Do not store below the following temperature: 5°C (41°F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
4-chloro-α,α,α-trifluorotoluene IPEL (-).
TWA: 0.57 ppm
STEL: 1.71 ppm
pentane-2,4-dione ACGIH TLV (United States, 3/2020).
Absorbed through skin.
TWA: 25 ppm 8 hours.
acetone ACGIH TLV (United States, 3/2020).
STEL: 500 ppm 15 minutes.
TWA: 250 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 2400 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.
dibutyltin dilaurate ACGIH TLV (United States, 3/2020).
Absorbed through skin.
STEL: 0.2 mg/m³, (as Sn) 15 minutes.
TWA: 0.1 mg/m³, (as Sn) 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 0.1 mg/m³, (as Sn) 8 hours.
OSHA PEL (United States).
TWA: 0.1 mg/m³, (as Sn)
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
Recommended monitoring
procedures
:If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Key to abbreviations
A Acceptable Maximum Peak=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
TD =Total dust
Consult local authorities for acceptable exposure limits.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
STEL =
=
Short term Exposure limit values
United States Page: 6/15
STANDARD ACTIVATORProduct name
16Product code Date of issue VersionESX51013 June 2021
Section 8. Exposure controls/personal protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :
Chemical splash goggles.
Gloves For prolonged or repeated handling, use the following type of gloves:
Recommended: butyl rubber
:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.
The respiratory protection shall be in accordance to 29 CFR 1910.134.
United States Page: 7/15
STANDARD ACTIVATORProduct name
16Product code Date of issue VersionESX51013 June 2021
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.14
Not available.
Not available.
Insoluble in the following materials: cold water.
Not available.Odor
pH
Clear.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31.11°C (88°F)
Not applicable.
Not applicable.
Viscosity Kinematic (40°C (104°F)): >21 mm2/s (>21 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :>37.78°C (>100°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
% Solid. (w/w):0.299
Density ( lbs / gal ):9.51
Volatility :100% (v/v), 99.701% (w/w)
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
The product is stable.Chemical stability :
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
When exposed to high temperatures may produce hazardous decomposition products.
Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
Refer to protective measures listed in sections 7 and 8.
Depending on conditions, decomposition products may include the following materials:
carbon oxides halogenated compounds carbonyl halides
United States Page: 8/15
STANDARD ACTIVATORProduct name
16Product code Date of issue VersionESX51013 June 2021
Section 11. Toxicological information
Acute toxicity
4-chloro-α,α,α-trifluorotoluene LC50 Inhalation Vapor Rat 33080 mg/m³4 hours
LD50 Dermal Rabbit >2.7 g/kg -
LD50 Oral Rat 13 g/kg -
pentane-2,4-dione LC50 Inhalation Vapor Rat 5.1 mg/l 4 hours
LD50 Dermal Rat 790 mg/kg -
LD50 Oral Rat 570 mg/kg -
acetone LC50 Inhalation Vapor Rat 76000 mg/m³4 hours
LD50 Dermal Rabbit 15.8 g/kg -
LD50 Oral Rat 5800 mg/kg -
dibutyltin dilaurate LD50 Oral Rat 2071 mg/kg -
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary :
Carcinogenicity
Conclusion/Summary :
Mutagenicity
Conclusion/Summary :
Teratogenicity
Conclusion/Summary :
Reproductive toxicity
Conclusion/Summary :
Irritation/Corrosion
Conclusion/Summary
Skin :
Eyes :
Respiratory :
Sensitization
Conclusion/Summary
Skin :
Respiratory :
Specific target organ toxicity (single exposure)
Information on toxicological effects
Classification
4-chloro-α,α,α-trifluorotoluene -2B -
Product/ingredient name NTPIARCOSHA
Carcinogen Classification code:
IARC: 1, 2A, 2B, 3, 4
NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen
OSHA: +
Not listed/not regulated: -
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
United States Page: 9/15
STANDARD ACTIVATORProduct name
16Product code Date of issue VersionESX51013 June 2021
Section 11. Toxicological information
Information on the likely routes of exposure
Specific target organ toxicity (repeated exposure)
Aspiration hazard
Not available.
Potential acute health effects
Inhalation :May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Harmful in contact with skin. Causes skin irritation. Defatting to the skin. May cause
an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
dryness
cracking
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Target organs :Contains material which causes damage to the following organs: mucous membranes,
brain, , central nervous system (CNS).
Contains material which may cause damage to the following organs: the nervous
system, liver, gastrointestinal tract, upper respiratory tract, skin, adrenal, eye, lens or
cornea.
Name
4-chloro-α,α,α-trifluorotoluene Category 3 -Respiratory tract
irritation
acetone Category 3 -Narcotic effects
dibutyltin dilaurate Category 1 -thymus
Category Route of
exposure
Target organs
Name Category
dibutyltin dilaurate Category 1 oral immune system
Route of
exposure
Target organs
United States Page: 10/15
STANDARD ACTIVATORProduct name
16Product code Date of issue VersionESX51013 June 2021
Section 11. Toxicological information
Conclusion/Summary :
General :
Carcinogenicity :
Mutagenicity :
Reproductive toxicity :
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Acute toxicity estimates
Potential immediate
effects
:
Short term exposure
Potential delayed effects :
Potential immediate
effects
:
Long term exposure
Potential delayed effects :
Ingestion Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
There are no data available on the mixture itself. Exposure to component solvent vapor
concentrations in excess of the stated occupational exposure limit may result in adverse
health effects such as mucous membrane and respiratory system irritation and adverse
effects on the kidneys, liver and central nervous system. Symptoms and signs include
headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases,
loss of consciousness. Solvents may cause some of the above effects by absorption
through the skin. There is some evidence that repeated exposure to organic solvent
vapors in combination with constant loud noise can cause greater hearing loss than
expected from exposure to noise alone. If splashed in the eyes, the liquid may cause
irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic
effects of components from short-term and long-term exposure by oral, inhalation and
dermal routes of exposure and eye contact.
Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or
dermatitis. Once sensitized, a severe allergic reaction may occur when subsequently
exposed to very low levels.
May damage fertility or the unborn child.
No known significant effects or critical hazards.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Product/ingredient name
STANDARD ACTIVATOR 2606.3 1872.6 N/A 23.3 N/A
4-chloro-α,α,α-trifluorotoluene 13000 2500 N/A 33.08 N/A
pentane-2,4-dione 570 790 N/A 5.1 N/A
acetone 5800 15800 N/A 76 N/A
dibutyltin dilaurate 2071 N/A N/A N/A N/A
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm)
Inhalation
(vapors)
(mg/l)
Inhalation
(dusts and
mists) (mg/
l)
United States Page: 11/15
STANDARD ACTIVATORProduct name
16Product code Date of issue VersionESX51013 June 2021
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
pentane-2,4-dione 0.68 -low
acetone -0.23 3 low
dibutyltin dilaurate 4.44 -high
Product/ingredient name Aquatic half-life Photolysis Biodegradability
acetone --Readily
Toxicity
acetone Acute LC50 4.42589 ml/L Marine water Crustaceans - Acartia tonsa -
Copepodid
48 hours
Acute LC50 5540 mg/l Fish 96 hours
dibutyltin dilaurate EC50 0.463 mg/l Daphnia 48 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
acetone -90.9 % - Readily - 28 days --
Product/ingredient name Test DoseResult Inoculum
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
United States Page: 12/15
STANDARD ACTIVATORProduct name
16Product code Date of issue VersionESX51013 June 2021
14. Transport information
PAINT RELATED MATERIAL
3
III
PAINT RELATED MATERIAL
3
III
PAINT RELATED MATERIAL
UN1263
3
III
UN1263 UN1263
DOT IMDG IATA
UN number
UN proper shipping
name
Transport hazard class
(es)
Packing group
Environmental hazards No.No.No.
Marine pollutant
substances
Not applicable.Not applicable.
RQ substances
39136.5
(acetone)
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
Package sizes shipped in quantities less than the product reportable quantity are not subject to the
RQ (reportable quantity) transportation requirements.
None identified.
DOT
IMDG
:
:
IATA :None identified.
Product RQ (lbs)
Transport in bulk according
to IMO instruments
:Not applicable.
Section 15. Regulatory information
SARA 302/304
SARA 304 RQ :Not applicable.
Composition/information on ingredients
All components are active or exempted.United States inventory (TSCA 8b):
United States
U.S. Federal regulations :
United States - TSCA 12(b) - Chemical export notification:
pentane-2,4-dione One time notification
United States - TSCA 5(a)2 - Final significant new use rules:
United States - TSCA 5(a)2 - Proposed significant new use rules:
No products were found.
4-chloro-α,α,α-trifluorotoluene Listed 40 CFR 799.5089
pentane-2,4-dione Listed
SARA 311/312
United States Page: 13/15
STANDARD ACTIVATORProduct name
16Product code Date of issue VersionESX51013 June 2021
Section 15. Regulatory information
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
California Prop. 65
Classification :FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (dermal) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
HNOC - Defatting irritant
4-chloro-α,α,α-trifluorotoluene ≥50 - ≤75 FLAMMABLE LIQUIDS - Category 3
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
HNOC - Defatting irritant
pentane-2,4-dione ≥20 - ≤25 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (dermal) - Category 3
ACUTE TOXICITY (inhalation) - Category 3
acetone ≥10 - <20 FLAMMABLE LIQUIDS - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
HNOC - Defatting irritant
dibutyltin dilaurate <1.0 SKIN CORROSION - Category 1C
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
GERM CELL MUTAGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) -
Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 1
Name %Classification
Composition/information on ingredients
WARNING: Cancer - www.P65Warnings.ca.gov.
United States Page: 14/15
STANDARD ACTIVATORProduct name
16Product code Date of issue VersionESX51013 June 2021
Section 16. Other information
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Hazardous Material Information System (U.S.A.)
3
03
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Date of previous issue 7/22/2020:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Indicates information that has changed from previously issued version.
Organization that prepared
the SDS
:EHS
:::
:::2 *
2
0
( * ) - Chronic effects
United States Page: 15/15
GENERAL PURPOSE SOLVENT
Not available.
Liquid.
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Section 1. Identification
:
:
:
Product code :MS151
Date of issue/Date of revision 16 June 2021
Version 10
Relevant identified uses of the substance or mixture and uses advised against
Coating. Paints. Painting-related materials.
Uses advised against Not applicable.
Product use :Industrial applications.
Use of the substance/
mixture
:
:
Manufacturer PPG Industries, Inc.
One PPG Place,
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
SETIQ Interior de la República: 800-00-214-00 (México)
SETIQ Ciudad de México: (55) 5559-1588 (México)
Emergency telephone
number
:
:
Technical Phone Number :1-800-647-6050
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 3.1%
(oral), 3.1% (dermal)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
United States Page: 1/13
GENERAL PURPOSE SOLVENTProduct name
10Product code Date of issue VersionMS15116 June 2021
Section 2. Hazards identification
Hazard statements :Highly flammable liquid and vapor.
Causes serious eye irritation.
May cause drowsiness or dizziness.
Precautionary statements
Prevention :Wear protective gloves, protective clothing and eye or face protection. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use
explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools.
Take action to prevent static discharges. Use only outdoors or in a well-ventilated area.
Avoid breathing vapor. Wash thoroughly after handling.
Response :IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a
POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice or attention.
Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep
cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label
elements
:Repeated exposure to high vapor concentrations may cause irritation of the respiratory
system and permanent brain and nervous system damage. Inhalation of vapor/aerosol
concentrations above the recommended exposure limits causes headaches,
drowsiness and nausea and may lead to unconsciousness or death. Avoid contact with
skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated.
Hazards not otherwise
classified
:Prolonged or repeated contact may dry skin and cause irritation.
Section 3. Composition/information on ingredients
acetone ≥90 67-64-1
Ligroine ≥1.0 - ≤5.0 8032-32-4
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Product name GENERAL PURPOSE SOLVENT:
SUB codes represent substances without registered CAS Numbers.
United States Page: 2/13
GENERAL PURPOSE SOLVENTProduct name
10Product code Date of issue VersionMS15116 June 2021
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :
:Ingestion
Skin contact :
:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
No specific data.
Adverse symptoms may include the following:
irritation
dryness
cracking
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids
apart for at least 10 minutes and seek immediate medical advice.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
Causes serious eye irritation.
Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
Can cause central nervous system (CNS) depression.
Defatting to the skin. May cause skin dryness and irritation.
United States Page: 3/13
GENERAL PURPOSE SOLVENTProduct name
10Product code Date of issue VersionMS15116 June 2021
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon oxides
Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur
and the container may burst, with the risk of a subsequent explosion. Runoff to sewer
may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
United States Page: 4/13
GENERAL PURPOSE SOLVENTProduct name
10Product code Date of issue VersionMS15116 June 2021
Section 6. Accidental release measures
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store below the following temperature: 5°C (41°F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid
contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Special precautions :If this material is part of a multiple component system, read the Safety Data Sheet(s) for
the other component or components before blending as the resulting mixture may have
the hazards of all of its parts.
acetone ACGIH TLV (United States, 3/2020).
STEL: 500 ppm 15 minutes.
TWA: 250 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 2400 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.
Ligroine CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 1400 mg/m³ 8 hours.
8 hrs OEL: 300 ppm 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
Key to abbreviations
A Acceptable Maximum Peak=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
=
United States Page: 5/13
GENERAL PURPOSE SOLVENTProduct name
10Product code Date of issue VersionMS15116 June 2021
Section 8. Exposure controls/personal protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Eye/face protection
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :
Recommended monitoring
procedures
:If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Chemical splash goggles.
Gloves For prolonged or repeated handling, use the following type of gloves:
Recommended: butyl rubber
:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
TD =Total dust
Consult local authorities for acceptable exposure limits.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
STEL =Short term Exposure limit values
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GENERAL PURPOSE SOLVENTProduct name
10Product code Date of issue VersionMS15116 June 2021
Section 8. Exposure controls/personal protection
Respiratory protection :Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.
The respiratory protection shall be in accordance to 29 CFR 1910.134.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
0.79
Not available.
Not available.
Partially soluble in the following materials: cold water.
Not available.Odor
pH
Not available.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: -16.11°C (3°F)
Not applicable.
Not available.
Viscosity Kinematic (40°C (104°F)): <14 mm2/s (<14 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :>37.78°C (>100°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
% Solid. (w/w):0
Density ( lbs / gal ):6.59
Volatility :100% (v/v), 100% (w/w)
Section 10. Stability and reactivity
Conditions to avoid
The product is stable.Chemical stability :
:
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
When exposed to high temperatures may produce hazardous decomposition products.
United States Page: 7/13
GENERAL PURPOSE SOLVENTProduct name
10Product code Date of issue VersionMS15116 June 2021
Section 10. Stability and reactivity
Hazardous decomposition
products
:
Incompatible materials :Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
Refer to protective measures listed in sections 7 and 8.
Depending on conditions, decomposition products may include the following materials:
carbon oxides
Section 11. Toxicological information
Acute toxicity
acetone LC50 Inhalation Vapor Rat 76000 mg/m³4 hours
LD50 Dermal Rabbit 15.8 g/kg -
LD50 Oral Rat 5800 mg/kg -
Ligroine LC50 Inhalation Gas.Rat 3400 ppm 4 hours
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary :
Carcinogenicity
Conclusion/Summary :
Mutagenicity
Conclusion/Summary :
Teratogenicity
Conclusion/Summary :
Reproductive toxicity
Conclusion/Summary :
Irritation/Corrosion
Conclusion/Summary
Skin :
Eyes :
Respiratory :
Sensitization
Conclusion/Summary
Skin :
Respiratory :
Specific target organ toxicity (single exposure)
Information on toxicological effects
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Specific target organ toxicity (repeated exposure)
Name
acetone Category 3 -Narcotic effects
Category Route of
exposure
Target organs
Not available.
United States Page: 8/13
GENERAL PURPOSE SOLVENTProduct name
10Product code Date of issue VersionMS15116 June 2021
Section 11. Toxicological information
Conclusion/Summary :
Information on the likely routes of exposure
Delayed and immediate effects and also chronic effects from short and long term exposure
Aspiration hazard
Name Result
Ligroine ASPIRATION HAZARD - Category 1
Potential immediate
effects
:
Short term exposure
Potential acute health effects
Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
Can cause central nervous system (CNS) depression.:Ingestion
Skin contact :Defatting to the skin. May cause skin dryness and irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
No specific data.
Adverse symptoms may include the following:
irritation
dryness
cracking
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
There are no data available on the mixture itself. Exposure to component solvent vapor
concentrations in excess of the stated occupational exposure limit may result in adverse
health effects such as mucous membrane and respiratory system irritation and adverse
effects on the kidneys, liver and central nervous system. Symptoms and signs include
headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases,
loss of consciousness. Solvents may cause some of the above effects by absorption
through the skin. There is some evidence that repeated exposure to organic solvent
vapors in combination with constant loud noise can cause greater hearing loss than
expected from exposure to noise alone. If splashed in the eyes, the liquid may cause
irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic
effects of components from short-term and long-term exposure by oral, inhalation and
dermal routes of exposure and eye contact.
There are no data available on the mixture itself.
Target organs :Contains material which causes damage to the following organs: brain.
Contains material which may cause damage to the following organs: the nervous
system, gastrointestinal tract, upper respiratory tract, skin, central nervous system
(CNS), eye, lens or cornea.
United States Page: 9/13
GENERAL PURPOSE SOLVENTProduct name
10Product code Date of issue VersionMS15116 June 2021
Section 11. Toxicological information
General :
Carcinogenicity :
Mutagenicity :
Reproductive toxicity :
Potential chronic health effects
Numerical measures of toxicity
Acute toxicity estimates
Potential delayed effects :
Potential immediate
effects
:
Long term exposure
Potential delayed effects :
No known significant effects or critical hazards.
Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or
dermatitis.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Product/ingredient name
GENERAL PURPOSE SOLVENT N/A N/A 110393.6 N/A N/A
acetone 5800 15800 N/A 76 N/A
Ligroine N/A N/A 3400 N/A N/A
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm)
Inhalation
(vapors)
(mg/l)
Inhalation
(dusts and
mists) (mg/
l)
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
acetone -0.23 3 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
acetone --Readily
Toxicity
acetone Acute LC50 4.42589 ml/L Marine water Crustaceans - Acartia tonsa -
Copepodid
48 hours
Acute LC50 5540 mg/l Fish 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
acetone -90.9 % - Readily - 28 days --
Product/ingredient name Test DoseResult Inoculum
Mobility in soil
United States Page: 10/13
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10Product code Date of issue VersionMS15116 June 2021
Section 12. Ecological information
Soil/water partition
coefficient (KOC)
:Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
14. Transport information
PAINT RELATED MATERIAL
3
II
PAINT RELATED MATERIAL
3
II
PAINT RELATED MATERIAL
UN1263
3
II
UN1263 UN1263
DOT IMDG IATA
UN number
UN proper shipping
name
Transport hazard class
(es)
Packing group
Environmental hazards No.No.No.
Marine pollutant
substances
Not applicable.Not applicable.
RQ substances
5186.5
(acetone)
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Additional information
Package sizes shipped in quantities less than the product reportable quantity are not subject to the
RQ (reportable quantity) transportation requirements.
None identified.
DOT
IMDG
:
:
IATA :None identified.
Product RQ (lbs)
United States Page: 11/13
GENERAL PURPOSE SOLVENTProduct name
10Product code Date of issue VersionMS15116 June 2021
14. Transport information
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Transport in bulk according
to IMO instruments
:Not applicable.
Section 15. Regulatory information
SARA 302/304
SARA 304 RQ :Not applicable.
Composition/information on ingredients
All components are active or exempted.United States inventory (TSCA 8b):
United States
U.S. Federal regulations :
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
No products were found.
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
HNOC - Defatting irritant
acetone ≥90 FLAMMABLE LIQUIDS - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
HNOC - Defatting irritant
Ligroine ≥1.0 - ≤5.0 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
EYE IRRITATION - Category 2A
ASPIRATION HAZARD - Category 1
HNOC - Defatting irritant
Name %Classification
Composition/information on ingredients
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GENERAL PURPOSE SOLVENTProduct name
10Product code Date of issue VersionMS15116 June 2021
Section 16. Other information
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Hazardous Material Information System (U.S.A.)
3
03
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Date of previous issue 6/15/2020:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Indicates information that has changed from previously issued version.
Organization that prepared
the SDS
:EHS
:::
:::2
2
0
( * ) - Chronic effects
United States Page: 13/13
ENVIROCRON XZR POWDER
Not available.
Powder.
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Section 1. Identification
:
:
:
Product code :PCM70140/22.7K-C2
Supplier PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
01-800-00-21-400 (Mexico)
Emergency telephone
number
:
:
Technical Phone Number :[phone] (OAK CREEK, WI) 8:00 a.m. - 5:00 p.m. Central
Date of issue/Date of revision 17 August 2015
Version 1
Relevant identified uses of the substance or mixture and uses advised against
Coating. Paints. Painting-related materials.
Uses advised against Not applicable.
Product use :Industrial applications.
Use of the substance/
mixture
:
:
Section 2. Hazards identification
COMBUSTIBLE DUSTS
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
TOXIC TO REPRODUCTION (Fertility) - Category 2
Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 90.6%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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Section 2. Hazards identification
Hazard statements :May form combustible dust concentrations in air.
Causes serious eye irritation.
Causes skin irritation.
May cause an allergic skin reaction.
Suspected of damaging fertility.
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Avoid breathing dust. Wash hands thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response :IF exposed or concerned: Get medical attention. IF ON SKIN: Wash with plenty of
soap and water. Wash contaminated clothing before reuse. If skin irritation or rash
occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical attention.
Storage :Store locked up.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label
elements
:Keep container tightly closed. Keep away from heat, sparks, open flames and hot
surfaces. - No smoking. Sanding and grinding dusts may be harmful if inhaled. Prevent
dust accumulation. Emits toxic fumes when heated.
Hazards not otherwise
classified
:Fine dust clouds may form explosive mixtures with air. Handling and/or processing of
this material may generate a dust which can cause mechanical irritation of the eyes,
skin, nose and throat.
Section 3. Composition/information on ingredients
reaction product: bisphenol-A-(epichlorhydrin); epoxy resin ≥5 - <10 25068-38-6
Phenol, 4,4'-(1-methylethylidene)bis-, polymer with 2,2'-[(1-methylethylidene)
bis(4,1-phenyleneoxymethylene)]bis[oxirane]
≥5 - <10 25036-25-3
zinc oxide ≥3 - <5 1314-13-2
Epoxy Resin (MW<=700)≥2 - <3 25036-25-3
bisphenol A ≥0.3 - <1 80-05-7
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Product name ENVIROCRON XZR POWDER:
SUB codes represent substances without registered CAS Numbers.
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Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :
:Ingestion
Skin contact :
:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids
apart for at least 10 minutes and seek immediate medical advice.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
Causes serious eye irritation.
Exposure to airborne concentrations above statutory or recommended exposure limits
may cause irritation of the nose, throat and lungs.
No known significant effects or critical hazards.
Causes skin irritation. May cause an allergic skin reaction.
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Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
halogenated compounds
metal oxide/oxides
Fine dust clouds may form explosive mixtures with air. This material is very toxic to
aquatic life with long lasting effects. Fire water contaminated with this material must be
contained and prevented from being discharged to any waterway, sewer or drain.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical powder.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing dust. Provide adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Put on
appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
For non-emergency
personnel
For emergency responders :If specialised clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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Section 6. Accidental release measures
Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Approach release from upwind. Prevent entry into sewers, water courses, basements
or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with
equipment fitted with a HEPA filter and place in a closed, labeled waste container.
Avoid creating dusty conditions and prevent wind dispersal. Dispose of via a licensed
waste disposal contractor. Note: see Section 1 for emergency contact information and
Section 13 for waste disposal.
Large spill :
Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a
HEPA filter and place in a closed, labeled waste container. Place spilled material in a
designated, labeled waste container. Dispose of via a licensed waste disposal
contractor.
Small spill :
Methods and materials for containment and cleaning up
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid
breathing dust. Avoid the creation of dust when handling and avoid all possible sources
of ignition (spark or flame). Prevent dust accumulation. Use only with adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Electrical equipment and lighting should be protected to
appropriate standards to prevent dust coming into contact with hot surfaces, sparks or
other ignition sources. Take precautionary measures against electrostatic discharges.
To avoid fire or explosion, dissipate static electricity during transfer by grounding and
bonding containers and equipment before transferring material. Empty containers retain
product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
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reaction product: bisphenol-A-(epichlorhydrin); epoxy resin None.
Phenol, 4,4'-(1-methylethylidene)bis-, polymer with 2,2'-[
(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis[oxirane]
None.
zinc oxide OSHA PEL (United States, 2/2013).
TWA: 5 mg/m³ 8 hours. Form: Fume
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
ACGIH TLV (United States, 4/2014).
STEL: 10 mg/m³ 15 minutes. Form:
Respirable fraction
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction
Epoxy Resin (MW<=700)None.
bisphenol A IPEL (PPG).
STEL: 5 mg/m³
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits. The engineering controls also need to keep gas, vapor or dust concentrations
below any lower explosive limits. Use explosion-proof ventilation equipment.
Control parameters
Individual protection measures
Occupational exposure limits
Recommended monitoring
procedures
:If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Key to abbreviations
A Acceptable Maximum Peak=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
TD =Total dust
Consult local authorities for acceptable exposure limits.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
STEL =
=
Short term Exposure limit values
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Section 8. Exposure controls/personal protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Skin protection
Other skin protection :
Chemical splash goggles.
Gloves butyl rubber:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Solid.
Not available.
0 kPa (0 mm Hg) [room temperature]
Not available.Odor
pH
Not available.Color
Evaporation rate 0 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: Not applicable.
Not available.
Not available.Odor threshold
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :Not available.
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
Yes.:Material supports
combustion.
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Section 9. Physical and chemical properties
Relative density
Vapor density
Solubility
3.6
Not available.
Insoluble in the following materials: cold water.
Not available.
Viscosity Kinematic (40°C (104°F)): Not applicable.
Partition coefficient: n-
octanol/water
:
:
:
:
:
% Solid. (w/w):100
Density ( lbs / gal ):30.04
Volatility :0% (v/v), 0% (w/w)
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
The product is stable.Chemical stability :
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
When exposed to high temperatures may produce hazardous decomposition products.
Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
Decomposition products may include the following materials: carbon monoxide, carbon
dioxide, smoke, oxides of nitrogen.
Refer to protective measures listed in sections 7 and 8.
Section 11. Toxicological information
Acute toxicity
reaction product: bisphenol-A-
(epichlorhydrin); epoxy resin
LD50 Dermal Rabbit >2 g/kg -
LD50 Oral Rat 11.4 g/kg -
bisphenol A LD50 Dermal Rabbit 3 g/kg -
LD50 Oral Rat 1200 mg/kg -
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary :
Irritation/Corrosion
Conclusion/Summary
Skin :
Eyes :
Respiratory :
Information on toxicological effects
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
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Section 11. Toxicological information
Carcinogenicity
Conclusion/Summary :
Mutagenicity
Conclusion/Summary :
Teratogenicity
Conclusion/Summary :
Reproductive toxicity
Conclusion/Summary :
Sensitization
Conclusion/Summary
Skin :
Respiratory :
Specific target organ toxicity (single exposure)
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Name
Information on the likely routes of exposure
Specific target organ toxicity (repeated exposure)
bisphenol A Category 3
Category
Not available.
Aspiration hazard
Not available.
Potential acute health effects
Inhalation :Exposure to airborne concentrations above statutory or recommended exposure limits
may cause irritation of the nose, throat and lungs.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Target organs :Contains material which may cause damage to the following organs: upper respiratory
tract.
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Section 11. Toxicological information
Conclusion/Summary :
General :
Carcinogenicity :
Mutagenicity :
Teratogenicity :
Developmental effects :
Fertility effects :
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:
Short term exposure
Potential delayed effects :
Potential immediate
effects
:
Long term exposure
Potential delayed effects :
Skin contact
Ingestion Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
No known significant effects or critical hazards.
There are no data available on the mixture itself. Repeated exposure of the eyes to a
low level of dust can produce eye irritation. Repeated or prolonged inhalation of dust
may lead to chronic respiratory irritation. Ingestion may cause nausea, diarrhea and
vomiting. This takes into account, where known, delayed and immediate effects and
also chronic effects of components from short-term and long-term exposure by oral,
inhalation and dermal routes of exposure and eye contact.
Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation. Once
sensitized, a severe allergic reaction may occur when subsequently exposed to very low
levels.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Suspected of damaging fertility.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Section 12. Ecological information
Toxicity
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
bisphenol A 3.32 43.65 low
zinc oxide Acute EC50 0.481 mg/l Fresh water Daphnia - Daphnia magna -
Neonate
48 hours
bisphenol A Acute EC50 20.5 mg/l Fresh water Daphnia - Daphnia magna -
Juvenile (Fledgling, Hatchling,
Weanling)
48 hours
Chronic EC10 3.47 mg/l Marine water Algae - Cochlodinium
polykrikoides - Exponential
growth phase
72 hours
Chronic NOEC 0.86 mg/l Fresh water Daphnia - Daphnia magna -
Neonate
21 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
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14. Transport information
ENVIRONMENTALLY
HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
9
III
ENVIRONMENTALLY
HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
9
III
ENVIRONMENTALLY
HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
UN3077
9
III
UN3077 UN3077
DOT IMDG IATA
UN number
UN proper shipping
name
Transport hazard class
(es)
Packing group
Environmental hazards No.Yes.Yes.
Marine pollutant
substances
Not applicable.(Zinc powder - zinc dust
(stabilized), reaction product:
bisphenol-A-(epichlorhydrin);
epoxy resin)
(Zinc powder - zinc dust
(stabilized), reaction product:
bisphenol-A-(epichlorhydrin);
epoxy resin)
(Zinc powder - zinc dust
(stabilized))
(Zinc powder - zinc dust
(stabilized), reaction product:
bisphenol-A-(epichlorhydrin);
epoxy resin)
RQ substances
1302
(Zinc powder - zinc dust
(stabilized))
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
The classification of the product is due solely to the presence of one or more US DOT-listed
‘Hazardous substances’ that are subject to reportable quantity requirements and only applies to
shipments of packages greater than, or equal to, the product reportable quantity. Package sizes
less than the product reportable quantity are not regulated as hazardous materials.
This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg,
provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8. The
segregation group has been manually assigned based upon product analysis.
DOT
IMDG
:
:
IATA :This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg,
provided the packagings meet the general provisions of 5.0.2.4.1, 5.0.2.6.1.1 and 5.0.2.8.
Product RQ (lbs)
Section 15. Regulatory information
SARA 302/304
SARA 304 RQ :Not applicable.
Composition/information on ingredients
All components are listed or exempted.United States inventory (TSCA 8b):
United States
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Section 15. Regulatory information
SARA 313
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
reaction product: bisphenol-A-
(epichlorhydrin); epoxy resin
No.No.No.Yes.No.-
Phenol, 4,4'-(1-methylethylidene)bis-,
polymer with 2,2'-[(1-methylethylidene)
bis(4,1-phenyleneoxymethylene)]bis
[oxirane]
Yes.No.No.Yes.No.-
Epoxy Resin (MW<=700)Yes.No.No.Yes.No.-
bisphenol A Yes.No.No.Yes.Yes.-
Name Fire
hazard
Sudden
release of
pressure
Reactive Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Composition/information on ingredients
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.
Supplier notification
Chemical name
:Zinc powder - zinc dust (stabilized)7440-66-6 60 - 100
zinc oxide 1314-13-2 1 - 5
CAS number Concentration
No products were found.
Section 16. Other information
Hazardous Material Information System (U.S.A.)
0
10
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Date of previous issue No previous validation:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are
to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS®
materials may be purchased exclusively from J. J. Keller [phone].
The customer is responsible for determining the PPE code for this material.
Organization that prepared
the MSDS
:EHS
:::
:::2
2
1
( * ) - Chronic effects
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Section 16. Other information
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Indicates information that has changed from previously issued version.
United States Page: 14/14
BLACK POLYESTERProduct name
Product and company identification
:
1 .
PCTJ99104
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
01-800-00-21-400 (Mexico)
Supplier
Code
Emergency telephone
number
:
:
:
Technical Phone Number :1-800-647-6050
Material Safety Data Sheet
Date of issue 16 February 2015
Version 10
Emergency overview
Hazards identification
Potential acute health effects
May be harmful if swallowed.
Eyes
Skin
Inhalation
Ingestion
WARNING!:
:
:
:
:
Medical conditions
aggravated by over-
exposure
Pre-existing respiratory and skin disorders and disorders involving any other target
organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to
this product.
:
2 .
Over-exposure signs/symptoms
Ingestion :
Skin :
Eyes :
Inhalation :
Keep away from heat, sparks and flame. Prevent dust accumulation. Do not breathe
dust. Do not get on skin or clothing. Use only with adequate ventilation. Keep
container tightly closed and sealed until ready for use. Wash thoroughly after handling.
MAY FORM EXPLOSIVE DUST-AIR MIXTURES. MAY CAUSE ALLERGIC
RESPIRATORY AND SKIN REACTION. MAY BE HARMFUL IF INHALED OR
SWALLOWED. MAY CAUSE RESPIRATORY TRACT IRRITATION. CONTAINS
MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. CONTAINS MATERIAL
WHICH MAY CAUSE HERITABLE GENETIC EFFECTS.
May be harmful if inhaled. Exposure to airborne concentrations above statutory or
recommended exposure limits may cause irritation of the nose, throat and lungs. May
cause sensitization by inhalation. Exposure to decomposition products may cause a
health hazard. Serious effects may be delayed following exposure.
Exposure to airborne concentrations above statutory or recommended exposure limits
may cause irritation of the eyes.
May cause an allergic skin reaction.
Adverse symptoms may include the following:
respiratory tract irritation
coughing
wheezing and breathing difficulties
asthma
No specific data.
Adverse symptoms may include the following:
irritation
redness
Adverse symptoms may include the following:
irritation
redness
Page: 1/7Canada - Mexico
BLACK POLYESTERProduct name
10Product code Date of issue VersionPCTJ9910416 February 2015
Hazards identification2 .
See toxicological information (Section 11)
This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials
Information System (WHMIS).
Composition/information on ingredients3 .
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
proprietary polyester resin Not available.60 - 100
1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione 2451-62-9 3 - 7
carbon black, respirable powder 1333-86-4 0.5 - 1.5
Name CAS number % (w/w)
First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
Notes to physician
:
:
:
:
:
4 .
Check for and remove any contact lenses. Immediately flush eyes with running
water for at least 15 minutes, keeping eyelids open. Seek immediate medical
attention.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognized skin cleanser. Do NOT use solvents or thinners.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
If swallowed, seek medical advice immediately and show this container or label.
Keep person warm and at rest. Do NOT induce vomiting.
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this
product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Use dry chemical powder.
Fire-fighting measures
Extinguishing media
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Fine dust clouds may form explosive mixtures with air. Runoff to sewer may create fire
or explosion hazard.
Special protective
equipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
5 .
Special exposure hazards :
Do not use water jet.
Suitable :
Not suitable :
Hazardous combustion
products
:Decomposition products may include the following materials:
carbon oxides
nitrogen oxides
Hydrogen cyanide (HCN).
Cyanate and isocyanate.
Flammability of the product :
Page: 2/7Canada - Mexico
BLACK POLYESTERProduct name
10Product code Date of issue VersionPCTJ9910416 February 2015
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing dust. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment (see Section 8).
Move containers from spill area. Approach release from upwind. Use spark-proof tools
and explosion-proof equipment. Prevent entry into sewers, water courses, basements
or confined areas. Vacuum or sweep up material and place in a designated, labeled
waste container. Avoid creating dusty conditions and prevent wind dispersal. Dispose
of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Environmental precautions
Accidental release measures
:Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Personal precautions :
Large spill :
6 .
Move containers from spill area. Vacuum or sweep up material and place in a
designated, labeled waste container. Dispose of via a licensed waste disposal
contractor.
Small spill :
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Persons with a history of skin sensitization problems or asthma, allergies or
chronic or recurrent respiratory disease should not be employed in any process in which
this product is used. Do not breathe dust. Do not swallow. Do not get in eyes or on
skin or clothing. Avoid the creation of dust when handling and avoid all possible sources
of ignition (spark or flame). Prevent dust accumulation. Use only with adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Electrical equipment and lighting should be protected to
appropriate standards to prevent dust coming into contact with hot surfaces, sparks or
other ignition sources. Empty containers retain product residue and can be hazardous.
Do not reuse container.
Handling and storage
Handling
Storage
:
:
7 .
Exposure controls/personal protection8 .
Acceptable Maximum PeakA=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
SR =Respiratory sensitization
=Skin sensitizationSS
TD =Total dust
Key to abbreviations
=Threshold Limit ValueTLV
Fume=F
IPEL =Internal Permissible Exposure Limit
proprietary polyester resin TWA 10 mg/m³
(Total dust)
Not established Not established Not established
___________________________________________________________________________________
1,3,5-tris(oxiranylmethyl)-1,3,
5-triazine-2,4,6(1H,3H,5H)-trione
TWA 0.05 mg/m³0.05 mg/m³Not established Not established
___________________________________________________________________________________
carbon black, respirable powder TWA 3 mg/m³3 mg/m³3.5 mg/m³Not established
STEL Not established Not established 7 mg/m³Not established
___________________________________________________________________________________
Name Result ACGIH Ontario Mexico PPG
STEL =Short term Exposure limit values
Page: 3/7Canada - Mexico
BLACK POLYESTERProduct name
10Product code Date of issue VersionPCTJ9910416 February 2015
Exposure controls/personal protection8 .
Potential skin absorptionS
If workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator
complying with an approved standard if a risk assessment indicates this is necessary.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator.
Safety glasses with side shields.
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Personal protection
Eyes
Skin
Respiratory
Consult local authorities for acceptable exposure limits.
:
:
:
butyl rubberGloves:
Engineering measures :Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits. The engineering controls also need to keep gas, vapor or dust concentrations
below any lower explosive limits. Use explosion-proof ventilation equipment.
Hygiene measures :Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Recommended monitoring
procedures
:If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment will
be necessary to reduce emissions to acceptable levels.
TWA =Time Weighted Average
Hands :Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
R =Respirable
=
Not available.
Solid.
Not available.
Not available.
Not available.
Not available.
Boiling/condensation point
Melting/freezing point
Physical and chemical properties
Physical state
pH
Odor
Color
:
:
:
:
:
:
Flash point :Closed cup: Not applicable.
9 .
Yes.:Material supports
combustion.
Page: 4/7Canada - Mexico
BLACK POLYESTERProduct name
10Product code Date of issue VersionPCTJ9910416 February 2015
Physical and chemical properties9 .
0% (v/v), 0% (w/w)
1.21
Not available.
0 kPa (0 mm Hg) [room temperature]
Insoluble in the following materials: cold water.
0 (butyl acetate = 1)
Specific gravity
Vapor pressure
Vapor density
Volatility
Evaporation rate
Solubility
:
:
:
:
:
:
Partition coefficient: n-
octanol/water
:Not available.
% Solid. (w/w):100
Density ( lbs / gal ):10.1
The product may not be stable under certain conditions of storage or use.
Reactive or incompatible with the following materials:,oxidizing materials,strong acids,
strong alkalis
Under normal conditions of storage and use, hazardous polymerization will not occur.
Cyanate and isocyanate.
Avoid the creation of dust when handling and avoid all possible sources of ignition
(spark or flame). Prevent dust accumulation. Avoid increased storage temperature.
Pressure hazard
Stability and reactivity
Stability
Conditions to avoid
Materials to avoid
Hazardous decomposition
products
Hazardous polymerization
:
:
:
:
:
10 .
11 .Toxicological information
Conclusion/Summary :Not available.
Chronic toxicity
Conclusion/Summary :Not available.
Carcinogenicity
Classification
Carcinogenicity :Contains material which may cause cancer, based on animal data. Risk of cancer
depends on duration and level of exposure.
Target organs :Contains material which causes damage to the following organs: upper respiratory tract,
skin, eyes.
Contains material which may cause damage to the following organs: kidneys, lungs, the
reproductive system, , testes.
1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,
6(1H,3H,5H)-trione
LD50 Oral Rat - Male <100 mg/kg -
LC50 Inhalation
Dusts and mists
Rat - Female 650 mg/m³4 hours
carbon black, respirable powder LD50 Oral Rat >15400 mg/kg -
LD50 Dermal Rabbit >3 g/kg -
Product/ingredient name Result Species Dose Exposure
Acute toxicity
Product/ingredient name
carbon black, respirable powder A3 2B -
ACGIH NTPIARC
Page: 5/7Canada - Mexico
BLACK POLYESTERProduct name
10Product code Date of issue VersionPCTJ9910416 February 2015
11 .Toxicological information
Carcinogen Classification code:
Mutagenicity
Mutagenicity :Contains material which may cause heritable genetic effects.
ACGIH: A1, A2, A3, A4, A5
IARC: 1, 2A, 2B, 3, 4
NTP: Known to be a human carcinogen; Reasonably anticipated to be
a human carcinogen
Not listed or regulated as a carcinogen: -
Ecological information
Environmental effects :No known significant effects or critical hazards.
12 .
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Waste disposal
Disposal considerations
Disposal should be in accordance with applicable regional, national and local laws and regulations.
:
13 .
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
14. Transport information
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
None identified.
None identified.
TDG
Mexico
:
:
-
-
-
Not regulated.
Mexico
UN number
UN proper shipping
name
Transport hazard
class(es)
Packing group
Environmental
hazards
No.
TDG
Not regulated.
-
-
-
No.
Marine pollutant
substances
IMDG :None identified.
IMDG
Not regulated.
-
-
-
No.
Not applicable.Not applicable.Not applicable.
Page: 6/7Canada - Mexico
BLACK POLYESTERProduct name
10Product code Date of issue VersionPCTJ9910416 February 2015
14. Transport information
15 .Regulatory information
Not determined.
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
At least one component is not listed.
At least one component is not listed.
Not determined.
All components are listed or exempted.United States inventory (TSCA 8b):
Australia inventory (AICS)
Canada inventory ( DSL ):
China inventory (IECSC):
Japan inventory (ENCS):
Korea inventory (KECI):
New Zealand ( NZIoC ):
Philippines inventory (PICCS):
:
Europe inventory ( REACH ):Please contact your supplier for information on the inventory status of this material.
WHMIS (Canada)Class D-1B: Material causing immediate and serious toxic effects (Toxic). Class D-2A:
Material causing other toxic effects (Very toxic). Class D-2B: Material causing other
toxic effects (Toxic).
:
Canada
Mexico
0 2 1HealthFlammabilityReactivity
Classification
:::
Other information
Hazardous Material Information System (U.S.A.)
0
10
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Date of previous issue 10/9/2014.:
16 .
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller [phone].
The customer is responsible for determining the PPE code for this material.
Indicates information that has changed from previously issued version.
Organization that prepared
the MSDS
:EHS
:::
:::2 *
2
1
( * ) - Chronic
effects
Page: 7/7Canada - Mexico
WINTER WHITE EXTERIOR POLYESTERProduct name
Product and company identification
:
1 .
PCTZ89107
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
01-800-00-21-400 (Mexico)
Supplier
Code
Emergency telephone
number
:
:
:
Technical Phone Number :1-800-647-6050
Material Safety Data Sheet
Date of issue 2 July 2015
Version 24
Emergency overview
Hazards identification
Potential acute health effects
May be harmful if swallowed.
Eyes
Skin
Inhalation
Ingestion
WARNING!:
:
:
:
:
Medical conditions
aggravated by over-
exposure
Pre-existing respiratory and skin disorders and disorders involving any other target
organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to
this product.
:
2 .
Over-exposure signs/symptoms
Ingestion :
Skin :
Eyes :
Inhalation :
Do not breathe vapor or mist. Do not get in eyes or on skin or clothing. Use only with
adequate ventilation. Keep container tightly closed and sealed until ready for use.
Wash thoroughly after handling.
HARMFUL IF INHALED. CAUSES EYE IRRITATION. MAY CAUSE ALLERGIC
RESPIRATORY AND SKIN REACTION. MAY BE HARMFUL IF SWALLOWED.
SANDING AND GRINDING DUSTS MAY BE HARMFUL IF INHALED. MAY CAUSE
RESPIRATORY TRACT IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE
TARGET ORGAN DAMAGE. CONTAINS MATERIAL WHICH MAY CAUSE
HERITABLE GENETIC EFFECTS.
Harmful if inhaled. May cause sensitization by inhalation. Exposure to decomposition
products may cause a health hazard. Serious effects may be delayed following
exposure.
Severely irritating to eyes. Risk of serious damage to eyes.
May cause an allergic skin reaction.
This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials
Information System (WHMIS).
Adverse symptoms may include the following:
wheezing and breathing difficulties
asthma
No specific data.
Adverse symptoms may include the following:
irritation
redness
Adverse symptoms may include the following:
pain or irritation
watering
redness
Page: 1/7Canada - Mexico
WINTER WHITE EXTERIOR POLYESTERProduct name
24Product code Date of issue VersionPCTZ891072 July 2015
Hazards identification2 .
See toxicological information (Section 11)
Composition/information on ingredients3 .
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
proprietary polyester resin Not available.40 - 70
titanium dioxide 13463-67-7 10 - 30
barium sulfate 7727-43-7 7 - 13
1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione 2451-62-9 1 - 5
Name CAS number % (w/w)
First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
Notes to physician
:
:
:
:
:
4 .
Check for and remove any contact lenses. Immediately flush eyes with running
water for at least 15 minutes, keeping eyelids open. Seek immediate medical
attention.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognized skin cleanser. Do NOT use solvents or thinners.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
If swallowed, seek medical advice immediately and show this container or label.
Keep person warm and at rest. Do NOT induce vomiting.
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this
product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Use an extinguishing agent suitable for the surrounding fire.
Fire-fighting measures
Extinguishing media
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
In a fire or if heated, a pressure increase will occur and the container may burst.
Special protective
equipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
5 .
Special exposure hazards :
None known.
Suitable :
Not suitable :
Hazardous combustion
products
:Decomposition products may include the following materials:
carbon oxides
nitrogen oxides
sulfur oxides
metal oxide/oxides
Flammability of the product :
Page: 2/7Canada - Mexico
WINTER WHITE EXTERIOR POLYESTERProduct name
24Product code Date of issue VersionPCTZ891072 July 2015
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment (see Section 8).
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see Section
1 for emergency contact information and Section 13 for waste disposal.
Environmental precautions
Accidental release measures
:Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Personal precautions :
Large spill :
6 .
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble or absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Persons with a history of skin sensitization problems or asthma, allergies or
chronic or recurrent respiratory disease should not be employed in any process in which
this product is used. Do not breathe vapor or mist. Do not swallow. Do not get in eyes
or on skin or clothing. Use only with adequate ventilation. Wear appropriate respirator
when ventilation is inadequate. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use. Empty containers
retain product residue and can be hazardous. Do not reuse container.
Handling and storage
Handling
Storage
:
:
7 .
Exposure controls/personal protection8 .
Acceptable Maximum PeakA=
ACGIH =American Conference of Governmental Industrial Hygienists.
SR =Respiratory sensitization
=Skin sensitizationSS
Key to abbreviations
proprietary polyester resin TWA 10 mg/m³
(Total dust)
Not established Not established Not established
___________________________________________________________________________________
titanium dioxide TWA 10 mg/m³10 mg/m³ TD 10 mg/m³ (as
Ti)
Not established
STEL Not established Not established 20 mg/m³ (as
Ti)
Not established
___________________________________________________________________________________
barium sulfate TWA 5 mg/m³10 mg/m³ TD Not established Not established
___________________________________________________________________________________
1,3,5-tris(oxiranylmethyl)-1,3,
5-triazine-2,4,6(1H,3H,5H)-trione
TWA 0.05 mg/m³0.05 mg/m³Not established Not established
___________________________________________________________________________________
Name Result ACGIH Ontario Mexico PPG
Page: 3/7Canada - Mexico
WINTER WHITE EXTERIOR POLYESTERProduct name
24Product code Date of issue VersionPCTZ891072 July 2015
Exposure controls/personal protection8 .
C =Ceiling Limit
Potential skin absorptionS
TD =Total dust
By spraying: air-fed respirator. By other operations than spraying, in well ventilated
areas, air-fed respirators could be replaced by a combination charcoal filter and
particulate filter mask. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected
respirator.
Chemical splash goggles.
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Personal protection
Eyes
Skin
Respiratory
Consult local authorities for acceptable exposure limits.
:
:
:
butyl rubberGloves:
Engineering measures :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits.
Hygiene measures :Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Recommended monitoring
procedures
:If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment will
be necessary to reduce emissions to acceptable levels.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Hands :Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Fume=F
IPEL =Internal Permissible Exposure Limit
R =Respirable
STEL =
=
Short term Exposure limit values
>37.78°C (>100°F)
Liquid.
Not available.
Not available.
1.57
Not available.
Not available.
Boiling/condensation point
Melting/freezing point
Physical and chemical properties
Physical state
pH
Specific gravity
Odor
Color
:
:
:
:
:
:
:
Flash point :Closed cup: Not applicable.
9 .
Page: 4/7Canada - Mexico
WINTER WHITE EXTERIOR POLYESTERProduct name
24Product code Date of issue VersionPCTZ891072 July 2015
Physical and chemical properties9 .
0% (v/v), 0% (w/w)
Not available.
0 kPa (0 mm Hg) [room temperature]
Insoluble in the following materials: cold water.
0 (butyl acetate = 1)
Vapor pressure
Vapor density
Volatility
Evaporation rate
Solubility
:
:
:
:
:
Partition coefficient: n-
octanol/water
:Not available.
% Solid. (w/w):100
Density ( lbs / gal ):13.1
Stable under recommended storage and handling conditions (see Section 7).
Reactive or incompatible with the following materials:,acids,oxidizing materials,strong
alkalis
Under normal conditions of storage and use, hazardous polymerization will not occur.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
No specific data.
Stability and reactivity
Stability
Conditions to avoid
Materials to avoid
Hazardous decomposition
products
Hazardous polymerization
:
:
:
:
:
10 .
11 .Toxicological information
Conclusion/Summary :Not available.
Chronic toxicity
Conclusion/Summary :Not available.
Carcinogenicity
Classification
Carcinogenicity :Contains material which may cause cancer, based on animal data. Risk of cancer
depends on duration and level of exposure.
Target organs :Contains material which causes damage to the following organs: upper respiratory tract,
skin, eyes.
Contains material which may cause damage to the following organs: kidneys, lungs, the
reproductive system, , testes.
titanium dioxide LD50 Oral Rat >10 g/kg -
1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,
6(1H,3H,5H)-trione
LD50 Oral Rat - Male <100 mg/kg -
LC50 Inhalation
Dusts and mists
Rat - Female 650 mg/m³4 hours
Product/ingredient name Result Species Dose Exposure
Acute toxicity
Product/ingredient name
titanium dioxide A4 2B -
ACGIH NTPIARC
Carcinogen Classification code:
Mutagenicity
ACGIH: A1, A2, A3, A4, A5
IARC: 1, 2A, 2B, 3, 4
NTP: Known to be a human carcinogen; Reasonably anticipated to be
a human carcinogen
Not listed or regulated as a carcinogen: -
Page: 5/7Canada - Mexico
WINTER WHITE EXTERIOR POLYESTERProduct name
24Product code Date of issue VersionPCTZ891072 July 2015
11 .Toxicological information
Mutagenicity :Contains material which may cause heritable genetic effects.
Ecological information
Environmental effects :No known significant effects or critical hazards.
12 .
Aquatic ecotoxicity
titanium dioxide Acute LC50 >100 mg/l Fresh water Daphnia - Daphnia magna 48 hours
_________________________________________________________________________________________________
Product/ingredient
name
SpeciesResult Exposure
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Waste disposal
Disposal considerations
Disposal should be in accordance with applicable regional, national and local laws and regulations.
:
13 .
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
14. Transport information
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
None identified.
None identified.
TDG
Mexico
:
:
-
-
-
Not regulated.
Mexico
UN number
UN proper shipping
name
Transport hazard
class(es)
Packing group
Environmental
hazards
No.
TDG
Not regulated.
-
-
-
No.
Marine pollutant
substances
IMDG :None identified.
IMDG
Not regulated.
-
-
-
No.
Not applicable.Not applicable.Not applicable.
Page: 6/7Canada - Mexico
WINTER WHITE EXTERIOR POLYESTERProduct name
24Product code Date of issue VersionPCTZ891072 July 2015
14. Transport information
15 .Regulatory information
All components are listed or exempted.Canada inventory ( DSL ):
WHMIS (Canada)Class D-1B: Material causing immediate and serious toxic effects (Toxic). Class D-2A:
Material causing other toxic effects (Very toxic). Class D-2B: Material causing other
toxic effects (Toxic).
:
Canada
Mexico
0 2 0HealthFlammabilityReactivity
Classification
:::
Other information
Hazardous Material Information System (U.S.A.)
0
00
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Date of previous issue 2/18/2015:
16 .
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller [phone].
The customer is responsible for determining the PPE code for this material.
Indicates information that has changed from previously issued version.
Organization that prepared
the MSDS
:EHS
:::
:::2 *
2
0
( * ) - Chronic
effects
Page: 7/7Canada - Mexico
ACETONE
Not available.
Liquid.
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Section 1. Identification
:
:
:
Product code :Q30
Date of issue/Date of revision 28 November 2022
Version 8.03
Relevant identified uses of the substance or mixture and uses advised against
Uses advised against Not applicable.
Product use :Industrial applications.
Use of the substance/
mixture
:Cleaner.; Thinner.
:
Manufacturer PPG Industries, Inc.
One PPG Place,
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
SETIQ Interior de la República: 800-00-214-00 (México)
SETIQ Ciudad de México: (55) 5559-1588 (México)
Emergency telephone
number
:
:
Technical Phone Number :1-800-647-6050
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Highly flammable liquid and vapor.
Causes serious eye irritation.
May cause drowsiness or dizziness.
Hazard pictograms :
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
United States Page: 1/13
ACETONEProduct name
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Section 2. Hazards identification
Precautionary statements
Prevention :Wear protective gloves, protective clothing and eye or face protection. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use
explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools.
Take action to prevent static discharges. Use only outdoors or in a well-ventilated area.
Avoid breathing vapor. Wash thoroughly after handling.
Response :IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a
POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice or attention.
Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep
cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label
elements
:Repeated exposure to high vapor concentrations may cause irritation of the respiratory
system and permanent brain and nervous system damage. Inhalation of vapor/aerosol
concentrations above the recommended exposure limits causes headaches,
drowsiness and nausea and may lead to unconsciousness or death. Avoid contact with
skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated.
Hazards not otherwise
classified
:Prolonged or repeated contact may dry skin and cause irritation.
Section 3. Composition/information on ingredients
acetone ≥90 67-64-1
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Product name ACETONE:
SUB codes represent substances without registered CAS Numbers.
Section 4. First aid measures
Eye contact :
Description of necessary first aid measures
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids
apart for at least 10 minutes and seek immediate medical advice.
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Section 4. First aid measures
Skin contact
Inhalation
Ingestion :
:
:
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :
:Ingestion
Skin contact :
:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
No specific data.
Adverse symptoms may include the following:
irritation
dryness
cracking
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
Causes serious eye irritation.
Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
Can cause central nervous system (CNS) depression.
Defatting to the skin. May cause skin dryness and irritation.
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8.03Product code Date of issue VersionQ3028 November 2022
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon oxides
Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur
and the container may burst, with the risk of a subsequent explosion. Vapors may
accumulate in low or confined areas or travel a considerable distance to a source of
ignition and flash back. Runoff to sewer may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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Section 6. Accidental release measures
information and Section 13 for waste disposal.
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 37.78°C (100°F). Store in accordance
with local regulations. Store in a segregated and approved area. Store in original
container protected from direct sunlight in a dry, cool and well-ventilated area, away
from incompatible materials (see Section 10) and food and drink. Store locked up.
Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly
closed and sealed until ready for use. Containers that have been opened must be
carefully resealed and kept upright to prevent leakage. Do not store in unlabeled
containers. Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid
contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Special precautions :Vapors may accumulate in low or confined areas or travel a considerable distance to a
source of ignition and flash back. Vapors are heavier than air and may spread along
floors. If this material is part of a multiple component system, read the Safety Data
Sheet(s) for the other component or components before blending as the resulting
mixture may have the hazards of all of its parts.
acetone ACGIH TLV (United States, 1/2022).
STEL: 500 ppm 15 minutes.
TWA: 250 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 2400 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
Key to abbreviations
A Acceptable Maximum Peak=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
=
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Section 8. Exposure controls/personal protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Eye/face protection
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :
Recommended monitoring
procedures
:Reference should be made to appropriate monitoring standards. Reference to national
guidance documents for methods for the determination of hazardous substances will
also be required.
Chemical splash goggles.
Gloves For prolonged or repeated handling, use the following type of gloves:
Recommended: butyl rubber
:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
TD =Total dust
Consult local authorities for acceptable exposure limits.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
STEL =Short term Exposure limit values
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ACETONEProduct name
8.03Product code Date of issue VersionQ3028 November 2022
Section 8. Exposure controls/personal protection
Respiratory protection :Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.
The respiratory protection shall be in accordance to 29 CFR 1910.134.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Liquid.
Not available.
0.79
Not available.
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 11.6 (butyl acetate = 1)
Auto-ignition temperature
Flash point
465°C (869°F)
Closed cup: -20°C (-4°F)
Not applicable.
5 to 6
Viscosity Kinematic (40°C (104°F)): <14 mm2/s (<14 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :133°C (271.4°F)
Flammability :Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
% Solid. (w/w):0
Density ( lbs / gal ):6.59
Volatility :100% (v/v), 100% (w/w)
Solubility(ies):Media Result
cold water Partially soluble
Section 10. Stability and reactivity
The product is stable.Chemical stability :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
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Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid :
:
Incompatible materials :
When exposed to high temperatures may produce hazardous decomposition products.
Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
Refer to protective measures listed in sections 7 and 8.
Depending on conditions, decomposition products may include the following materials:
carbon oxides
Section 11. Toxicological information
Acute toxicity
acetone LC50 Inhalation Vapor Rat 76000 mg/m³4 hours
LD50 Dermal Rabbit 15.8 g/kg -
LD50 Oral Rat 5800 mg/kg -
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary :
Carcinogenicity
Conclusion/Summary :
Mutagenicity
Conclusion/Summary :
Teratogenicity
Conclusion/Summary :
Reproductive toxicity
Conclusion/Summary :
Irritation/Corrosion
Conclusion/Summary
Skin :
Eyes :
Respiratory :
Sensitization
Conclusion/Summary
Skin :
Respiratory :
Specific target organ toxicity (single exposure)
Information on toxicological effects
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Specific target organ toxicity (repeated exposure)
Name
acetone Category 3 -Narcotic effects
Category Route of
exposure
Target organs
Not available.
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Section 11. Toxicological information
Conclusion/Summary :
Information on the likely routes of exposure
Delayed and immediate effects and also chronic effects from short and long term exposure
Aspiration hazard
Not available.
Potential immediate
effects
:
Short term exposure
Potential delayed effects :
Long term exposure
Potential acute health effects
Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
Can cause central nervous system (CNS) depression.:Ingestion
Skin contact :Defatting to the skin. May cause skin dryness and irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
No specific data.
Adverse symptoms may include the following:
irritation
dryness
cracking
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
There are no data available on the mixture itself. Exposure to component solvent vapor
concentrations in excess of the stated occupational exposure limit may result in adverse
health effects such as mucous membrane and respiratory system irritation and adverse
effects on the kidneys, liver and central nervous system. Symptoms and signs include
headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases,
loss of consciousness. Solvents may cause some of the above effects by absorption
through the skin. There is some evidence that repeated exposure to organic solvent
vapors in combination with constant loud noise can cause greater hearing loss than
expected from exposure to noise alone. If splashed in the eyes, the liquid may cause
irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic
effects of components from short-term and long-term exposure by oral, inhalation and
dermal routes of exposure and eye contact.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Target organs :Contains material which causes damage to the following organs: brain.
Contains material which may cause damage to the following organs: gastrointestinal
tract, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea.
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Section 11. Toxicological information
General :
Carcinogenicity :
Mutagenicity :
Reproductive toxicity :
Potential chronic health effects
Numerical measures of toxicity
Acute toxicity estimates
Potential immediate
effects
:
Potential delayed effects :
No known significant effects or critical hazards.
Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or
dermatitis.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Product/ingredient name
acetone 5800 15800 N/A 76 N/A
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm)
Inhalation
(vapors)
(mg/l)
Inhalation
(dusts and
mists) (mg/
l)
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
acetone -0.23 3 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
acetone --Readily
Toxicity
acetone Acute LC50 4.42589 ml/L Marine water Crustaceans - Acartia tonsa -
Copepodid
48 hours
Acute LC50 5540 mg/l Fish 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
acetone -90.9 % - Readily - 28 days --
Product/ingredient name Test DoseResult Inoculum
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
United States Page: 10/13
ACETONEProduct name
8.03Product code Date of issue VersionQ3028 November 2022
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
14. Transport information
ACETONE
3
II
ACETONE
3
II
ACETONE
UN1090
3
II
UN1090 UN1090
DOT IMDG IATA
UN number
UN proper shipping
name
Transport hazard class
(es)
Packing group
Environmental hazards No.No.No.
Marine pollutant
substances
Not applicable.Not applicable.
RQ substances
5025.1
(acetone)
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
Package sizes shipped in quantities less than the product reportable quantity are not subject to the
RQ (reportable quantity) transportation requirements.
None identified.
DOT
IMDG
:
:
IATA :None identified.
Product RQ (lbs)
Transport in bulk according
to IMO instruments
:Not applicable.
United States Page: 11/13
ACETONEProduct name
8.03Product code Date of issue VersionQ3028 November 2022
Section 15. Regulatory information
SARA 302/304
SARA 304 RQ :Not applicable.
Composition/information on ingredients
All components are active or exempted.United States inventory (TSCA 8b):
United States
U.S. Federal regulations :
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
No products were found.
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
HNOC - Defatting irritant
acetone ≥90 FLAMMABLE LIQUIDS - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
HNOC - Defatting irritant
Name %Classification
Composition/information on ingredients
Section 16. Other information
Hazardous Material Information System (U.S.A.)
3
03
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Date of previous issue 3/25/2022:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Organization that prepared
the SDS
:EHS
:::
:::2
2
0
( * ) - Chronic effects
United States Page: 12/13
ACETONEProduct name
8.03Product code Date of issue VersionQ3028 November 2022
Section 16. Other information
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Indicates information that has changed from previously issued version.
United States Page: 13/13
XYLENE
Not available.
Liquid.
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Section 1. Identification
:
:
:
Product code :Q80
Date of issue/Date of revision 28 November 2022
Version 12
Relevant identified uses of the substance or mixture and uses advised against
Coating. Paints. Painting-related materials.
Uses advised against Not applicable.
Product use :Industrial applications.
Use of the substance/
mixture
:
:
Manufacturer PPG Industries, Inc.
One PPG Place,
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
SETIQ Interior de la República: 800-00-214-00 (México)
SETIQ Ciudad de México: (55) 5559-1588 (México)
Emergency telephone
number
:
:
Technical Phone Number :1-800-647-6050
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the
substance or mixture
:
Hazard pictograms :
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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XYLENEProduct name
12Product code Date of issue VersionQ8028 November 2022
Section 2. Hazards identification
Signal word :Warning
Hazard statements :Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
Harmful if inhaled.
May cause respiratory irritation.
Suspected of causing cancer.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure. (hearing organs)
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or
in a well-ventilated area. Do not breathe vapor. Wash thoroughly after handling.
Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water. IF ON SKIN: Wash with plenty of water. If skin irritation
occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If
eye irritation persists: Get medical advice or attention.
Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep
cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label
elements
:Repeated exposure to high vapor concentrations may cause irritation of the respiratory
system and permanent brain and nervous system damage. Inhalation of vapor/aerosol
concentrations above the recommended exposure limits causes headaches,
drowsiness and nausea and may lead to unconsciousness or death. Avoid contact with
skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated.
Hazards not otherwise
classified
:Prolonged or repeated contact may dry skin and cause irritation.
Section 3. Composition/information on ingredients
xylene ≥75 - <85 1330-20-7
ethylbenzene ≥10 - ≤17 100-41-4
toluene <1.0 108-88-3
Ingredient name CAS number%
Substance/mixture :Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Product name XYLENE:
SUB codes represent substances without registered CAS Numbers.
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12Product code Date of issue VersionQ8028 November 2022
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :
:Ingestion
Skin contact :
:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
dryness
cracking
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids
apart for at least 10 minutes and seek immediate medical advice.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
Causes serious eye irritation.
Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.
Causes skin irritation. Defatting to the skin.
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12Product code Date of issue VersionQ8028 November 2022
Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon oxides
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the
container may burst, with the risk of a subsequent explosion. Runoff to sewer may
create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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XYLENEProduct name
12Product code Date of issue VersionQ8028 November 2022
Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store below the following temperature: 5°C (41°F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Avoid exposure during pregnancy. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Special precautions :If this material is part of a multiple component system, read the Safety Data Sheet(s) for
the other component or components before blending as the resulting mixture may have
the hazards of all of its parts.
United States Page: 5/15
XYLENEProduct name
12Product code Date of issue VersionQ8028 November 2022
xylene ACGIH TLV (United States, 1/2022). [xylene]
STEL: 651 mg/m³ 15 minutes.
TWA: 434 mg/m³ 8 hours.
TWA: 20 ppm 8 hours.
OSHA PEL (United States, 5/2018).
[Xylenes]
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
ethylbenzene ACGIH TLV (United States, 1/2022).
Ototoxicant.
TWA: 20 ppm 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
toluene OSHA PEL Z2 (United States, 2/2013).
AMP: 500 ppm 10 minutes.
CEIL: 300 ppm
TWA: 200 ppm 8 hours.
ACGIH TLV (United States, 1/2022).
Ototoxicant.
TWA: 20 ppm 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Control parameters
Individual protection measures
Occupational exposure limits
Recommended monitoring
procedures
:Reference should be made to appropriate monitoring standards. Reference to national
guidance documents for methods for the determination of hazardous substances will
also be required.
Key to abbreviations
A Acceptable Maximum Peak=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
TD =Total dust
Consult local authorities for acceptable exposure limits.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
STEL =
=
Short term Exposure limit values
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12Product code Date of issue VersionQ8028 November 2022
Section 8. Exposure controls/personal protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Skin protection
Other skin protection :
Chemical splash goggles.
Gloves For prolonged or repeated handling, use the following type of gloves:
Not recommended: nitrile rubber
Recommended: polyvinyl alcohol (PVA), Viton®
:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.
The respiratory protection shall be in accordance to 29 CFR 1910.134.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Not available.Odor
pH
Not available.Color
Auto-ignition temperature
Flash point
Not available.
Closed cup: 27.22°C (81°F)
Not applicable.
Not available.Odor threshold
:
:
:
:
:
:
:
:
Appearance
Boiling point :>37.78°C (>100°F)
Flammability :Not available.
Decomposition temperature :Not available.
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12Product code Date of issue VersionQ8028 November 2022
Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
0.87
Not available.
Not available.
Evaporation rate Not available.
Not applicable.
Viscosity Kinematic (40°C (104°F)): >21 mm2/s (>21 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
Lower and upper explosive
(flammable) limits
:Not available.
% Solid. (w/w):0
Density ( lbs / gal ):7.26
Volatility :100% (v/v), 100% (w/w)
Solubility(ies):Media Result
cold water Not soluble
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
The product is stable.Chemical stability :
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
When exposed to high temperatures may produce hazardous decomposition products.
Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
Refer to protective measures listed in sections 7 and 8.
Depending on conditions, decomposition products may include the following materials:
carbon oxides
Section 11. Toxicological information
Acute toxicity
Information on toxicological effects
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Section 11. Toxicological information
xylene LD50 Dermal Rabbit 1.7 g/kg -
LD50 Oral Rat 4.3 g/kg -
ethylbenzene LC50 Inhalation Vapor Rat 17.8 mg/l 4 hours
LD50 Dermal Rabbit 17.8 g/kg -
LD50 Oral Rat 3.5 g/kg -
toluene LC50 Inhalation Vapor Rat 49 g/m³4 hours
LD50 Dermal Rabbit 8.39 g/kg -
LD50 Oral Rat 5580 mg/kg -
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary :
Carcinogenicity
Conclusion/Summary :
Mutagenicity
Conclusion/Summary :
Teratogenicity
Conclusion/Summary :
Reproductive toxicity
Conclusion/Summary :
Irritation/Corrosion
xylene Skin - Moderate irritant Rabbit -24 hours 500
mg
-
Product/ingredient name Result Score Exposure Observation
Conclusion/Summary
Skin :
Eyes :
Respiratory :
Sensitization
Conclusion/Summary
Skin :
Respiratory :
Species
Specific target organ toxicity (single exposure)
Classification
xylene -3 -
ethylbenzene -2B -
toluene -3 -
Product/ingredient name NTPIARCOSHA
Carcinogen Classification code:
IARC: 1, 2A, 2B, 3, 4
NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen
OSHA: +
Not listed/not regulated: -
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
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Section 11. Toxicological information
Information on the likely routes of exposure
Specific target organ toxicity (repeated exposure)
Aspiration hazard
Name Result
xylene ASPIRATION HAZARD - Category 1
ethylbenzene ASPIRATION HAZARD - Category 1
toluene ASPIRATION HAZARD - Category 1
Potential acute health effects
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. Defatting to the skin.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
dryness
cracking
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Target organs :Contains material which causes damage to the following organs: brain.
Contains material which may cause damage to the following organs: blood, kidneys,
lungs, the nervous system, liver, upper respiratory tract, skin, central nervous system
(CNS), ears, eye, lens or cornea.
Name
xylene Category 3 -Respiratory tract
irritation
toluene Category 3 -Narcotic effects
Category Route of
exposure
Target organs
Name Category
ethylbenzene Category 2 -hearing organs
toluene Category 2 --
Route of
exposure
Target organs
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Section 11. Toxicological information
Conclusion/Summary :
General :
Carcinogenicity :
Mutagenicity :
Reproductive toxicity :
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Acute toxicity estimates
Potential immediate
effects
:
Short term exposure
Potential delayed effects :
Potential immediate
effects
:
Long term exposure
Potential delayed effects :
Ingestion Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
There are no data available on the mixture itself. Exposure to component solvent vapor
concentrations in excess of the stated occupational exposure limit may result in adverse
health effects such as mucous membrane and respiratory system irritation and adverse
effects on the kidneys, liver and central nervous system. Symptoms and signs include
headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases,
loss of consciousness. Solvents may cause some of the above effects by absorption
through the skin. There is some evidence that repeated exposure to organic solvent
vapors in combination with constant loud noise can cause greater hearing loss than
expected from exposure to noise alone. If splashed in the eyes, the liquid may cause
irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic
effects of components from short-term and long-term exposure by oral, inhalation and
dermal routes of exposure and eye contact.
May cause damage to organs through prolonged or repeated exposure. Prolonged or
repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
Suspected of damaging fertility or the unborn child.
No known significant effects or critical hazards.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Product/ingredient name
XYLENE 4174.2 2009.8 N/A 11.7 1.5
xylene 4300 1700 N/A 11 1.5
ethylbenzene 3500 17800 N/A 17.8 1.5
toluene 5580 8390 N/A 49 N/A
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm)
Inhalation
(vapors)
(mg/l)
Inhalation
(dusts and
mists) (mg/
l)
United States Page: 11/15
XYLENEProduct name
12Product code Date of issue VersionQ8028 November 2022
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
xylene 3.12 7.4 to 18.5 low
ethylbenzene 3.6 79.43 low
toluene 2.73 8.32 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
xylene --Readily
ethylbenzene --Readily
toluene --Readily
Toxicity
ethylbenzene Acute EC50 1.8 mg/l Fresh water Daphnia 48 hours
Chronic NOEC 1 mg/l Fresh water Daphnia - Ceriodaphnia dubia -
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
ethylbenzene -79 % - Readily - 10 days --
Product/ingredient name Test DoseResult Inoculum
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
United States Page: 12/15
XYLENEProduct name
12Product code Date of issue VersionQ8028 November 2022
14. Transport information
XYLENES
3
III
XYLENES
3
III
XYLENES
UN1307
3
III
UN1307 UN1307
DOT IMDG IATA
UN number
UN proper shipping
name
Transport hazard class
(es)
Packing group
Environmental hazards No.No.No.
Marine pollutant
substances
Not applicable.Not applicable.
RQ substances
118.22
(xylene, ethylbenzene)
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
Package sizes shipped in quantities less than the product reportable quantity are not subject to the
RQ (reportable quantity) transportation requirements.
None identified.
DOT
IMDG
:
:
IATA :None identified.
Product RQ (lbs)
Transport in bulk according
to IMO instruments
:Not applicable.
Section 15. Regulatory information
SARA 302/304
SARA 304 RQ :Not applicable.
Composition/information on ingredients
All components are active or exempted.United States inventory (TSCA 8b):
United States
U.S. Federal regulations :
No products were found.
SARA 311/312
United States Page: 13/15
XYLENEProduct name
12Product code Date of issue VersionQ8028 November 2022
Section 15. Regulatory information
SARA 313
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
California Prop. 65
Supplier notification
Chemical name
:xylene 1330-20-7 60 - 100
ethylbenzene 100-41-4 10 - 30
CAS number Concentration
Classification :FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
HNOC - Defatting irritant
xylene ≥75 - <85 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
ASPIRATION HAZARD - Category 1
ethylbenzene ≥10 - ≤17 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
HNOC - Defatting irritant
toluene <1.0 FLAMMABLE LIQUIDS - Category 2
SKIN IRRITATION - Category 2
TOXIC TO REPRODUCTION - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
HNOC - Defatting irritant
Name %Classification
Composition/information on ingredients
WARNING: Cancer and Reproductive Harm - www.P65Warnings.ca.gov.
United States Page: 14/15
XYLENEProduct name
12Product code Date of issue VersionQ8028 November 2022
Section 16. Other information
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Hazardous Material Information System (U.S.A.)
3
03
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Date of previous issue 6/20/2021:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Indicates information that has changed from previously issued version.
Organization that prepared
the SDS
:EHS
:::
:::2 *
2
0
( * ) - Chronic effects
United States Page: 15/15
LV
Performance and value for the
compliant market.
Performance and value from start to finish.
©2016 PPG Industries, Inc. All rights reserved.
The PPG Logo and Bringing innovation to the surface are registered trademarks, and OMNI and EuroPlus are trademarks of PPG Industries, Inc. Part No. OBBR001, 1/16
Performance
and value for
the compliant
market.
PPG Automotive Refinish
19699 Progress Drive
Strongsville, OH 44149
800.647.6050
PPG Canada Inc.
2301 Royal Windsor Drive, Unit #6
Mississauga, Ontario L5J 1K5
888.310.4762
Follow us online:
www.ppgrefinish.com
Clearcoats
MC2910 2.1 VOC EuroPlus Multi-Panel Clearcoat
MC2910 is ideal for multiple panels and overall repairs.
Easy-to-use compliant clear that delivers excellent gloss
finish. Easily adjusts to size and working conditions, with
choice of two hardeners.
PRODUCT CODE SIZE MIX RATIO RTS VOC PDS
Clearcoat MC2910 N5 2 : 1 1.95 OB58
Hardener MH2918 N2
Hardener MH2919 N2
MC730 2.1 VOC Production Clear
MC730 is economically priced, ideal for spot and panel
repairs. Easy to use and provides fast cycle time. Delivers
excellent flexibility, with choice of three hardeners.
PRODUCT CODE SIZE MIX RATIO RTS VOC PDS
Clearcoat MC730 04, 01 4 : 1 : 0.5 2.08 OB59
Hardener MH737 04
Hardener MH738 8Z, 04
Hardener MH739 04
Reducer MR295/296 04, 01
MC262 2.1 VOC Urethane Clear
MC262 is a 2.1 VOC, fast-drying, two-component, acrylic
urethane clear. This versatile clear can be used for spot
repairs or overall paint jobs.
PRODUCT CODE SIZE MIX RATIO RTS VOC PDS
Clearcoat MC262 04, 01 4 : 1 2.1 OB37
Hardener MH266 8Z, 04
Hardener MH267 8Z, 04
Hardener MH268 04
MC760 2.1 VOC Universal Clear
MC760 is a fast-drying, two-component 2.1 VOC universal clear
developed for production shops for use in either downdraft or cross
flow spray booths. MC760 delivers very good gloss and DOI.
PRODUCT CODE SIZE MIX RATIO RTS VOC PDS
Clearcoat MC760 01 4 : 1 : 1 2.08 OB52
Hardener MH267 8Z, 04
Hardener MH268 04
Reducer MR295/296
DESCRIPTION CODE SIZE
ORGANIC RED M104 04, 01
HIGH STRENGTH RED M105 04, 01
RED OXIDE M106 04, 01
TRANSPARENT RED OXIDE M108 04, 01
FINE RUSSET PEARL M109 4Z
VIOLET PEARL M110 4Z
TRANSPARENT YELLOW OXIDE M111 04, 01
GOLD M112NF 04, 01
YELLOW OXIDE M115 04, 01
RED SHADE YELLOW M116NF 04, 01
JET BLACK M117 01
TINTING BLACK M118 04, 01
HI HIDING WHITE M119 01
TINTING WHITE M120 04, 01
GREEN SHADE BLUE M121 04, 01
RED SHADE BLUE M122 04, 01
INDO BLUE M123 04, 01
MEDIUM BLUE M124 04, 01
MEDIUM ALUMINUM M125 04, 01
COARSE ALUMINUM M126 04, 01
MEDIUM BRIGHT ALUMINUM M127 04, 01
BLUE SHADE GREEN M128 04, 01
YELLOW SHADE GREEN M129 04, 01
QUINDO MAROON M131 04, 01
PERYLENE MAROON M132 04, 01
VIOLET M133 04, 01
QUINDO VIOLET M134NF 04, 01
FINE GREY ALUMINUM M135 04, 01
RED PEARL M141 4Z
WHITE PEARL M142 4Z
BLUE PEARL M143 4Z
GREEN PEARL M144 4Z
RED PEARL M145 4Z
COPPER PEARL M146 4Z
GOLD PEARL M147 4Z
FLATTING AGENT M148 04
MIXING CLEAR M149 01
ORGANIC YELLOW LF M152 04, 01
RED SHADE YELLOW LF M153 04
ORGANIC ORANGE LF M154 04
COARSE SILVER DOLLAR ALUMINUM M157 01
MICRONIZED WHITE M158 04
OMNI Compliant Toners OMNI Plus Toners
DESCRIPTION CODE SIZE
FINE WHITE PEARL M561 04
FINE BLUE PEARL M570 04
VIOLET M571 04
DEEP VIOLET M572 04
PERRINDO MAROON M573 04
BLUE (GREEN SHADE) M575 04
MAGENTA M576 04
TRANSPARENT RED OXIDE M577 04
GREEN (YELLOW SHADE) M578 04
INORGANIC YELLOW (GREEN SHADE) M581 04
RED (BLUE SHADE) M582 04
BLUE ALUMINUM M583 04
DEEP BASECOAT BLACK M589 01
FLATTENING BASE M590 04
FINE SATIN ALUMINUM M591 04
FINE BRIGHT ALUMINUM M592 04
EXTRA FINE ALUMINUM M593 04
VERY COARSE ALUMINUM M594 04, 01
GOLD ALUMINUM M596 04
ORANGE ALUMINUM M597 04
MIXING CLEAR M598 01
OMNI Plus Diamond Toners
DESCRIPTION CODE SIZE
SILVER DIAMONDS M551 AZ
GOLD DIAMONDS M552 AZ
RUSSET DIAMONDS M553 AZ
BLUE DIAMONDS M554 AZ
RED DIAMONDS M555 AZ
GREEN DIAMONDS M556 AZ
COPPER DIAMONDS M557 AZ
VIOLET DIAMONDS M558 AZ
OMNI Compliant Converters
DESCRIPTION CODE SIZE
MTX CONVERTER M728 01
MBX BASECOAT CONVERTER M736 01
MLX CONVERTER M743* 01
MBPX CONVERTER M799 01
THE OMNI COMPLIANT SYSTEM Performance and value for the compliant market.
CODE/DESCRIPTION SIZE CODE/DESCRIPTION SIZE
01 Gallon 4Z 4 Ounce
04 Quart 8Z 8 Ounce
05 5 Gallon AZ 12 Ounce
08 Pint N5 5 Liter
55 55 Gallon N2 2.5 Liter
Product Size Guide
*Not available in Canada
Cleaners/Solvent
MS151 0.21 VOC General Purpose Solvent
MS151 is a 100% virgin cleaning solvent with a VOC
composite partial pressure of 0.295 mmHg which meets low
vapor pressure restrictions in various California counties and
is used for clean up of spray guns and equipment.
PRODUCT SIZE
MS151 01, 05
Reducers
MR29X Compliant Reducers
MR29X low-VOC compliant reducers are used for thinning
basecoats, single stage topcoats, clears and primers in VOC
restricted areas.
PRODUCT SIZE
MR294 Fast 04, 01
MR295 Medium 04, 01
MR296 Slow 04, 01
MR297 Retarder 04
Undercoats
MP243 Polyester Primer
MP243 is a fast drying two-component, high build gray
polyester primer with excellent filling properties that can
be used over a wide variety of substrates. MP243 is lead-
and chromate-free and is ideal for use in areas where VOC
compliance is required. Once fully cured and sanded,
MP243 may be topcoated with all OMNI undercoats and
topcoats.
PRODUCT CODE SIZE MIX RATIO RTS VOC PDS
Primer MP243 01 1 qt : 1/2 oz 1.67 OB44
Hardener Included
MP80X 2.1 VOC Multi-Purpose Primer
MP80X is a fast-drying, two-component multi purpose 2.1
VOC primer which may be used as a primer surfacer or as a
wet-on-wet sealer when integrated with clearcoat. Available
in white (MP801), gray (MP802) and black (MP803).
PRODUCT CODE SIZE MIX RATIO RTS VOC PDS
Primer Surfacer MP80X 04, 01 4 : 1 : 2 2.1 OB48
Hardener MH810 8Z, 04
Primer Sealer MP80X 04, 01 3 : 1 : 1 : 1 2.1 OB48
(with OMNI clearcoats)
Reducer MR29X 04, 01
*See page 1 for the required compliant mixing system converters.
**Not available in Canada
Undercoats
MP831 2.1 VOC 1K Primer Surfacer
MP831 is a single-component, gray primer surfacer
designed for fast dry, easy build and sanding with good
adhesion and color holdout properties.
PRODUCT CODE SIZE MIX RATIO RTS VOC PDS
Primer Surfacer MP831 04 2 : 1 2.1 OB54
Reducer MP29X 04, 01
MP871 2.1 VOC Epoxy Primer
MP871 is a two-component, 2.1 VOC gray epoxy primer
designed to provide optimum adhesion and corrosion
resistance when applied over properly cleaned and sanded
bare metal, fiberglass and painted surfaces. MP871 can also
be used as a low VOC sealer.
PRODUCT CODE SIZE MIX RATIO RTS VOC PDS
Primer MP871 04 2 : 1 : 1 2.1 OB53
Hardener MP875 08
Reducer MR29X 04, 01
Sealer MP871 04 2 : 1 : 2 2.1
MP89X 2.1 VOC Urethane Sealer
MP89X 2.1 VOC Urethane Sealer is a fast-drying, two-
component sealer that delivers excellent topcoat holdout for
enhanced appearance. Compatible with a range of reducers,
MP89X can be tailored to meet individual production
conditions, such as temperature and job size. Available in
white (MP891), gray (MP895) and dark gray (MP897).
PRODUCT CODE SIZE MIX RATIO RTS VOC PDS
Primer MP89X 04, 01 4 : 1 : 1 2.1 OB56
Hardener MH810 8Z, 04
Reducer MR29X 04, 01
Topcoats*
MBPX OMNI Plus 3.5 VOC Acrylic Urethane Basecoat
MBPX OMNI Plus basecoat is the top-of-the-line OMNI
compliant basecoat, offering high hiding and prime color
match capability. Tri-coats are also available.
PRODUCT CODE SIZE MIX RATIO RTS VOC PDS
Color MBPX 08, 04, 01 1 : 1 3.5 OB49
Reducer MR29X 04, 01
MBX 3.5 VOC Acrylic Basecoat
MBX is a fast-drying, acrylic basecoat designed for today’s
automotive collision centers. For VOC compliance, MBX
must be topcoated with a compliant OMNI clearcoat.
PRODUCT CODE SIZE MIX RATIO RTS VOC PDS
Color MBX 08, 04, 01 1 : 1 3.5 OB45
Reducer MR29X 04, 01
MTX 2.8 VOC Single Stage
MTX is a low-VOC, fast-drying acrylic urethane single stage
topcoat designed for today’s automotive collision centers. It
is available in both solid and metallic colors.
PRODUCT CODE SIZE MIX RATIO RTS VOC PDS
Color MTX 08, 04, 01 4 : 1 : 2 2.8 OB47
Hardener MH238 8Z, 04
Reducer MR29X 04, 01
MLX 2.8 VOC Acrylic Enamel**
MLX is a 2.8 VOC fast, cost effective acrylic enamel topcoat.
Must be activated to meet 2.8 VOC lbs/gal.
PRODUCT CODE SIZE MIX RATIO RTS VOC PDS
Color MLX 08,04,01 4 : 1 : 1 2.8 OB50
Hardener MH238 8Z, 04
Reducer MR29X 04, 01
2/12/24, 9:44 AM State of Utah Mail - Solvents Used
https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-f:1790271374459215846&simpl=msg-f:17902713744592158…1/1
Daniel Riddle <[e-mail]>
Solvents Used
1 message
Kevin Sorensen <[e-mail]>Wed, Feb 7, 2024 at 12:57 PM
To: Daniel Riddle <[e-mail]>
Daniel,

Sorry this email response is not attached to the email you just sent me. I am having an issue with my emails today with
emails appearing and then disappearing. I simply can’t find the email you just sent me, good thing I read it and
remembered your question.

Attached is the solvent SDS sheet for the MS151 multi-purpose solvent we use. This is mainly used to wash and clean
paint guns, etc. It is used occasionally to clean a small area that needs to be touched up on a metal surface. Our main
metal prep process we use is a wheelabrator that cleans the surface of our dump bodies prior to applying a powder coat.

Hopefullly, this is the information you had asked for.

Thank You,
Kevin Sorensen
General Manager
Williamsen – Godwin Truck Body Co, LLC.
PH 801-973-9400
Fax [phone]

MS151.pdf
139K