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Home My WebLink AboutDAQ-2024-004984 DAQE-AN115980009-24 {{$d1 }} Brian Kliesch Quality Steel Corporation 2914 U.S. Highway 61 PO Box 249 Cleveland, MS 38732 BKliesch@propanetank.com Dear Mr. Kliesch: Re: Approval Order: Modification to Approval Order DAQE-AN115980008-18 to Increase the Hours of Operation and the VOC Emission Limit Project Number: N115980009 The attached Approval Order (AO) is issued pursuant to the Notice of Intent (NOI) received on June 14, 2022. Quality Steel Corporation must comply with the requirements of this AO, all applicable state requirements (R307), and Federal Standards. The project engineer for this action is Mr. Tim DeJulis, who can be contacted at (385) 306-6523 or tdejulis@utah.gov. Future correspondence on this AO should include the engineer's name as well as the DAQE number shown on the upper right-hand corner of this letter. No public comments were received on this action. Sincerely, {{$s }} Bryce C. Bird Director BCB:TD:jg cc: Salt Lake County Health Department 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 536-4414 www.deq.utah.gov Printed on 100% recycled paper State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director February 1, 2024 STATE OF UTAH Department of Environmental Quality Division of Air Quality {{#s=Sig_es_:signer1:signature}} {{#d1=date1_es_:signer1:date:format(date, "mmmm d, yyyy")}} {{#d2=date1_es_:signer1:date:format(date, "mmmm d, yyyy"):align(center)}} APPROVAL ORDER DAQE-AN115980009-24 Modification to Approval Order DAQE-AN115980008-18 to Increase the Hours of Operation and the VOC Emission Limit Prepared By Mr. Tim DeJulis, Engineer (385) 306-6523 tdejulis@utah.gov Issued to Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant Issued On {{$d2 }} Issued By {{$s }} Bryce C. Bird Director Division of Air Quality February 1, 2024 TABLE OF CONTENTS TITLE/SIGNATURE PAGE ....................................................................................................... 1 GENERAL INFORMATION ...................................................................................................... 3 CONTACT/LOCATION INFORMATION ............................................................................... 3 SOURCE INFORMATION ........................................................................................................ 3 General Description ................................................................................................................ 3 NSR Classification .................................................................................................................. 3 Source Classification .............................................................................................................. 3 Applicable Federal Standards ................................................................................................. 3 Project Description.................................................................................................................. 4 SUMMARY OF EMISSIONS .................................................................................................... 4 SECTION I: GENERAL PROVISIONS .................................................................................... 4 SECTION II: PERMITTED EQUIPMENT .............................................................................. 5 SECTION II: SPECIAL PROVISIONS ..................................................................................... 5 PERMIT HISTORY ..................................................................................................................... 8 ACRONYMS ................................................................................................................................. 9 DAQE-AN115980009-24 Page 3 GENERAL INFORMATION CONTACT/LOCATION INFORMATION Owner Name Source Name Quality Steel Corporation Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant Mailing Address Physical Address 2914 U.S. Highway 61 PO Box 249 5520 West Old Bingham Highway West Jordan, UT 84084 Cleveland, MS 38732 Source Contact UTM Coordinates Name: Brian Kliesch 413,558 m Easting Phone: (801) 280-1133 4,491,920 m Northing Email: BKliesch@propanetank.com Datum NAD83 UTM Zone 12 SIC code 3443 (Fabricated Plate Work (Boiler Shop)) SOURCE INFORMATION General Description Quality Steel Corporation (QSC) operates a steel fabrication plant in West Jordan, Salt Lake County. QSC makes large propane tanks. This involves cutting the steel for the tank, welding the pieces into the final form, priming the tanks, painting the dome components (where the nozzle connector is), and finishing with the top coat of paint. QSC will remove the painting of the dome components to an offsite, secondary vendor. NSR Classification Minor Modification at Minor Source Source Classification Located in Northern Wasatch Front O3 NAA, Salt Lake City UT PM2.5 NAA, Salt Lake County SO2 NAA Salt Lake County Airs Source Size: B Applicable Federal Standards MACT (Part 63), A: General Provisions MACT (Part 63), XXXXXX: National Emission Standards for Hazardous Air Pollutants Area Source Standards for Nine (9) Metal Fabrication and Finishing Source Categories DAQE-AN115980009-24 Page 4 Project Description QSC has requested a modification to AO DAQE-AN115980008-18, dated November 19, 2018, to increase the hours of operation from 2,500 hours per year to 3,500 hours per year. This increase in annual hours worked will increase the VOC emissions limitation from 45.01 tons per year to 49.30 tons per year. QSC will not be adding any pollution generating equipment or emission control equipment at this time. SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) CO2 Equivalent 0 2901.00 Carbon Monoxide 0 0.22 Nitrogen Oxides 0 1.01 Particulate Matter - PM10 0 4.60 Particulate Matter - PM2.5 0 4.60 Sulfur Dioxide 0 0.02 Volatile Organic Compounds 4.29 49.30 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) Xylenes (Isomers And Mixture) (CAS #1330207) 0 996 Change (TPY) Total (TPY) Total HAPs 0 0.50 SECTION I: GENERAL PROVISIONS I.1 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.2 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.3 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.4 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.5 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] DAQE-AN115980009-24 Page 5 I.6 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150] SECTION II: PERMITTED EQUIPMENT II.A THE APPROVED EQUIPMENT II.A.1 Fuel Storage Tank Manufacturing Plant II.A.2 One (1) Product Dryer Fuel Type: Natural Gas Heating Capacity: <5 MMBtu/hr II.A.3 Two (2) Paint Booths Identification: Prime, and Top Coat Attached Equipment: Paint arrestor filters 64 arrestor filters (Prime), and 64 arrestor filters (Top Coat) II.A.4 Various Equipment Items HVLP Spray Guns II.A.5 One (1) Shot Blaster Shot blaster with baghouse (GS-20 cartridge filter system) II.A.6 Plasma Cutter and Welding Operations One (1) dry plasma cutter Control device: dust collector Various welders SECTION II: SPECIAL PROVISIONS II.B REQUIREMENTS AND LIMITATIONS II.B.1 The Fuel Storage Tank Manufacturing Plant shall be subject to the following: II.B.1.a The owner/operator shall control process streams from the Prime and Top Coat paint booths with paint arrestor filters. All exhaust air from each paint booth shall be routed through a double filtered paint arrestor filter bank containing the full complement of filter panels before being vented to the atmosphere. [R307-401-8] DAQE-AN115980009-24 Page 6 II.B.1.b The paint booth stack heights shall be as follows: A. Four (4) Prime Stacks - 42 feet above grade each B. Four (4) Top Coat Stacks - 42 feet above grade each C. One (1) Dryer Stack - 38 feet above grade The nine (9) stacks shall be configured as unrestricted, vertically venting. [R307-401-8] II.B.1.c Visible emissions from any stationary point or fugitive emission source associated with the source or with the control facilities shall not exceed 10% opacity. [R307-401-8] II.B.1.c.1 Opacity observations of emissions from stationary sources shall be conducted in accordance with 40 CFR 60, Appendix A, Method 9. [R307-305-3] II.B.2 VOC Limitations II.B.2.a The owner/operator shall comply with the applicable requirements of R307-350 during operations. [R307-350] II.B.2.b The owner/operator shall not emit more than the following from evaporative sources (painting, printing, coating, and/or cleaning) on site: 49.30 tons per rolling 12-month period for VOCs 0.51 tons per rolling 12-month period for all HAPs combined. [R307-401-8] II.B.2.b.1 The owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. The owner/operator shall use a mass-balance method to calculate emissions from evaporative sources. The owner/operator may use the following equations with applicable units to comply with the mass-balance method: VOCs = [% VOCs by Weight/100] x [Density] x [Volume Consumed] HAPs = [% HAPs by Weight/100] x [Density] x [Volume Consumed]. [R307-401-8] DAQE-AN115980009-24 Page 7 II.B.2.c The owner/operator shall keep records each month of the following: A. The name (as per SDS) of the VOC- and HAP-emitting material B. The maximum percent by weight of VOCs and HAPs in each material used C. The density of each material used D. The volume of each VOC- and HAP-emitting material used E. The amount of VOCs- and HAPs-emitted from each material F. The amount of VOCs reclaimed and/or controlled from each material G. The total amount of VOCs emitted from all materials (in tons). [R307-401-8] II.B.2.d The owner/operator shall use a mass-balance method to quantify any amount of VOCs and HAPs reclaimed. The owner/operator shall subtract the amount of VOCs and HAPs reclaimed from the quantities calculated above to provide the monthly total emissions of VOCs and HAPs. [R307-401-8] II.B.3 Baghouses Limitation II.B.3.a The owner/operator shall use a baghouse to control particulate emissions from the shot blaster. [R307-401-8] II.B.3.b The owner/operator shall not allow visible emissions from the baghouse to exceed 10% opacity. [R307-401-8] II.B.3.b.1 The owner/operator shall install a manometer or magnehelic pressure gauge to measure the static pressure differential across the baghouse. [R307-401-8] II.B.3.b.2 The pressure gauge shall be located such that an inspector/operator can safely read the indicator at any time. [R307-401-8] II.B.3.b.3 The pressure gauge shall measure the static pressure differential in 0.5-inch water column increments or less. [R307-401-8] II.B.3.c During operation of the baghouse, the owner/operator shall maintain the static pressure differential across the baghouse between 0.5 and 6.0 inches of water column. [R307-401-8] II.B.3.c.1 The owner/operator shall record the static pressure differential at least once per operating day while the baghouse is operating. [R307-401-8] II.B.3.c.2 The owner/operator shall maintain the following records of the static pressure differential: A. Unit identification; B. Manufacturer recommended static pressure differential for the unit (if applicable); C. Weekly static pressure differential readings; D. Date of reading. [R307-401-8] DAQE-AN115980009-24 Page 8 II.B.3.d At least once every 12 months, the owner/operator shall calibrate the pressure gauge in accordance with the manufacturer's instructions or replace the pressure gauge. [R307-401-8] II.B.3.d.1 The owner/operator shall maintain records of the pressure gauge calibrations and replacements. [R307-401-8] PERMIT HISTORY This Approval Order shall supersede (if a modification) or will be based on the following documents: Supersedes AO DAQE-AN115980008-18 dated November 19, 2018 Is Derived From NOI dated June 14, 2022 Incorporates Additional information dated September 30, 2022 Incorporates Additional information dated October 5, 2022 Incorporates Additional information dated January 24, 2023 Incorporates Additional information dated February 6, 2023 Incorporates Additional information dated February 8, 2023 Incorporates Additional information dated March 23, 2023 Incorporates Additional information dated June 2, 2023 Incorporates Additional information dated November 16, 2023 DAQE-AN115980009-24 Page 9 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by Environmental Protection Agency to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - Title 40 of the Code of Federal Regulations Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal Division of Air Quality use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - Title 40 of the Code of Federal Regulations 52.21 (b)(49)(i) GWP Global Warming Potential - Title 40 of the Code of Federal Regulations Part 86.1818- 12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds DAQE-IN115980009-23 December 21, 2023 Brian Kliesch Quality Steel Corporation 2914 U.S. Highway 61 PO Box 249 Cleveland, MS 38732 BKliesch@propanetank.com Dear Mr. Kliesch: Re: Intent to Approve: Modification to Approval Order DAQE-AN115980008-18 to Increase the Hours of Operation and the VOC Emission Limit Project Number: N115980009 The attached document is the Intent to Approve (ITA) for the above-referenced project. The ITA is subject to public review. Any comments received shall be considered before an Approval Order (AO) is issued. The Division of Air Quality is authorized to charge a fee for reimbursement of the actual costs incurred in the issuance of an AO. An invoice will follow upon issuance of the final AO. Future correspondence on this ITA should include the engineer's name, Mr. Tim DeJulis, as well as the DAQE number as shown on the upper right-hand corner of this letter. Mr. Tim DeJulis, can be reached at (385) 306-6523 or tdejulis@utah.gov, if you have any questions. Sincerely, {{$s }} Alan D. Humpherys, Manager New Source Review Section ADH:TD:jg cc: Salt Lake County Health Department 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 536-4414 www.deq.utah.gov Printed on 100% recycled paper State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director STATE OF UTAH Department of Environmental Quality Division of Air Quality INTENT TO APPROVE DAQE-IN115980009-23 Modification to Approval Order DAQE-AN115980008-18 to Increase the Hours of Operation and the VOC Emission Limit Prepared By Mr. Tim DeJulis, Engineer (385) 306-6523 tdejulis@utah.gov Issued to Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant Issued On December 21, 2023 {{$s }} New Source Review Section Manager Alan D. Humpherys {{#s=Sig_es_:signer1:signature}} TABLE OF CONTENTS TITLE/SIGNATURE PAGE ....................................................................................................... 1 GENERAL INFORMATION ...................................................................................................... 3 CONTACT/LOCATION INFORMATION ............................................................................... 3 SOURCE INFORMATION ........................................................................................................ 3 General Description ................................................................................................................ 3 NSR Classification .................................................................................................................. 3 Source Classification .............................................................................................................. 3 Applicable Federal Standards ................................................................................................. 3 Project Description.................................................................................................................. 3 SUMMARY OF EMISSIONS .................................................................................................... 4 PUBLIC NOTICE STATEMENT............................................................................................... 4 SECTION I: GENERAL PROVISIONS .................................................................................... 4 SECTION II: PERMITTED EQUIPMENT .............................................................................. 5 SECTION II: SPECIAL PROVISIONS ..................................................................................... 6 PERMIT HISTORY ..................................................................................................................... 8 ACRONYMS ................................................................................................................................. 9 DAQE-IN115980009-23 Page 3 GENERAL INFORMATION CONTACT/LOCATION INFORMATION Owner Name Source Name Quality Steel Corporation Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant Mailing Address Physical Address 2914 U.S. Highway 61 PO Box 249 5520 West Old Bingham Highway West Jordan, UT 84084 Cleveland, MS 38732 Source Contact UTM Coordinates Name Brian Kliesch 413,558 m Easting Phone (801) 280-1133 4,491,920 m Northing Email BKliesch@propanetank.com Datum NAD83 UTM Zone 12 SIC code 3443 (Fabricated Plate Work (Boiler Shop)) SOURCE INFORMATION General Description Quality Steel Company (QSC) operates a steel fabrication plant in West Jordan, Salt Lake County. QSC makes large propane tanks. This involves cutting the steel for the tank, welding the pieces into the final form, priming the tanks, painting the dome components (where the nozzle connector is), and finishing with the top coat of paint. QSC will remove the painting of the dome components to an offsite, secondary vendor. NSR Classification Minor Modification at Minor Source Source Classification Located in Northern Wasatch Front O3 NAA, Salt Lake City UT PM2.5 NAA, Salt Lake County SO2 NAA Salt Lake County Airs Source Size: B Applicable Federal Standards MACT (Part 63), A: General Provisions MACT (Part 63), XXXXXX: National Emission Standards for Hazardous Air Pollutants Area Source Standards for Nine Metal Fabrication and Finishing Source Categories Project Description QSC has requested a modification to AO DAQE-AN115980008-18, dated November 19, 2018, to increase the hours of operation from 2,500 hours per year to 3,500 hours per year. This increase in annual DAQE-IN115980009-23 Page 4 hours worked will increase the VOC emissions limitation from 45.01 tons per year to 49.30 tons per year. QSC will not be adding any pollution generating equipment or emission control equipment at this time. SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) CO2 Equivalent 0 2901.00 Carbon Monoxide 0 0.22 Nitrogen Oxides 0 1.01 Particulate Matter - PM10 0 4.60 Particulate Matter - PM2.5 0 4.60 Sulfur Dioxide 0 0.02 Volatile Organic Compounds 4.29 49.30 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) Xylenes (Isomers And Mixture) (CAS #1330207) 996 Change (TPY) Total (TPY) Total HAPs 0.50 PUBLIC NOTICE STATEMENT The NOI for the above-referenced project has been evaluated and has been found to be consistent with the requirements of UAC R307. Air pollution producing sources and/or their air control facilities may not be constructed, installed, established, or modified prior to the issuance of an AO by the Director. A 30-day public comment period will be held in accordance with UAC R307-401-7. A notification of the intent to approve will be published in the Salt Lake Tribune and Deseret News on December 24, 2023. During the public comment period the proposal and the evaluation of its impact on air quality will be available for the public to review and provide comment. If anyone so requests a public hearing within 15 days of publication, it will be held in accordance with UAC R307-401-7. The hearing will be held as close as practicable to the location of the source. Any comments received during the public comment period and the hearing will be evaluated. The proposed conditions of the AO may be changed as a result of the comments received. SECTION I: GENERAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. I.1 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] DAQE-IN115980009-23 Page 5 I.2 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.3 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.4 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.5 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.6 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150] SECTION II: PERMITTED EQUIPMENT The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. II.A THE APPROVED EQUIPMENT II.A.1 Fuel Storage Tank Manufacturing Plant II.A.2 One (1) Product Dryer Fuel Type: Natural Gas Heating Capacity: <5 MMBtu/hr II.A.3 Two (2) Paint Booths Identification: Prime, and Top Coat Attached Equipment: Paint arrestor filters 64 arrestor filters (Prime), and 64 arrestor filters (Top Coat) II.A.4 Various Equipment Items HVLP Spray Guns II.A.5 One (1) Shot Blaster Shot blaster with baghouse (GS-20 cartridge filter system) DAQE-IN115980009-23 Page 6 II.A.6 Plasma Cutter and Welding Operations One (1) dry plasma cutter Control device: dust collector Various welders SECTION II: SPECIAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. II.B REQUIREMENTS AND LIMITATIONS II.B.1 The Fuel Storage Tank Manufacturing Plant shall be subject to the following: II.B.1.a The owner/operator shall control process streams from the Prime and Top Coat paint booths with paint arrestor filters. All exhaust air from each paint booth shall be routed through a double filtered paint arrestor filter bank containing the full complement of filter panels before being vented to the atmosphere. [R307-401-8] II.B.1.b The paint booth stack heights shall be as follows: A. Four (4) Prime Stacks - 42 feet above grade each B. Four (4) Top Coat Stacks - 42 feet above grade each C. One (1) Dryer Stack - 38 feet above grade The nine (9) stacks shall be configured as unrestricted, vertically venting. [R307-401-8] II.B.1.c Visible emissions from any stationary point or fugitive emission source associated with the source or with the control facilities shall not exceed 10% opacity. [R307-401-8] II.B.1.c.1 Opacity observations of emissions from stationary sources shall be conducted in accordance with 40 CFR 60, Appendix A, Method 9. [R307-305-3] II.B.2 VOC Limitations II.B.2.a The owner/operator shall comply with the applicable requirements of R307-350 during operations. [R307-350] II.B.2.b The owner/operator shall not emit more than the following from evaporative sources (painting, printing, coating, and/or cleaning) on site: 49.30 tons per rolling 12-month period for VOCs 0.51 tons per rolling 12-month period for all HAPs combined. [R307-401-8] DAQE-IN115980009-23 Page 7 II.B.2.b.1 The owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. The owner/operator shall use a mass-balance method to calculate emissions from evaporative sources. The owner/operator may use the following equations with applicable units to comply with the mass-balance method: VOCs = [% VOCs by Weight/100] x [Density] x [Volume Consumed] HAPs = [% HAPs by Weight/100] x [Density] x [Volume Consumed] [R307-401-8] II.B.2.c The owner/operator shall keep records each month of the following: A. The name (as per SDS) of the VOC- and HAP-emitting material B. The maximum percent by weight of VOCs and HAPs in each material used C. The density of each material used D. The volume of each VOC- and HAP-emitting material used E. The amount of VOCs- and HAPs-emitted from each material F. The amount of VOCs reclaimed and/or controlled from each material G. The total amount of VOCs emitted from all materials (in tons). [R307-401-8] II.B.2.d The owner/operator shall use a mass-balance method to quantify any amount of VOCs and HAPs reclaimed. The owner/operator shall subtract the amount of VOCs and HAPs reclaimed from the quantities calculated above to provide the monthly total emissions of VOCs and HAPs. [R307-401-8] II.B.3 Baghouses Limitation II.B.3.a The owner/operator shall use a baghouse to control particulate emissions from the shot blaster. [R307-401-8] II.B.3.b The owner/operator shall not allow visible emissions from the baghouse to exceed 10% opacity. [R307-401-8] II.B.3.b.1 The owner/operator shall install a manometer or magnehelic pressure gauge to measure the static pressure differential across the baghouse. [R307-401-8] II.B.3.b.2 The pressure gauge shall be located such that an inspector/operator can safely read the indicator at any time. [R307-401-8] II.B.3.b.3 The pressure gauge shall measure the static pressure differential in 0.5-inch water column increments or less. [R307-401-8] II.B.3.c During operation of the baghouse, the owner/operator shall maintain the static pressure differential across the baghouse between 0.5 and 6.0 inches of water column. [R307-401-8] II.B.3.c.1 The owner/operator shall record the static pressure differential at least once per operating day while the baghouse is operating. [R307-401-8] DAQE-IN115980009-23 Page 8 II.B.3.c.2 The owner/operator shall maintain the following records of the static pressure differential: A. Unit identification; B. Manufacturer recommended static pressure differential for the unit (if applicable); C. Weekly static pressure differential readings; D. Date of reading. [R307-401-8] II.B.3.d At least once every 12 months, the owner/operator shall calibrate the pressure gauge in accordance with the manufacturer's instructions or replace the pressure gauge. [R307-401-8] II.B.3.d.1 The owner/operator shall maintain records of the pressure gauge calibrations and replacements. [R307-401-8] PERMIT HISTORY This Approval Order shall supersede (if a modification) or will be based on the following documents: Supersedes AO DAQE-AN115980008-18 dated November 19, 2018 Is Derived From NOI dated June 14, 2022 Incorporates Additional information dated September 30, 2022 Incorporates Additional information dated October 5, 2022 Incorporates Additional information dated January 24, 2023 Incorporates Additional information dated February 6, 2023 Incorporates Additional information dated February 8, 2023 Incorporates Additional information dated March 23, 2023 Incorporates Additional information dated June 2, 2023 Incorporates Additional information dated November 16, 2023 DAQE-IN115980009-23 Page 9 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by Environmental Protection Agency to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - Title 40 of the Code of Federal Regulations Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal Division of Air Quality use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - Title 40 of the Code of Federal Regulations 52.21 (b)(49)(i) GWP Global Warming Potential - Title 40 of the Code of Federal Regulations Part 86.1818- 12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds 12/21/23, 10:08 AM State of Utah Mail - Legal Notice to be published December 24, 2023 https://mail.google.com/mail/u/0/?ik=b4fd0e1085&view=pt&search=all&permmsgid=msg-f:1785910329969870275&simpl=msg-f:1785910329969870275 1/1 Jeree Greenwood <jereeg@utah.gov> Legal Notice to be published December 24, 2023 Rylie Stegman <rstegman@sltrib.com>Thu, Dec 21, 2023 at 9:40 AM To: Jeree Greenwood <jereeg@utah.gov> Good morning! You are all set with ad number SLT0025568! [Quoted text hidden] -- Rylie Stegman (She/Her) Advertising Account Executive M: (801) 237.2000 90 S. 400 W. SLC, UT. 84101 STE. 600 Support The Tribune | Subscribe Today! DAQE-NN115980009-23 December 21, 2023 Salt Lake Tribune and Deseret News Legal Advertising Dept. P.O. Box 704055 West Valley City, UT 84170 Acct #9001399880 RE: Legal Notice of Intent to Approve This letter will confirm the authorization to publish the attached NOTICE in the Salt Lake Tribune and Deseret News on December 24, 2023. Please mail the invoice and affidavit of publication to the Utah State Department of Environmental Quality, Division of Air Quality, P.O. Box 144820, Salt Lake City, Utah 84114-4820. If you have any questions, contact Jeree Greenwood, who may be reached at (385) 306-6514. Sincerely, {{$s }} Jeree Greenwood Office Technician Enclosure cc: Salt Lake County cc: Wasatch Front Regional Council 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 903-3978 www.deq.utah.gov Printed on 100% recycled paper State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director DAQE-NN115980009-23 Page 2 NOTICE A Notice of Intent for the following project submitted in accordance with R307-401-1, Utah Administrative Code (UAC), has been received for consideration by the Director: Company Name: Quality Steel Corporation Location: Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant – 5520 W. Old Bingham Highway, West Jordan, UT Project Description: Quality Steel Corporation has requested a modification to Approval Order DAQE-AN115980008-18, dated November 19, 2018, to increase the hours of operation from 2,500 hours per year to 3,500 hours per year. This increase in annual hours worked will increase the Volatile organic compounds emissions limitation from 45.01 tons per year to 49.30 tons per year. Quality Steel Corporation will not be adding any pollution generating equipment or emission control equipment at this time. The completed engineering evaluation and air quality impact analysis showed the proposed project meets the requirements of federal air quality regulations and the State air quality rules. The Director intends to issue an Approval Order pending a 30-day public comment period. The project proposal, estimate of the effect on local air quality and draft Approval Order are available for public inspection and comment at the Utah Division of Air Quality, 195 North 1950 West, Salt Lake City, UT 84116. Written comments received by the Division at this same address on or before January 23, 2024 will be considered in making the final decision on the approval/disapproval of the proposed project. Email comments will also be accepted at tdejulis@utah.gov. If anyone so requests to the Director in writing within 15 days of publication of this notice, a hearing will be held in accordance with R307-401-7, UAC. Under Section 19-1-301.5, a person who wishes to challenge a Permit Order may only raise an issue or argument during an adjudicatory proceeding that was raised during the public comment period and was supported with sufficient information or documentation to enable the Director to fully consider the substance and significance of the issue. Date of Notice: December 24, 2023 {{#s=Sig_es_:signer1:signature}} DAQE- RN115980009 December 14, 2023 Brian Kliesch Quality Steel Corporation PO Box 249 2914 U.S. Highway 61 Cleveland, MS 38732 BKliesch@propanetank.com Dear Brian Kliesch, Re: Engineer Review: Modification to DAQE-AN115980008-18 to Increase the Hours of Operation and the VOC Emission Limit Project Number: N115980009 The DAQ requests a company representative review and sign the attached Engineer Review (ER). This ER identifies all applicable elements of the New Source Review permitting program. Quality Steel Corporation should complete this review within 10 business days of receipt. Quality Steel Corporation should contact Mr. Tim DeJulis at (385) 306-6523 if there are questions or concerns with the review of the draft permit conditions. Upon resolution of your concerns, please email Mr. Tim DeJulis at tdejulis@utah.gov the signed cover letter. Upon receipt of the signed cover letter, the DAQ will prepare an ITA for a 30-day public comment period. At the completion of the comment period, the DAQ will address any comments and will prepare an Approval Order (AO) for signature by the DAQ Director. If Quality Steel Corporation does not respond to this letter within 10 business days, the project will move forward without source concurrence. If Quality Steel Corporation has concerns that cannot be resolved and the project becomes stagnant, the DAQ Director may issue an Order prohibiting construction. Approval Signature _____________________________________________________________ (Signature & Date) 195 North 1950 West • Salt Lake City, UT Mailing Address: P.O. Box 144820 • Salt Lake City, UT 84114-4820 Telephone (801) 536-4000 • Fax (801) 536-4099 • T.D.D. (801) 903-3978 www.deq.utah.gov Printed on 100% recycled paper Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF AIR QUALITY Bryce C. Bird Director State of Utah SPENCER J. COX Governor DEIDRE HENDERSON Lieutenant Governor Engineer Review N115980009: Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant December 14, 2023 Page 1 UTAH DIVISION OF AIR QUALITY ENGINEER REVIEW SOURCE INFORMATION Project Number N115980009 Owner Name Quality Steel Corporation Mailing Address PO Box 249 2914 U.S. Highway 61 Cleveland, MS, 38732 Source Name Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant Source Location 5520 W. Old Bingham Highway West Jordan, UT 84084 UTM Projection 413,558 m Easting, 4,491,920 m Northing UTM Datum NAD83 UTM Zone UTM Zone 12 SIC Code 3443 (Fabricated Plate Work (Boiler Shop)) Source Contact Brian Kliesch Phone Number (801) 280-1133 Email BKliesch@propanetank.com Billing Contact Brian Kliesch Phone Number (801) 280-1133 Email BKliesch@propanetank.com Project Engineer Mr. Tim DeJulis, Engineer Phone Number (385) 306-6523 Email tdejulis@utah.gov Notice of Intent (NOI) Submitted June 14, 2022 Date of Accepted Application October 5, 2022 Engineer Review N115980009: Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant December 14, 2023 Page 2 SOURCE DESCRIPTION General Description Quality Steel Company (QSC) operates a steel fabrication plant in West Jordan, Salt Lake County. QSC makes large propane tanks. This involves cutting the steel for the tank, welding the pieces into the final form, priming the tanks, painting the dome components (where the nozzle connector is), and finishing with the top coat of paint. QSC will remove the painting of the dome components to an offsite, secondary vendor. NSR Classification: Minor Modification at Minor Source Source Classification Located in Northern Wasatch Front O3 NAA, Salt Lake City UT PM2.5 NAA, Salt Lake County SO2 NAA Salt Lake County Airs Source Size: B Applicable Federal Standards MACT (Part 63), A: General Provisions MACT (Part 63), XXXXXX: National Emission Standards for Hazardous Air Pollutants Area Source Standards for Nine Metal Fabrication and Finishing Source Categories Project Proposal Modification to DAQE-AN115980008-18 to Increase the Hours of Operation and the VOC Emission Limit Project Description QSC has requested a modification to DAQE-AN115980008-18, dated November 19, 2018 to increase the hours of operation from 2,500 hours per year to 3,500 hours per year. This increase in annual hours worked will increase the VOC emissions limitation from 45.01 tons per year to 49.30 tons per year. QSC will not be adding any pollution generating equipment or emission control equipment at this time. EMISSION IMPACT ANALYSIS All criteria pollutants are below the modeling thresholds contained in R307-410-4. All HAP emissions are below their respective emission threshold values in R307-410-5. Therefore, no modeling is required from this source. [Last updated October 19, 2022] Engineer Review N115980009: Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant December 14, 2023 Page 3 SUMMARY OF EMISSIONS The emissions listed below are an estimate of the total potential emissions from the source. Some rounding of emissions is possible. Criteria Pollutant Change (TPY) Total (TPY) CO2 Equivalent 0 2901.00 Carbon Monoxide 0 0.22 Nitrogen Oxides 0 1.01 Particulate Matter - PM10 0 4.60 Particulate Matter - PM2.5 0 4.60 Sulfur Dioxide 0 0.02 Volatile Organic Compounds 4.29 49.30 Hazardous Air Pollutant Change (lbs/yr) Total (lbs/yr) Xylenes (Isomers And Mixture) (CAS #1330207) 996 Change (TPY) Total (TPY) Total HAPs 0.50 Note: Change in emissions indicates the difference between previous AO and proposed modification. Engineer Review N115980009: Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant December 14, 2023 Page 4 Review of BACT for New/Modified Emission Units 1. BACT review regarding Process Equipment QSC has evaluated the control of the additional hours of operation to create new propane storage tanks. The hours of operations will go from 2,500 hrs/yr to 3,500 hrs/yr. PM10/PM2.5 The increase in the annual hours of operation, will increase the PM10/PM2.5 emissions. The PM10/PM2.5 comes from welding, plasma cutting, and the shot blaster. Welding is an uncontrolled emission source. Based on the additional PM10/PM2.5 emissions from the extra hours of operation, control of the welding activity emissions is economically infeasible. The plasma cutting and shot blaster emission sources will continue to use the existing baghouses to control the emissions from the plant. Since the baghouses (99.99% control in the first and 99.97% control in the second) are already installed; therefore, use of the baghouses is economically feasible. This is considered BACT. VOC The increase in the annual hours of operation will increase the VOC emissions. The VOC comes from the paint booths and the spray guns. Each separate paint booth would require a separate control rather than a combined control. The control options, according to the RBLC, use of a low VOC coating material; using water-based coatings; using less coating material for each unit; using powder coating; using condensers, adsorption, UV oxidation, flares, biofiltration, membrane separation technologies, and non-thermal plasma technologies are technically infeasible. The control options, according to the RBLC, of a regenerative thermal oxidizer (RTO), a fixed bed catalytic oxidizer (FBCO), or a regenerative catalytic oxidizer (RCO) are technically feasible. Use of two RTO units is economically infeasible. Use of two FBCO units are economically infeasible. Use of two RCO units are economically infeasible. QSC will use the existing control option of allowing the VOC containing emissions to flow to the atmosphere without a control. [Last updated November 27, 2023] SECTION I: GENERAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): I.1 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.2 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.3 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] Engineer Review N115980009: Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant December 14, 2023 Page 5 I.4 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.5 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.6 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307- 401-4] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307- 150] SECTION II: PERMITTED EQUIPMENT The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.A THE APPROVED EQUIPMENT II.A.1 Fuel Storage Tank Manufacturing Plant II.A.2 One (1) Product Dryer Fuel Type: Natural Gas Heating Capacity: <5 MMBtu/hr II.A.3 Two (2) Paint Booths Identification: Prime, and Top Coat Attached Equipment: Paint arrestor filters 64 arrestor filters (Prime), and 64 arrestor filters (Top Coat) II.A.4 Various Equipment Items HVLP Spray Guns II.A.5 One (1) Shot Blaster Shot blaster with baghouse (GS-20 cartridge filter system) Engineer Review N115980009: Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant December 14, 2023 Page 6 II.A.6 Plasma Cutter and Welding Operations One (1) dry plasma cutter Control device: dust collector Various welders SECTION II: SPECIAL PROVISIONS The intent is to issue an air quality AO authorizing the project with the following recommended conditions and that failure to comply with any of the conditions may constitute a violation of the AO. (New or Modified conditions are indicated as “New” in the Outline Label): II.B REQUIREMENTS AND LIMITATIONS II.B.1 The Fuel Storage Tank Manufacturing Plant shall be subject to the following: II.B.1.a NEW The owner/operator shall control process streams from the Prime and Top Coat paint booths with paint arrestor filters. All exhaust air from each paint booth shall be routed through a double filtered paint arrestor filter bank containing the full complement of filter panels before being vented to the atmosphere. [R307-401-8] II.B.1.b NEW The paint booth stack heights shall be as follows: A. Four (4) Prime Stacks - 42 feet above grade each B. Four (4) Top Coat Stacks - 42 feet above grade each C. One (1) Dryer Stack - 38 feet above grade The nine (9) stacks shall be configured as unrestricted, vertically venting. [R307-401-8] II.B.1.c Visible emissions from any stationary point or fugitive emission source associated with the source or with the control facilities shall not exceed 10% opacity. [R307-401-8] II.B.1.c.1 Opacity observations of emissions from stationary sources shall be conducted in accordance with 40 CFR 60, Appendix A, Method 9. [R307-305-3] II.B.2 VOC Limitations II.B.2.a NEW The owner/operator shall comply with the applicable requirements of R307-350 during operations. [R307-350] Engineer Review N115980009: Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant December 14, 2023 Page 7 II.B.2.b NEW The owner/operator shall not emit more than the following from evaporative sources (painting, printing, coating, and/or cleaning) on site: 49.30 tons per rolling 12-month period for VOCs 0.51 tons per rolling 12-month period for all HAPs combined. [R307-401-8] II.B.2.b.1 NEW The owner/operator shall calculate a new 12-month total by the 20th day of each month using data from the previous 12 months. The owner/operator shall use a mass-balance method to calculate emissions from evaporative sources. The owner/operator may use the following equations with applicable units to comply with the mass-balance method: VOCs = [% VOCs by Weight/100] x [Density] x [Volume Consumed] HAPs = [% HAPs by Weight/100] x [Density] x [Volume Consumed]. [R307-401-8] II.B.2.c NEW The owner/operator shall keep records each month of the following: A. The name (as per SDS) of the VOC- and HAP-emitting material B. The maximum percent by weight of VOCs and HAPs in each material used C. The density of each material used D. The volume of each VOC- and HAP-emitting material used E. The amount of VOCs- and HAPs-emitted from each material F. The amount of VOCs reclaimed and/or controlled from each material G. The total amount of VOCs emitted from all materials (in tons). [R307-401-8] II.B.2.d NEW The owner/operator shall use a mass-balance method to quantify any amount of VOCs and HAPs reclaimed. The owner/operator shall subtract the amount of VOCs and HAPs reclaimed from the quantities calculated above to provide the monthly total emissions of VOCs and HAPs. [R307-401-8] II.B.3 Baghouses Limitation II.B.3.a NEW The owner/operator shall use a baghouse to control particulate emissions from the shot blaster. [R307-401-8] II.B.3.b NEW The owner/operator shall not allow visible emissions from the baghouse to exceed 10% opacity. [R307-401-8] Engineer Review N115980009: Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant December 14, 2023 Page 8 II.B.3.b.1 NEW The owner/operator shall install a manometer or magnehelic pressure gauge to measure the static pressure differential across the baghouse. [R307-401-8] II.B.3.b.2 NEW The pressure gauge shall be located such that an inspector/operator can safely read the indicator at any time. [R307-401-8] II.B.3.b.3 NEW The pressure gauge shall measure the static pressure differential in 0.5-inch water column increments or less. [R307-401-8] II.B.3.c NEW During operation of the baghouse, the owner/operator shall maintain the static pressure differential across the baghouse between 0.5 and 6.0 inches of water column. [R307-401-8] II.B.3.c.1 NEW The owner/operator shall record the static pressure differential at least once per operating day while the baghouse is operating. [R307-401-8] II.B.3.c.2 NEW The owner/operator shall maintain the following records of the static pressure differential: A. Unit identification; B. Manufacturer recommended static pressure differential for the unit (if applicable); C. Weekly static pressure differential readings; D. Date of reading. [R307-401-8] II.B.3.d NEW At least once every 12 months, the owner/operator shall calibrate the pressure gauge in accordance with the manufacturer's instructions or replace the pressure gauge. [R307-401-8] II.B.3.d.1 NEW The owner/operator shall maintain records of the pressure gauge calibrations and replacements. [R307-401-8] Engineer Review N115980009: Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant December 14, 2023 Page 9 PERMIT HISTORY When issued, the approval order shall supersede (if a modification) or will be based on the following documents: Supersedes DAQE-AN115980008-18 dated November 19, 2018 Is Derived From NOI dated June 14, 2022 Incorporates Additional information dated September 30, 2022 Incorporates Additional information dated October 5, 2022 Incorporates Additional information dated January 24, 2023 Incorporates Additional information dated February 6, 2023 Incorporates Additional information dated February 8, 2023 Incorporates Additional information dated March 23, 2023 Incorporates Additional information dated June 2, 2023 Incorporates Additional information dated November 16, 2023 REVIEWER COMMENTS 1. Comment regarding Emission Estimates: The welding emission estimates are by AP-42 Section 12.19 The shot blaster emission estimates are by based on the amount of material sent to each shot blaster with a control efficiency The plasma cutter emission estimates are based on AP-42 Section 12.19 The spray booth emission estimates are based on a material balance of the materials used for applying the coatings to the finished products and the amount used to coat each product. [Last updated March 15, 2023] 2. Comment regarding NSPS and MACT : NSPS 40 CFR 60 does not apply to this plant. This plant is subject to MACT standard 40 CFR 63. MACT Subpart MMMM applies to the metal components of the following product categories: motor vehicle parts and accessories, bicycles and sporting goods, recreational vehicles, extruded aluminum structural components, railroad cars, heavy duty trucks, medical equipment, lawn and garden equipment, electronic equipment, magnet wire, steel drums, industrial machinery, metal pipes, and numerous other industrial, household, and consumer products. The source applies if the surface coating materials used at a rate of more than 250 gallons (946 liters) of materials containing HAPs at a major source. Quality Steel uses more than 250 gallons of material containing HAPs. The limits for existing HAP containing chemicals are 2.6 lbs/gal each, for general use coatings. These individual limits in each coating material, for xylene and MMA emissions, are below the 2.6 lbs/gal emissions value. This is a minor source though. This subpart does not apply to the source. MACT Subpart HHHHHH, applies to the following source categories: (a) Paint stripping operations that involve the use of chemical strippers that contain methylene chloride (MeCl), Chemical Abstract Service number 75092, in paint removal processes; (b) Autobody refinishing operations that encompass motor vehicle and mobile equipment spray- applied surface coating operations; Engineer Review N115980009: Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant December 14, 2023 Page 10 (c) Spray application of coatings containing compounds of chromium (Cr), lead (Pb), manganese (Mn), nickel (Ni), or cadmium (Cd), collectively referred to as the target HAP to any part or product made of metal or plastic, or combinations of metal and plastic that are not motor vehicles or mobile equipment. The activities taking place at this source are NOT subject to Subpart HHHHHH because they do not coat with materials containing Cr, Pb, Mn, Ni, or Cd . MACT Standard Subpart XXXXXX applies to this plant. 40 CFR 63.11514(b)(5) is the applicable standard. The welding activity taking place at this source is subject to the Subpart XXXXXX. Due to the composition of Chromium in the steel, metal fabrication HAP (MFHAP) being used at the plant, they are subject to this MACT Standard. The MFHAP of Chromium is greater than 0.1 percent by weight, therefore this subpart applies. [Last updated December 14, 2023] 3. Comment regarding Title V Applicability: Title V of the 1990 Clean Air Act (Title V) applies to the following: 1. Any major source 2. Any source subject to a standard, limitation, or other requirement under Section 111 of the Act, Standards of Performance for New Stationary Sources; 3. Any source subject to a standard or other requirement under Section 112 of the Act, Hazardous Air Pollutants. 4. Any Title IV affected source. This facility is not a major source and is not a Title IV source. QSC is not subject to 40 CFR 60 (NSPS) or 40 CFR 61 (NESHAP) standards. QSC is subject to 40 CFR 63 (MACT) Subpart XXXXXX. However, Title V does not apply because MACT Subpart XXXXXX exempts sources from the obligation to obtain a permit under 40 CFR part 70 (Title V permit) if the source is not otherwise required by law to obtain a permit. There are no other reasons why this source would be required to obtain a part 70 permit as an area source; therefore, Title V does not apply to this facility as per R307-415-4(2)(c). [Last updated December 14, 2023] 4. Comment regarding Plasma Cutting, Welding, and Shot Blaster Operations: The plasma cutter, welding, and shot blaster operations currently have annual emissions of PM10/PM2.5 at 4.60 tpy. There is an increase in the hours of operation from 2,500 hours to 3,500 hours however, there isn't any new limit on the plasma cutter, welding, or shot blaster operations. The annual hours of operation for all three of these activities is 8,760 hrs/yr. The DAQ will continue to use the PM10/PM2.5 emissions at 4.60 tpy. [Last updated December 1, 2023] 5. Comment regarding The Amount of Shot Blasters: In DAQE-AN115980008-18, there are two shot blasters specified in the equipment list. Based on information from QSC, one shot blaster has been removed from service, leaving one shot blaster to be listed in the future AO. [Last updated April 17, 2023] 6. Comment regarding HAP Constituents: In the SDS for QS, three HAPs are identified as constituents, hexamethylene diisocyanate, xylene, and methyl methacrylate (MMA). In the current NOI [06/14/22], it says "...no HAPs are present..." Engineer Review N115980009: Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant December 14, 2023 Page 11 QS was asked about this and they said, "The Hexamethylene Diisocyanate Polymer (CAS 28182-81- 2) in the Sherwin Williams Polane Catalyst is not the same chemical compound as the hazardous air pollutant (HAP), Hexamethylene-1,6-diisocyanate (CAS 822-06-0). Sherwin Williams identifies these coating materials as "HAP free" coatings according to the SDSs. We are aware there are trace amounts of various HAPs (xylene, MMA) in some coatings, which are non-carcinogenic and are less than the 1% reporting threshold contained in MACT Subpart MMMM." In the SDS' submitted with this NOI, the percentages of xylene and MMA are both 0.3%. The HAP limitation for xylene, at less than 20 meters to the property boundary, fugitive release is 22.14 lbs/hr. 0.3% of this value is 0.066 lbs/hr. This value multiplied by the increase in the hours of operation, 1,000 hrs/yr equals 66 lbs/yr or 0.033 tons/yr. Similarly, the HAP limitation for MMA, at less than 20 meters to the property boundary, fugitive release is 10.44 lbs/hr. 0.3% of this value is 0.031 lbs/hr. This value multiplied by the increase in the hours of operation, 1,000 hrs/yr equals 31 lbs/yr or 0.0155 tons/yr. The owner/operator shall keep a record of xylene and MMA produced by the operations of the spray booth, monthly. [Last updated November 27, 2023] Engineer Review N115980009: Quality Steel Corporation - Fuel Storage Tank Manufacturing Plant December 14, 2023 Page 12 ACRONYMS The following lists commonly used acronyms and associated translations as they apply to this document: 40 CFR Title 40 of the Code of Federal Regulations AO Approval Order BACT Best Available Control Technology CAA Clean Air Act CAAA Clean Air Act Amendments CDS Classification Data System (used by EPA to classify sources by size/type) CEM Continuous emissions monitor CEMS Continuous emissions monitoring system CFR Code of Federal Regulations CMS Continuous monitoring system CO Carbon monoxide CO2 Carbon Dioxide CO2e Carbon Dioxide Equivalent - 40 CFR Part 98, Subpart A, Table A-1 COM Continuous opacity monitor DAQ/UDAQ Division of Air Quality DAQE This is a document tracking code for internal UDAQ use EPA Environmental Protection Agency FDCP Fugitive dust control plan GHG Greenhouse Gas(es) - 40 CFR 52.21 (b)(49)(i) GWP Global Warming Potential - 40 CFR Part 86.1818-12(a) HAP or HAPs Hazardous air pollutant(s) ITA Intent to Approve LB/HR Pounds per hour LB/YR Pounds per year MACT Maximum Achievable Control Technology MMBTU Million British Thermal Units NAA Nonattainment Area NAAQS National Ambient Air Quality Standards NESHAP National Emission Standards for Hazardous Air Pollutants NOI Notice of Intent NOx Oxides of nitrogen NSPS New Source Performance Standard NSR New Source Review PM10 Particulate matter less than 10 microns in size PM2.5 Particulate matter less than 2.5 microns in size PSD Prevention of Significant Deterioration PTE Potential to Emit R307 Rules Series 307 R307-401 Rules Series 307 - Section 401 SO2 Sulfur dioxide Title IV Title IV of the Clean Air Act Title V Title V of the Clean Air Act TPY Tons per year UAC Utah Administrative Code VOC Volatile organic compounds Quality Steel - LT Corp - West Jordan Operations - Estimated VOC and HAP Emissions Usage Summary 2021-2022 Gallons VOC tpm Ave. VOC lb/gal % Topcoat HAPs Analysis Proposed Emissions for adding 1,000 hours to work schedule and 60% of 12,000 gallons is topcoat January 2,366 2.83 2.40 68%Conc.Prop Em Total Em February 2,043 3.02 2.96 44%Xylene 0.15%Present in all materials March 3,223 3.37 2.09 59%MMA 0.15%Present in Aluminum, Superior green, and star blue Polane Polyurethane Enamel topcoats (up to 50% of usage) April #REF!2.83 #REF!57%Ethylbenzene 0.10%Present in white topcoat only (up to 25% of coatings) May 2,338 2.69 2.30 58%Xylene 173.39 pounds per year 0.087 tpy increase 0.303 tpy total June 2,538 2.96 2.33 59%MMA 86.69 pounds per year 0.043 tpy increase 0.152 tpy total July 2,233 2.65 2.38 55%Ethylbenzene 28.90 pounds per year 0.014 tpy increase 0.051 tpy total August 2,829 3.28 2.32 67%Notes: September 2,882 3.49 2.42 54%Activator has no HAPs October 2,509 2.96 2.36 61%Catalyst has no HAPs November 2,501 2.81 2.24 60%MMA is only present in Polane topcoats Aluminum, Superior Green, and Star Blue at 0.3% each. December 1,801 2.30 2.55 61%Ethylbenzene is present in white topcoat only, for up to 25% of total usage Total 2021 #REF!35.19 at 2500 hours of operation Annual average Topcoat 60%, Primer 40% #REF!gallons per month, average #REF!gallons per day, average #REF!gallons per hour, average 2.38 lb/gal Average VOC content Proposed #REF!gallons 3500 hours Note: 11,000 gallon increase in usage for 1000 additional hours. Average VOC Content 2.38 lb VOC /gal Est. VOC Emissions #REF!lb VOC/yr Est. VOC Emissions #REF!tpy VOC January Usage Product description Product Part #Cycle Count Qty Qty Received 2nd Count Qty Primer 03-061-1 53632 104320 65456 Zinc Primer 03-061-2 10240 0 7808 Star Blue 03-062-1 18944 0 18304 Aluminum 03-063-1 19968 12672 15744 White 03-064-1 85760 76800 53888 Tan 03-065-1 23040 12160 31872 Desert Tan 03-065-2 2816 18944 8832 Tractor Green 03-066-2 0 0 0 Superior Green 03-068-1 3200 0 3200 UG Green 03-069-1 49920 0 33152 Urethane Activator 03-070-1 41728 25600 35584 Epoxy Catalyst 03-071-1 53504 17536 55168 Zinc Primer Catalyst 03-071-2 3072 0 2048 Qty Used (OZ)Qty Used (Gallons) 92496 723 2432 19 Primer 750 gallons 640 5 TopCoat 1616 gallons 16896 132 108672 849 Primer =32%6.3 tons/yr 3328 26 Topcoat =68%13.7 tons/yr 12928 101 0 0 0 0 16768 131 31744 248 15872 124 1024 8 2366 February Usage Product description Product Part #Cycle Count Qty Qty Received 2nd Count Qty Qty Used (OZ)Qty Used (Gallons) Primer 03-061-1 65456 126464 45824 146096 1141 Zinc Primer 03-061-2 7808 0 7808 0 0 Star Blue 03-062-1 18304 6272 21504 3072 24 Aluminum 03-063-1 15744 0 15744 0 0 White 03-064-1 53888 102400 137600 18688 146 Tan 03-065-1 31872 12672 37760 6784 53 Desert Tan 03-065-2 8832 12800 12160 9472 74 Tractor Green 03-066-2 0 0 0 0 0 Superior Green 03-068-1 3200 12544 3840 11904 93 UG Green 03-069-1 33152 24704 43520 14336 112 Urethane Activator 03-070-1 35584 50560 51456 34688 271 Epoxy Catalyst 03-071-1 55168 6400 45056 16512 129 Zinc Primer Catalyst 03-071-2 2048 0 2048 0 0 2043 Primer 1141 gallons TopCoat 902 gallons assume equal use of catalyst, activator Primer =56%11.2 tons/yr Topcoat =44%8.8 tons/yr March Usage Product description Product Part #Cycle Count Qty Qty Received 2nd Count Qty Qty Used (OZ)Qty Used (Gallons) Primer 03-061-1 45824 154143 31479 168488 1316 Zinc Primer 03-061-2 7808 0 7808 0 0 Star Blue 03-062-1 21504 0 21504 0 0 Aluminum 03-063-1 15744 6400 21197 947 7 White 03-064-1 137600 103040 95488 145152 1134 Tan 03-065-1 37760 0 28288 9472 74 Desert Tan 03-065-2 12160 6144 12330 5974 47 Tractor Green 03-066-2 0 0 0 0 0 Superior Green 03-068-1 3840 0 3840 0 0 UG Green 03-069-1 43520 51200 71424 23296 182 Urethane Activator 03-070-1 51456 25344 38690 38110 298 Epoxy Catalyst 03-071-1 45056 25600 49492 21164 165 Zinc Primer Catalyst 03-071-2 2048 0 2048 0 0 3223 Primer 1316 gallons TopCoat 1907 gallons assume equal use of catalyst, activator Primer =41%8.2 tons/yr Topcoat =59%11.8 tons/yr April Usage Product description Product Part #Cycle Count Qty Qty Received 2nd Count Qty Qty Used (OZ)Qty Used (Gallons) Primer 03-061-1 31479 124032 14592 140919 1101 Zinc Primer 03-061-2 7808 0 6784 1024 8 Primer Star Blue 03-062-1 21504 0 21504 0 0 TopCoat Aluminum 03-063-1 21197 19456 16640 24013 188 White 03-064-1 95488 51456 90496 56448 441 Primer = Tan 03-065-1 28288 12544 27136 13696 107 Topcoat = Desert Tan 03-065-2 12330 6272 5376 13226 103 Tractor Green 03-066-2 0 0 0 0 0 Superior Green 03-068-1 3840 0 3840 0 0 UG Green 03-069-1 71424 0 47488 23936 187 Urethane Activator 03-070-1 38690 51200 50560 39330 307 Epoxy Catalyst 03-071-1 49492 25600 55040 20052 157 Zinc Primer Catalyst 03-071-2 2048 0 1792 256 2 #REF! 1111 gallons 1490 gallons assume equal use of catalyst, activator 43%8.5 tons/yr 57%11.5 tons/yr May Usage Product description Product Part #Cycle Count Qty Qty Received 2nd Count Qty Qty Used (OZ)Qty Used (Gallons) Primer 03-061-1 14592 204288 91904 126976 992 Zinc Primer 03-061-2 6784 0 6784 0 0 Primer Star Blue 03-062-1 21504 0 21504 0 0 TopCoat Aluminum 03-063-1 16640 25216 21120 20736 162 White 03-064-1 90496 51200 91264 50432 394 Primer = Tan 03-065-1 27136 6400 28288 5248 41 Topcoat = Desert Tan 03-065-2 5376 12800 7424 10752 84 Tractor Green 03-066-2 0 0 0 0 0 Superior Green 03-068-1 3840 0 3840 0 0 UG Green 03-069-1 47488 25600 43520 29568 231 Urethane Activator 03-070-1 50560 12288 25472 37376 292 Epoxy Catalyst 03-071-1 55040 25600 62464 18176 142 Zinc Primer Catalyst 03-071-2 1792 0 1792 0 0 2338 992 gallons 1346 gallons assume equal use of catalyst, activator 42%8.5 tons/yr 58%11.5 tons/yr June Usage Product description Product Part #Cycle Count Qty Qty Received 2nd Count Qty Qty Used (OZ)Qty Used (Gallons) Primer 03-061-1 91904 100480 62720 129664 1013 Zinc Primer 03-061-2 6784 0 3456 3328 26 Star Blue 03-062-1 21504 6144 25728 1920 15 Aluminum 03-063-1 21120 19200 25088 15232 119 White 03-064-1 91264 38400 69376 60288 471 Tan 03-065-1 28288 0 18944 9344 73 Desert Tan 03-065-2 7424 19456 15104 11776 92 Tractor Green 03-066-2 0 0 0 0 0 Superior Green 03-068-1 3840 3200 4352 2688 21 UG Green 03-069-1 43520 25600 37888 31232 244 Urethane Activator 03-070-1 25472 51200 36992 39680 310 Epoxy Catalyst 03-071-1 62464 0 43904 18560 145 Zinc Primer Catalyst 03-071-2 1792 0 640 1152 9 2538 Primer 1048 gallons TopCoat 1490 gallons assume equal use of catalyst, activator Primer =41%8.3 tons/yr Topcoat =59%11.7 tons/yr July Usage Product description Product Part #Cycle Count Qty Qty Received 2nd Count Qty Qty Used (OZ)Qty Used (Gallons) Primer 03-061-1 62720 106222 41177 127765 998 Zinc Primer 03-061-2 3456 1920 5376 0 0 Primer Star Blue 03-062-1 25728 0 18560 7168 56 TopCoat Aluminum 03-063-1 25088 12544 23424 14208 111 White 03-064-1 69376 51200 74022 46554 364 Primer = Tan 03-065-1 18944 12288 27006 4226 33 Topcoat = Desert Tan 03-065-2 15104 12416 17869 9651 75 Tractor Green 03-066-2 0 0 0 0 Superior Green 03-068-1 4352 0 4352 0 0 UG Green 03-069-1 37888 25344 42880 20352 159 Urethane Activator 03-070-1 36992 25216 24192 38016 297 Epoxy Catalyst 03-071-1 43904 25600 51584 17920 140 Zinc Primer Catalyst 03-071-2 640 1280 1920 0 0 2233 998 gallons 1235 gallons assume equal use of catalyst, activator 45%8.9 tons/yr 55%11.1 tons/yr August Usage Product description Product Part #Cycle Count Qty Qty Received 2nd Count Qty Qty Used (OZ)Qty Used (Gallons) Primer 03-061-1 41177 167424 88192 120409 941 Zinc Primer 03-061-2 5376 0 5376 0 0 Star Blue 03-062-1 18560 0 18560 0 0 Aluminum 03-063-1 23424 25600 25344 23680 185 White 03-064-1 74022 102400 103552 72870 569 Tan 03-065-1 27006 12672 30464 9214 72 Desert Tan 03-065-2 17869 0 3840 14029 110 Tractor Green 03-066-2 0 0 0 0 0 Superior Green 03-068-1 4352 0 4352 0 0 UG Green 03-069-1 42880 43904 40832 45952 359 Urethane Activator 03-070-1 24192 63488 26880 60800 475 Epoxy Catalyst 03-071-1 51584 53120 89600 15104 118 Zinc Primer Catalyst 03-071-2 1920 0 1920 0 0 2829 Primer 941 gallons TopCoat 1888 gallons assume equal use of catalyst, activator Primer =33%6.7 tons/yr Topcoat =67%13.3 tons/yr September Usage Product description Product Part #Cycle Count Qty Qty Received 2nd Count Qty Qty Used (OZ)Qty Used (Gallons) Primer 03-061-1 88192 153600 73600 168192 1314 Zinc Primer 03-061-2 5376 0 5376 0 0 Star Blue 03-062-1 18560 0 18560 0 0 Aluminum 03-063-1 25344 6400 15104 16640 130 White 03-064-1 103552 0 39040 64512 504 Tan 03-065-1 30464 6272 30080 6656 52 Desert Tan 03-065-2 3840 31104 23040 11904 93 Tractor Green 03-066-2 0 0 0 0 0 Superior Green 03-068-1 4352 0 4352 0 0 UG Green 03-069-1 40832 32000 32896 39936 312 Urethane Activator 03-070-1 26880 48054 32512 42422 331 Epoxy Catalyst 03-071-1 89600 0 70912 18688 146 Zinc Primer Catalyst 03-071-2 1920 0 1920 0 0 2882 Primer 1314 gallons TopCoat 1568 gallons assume equal use of catalyst, activator Primer =46%9.1 tons/yr Topcoat =54%10.9 tons/yr October Usage Product description Product Part #Cycle Count Qty Qty Received 2nd Count Qty Qty Used (OZ)Qty Used (Gallons) Primer 03-061-1 73600 99072 46080 126592 989 Zinc Primer 03-061-2 5376 0 5376 0 0 Star Blue 03-062-1 18560 0 18560 0 0 Aluminum 03-063-1 15104 19200 17920 16384 128 White 03-064-1 39040 55040 31616 62464 488 Tan 03-065-1 30080 6400 31616 4864 38 Desert Tan 03-065-2 23040 12672 27520 8192 64 Tractor Green 03-066-2 0 0 0 0 0 Superior Green 03-068-1 4352 0 4352 0 0 UG Green 03-069-1 32896 50688 48640 34944 273 Urethane Activator 03-070-1 32512 50816 39552 43776 342 Epoxy Catalyst 03-071-1 70912 0 46976 23936 187 Zinc Primer Catalyst 03-071-2 1920 0 1920 0 0 2509 Primer 989 gallons TopCoat 1520 gallons assume equal use of catalyst, activator Primer =39%7.9 tons/yr Topcoat =61%12.1 tons/yr Product description Product Part #Cycle Count Qty Qty Received 2nd Count Qty Qty Used (OZ)Qty Used (Gallons) Primer 03-061-1 46080 153856 71424 128512 1004 Zinc Primer 03-061-2 5376 0 5376 0 0 Star Blue 03-062-1 18560 0 18560 0 0 Aluminum 03-063-1 17920 12800 26880 3840 30 White 03-064-1 31616 132736 85760 78592 614 Tan 03-065-1 31616 6400 25600 12416 97 Desert Tan 03-065-2 27520 6272 27776 6016 47 Tractor Green 03-066-2 0 0 0 0 0 Superior Green 03-068-1 4352 0 4352 0 0 UG Green 03-069-1 48640 25600 45184 29056 227 Urethane Activator 03-070-1 39552 32000 28416 43136 337 Epoxy Catalyst 03-071-1 46976 25344 53760 18560 145 Zinc Primer Catalyst 03-071-2 1920 0 1920 0 0 2501 Primer 1004 gallons TopCoat 1497 gallons assume equal use of catalyst, activator Primer =40%8.0 tons/yr Topcoat =60%12.0 tons/yr Product description Product Part #Cycle Count Qty Qty Received 2nd Count Qty Qty Used (OZ)Qty Used (Gallons) Primer 03-061-1 71424 51200 32000 90624 708 Zinc Primer 03-061-2 5376 0 5376 0 0 Star Blue 03-062-1 18560 0 18560 0 0 Aluminum 03-063-1 26880 12288 31232 7936 62 White 03-064-1 85760 50304 75520 60544 473 Tan 03-065-1 25600 6272 21760 10112 79 Desert Tan 03-065-2 27776 0 24704 3072 24 Tractor Green 03-066-2 0 0 0 0 0 Superior Green 03-068-1 4352 0 4352 0 0 UG Green 03-069-1 45184 22784 54144 13824 108 Urethane Activator 03-070-1 28416 44800 45184 28032 219 Epoxy Catalyst 03-071-1 53760 0 37376 16384 128 Zinc Primer Catalyst 03-071-2 1920 0 1920 0 0 1801 Primer 708 gallons TopCoat 1093 gallons assume equal use of catalyst, activator Primer =39%7.9 tons/yr Topcoat =61%12.1 tons/yr Quality Steel - LT Corp - West Jordan Operations - Estimated VOC and HAP Emissions Usage Summary 2021-2022 Gallons VOC tpm Ave. VOC lb/gal % Topcoat HAPs Analysis Proposed Emissions for adding 1,000 hours to work schedule and 60% of 12,000 gallons is topcoat January 2,366 2.83 2.40 68%Conc.Prop Em Total Em February 2,043 3.02 2.96 44%Xylene 0.15%Present in all materials March 3,223 3.37 2.09 59%MMA 0.15%Present in Aluminum, Superior green, and star blue Polane Polyurethane Enamel topcoats (up to 50% of usage) April 2,601 2.83 2.18 57%Ethylbenzene 0.10%Present in white topcoat only (up to 25% of coatings) May 2,338 2.69 2.30 58%Xylene 173.39 pounds per year 0.087 tpy increase 0.303 tpy total June 2,538 2.96 2.33 59%MMA 86.69 pounds per year 0.043 tpy increase 0.152 tpy total July 2,233 2.65 2.38 55%Ethylbenzene 28.90 pounds per year 0.014 tpy increase 0.051 tpy total August 2,829 3.28 2.32 67%Notes: September 2,882 3.49 2.42 54%Activator has no HAPs October 2,509 2.96 2.36 61%Catalyst has no HAPs November 2,501 2.81 2.24 60%MMA is only present in Polane topcoats Aluminum, Superior Green, and Star Blue at 0.3% each. December 1,801 2.30 2.55 61%Ethylbenzene is present in white topcoat only, for up to 25% of total usage Total 2021 27,499 35.19 at 2500 hours of operation Annual average Topcoat 60%, Primer 40% 2,292 gallons per month, average 110.0 gallons per day, average 11.0 gallons per hour, average 2.38 lb/gal Average VOC content Proposed 38,498 gallons 3500 hours Note: 11,000 gallon increase in usage for 1000 additional hours. Average VOC Content (lb/gal)2.38 lb VOC /gal Est. VOC Emissions 98,532 lb VOC/yr Est. VOC Emissions 49.3 tpy VOC The Sherwin‐Williams Company Regulatory Affairs & Global Product Stewardship 101 Prospect Avenue Cleveland, OH 44115 June 28, 2023 Re: Quality Steel HAPS content PLEASE BE ADVISED that the following Sherwin‐Williams products, as supplied: E90HXA233-4371 - 2.8 Epoxy Primer, Blue F63GXL33693-4371 - Polane 8910 Polyurethane Enamel, Star Blue F63GXA33690-4371 - Polane 8910 Polyurethane Enamel, RAL 7038 Aluminum F63GXW32595-4371 - F63GX POLANE G PLUS 8910 WITH PHX COLORANTS, White F63GXH33692-4371 - Polane 8910 Polyurethane Enamel, RAL 1014 Tan F63GXH33691-4371 - Polane 8910 Polyurethane Enamel, RAL 1001 Desert F63GXG32596-4371 - F63GX/GP Polane G Plus 8910 Polyurethane With Opticolor Xp, Green Ral 6009 (pre- reduced) B65V00625 - Polane Catalyst V93V00236 - 2K Epoxy Hardener V66VL0019 - Fast 2K Epoxy Catalyst F63GXG33703-4371 - Polane 8910 Polyurethane Enamel, RAL 6003 Superior Green do not contain any reportable Hazardous Air Pollutants (HAPS) per NESHAP Standard 40 CFR 63 Subpart MMMM: Miscellaneous Metal Parts and Products Surface Coating. This information is based on the current product formulations and their intentionally added ingredients and relies on the information provided by our raw material suppliers. Sincerely, Nicholas Klimkowicz Global Product Stewardship (216)566‐2902 Opt. 3 RegTech@sherwin.com 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&simp…1/56 Tim Dejulis <tdejulis@utah.gov> Quality Steels Status 27 messages Tim Dejulis <tdejulis@utah.gov>Thu, Jun 1, 2023 at 12:46 PM To: Charles Smiley <csmiley@propanetank.com> Cc: "Zopff, David L" <david.zopff@woodplc.com> Bcc: Alan Humpherys <ahumpherys@utah.gov> Charles, Please accept my apologies for taking so long to get through the process of getting Quality Steels (QS) engineering review (ER) ready. QS been patient with me throughout our process and I appreciate this. We have one question for QS. It says in the NOI that "...no HAPs are present..." in describing the emission estimates, however we find two chemicals in the SDS submitted that show that HAPs are present (hexamethylene diisocyanate and xylene). Does QS not want these two chemicals included? This would surely be on compliances radar when they inspect this source. I can certainly put them into the ER with a notice from QS to the DAQ to take out the "...no HAPs are present..." statement from the NOI. Please advise. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov Zopff, David <david.zopff@wsp.com>Thu, Jun 1, 2023 at 12:57 PM To: Tim Dejulis <tdejulis@utah.gov> Cc: "snelson@propanetank.com" <snelson@propanetank.com>, "BKliesch@propanetank.com" <BKliesch@propanetank.com> Tim, Thanks for the note. Hope all is well. 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&simp…2/56 I found some correspondence from March regarding these chemicals. The HDMI present is the polymer not the monomer, so it is not regulated (note the CAS numbers are different on these related, but distinctly different, chemical compounds). The xylene appears to be present less than the 1% reporting threshold for non-carcinogenic materials. We could ask Sherwin Williams to provide the exact content. I suspect they reported it for industrial hygiene purposes. Let us know if you need further information or want to discuss these matters further. BTW, Mr. Smiley left Quality Steel some time ago. Please direct correspondence to Stacey Nelson. David Zopff Assistant VP - Environmental Engineer Professional Engineer T+ 1 502-267-2362 M+ 1 502-643-7211 WSP USA 11003 Bluegrass Parkway, #690 Louisville, Kentucky, USA 40299 wsp.com 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&simp…3/56 From: Tim Dejulis <tdejulis@utah.gov> Sent: Thursday, June 1, 2023 2:47 PM To: Charles Smiley <csmiley@propanetank.com> Cc: Zopff, David <david.zopff@wsp.com> Subject: Quality Steels Status CAUTION: External email. Please do not click on links/attachments unless you know the content is genuine and safe. [Quoted text hidden] This message is the property of John Wood Group PLC and/or its subsidiaries and/or affiliates and is intended only for the named recipient(s). 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This 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&simp…4/56 message is for the sole use of the intended recipient(s). Any unauthorized use, disclosure, viewing, copying, alteration, dissemination or distribution of, or reliance on, this message is strictly prohibited. If you have received this message in error, or you are not an authorized or intended recipient, please notify the sender immediately by replying to this message, delete this message and all copies from your e-mail system and destroy any printed copies. -LAEmHhHzdJzBlTWfa4Hgs7pbKl ---------- Forwarded message ---------- From: "Zopff, David L" <david.zopff@woodplc.com> To: Tim Dejulis <tdejulis@utah.gov> Cc: Alan Humpherys <ahumpherys@utah.gov>, Chad Gilgen <cgilgen@utah.gov>, Stacey Nelson <snelson@propanetank.com>, Brian Kliesch <BKliesch@propanetank.com> Bcc: Date: Thu, 23 Mar 2023 17:24:56 +0000 Subject: RE: Is Tim, I’ve reviewed the documents. The Hexamethylene Diisocyanate Polymer (CAS 28182-81-2) in the Sherwin Williams Polane Catalyst is not the same chemical compound as the hazardous air pollutant (HAP), Hexamethylene-1,6-diisocyanate (CAS 822-06-0). Sherwin Williams identifies these coating materials as “HAP free” coatings according to the SDSs. We are aware there are trace amounts of various HAPs (xylene, methyl methacrylate) in some coatings, which are non-carcinogenic and are less than the 1% reporting threshold. Please let us know if you have additional questions. Logo WSP David Zopff Assistant VP - Environmental Engineer Professional Engineer T+ 1 502-267-2362 M+ 1 502-643-7211 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&simp…5/56 WSP USA 11003 Bluegrass Parkway, #690 Louisville, Kentucky, USA 40299 wsp.com From: Tim Dejulis <tdejulis@utah.gov> Sent: Monday, March 20, 2023 3:59 PM To: Stacey Nelson <snelson@propanetank.com>; Charles Smiley <csmiley@propanetank.com> Cc: Zopff, David L <david.zopff@woodplc.com>; Alan Humpherys <ahumpherys@utah.gov>; Chad Gilgen <cgilgen@utah.gov> Subject: Is CAUTION: External email. Please do not click on links/attachments unless you know the content is genuine and safe. Stacey and Charles, A question has come up regarding whether hexamethylene 1,6 diisocyanate (HMDI) is present in the painting activity at Quality Steel (QS). There is no mention of HMDI being present in the current NOI application. According to a compliance advisory issued to QS from 2020, HMDI was found to be present. Is HMDI included in the painting activity occurring at the West Jordan plant? Please let us know. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&simp…6/56 airquality.utah.gov RE: Is.eml 25K Tim Dejulis <tdejulis@utah.gov>Fri, Jun 2, 2023 at 8:47 AM To: "Zopff, David" <david.zopff@wsp.com> Cc: "snelson@propanetank.com" <snelson@propanetank.com>, "BKliesch@propanetank.com" <BKliesch@propanetank.com> I'll go ahead and make a comment describing the HAP situation so that this will answer any questions that might arise. Look for a copy of the ER to QS to inspect next week. Thank you for assisting me with this! Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov [Quoted text hidden] Tim Dejulis <tdejulis@utah.gov>Thu, Jun 15, 2023 at 2:30 PM To: "Zopff, David" <david.zopff@wsp.com> Cc: "snelson@propanetank.com" <snelson@propanetank.com>, "BKliesch@propanetank.com" <BKliesch@propanetank.com>, Alan Humpherys <ahumpherys@utah.gov> Stacey, We have redone Quality Steel (QS) engineering review, only to have it not pass our specifications. I told you that we would have a copy of the engineering review for QS to inspect this week. Here's the problem we have. We have done the analysis of how much xylene and methyl methacrylate (MMA) is present from QS's new operations. The amount stated in the SDS for each painting chemical with xylene and MMA was used in our calculation. Both of these chemicals are listed in the SDS's as 0.3% by weight each. We used this value and the Division of Air Quality's (DAQ) theoretical modeling threshold. We used the emission value, in lbs/hr, at less than 20 meters with fugitive release for both chemicals. It isn't clear to us that QS used the DAQ threshold value though, since it wasn't presented in QS's calculations. We used the additional hours of operation at 2,000 hrs/yr. This resulted in 0.066 tons/yr of xylene and 0.031 of MMA. This is not zero HAPs. Could we include the 0.066 tons/yr xylene and 0.031 tons/yr MMA into QS's permit? Please let us know if this is acceptable or not. 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&simp…7/56 Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov [Quoted text hidden] Stacey Nelson <snelson@propanetank.com>Thu, Jun 15, 2023 at 4:05 PM To: Tim Dejulis <tdejulis@utah.gov>, "Zopff, David" <david.zopff@wsp.com> Cc: Brian Kliesch <bkliesch@propanetank.com>, Alan Humpherys <ahumpherys@utah.gov> Tim, Before I can answer the question if it is acceptable to add the xylene and MMA into our permit, I need to understand the ramifications that would cause for Quality Steel. What would be the result of adding them to our permit? Thank you. Stacey Nelson Director of Supply Chain Quality Steel Corporation West Jordan, UT 385-256-4191 [Quoted text hidden] 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&simp…8/56 Tim Dejulis <tdejulis@utah.gov>Fri, Jun 16, 2023 at 11:48 AM To: Stacey Nelson <snelson@propanetank.com> Cc: "Zopff, David" <david.zopff@wsp.com>, Brian Kliesch <bkliesch@propanetank.com>, Alan Humpherys <ahumpherys@utah.gov> Stacey, The only expectation we would have is that when we ask QS for their records, at some point in the future, these records would include the requirement to include the xylene and MMA. QS should do the same procedure as they use with reporting their existing emissions of VOC. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov [Quoted text hidden] Stacey Nelson <snelson@propanetank.com>Fri, Jun 16, 2023 at 12:20 PM To: Tim Dejulis <tdejulis@utah.gov> Cc: "Zopff, David" <david.zopff@wsp.com>, Brian Kliesch <bkliesch@propanetank.com>, Alan Humpherys <ahumpherys@utah.gov> Would adding Xylene and MMA to the same report as the VOC emissions be acceptable, or would it need to be a separate tracking spreadsheet? [Quoted text hidden] Tim Dejulis <tdejulis@utah.gov>Tue, Jun 20, 2023 at 9:23 AM To: Stacey Nelson <snelson@propanetank.com> Cc: "Zopff, David" <david.zopff@wsp.com>, Brian Kliesch <bkliesch@propanetank.com>, Alan Humpherys <ahumpherys@utah.gov> We would add xylene and MMA to the same condition as the VOC requirements. It would appear just under the VOC. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&simp…9/56 [Quoted text hidden] Tim Dejulis <tdejulis@utah.gov>Fri, Jul 7, 2023 at 8:49 AM To: Stacey Nelson <snelson@propanetank.com> Cc: "Zopff, David" <david.zopff@wsp.com>, Brian Kliesch <bkliesch@propanetank.com>, Alan Humpherys <ahumpherys@utah.gov>, Jon Black <jlblack@utah.gov> Stacey, An issue came up with regards to Quality Steel's (QS) effort at adding a shift to their production that we should make you aware of. During a recent staff meeting we were told that in 2025, areas within the Wasatch front in Utah will be in serious nonattainment for ozone. Ozone is created by a combination of VOCs and NOx. If either of these emissions is above 50 tons/yr, the source will be considered major, requiring a Title V permit or will be subject to enacting reasonably achievable control technology (RACT) measures to have each of these emissions below 50 tons/yr. A source enacting RACT must have one or more of the controls that they have proposed in their best available control technology (BACT) review, but we don't consider the environmental, energy, or economic cost in the RACT analysis like we do in the BACT analysis. One or more of the controls for the paint booth would have to be installed, if QS wants to expand their production to an additional shift. QS has a choice in front of them then. QS could choose to not undergo the additional shift they have asked for. We would have to consider the changes to the xylene and MMA though. QS can choose to install one or more of the measures mentioned in the current BACT analysis, as a RACT measure, to control the VOC emissions from the paint booth in the NOI. Please let us know how QS will deal with this serious ozone nonattainment issue. Please ask me if QS has any questions or concerns about this. Thank you. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov [Quoted text hidden] Zopff, David <david.zopff@wsp.com>Fri, Jul 7, 2023 at 12:51 PM To: Tim Dejulis <tdejulis@utah.gov> Cc: Brian Kliesch <bkliesch@propanetank.com>, Alan Humpherys <ahumpherys@utah.gov>, Jon Black <jlblack@utah.gov>, Anthony Torres <atorres@propanetank.com>, Corey Fowler <cfowler@propanetank.com>, Joe Steinem <jsteinem@propanetank.com>, Stacey Nelson <snelson@propanetank.com> Tim, Thank you for the heads up regarding the ozone non-attainment area designations. We will review our options for future compliance, but we need the additional capacity to meet our contractual obligations in the short term. Please continue processing the current request for a 65-ton limit. Please let us know when the agency establishes deadlines for compliance with the new ozone standards and/or submittal of an application for a new approval. 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…10/56 With regard to the xylene and MMA HAPs, please find the attached HAPs statement and Environmental Data Sheets (EDS) from Sherwin-Williams for our product lines. While we believe they meet the requirements to be considered HAP-free products, we understand you need to track those emissions and include them in our approval, and we will incorporate those in our emissions calculations and reporting. Thanks again, David [Quoted text hidden] 12 attachments F63GXH33691-4371 EDS.pdf 51K F63GXH33692-4371 EDS.pdf 51K F63GXL33693-4371 EDS.pdf 52K F63GXW32595-4371 EDS.pdf 51K V66V280 EDS.pdf 46K V66VC304 EDS.pdf 48K V66VL19 EDS.pdf 48K E90HXA233-4371 EDS.pdf 53K F63GXA33690-4371 EDS.pdf 51K F63GXG32596-4371 EDS.pdf 51K F63GXG33703-4371 EDS.pdf 52K Chemicals of Concern - No HAPS 6-28-2023 NK.pdf 145K 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…11/56 Jon Black <jlblack@utah.gov>Sun, Jul 9, 2023 at 11:35 PM To: Tim Dejulis <tdejulis@utah.gov>, Alan Humpherys <ahumpherys@utah.gov> Thank you for the update on this source. I will pass along the information to Ana and John. Let me know if you have any questions at all. Thanks again, Jon [Quoted text hidden] -- Jon L. Black | Manager | Major New Source Review 801.536.4047 (office) | 801.536.4099 (fax) | 385.306.6511 (cell) 195 North 1950 West, Salt Lake City, UT 84116 Emails to and from this email address may be considered public records and thus subject to Utah GRAMA requirements. Tim Dejulis <tdejulis@utah.gov>Tue, Jul 11, 2023 at 11:13 AM To: "Zopff, David L" <david.zopff@woodplc.com>, Stacey Nelson <snelson@propanetank.com> Cc: Alan Humpherys <ahumpherys@utah.gov>, Jon Black <jlblack@utah.gov> David, We have several SDS' in Quality Steels (QS) current Notice of Intent listing the MMA and the xylene in their formulations. Is the use of these nine SDS', listed in the supplemental letter sent to us on September 30, 2022, useless information now? Please advise us. The date of the serious ozone nonattainment area reclassification will be February 2025, but in order for the DAQ to be prepared for this, we must have several things in place before that. We expect the new application to be submitted this month, July 2023, to make the changes to lower the VOC or NOx below 50 tons per year. We need QS RACT to be submitted in January 2024, so we don't have much time to get this current project through our permitting process before we would need to have it be resubmitted in order to go back through DAQ's permitting process again. We understand the contractual obligations QS is under right now. The current engineering review is currently in QS hands though. We haven't started the public comment period because we're waiting for a signature from Mr. Nelson on that engineering review. If QS would like to discuss the serious ozone NA area or any other issue, please let me know. Thank you. 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…12/56 Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov [Quoted text hidden] Tim Dejulis <tdejulis@utah.gov>Tue, Aug 8, 2023 at 8:17 AM To: "Zopff, David L" <david.zopff@woodplc.com>, Stacey Nelson <snelson@propanetank.com> Cc: Alan Humpherys <ahumpherys@utah.gov>, Jon Black <jlblack@utah.gov> David, What is the answer to our questions? Please let us know if you have any questions or concerns. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov [Quoted text hidden] Tim Dejulis <tdejulis@utah.gov>Mon, Sep 11, 2023 at 11:53 AM To: "Zopff, David L" <david.zopff@woodplc.com>, Stacey Nelson <snelson@propanetank.com> Cc: Alan Humpherys <ahumpherys@utah.gov>, Jon Black <jlblack@utah.gov> Stacey, I received a phone call a few weeks ago from David, addressing why we need changes to the current emission estimates due to the situation with ozone. We discussed how the plant doesn't have the room for the additional pollution control equipment and it was decided that we will undergo a different approach. I was supposed to get another email from you Stacey, with the outlines of where Quality Steel wanted to go moving forward, but I haven't received anything yet. How will Quality Steel approach staying below 50 tons/yr of VOC? If I can be of any assistance, please let me know. [Quoted text hidden] Zopff, David <david.zopff@wsp.com>Mon, Sep 11, 2023 at 12:25 PM 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…13/56 To: Tim Dejulis <tdejulis@utah.gov> Cc: Alan Humpherys <ahumpherys@utah.gov>, Jon Black <jlblack@utah.gov>, "BKliesch@propanetank.com" <bkliesch@propanetank.com>, Anthony Torres <atorres@propanetank.com>, Corey Fowler <cfowler@propanetank.com>, "snelson@propanetank.com" <snelson@propanetank.com> Hi Tim, FYI, Stacey has moved to a new role, and Anthony Torres is now the Plant Manager at the West Jordan facility. We have recently reached an agreement for me to revise the application to reflect the 50 ton VOC limit and include the HAP emissions. Working through it now and hope to have all changes to you by the end of the month. Best regards, David David Zopff Assistant VP - Environmental Engineer Professional Engineer T+ 1 502-267-2362 M+ 1 502-643-7211 WSP USA 11003 Bluegrass Parkway, #690 Louisville, Kentucky, USA 40299 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…14/56 wsp.com From: Tim Dejulis <tdejulis@utah.gov> Sent: Monday, September 11, 2023 1:53 PM To: Zopff, David <david.zopff@wsp.com>; Stacey Nelson <snelson@propanetank.com> Cc: Alan Humpherys <ahumpherys@utah.gov>; Jon Black <jlblack@utah.gov> Subject: Re: Quality Steels Status CAUTION: External email. Please do not click on links/attachments unless you know the content is genuine and safe. [Quoted text hidden] Tim Dejulis <tdejulis@utah.gov>Fri, Oct 27, 2023 at 12:34 PM To: "Zopff, David" <david.zopff@wsp.com> Cc: Alan Humpherys <ahumpherys@utah.gov>, Jon Black <jlblack@utah.gov>, "BKliesch@propanetank.com" <bkliesch@propanetank.com>, Anthony Torres <atorres@propanetank.com>, Corey Fowler <cfowler@propanetank.com> David, We're still waiting for the updated calculation's for the revised operations at Quality Steel, to keep the emissions of VOC below 50 tpy. How can we be of assistance in getting this information submitted soon? Please let us know where we are at with this project. Thank you. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov [Quoted text hidden] Zopff, David <david.zopff@wsp.com>Fri, Oct 27, 2023 at 1:12 PM To: Tim Dejulis <tdejulis@utah.gov> Cc: Alan Humpherys <ahumpherys@utah.gov>, Jon Black <jlblack@utah.gov>, "BKliesch@propanetank.com" <bkliesch@propanetank.com>, Anthony Torres <atorres@propanetank.com>, Corey Fowler <cfowler@propanetank.com> 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…15/56 Hey Tim, we have been working on it and I think it is ready to go early next week. Thank you for your patience. Thanks, David David Zopff PE Asst.VP-Environmental Engineer 11003 Bluegrass Parkway #690 Louisville, Kentucky 40299 Direct: +1 (502) 471-2362 Mobile: +1 (502) 643-7211 www.WSP.com From: Tim Dejulis <tdejulis@utah.gov> Sent: Friday, October 27, 2023 2:34:42 PM To: Zopff, David <david.zopff@wsp.com> Cc: Alan Humpherys <ahumpherys@utah.gov>; Jon Black <jlblack@utah.gov>; BKliesch@propanetank.com <bkliesch@propanetank.com>; Anthony Torres <atorres@propanetank.com>; Corey Fowler <cfowler@propanetank.com> [Quoted text hidden] [Quoted text hidden] Tim Dejulis <tdejulis@utah.gov>Fri, Oct 27, 2023 at 1:39 PM To: "Zopff, David" <david.zopff@wsp.com> Cc: Alan Humpherys <ahumpherys@utah.gov>, Jon Black <jlblack@utah.gov>, "BKliesch@propanetank.com" <bkliesch@propanetank.com>, Anthony Torres <atorres@propanetank.com>, Corey Fowler <cfowler@propanetank.com> Thank you for the update. I will follow up next week then. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov [Quoted text hidden] Brian Kliesch <bkliesch@propanetank.com>Mon, Oct 30, 2023 at 4:51 AM To: Tim Dejulis <tdejulis@utah.gov> 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…16/56 Tim thanks for all your help and patience during this process. We have several new people in the organization, and it is a learning process for us. Any guidance or education on this subject from you is welcome. I am always available to you. Please feel free to contact me if you have any questions. Brian Kliesch Senior EHS Manager Quality Steel Corporation 721 Graham Drive|Fremont Ohio, 43420 Mobile: 419-351-2941 From: Tim Dejulis <tdejulis@utah.gov> Sent: Friday, October 27, 2023 3:39 PM To: Zopff, David <david.zopff@wsp.com> Cc: Alan Humpherys <ahumpherys@utah.gov>; Jon Black <jlblack@utah.gov>; Brian Kliesch <bkliesch@propanetank.com>; Anthony Torres <atorres@propanetank.com>; Corey Fowler <cfowler@propanetank.com> Subject: Re: Quality Steels Status Thank you for the update. I will follow up next week then. Image removed by sender. Division Name Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…17/56 airquality.utah.gov On Fri, Oct 27, 2023 at 1:12 PM Zopff, David <david.zopff@wsp.com> wrote: Hey Tim, we have been working on it and I think it is ready to go early next week. Thank you for your patience. Thanks, David David Zopff PE Asst.VP-Environmental Engineer 11003 Bluegrass Parkway #690 Louisville, Kentucky 40299 Direct: +1 (502) 471-2362 Mobile: +1 (502) 643-7211 www.WSP.com From: Tim Dejulis <tdejulis@utah.gov> Sent: Friday, October 27, 2023 2:34:42 PM To: Zopff, David <david.zopff@wsp.com> Cc: Alan Humpherys <ahumpherys@utah.gov>; Jon Black <jlblack@utah.gov>; BKliesch@propanetank.com <bkliesch@propanetank.com>; Anthony Torres <atorres@propanetank.com>; Corey Fowler <cfowler@propanetank.com> Subject: Re: Quality Steels Status David, We're still waiting for the updated calculation's for the revised operations at Quality Steel, to keep the emissions of VOC below 50 tpy. How can we be of assistance in getting this information submitted soon? Please let us know where we are at with this project. Thank you. 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…18/56 Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov On Mon, Sep 11, 2023 at 12:25 PM Zopff, David <david.zopff@wsp.com> wrote: Hi Tim, FYI, Stacey has moved to a new role, and Anthony Torres is now the Plant Manager at the West Jordan facility. We have recently reached an agreement for me to revise the applicaon to reflect the 50 ton VOC limit and include the HAP emissions. Working through it now and hope to have all changes to you by the end of the month. Best regards, David David Zopff Assistant VP - Environmental Engineer 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…19/56 Professional Engineer T+ 1 502-267-2362 M+ 1 502-643-7211 WSP USA 11003 Bluegrass Parkway, #690 Louisville, Kentucky, USA 40299 wsp.com From: Tim Dejulis <tdejulis@utah.gov> Sent: Monday, September 11, 2023 1:53 PM To: Zopff, David <david.zopff@wsp.com>; Stacey Nelson <snelson@propanetank.com> Cc: Alan Humpherys <ahumpherys@utah.gov>; Jon Black <jlblack@utah.gov> Subject: Re: Quality Steels Status CAUTION: External email. Please do not click on links/aachments unless you know the content is genuine and safe. Stacey, I received a phone call a few weeks ago from David, addressing why we need changes to the current emission esmates due to the situaon with ozone. We discussed how the plant doesn't have the room for the addional polluon control equipment and it was decided that we will undergo a 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…20/56 different approach. I was supposed to get another email from you Stacey, with the outlines of where Quality Steel wanted to go moving forward, but I haven't received anything yet. How will Quality Steel approach staying below 50 tons/yr of VOC? If I can be of any assistance, please let me know. On Tue, Aug 8, 2023 at 8:17 AM Tim Dejulis <tdejulis@utah.gov> wrote: David, What is the answer to our quesons? Please let us know if you have any quesons or concerns. Image removed by sender. Division Name Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov On Tue, Jul 11, 2023 at 11:13 AM Tim Dejulis <tdejulis@utah.gov> wrote: David, We have several SDS' in Quality Steels (QS) current Noce of Intent lisng the MMA and the xylene in their formulaons. Is the use of these nine SDS', listed in the supplemental leer sent to us on September 30, 2022, useless informaon now? Please advise us. 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…21/56 The date of the serious ozone nonaainment area reclassificaon will be February 2025, but in order for the DAQ to be prepared for this, we must have several things in place before that. We expect the new applicaon to be submied this month, July 2023, to make the changes to lower the VOC or NOx below 50 tons per year. We need QS RACT to be submied in January 2024, so we don't have much me to get this current project through our perming process before we would need to have it be resubmied in order to go back through DAQ's perming process again. We understand the contractual obligaons QS is under right now. The current engineering review is currently in QS hands though. We haven't started the public comment period because we're waing for a signature from Mr. Nelson on that engineering review. If QS would like to discuss the serious ozone NA area or any other issue, please let me know. Thank you. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov On Sun, Jul 9, 2023 at 11:35 PM Jon Black <jlblack@utah.gov> wrote: Thank you for the update on this source. I will pass along the informaon to Ana and John. Let me know if you have any quesons at all. Thanks again, 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…22/56 Jon On Fri, Jul 7, 2023 at 12:51 PM Zopff, David <david.zopff@wsp.com> wrote: Tim, Thank you for the heads up regarding the ozone non-aainment area designaons. We will review our opons for future compliance, but we need the addional capacity to meet our contractual obligaons in the short term. Please connue processing the current request for a 65- ton limit. Please let us know when the agency establishes deadlines for compliance with the new ozone standards and/or submial of an applicaon for a new approval. With regard to the xylene and MMA HAPs, please find the aached HAPs statement and Environmental Data Sheets (EDS) from Sherwin- Williams for our product lines. While we believe they meet the requirements to be considered HAP-free products, we understand you need to track those emissions and include them in our approval, and we will incorporate those in our emissions calculaons and reporng. Thanks again, David David Zopff Assistant VP - Environmental Engineer Professional Engineer T+ 1 502-267-2362 M+ 1 502-643-7211 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…23/56 WSP USA 11003 Bluegrass Parkway, #690 Louisville, Kentucky, USA 40299 wsp.com From: Tim Dejulis <tdejulis@utah.gov> Sent: Friday, July 7, 2023 10:50 AM To: Stacey Nelson <snelson@propanetank.com> Cc: Zopff, David <david.zopff@wsp.com>; Brian Kliesch <bkliesch@propanetank.com>; Alan Humpherys <ahumpherys@utah.gov>; Jon Black <jlblack@utah.gov> Subject: Re: Quality Steels Status Stacey, An issue came up with regards to Quality Steel's (QS) effort at adding a shi to their producon that we should make you aware of. During a recent staff meeng we were told that in 2025, areas within the Wasatch front in Utah will be in serious nonaainment for ozone. Ozone is created by a combinaon of VOCs and NOx. If either of these emissions is above 50 tons/yr, the source will be considered major, requiring a Title V permit or will be subject to enacng reasonably achievable control technology (RACT) measures to have each of these emissions below 50 tons/yr. A source enacng RACT must have one or more of the controls that they have proposed in their best available control technology (BACT) review, but we don't consider the environmental, energy, or economic cost in the RACT analysis like we do in the BACT analysis. One or more of the controls for the paint booth would have to be installed, if QS wants to expand their producon to an addional shi. QS has a choice in front of them then. QS could choose to not undergo the addional shi they have asked for. We would have to consider the changes to the xylene and MMA though. QS can choose to install one or more of the measures menoned in the current BACT analysis, as a RACT measure, to control the VOC 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…24/56 emissions from the paint booth in the NOI. Please let us know how QS will deal with this serious ozone nonaainment issue. Please ask me if QS has any quesons or concerns about this. Thank you. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov On Tue, Jun 20, 2023 at 9:23 AM Tim Dejulis <tdejulis@utah.gov> wrote: We would add xylene and MMA to the same condion as the VOC requirements. It would appear just under the VOC. Image removed by sender. Division Name Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…25/56 On Fri, Jun 16, 2023 at 12:20 PM Stacey Nelson <snelson@propanetank.com> wrote: Would adding Xylene and MMA to the same report as the VOC emissions be acceptable, or would it need to be a separate tracking spreadsheet? Thank you. Stacey Nelson Director of Supply Chain Quality Steel Corporaon West Jordan, UT 385-256-4191 From: Tim Dejulis <tdejulis@utah.gov> Sent: Friday, June 16, 2023 11:49 AM To: Stacey Nelson <snelson@propanetank.com> Cc: Zopff, David <david.zopff@wsp.com>; Brian Kliesch <bkliesch@propanetank.com>; Alan Humpherys <ahumpherys@utah.gov> Subject: Re: Quality Steels Status Stacey, The only expectaon we would have is that when we ask QS for their records, at some point in the future, these records would include the requirement to include the xylene and MMA. QS should do the same procedure as they use with reporng their exisng emissions of 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…26/56 VOC. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov On Thu, Jun 15, 2023 at 4:05 PM Stacey Nelson <snelson@propanetank.com> wrote: Tim, Before I can answer the queson if it is acceptable to add the xylene and MMA into our permit, I need to understand the ramificaons that would cause for Quality Steel. What would be the result of adding them to our permit? Thank you. Stacey Nelson Director of Supply Chain 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…27/56 Quality Steel Corporaon West Jordan, UT 385-256-4191 From: Tim Dejulis <tdejulis@utah.gov> Sent: Thursday, June 15, 2023 2:31 PM To: Zopff, David <david.zopff@wsp.com> Cc: Stacey Nelson <snelson@propanetank.com>; Brian Kliesch <BKliesch@propanetank.com>; Alan Humpherys <ahumpherys@utah.gov> Subject: Re: Quality Steels Status Stacey, We have redone Quality Steel (QS) engineering review, only to have it not pass our specificaons. I told you that we would have a copy of the engineering review for QS to inspect this week. Here's the problem we have. We have done the analysis of how much xylene and methyl methacrylate (MMA) is present from QS's new operaons. The amount stated in the SDS for each painng chemical with xylene and MMA was used in our calculaon. Both of these chemicals are listed in the SDS's as 0.3% by weight each. We used this value and the Division of Air Quality's (DAQ) theorecal modeling threshold. We used the emission value, in lbs/hr, at less than 20 meters with fugive release for both chemicals. It isn't clear to us that QS used the DAQ threshold value though, since it wasn't presented in QS's calculaons. We used the addional hours of operaon at 2,000 hrs/yr. This resulted in 0.066 tons/yr of xylene and 0.031 of MMA. This is not zero HAPs. Could we include the 0.066 tons/yr xylene and 0.031 tons/yr MMA into QS's permit? Please let us know if this is acceptable or not. 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…28/56 Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov On Fri, Jun 2, 2023 at 8:47 AM Tim Dejulis <tdejulis@utah.gov> wrote: I'll go ahead and make a comment describing the HAP situaon so that this will answer any quesons that might arise. Look for a copy of the ER to QS to inspect next week. Thank you for assisng me with this! Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…29/56 On Thu, Jun 1, 2023 at 12:57 PM Zopff, David <david.zopff@wsp.com> wrote: Tim, Thanks for the note. Hope all is well. I found some correspondence from March regarding these chemicals. The HDMI present is the polymer not the monomer, so it is not regulated (note the CAS numbers are different on these related, but distinctly different, chemical compounds). The xylene appears to be present less than the 1% reporting threshold for non-carcinogenic materials. We could ask Sherwin Williams to provide the exact content. I suspect they reported it for industrial hygiene purposes. Let us know if you need further informaon or want to discuss these maers further. BTW, Mr. Smiley le Quality Steel some me ago. Please direct correspondence to Stacey Nelson. Logo WSP David Zopff Assistant VP - Environmental Engineer Professional Engineer T+ 1 502-267-2362 M+ 1 502-643-7211 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…30/56 WSP USA 11003 Bluegrass Parkway, #690 Louisville, Kentucky, USA 40299 wsp.com From: Tim Dejulis <tdejulis@utah.gov> Sent: Thursday, June 1, 2023 2:47 PM To: Charles Smiley <csmiley@propanetank.com> Cc: Zopff, David <david.zopff@wsp.com> Subject: Quality Steels Status CAUTION: External email. Please do not click on links/aachments unless you know the content is genuine and safe. Charles, Please accept my apologies for taking so long to get through the process of geng Quality Steels (QS) engineering review (ER) ready. QS been paent with me throughout our process and I appreciate this. We have one queson for QS. It says in the NOI that "...no HAPs are present..." in describing the emission esmates, however we find two chemicals in the SDS submied that show that HAPs are present (hexamethylene diisocyanate and xylene). Does QS not want these two chemicals included? This would surely be on compliances radar when they inspect this source. I can certainly put them into the ER with a noce from QS to the DAQ to take out the "...no HAPs are present..." statement from the NOI. Please advise. 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…31/56 Image removed by sender. Division Name Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov This message is the property of John Wood Group PLC and/or its subsidiaries and/or affiliates and is intended only for the named recipient(s). Its contents (including any attachments) may be confidential, legally privileged or otherwise protected from disclosure by law. Unauthorized use, copying, distribution or disclosure of any of it may be unlawful and is strictly prohibited. We assume no responsibility to persons other than the intended named recipient(s) and do not accept liability for any errors or omissions which are a result of email transmission. If you have received this message in error, please notify us immediately by reply email to the sender and confirm that the original message and any attachments and copies have been destroyed and deleted from your system. 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For more information on our privacy practices and your data protection rights, please see our privacy notice at https://www.woodplc.com/policies/privacy-notice 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…32/56 NOTICE: This communication and any attachments ("this message") may contain information which is privileged, confidential, proprietary or otherwise subject to restricted disclosure under applicable law. This message is for the sole use of the intended recipient(s). Any unauthorized use, disclosure, viewing, copying, alteration, dissemination or distribution of, or reliance on, this message is strictly prohibited. If you have received this message in error, or you are not an authorized or intended recipient, please notify the sender immediately by replying to this message, delete this message and all copies from your e-mail system and destroy any printed copies. -LAEmHhHzdJzBlTWfa4Hgs7pbKl -- Jon L. Black | Manager | Major New Source Review 801.536.4047 (office) | 801.536.4099 (fax) | 385.306.6511 (cell) 195 North 1950 West, Salt Lake City, UT 84116 Emails to and from this email address may be considered public records and thus subject to Utah GRAMA requirements. Tim Dejulis <tdejulis@utah.gov>Mon, Oct 30, 2023 at 4:40 PM To: Brian Kliesch <bkliesch@propanetank.com> Brian, We offered Quality Steel (QS) a copy of the engineering review (ER) to inspect for any details that we might have missed while processing it. This is the last step in our process before we begin the 30-day public comment period. Then the ozone nonattainment state implementation plan came into play, while we waited for QS to 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…33/56 sign off on the ER. This means that what was originally in QS' proposal couldn't be satisfied without undergoing a reasonably available control technology (RACT) analysis. I don't know whether you know what goes into a best available control technology (BACT) analysis, but in the RACT, we would impose a control method for volatile organic compounds (VOC), rather than letting environmental, economic, or energy considerations dictate what should be applied to QS in a BACT analysis. David's been great to work with and his work will be coming to the DAQ soon. If you have any questions in the meantime, please let me know. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov [Quoted text hidden] [Quoted text hidden] [Quoted text hidden] [Quoted text hidden] [Quoted text hidden] [Quoted text hidden] [Quoted text hidden] [Quoted text hidden] [Quoted text hidden] [Quoted text hidden] [Quoted text hidden] [Quoted text hidden] [Quoted text hidden] [Quoted text hidden] [Quoted text hidden] 801.536.4047 (office) | 801.536.4099 (fax) | 385.306.6511 (cell) [Quoted text hidden] 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…34/56 Brian Kliesch <bkliesch@propanetank.com>Tue, Oct 31, 2023 at 4:57 AM To: Tim Dejulis <tdejulis@utah.gov> Thanks Tim it is my understanding that if we stay under the 50-ton VOC limit that new controls would not be necessary. I understand the terminology but none of my previous facilities were in a non-attainment area. All my facilities were automotive plastic, and we were under the exemption for thermoplastic resins. We tracked VOC’s and HAPs to verify that we stayed under the exemption limits. Any guidance and education that you can provide me is welcome. [Quoted text hidden] Zopff, David <david.zopff@wsp.com>Tue, Nov 7, 2023 at 1:23 PM To: Tim Dejulis <tdejulis@utah.gov> Cc: Jon Black <jlblack@utah.gov>, Alan Humpherys <ahumpherys@utah.gov>, "BKliesch@propanetank.com" <bkliesch@propanetank.com>, Anthony Torres <atorres@propanetank.com>, Corey Fowler <cfowler@propanetank.com> Tim, Attached are a revised application letter with HAP calculations, EDS sheets from Sherwin Williams, and the spreadsheet calculations. We tried to match your HAP numbers exactly but still have some minor differences. We did identify one more Hap, ethylbenzene present in trace quantities. Quality Steel will include HAPs in future emission reports. Let us know if you need anything else. Thanks for your patience, [Quoted text hidden] 3 attachments WJO Paint Emissions 11.8.23.xlsx 41K EDS combined.pdf 518K 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…35/56 Quality Steel - Appl Revision 11.2023.pdf 303K Tim Dejulis <tdejulis@utah.gov>Thu, Nov 16, 2023 at 1:03 PM To: "Zopff, David" <david.zopff@wsp.com> Cc: Jon Black <jlblack@utah.gov>, Alan Humpherys <ahumpherys@utah.gov>, "BKliesch@propanetank.com" <bkliesch@propanetank.com>, Anthony Torres <atorres@propanetank.com>, Corey Fowler <cfowler@propanetank.com> This is great, thank you! I will look at this information and get back to you soon. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov [Quoted text hidden] Zopff, David <david.zopff@wsp.com>Thu, Nov 16, 2023 at 1:27 PM To: Tim Dejulis <tdejulis@utah.gov> Thanks Tim, Just give me a call if needed. [Quoted text hidden] Tim Dejulis <tdejulis@utah.gov>Mon, Nov 27, 2023 at 10:35 AM To: "Zopff, David" <david.zopff@wsp.com>, Anthony Torres <atorres@propanetank.com>, Corey Fowler <cfowler@propanetank.com>, Brian Kliesch <BKliesch@propanetank.com> David, Looking through the calculations for the plant, "WJO Paint Emissions 11.08.23", it shows a total VOC emitted at Quality Steel of 261 tpy! In "Quality Steel - Appl Revision2" it shows 49.3 tpy Could we have the revised calculations in "WJO Plant Emissions" re-submitted to us. I will go ahead with the VOCs at 49.3 tpy in the meantime. Thank you. 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…36/56 Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov [Quoted text hidden] Tim Dejulis <tdejulis@utah.gov>Mon, Nov 27, 2023 at 11:05 AM To: "Zopff, David" <david.zopff@wsp.com>, Anthony Torres <atorres@propanetank.com>, Corey Fowler <cfowler@propanetank.com>, Brian Kliesch <BKliesch@propanetank.com> One more thing in "WJO Calculations 11.08.23." There are six HAPs present in the summary calculations, greater than zero, but in the language of the requirements, condition II.B.2.e it lets us know that no chemicals with HAPs will be used in the spray booth. Could Quality Steel rectify this HAPs situation for us? I'm going forward with the statement that no HAPs are being emitted by the paint booth, unless new information arrives. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov [Quoted text hidden] Zopff, David <david.zopff@wsp.com>Mon, Nov 27, 2023 at 1:55 PM To: Tim Dejulis <tdejulis@utah.gov> Cc: Brian Kliesch <BKliesch@propanetank.com>, Anthony Torres <atorres@propanetank.com>, Corey Fowler <cfowler@propanetank.com> Tim, Looking at the calculations, the 49.3 tpy VOC is our best estimate of emissions once operations expand from 2500 to 3500 hours per year. Cannot find the 261 tpy you reference. Also, there are only 3 HAPs listed in the calculations; xylene, MMA, and ethylbenzene. The same three are listed twice (once showing the concentration in the coatings, and then again below that with the emissions calculations). Sorry for the confusion on that. 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…37/56 It appears the confusion regarding the presence of HAPs is that Quality Steel understood in 2019 from Sherwin Williams that the new coatings were HAPS-free, but in reality the concentrations are just less than the Subpart MMMM applicability thresholds (as stated in the SW letter). I was not involved in the last modification of the approval order (2019), but my understanding is that Quality Steel switched to what they understood to be “HAPs-free” coating systems as advertised by Sherwin-Williams, hence stated that in the 2019 application. Sherwin Williams certifies these coatings have HAPs less than the concentrations stated in the definition of “non-HAP coatings”, as defined in 40 CFR 63.9381, and are therefore not subject to Subpart MMMM. Def: “Non-HAP Coating” means, for the purposes of this subpart, a coating that contains no more than 0.1 percent by mass of any individual organic HAP that is listed in Table 5 to this subpart and no more than 1.0 percent by mass for any other individual HAP. https://www.ecfr.gov/current/title-40/chapter-I/subchapter-C/part-63/subpart-MMMM#63.3981 Moving forward, Quality Steel will accept a revised approval order acknowledging: 1) the HAP emissions and 2) that the non-HAP coatings are exempt from Subpart MMMM. We will gladly report the actual HAP emissions on an ongoing basis. Please feel free to give me a call if needed. Thanks David David Zopff Assistant VP - Environmental Engineer Professional Engineer T+ 1 502-267-2362 M+ 1 502-643-7211 WSP USA 11003 Bluegrass Parkway, #690 Louisville, Kentucky, USA 40299 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…38/56 wsp.com From: Tim Dejulis <tdejulis@utah.gov> Sent: Monday, November 27, 2023 12:35 PM To: Zopff, David <david.zopff@wsp.com>; Anthony Torres <atorres@propanetank.com>; Corey Fowler <cfowler@propanetank.com>; Brian Kliesch <BKliesch@propanetank.com> Subject: Re: Quality Steels Status David, Looking through the calculations for the plant, "WJO Paint Emissions 11.08.23", it shows a total VOC emitted at Quality Steel of 261 tpy! In "Quality Steel - Appl Revision2" it shows 49.3 tpy Could we have the revised calculations in "WJO Plant Emissions" re-submitted to us. I will go ahead with the VOCs at 49.3 tpy in the meantime. Thank you. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov On Thu, Nov 16, 2023 at 1:27 PM Zopff, David <david.zopff@wsp.com> wrote: Thanks Tim, 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…39/56 Just give me a call if needed. David Zopff Assistant VP - Environmental Engineer Professional Engineer T+ 1 502-267-2362 M+ 1 502-643-7211 WSP USA 11003 Bluegrass Parkway, #690 Louisville, Kentucky, USA 40299 wsp.com From: Tim Dejulis <tdejulis@utah.gov> Sent: Thursday, November 16, 2023 3:04 PM To: Zopff, David <david.zopff@wsp.com> Cc: Jon Black <jlblack@utah.gov>; Alan Humpherys <ahumpherys@utah.gov>; BKliesch@propanetank.com; Anthony Torres <atorres@propanetank.com>; Corey Fowler <cfowler@propanetank.com> Subject: Re: Quality Steels Status This is great, thank you! I will look at this information and get back to you soon. 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…40/56 Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov On Tue, Nov 7, 2023 at 1:24 PM Zopff, David <david.zopff@wsp.com> wrote: Tim, Attached are a revised application letter with HAP calculations, EDS sheets from Sherwin Williams, and the spreadsheet calculations. We tried to match your HAP numbers exactly but still have some minor differences. We did identify one more Hap, ethylbenzene present in trace quantities. Quality Steel will include HAPs in future emission reports. Let us know if you need anything else. Thanks for your patience, David 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…41/56 David Zopff Assistant VP - Environmental Engineer Professional Engineer T+ 1 502-267-2362 M+ 1 502-643-7211 WSP USA 11003 Bluegrass Parkway, #690 Louisville, Kentucky, USA 40299 wsp.com From: Tim Dejulis <tdejulis@utah.gov> Sent: Friday, October 27, 2023 3:39 PM To: Zopff, David <david.zopff@wsp.com> Cc: Alan Humpherys <ahumpherys@utah.gov>; Jon Black <jlblack@utah.gov>; BKliesch@propanetank.com; Anthony Torres <atorres@propanetank.com>; Corey Fowler <cfowler@propanetank.com> Subject: Re: Quality Steels Status Thank you for the update. I will follow up next week then. 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…42/56 Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov On Fri, Oct 27, 2023 at 1:12 PM Zopff, David <david.zopff@wsp.com> wrote: Hey Tim, we have been working on it and I think it is ready to go early next week. Thank you for your patience. Thanks, David David Zopff PE Asst.VP-Environmental Engineer 11003 Bluegrass Parkway #690 Louisville, Kentucky 40299 Direct: +1 (502) 471-2362 Mobile: +1 (502) 643-7211 www.WSP.com From: Tim Dejulis <tdejulis@utah.gov> Sent: Friday, October 27, 2023 2:34:42 PM To: Zopff, David <david.zopff@wsp.com> Cc: Alan Humpherys <ahumpherys@utah.gov>; Jon Black <jlblack@utah.gov>; BKliesch@propanetank.com <bkliesch@propanetank.com>; Anthony Torres <atorres@propanetank.com>; Corey Fowler <cfowler@propanetank.com> Subject: Re: Quality Steels Status 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…43/56 David, We're still waiting for the updated calculation's for the revised operations at Quality Steel, to keep the emissions of VOC below 50 tpy. How can we be of assistance in getting this information submitted soon? Please let us know where we are at with this project. Thank you. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov On Mon, Sep 11, 2023 at 12:25 PM Zopff, David <david.zopff@wsp.com> wrote: Hi Tim, FYI, Stacey has moved to a new role, and Anthony Torres is now the Plant Manager at the West Jordan facility. We have recently reached an agreement for me to revise the application to reflect the 50 ton VOC limit and include the HAP emissions. Working through it now and hope to have all changes to you by the end of the month. Best regards, 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…44/56 David Logo WSP David Zopff Assistant VP - Environmental Engineer Professional Engineer T+ 1 502-267-2362 M+ 1 502-643-7211 WSP USA 11003 Bluegrass Parkway, #690 Louisville, Kentucky, USA 40299 wsp.com From: Tim Dejulis <tdejulis@utah.gov> Sent: Monday, September 11, 2023 1:53 PM To: Zopff, David <david.zopff@wsp.com>; Stacey Nelson <snelson@propanetank.com> Cc: Alan Humpherys <ahumpherys@utah.gov>; Jon Black <jlblack@utah.gov> Subject: Re: Quality Steels Status CAUTION: External email. Please do not click on links/attachments unless you know the content is genuine and safe. Stacey, 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…45/56 I received a phone call a few weeks ago from David, addressing why we need changes to the current emission estimates due to the situation with ozone. We discussed how the plant doesn't have the room for the additional pollution control equipment and it was decided that we will undergo a different approach. I was supposed to get another email from you Stacey, with the outlines of where Quality Steel wanted to go moving forward, but I haven't received anything yet. How will Quality Steel approach staying below 50 tons/yr of VOC? If I can be of any assistance, please let me know. On Tue, Aug 8, 2023 at 8:17 AM Tim Dejulis <tdejulis@utah.gov> wrote: David, What is the answer to our questions? Please let us know if you have any questions or concerns. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov On Tue, Jul 11, 2023 at 11:13 AM Tim Dejulis <tdejulis@utah.gov> wrote: David, We have several SDS' in Quality Steels (QS) current Notice of Intent listing the MMA and the xylene in their formulations. Is the use of these nine SDS', listed in the supplemental letter sent to us on September 30, 2022, useless information now? Please advise us. The date of the serious ozone nonattainment area reclassification will be February 2025, but in order for the DAQ to be prepared for this, we must have several things in place before that. We expect the new application to be submitted this month, July 2023, to make the changes to lower the 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…46/56 VOC or NOx below 50 tons per year. We need QS RACT to be submitted in January 2024, so we don't have much time to get this current project through our permitting process before we would need to have it be resubmitted in order to go back through DAQ's permitting process again. We understand the contractual obligations QS is under right now. The current engineering review is currently in QS hands though. We haven't started the public comment period because we're waiting for a signature from Mr. Nelson on that engineering review. If QS would like to discuss the serious ozone NA area or any other issue, please let me know. Thank you. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov On Sun, Jul 9, 2023 at 11:35 PM Jon Black <jlblack@utah.gov> wrote: Thank you for the update on this source. I will pass along the information to Ana and John. Let me know if you have any questions at all. Thanks again, Jon On Fri, Jul 7, 2023 at 12:51 PM Zopff, David <david.zopff@wsp.com> wrote: 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…47/56 Tim, Thank you for the heads up regarding the ozone non-attainment area designations. We will review our options for future compliance, but we need the additional capacity to meet our contractual obligations in the short term. Please continue processing the current request for a 65-ton limit. Please let us know when the agency establishes deadlines for compliance with the new ozone standards and/or submittal of an application for a new approval. With regard to the xylene and MMA HAPs, please find the attached HAPs statement and Environmental Data Sheets (EDS) from Sherwin- Williams for our product lines. While we believe they meet the requirements to be considered HAP-free products, we understand you need to track those emissions and include them in our approval, and we will incorporate those in our emissions calculations and reporting. Thanks again, David David Zopff Assistant VP - Environmental Engineer Professional Engineer T+ 1 502-267-2362 M+ 1 502-643-7211 WSP USA 11003 Bluegrass Parkway, #690 Louisville, Kentucky, USA 40299 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…48/56 wsp.com From: Tim Dejulis <tdejulis@utah.gov> Sent: Friday, July 7, 2023 10:50 AM To: Stacey Nelson <snelson@propanetank.com> Cc: Zopff, David <david.zopff@wsp.com>; Brian Kliesch <bkliesch@propanetank.com>; Alan Humpherys <ahumpherys@utah.gov>; Jon Black <jlblack@utah.gov> Subject: Re: Quality Steels Status Stacey, An issue came up with regards to Quality Steel's (QS) effort at adding a shift to their production that we should make you aware of. During a recent staff meeting we were told that in 2025, areas within the Wasatch front in Utah will be in serious nonattainment for ozone. Ozone is created by a combination of VOCs and NOx. If either of these emissions is above 50 tons/yr, the source will be considered major, requiring a Title V permit or will be subject to enacting reasonably achievable control technology (RACT) measures to have each of these emissions below 50 tons/yr. A source enacting RACT must have one or more of the controls that they have proposed in their best available control technology (BACT) review, but we don't consider the environmental, energy, or economic cost in the RACT analysis like we do in the BACT analysis. One or more of the controls for the paint booth would have to be installed, if QS wants to expand their production to an additional shift. QS has a choice in front of them then. QS could choose to not undergo the additional shift they have asked for. We would have to consider the changes to the xylene and MMA though. QS can choose to install one or more of the measures mentioned in the current BACT analysis, as a RACT measure, to control the VOC emissions from the paint booth in the NOI. Please let us know how QS will deal with this serious ozone nonattainment issue. Please ask me if QS has any questions or concerns about this. Thank you. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…49/56 airquality.utah.gov On Tue, Jun 20, 2023 at 9:23 AM Tim Dejulis <tdejulis@utah.gov> wrote: We would add xylene and MMA to the same condition as the VOC requirements. It would appear just under the VOC. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov On Fri, Jun 16, 2023 at 12:20 PM Stacey Nelson <snelson@propanetank.com> wrote: Would adding Xylene and MMA to the same report as the VOC emissions be acceptable, or would it need to be a separate tracking spreadsheet? Thank you. Stacey Nelson Director of Supply Chain 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…50/56 Quality Steel Corporation West Jordan, UT 385-256-4191 From: Tim Dejulis <tdejulis@utah.gov> Sent: Friday, June 16, 2023 11:49 AM To: Stacey Nelson <snelson@propanetank.com> Cc: Zopff, David <david.zopff@wsp.com>; Brian Kliesch <bkliesch@propanetank.com>; Alan Humpherys <ahumpherys@utah.gov> Subject: Re: Quality Steels Status Stacey, The only expectation we would have is that when we ask QS for their records, at some point in the future, these records would include the requirement to include the xylene and MMA. QS should do the same procedure as they use with reporting their existing emissions of VOC. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…51/56 On Thu, Jun 15, 2023 at 4:05 PM Stacey Nelson <snelson@propanetank.com> wrote: Tim, Before I can answer the question if it is acceptable to add the xylene and MMA into our permit, I need to understand the ramifications that would cause for Quality Steel. What would be the result of adding them to our permit? Thank you. Stacey Nelson Director of Supply Chain Quality Steel Corporation West Jordan, UT 385-256-4191 From: Tim Dejulis <tdejulis@utah.gov> Sent: Thursday, June 15, 2023 2:31 PM To: Zopff, David <david.zopff@wsp.com> Cc: Stacey Nelson <snelson@propanetank.com>; Brian Kliesch <BKliesch@propanetank.com>; Alan Humpherys <ahumpherys@utah.gov> Subject: Re: Quality Steels Status Stacey, 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…52/56 We have redone Quality Steel (QS) engineering review, only to have it not pass our specifications. I told you that we would have a copy of the engineering review for QS to inspect this week. Here's the problem we have. We have done the analysis of how much xylene and methyl methacrylate (MMA) is present from QS's new operations. The amount stated in the SDS for each painting chemical with xylene and MMA was used in our calculation. Both of these chemicals are listed in the SDS's as 0.3% by weight each. We used this value and the Division of Air Quality's (DAQ) theoretical modeling threshold. We used the emission value, in lbs/hr, at less than 20 meters with fugitive release for both chemicals. It isn't clear to us that QS used the DAQ threshold value though, since it wasn't presented in QS's calculations. We used the additional hours of operation at 2,000 hrs/yr. This resulted in 0.066 tons/yr of xylene and 0.031 of MMA. This is not zero HAPs. Could we include the 0.066 tons/yr xylene and 0.031 tons/yr MMA into QS's permit? Please let us know if this is acceptable or not. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov On Fri, Jun 2, 2023 at 8:47 AM Tim Dejulis <tdejulis@utah.gov> wrote: I'll go ahead and make a comment describing the HAP situation so that this will answer any questions that might arise. Look for a copy of the ER to QS to inspect next week. Thank you for assisting me with this! 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…53/56 Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov On Thu, Jun 1, 2023 at 12:57 PM Zopff, David <david.zopff@wsp.com> wrote: Tim, Thanks for the note. Hope all is well. I found some correspondence from March regarding these chemicals. The HDMI present is the polymer not the monomer, so it is not regulated (note the CAS numbers are different on these related, but distinctly different, chemical compounds). The xylene appears to be present less than the 1% reporting threshold for non-carcinogenic materials. We could ask Sherwin Williams to provide the exact content. I suspect they reported it for industrial hygiene purposes. Let us know if you need further information or want to discuss these matters further. BTW, Mr. Smiley left Quality Steel some time ago. Please direct correspondence to Stacey Nelson. Logo WSP David Zopff 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…54/56 Assistant VP - Environmental Engineer Professional Engineer T+ 1 502-267-2362 M+ 1 502-643-7211 WSP USA 11003 Bluegrass Parkway, #690 Louisville, Kentucky, USA 40299 wsp.com From: Tim Dejulis <tdejulis@utah.gov> Sent: Thursday, June 1, 2023 2:47 PM To: Charles Smiley <csmiley@propanetank.com> Cc: Zopff, David <david.zopff@wsp.com> Subject: Quality Steels Status CAUTION: External email. Please do not click on links/attachments unless you know the content is genuine and safe. Charles, Please accept my apologies for taking so long to get through the process of getting Quality Steels (QS) engineering review (ER) ready. QS been patient with me throughout our process and I appreciate this. 12/14/23, 4:08 PM State of Utah Mail - Quality Steels Status https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r6280085533048562753&simpl=msg-a:r6281738016265246881&simpl=msg-f:1768884427664084056&sim…55/56 We have one question for QS. It says in the NOI that "...no HAPs are present..." in describing the emission estimates, however we find two chemicals in the SDS submitted that show that HAPs are present (hexamethylene diisocyanate and xylene). Does QS not want these two chemicals included? This would surely be on compliances radar when they inspect this source. I can certainly put them into the ER with a notice from QS to the DAQ to take out the "...no HAPs are present..." statement from the NOI. Please advise. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov This message is the property of John Wood Group PLC and/or its subsidiaries and/or affiliates and is intended only for the named recipient(s). Its contents (including any attachments) may be confidential, legally privileged or otherwise protected from disclosure by law. Unauthorized use, copying, distribution or disclosure of any of it may be unlawful and is strictly prohibited. We assume no responsibility to persons other than the intended named recipient(s) and do not accept liability for any errors or omissions which are a result of email transmission. If you have received this message in error, please notify us immediately by reply email to the sender and confirm that the original message and any attachments and copies have been destroyed and deleted from your system. 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Black | Manager | Major New Source Review 801.536.4047 (office) | 801.536.4099 (fax) | 385.306.6511 (cell) 195 North 1950 West, Salt Lake City, UT 84116 Emails to and from this email address may be considered public records and thus subject to Utah GRAMA requirements. page 1 of 4 ENVIRONMENTAL DATA SHEET (Certified Product Data Sheet) 01IXF00 [0833] Date of Preparation Jun 27, 2023 PRODUCT NUMBER F63GXH33692-4371 PRODUCT NAME Polane 8910 Polyurethane Enamel, RAL 1014 Tan MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a). All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur on individual batches due to adjustments made during production. Hazard Category (for SARA 311.312) F63GXH33692-4371 = | Acute | Chronic | Fire | Product Weight 9.29 lb/gal Specific Gravity 1.12 FLASH POINT 94 °F TCC Volatile Ingredients Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume p-Chlorobenzotrifluoride 98-56-6 N N N N 10 8 Methyl n-Amyl Ketone 110-43-0 N N N N 24 33 n-Butyl Acetate 123-86-4 N Y N N 5 6 1-Methoxy-2-Propanol Acetate 108-65-6 N N N N 1 2 Dimethyl Glutarate 1119-40-0 N N N N 1 1 F63GXH33692-4371 page 2 of 4 Volatile Organic Compounds - U.S. EPA / Canada F63GXH33692-4371 LB/Gal g/L Coating Density 9.29 1113 By wt By vol Total Volatiles 44.7%54.1% Federally exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 10.0%8.3% Organic Volatiles 34.7%45.8% Percent Non-Volatile 55.3%45.9% VOC Content LB/Gal g/L Total 3.22 385 Less exempt solvents 3.51 420 Of solids 7.01 840 Of solids 0.62 lb/lb 0.62 kg/kg By wt By wt LVP-VOC 33.1% Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.98 Volatile Organic Compounds - California F63GXH33692-4371 LB/Gal g/L Coating Density 9.29 1113 By wt By vol Total Volatiles 44.7%54.1% Exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 10.0%8.3% Organic Volatiles 34.7%45.8% Percent Non-Volatile 55.3%45.9% VOC Content LB/Gal g/L Total 3.22 385 Less exempt solvents 3.51 420 Of solids 7.01 840 Of solids 0.62 lb/lb 0.62 kg/kg By wt By wt LVP-VOC 33.1% Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.79 F63GXH33692-4371 page 3 of 4 Volatile Organic Compounds - South Coast Air Quality Management District, California, US F63GXH33692-4371 LB/Gal g/L Coating Density 9.29 1113 By wt By vol Total Volatiles 44.7%54.1% Exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 10.0%8.3% Organic Volatiles 34.7%45.8% Percent Non-Volatile 55.3%45.9% VOC Content LB/Gal g/L Total 3.22 385 Less exempt solvents 3.51 420 Of solids 7.01 840 Of solids 0.62 lb/lb 0.62 kg/kg Volatile Organic Compounds - EU Directive 2004/42/EC F63GXH33692-4371 By wt By vol Total Volatiles 44.7%54.1% VOC Content LB/Gal g/L Total 4.14 497 Volatile Organic Compounds - EU Directive 2010/75/EU F63GXH33692-4371 By wt By vol Total Volatiles 43.2%52.6% VOC Content LB/Gal g/L Total 4.01 480 Volatile Organic Compounds - Mexico F63GXH33692-4371 LB/Gal g/L Coating Density 9.29 1113 By wt By vol Total Volatiles 44.7%54.1% Exempt solvents Water 0.0%0.0% Organic Volatiles 44.7%54.1% Percent Non-Volatile 55.3%45.9% VOC Content LB/Gal g/L Total 4.14 497 Less exempt solvents 4.14 497 Of solids 9.03 1082 Of solids 0.80 lb/lb 0.80 kg/kg F63GXH33692-4371 page 4 of 4 Hazardous Air Pollutants (Clean Air Act, Section 112(b)) F63GXH33692-4371 LB/Gal kg/L Volatile HAPS 0.00 0.000 Of solids 0.00 0.000 Of solids 0.00 lb/lb 0.00 kg/kg Air Quality Data Density of Organic Solvent Blend 7.67 lb/gal Photochemically Reactive No Additional Regulatory Information US EPA TSCA: Not Applicable Relevant identified uses of the substance or mixture and uses advised against: Not Applicable Waste Disposal Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. page 1 of 4 ENVIRONMENTAL DATA SHEET (Certified Product Data Sheet) 01IXF00 [1323] Date of Preparation Jun 27, 2023 PRODUCT NUMBER F63GXL33693-4371 PRODUCT NAME Polane 8910 Polyurethane Enamel, Star BLue MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a). All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur on individual batches due to adjustments made during production. Hazard Category (for SARA 311.312) F63GXL33693-4371 = | Acute | Chronic | Fire | Product Weight 8.96 lb/gal Specific Gravity 1.08 FLASH POINT 93 °F TCC Volatile Ingredients Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume p-Chlorobenzotrifluoride 98-56-6 N N N N 10 8 2,4-Pentanedione 123-54-6 N N N N 1 1 Methyl n-Amyl Ketone 110-43-0 N N N N 26 34 n-Butyl Acetate 123-86-4 N Y N N 6 7 1-Methoxy-2-Propanol Acetate 108-65-6 N N N N 1 1 Dimethyl Glutarate 1119-40-0 N N N N 1 1 F63GXL33693-4371 page 2 of 4 Volatile Organic Compounds - U.S. EPA / Canada F63GXL33693-4371 LB/Gal g/L Coating Density 8.96 1073 By wt By vol Total Volatiles 47.1%55.1% Federally exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 10.3%8.3% Organic Volatiles 36.8%46.8% Percent Non-Volatile 52.9%44.9% VOC Content LB/Gal g/L Total 3.29 394 Less exempt solvents 3.59 430 Of solids 7.33 879 Of solids 0.69 lb/lb 0.69 kg/kg By wt By wt LVP-VOC 35.1% Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 1.07 Volatile Organic Compounds - California F63GXL33693-4371 LB/Gal g/L Coating Density 8.96 1073 By wt By vol Total Volatiles 47.1%55.1% Exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 10.3%8.3% Organic Volatiles 36.8%46.8% Percent Non-Volatile 52.9%44.9% VOC Content LB/Gal g/L Total 3.29 394 Less exempt solvents 3.59 430 Of solids 7.33 879 Of solids 0.69 lb/lb 0.69 kg/kg By wt By wt LVP-VOC 35.1% Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.85 F63GXL33693-4371 page 3 of 4 Volatile Organic Compounds - South Coast Air Quality Management District, California, US F63GXL33693-4371 LB/Gal g/L Coating Density 8.96 1073 By wt By vol Total Volatiles 47.1%55.1% Exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 10.3%8.3% Organic Volatiles 36.8%46.8% Percent Non-Volatile 52.9%44.9% VOC Content LB/Gal g/L Total 3.29 394 Less exempt solvents 3.59 430 Of solids 7.33 879 Of solids 0.69 lb/lb 0.69 kg/kg Volatile Organic Compounds - EU Directive 2004/42/EC F63GXL33693-4371 By wt By vol Total Volatiles 47.1%55.1% VOC Content LB/Gal g/L Total 4.21 505 Volatile Organic Compounds - EU Directive 2010/75/EU F63GXL33693-4371 By wt By vol Total Volatiles 45.6%53.6% VOC Content LB/Gal g/L Total 4.08 489 Volatile Organic Compounds - Mexico F63GXL33693-4371 LB/Gal g/L Coating Density 8.96 1073 By wt By vol Total Volatiles 47.1%55.1% Exempt solvents Water 0.0%0.0% Organic Volatiles 47.1%55.1% Percent Non-Volatile 52.9%44.9% VOC Content LB/Gal g/L Total 4.21 505 Less exempt solvents 4.21 505 Of solids 9.38 1124 Of solids 0.88 lb/lb 0.88 kg/kg F63GXL33693-4371 page 4 of 4 Hazardous Air Pollutants (Clean Air Act, Section 112(b)) F63GXL33693-4371 LB/Gal kg/L Volatile HAPS 0.00 0.000 Of solids 0.00 0.000 Of solids 0.00 lb/lb 0.00 kg/kg Air Quality Data Density of Organic Solvent Blend 7.66 lb/gal Photochemically Reactive No Additional Regulatory Information US EPA TSCA: Not Applicable Relevant identified uses of the substance or mixture and uses advised against: Not Applicable Waste Disposal Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. page 1 of 4 ENVIRONMENTAL DATA SHEET (Certified Product Data Sheet) 01IXF00 [1443] Date of Preparation Jun 27, 2023 PRODUCT NUMBER F63GXW32595-4371 PRODUCT NAME F63GX POLANE G PLUS 8910 WITH PHX COLORANTS, WHITE RAL 9003 (Pre-Reduced) MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a). All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur on individual batches due to adjustments made during production. Hazard Category (for SARA 311.312) F63GXW32595-4371 = | Acute | Chronic | Fire | Product Weight 10.43 lb/gal Specific Gravity 1.26 FLASH POINT 98 °F TCC Volatile Ingredients Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume Ethylbenzene 100-41-4 N Y Y Y 0.1 < 1 p-Chlorobenzotrifluoride 98-56-6 N N N N 9 8 Methyl n-Amyl Ketone 110-43-0 N N N N 22 34 n-Butyl Acetate 123-86-4 N Y N N 2 3 Dimethyl Glutarate 1119-40-0 N N N N 1 1 F63GXW32595-4371 page 2 of 4 Volatile Organic Compounds - U.S. EPA / Canada F63GXW32595-4371 LB/Gal g/L Coating Density 10.43 1249 By wt By vol Total Volatiles 37.0%50.4% Federally exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 8.9%8.3% Organic Volatiles 28.1%42.1% Percent Non-Volatile 63.0%49.6% VOC Content LB/Gal g/L Total 2.93 351 Less exempt solvents 3.19 383 Of solids 5.90 708 Of solids 0.44 lb/lb 0.44 kg/kg By wt By wt LVP-VOC 26.7% Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.79 Volatile Organic Compounds - California F63GXW32595-4371 LB/Gal g/L Coating Density 10.43 1249 By wt By vol Total Volatiles 37.0%50.4% Exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 8.9%8.3% Organic Volatiles 28.1%42.1% Percent Non-Volatile 63.0%49.6% VOC Content LB/Gal g/L Total 2.93 351 Less exempt solvents 3.19 383 Of solids 5.90 708 Of solids 0.44 lb/lb 0.44 kg/kg By wt By wt LVP-VOC 26.7% Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.65 F63GXW32595-4371 page 3 of 4 Volatile Organic Compounds - South Coast Air Quality Management District, California, US F63GXW32595-4371 LB/Gal g/L Coating Density 10.43 1249 By wt By vol Total Volatiles 37.0%50.4% Exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 8.9%8.3% Organic Volatiles 28.1%42.1% Percent Non-Volatile 63.0%49.6% VOC Content LB/Gal g/L Total 2.93 351 Less exempt solvents 3.19 383 Of solids 5.90 708 Of solids 0.44 lb/lb 0.44 kg/kg Volatile Organic Compounds - EU Directive 2004/42/EC F63GXW32595-4371 By wt By vol Total Volatiles 37.0%50.4% VOC Content LB/Gal g/L Total 3.86 462 Volatile Organic Compounds - EU Directive 2010/75/EU F63GXW32595-4371 By wt By vol Total Volatiles 35.7%48.9% VOC Content LB/Gal g/L Total 3.72 446 Volatile Organic Compounds - Mexico F63GXW32595-4371 LB/Gal g/L Coating Density 10.43 1249 By wt By vol Total Volatiles 37.0%50.4% Exempt solvents Water 0.0%0.0% Organic Volatiles 37.0%50.4% Percent Non-Volatile 63.0%49.6% VOC Content LB/Gal g/L Total 3.85 462 Less exempt solvents 3.85 462 Of solids 7.77 931 Of solids 0.58 lb/lb 0.58 kg/kg F63GXW32595-4371 page 4 of 4 Hazardous Air Pollutants (Clean Air Act, Section 112(b)) F63GXW32595-4371 LB/Gal kg/L Volatile HAPS 0.01 0.001 Of solids 0.03 0.003 Of solids 0.00 lb/lb 0.00 kg/kg Air Quality Data Density of Organic Solvent Blend 7.66 lb/gal Photochemically Reactive No Additional Regulatory Information US EPA TSCA: Not Applicable Relevant identified uses of the substance or mixture and uses advised against: Not Applicable Waste Disposal Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. page 1 of 3 ENVIRONMENTAL DATA SHEET (Certified Product Data Sheet) 04 00 [3468] Date of Preparation Jun 27, 2023 PRODUCT NUMBER V66V280 PRODUCT NAME Polane® Catalyst MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115 This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a). All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur on individual batches due to adjustments made during production. Hazard Category (for SARA 311.312) V66V280 = | Acute | Chronic | Product Weight 9.60 lb/gal Specific Gravity 1.16 FLASH POINT > 200 °F PMCC Volatile Ingredients Not Applicable Volatile Organic Compounds - U.S. EPA / Canada V66V280 LB/Gal g/L Coating Density 9.60 1150 By wt By vol Total Volatiles 0.0%0.0% Federally exempt solvents Water 0.0%0.0% Organic Volatiles 0.0%0.0% Percent Non-Volatile 100.0%100.0% VOC Content LB/Gal g/L Total 0.00 0 Less exempt solvents 0.00 0 Of solids 0.00 0 Of solids 0.00 lb/lb 0.00 kg/kg By wt By wt LVP-VOC 0.0% Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.00 V66V280 page 2 of 3 Volatile Organic Compounds - California V66V280 LB/Gal g/L Coating Density 9.60 1150 By wt By vol Total Volatiles 0.0%0.0% Exempt solvents Water 0.0%0.0% Organic Volatiles 0.0%0.0% Percent Non-Volatile 100.0%100.0% VOC Content LB/Gal g/L Total 0.00 0 Less exempt solvents 0.00 0 Of solids 0.00 0 Of solids 0.00 lb/lb 0.00 kg/kg By wt By wt LVP-VOC 0.0% Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.00 Volatile Organic Compounds - South Coast Air Quality Management District, California, US V66V280 LB/Gal g/L Coating Density 9.60 1150 By wt By vol Total Volatiles 0.0%0.0% Exempt solvents Water 0.0%0.0% Organic Volatiles 0.0%0.0% Percent Non-Volatile 100.0%100.0% VOC Content LB/Gal g/L Total 0.00 0 Less exempt solvents 0.00 0 Of solids 0.00 0 Of solids 0.00 lb/lb 0.00 kg/kg Volatile Organic Compounds - EU Directive 2004/42/EC V66V280 By wt By vol Total Volatiles 0.0%0.0% VOC Content LB/Gal g/L Total 0.00 0 Volatile Organic Compounds - EU Directive 2010/75/EU V66V280 By wt By vol Total Volatiles 0.0%0.0% VOC Content LB/Gal g/L Total 0.00 0 V66V280 page 3 of 3 Volatile Organic Compounds - Mexico V66V280 LB/Gal g/L Coating Density 9.60 1150 By wt By vol Total Volatiles 0.0%0.0% Exempt solvents Water 0.0%0.0% Organic Volatiles 0.0%0.0% Percent Non-Volatile 100.0%100.0% VOC Content LB/Gal g/L Total 0.00 0 Less exempt solvents 0.00 0 Of solids 0.00 0 Of solids 0.00 lb/lb 0.00 kg/kg Hazardous Air Pollutants (Clean Air Act, Section 112(b)) V66V280 LB/Gal kg/L Volatile HAPS 0.00 0.000 Of solids 0.00 0.000 Of solids 0.00 lb/lb 0.00 kg/kg Air Quality Data Density of Organic Solvent Blend Not Applicable Photochemically Reactive No Additional Regulatory Information US EPA TSCA: Not Applicable Relevant identified uses of the substance or mixture and uses advised against: Not Applicable Waste Disposal Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. page 1 of 3 ENVIRONMENTAL DATA SHEET (Certified Product Data Sheet) 04 00 [3230] Date of Preparation Jun 27, 2023 PRODUCT NUMBER V66VC304 PRODUCT NAME 2K Epoxy Hardener MANUFACTURER'S NAME THE SHERWIN-WILLIAMS CO. 101 W. Prospect Avenue Cleveland, OH 44115 This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a). All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur on individual batches due to adjustments made during production. Hazard Category (for SARA 311.312) V66VC304 = | Acute | Chronic | Fire | Product Weight 7.59 lb/gal Specific Gravity 0.91 FLASH POINT 73 °F PMCC Volatile Ingredients Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume 2-Propanol 67-63-0 N N N N 25 29 1-Butanol 71-36-3 N Y Y N 26 30 Volatile Organic Compounds - U.S. EPA / Canada V66VC304 LB/Gal g/L Coating Density 7.59 908 By wt By vol Total Volatiles 50.5%58.9% Federally exempt solvents Water 0.0%0.0% Organic Volatiles 50.5%58.9% Percent Non-Volatile 49.5%41.1% VOC Content LB/Gal g/L Total 3.83 459 Less exempt solvents 3.83 459 Of solids 9.32 1117 Of solids 1.02 lb/lb 1.02 kg/kg By wt By wt LVP-VOC 50.5% Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 1.03 V66VC304 page 2 of 3 Volatile Organic Compounds - California V66VC304 LB/Gal g/L Coating Density 7.59 908 By wt By vol Total Volatiles 50.5%58.9% Exempt solvents Water 0.0%0.0% Organic Volatiles 50.5%58.9% Percent Non-Volatile 49.5%41.1% VOC Content LB/Gal g/L Total 3.83 459 Less exempt solvents 3.83 459 Of solids 9.32 1117 Of solids 1.02 lb/lb 1.02 kg/kg By wt By wt LVP-VOC 50.5% Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.88 Volatile Organic Compounds - South Coast Air Quality Management District, California, US V66VC304 LB/Gal g/L Coating Density 7.59 908 By wt By vol Total Volatiles 50.5%58.9% Exempt solvents Water 0.0%0.0% Organic Volatiles 50.5%58.9% Percent Non-Volatile 49.5%41.1% VOC Content LB/Gal g/L Total 3.83 459 Less exempt solvents 3.83 459 Of solids 9.32 1117 Of solids 1.02 lb/lb 1.02 kg/kg Volatile Organic Compounds - EU Directive 2004/42/EC V66VC304 By wt By vol Total Volatiles 52.1%60.4% VOC Content LB/Gal g/L Total 3.95 473 Volatile Organic Compounds - EU Directive 2010/75/EU V66VC304 By wt By vol Total Volatiles 50.5%58.9% VOC Content LB/Gal g/L Total 3.83 459 V66VC304 page 3 of 3 Volatile Organic Compounds - Mexico V66VC304 LB/Gal g/L Coating Density 7.59 908 By wt By vol Total Volatiles 50.5%58.9% Exempt solvents Water 0.0%0.0% Organic Volatiles 50.5%58.9% Percent Non-Volatile 49.5%41.1% VOC Content LB/Gal g/L Total 3.83 459 Less exempt solvents 3.83 459 Of solids 9.32 1117 Of solids 1.02 lb/lb 1.02 kg/kg Hazardous Air Pollutants (Clean Air Act, Section 112(b)) V66VC304 LB/Gal kg/L Volatile HAPS 0.00 0.000 Of solids 0.00 0.000 Of solids 0.00 lb/lb 0.00 kg/kg Air Quality Data Density of Organic Solvent Blend 6.50 lb/gal Photochemically Reactive No Additional Regulatory Information US EPA TSCA: Not Applicable Relevant identified uses of the substance or mixture and uses advised against: Not Applicable Waste Disposal Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. page 1 of 3 ENVIRONMENTAL DATA SHEET (Certified Product Data Sheet) 03 00 [1033] Date of Preparation Jun 27, 2023 PRODUCT NUMBER V66VL19 PRODUCT NAME Fast 2K Epoxy Hardener MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115 This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a). All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur on individual batches due to adjustments made during production. Hazard Category (for SARA 311.312) V66VL19 = | Acute | Chronic | Fire | Product Weight 7.66 lb/gal Specific Gravity 0.92 FLASH POINT 70 °F PMCC Volatile Ingredients Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume 2-Propanol 67-63-0 N N N N 21 25 1-Butanol 71-36-3 N Y Y N 23 27 Volatile Organic Compounds - U.S. EPA / Canada V66VL19 LB/Gal g/L Coating Density 7.66 918 By wt By vol Total Volatiles 44.6%52.6% Federally exempt solvents Water 0.0%0.0% Organic Volatiles 44.6%52.6% Percent Non-Volatile 55.4%47.4% VOC Content LB/Gal g/L Total 3.41 409 Less exempt solvents 3.41 409 Of solids 7.20 863 Of solids 0.80 lb/lb 0.80 kg/kg By wt By wt LVP-VOC 44.6% Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.92 V66VL19 page 2 of 3 Volatile Organic Compounds - California V66VL19 LB/Gal g/L Coating Density 7.66 918 By wt By vol Total Volatiles 44.6%52.6% Exempt solvents Water 0.0%0.0% Organic Volatiles 44.6%52.6% Percent Non-Volatile 55.4%47.4% VOC Content LB/Gal g/L Total 3.41 409 Less exempt solvents 3.41 409 Of solids 7.20 863 Of solids 0.80 lb/lb 0.80 kg/kg By wt By wt LVP-VOC 44.6% Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.79 Volatile Organic Compounds - South Coast Air Quality Management District, California, US V66VL19 LB/Gal g/L Coating Density 7.66 918 By wt By vol Total Volatiles 44.6%52.6% Exempt solvents Water 0.0%0.0% Organic Volatiles 44.6%52.6% Percent Non-Volatile 55.4%47.4% VOC Content LB/Gal g/L Total 3.41 409 Less exempt solvents 3.41 409 Of solids 7.20 863 Of solids 0.80 lb/lb 0.80 kg/kg Volatile Organic Compounds - EU Directive 2004/42/EC V66VL19 By wt By vol Total Volatiles 46.1%54.1% VOC Content LB/Gal g/L Total 3.53 423 Volatile Organic Compounds - EU Directive 2010/75/EU V66VL19 By wt By vol Total Volatiles 44.6%52.6% VOC Content LB/Gal g/L Total 3.41 409 V66VL19 page 3 of 3 Volatile Organic Compounds - Mexico V66VL19 LB/Gal g/L Coating Density 7.66 918 By wt By vol Total Volatiles 44.6%52.6% Exempt solvents Water 0.0%0.0% Organic Volatiles 44.6%52.6% Percent Non-Volatile 55.4%47.4% VOC Content LB/Gal g/L Total 3.41 409 Less exempt solvents 3.41 409 Of solids 7.20 863 Of solids 0.80 lb/lb 0.80 kg/kg Hazardous Air Pollutants (Clean Air Act, Section 112(b)) V66VL19 LB/Gal kg/L Volatile HAPS 0.00 0.000 Of solids 0.00 0.000 Of solids 0.00 lb/lb 0.00 kg/kg Air Quality Data Density of Organic Solvent Blend 6.50 lb/gal Photochemically Reactive No Additional Regulatory Information US EPA TSCA: Not Applicable Relevant identified uses of the substance or mixture and uses advised against: Not Applicable Waste Disposal Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. page 1 of 4 ENVIRONMENTAL DATA SHEET (Certified Product Data Sheet) 01IXF00 [1773] Date of Preparation Jun 27, 2023 PRODUCT NUMBER E90HXA233-4371 PRODUCT NAME PERFORMANCE COATINGS FINISHES, 2.8 epoxy primer part a Blue MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a). All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur on individual batches due to adjustments made during production. Hazard Category (for SARA 311.312) E90HXA233-4371 = | Acute | Chronic | Fire | Product Weight 10.67 lb/gal Specific Gravity 1.28 FLASH POINT 26 °F TCC Volatile Ingredients Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume Acetone 67-64-1 N Y N N 13 21 Methyl Ethyl Ketone 78-93-3 N Y N N 4 7 Methyl Isobutyl Ketone 108-10-1 N Y Y Y 0.3 < 1 Methyl n-Amyl Ketone 110-43-0 N N N N 11 17 Dimethyl Carbonate 616-38-6 N N N N 7 8 Regulated Compounds SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume Zinc (as Zn)N Y Y N 3 Zinc Compound N N Y N 6 E90HXA233-4371 page 2 of 4 Volatile Organic Compounds - U.S. EPA / Canada E90HXA233-4371 LB/Gal g/L Coating Density 10.67 1279 By wt By vol Total Volatiles 35.7%54.5% Federally exempt solvents Water 0.0%0.0% Acetone 12.8%20.7% Dimethyl Carbonate 6.5%7.8% Organic Volatiles 16.4%25.9% Percent Non-Volatile 64.3%45.5% VOC Content LB/Gal g/L Total 1.74 209 Less exempt solvents 2.44 293 Of solids 3.83 460 Of solids 0.25 lb/lb 0.25 kg/kg By wt By wt LVP-VOC 16.4% Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.48 Volatile Organic Compounds - California E90HXA233-4371 LB/Gal g/L Coating Density 10.67 1279 By wt By vol Total Volatiles 35.7%54.5% Exempt solvents Water 0.0%0.0% Acetone 12.8%20.7% Organic Volatiles 22.9%33.7% Percent Non-Volatile 64.3%45.5% VOC Content LB/Gal g/L Total 2.44 292 Less exempt solvents 3.08 369 Of solids 5.36 643 Of solids 0.35 lb/lb 0.35 kg/kg By wt By wt LVP-VOC 22.9% Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.42 E90HXA233-4371 page 3 of 4 Volatile Organic Compounds - South Coast Air Quality Management District, California, US E90HXA233-4371 LB/Gal g/L Coating Density 10.67 1279 By wt By vol Total Volatiles 35.7%54.5% Exempt solvents Water 0.0%0.0% Acetone 12.8%20.7% Organic Volatiles 22.9%33.7% Percent Non-Volatile 64.3%45.5% VOC Content LB/Gal g/L Total 2.44 292 Less exempt solvents 3.08 369 Of solids 5.36 643 Of solids 0.35 lb/lb 0.35 kg/kg Volatile Organic Compounds - EU Directive 2004/42/EC E90HXA233-4371 By wt By vol Total Volatiles 36.8%55.8% VOC Content LB/Gal g/L Total 3.92 470 Volatile Organic Compounds - EU Directive 2010/75/EU E90HXA233-4371 By wt By vol Total Volatiles 35.7%54.5% VOC Content LB/Gal g/L Total 3.81 456 Volatile Organic Compounds - Mexico E90HXA233-4371 LB/Gal g/L Coating Density 10.67 1279 By wt By vol Total Volatiles 35.7%54.5% Exempt solvents Water 0.0%0.0% Acetone 12.8%20.7% Organic Volatiles 22.9%33.7% Percent Non-Volatile 64.3%45.5% VOC Content LB/Gal g/L Total 2.44 292 Less exempt solvents 3.08 369 Of solids 5.36 643 Of solids 0.35 lb/lb 0.35 kg/kg E90HXA233-4371 page 4 of 4 Hazardous Air Pollutants (Clean Air Act, Section 112(b)) E90HXA233-4371 LB/Gal kg/L Volatile HAPS 0.04 0.004 Of solids 0.09 0.010 Of solids 0.00 lb/lb 0.00 kg/kg Air Quality Data Density of Organic Solvent Blend 6.99 lb/gal Photochemically Reactive No Additional Regulatory Information US EPA TSCA: Not Applicable Relevant identified uses of the substance or mixture and uses advised against: Not Applicable Waste Disposal Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. page 1 of 4 ENVIRONMENTAL DATA SHEET (Certified Product Data Sheet) 01IXF00 [1443] Date of Preparation Jun 27, 2023 PRODUCT NUMBER F63GXA33690-4371 PRODUCT NAME Polane 8910 Polyurethane Enamel, RAL 7038 Aluminum MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a). All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur on individual batches due to adjustments made during production. Hazard Category (for SARA 311.312) F63GXA33690-4371 = | Acute | Chronic | Fire | Product Weight 9.01 lb/gal Specific Gravity 1.08 FLASH POINT 93 °F TCC Volatile Ingredients Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume p-Chlorobenzotrifluoride 98-56-6 N N N N 10 8 2,4-Pentanedione 123-54-6 N N N N 1 1 Methyl n-Amyl Ketone 110-43-0 N N N N 26 34 n-Butyl Acetate 123-86-4 N Y N N 5 7 Dimethyl Glutarate 1119-40-0 N N N N 1 1 F63GXA33690-4371 page 2 of 4 Volatile Organic Compounds - U.S. EPA / Canada F63GXA33690-4371 LB/Gal g/L Coating Density 9.01 1080 By wt By vol Total Volatiles 46.7%55.0% Federally exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 10.3%8.4% Organic Volatiles 36.4%46.6% Percent Non-Volatile 53.3%45.0% VOC Content LB/Gal g/L Total 3.27 392 Less exempt solvents 3.57 428 Of solids 7.28 872 Of solids 0.68 lb/lb 0.68 kg/kg By wt By wt LVP-VOC 34.7% Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 1.06 Volatile Organic Compounds - California F63GXA33690-4371 LB/Gal g/L Coating Density 9.01 1080 By wt By vol Total Volatiles 46.7%55.0% Exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 10.3%8.4% Organic Volatiles 36.4%46.6% Percent Non-Volatile 53.3%45.0% VOC Content LB/Gal g/L Total 3.27 392 Less exempt solvents 3.57 428 Of solids 7.28 872 Of solids 0.68 lb/lb 0.68 kg/kg By wt By wt LVP-VOC 34.7% Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.84 F63GXA33690-4371 page 3 of 4 Volatile Organic Compounds - South Coast Air Quality Management District, California, US F63GXA33690-4371 LB/Gal g/L Coating Density 9.01 1080 By wt By vol Total Volatiles 46.7%55.0% Exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 10.3%8.4% Organic Volatiles 36.4%46.6% Percent Non-Volatile 53.3%45.0% VOC Content LB/Gal g/L Total 3.27 392 Less exempt solvents 3.57 428 Of solids 7.28 872 Of solids 0.68 lb/lb 0.68 kg/kg Volatile Organic Compounds - EU Directive 2004/42/EC F63GXA33690-4371 By wt By vol Total Volatiles 46.7%55.0% VOC Content LB/Gal g/L Total 4.21 504 Volatile Organic Compounds - EU Directive 2010/75/EU F63GXA33690-4371 By wt By vol Total Volatiles 45.2%53.5% VOC Content LB/Gal g/L Total 4.07 488 Volatile Organic Compounds - Mexico F63GXA33690-4371 LB/Gal g/L Coating Density 9.01 1080 By wt By vol Total Volatiles 46.7%55.0% Exempt solvents Water 0.0%0.0% Organic Volatiles 46.7%55.0% Percent Non-Volatile 53.3%45.0% VOC Content LB/Gal g/L Total 4.20 504 Less exempt solvents 4.20 504 Of solids 9.35 1120 Of solids 0.87 lb/lb 0.87 kg/kg F63GXA33690-4371 page 4 of 4 Hazardous Air Pollutants (Clean Air Act, Section 112(b)) F63GXA33690-4371 LB/Gal kg/L Volatile HAPS 0.00 0.000 Of solids 0.00 0.000 Of solids 0.00 lb/lb 0.00 kg/kg Air Quality Data Density of Organic Solvent Blend 7.66 lb/gal Photochemically Reactive No Additional Regulatory Information US EPA TSCA: Not Applicable Relevant identified uses of the substance or mixture and uses advised against: Not Applicable Waste Disposal Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. page 1 of 4 ENVIRONMENTAL DATA SHEET (Certified Product Data Sheet) 01IXF00 [1153] Date of Preparation Jun 27, 2023 PRODUCT NUMBER F63GXG32596-4371 PRODUCT NAME F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP, GREEN RAL 6009 (Pre-Reduced) MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a). All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur on individual batches due to adjustments made during production. Hazard Category (for SARA 311.312) F63GXG32596-4371 = | Acute | Chronic | Fire | Product Weight 8.66 lb/gal Specific Gravity 1.04 FLASH POINT 92 °F TCC Volatile Ingredients Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume p-Chlorobenzotrifluoride 98-56-6 N N N N 10 8 Methyl n-Amyl Ketone 110-43-0 N N N N 24 31 n-Butyl Acetate 123-86-4 N Y N N 7 8 1-Methoxy-2-Propanol Acetate 108-65-6 N N N N 4 4 Dimethyl Glutarate 1119-40-0 N N N N 1 1 F63GXG32596-4371 page 2 of 4 Volatile Organic Compounds - U.S. EPA / Canada F63GXG32596-4371 LB/Gal g/L Coating Density 8.66 1037 By wt By vol Total Volatiles 49.7%56.0% Federally exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 10.2%7.9% Organic Volatiles 39.5%48.1% Percent Non-Volatile 50.3%44.0% VOC Content LB/Gal g/L Total 3.41 409 Less exempt solvents 3.71 444 Of solids 7.77 931 Of solids 0.78 lb/lb 0.78 kg/kg By wt By wt LVP-VOC 37.8% Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 1.08 Volatile Organic Compounds - California F63GXG32596-4371 LB/Gal g/L Coating Density 8.66 1037 By wt By vol Total Volatiles 49.7%56.0% Exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 10.2%7.9% Organic Volatiles 39.5%48.1% Percent Non-Volatile 50.3%44.0% VOC Content LB/Gal g/L Total 3.41 409 Less exempt solvents 3.71 444 Of solids 7.77 931 Of solids 0.78 lb/lb 0.78 kg/kg By wt By wt LVP-VOC 37.8% Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.86 F63GXG32596-4371 page 3 of 4 Volatile Organic Compounds - South Coast Air Quality Management District, California, US F63GXG32596-4371 LB/Gal g/L Coating Density 8.66 1037 By wt By vol Total Volatiles 49.7%56.0% Exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 10.2%7.9% Organic Volatiles 39.5%48.1% Percent Non-Volatile 50.3%44.0% VOC Content LB/Gal g/L Total 3.41 409 Less exempt solvents 3.71 444 Of solids 7.77 931 Of solids 0.78 lb/lb 0.78 kg/kg Volatile Organic Compounds - EU Directive 2004/42/EC F63GXG32596-4371 By wt By vol Total Volatiles 49.7%56.0% VOC Content LB/Gal g/L Total 4.30 515 Volatile Organic Compounds - EU Directive 2010/75/EU F63GXG32596-4371 By wt By vol Total Volatiles 48.2%54.6% VOC Content LB/Gal g/L Total 4.17 500 Volatile Organic Compounds - Mexico F63GXG32596-4371 LB/Gal g/L Coating Density 8.66 1037 By wt By vol Total Volatiles 49.7%56.0% Exempt solvents Water 0.0%0.0% Organic Volatiles 49.7%56.0% Percent Non-Volatile 50.3%44.0% VOC Content LB/Gal g/L Total 4.30 515 Less exempt solvents 4.30 515 Of solids 9.78 1172 Of solids 0.98 lb/lb 0.98 kg/kg F63GXG32596-4371 page 4 of 4 Hazardous Air Pollutants (Clean Air Act, Section 112(b)) F63GXG32596-4371 LB/Gal kg/L Volatile HAPS 0.00 0.000 Of solids 0.00 0.000 Of solids 0.00 lb/lb 0.00 kg/kg Air Quality Data Density of Organic Solvent Blend 7.68 lb/gal Photochemically Reactive No Additional Regulatory Information US EPA TSCA: Not Applicable Relevant identified uses of the substance or mixture and uses advised against: Not Applicable Waste Disposal Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. page 1 of 4 ENVIRONMENTAL DATA SHEET (Certified Product Data Sheet) 01IXF00 [2142] Date of Preparation Jun 27, 2023 PRODUCT NUMBER F63GXG33703-4371 PRODUCT NAME Polane 8910 Polyurethane Enamel, RAL 6003 Superior Green MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a). All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur on individual batches due to adjustments made during production. Hazard Category (for SARA 311.312) F63GXG33703-4371 = | Acute | Chronic | Fire | Product Weight 8.68 lb/gal Specific Gravity 1.04 FLASH POINT 92 °F TCC Volatile Ingredients Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume p-Chlorobenzotrifluoride 98-56-6 N N N N 11 9 2,4-Pentanedione 123-54-6 N N N N 1 1 Methyl n-Amyl Ketone 110-43-0 N N N N 26 33 n-Butyl Acetate 123-86-4 N Y N N 6 8 1-Methoxy-2-Propanol Acetate 108-65-6 N N N N 2 2 Dimethyl Glutarate 1119-40-0 N N N N 1 1 F63GXG33703-4371 page 2 of 4 Volatile Organic Compounds - U.S. EPA / Canada F63GXG33703-4371 LB/Gal g/L Coating Density 8.68 1040 By wt By vol Total Volatiles 50.2%56.6% Federally exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 11.0%8.5% Organic Volatiles 39.2%48.1% Percent Non-Volatile 49.8%43.4% VOC Content LB/Gal g/L Total 3.40 407 Less exempt solvents 3.71 445 Of solids 7.84 939 Of solids 0.78 lb/lb 0.78 kg/kg By wt By wt LVP-VOC 37.4% Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 1.11 Volatile Organic Compounds - California F63GXG33703-4371 LB/Gal g/L Coating Density 8.68 1040 By wt By vol Total Volatiles 50.2%56.6% Exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 11.0%8.5% Organic Volatiles 39.2%48.1% Percent Non-Volatile 49.8%43.4% VOC Content LB/Gal g/L Total 3.40 407 Less exempt solvents 3.71 445 Of solids 7.84 939 Of solids 0.78 lb/lb 0.78 kg/kg By wt By wt LVP-VOC 37.4% Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.89 F63GXG33703-4371 page 3 of 4 Volatile Organic Compounds - South Coast Air Quality Management District, California, US F63GXG33703-4371 LB/Gal g/L Coating Density 8.68 1040 By wt By vol Total Volatiles 50.2%56.6% Exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 11.0%8.5% Organic Volatiles 39.2%48.1% Percent Non-Volatile 49.8%43.4% VOC Content LB/Gal g/L Total 3.40 407 Less exempt solvents 3.71 445 Of solids 7.84 939 Of solids 0.78 lb/lb 0.78 kg/kg Volatile Organic Compounds - EU Directive 2004/42/EC F63GXG33703-4371 By wt By vol Total Volatiles 50.2%56.6% VOC Content LB/Gal g/L Total 4.35 521 Volatile Organic Compounds - EU Directive 2010/75/EU F63GXG33703-4371 By wt By vol Total Volatiles 48.6%55.1% VOC Content LB/Gal g/L Total 4.21 504 Volatile Organic Compounds - Mexico F63GXG33703-4371 LB/Gal g/L Coating Density 8.68 1040 By wt By vol Total Volatiles 50.2%56.6% Exempt solvents Water 0.0%0.0% Organic Volatiles 50.1%56.6% Percent Non-Volatile 49.8%43.4% VOC Content LB/Gal g/L Total 4.35 521 Less exempt solvents 4.35 521 Of solids 10.03 1202 Of solids 1.00 lb/lb 1.00 kg/kg F63GXG33703-4371 page 4 of 4 Hazardous Air Pollutants (Clean Air Act, Section 112(b)) F63GXG33703-4371 LB/Gal kg/L Volatile HAPS 0.00 0.000 Of solids 0.00 0.000 Of solids 0.00 lb/lb 0.00 kg/kg Air Quality Data Density of Organic Solvent Blend 7.69 lb/gal Photochemically Reactive No Additional Regulatory Information US EPA TSCA: Not Applicable Relevant identified uses of the substance or mixture and uses advised against: Not Applicable Waste Disposal Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. page 1 of 4 ENVIRONMENTAL DATA SHEET (Certified Product Data Sheet) 01IXF00 [0883] Date of Preparation Jun 27, 2023 PRODUCT NUMBER F63GXH33691-4371 PRODUCT NAME Polane 8910 Polyurethane Enamel, RAL 1001 Desert MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a). All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur on individual batches due to adjustments made during production. Hazard Category (for SARA 311.312) F63GXH33691-4371 = | Acute | Chronic | Fire | Product Weight 9.27 lb/gal Specific Gravity 1.12 FLASH POINT 94 °F TCC Volatile Ingredients Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume p-Chlorobenzotrifluoride 98-56-6 N N N N 9 8 Methyl n-Amyl Ketone 110-43-0 N N N N 24 32 n-Butyl Acetate 123-86-4 N Y N N 5 6 1-Methoxy-2-Propanol Acetate 108-65-6 N N N N 2 2 Dimethyl Glutarate 1119-40-0 N N N N 1 1 F63GXH33691-4371 page 2 of 4 Volatile Organic Compounds - U.S. EPA / Canada F63GXH33691-4371 LB/Gal g/L Coating Density 9.27 1110 By wt By vol Total Volatiles 43.7%53.0% Federally exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 9.2%7.6% Organic Volatiles 34.5%45.4% Percent Non-Volatile 56.3%47.0% VOC Content LB/Gal g/L Total 3.19 383 Less exempt solvents 3.46 415 Of solids 6.81 816 Of solids 0.61 lb/lb 0.61 kg/kg By wt By wt LVP-VOC 33.0% Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.97 Volatile Organic Compounds - California F63GXH33691-4371 LB/Gal g/L Coating Density 9.27 1110 By wt By vol Total Volatiles 43.7%53.0% Exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 9.2%7.6% Organic Volatiles 34.5%45.4% Percent Non-Volatile 56.3%47.0% VOC Content LB/Gal g/L Total 3.19 383 Less exempt solvents 3.46 415 Of solids 6.81 816 Of solids 0.61 lb/lb 0.61 kg/kg By wt By wt LVP-VOC 33.0% Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.78 F63GXH33691-4371 page 3 of 4 Volatile Organic Compounds - South Coast Air Quality Management District, California, US F63GXH33691-4371 LB/Gal g/L Coating Density 9.27 1110 By wt By vol Total Volatiles 43.7%53.0% Exempt solvents Water 0.0%0.0% P-Chlorobenzotrifluoride 9.2%7.6% Organic Volatiles 34.5%45.4% Percent Non-Volatile 56.3%47.0% VOC Content LB/Gal g/L Total 3.19 383 Less exempt solvents 3.46 415 Of solids 6.81 816 Of solids 0.61 lb/lb 0.61 kg/kg Volatile Organic Compounds - EU Directive 2004/42/EC F63GXH33691-4371 By wt By vol Total Volatiles 43.7%53.0% VOC Content LB/Gal g/L Total 4.05 485 Volatile Organic Compounds - EU Directive 2010/75/EU F63GXH33691-4371 By wt By vol Total Volatiles 42.4%51.7% VOC Content LB/Gal g/L Total 3.92 470 Volatile Organic Compounds - Mexico F63GXH33691-4371 LB/Gal g/L Coating Density 9.27 1110 By wt By vol Total Volatiles 43.7%53.0% Exempt solvents Water 0.0%0.0% Organic Volatiles 43.7%53.0% Percent Non-Volatile 56.3%47.0% VOC Content LB/Gal g/L Total 4.05 485 Less exempt solvents 4.05 485 Of solids 8.62 1033 Of solids 0.77 lb/lb 0.77 kg/kg F63GXH33691-4371 page 4 of 4 Hazardous Air Pollutants (Clean Air Act, Section 112(b)) F63GXH33691-4371 LB/Gal kg/L Volatile HAPS 0.00 0.000 Of solids 0.00 0.000 Of solids 0.00 lb/lb 0.00 kg/kg Air Quality Data Density of Organic Solvent Blend 7.64 lb/gal Photochemically Reactive No Additional Regulatory Information US EPA TSCA: Not Applicable Relevant identified uses of the substance or mixture and uses advised against: Not Applicable Waste Disposal Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Client Name of Project Primer Construction Year 2022 Producer Price Index (PPI) for construction year (2022) -Power Boiler and Heat Exchanger Manufacturing: Fabricated Heat Exchangers and Steam Condensers, (PCU3324103324101) 493.3 PPI for reference year (1999) for -Power Boiler and Heat Exchanger Manufacturing: Fabricated Heat Exchangers and Steam Condensers, (PCU3324103324101) 206 Permanent Total Enclosure Total Potential to emit VOC (ton/year) catpured 7.5PTE Capture %100%Volume of PTEEst. Capital Cost of PTE (2002) (Est. $150k each)0 Producer Price Index, 2003 100 Producer Price Index, 2022 286 Capital Cost of PTE (2022)-$ Capital recovery factor,0.071$ Indirect Annual Capital Recovery Cost -$ Estimated O&M Costs (2002) Estimated O&M Costs (2022) Annualized PTE Total Cost Estimate (2022) Annualized PTE Total Cost Estimate (2022), per line PTE Cost of Capture ($/ton VOC captured)-$ Air Flow Requirements per unitAmount of VOCs Controlled (tons/year)7.5 Average Amount of VOCs Controlled (lb/hr)7.5 Concentration of VOC in gas stream (mg/m3)40.7 Combined Air Flow Requirements 49200 Air flow rate, E1 A/B (acfm) Air flow rate, E2 A/B (acfm) Air flow rate, E3 A/B (acfm) Air flow rate, E4 A/B (acfm) Air flow rate, E5 (acfm) Air flow rate, E6 (acfm) Air flow rate, E7 (acfm) Air flow rate, E9 (acfm) Air flow rate, E10 A/B (acfm) Air flow rate, E11 A/B/C (acfm) Air flow rate, E12 (acfm) Total Air Flow Requirements (ACFM)49200 Annual Operating hours 2000 Qualit NA-Process alr Table 3: Estimated Cost of Control for Recuperative TO Estimated Cost of Recuperative TO @ 70% ER ( EPA 453/b-96-001, OAQPS Control Cost Manual, Section 2 Fig. 2.4); See link for reference:325,000$ PPI for construction year (PCU3324103324101-Power Boiler and Heat Exchanger Manufacturing: Fabricated Heat Exchangers and Steam Condensers )493.3 Reference year PPI (1999)206 Estimated Purchased Cost of Recuperative TO (2022)778,342$ Estimated Cost of Recuperative TO Installation, Taxes, Freight, Foundations & 583,756.40$ Estimated Cost of Recuperative TO, Installed (2022)1,362,098.27$ Capital recovery factor 0.0710 Indirect Annual Capital Recovery Cost 96,644.22$ Power - electricity consumption (KW). (Ref: US EPA Air Pollution Control Cost 221.0 Direct Annual Electricity Cost (assumes electricity cost = $0.13 / KW-hr; 8760 57,447.71$ Direct Annual Maintenance Labor Cost, 1 operator per hour per day, or 365 m-9,125.00$ Direct Annual Maintenance Cost = 100% of maintenance labor 9,125.00$ Direct Annual Natural Gas Cost; assumes 2.0 mmBtu/hr burner per 10,000 acfm 83,640.00$ Indirect Annual Cost (overhead, admin, taxes, insurance)=15% of Direct Annual 23,900.66$ Total Annualized Direct & Indirect Cost of Recuperative TO System (25-yr life 279,882.58$ Total Tons VOC Controlled. Assumes 98% control efficiency.7.35 Total Cost Per Ton VOC Controlled ($/ton)38,079$ References: https://download.bls.gov/pub/time.series/pc/pc.data.18.FabricatedMetalProduct Table 4: Estimated Cost of Control for Regenerative TO Estimated Cost of Regenerative TO 95% ER ( EPA 453/b-96-001, OAQPS Control Cost Manual, Section 2, Fig. 2.5)800,000$ PPI for construction year (2022)493.3 Reference year PPI (1999)206 Estimated Purchased Cost of Regenerative TO (2022)1,915,918$ Estimated Cost of Regenerative TO Installation, Taxes, Freight, Foundations & 1,436,938.83$ Estimated Cost of Regenerative TO, Installed (2022)3,352,857.28$ Capital recovery factor 0.071 Indirect Annual Capital Recovery Cost 237,893.46$ Power - electricity consumption (KW). (Ref: US EPA Air Pollution Control Cost 221.0 Direct Annual Electricity Cost (assumes electricity cost = $0.13 / KW-hr; 8760 57,447.71$ Direct Annual Maintenance Labor Cost (365 m-h/year x $25/hr)9,125.00$ Direct Annual Maintenance Cost = 100% of maintenance labor 9,125.00$ Direct Annual Natural Gas Cost 83,640.00$ Indirect Annual Cost (overhead, admin, taxes, insurance)23,900.66$ Total Annualized Direct & Indirect Cost of Regenerative TO System (25-yr life 421,131.83$ Total Tons VOC Controlled 7.35 Total Cost Per Ton VOC Controlled ($/ton)57,297$ Estimated Cost of Fixed Bed Catalytic TO 70% ER (EPA 453/b-96-001, OAQPS Control Cost Manual, Section 2 Fig. 2.6)575,000$ PPI for construction year 2022 (PCU3324103324101-Power Boiler and Heat Exchanger Manufacturing: Fabricated Heat Exchangers and Steam Condensers )493.3 Reference year PPI (1999)206 Estimated Purchased Cost of Catalytic TO (2022)1,377,066$ Estimated Cost of Catalytic TO Installation, Taxes, Freight, Foundations & 1,032,799.79$ Estimated Cost of Catalytic TO, Installed (2022)2,409,866.17$ Capital recovery factor 0.071 Indirect Annual Capital Recovery Cost 170,985.93$ Power - electricity consumption (KW). (Ref: US EPA Air Pollution Control Cost Manual, Section 3.2 Chapter 2 Incinerators, 2.5.2.1 Direct Annual Costs, Equation 2.42) 267.5 Direct Annual Electricity Cost (assumes electricity cost = $0.13 / KW-hr; 8760 69,541.96$ Direct Annual Maintenance Labor Cost (365 m-h/year x $25/hr)9,125.00$ Direct Annual Maintenance Cost = 100% of maintenance labor 9,125.00$ Direct Annual Catalyst Replacement Cost 155,668.37$ Direct Annual Natural Gas Cost 20,910.00$ Indirect Annual Cost (overhead, admin, taxes, insurance)= 15% of Direct Annual 39,655.55$ Total Annualized Direct & Indirect Cost of Catalytic TO System (25-yr life span)475,011.81$ Total Tons VOC Controlled 7.35 Total Cost-effectiveness Per Ton VOC Controlled ($/ton)64,833$ Table 5: Estimated Cost of Control for Catalytic TO QS Assumptions/Notes/Links Topcoat 2 existing booths 2022 493.3 206 https://www3.epa.gov/ttn/catc/dir1/fpte.pdf 12.5 Total Increase of Potential to emit VOC (ton/year)100%PTE Capture %Volume of PTEEst. Capital Cost of PTE (2002) (Est. $150k each) Producer Price Index, 2003 Producer Price Index, 2022 Capital Cost of PTE (2022) Capital recovery factor, Indirect Annual Capital Recovery Cost Estimated O&M Costs (2002) Estimated O&M Costs (2022) Annualized PTE Total Cost Estimate (2022) Annualized PTE Total Cost Estimate (2022), per line -$ PTE Cost of Capture ($/ton VOC captured)Air Flow Requirements per unit12.5 Amount of VOCs Controlled (tons/year) 12.5 Average Amount of VOCs Controlled (lb/hr) 67.8 Concentration of VOC in gas stream (mg/m3) 49200 Combined Air Flow Requirements Air flow rate, E1 A/B (acfm) Air flow rate, E2 A/B (acfm) Air flow rate, E3 A/B (acfm) Air flow rate, E4 A/B (acfm) Air flow rate, E5 (acfm) Air flow rate, E6 (acfm) Air flow rate, E7 (acfm) Air flow rate, E9 (acfm) Air flow rate, E10 A/B (acfm) Air flow rate, E11 A/B/C (acfm) Air flow rate, E12 (acfm) 49200 Total Air Flow Requirements (ACFM) 2000 Increase in operating hours is 2,000 by adding 1 shift ty Steel Producer Price Index (PPI) for -Power Boiler and Heat Exchanger Manufacturing: Fabricated Heat Exchangers and Steam Condensers, (PCU3324103324101) ready enclosed 325,000$ See link for reference: https://www.epa.gov/sites/production/files/2020- 07/documents/cs3-2ch2.pdf 493.3 206 778,265$ 583,698.42$ EPA CCM Section 2.5.2 1,361,962.99$ 0.0710 Assumes 25-yr lifespan at 5% interest, 96,634.62$ Indirect Annual Capital Recovery Cost = CRF x Installed 221.0 Ref: US EPA Air Pollution Control Cost Manual, Section 57,447.71$ Assumes electricity cost = $0.13 / KW-hr; 8760 hrs/yr 9,125.00$ Operator 1 hour per day. 9,125.00$ Maint. Cost =100% of maintenance labor 83,640.00$ Assume 2.0 MMBtu/hr burner per 10,000 acfm at 50% 23,900.66$ = 15% of Direct Annual costs 279,872.99$ 12.25 Assumes 98% control efficiency 22,847$ 800,000$ https://www.epa.gov/sites/production/files/2020- 07/documents/cs3-2ch2.pdf 493.3 206 1,915,918$ 1,436,938.83$ EPA CCM Section 2.5.2 3,352,857.28$ 0.071 Assumes 25-yr lifespan at 5% interest 237,893.46$ Indirect Annual Capital Recovery Cost = CRF x Installed 221.0 Ref: US EPA Air Pollution Control Cost Manual, Section 57,447.71$ Assumes electricity cost = $0.13 / KW-hr; 8760 hrs/yr 9,125.00$ Operator 1 hour per day. 9,125.00$ Maint. Cost =100% of maintenance labor PPI for construction year (PCU3324103324101-Power Boiler and Heat Exchanger Manufacturing: Fabricated Heat Exchangers and Steam Condensers ) PPI for construction year (PCU3324103324101-Power Boiler and Heat Exchanger Manufacturing: Fabricated Heat Exchangers and Steam Condensers ) 83,640.00$ Assume 2.0 MMBtu/hr burner per 10,000 acfm at 50% 23,900.66$ = 15% of Direct Annual costs 421,131.83$ 12.25 Assumes 98% control efficiency 34,378$ Includes cost of PTE for capture, if applicable 575,000$ https://www.epa.gov/sites/production/files/2020- 07/documents/cs3-2ch2.pdf 493.3 206 1,377,066$ 1,032,799.79$ EPA CCM Section 2.5.2 2,409,866.17$ 0.071 Assumes 25-yr lifespan at 5% interest, 170,985.93$ Indirect Annual Capital Recovery Cost = CRF x Installed cost 267.5 Ref: US EPA Air Pollution Control Cost Manual, Section 3.2 Chapter 2 Incinerators, 2.5.2.1 Direct Annual Costs, Equation 2.42 69,541.96$ Assumes electricity cost = $0.13 / KW-hr; 8760 hrs/yr 9,125.00$ Operator 1 hour per day. 9,125.00$ Maint. Cost =100% of maintenance labor 155,668.37$ ($650/cu ft base metal oxide x 100 cu ft x PPI 20,910.00$ Assume 0.5 MMBtu/hr burner per 10,000 acfm at 50% 39,655.55$ = 15% of Direct Annual costs 475,011.81$ 12.25 Assumes 98% control efficiency 38,982$ Includes cost of PTE for capture, if applicable PPI for construction year (PCU3324103324101-Power Boiler and Heat Exchanger Manufacturing: Fabricated Heat Exchangers and Steam Condensers ) 3/23/23, 12:18 PM State of Utah Mail - Is https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r-7937686486928674738&simpl=msg-a:r-51055421984738…1/5 Tim Dejulis <tdejulis@utah.gov> Is 6 messages Tim Dejulis <tdejulis@utah.gov>Mon, Mar 20, 2023 at 1:59 PM To: Stacey Nelson <snelson@propanetank.com>, Charles Smiley <csmiley@propanetank.com> Cc: "Zopff, David L" <david.zopff@woodplc.com>, Alan Humpherys <ahumpherys@utah.gov>, Chad Gilgen <cgilgen@utah.gov> Stacey and Charles, A question has come up regarding whether hexamethylene 1,6 diisocyanate (HMDI) is present in the painting activity at Quality Steel (QS). There is no mention of HMDI being present in the current NOI application. According to a compliance advisory issued to QS from 2020, HMDI was found to be present. Is HMDI included in the painting activity occurring at the West Jordan plant? Please let us know. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov Zopff, David L <david.zopff@woodplc.com>Mon, Mar 20, 2023 at 2:57 PM To: Tim Dejulis <tdejulis@utah.gov> Cc: Alan Humpherys <ahumpherys@utah.gov>, Chad Gilgen <cgilgen@utah.gov>, Stacey Nelson <snelson@propanetank.com>, Shannon Cutts <scutts@propanetank.com> Tim, In the second SDS in the September 30, 2022 supplemental information (attached), the Sherwin Williams Polane Catalyst contains HDMI polymer and is added to each batch of paint in a small quantity as a catalyst. As you know, most of the HMDI used as a catalyst immediately reacts with and triggers the cross-linking of the polyurethane enamel paint resins. We will determine how much of the catalyst is used and get back to you with an estimated emission rate ASAP. David Zopff Assistant VP - Environmental Engineer 3/23/23, 12:18 PM State of Utah Mail - Is https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r-7937686486928674738&simpl=msg-a:r-51055421984738…2/5 Professional Engineer T+ 1 502-267-2362 M+ 1 502-643-7211 WSP USA 11003 Bluegrass Parkway, #690 Louisville, Kentucky, USA 40299 wsp.com From: Tim Dejulis <tdejulis@utah.gov> Sent: Monday, March 20, 2023 3:59 PM To: Stacey Nelson <snelson@propanetank.com>; Charles Smiley <csmiley@propanetank.com> Cc: Zopff, David L <david.zopff@woodplc.com>; Alan Humpherys <ahumpherys@utah.gov>; Chad Gilgen <cgilgen@utah.gov> Subject: Is CAUTION: External email. Please do not click on links/attachments unless you know the content is genuine and safe. Stacey and Charles, A question has come up regarding whether hexamethylene 1,6 diisocyanate (HMDI) is present in the painting activity at Quality Steel (QS). There is no mention of HMDI being present in the current NOI application. According to a compliance advisory issued to QS from 2020, HMDI was found to be present. Is HMDI included in the painting activity occurring at the West Jordan plant? Please let us know. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov 3/23/23, 12:18 PM State of Utah Mail - Is https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r-7937686486928674738&simpl=msg-a:r-51055421984738…3/5 This message is the property of John Wood Group PLC and/or its subsidiaries and/or affiliates and is intended only for the named recipient(s). Its contents (including any attachments) may be confidential, legally privileged or otherwise protected from disclosure by law. Unauthorized use, copying, distribution or disclosure of any of it may be unlawful and is strictly prohibited. We assume no responsibility to persons other than the intended named recipient(s) and do not accept liability for any errors or omissions which are a result of email transmission. If you have received this message in error, please notify us immediately by reply email to the sender and confirm that the original message and any attachments and copies have been destroyed and deleted from your system. If you do not wish to receive future unsolicited commercial electronic messages from us, please forward this email to: unsubscribe@woodplc.com and include “Unsubscribe” in the subject line. If applicable, you will continue to receive invoices, project communications and similar factual, non-commercial electronic communications. Please click http://www.woodplc.com/email-disclaimer for notices and company information in relation to emails originating in the UK, Italy or France. As a recipient of an email from a John Wood Group Plc company, your contact information will be on our systems and we may hold other personal data about you such as identification information, CVs, financial information and information contained in correspondence. For more information on our privacy practices and your data protection rights, please see our privacy notice at https://www.woodplc.com/policies/privacy-notice QSC Letter to Utah DAQ Supplemental 9-30-22.pdf 6011K Tim Dejulis <tdejulis@utah.gov>Mon, Mar 20, 2023 at 3:24 PM To: "Zopff, David L" <david.zopff@woodplc.com> Cc: Alan Humpherys <ahumpherys@utah.gov>, Chad Gilgen <cgilgen@utah.gov>, Stacey Nelson <snelson@propanetank.com>, Shannon Cutts <scutts@propanetank.com> David, I was going off the WJO 2021- 2022 Increase.xlsx spreadsheet Quality Steel gave to us. We need the answer to this question of whether any HMDI is present or not, in Quality Steel's painting process. Please let me know if I can be of further assistance. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov [Quoted text hidden] Chad Gilgen <cgilgen@utah.gov>Tue, Mar 21, 2023 at 4:28 PM 3/23/23, 12:18 PM State of Utah Mail - Is https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r-7937686486928674738&simpl=msg-a:r-51055421984738…4/5 To: Tim Dejulis <tdejulis@utah.gov> Cc: "Zopff, David L" <david.zopff@woodplc.com>, Alan Humpherys <ahumpherys@utah.gov>, Stacey Nelson <snelson@propanetank.com>, Shannon Cutts <scutts@propanetank.com> Tim, The attachment (QSC Letter to Utah DAQ Supplemental 9-30-22) provided in David's email indicates the Polane Catalyst, listed on page 27, is 99.91% Hexamethylene Diisocyanate Polymer. Chad Chad Gilgen | Manager | Minor Source Compliance 385-306-6500 (cell) Emails to and from this email address may be considered public records and thus subject to Utah GRAMA requirements. [Quoted text hidden] Zopff, David L <david.zopff@woodplc.com>Thu, Mar 23, 2023 at 11:24 AM To: Tim Dejulis <tdejulis@utah.gov> Cc: Alan Humpherys <ahumpherys@utah.gov>, Chad Gilgen <cgilgen@utah.gov>, Stacey Nelson <snelson@propanetank.com>, Brian Kliesch <BKliesch@propanetank.com> Tim, I’ve reviewed the documents. The Hexamethylene Diisocyanate Polymer (CAS 28182-81-2) in the Sherwin Williams Polane Catalyst is not the same chemical compound as the hazardous air pollutant (HAP), Hexamethylene-1,6- diisocyanate (CAS 822-06-0). Sherwin Williams identifies these coating materials as “HAP free” coatings according to the SDSs. We are aware there are trace amounts of various HAPs (xylene, methyl methacrylate) in some coatings, which are non-carcinogenic and are less than the 1% reporting threshold. Please let us know if you have additional questions. David Zopff Assistant VP - Environmental Engineer Professional Engineer T+ 1 502-267-2362 M+ 1 502-643-7211 3/23/23, 12:18 PM State of Utah Mail - Is https://mail.google.com/mail/u/0/?ik=67721adfe9&view=pt&search=all&permthid=thread-a:r-7937686486928674738&simpl=msg-a:r-51055421984738…5/5 WSP USA 11003 Bluegrass Parkway, #690 Louisville, Kentucky, USA 40299 wsp.com From: Tim Dejulis <tdejulis@utah.gov> Sent: Monday, March 20, 2023 3:59 PM To: Stacey Nelson <snelson@propanetank.com>; Charles Smiley <csmiley@propanetank.com> Cc: Zopff, David L <david.zopff@woodplc.com>; Alan Humpherys <ahumpherys@utah.gov>; Chad Gilgen <cgilgen@utah.gov> Subject: Is CAUTION: External email. Please do not click on links/attachments unless you know the content is genuine and safe. Stacey and Charles, [Quoted text hidden] [Quoted text hidden] Tim Dejulis <tdejulis@utah.gov>Thu, Mar 23, 2023 at 12:15 PM To: "Zopff, David L" <david.zopff@woodplc.com> Cc: Alan Humpherys <ahumpherys@utah.gov>, Chad Gilgen <cgilgen@utah.gov>, Stacey Nelson <snelson@propanetank.com>, Brian Kliesch <BKliesch@propanetank.com> David, We appreciate you taking the time to answer the question. Thank you. Timothy DeJulis, PE Environmental Engineer | Minor NSR Section P: (385) 306-6523 airquality.utah.gov [Quoted text hidden] 9/23/2020 State of Utah Mail - Quality Steel Inspection (Site ID 11598) https://mail.google.com/mail/u/0?ik=36f4379b4d&view=pt&search=all&permthid=thread-a%3Ar-7009127937192083083&simpl=msg-a%3Ar-26122532…1/4 Chad Gilgen <cgilgen@utah.gov> Quality Steel Inspection (Site ID 11598) 7 messages Chad Gilgen <cgilgen@utah.gov>Wed, Jul 22, 2020 at 3:58 PM To: Alan Humpherys <ahumpherys@utah.gov> Cc: Rik Ombach <ROMBACH@utah.gov> Hello Alan, I conducted an inspection at Quality Steel this morning and wanted to let you know about something I observed that differs from the AO (attached). Condition II.B.1.b indicates there are two stacks. The NOI (attached - page 12 of the pdf) indicates the painting booths have been modified and there are now nine stacks associated with the Prime, Top, and Dryer stacks. The Prime and Top are large paint booths that each have four separate exhaust vents/stacks. Today I observed the information in the NOI was correct over what made it into the final AO. Since this AO was processed as an Administrative Amendment, no modeling was conducted and I don't know if that is something that should have occurred as the source had modified their operations/added emission points. I spoke with Rik and decided I would note the discrepancy in my inspection memo but we will not pursue any compliance action as the information provided as part of their NOI did not make it into the final AO. I don't know if this is something you would like to address as an amendment or if it even needs to be addressed as their only real condition related to emission limits is the VOC limitation in condition II.B.2.b but I wanted to let you know. What are your thoughts? If it's not something you think is worth addressing now, I have also let the source know this is something they should fix in future AO modifications for other reasons. Thanks, Chad Chad Gilgen | Environmental Scientist | Minor Source Compliance 801.536.4237 (office) Emails to and from this email address may be considered public records and thus subject to Utah GRAMA requirements. 2 attachments AN115980008-18.docx 139K DAQ-2018-016403_0.pdf 5958K Alan Humpherys <ahumpherys@utah.gov>Tue, Jul 28, 2020 at 2:21 PM To: Chad Gilgen <cgilgen@utah.gov> Cc: Rik Ombach <ROMBACH@utah.gov> Chad, As long as the actual stack heights comply with the stacks, I don't think there would be an issue with the source. I would want to update the permit the next time they come in for a permit modification. If you have any questions about this, please let me know. 9/23/2020 State of Utah Mail - Quality Steel Inspection (Site ID 11598) https://mail.google.com/mail/u/0?ik=36f4379b4d&view=pt&search=all&permthid=thread-a%3Ar-7009127937192083083&simpl=msg-a%3Ar-26122532…2/4 Thanks, Alan [Quoted text hidden] -- Alan Humpherys Manager | Minor NSR Section P: (801) 536-4142 F: (801) 536-4099 airquality.utah.gov [Quoted text hidden] Chad Gilgen <cgilgen@utah.gov>Tue, Jul 28, 2020 at 3:40 PM To: Alan Humpherys <ahumpherys@utah.gov> Cc: Rik Ombach <ROMBACH@utah.gov> Hi Alan, Thanks for getting back to me. I have let the source know that this is something that should be evaluated in future AO modifications. I will also put an NSR recommendation in my final memo and upload it to Tempo. Thanks, Chad Chad Gilgen | Environmental Scientist | Minor Source Compliance 801.536.4237 (office) Emails to and from this email address may be considered public records and thus subject to Utah GRAMA requirements. [Quoted text hidden] Alan Humpherys <ahumpherys@utah.gov>Tue, Jul 28, 2020 at 3:51 PM To: Chad Gilgen <cgilgen@utah.gov> Cc: Rik Ombach <ROMBACH@utah.gov> Sounds good. Thanks. [Quoted text hidden] Chad Gilgen <cgilgen@utah.gov>Wed, Jul 29, 2020 at 4:35 PM To: Alan Humpherys <ahumpherys@utah.gov> Cc: Rik Ombach <ROMBACH@utah.gov> Hi Alan, I came across something else while reviewing their submitted records that I wanted to let you know about. In the NOI I forwarded to you earlier, the source also requested to have their HAPs limit removed. NSR granted that request. Following my inspection, one of the Safety Data Sheets they provided (copy attached as PPG URETHANE ACTIVATOR Ver. 3 10.18.19) contains Hexamethylene-1,6-diisocyanate (a HAP). This is found on page 3 of the sheet. It's less than 1% but I looked into it a bit further. In the NOI, I found an email where the source sent all of their Safety Data Sheets to 9/23/2020 State of Utah Mail - Quality Steel Inspection (Site ID 11598) https://mail.google.com/mail/u/0?ik=36f4379b4d&view=pt&search=all&permthid=thread-a%3Ar-7009127937192083083&simpl=msg-a%3Ar-26122532…3/4 the DAQ for evaluation (email attached as NOI SDS email). I couldn't find the actual Safety Data Sheets in the NOI so I contacted the source and asked them to send me the Urethane Activator sheet they included as part of their NOI package. It is attached as "PPG Urethane Activator Version 1 - 2017". The formulation they provided for the NOI is the same as the one provided during my inspection. I don't know if this was missed during the NSR evaluation or if the limit is small enough to not require them to have a HAPs limit? Since they provided the information, and NSR removed the HAPs limit, I wanted to let you know. I have let the source know this is something they can address during future AO modifications for other reasons. I will also note it in my memo as a recommendation to NSR, but I didn't feel it merited a compliance action since they followed through with the NOI process. Let me know your thoughts. Thanks, Chad Chad Gilgen | Environmental Scientist | Minor Source Compliance 801.536.4237 (office) Emails to and from this email address may be considered public records and thus subject to Utah GRAMA requirements. [Quoted text hidden] 3 attachments PPG URETHANE ACTIVATOR Ver. 3 10.18.19.pdf 157K PPG Urethane Activator Version 1 - 2017.pdf 146K NOI SDS Email.pdf 1690K Alan Humpherys <ahumpherys@utah.gov>Wed, Jul 29, 2020 at 5:25 PM To: Chad Gilgen <cgilgen@utah.gov> Cc: Rik Ombach <ROMBACH@utah.gov> Chad, Good catch. The source will need to get that added to their permit. I show condition II.B.2.c requires that the source not use any chemicals that contain HAP in the painting operations. If the source is using a chemical in their painting operations that has a HAP in it, they would need to modify their permit to change that condition. Thanks, Alan [Quoted text hidden] Chad Gilgen <cgilgen@utah.gov>Thu, Jul 30, 2020 at 4:15 PM To: Alan Humpherys <ahumpherys@utah.gov> Cc: Rik Ombach <ROMBACH@utah.gov> Hi Alan, Thanks for getting back to me. From a compliance standpoint, the source did everything correctly and NSR removed the 9/23/2020 State of Utah Mail - Quality Steel Inspection (Site ID 11598) https://mail.google.com/mail/u/0?ik=36f4379b4d&view=pt&search=all&permthid=thread-a%3Ar-7009127937192083083&simpl=msg-a%3Ar-26122532…4/4 HAPs limit even though a submitted SDS showed HAPs. Based on this, we will not be requiring them to modify their AO. I will document in my memo that it is something they can address in future modifications for other reasons. If NSR wants to pursue a modification, I don't think the source should be billed as it was something missed on our end. Thanks, Chad Chad Gilgen | Environmental Scientist | Minor Source Compliance 801.536.4237 (office) Emails to and from this email address may be considered public records and thus subject to Utah GRAMA requirements. [Quoted text hidden] 9/23/2020 State of Utah Mail - FW: <EXT>Epoxy Curing Agent https://mail.google.com/mail/u/0?ik=36f4379b4d&view=pt&search=all&permthid=thread-f%3A1673410147902539144&simpl=msg-f%3A16734101479…1/4 Chad Gilgen <cgilgen@utah.gov> FW: <EXT>Epoxy Curing Agent 5 messages Eddie Scow <escow@propanetank.com>Mon, Jul 27, 2020 at 4:17 PM To: "cgilgen@utah.gov" <cgilgen@utah.gov> Cc: Stacey Nelson <snelson@propanetank.com> Chad, Regarding the HAP’S in the Epoxy Curing Agent, our supplier gave us an SDS for the wrong product. Please see attached SDS. This is the correct SDS for the product we use. It does not contain toluene. As for the urethane activator, it contains less than 1% of hexamethylene-diisocyanate. To my understanding, it is not required to report at levels this small. Please correct us if we are mistaken. We are continuing to work on the other items. Thanks Chad. From: Moran, Gus <gmoran@ppg.com> Sent: Monday, July 27, 2020 3:55 PM To: Eddie Scow <escow@propanetank.com> Cc: Stacey Nelson <snelson@propanetank.com> Subject: RE: <EXT>Epoxy Curing Agent Caution: This email originated from a source outside our organization. Do not click on links or open attachments unless you recognize the sender and you know the content is safe. Eddie I have attached correct catalyst you use for your Epoxy Primer. Thanks, Gus 9/23/2020 State of Utah Mail - FW: <EXT>Epoxy Curing Agent https://mail.google.com/mail/u/0?ik=36f4379b4d&view=pt&search=all&permthid=thread-f%3A1673410147902539144&simpl=msg-f%3A16734101479…2/4 From: Eddie Scow <escow@propanetank.com> Sent: Monday, July 27, 2020 5:30 PM To: Moran, Gus Cc: Stacey Nelson Subject: <EXT>Epoxy Curing Agent CAUTION: This email originated from outside of the organization. Do not click links or open attachments unless you recognize the sender and know the content is safe. Good afternoon Gus, Why does this product have HAP’s in it? Please let me know as soon as you can. Thanks. Eddie Scow EHS/T Manager Quality Steel Corp. escow@propanetank.com o- 801-280-7084 c- 801-803-1085 PPG Epoxy Catalyst (High Build) Version 7.pdf 173K Chad Gilgen <cgilgen@utah.gov>Mon, Jul 27, 2020 at 4:50 PM To: Eddie Scow <escow@propanetank.com> Cc: Stacey Nelson <snelson@propanetank.com> Hello Eddie, Thanks for sending over the corrected SDS for the Epoxy Curing Agent. That is helpful. 9/23/2020 State of Utah Mail - FW: <EXT>Epoxy Curing Agent https://mail.google.com/mail/u/0?ik=36f4379b4d&view=pt&search=all&permthid=thread-f%3A1673410147902539144&simpl=msg-f%3A16734101479…3/4 I will check with our permitting group regarding the small amount of HAPs in the Urethane Activator and let you know what I find out. Thanks, Chad Chad Gilgen | Environmental Scientist | Minor Source Compliance 801.536.4237 (office) Emails to and from this email address may be considered public records and thus subject to Utah GRAMA requirements. [Quoted text hidden] Chad Gilgen <cgilgen@utah.gov>Tue, Jul 28, 2020 at 10:53 AM To: Eddie Scow <escow@propanetank.com> Cc: Stacey Nelson <snelson@propanetank.com> Hi Eddie and Stacey, I am still looking into the HAPs question related to the Urethane Activator and was hoping you might be able to provide me with some information. All I can find in our permitting file is a printed copy of an email you sent to the permit writer with an SDS list. The actual SDS documents aren't included. I have included a copy of that email. Do you happen to still have the SDS for PPG Urethane Activator Y-6238GM Ver. 1.01.pdf that was included with this June 12, 2018, email? Also, is this the same Urethane Activator you are currently using? Thanks, Chad Chad Gilgen | Environmental Scientist | Minor Source Compliance 801.536.4237 (office) Emails to and from this email address may be considered public records and thus subject to Utah GRAMA requirements. [Quoted text hidden] NOI SDS Email.pdf 1690K Eddie Scow <escow@propanetank.com>Tue, Jul 28, 2020 at 2:29 PM To: Chad Gilgen <cgilgen@utah.gov> Cc: Stacey Nelson <snelson@propanetank.com> Chad, Attached is the copy of the SDS you are requesting. 9/23/2020 State of Utah Mail - FW: <EXT>Epoxy Curing Agent https://mail.google.com/mail/u/0?ik=36f4379b4d&view=pt&search=all&permthid=thread-f%3A1673410147902539144&simpl=msg-f%3A16734101479…4/4 There are 2 components that have been added to this product since this SDS. Refer to the Urethane Activator SDS I sent to you and compare the 2. The components are tert-butyl acetate and 1,2,4-trimethylbenzene. These 2 components are not on the HAP’s list. I hope this is what you need. Let me know if you have any other questions. Thanks. [Quoted text hidden] PPG Urethane Activator Version 1.pdf 146K Chad Gilgen <cgilgen@utah.gov>Tue, Jul 28, 2020 at 3:39 PM To: Eddie Scow <escow@propanetank.com> Cc: Stacey Nelson <snelson@propanetank.com> Hi Eddie, Thanks for sending that over. It covers everything I needed. Based on what you provided, this SDS indicates the HAP in question (Hexamethylene-1,6-diisocyanate) was present in the information you provided to the DAQ permit writer in 2018 and probably should have been evaluated as part of their permitting process. I don't think there is anything that needs to be addressed in the current approval order but I will make the recommendation to our permitting group that the next time Quality Steel needs to modify the approval order (for other reasons) that the permit writer evaluates if a HAPs limit needs to be included. I will also recommend they change the number of stacks for the paint booths to accurately reflect what is on-site. Let me know if you have any questions. Thanks, Chad Chad Gilgen | Environmental Scientist | Minor Source Compliance 801.536.4237 (office) Emails to and from this email address may be considered public records and thus subject to Utah GRAMA requirements. [Quoted text hidden] 1 of 5 Highway 61 South, P.O. Box 249 Cleveland, MS 38732 Tel: (800) 345-2495 Fax: (662) 843-4048 September 30, 2022 Via U.S. Mail Mr. Tim DeJulis Utah Division of Air Quality 195 North 1950 West P.O. Box 144820 Salt Lake City, UT 84114-4820 Subject: Supplemental Application Documents for Approval Order DAQE-AN115980008-18 Quality Steel Corporation, 5520 W. Old Bingham Highway, West Jordan, UT Dear Mr. Bird: Pursuant to Utah Administrative Code (UAC) Rule R307-415, Permits, this letter contains additional information to supplement our notice of intent (NOI) submitted on or about June 7, 2022 for an increase to the volatile organic compound (VOC) permit limit for our Quality Steel Corporation (QSC) propane tank manufacturing facility in West Jordan, UT. 1)Site Plans – Attachment A 2)Safety Data Sheets (SDS) – Attachment B. While we have not generally changed the types of coatings since the 2017 application, at which time we eliminated hazardous air pollutant (HAP) containing coatings, the attached SDSs are representative of the coatings currently in use at the facility. 3)Best Available Control Technology (BACT) review – Attachment C 4)The source is not required to model pollutant impacts per Rules 307-410-4 and 410-5 because the potential to emit (PTE) of pollutants are below thresholds as follows: Pollutant Existing Pollutant PTE (tpy) Proposed Sitewide Increase in Pollutant PTE (tpy) R307-410-4 Table 1 Increase Threshold Requiring Impact Analysis (tpy) VOC 45.01 20.0 NA Oxides of Nitrogen (NOx) 1.01 0.0 40 Particulate Matter <10 micron (PM10) (non-fugitive) 4.6 0.0 15 PM10 (fugitive emissions + dust) 0.0 0.0 5 PM2.5 (fugitive and non-fugitive) 4.6 0.0 10 Carbon Monoxide (CO) 0.22 0.0 100 Lead 0.0 0.0 0.6 Hazardous Air Pollutants 0.0 0.0 per R307-410-5 Table 2 3 of 5 Highway 61 South, P.O. Box 249 Cleveland, MS 38732 Tel: (800) 345-2495 Fax: (662) 843-4048 Attachment A Site Plans DATUM: PROJECTION: SCALE: MAP BY: DATE: PROJECT #: 7630223002 FIGURE #: 1 Quality SteelSite Location MapCHK'D BY: daniel.conn MW North American 1983 9/28/2022 LEGEND: 3:47:55 PM 1 in=1,000 ft E:\WoodPLC\QualitySteel\Topo_Fig1.mxd Parcel µ0 1,000 Feet 0 100 200 Meters WSP USAEnvironment & Infrastructure Inc.690 Commonwealth Center11003 Bluegrass ParkwayLouisville, KY 40299 TIME: NAD 1983 StatePlaneUtah Central FIPS 4302 Imagery: 24k TOPO - Lark, UT - 1979 PARCEL OWNER: POWELL, LAMAR J. #26-12-152-005 9740 S HAWLEY PARK RD PARCEL OWNER: JK INVESTMENTS LLC #26-11-200-025 5633 W AXEL PARK ROAD PARCEL AREA 2 5511 West Axel Park Rd #26-12-152-003 85,121.26 SQ/FT; 1.95 ACRES PARCEL AREA 3 5601 West Axel Park Rd #26-12-152-006 137,119.95 SQ/FT; 3.15 ACRES PARCEL OWNER: SME STEEL CONTRACTORS INC #26-12-152-002 5530 W OLD BINGHAM HWY PARCEL OWNER: FORESTDALE INVESTMENTS LLC #26-12-153-001 5487 W AXEL PARK RD PARCEL OWNER: TLC RV STORAGE LLC #26-12-153-003 AXEL PARK ROAD OLD BINGHAM HIGHWAY HA W L E Y P A R K R O A D PARCEL OWNER: LAMBSON CONSTRUCTION COMPANY #26-12-151-006 9682 S HAWLEY PARK RD PARCEL OWNER: ALTA SKI LIFTS COMPANY #26-12-151-002 5594 W AXEL PARK RD PARCEL OWNER: ARROW ROCK & STONE LLC #26-12-151-018 5602 W AXEL PARK RD PARCEL AREA 1 5520 West Old Bingham Highway #26-12-152-001 172,506.28 SQ/FT; 3.98 ACRES TOTAL AREA 395,747.49 SQ/FT; 9.09 ACRES ALL WORK AND MATERIALS MUST CONFORM TO THE CITY OF WEST JORDAN STANDARDS AND SPECIFICATIONS QUALITY STEEL BUILDING ADDITION CONSTRUCTION PLANS VICINITY MAP SITE 5601 AXEL PARK ROAD WEST JORDAN, UTAH N.T.S. CLIENT: CARPENTER STRINGHAM ARCHITECTS, LLC REPRESENTATIVE: PASCAL MEYER ENGINEERING CONTACT: ROB POIRIER 8610 SOUTH SANDY PARKWAY SUITE 200 SANDY, UTAH 84070 (801) 984-2846 CONTACT INFORMATION SCALE: 1" = N O R T H 50' 0 25'50'100'150' DRAWING INDEX SHEET DESCRIPTION C0.00 CIVIL COVER SHEET TOPOGRAPHY SURVEY C0.01 GENERAL NOTES, LEGEND AND ABBREVIATIONS C1.01 HORIZONTAL CONTROL PLAN C2.00 OVERALL DRAINAGE PLAN C2.01 GRADING AND DRAINAGE PLAN C2.02 EROSION CONTROL PLAN C5.01 CIVIL DETAILS C5.02 CIVIL DETAILS C5.03 EROSION CONTROL DETAILS EXIST. BUILDING EXIST. BUILDING EXIST. BUILDING PROPOSED BUILDING ADDITION EXIST. SHED Old B i n g h a m H i g h w a y Mo u n t a i n V i e w C o r r i d o r Wells Park Road H a w l e y P a r k R o a d Dannon Way Axel Park Road Ba g l e y P a r k r o a d ") ") ") ") ") DATUM: PROJECTION: SCALE: MAP BY: DATE: PROJECT #: 7630223002 FIGURE #: 2 Quality SteelEmission UnitsCHK'D BY: daniel.conn MW North American 1983 9/28/2022 LEGEND: 7:16:20 PM 1 in=100 ft E:\WoodPLC\QualitySteel\Aerial_Fig2.mxd ")Paint ")Plasma ")Shot Baghouse ")Shot Blaster ")Welding Parcel µ0 100 Feet 0 25 Meters WSP USAEnvironment & Infrastructure Inc.690 Commonwealth Center11003 Bluegrass ParkwayLouisville, KY 40299 TIME: NAD 1983 StatePlaneUtah Central FIPS 4302 Imagery: ESRI World Imagery !( !( !( !( !( !( !( DATUM: PROJECTION: SCALE: MAP BY: DATE: PROJECT #: 7630223002 FIGURE #: 3 Quality Steel - Emission Unit ExhaustCHK'D BY: daniel.conn MW North American 1983 9/28/2022 LEGEND: 3:27:22 PM 1 in=100 ft E:\WoodPLC\QualitySteel\Aerial_Fig3.mxd !(Paint Exhaust Units !(Roof Exhaust Units !(Shot Baghouse Parcel µ0 100 Feet 0 25 Meters WSP USAEnvironment & Infrastructure Inc.690 Commonwealth Center11003 Bluegrass ParkwayLouisville, KY 40299 TIME: NAD 1983 StatePlaneUtah Central FIPS 4302 Imagery: ESRI World Imagery 4 of 5 Highway 61 South, P.O. Box 249 Cleveland, MS 38732 Tel: (800) 345-2495 Fax: (662) 843-4048 Attachment B Safety Data Sheets (SDS) F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) Not available. Liquid. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer :THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. F63GXW32595-4371 F63GXW32595-4371Product code : Product Information Telephone Number :Not available. Regulatory Information Telephone Number :(216) 566-2902 Transportation Emergency Telephone Number :(800) 424-9300 Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 3 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Classification of the substance or mixture : Signal word :Warning Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 5.5% (oral), 14.4% (dermal), 15.4% (inhalation) OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision :7/18/2022 Date of previous issue :6/9/2022 Version :10.02 1/17 F63GXW32595-4371 F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) SHW-85-NA-GHS-US Section 2. Hazards identification Precautionary statements Prevention :Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General :Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified :None known. Flammable liquid and vapor. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Section 3. Composition/information on ingredients Other means of identification :Not available. Substance/mixture CAS number/other identifiers :Mixture Date of issue/Date of revision :7/18/2022 Date of previous issue :6/9/2022 Version :10.02 2/17 F63GXW32595-4371 F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) SHW-85-NA-GHS-US Section 3. Composition/information on ingredients Titanium Dioxide ≥25 - ≤50 13463-67-7 Methyl n-Amyl Ketone ≥10 - ≤25 110-43-0 p-Chlorobenzotrifluoride ≤10 98-56-6 Aspartic Ester ≤10 136210-32-7 Amorphous Silica ≤3 7631-86-9 Aluminum Hydroxide ≤3 21645-51-2 n-Butyl Acetate ≤3 123-86-4 2-Ethyl-1,3-hexanediol ≤1.6 94-96-2 UV Light Absorber ≤0.3 104810-48-2 Bis(pentamethyl-4-piperidyl)sebacate ≤0.3 41556-26-7 Benzotriazole Hydroxyphenyl Polymer ≤0.3 104810-47-1 2-Ethyl-2-(hydroxymethyl)-1,3-propanediol ≤0.3 77-99-6 Xylene, mixed isomers ≤0.3 1330-20-7 Butyl Methacrylate ≤0.3 97-88-1 Ingredient name CAS number% by weight Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Causes serious eye irritation.:Eye contact Potential acute health effects Date of issue/Date of revision :7/18/2022 Date of previous issue :6/9/2022 Version :10.02 3/17 F63GXW32595-4371 F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments :No specific treatment. Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Use dry chemical, CO₂, water spray (fog) or foam. Extinguishing media Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision :7/18/2022 Date of previous issue :6/9/2022 Version :10.02 4/17 F63GXW32595-4371 F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) SHW-85-NA-GHS-US Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides halogenated compounds carbonyl halides metal oxide/oxides Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision :7/18/2022 Date of previous issue :6/9/2022 Version :10.02 5/17 F63GXW32595-4371 F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) SHW-85-NA-GHS-US Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 1/2021). TWA: 10 mg/m³ 8 hours. OSHA PEL (United States, 5/2018). TWA: 15 mg/m³ 8 hours. Form: Total dust Methyl n-Amyl Ketone 110-43-0 ACGIH TLV (United States, 1/2021). TWA: 50 ppm 8 hours. TWA: 233 mg/m³ 8 hours. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 465 mg/m³ 10 hours. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 465 mg/m³ 8 hours. p-Chlorobenzotrifluoride 98-56-6 None. Aspartic Ester 136210-32-7 None. Amorphous Silica 7631-86-9 NIOSH REL (United States, 10/2020). TWA: 6 mg/m³ 10 hours. Aluminum Hydroxide 21645-51-2 ACGIH TLV (United States, 1/2021). TWA: 1 mg/m³ 8 hours. Form: Respirable fraction n-Butyl Acetate 123-86-4 NIOSH REL (United States, 10/2020). TWA: 150 ppm 10 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) CAS # Date of issue/Date of revision :7/18/2022 Date of previous issue :6/9/2022 Version :10.02 6/17 F63GXW32595-4371 F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection TWA: 710 mg/m³ 10 hours. STEL: 200 ppm 15 minutes. STEL: 950 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 150 ppm 8 hours. TWA: 710 mg/m³ 8 hours. ACGIH TLV (United States, 1/2021). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. 2-Ethyl-1,3-hexanediol 94-96-2 None. UV Light Absorber 104810-48-2 None. Bis(pentamethyl-4-piperidyl)sebacate 41556-26-7 None. Benzotriazole Hydroxyphenyl Polymer 104810-47-1 None. 2-Ethyl-2-(hydroxymethyl)-1,3-propanediol 77-99-6 None. Xylene, mixed isomers 1330-20-7 ACGIH TLV (United States, 1/2021). TWA: 100 ppm 8 hours. TWA: 434 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours. Butyl Methacrylate 97-88-1 None. Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada, 6/2021). TWA: 10 mg/m³ 8 hours. Form: Total dust TWA: 3 mg/m³ 8 hours. Form: respirable fraction CA Quebec Provincial (Canada, 6/2021). TWAEV: 10 mg/m³ 8 hours. Form: Total dust. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 10 mg/m³ 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 10 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 20 mg/m³ 15 minutes. TWA: 10 mg/m³ 8 hours. Methyl n-amyl ketone 110-43-0 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 233 mg/m³ 8 hours. 8 hrs OEL: 50 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 50 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 25 ppm 8 hours. TWA: 115 mg/m³ 8 hours. CA Quebec Provincial (Canada, 6/2021). TWAEV: 50 ppm 8 hours. TWAEV: 233 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 60 ppm 15 minutes. TWA: 50 ppm 8 hours. Ingredient name Exposure limits Occupational exposure limits (Canada) CAS # Date of issue/Date of revision :7/18/2022 Date of previous issue :6/9/2022 Version :10.02 7/17 F63GXW32595-4371 F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection n-butyl acetate 123-86-4 CA Alberta Provincial (Canada, 6/2018). 15 min OEL: 200 ppm 15 minutes. 15 min OEL: 950 mg/m³ 15 minutes. 8 hrs OEL: 150 ppm 8 hours. 8 hrs OEL: 713 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 200 ppm 15 minutes. TWA: 150 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA Quebec Provincial (Canada, 6/2021). STEV: 150 ppm 15 minutes. TWAEV: 50 ppm 8 hours. Xylene 1330-20-7 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 100 ppm 8 hours. 15 min OEL: 651 mg/m³ 15 minutes. 15 min OEL: 150 ppm 15 minutes. 8 hrs OEL: 434 mg/m³ 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 100 ppm 8 hours. STEL: 150 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m³ 8 hours. STEV: 150 ppm 15 minutes. STEV: 651 mg/m³ 15 minutes. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. Butyl Methacrylate 97-88-1 CA British Columbia Provincial (Canada, 6/2021). TWA: 50 ppm 8 hours. Methyl n-Amyl Ketone 110-43-0 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 50 ppm 8 hours. n-Butyl Acetate 123-86-4 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 150 ppm 8 hours. STEL: 200 ppm 15 minutes. Exposure limits Occupational exposure limits (Mexico) CAS # Date of issue/Date of revision :7/18/2022 Date of previous issue :6/9/2022 Version :10.02 8/17 F63GXW32595-4371 F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Environmental exposure controls : Section 9. Physical and chemical properties Physical state Melting point/freezing point Liquid. Not available. Not available.Odor pH Not available.Color Not applicable. Not available.Odor threshold : : : : : : Appearance :123°C (253.4°F)Boiling point, initial boiling point, and boiling range The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. Date of issue/Date of revision :7/18/2022 Date of previous issue :6/9/2022 Version :10.02 9/17 F63GXW32595-4371 F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) SHW-85-NA-GHS-US Section 9. Physical and chemical properties Vapor pressure Relative density Solubility 1.35 3.94 [Air = 1] Not available. Evaporation rate 1 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 37°C (98.6°F) [Pensky-Martens Closed Cup] Not applicable. Viscosity Kinematic (40°C (104°F)): >20.5 mm2/s (>20.5 cSt) Partition coefficient: n- octanol/water : : : : : : : : : :Not available. :Lower: 0.9% Upper: 10.5% Decomposition temperature :Not available. Heat of combustion :13.619 kJ/g Aerosol product Molecular weight :Not applicable. Flammability Lower and upper explosion limit/flammability limit Relative vapor density 1.3 kPa (10 mm Hg) Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Methyl n-Amyl Ketone LD50 Oral Rat 1600 mg/kg - p-Chlorobenzotrifluoride LD50 Oral Rat 13 g/kg - n-Butyl Acetate LD50 Dermal Rabbit >17600 mg/kg - LD50 Oral Rat 10768 mg/kg - 2-Ethyl-1,3-hexanediol LD50 Dermal Rabbit 2 g/kg - LD50 Oral Rat 1400 mg/kg - 2-Ethyl-2-(hydroxymethyl) -1,3-propanediol LD50 Oral Rat 14000 mg/kg - Xylene, mixed isomers LC50 Inhalation Gas.Rat 6700 ppm 4 hours Product/ingredient name Result Species Dose Exposure Information on toxicological effects Date of issue/Date of revision :7/18/2022 Date of previous issue :6/9/2022 Version :10.02 10/17 F63GXW32595-4371 F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) SHW-85-NA-GHS-US Section 11. Toxicological information LD50 Oral Rat 4300 mg/kg - Butyl Methacrylate LC50 Inhalation Gas.Rat 4910 ppm 4 hours LD50 Oral Rat 16 g/kg - Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Irritation/Corrosion Titanium Dioxide Skin - Mild irritant Human -72 hours 300 ug I - Methyl n-Amyl Ketone Skin - Mild irritant Rabbit -24 hours 14 mg - Amorphous Silica Eyes - Mild irritant Rabbit -24 hours 25 mg - n-Butyl Acetate Eyes - Moderate irritant Rabbit -100 mg - Skin - Moderate irritant Rabbit -24 hours 500 mg - 2-Ethyl-1,3-hexanediol Eyes - Severe irritant Rabbit -20 mg - Skin - Mild irritant Rabbit -500 mg - Xylene, mixed isomers Eyes - Mild irritant Rabbit -87 mg - Eyes - Severe irritant Rabbit -24 hours 5 mg - Skin - Mild irritant Rat -8 hours 60 uL - Skin - Moderate irritant Rabbit -24 hours 500 mg - Skin - Moderate irritant Rabbit -100 %- Butyl Methacrylate Skin - Mild irritant Rabbit -500 uL - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Specific target organ toxicity (single exposure) Classification Titanium Dioxide -2B - p-Chlorobenzotrifluoride -2B - Amorphous Silica -3 - Xylene, mixed isomers -3 - Product/ingredient name NTPIARCOSHA Date of issue/Date of revision :7/18/2022 Date of previous issue :6/9/2022 Version :10.02 11/17 F63GXW32595-4371 F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) SHW-85-NA-GHS-US Section 11. Toxicological information Specific target organ toxicity (repeated exposure) Methyl n-Amyl Ketone Category 3 -Respiratory tract irritation Category 3 Narcotic effects p-Chlorobenzotrifluoride Category 3 -Respiratory tract irritation n-Butyl Acetate Category 3 -Narcotic effects 2-Ethyl-1,3-hexanediol Category 3 -Respiratory tract irritation Category 3 Narcotic effects Xylene, mixed isomers Category 3 -Respiratory tract irritation Butyl Methacrylate Category 3 -Respiratory tract irritation Name Category Name Category Methyl n-Amyl Ketone Category 2 -- 2-Ethyl-1,3-hexanediol Category 2 -- Xylene, mixed isomers Category 2 -- Aspiration hazard Name Result Xylene, mixed isomers ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs Information on the likely routes of exposure Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness :Not available. Potential acute health effects Date of issue/Date of revision :7/18/2022 Date of previous issue :6/9/2022 Version :10.02 12/17 F63GXW32595-4371 F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) SHW-85-NA-GHS-US Section 11. Toxicological information Not available. May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : Suspected of damaging the unborn child.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :Suspected of damaging fertility. Skin contact Ingestion Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 7542.88 mg/kg Dermal 159521.48 mg/kg Inhalation (vapors)46.55 mg/l Route ATE value Acute toxicity estimates Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Section 12. Ecological information Toxicity Date of issue/Date of revision :7/18/2022 Date of previous issue :6/9/2022 Version :10.02 13/17 F63GXW32595-4371 F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) SHW-85-NA-GHS-US Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name Aspartic Ester -0.25 low 2-Ethyl-2-(hydroxymethyl) -1,3-propanediol -<1 low Xylene, mixed isomers -8.1 to 25.9 low Product/ingredient name Aquatic half-life Photolysis Biodegradability Methyl n-Amyl Ketone --Readily n-Butyl Acetate --Readily Xylene, mixed isomers --Readily Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours Methyl n-Amyl Ketone Acute LC50 131000 µg/l Fresh water Fish - Pimephales promelas 96 hours Amorphous Silica Acute EC50 2.2 g/L Fresh water Daphnia - Daphnia magna - Neonate 48 hours Chronic NOEC 12.5 mg/l Fresh water Daphnia - Daphnia magna - Neonate 21 days n-Butyl Acetate Acute LC50 32 mg/l Marine water Crustaceans - Artemia salina 48 hours Acute LC50 18000 µg/l Fresh water Fish - Pimephales promelas 96 hours 2-Ethyl-1,3-hexanediol Acute LC50 624000 µg/l Fresh water Fish - Ictalurus punctatus - Fingerling 96 hours 2-Ethyl-2-(hydroxymethyl) -1,3-propanediol Acute EC50 13000000 µg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 14400000 µg/l Marine water Fish - Cyprinodon variegatus 96 hours Xylene, mixed isomers Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours Butyl Methacrylate Chronic NOEC 2.6 mg/l Fresh water Daphnia - Daphnia magna - Neonate 21 days Product/ingredient name SpeciesResult Exposure Persistence and degradability Soil/water partition coefficient (KOC) :Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact :Disposal methods Date of issue/Date of revision :7/18/2022 Date of previous issue :6/9/2022 Version :10.02 14/17 F63GXW32595-4371 F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) SHW-85-NA-GHS-US Section 13. Disposal considerations with soil, waterways, drains and sewers. Section 14. Transport information PAINT 3 III PAINT 3 III UN1263 UN1263 -Emergency schedules F-E, S- E DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to IMO instruments No.No. Not available. : Proper shipping name : Not available. : TDG Classification UN1263 PAINT 3 III No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). Mexico Classification UN1263 PAINT 3 III No. - Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. IATA UN1263 PAINT 3 III No. - 128 ERG No. 128 128 ERG No.ERG No. Date of issue/Date of revision :7/18/2022 Date of previous issue :6/9/2022 Version :10.02 15/17 F63GXW32595-4371 F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) SHW-85-NA-GHS-US Section 15. Regulatory information SARA 313 TSCA 5(a)2 proposed significant new use rules: 2,4-Pentanedione SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International regulations International lists : Section 16. Other information 7/18/2022 History Date of printing Date of issue/Date of revision Date of previous issue : : : 7/18/2022 6/9/2022 Hazardous Material Information System (U.S.A.) 2 3 0 *Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. FLAMMABLE LIQUIDS - Category 3 On basis of test data SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method SKIN SENSITIZATION - Category 1 Calculation method CARCINOGENICITY - Category 2 Calculation method TOXIC TO REPRODUCTION - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method Procedure used to derive the classification Classification Justification Date of issue/Date of revision :7/18/2022 Date of previous issue :6/9/2022 Version :10.02 16/17 F63GXW32595-4371 F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) SHW-85-NA-GHS-US Section 16. Other information Version It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. : Indicates information that has changed from previously issued version. Key to abbreviations : 10.02 Notice to reader ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision :7/18/2022 Date of previous issue :6/9/2022 Version :10.02 17/17 F63GXW32595-4371 F63GX POLANE G PLUS 8910 WITH PHX COLORANTS WHITE RAL 9003 (Pre-Reduced) SHW-85-NA-GHS-US Polane® Catalyst Not available. Liquid. US / Canada: (800) 424-9300 Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer :THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. V66V280 V66V280Product code : Product Information Telephone Number :US / Canada: 866-722-9710 Mexico: Not Available Regulatory Information Telephone Number :US / Canada: (216) 566-2902 Mexico: Not Available Transportation Emergency Telephone Number :US / Canada: (800) 424-9300 Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year National contact :Sherwin-Williams Canada Inc. 180 Brunel Road Mississauga, Ontario L4Z 1T5 Canada Section 2. Hazards identification ACUTE TOXICITY (inhalation) - Category 4 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Classification of the substance or mixture : Signal word :Warning Hazard pictograms : GHS label elements Date of issue/Date of revision :7/19/2022 Date of previous issue :6/18/2022 Version :10 1/12 V66V280 Polane® Catalyst SHW-85-NA-GHS-CA Section 2. Hazards identification Precautionary statements Prevention :Wear protective gloves. Wear eye or face protection. Use only outdoors or in a well- ventilated area. Avoid breathing vapor. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response :IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. Take off contaminated clothing and wash it before reuse. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified :None known. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Supplemental label elements FOR INDUSTRIAL USE ONLY. This product must be mixed with other components before use. Before opening the packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS. VAPOR AND SPRAY MIST HARMFUL. Gives off harmful vapor of solvents and isocyanates. DO NOT USE IF YOU HAVE CHRONIC (LONG- TERM) LUNG OR BREATHING PROBLEMS, OR IF YOU HAVE EVER HAD A REACTION TO ISOCYANATES. USE ONLY WITH ADEQUATE VENTILATION. WHERE OVERSPRAY IS PRESENT, A POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR (NIOSH approved) SHOULD BE WORN TO PREVENT EXPOSURE. IF UNAVAILABLE, AN APPROPRIATE PROPERLY FITTED APPROVED NIOSH VAPOR/ PARTICULATE RESPIRATOR MAY BE EFFECTIVE. Follow directions for respirator use. Wear the respirator for the whole time of spraying and until all vapors and mists are gone. If you have any breathing problems during use, LEAVE THE AREA and get fresh air. If problems remain or happen later, IMMEDIATELY call a doctor - If not available get emergency medical treatment. Have this label with you. Reacts with water in closed container to produce pressure which may cause container to burst. : Section 3. Composition/information on ingredients Hexamethylene Diisocyanate Polymer 99.91 28182-81-2 Ingredient name CAS number% by weight Other means of identification :Not available. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Date of issue/Date of revision :7/19/2022 Date of previous issue :6/18/2022 Version :10 2/12 V66V280 Polane® Catalyst SHW-85-NA-GHS-CA Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Description of necessary first aid measures Specific treatments :No specific treatment. Most important symptoms/effects, acute and delayed Inhalation :Harmful if inhaled. May cause respiratory irritation. No known significant effects or critical hazards.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision :7/19/2022 Date of previous issue :6/18/2022 Version :10 3/12 V66V280 Polane® Catalyst SHW-85-NA-GHS-CA Section 4. First aid measures Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. See toxicological information (Section 11) Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision :7/19/2022 Date of previous issue :6/18/2022 Version :10 4/12 V66V280 Polane® Catalyst SHW-85-NA-GHS-CA Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill : Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Hexamethylene Diisocyanate Polymer 28182-81-2 None. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Control parameters Occupational exposure limits (OSHA United States) None. Ingredient name Exposure limits Occupational exposure limits (Canada) Environmental exposure controls : None. Ingredient name Exposure limits Occupational exposure limits (Mexico) CAS # CAS # CAS # Date of issue/Date of revision :7/19/2022 Date of previous issue :6/18/2022 Version :10 5/12 V66V280 Polane® Catalyst SHW-85-NA-GHS-CA Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Liquid. Not available. Not available.Odor pH Not available.Color Evaporation rate Not available. Flash point Closed cup: 193°C (379.4°F) [Pensky-Martens Closed Cup] Not applicable. Not available.Odor threshold : : : : : : : : : Appearance :Not available. :Not available. :Not available. Boiling point, initial boiling point, and boiling range Flammability Lower and upper explosion limit/flammability limit The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. Not available. Date of issue/Date of revision :7/19/2022 Date of previous issue :6/18/2022 Version :10 6/12 V66V280 Polane® Catalyst SHW-85-NA-GHS-CA Section 9. Physical and chemical properties Relative density Solubility 1.15 Not available. Not available. Auto-ignition temperature Not available. Not applicable. Viscosity Kinematic (40°C (104°F)): >20.5 mm2/s (>20.5 cSt) Partition coefficient: n- octanol/water : : : : : : Decomposition temperature :Not available. Heat of combustion :0.039 kJ/g Aerosol product Molecular weight :Not applicable. Relative vapor density Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Hexamethylene Diisocyanate Polymer LC50 Inhalation Dusts and mists Rat 18500 mg/m³1 hours Product/ingredient name Result Species Dose Exposure Carcinogenicity Not available. Mutagenicity Not available. Reproductive toxicity Irritation/Corrosion Hexamethylene Diisocyanate Polymer Eyes - Moderate irritant Rabbit -100 mg - Skin - Moderate irritant Rabbit -500 mg - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Information on toxicological effects Date of issue/Date of revision :7/19/2022 Date of previous issue :6/18/2022 Version :10 7/12 V66V280 Polane® Catalyst SHW-85-NA-GHS-CA Section 11. Toxicological information Teratogenicity Not available. Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Hexamethylene Diisocyanate Polymer Category 3 -Respiratory tract irritation Name Category Not available. Aspiration hazard Not available. Route of exposure Target organs Not available. Information on the likely routes of exposure Inhalation :Harmful if inhaled. May cause respiratory irritation. No known significant effects or critical hazards.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure :Not available. Potential acute health effects Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Date of issue/Date of revision :7/19/2022 Date of previous issue :6/18/2022 Version :10 8/12 V66V280 Polane® Catalyst SHW-85-NA-GHS-CA Section 11. Toxicological information No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :No known significant effects or critical hazards. Numerical measures of toxicity Inhalation (dusts and mists)4.63 mg/l Route ATE value Acute toxicity estimates Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name Hexamethylene Diisocyanate Polymer -367.7 low Toxicity Not available. Persistence and degradability Soil/water partition coefficient (KOC) :Not available. Mobility in soil Not available. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Date of issue/Date of revision :7/19/2022 Date of previous issue :6/18/2022 Version :10 9/12 V66V280 Polane® Catalyst SHW-85-NA-GHS-CA Section 14. Transport information - - - - - - Not regulated.Not regulated. -- DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to IMO instruments No.No. Not available. : Proper shipping name : Not available. : TDG Classification Not regulated. - - - No. - Mexico Classification Not regulated. - - - No. - Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. IATA Not regulated. - - - No. - Section 15. Regulatory information Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International regulations International lists : Date of issue/Date of revision :7/19/2022 Date of previous issue :6/18/2022 Version :10 10/12 V66V280 Polane® Catalyst SHW-85-NA-GHS-CA Section 16. Other information 7/19/2022 History Date of printing Date of issue/Date of revision Version It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is Date of previous issue : : : : Indicates information that has changed from previously issued version. Key to abbreviations : 7/19/2022 6/18/2022 10 Hazardous Material Information System (U.S.A.) 2 1 0 *Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. ACUTE TOXICITY (inhalation) - Category 4 Calculation method SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method SKIN SENSITIZATION - Category 1 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method Procedure used to derive the classification Classification Justification Notice to reader ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision :7/19/2022 Date of previous issue :6/18/2022 Version :10 11/12 V66V280 Polane® Catalyst SHW-85-NA-GHS-CA Section 16. Other information responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of issue/Date of revision :7/19/2022 Date of previous issue :6/18/2022 Version :10 12/12 V66V280 Polane® Catalyst SHW-85-NA-GHS-CA Polane 8910 Polyurethane Enamel RAL 1001 Desert Not available. Liquid. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer :THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. F63GXH33691-4371 F63GXH33691-4371Product code : Product Information Telephone Number :Not available. Regulatory Information Telephone Number :(216) 566-2902 Transportation Emergency Telephone Number :(800) 424-9300 Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 3 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Classification of the substance or mixture : Signal word :Warning Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 7.1% (oral), 17.2% (dermal), 18.3% (inhalation) OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 1/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Section 2. Hazards identification Precautionary statements Prevention :Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General :Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified :None known. Flammable liquid and vapor. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Section 3. Composition/information on ingredients Other means of identification :Not available. Substance/mixture CAS number/other identifiers :Mixture Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 2/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Section 3. Composition/information on ingredients Methyl n-Amyl Ketone ≥10 - ≤25 110-43-0 Titanium Dioxide ≥10 - ≤25 13463-67-7 p-Chlorobenzotrifluoride ≥10 - ≤25 98-56-6 Aspartic Ester ≤10 136210-32-7 n-Butyl Acetate ≤5 123-86-4 2-methoxy-1-methylethyl acetate ≤3 108-65-6 2-Ethyl-1,3-hexanediol ≤1.2 94-96-2 2,4-Pentanedione ≤1.1 123-54-6 UV Light Absorber ≤1 104810-48-2 Benzotriazole Hydroxyphenyl Polymer ≤1 104810-47-1 Bis(pentamethyl-4-piperidyl)sebacate ≤1 41556-26-7 Butyl Methacrylate ≤0.3 97-88-1 Xylene, mixed isomers ≤0.3 1330-20-7 2-Hydroxyethyl Methacrylate ≤0.3 868-77-9 Ingredient name CAS number% by weight Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Causes serious eye irritation.:Eye contact Potential acute health effects Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 3/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments :No specific treatment. Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Use dry chemical, CO₂, water spray (fog) or foam. Extinguishing media Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 4/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides halogenated compounds carbonyl halides metal oxide/oxides Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 5/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Methyl n-Amyl Ketone 110-43-0 ACGIH TLV (United States, 1/2021). TWA: 50 ppm 8 hours. TWA: 233 mg/m³ 8 hours. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 465 mg/m³ 10 hours. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 465 mg/m³ 8 hours. Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 1/2021). TWA: 10 mg/m³ 8 hours. OSHA PEL (United States, 5/2018). TWA: 15 mg/m³ 8 hours. Form: Total dust p-Chlorobenzotrifluoride 98-56-6 None. Aspartic Ester 136210-32-7 None. n-Butyl Acetate 123-86-4 NIOSH REL (United States, 10/2020). TWA: 150 ppm 10 hours. TWA: 710 mg/m³ 10 hours. STEL: 200 ppm 15 minutes. STEL: 950 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 150 ppm 8 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) CAS # Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 6/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection TWA: 710 mg/m³ 8 hours. ACGIH TLV (United States, 1/2021). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. 2-methoxy-1-methylethyl acetate 108-65-6 OARS WEEL (United States, 1/2021). TWA: 50 ppm 8 hours. 2-Ethyl-1,3-hexanediol 94-96-2 None. 2,4-Pentanedione 123-54-6 ACGIH TLV (United States, 1/2021). Absorbed through skin. TWA: 25 ppm 8 hours. UV Light Absorber 104810-48-2 None. Benzotriazole Hydroxyphenyl Polymer 104810-47-1 None. Bis(pentamethyl-4-piperidyl)sebacate 41556-26-7 None. Butyl Methacrylate 97-88-1 None. Xylene, mixed isomers 1330-20-7 ACGIH TLV (United States, 1/2021). TWA: 100 ppm 8 hours. TWA: 434 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours. 2-Hydroxyethyl Methacrylate 868-77-9 None. Methyl n-amyl ketone 110-43-0 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 233 mg/m³ 8 hours. 8 hrs OEL: 50 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 50 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 25 ppm 8 hours. TWA: 115 mg/m³ 8 hours. CA Quebec Provincial (Canada, 6/2021). TWAEV: 50 ppm 8 hours. TWAEV: 233 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 60 ppm 15 minutes. TWA: 50 ppm 8 hours. Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada, 6/2021). TWA: 10 mg/m³ 8 hours. Form: Total dust TWA: 3 mg/m³ 8 hours. Form: respirable fraction CA Quebec Provincial (Canada, 6/2021). TWAEV: 10 mg/m³ 8 hours. Form: Total dust. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 10 mg/m³ 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 10 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 20 mg/m³ 15 minutes. TWA: 10 mg/m³ 8 hours. Ingredient name Exposure limits Occupational exposure limits (Canada) CAS # Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 7/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection n-butyl acetate 123-86-4 CA Alberta Provincial (Canada, 6/2018). 15 min OEL: 200 ppm 15 minutes. 15 min OEL: 950 mg/m³ 15 minutes. 8 hrs OEL: 150 ppm 8 hours. 8 hrs OEL: 713 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 200 ppm 15 minutes. TWA: 150 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA Quebec Provincial (Canada, 6/2021). STEV: 150 ppm 15 minutes. TWAEV: 50 ppm 8 hours. pentane-2,4-dione 123-54-6 CA Ontario Provincial (Canada, 6/2019). Absorbed through skin. TWA: 25 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). Absorbed through skin. Butyl Methacrylate 97-88-1 CA British Columbia Provincial (Canada, 6/2021). TWA: 50 ppm 8 hours. Xylene 1330-20-7 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 100 ppm 8 hours. 15 min OEL: 651 mg/m³ 15 minutes. 15 min OEL: 150 ppm 15 minutes. 8 hrs OEL: 434 mg/m³ 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 100 ppm 8 hours. STEL: 150 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m³ 8 hours. STEV: 150 ppm 15 minutes. STEV: 651 mg/m³ 15 minutes. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. Occupational exposure limits (Mexico) Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 8/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Environmental exposure controls : Methyl n-Amyl Ketone 110-43-0 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 50 ppm 8 hours. n-Butyl Acetate 123-86-4 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 150 ppm 8 hours. STEL: 200 ppm 15 minutes. pentane-2,4-dione 123-54-6 NOM-010-STPS-2014 (Mexico, 4/2016). Absorbed through skin. TWA: 20 ppm 8 hours. Exposure limitsCAS # Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 9/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Relative density Solubility Liquid. Not available. 1.12 3.5 [Air = 1] Not available. Not available.Odor pH Not available.Color Evaporation rate 1 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 34°C (93.2°F) [Pensky-Martens Closed Cup] Not applicable. Not applicable. Viscosity Kinematic (40°C (104°F)): <20.5 mm2/s (<20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance :123°C (253.4°F) :Not available. :Lower: 0.9% Upper: 13.1% Decomposition temperature :Not available. Heat of combustion :17.568 kJ/g Aerosol product Molecular weight :Not applicable. Boiling point, initial boiling point, and boiling range Flammability Lower and upper explosion limit/flammability limit Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. 1.3 kPa (10 mm Hg) Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 10/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Section 11. Toxicological information Acute toxicity Methyl n-Amyl Ketone LD50 Oral Rat 1600 mg/kg - p-Chlorobenzotrifluoride LD50 Oral Rat 13 g/kg - n-Butyl Acetate LD50 Dermal Rabbit >17600 mg/kg - LD50 Oral Rat 10768 mg/kg - 2-methoxy-1-methylethyl acetate LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat 8532 mg/kg - 2-Ethyl-1,3-hexanediol LD50 Dermal Rabbit 2 g/kg - LD50 Oral Rat 1400 mg/kg - 2,4-Pentanedione LD50 Oral Rat 55 mg/kg - Butyl Methacrylate LC50 Inhalation Gas.Rat 4910 ppm 4 hours LD50 Oral Rat 16 g/kg - Xylene, mixed isomers LC50 Inhalation Gas.Rat 6700 ppm 4 hours LD50 Oral Rat 4300 mg/kg - 2-Hydroxyethyl Methacrylate LD50 Oral Rat 5050 mg/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity Not available. Mutagenicity Not available. Irritation/Corrosion Methyl n-Amyl Ketone Skin - Mild irritant Rabbit -24 hours 14 mg - Titanium Dioxide Skin - Mild irritant Human -72 hours 300 ug I - n-Butyl Acetate Eyes - Moderate irritant Rabbit -100 mg - Skin - Moderate irritant Rabbit -24 hours 500 mg - 2-Ethyl-1,3-hexanediol Eyes - Severe irritant Rabbit -20 mg - Skin - Mild irritant Rabbit -500 mg - 2,4-Pentanedione Eyes - Severe irritant Rabbit -20 mg - Skin - Mild irritant Rabbit -488 mg - Skin - Mild irritant Rabbit -6 hours 11.2 Ml I - Skin - Moderate irritant Rabbit -48 hours 11.2 Ml I - Skin - Moderate irritant Rabbit -6 hours 33.6 Ml I - Butyl Methacrylate Skin - Mild irritant Rabbit -500 uL - Xylene, mixed isomers Eyes - Mild irritant Rabbit -87 mg - Eyes - Severe irritant Rabbit -24 hours 5 mg - Skin - Mild irritant Rat -8 hours 60 uL - Skin - Moderate irritant Rabbit -24 hours 500 mg - Skin - Moderate irritant Rabbit -100 %- Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Information on toxicological effects Classification Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 11/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Section 11. Toxicological information Teratogenicity Not available. Reproductive toxicity Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Methyl n-Amyl Ketone Category 3 -Respiratory tract irritation Category 3 Narcotic effects p-Chlorobenzotrifluoride Category 3 -Respiratory tract irritation n-Butyl Acetate Category 3 -Narcotic effects 2-methoxy-1-methylethyl acetate Category 3 -Narcotic effects 2-Ethyl-1,3-hexanediol Category 3 -Respiratory tract irritation Category 3 Narcotic effects 2,4-Pentanedione Category 3 -Respiratory tract irritation Category 3 Narcotic effects Butyl Methacrylate Category 3 -Respiratory tract irritation Xylene, mixed isomers Category 3 -Respiratory tract irritation Name Category Name Category Methyl n-Amyl Ketone Category 2 -- 2-Ethyl-1,3-hexanediol Category 2 -- 2,4-Pentanedione Category 2 -- Xylene, mixed isomers Category 2 -- Aspiration hazard Name Result Xylene, mixed isomers ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs Titanium Dioxide -2B - p-Chlorobenzotrifluoride -2B - Xylene, mixed isomers -3 - Product/ingredient name NTPIARCOSHA Information on the likely routes of exposure Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics :Not available. Potential acute health effects Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 12/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Section 11. Toxicological information Not available. May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :Suspected of damaging fertility. Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Acute toxicity estimates Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 13/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Section 11. Toxicological information Oral 5566.93 mg/kg Dermal 20586.46 mg/kg Inhalation (gases)55065.78 ppm Inhalation (vapors)32.14 mg/l Route ATE value Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name Aspartic Ester -0.25 low Xylene, mixed isomers -8.1 to 25.9 low Product/ingredient name Aquatic half-life Photolysis Biodegradability Methyl n-Amyl Ketone --Readily n-Butyl Acetate --Readily Xylene, mixed isomers --Readily Toxicity Methyl n-Amyl Ketone Acute LC50 131000 µg/l Fresh water Fish - Pimephales promelas 96 hours Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours n-Butyl Acetate Acute LC50 32 mg/l Marine water Crustaceans - Artemia salina 48 hours Acute LC50 18000 µg/l Fresh water Fish - Pimephales promelas 96 hours 2-Ethyl-1,3-hexanediol Acute LC50 624000 µg/l Fresh water Fish - Ictalurus punctatus - Fingerling 96 hours 2,4-Pentanedione Acute EC50 75000 µg/l Fresh water Crustaceans - Ceriodaphnia reticulata - Larvae 48 hours Acute LC50 47600 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 60100 µg/l Fresh water Fish - Lepomis macrochirus 96 hours Butyl Methacrylate Chronic NOEC 2.6 mg/l Fresh water Daphnia - Daphnia magna - Neonate 21 days Xylene, mixed isomers Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours 2-Hydroxyethyl Methacrylate Acute LC50 227000 µg/l Fresh water Fish - Pimephales promelas - Juvenile (Fledgling, Hatchling, Weanling) 96 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability Soil/water partition coefficient (KOC) :Not available. Mobility in soil Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 14/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 14. Transport information PAINT 3 III PAINT 3 III UN1263 UN1263 -Emergency schedules F-E, S- E DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No.No. TDG Classification UN1263 PAINT 3 III No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). Mexico Classification UN1263 PAINT 3 III No. - IATA UN1263 PAINT 3 III No. - 128 ERG No. 128 128 ERG No.ERG No. Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 15/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Section 14. Transport information Special precautions for user Transport in bulk according to IMO instruments Not available. : Proper shipping name : Not available. :Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. Section 15. Regulatory information SARA 313 TSCA 5(a)2 proposed significant new use rules: 2,4-Pentanedione SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International regulations International lists : Section 16. Other information Hazardous Material Information System (U.S.A.) 2 3 0 *Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. Procedure used to derive the classification Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 16/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Section 16. Other information 8/8/2022 History Date of printing Date of issue/Date of revision Version It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of previous issue : : : : Indicates information that has changed from previously issued version. Key to abbreviations : 8/8/2022 8/3/2022 4 FLAMMABLE LIQUIDS - Category 3 On basis of test data SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method SKIN SENSITIZATION - Category 1 Calculation method CARCINOGENICITY - Category 2 Calculation method TOXIC TO REPRODUCTION - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method Classification Justification Notice to reader ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 17/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Date of issue/Date of revision :8/8/2022 Date of previous issue :8/3/2022 Version :4 18/18 F63GXH33691-4371 Polane 8910 Polyurethane Enamel RAL 1001 Desert SHW-85-NA-GHS-US Polane 8910 Polyurethane Enamel RAL 7038 Aluminum Not available. Liquid. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer :THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. F63GXA33690-4371 F63GXA33690-4371Product code : Product Information Telephone Number :Not available. Regulatory Information Telephone Number :(216) 566-2902 Transportation Emergency Telephone Number :(800) 424-9300 Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 3 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Classification of the substance or mixture : Signal word :Warning Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 7.4% (oral), 17.9% (dermal), 19% (inhalation) OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 1/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Section 2. Hazards identification Precautionary statements Prevention :Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General :Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified :None known. Flammable liquid and vapor. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Section 3. Composition/information on ingredients Other means of identification :Not available. Substance/mixture CAS number/other identifiers :Mixture Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 2/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Section 3. Composition/information on ingredients Methyl n-Amyl Ketone ≥10 - ≤26 110-43-0 p-Chlorobenzotrifluoride ≥10 - ≤25 98-56-6 Titanium Dioxide ≥10 - ≤25 13463-67-7 Aspartic Ester ≤10 136210-32-7 n-Butyl Acetate ≤5 123-86-4 2-Ethyl-1,3-hexanediol ≤1.2 94-96-2 2,4-Pentanedione ≤1.1 123-54-6 UV Light Absorber ≤1 104810-48-2 Benzotriazole Hydroxyphenyl Polymer ≤1 104810-47-1 Bis(pentamethyl-4-piperidyl)sebacate ≤1 41556-26-7 Butyl Methacrylate ≤0.3 97-88-1 Xylene, mixed isomers ≤0.3 1330-20-7 2-Hydroxyethyl Methacrylate ≤0.3 868-77-9 Methyl Methacrylate ≤0.3 80-62-6 Ingredient name CAS number% by weight Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Causes serious eye irritation.:Eye contact Potential acute health effects Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 3/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments :No specific treatment. Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Use dry chemical, CO₂, water spray (fog) or foam. Extinguishing media Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 4/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides halogenated compounds carbonyl halides metal oxide/oxides Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 5/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Methyl n-Amyl Ketone 110-43-0 ACGIH TLV (United States, 1/2021). TWA: 50 ppm 8 hours. TWA: 233 mg/m³ 8 hours. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 465 mg/m³ 10 hours. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 465 mg/m³ 8 hours. p-Chlorobenzotrifluoride 98-56-6 None. Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 1/2021). TWA: 10 mg/m³ 8 hours. OSHA PEL (United States, 5/2018). TWA: 15 mg/m³ 8 hours. Form: Total dust Aspartic Ester 136210-32-7 None. n-Butyl Acetate 123-86-4 NIOSH REL (United States, 10/2020). TWA: 150 ppm 10 hours. TWA: 710 mg/m³ 10 hours. STEL: 200 ppm 15 minutes. STEL: 950 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 150 ppm 8 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) CAS # Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 6/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection TWA: 710 mg/m³ 8 hours. ACGIH TLV (United States, 1/2021). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. 2-Ethyl-1,3-hexanediol 94-96-2 None. 2,4-Pentanedione 123-54-6 ACGIH TLV (United States, 1/2021). Absorbed through skin. TWA: 25 ppm 8 hours. UV Light Absorber 104810-48-2 None. Benzotriazole Hydroxyphenyl Polymer 104810-47-1 None. Bis(pentamethyl-4-piperidyl)sebacate 41556-26-7 None. Butyl Methacrylate 97-88-1 None. Xylene, mixed isomers 1330-20-7 ACGIH TLV (United States, 1/2021). TWA: 100 ppm 8 hours. TWA: 434 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours. 2-Hydroxyethyl Methacrylate 868-77-9 None. Methyl Methacrylate 80-62-6 ACGIH TLV (United States, 1/2021). Skin sensitizer. TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 410 mg/m³ 10 hours. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 410 mg/m³ 8 hours. Methyl n-amyl ketone 110-43-0 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 233 mg/m³ 8 hours. 8 hrs OEL: 50 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 50 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 25 ppm 8 hours. TWA: 115 mg/m³ 8 hours. CA Quebec Provincial (Canada, 6/2021). TWAEV: 50 ppm 8 hours. TWAEV: 233 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 60 ppm 15 minutes. TWA: 50 ppm 8 hours. Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada, 6/2021). TWA: 10 mg/m³ 8 hours. Form: Total dust TWA: 3 mg/m³ 8 hours. Form: respirable fraction CA Quebec Provincial (Canada, 6/2021). Ingredient name Exposure limits Occupational exposure limits (Canada) CAS # Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 7/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection TWAEV: 10 mg/m³ 8 hours. Form: Total dust. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 10 mg/m³ 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 10 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 20 mg/m³ 15 minutes. TWA: 10 mg/m³ 8 hours. n-butyl acetate 123-86-4 CA Alberta Provincial (Canada, 6/2018). 15 min OEL: 200 ppm 15 minutes. 15 min OEL: 950 mg/m³ 15 minutes. 8 hrs OEL: 150 ppm 8 hours. 8 hrs OEL: 713 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 200 ppm 15 minutes. TWA: 150 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA Quebec Provincial (Canada, 6/2021). STEV: 150 ppm 15 minutes. TWAEV: 50 ppm 8 hours. pentane-2,4-dione 123-54-6 CA Ontario Provincial (Canada, 6/2019). Absorbed through skin. TWA: 25 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). Absorbed through skin. Butyl Methacrylate 97-88-1 CA British Columbia Provincial (Canada, 6/2021). TWA: 50 ppm 8 hours. Xylene 1330-20-7 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 100 ppm 8 hours. 15 min OEL: 651 mg/m³ 15 minutes. 15 min OEL: 150 ppm 15 minutes. 8 hrs OEL: 434 mg/m³ 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 100 ppm 8 hours. STEL: 150 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m³ 8 hours. STEV: 150 ppm 15 minutes. STEV: 651 mg/m³ 15 minutes. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 8/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Methyl methacrylate 80-62-6 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 205 mg/m³ 8 hours. 8 hrs OEL: 50 ppm 8 hours. 15 min OEL: 410 mg/m³ 15 minutes. 15 min OEL: 100 ppm 15 minutes. CA British Columbia Provincial (Canada, 6/2021). Skin sensitizer. TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). Skin sensitizer. TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). Skin sensitizer. TWAEV: 50 ppm 8 hours. STEV: 100 ppm 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). Skin sensitizer. STEL: 100 ppm 15 minutes. TWA: 50 ppm 8 hours. Environmental exposure controls : Methyl n-Amyl Ketone 110-43-0 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 50 ppm 8 hours. n-Butyl Acetate 123-86-4 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 150 ppm 8 hours. STEL: 200 ppm 15 minutes. pentane-2,4-dione 123-54-6 NOM-010-STPS-2014 (Mexico, 4/2016). Absorbed through skin. TWA: 20 ppm 8 hours. Exposure limits Occupational exposure limits (Mexico) CAS # Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 9/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Respiratory protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Relative density Solubility Liquid. Not available. 1.1 3.5 [Air = 1] Not available. Not available.Odor pH Not available.Color Evaporation rate 1 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 34°C (93.2°F) [Pensky-Martens Closed Cup] Not applicable. Not applicable. Viscosity Kinematic (40°C (104°F)): <20.5 mm2/s (<20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance :123°C (253.4°F) :Not available. :Lower: 0.9% Upper: 11.4% Decomposition temperature :Not available. Heat of combustion :18.158 kJ/g Aerosol product Molecular weight :Not applicable. Boiling point, initial boiling point, and boiling range Flammability Lower and upper explosion limit/flammability limit Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. 1.3 kPa (10 mm Hg) Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 10/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Methyl n-Amyl Ketone LD50 Oral Rat 1600 mg/kg - p-Chlorobenzotrifluoride LD50 Oral Rat 13 g/kg - n-Butyl Acetate LD50 Dermal Rabbit >17600 mg/kg - LD50 Oral Rat 10768 mg/kg - 2-Ethyl-1,3-hexanediol LD50 Dermal Rabbit 2 g/kg - LD50 Oral Rat 1400 mg/kg - 2,4-Pentanedione LD50 Oral Rat 55 mg/kg - Butyl Methacrylate LC50 Inhalation Gas.Rat 4910 ppm 4 hours LD50 Oral Rat 16 g/kg - Xylene, mixed isomers LC50 Inhalation Gas.Rat 6700 ppm 4 hours LD50 Oral Rat 4300 mg/kg - 2-Hydroxyethyl Methacrylate LD50 Oral Rat 5050 mg/kg - Methyl Methacrylate LC50 Inhalation Vapor Rat 78000 mg/m³4 hours LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat 7872 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Methyl n-Amyl Ketone Skin - Mild irritant Rabbit -24 hours 14 mg - Titanium Dioxide Skin - Mild irritant Human -72 hours 300 ug I - n-Butyl Acetate Eyes - Moderate irritant Rabbit -100 mg - Skin - Moderate irritant Rabbit -24 hours 500 mg - 2-Ethyl-1,3-hexanediol Eyes - Severe irritant Rabbit -20 mg - Skin - Mild irritant Rabbit -500 mg - 2,4-Pentanedione Eyes - Severe irritant Rabbit -20 mg - Skin - Mild irritant Rabbit -488 mg - Skin - Mild irritant Rabbit -6 hours 11.2 Ml I - Skin - Moderate irritant Rabbit -48 hours 11.2 - Product/ingredient name Result Score Exposure ObservationSpecies Information on toxicological effects Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 11/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Ml I Skin - Moderate irritant Rabbit -6 hours 33.6 Ml I - Butyl Methacrylate Skin - Mild irritant Rabbit -500 uL - Xylene, mixed isomers Eyes - Mild irritant Rabbit -87 mg - Eyes - Severe irritant Rabbit -24 hours 5 mg - Skin - Mild irritant Rat -8 hours 60 uL - Skin - Moderate irritant Rabbit -24 hours 500 mg - Skin - Moderate irritant Rabbit -100 %- Sensitization Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Methyl n-Amyl Ketone Category 3 -Respiratory tract irritation Category 3 Narcotic effects p-Chlorobenzotrifluoride Category 3 -Respiratory tract irritation n-Butyl Acetate Category 3 -Narcotic effects 2-Ethyl-1,3-hexanediol Category 3 -Respiratory tract irritation Category 3 Narcotic effects 2,4-Pentanedione Category 3 -Respiratory tract irritation Category 3 Narcotic effects Butyl Methacrylate Category 3 -Respiratory tract irritation Xylene, mixed isomers Category 3 -Respiratory tract irritation Methyl Methacrylate Category 3 -Respiratory tract irritation Name Category Route of exposure Target organs Classification p-Chlorobenzotrifluoride -2B - Titanium Dioxide -2B - Xylene, mixed isomers -3 - Methyl Methacrylate -3 - Product/ingredient name NTPIARCOSHA Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 12/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Section 11. Toxicological information Name Category Methyl n-Amyl Ketone Category 2 -- 2-Ethyl-1,3-hexanediol Category 2 -- 2,4-Pentanedione Category 2 -- Xylene, mixed isomers Category 2 -- Aspiration hazard Name Result Xylene, mixed isomers ASPIRATION HAZARD - Category 1 Route of exposure Target organs Information on the likely routes of exposure Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Delayed and immediate effects and also chronic effects from short and long term exposure :Not available. Potential acute health effects Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 13/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Section 11. Toxicological information Not available. May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :Suspected of damaging fertility. Potential chronic health effects Numerical measures of toxicity Oral 5376.34 mg/kg Dermal 20200.37 mg/kg Inhalation (gases)54131.41 ppm Inhalation (vapors)30.78 mg/l Route ATE value Acute toxicity estimates Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Section 12. Ecological information Toxicity Methyl n-Amyl Ketone Acute LC50 131000 µg/l Fresh water Fish - Pimephales promelas 96 hours Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours n-Butyl Acetate Acute LC50 32 mg/l Marine water Crustaceans - Artemia salina 48 hours Acute LC50 18000 µg/l Fresh water Fish - Pimephales promelas 96 hours 2-Ethyl-1,3-hexanediol Acute LC50 624000 µg/l Fresh water Fish - Ictalurus punctatus - Fingerling 96 hours 2,4-Pentanedione Acute EC50 75000 µg/l Fresh water Crustaceans - Ceriodaphnia reticulata - Larvae 48 hours Acute LC50 47600 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 60100 µg/l Fresh water Fish - Lepomis macrochirus 96 hours Butyl Methacrylate Chronic NOEC 2.6 mg/l Fresh water Daphnia - Daphnia magna - Neonate 21 days Xylene, mixed isomers Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours 2-Hydroxyethyl Methacrylate Acute LC50 227000 µg/l Fresh water Fish - Pimephales promelas - Juvenile (Fledgling, Hatchling, Weanling) 96 hours Methyl Methacrylate Acute LC50 130000 µg/l Fresh water Fish - Pimephales promelas - Adult 96 hours Product/ingredient name SpeciesResult Exposure Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 14/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name Aspartic Ester -0.25 low Xylene, mixed isomers -8.1 to 25.9 low Product/ingredient name Aquatic half-life Photolysis Biodegradability Methyl n-Amyl Ketone --Readily n-Butyl Acetate --Readily Xylene, mixed isomers --Readily Persistence and degradability Soil/water partition coefficient (KOC) :Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 14. Transport information PAINT 3 III PAINT 3 III UN1263 UN1263 DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No.No. TDG Classification UN1263 PAINT 3 III No. Mexico Classification UN1263 PAINT 3 III No. IATA UN1263 PAINT 3 III No. Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 15/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Section 14. Transport information -Emergency schedules F-E, S- E Additional information Special precautions for user Transport in bulk according to IMO instruments Not available. : Proper shipping name : Not available. : Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). - Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. - 128 ERG No. 128 128 ERG No.ERG No. Section 15. Regulatory information SARA 313 TSCA 5(a)2 proposed significant new use rules: 2,4-Pentanedione SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International regulations International lists : Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 16/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Section 16. Other information 8/4/2022 History Date of printing Date of issue/Date of revision Version Date of previous issue : : : : Indicates information that has changed from previously issued version. Key to abbreviations : 8/4/2022 8/1/2022 4 Hazardous Material Information System (U.S.A.) 2 3 0 *Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. FLAMMABLE LIQUIDS - Category 3 On basis of test data SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method SKIN SENSITIZATION - Category 1 Calculation method CARCINOGENICITY - Category 2 Calculation method TOXIC TO REPRODUCTION - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method Procedure used to derive the classification Classification Justification Notice to reader ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 17/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of issue/Date of revision :8/4/2022 Date of previous issue :8/1/2022 Version :4 18/18 F63GXA33690-4371 Polane 8910 Polyurethane Enamel RAL 7038 Aluminum SHW-85-NA-GHS-US Polane 8910 Polyurethane Enamel RAL 1014 Tan Not available. Liquid. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer :THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. F63GXH33692-4371 F63GXH33692-4371Product code : Product Information Telephone Number :Not available. Regulatory Information Telephone Number :(216) 566-2902 Transportation Emergency Telephone Number :(800) 424-9300 Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 3 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Classification of the substance or mixture : Signal word :Warning Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 6.8% (oral), 16.7% (dermal), 17.8% (inhalation) OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision :8/4/2022 Date of previous issue :6/8/2022 Version :3 1/17 F63GXH33692-4371 Polane 8910 Polyurethane Enamel RAL 1014 Tan SHW-85-NA-GHS-US Section 2. Hazards identification Precautionary statements Prevention :Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General :Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified :None known. Flammable liquid and vapor. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Section 3. Composition/information on ingredients Other means of identification :Not available. Substance/mixture CAS number/other identifiers :Mixture Date of issue/Date of revision :8/4/2022 Date of previous issue :6/8/2022 Version :3 2/17 F63GXH33692-4371 Polane 8910 Polyurethane Enamel RAL 1014 Tan SHW-85-NA-GHS-US Section 3. Composition/information on ingredients Methyl n-Amyl Ketone ≥10 - ≤25 110-43-0 Titanium Dioxide ≥10 - ≤25 13463-67-7 p-Chlorobenzotrifluoride ≤10 98-56-6 Aspartic Ester ≤10 136210-32-7 n-Butyl Acetate ≤5 123-86-4 2-Ethyl-1,3-hexanediol ≤1.4 94-96-2 2-methoxy-1-methylethyl acetate ≤3 108-65-6 UV Light Absorber ≤1 104810-48-2 Benzotriazole Hydroxyphenyl Polymer ≤1 104810-47-1 Bis(pentamethyl-4-piperidyl)sebacate ≤1 41556-26-7 Butyl Methacrylate ≤0.3 97-88-1 Xylene, mixed isomers ≤0.3 1330-20-7 Ingredient name CAS number% by weight Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Causes serious eye irritation.:Eye contact Potential acute health effects Date of issue/Date of revision :8/4/2022 Date of previous issue :6/8/2022 Version :3 3/17 F63GXH33692-4371 Polane 8910 Polyurethane Enamel RAL 1014 Tan SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments :No specific treatment. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Specific hazards arising from the chemical Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Use dry chemical, CO₂, water spray (fog) or foam. Extinguishing media : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision :8/4/2022 Date of previous issue :6/8/2022 Version :3 4/17 F63GXH33692-4371 Polane 8910 Polyurethane Enamel RAL 1014 Tan SHW-85-NA-GHS-US Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides halogenated compounds carbonyl halides metal oxide/oxides Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Precautions for safe handling Date of issue/Date of revision :8/4/2022 Date of previous issue :6/8/2022 Version :3 5/17 F63GXH33692-4371 Polane 8910 Polyurethane Enamel RAL 1014 Tan SHW-85-NA-GHS-US Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Methyl n-Amyl Ketone 110-43-0 ACGIH TLV (United States, 1/2021). TWA: 50 ppm 8 hours. TWA: 233 mg/m³ 8 hours. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 465 mg/m³ 10 hours. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 465 mg/m³ 8 hours. Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 1/2021). TWA: 10 mg/m³ 8 hours. OSHA PEL (United States, 5/2018). TWA: 15 mg/m³ 8 hours. Form: Total dust p-Chlorobenzotrifluoride 98-56-6 None. Aspartic Ester 136210-32-7 None. n-Butyl Acetate 123-86-4 NIOSH REL (United States, 10/2020). TWA: 150 ppm 10 hours. TWA: 710 mg/m³ 10 hours. STEL: 200 ppm 15 minutes. STEL: 950 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 150 ppm 8 hours. TWA: 710 mg/m³ 8 hours. ACGIH TLV (United States, 1/2021). Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) CAS # Date of issue/Date of revision :8/4/2022 Date of previous issue :6/8/2022 Version :3 6/17 F63GXH33692-4371 Polane 8910 Polyurethane Enamel RAL 1014 Tan SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. 2-Ethyl-1,3-hexanediol 94-96-2 None. 2-methoxy-1-methylethyl acetate 108-65-6 OARS WEEL (United States, 1/2021). TWA: 50 ppm 8 hours. UV Light Absorber 104810-48-2 None. Benzotriazole Hydroxyphenyl Polymer 104810-47-1 None. Bis(pentamethyl-4-piperidyl)sebacate 41556-26-7 None. Butyl Methacrylate 97-88-1 None. Xylene, mixed isomers 1330-20-7 ACGIH TLV (United States, 1/2021). TWA: 100 ppm 8 hours. TWA: 434 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours. Methyl n-amyl ketone 110-43-0 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 233 mg/m³ 8 hours. 8 hrs OEL: 50 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 50 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 25 ppm 8 hours. TWA: 115 mg/m³ 8 hours. CA Quebec Provincial (Canada, 6/2021). TWAEV: 50 ppm 8 hours. TWAEV: 233 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 60 ppm 15 minutes. TWA: 50 ppm 8 hours. Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada, 6/2021). TWA: 10 mg/m³ 8 hours. Form: Total dust TWA: 3 mg/m³ 8 hours. Form: respirable fraction CA Quebec Provincial (Canada, 6/2021). TWAEV: 10 mg/m³ 8 hours. Form: Total dust. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 10 mg/m³ 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 10 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 20 mg/m³ 15 minutes. TWA: 10 mg/m³ 8 hours. n-butyl acetate 123-86-4 CA Alberta Provincial (Canada, 6/2018). 15 min OEL: 200 ppm 15 minutes. 15 min OEL: 950 mg/m³ 15 minutes. 8 hrs OEL: 150 ppm 8 hours. Ingredient name Exposure limits Occupational exposure limits (Canada) CAS # Date of issue/Date of revision :8/4/2022 Date of previous issue :6/8/2022 Version :3 7/17 F63GXH33692-4371 Polane 8910 Polyurethane Enamel RAL 1014 Tan SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. 8 hrs OEL: 713 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 200 ppm 15 minutes. TWA: 150 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA Quebec Provincial (Canada, 6/2021). STEV: 150 ppm 15 minutes. TWAEV: 50 ppm 8 hours. Butyl Methacrylate 97-88-1 CA British Columbia Provincial (Canada, 6/2021). TWA: 50 ppm 8 hours. Xylene 1330-20-7 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 100 ppm 8 hours. 15 min OEL: 651 mg/m³ 15 minutes. 15 min OEL: 150 ppm 15 minutes. 8 hrs OEL: 434 mg/m³ 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 100 ppm 8 hours. STEL: 150 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m³ 8 hours. STEV: 150 ppm 15 minutes. STEV: 651 mg/m³ 15 minutes. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. Environmental exposure controls : Methyl n-Amyl Ketone 110-43-0 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 50 ppm 8 hours. n-Butyl Acetate 123-86-4 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 150 ppm 8 hours. STEL: 200 ppm 15 minutes. Exposure limits Occupational exposure limits (Mexico) CAS # Date of issue/Date of revision :8/4/2022 Date of previous issue :6/8/2022 Version :3 8/17 F63GXH33692-4371 Polane 8910 Polyurethane Enamel RAL 1014 Tan SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point/freezing point Liquid. Not available. Not available.Odor pH Not available.Color Evaporation rate 1 (butyl acetate = 1) Flash point Closed cup: 34°C (93.2°F) [Pensky-Martens Closed Cup] Not applicable. Not available.Odor threshold : : : : : : : : Appearance :123°C (253.4°F) :Not available. Boiling point, initial boiling point, and boiling range Flammability The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. Date of issue/Date of revision :8/4/2022 Date of previous issue :6/8/2022 Version :3 9/17 F63GXH33692-4371 Polane 8910 Polyurethane Enamel RAL 1014 Tan SHW-85-NA-GHS-US Section 9. Physical and chemical properties Vapor pressure Relative density Solubility 1.16 3.94 [Air = 1] Not available. Auto-ignition temperature Not available. Not applicable. Viscosity Kinematic (40°C (104°F)): <20.5 mm2/s (<20.5 cSt) Partition coefficient: n- octanol/water : : : : : : : :Lower: 0.9% Upper: 13.1% Decomposition temperature :Not available. Heat of combustion :16.885 kJ/g Aerosol product Molecular weight :Not applicable. Lower and upper explosion limit/flammability limit Relative vapor density 1.3 kPa (10 mm Hg) Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Methyl n-Amyl Ketone LD50 Oral Rat 1600 mg/kg - p-Chlorobenzotrifluoride LD50 Oral Rat 13 g/kg - n-Butyl Acetate LD50 Dermal Rabbit >17600 mg/kg - LD50 Oral Rat 10768 mg/kg - 2-Ethyl-1,3-hexanediol LD50 Dermal Rabbit 2 g/kg - LD50 Oral Rat 1400 mg/kg - 2-methoxy-1-methylethyl acetate LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat 8532 mg/kg - Butyl Methacrylate LC50 Inhalation Gas.Rat 4910 ppm 4 hours LD50 Oral Rat 16 g/kg - Xylene, mixed isomers LC50 Inhalation Gas.Rat 6700 ppm 4 hours LD50 Oral Rat 4300 mg/kg - Product/ingredient name Result Species Dose Exposure Information on toxicological effects Date of issue/Date of revision :8/4/2022 Date of previous issue :6/8/2022 Version :3 10/17 F63GXH33692-4371 Polane 8910 Polyurethane Enamel RAL 1014 Tan SHW-85-NA-GHS-US Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Irritation/Corrosion Methyl n-Amyl Ketone Skin - Mild irritant Rabbit -24 hours 14 mg - Titanium Dioxide Skin - Mild irritant Human -72 hours 300 ug I - n-Butyl Acetate Eyes - Moderate irritant Rabbit -100 mg - Skin - Moderate irritant Rabbit -24 hours 500 mg - 2-Ethyl-1,3-hexanediol Eyes - Severe irritant Rabbit -20 mg - Skin - Mild irritant Rabbit -500 mg - Butyl Methacrylate Skin - Mild irritant Rabbit -500 uL - Xylene, mixed isomers Eyes - Mild irritant Rabbit -87 mg - Eyes - Severe irritant Rabbit -24 hours 5 mg - Skin - Mild irritant Rat -8 hours 60 uL - Skin - Moderate irritant Rabbit -24 hours 500 mg - Skin - Moderate irritant Rabbit -100 %- Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Specific target organ toxicity (single exposure) Methyl n-Amyl Ketone Category 3 -Respiratory tract irritation Category 3 Narcotic effects p-Chlorobenzotrifluoride Category 3 -Respiratory tract irritation n-Butyl Acetate Category 3 -Narcotic effects 2-Ethyl-1,3-hexanediol Category 3 -Respiratory tract irritation Category 3 Narcotic effects 2-methoxy-1-methylethyl acetate Category 3 -Narcotic effects Butyl Methacrylate Category 3 -Respiratory tract irritation Xylene, mixed isomers Category 3 -Respiratory tract Name Category Route of exposure Target organs Classification Titanium Dioxide -2B - p-Chlorobenzotrifluoride -2B - Xylene, mixed isomers -3 - Product/ingredient name NTPIARCOSHA Date of issue/Date of revision :8/4/2022 Date of previous issue :6/8/2022 Version :3 11/17 F63GXH33692-4371 Polane 8910 Polyurethane Enamel RAL 1014 Tan SHW-85-NA-GHS-US Section 11. Toxicological information Specific target organ toxicity (repeated exposure) irritation Name Category Methyl n-Amyl Ketone Category 2 -- 2-Ethyl-1,3-hexanediol Category 2 -- Xylene, mixed isomers Category 2 -- Aspiration hazard Name Result Xylene, mixed isomers ASPIRATION HAZARD - Category 1 Route of exposure Target organs Information on the likely routes of exposure Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Delayed and immediate effects and also chronic effects from short and long term exposure :Not available. Potential acute health effects Potential immediate effects :Not available. Short term exposure Date of issue/Date of revision :8/4/2022 Date of previous issue :6/8/2022 Version :3 12/17 F63GXH33692-4371 Polane 8910 Polyurethane Enamel RAL 1014 Tan SHW-85-NA-GHS-US Section 11. Toxicological information Not available. May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :Suspected of damaging fertility. Potential chronic health effects Numerical measures of toxicity Oral 6487.28 mg/kg Dermal 149613.38 mg/kg Inhalation (vapors)38.66 mg/l Route ATE value Acute toxicity estimates Potential delayed effects :Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Section 12. Ecological information Bioaccumulative potential Product/ingredient name Aquatic half-life Photolysis Biodegradability Methyl n-Amyl Ketone --Readily n-Butyl Acetate --Readily Xylene, mixed isomers --Readily Toxicity Methyl n-Amyl Ketone Acute LC50 131000 µg/l Fresh water Fish - Pimephales promelas 96 hours Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours n-Butyl Acetate Acute LC50 32 mg/l Marine water Crustaceans - Artemia salina 48 hours Acute LC50 18000 µg/l Fresh water Fish - Pimephales promelas 96 hours 2-Ethyl-1,3-hexanediol Acute LC50 624000 µg/l Fresh water Fish - Ictalurus punctatus - Fingerling 96 hours Butyl Methacrylate Chronic NOEC 2.6 mg/l Fresh water Daphnia - Daphnia magna - Neonate 21 days Xylene, mixed isomers Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability Date of issue/Date of revision :8/4/2022 Date of previous issue :6/8/2022 Version :3 13/17 F63GXH33692-4371 Polane 8910 Polyurethane Enamel RAL 1014 Tan SHW-85-NA-GHS-US Section 12. Ecological information LogPow BCF Potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name Aspartic Ester -0.25 low Xylene, mixed isomers -8.1 to 25.9 low Soil/water partition coefficient (KOC) :Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 14. Transport information PAINT 3 III PAINT 3 III UN1263 UN1263 -Emergency schedules F-E, S- E DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No.No. TDG Classification UN1263 PAINT 3 III No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). Mexico Classification UN1263 PAINT 3 III No. - IATA UN1263 PAINT 3 III No. - ERG No.ERG No.ERG No. Date of issue/Date of revision :8/4/2022 Date of previous issue :6/8/2022 Version :3 14/17 F63GXH33692-4371 Polane 8910 Polyurethane Enamel RAL 1014 Tan SHW-85-NA-GHS-US Section 14. Transport information Special precautions for user Transport in bulk according to IMO instruments Not available. : Proper shipping name : Not available. :Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. 128 128 128 Section 15. Regulatory information SARA 313 TSCA 5(a)2 proposed significant new use rules: 2,4-Pentanedione SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International regulations International lists : Section 16. Other information Hazardous Material Information System (U.S.A.) 2 3 0 *Health Flammability Physical hazards The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. Date of issue/Date of revision :8/4/2022 Date of previous issue :6/8/2022 Version :3 15/17 F63GXH33692-4371 Polane 8910 Polyurethane Enamel RAL 1014 Tan SHW-85-NA-GHS-US Section 16. Other information 8/4/2022 History Date of printing Date of issue/Date of revision Version It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of previous issue : : : : Indicates information that has changed from previously issued version. Key to abbreviations : 8/4/2022 6/8/2022 3 Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. FLAMMABLE LIQUIDS - Category 3 On basis of test data SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method SKIN SENSITIZATION - Category 1 Calculation method CARCINOGENICITY - Category 2 Calculation method TOXIC TO REPRODUCTION - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method Procedure used to derive the classification Classification Justification Notice to reader ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision :8/4/2022 Date of previous issue :6/8/2022 Version :3 16/17 F63GXH33692-4371 Polane 8910 Polyurethane Enamel RAL 1014 Tan SHW-85-NA-GHS-US Date of issue/Date of revision :8/4/2022 Date of previous issue :6/8/2022 Version :3 17/17 F63GXH33692-4371 Polane 8910 Polyurethane Enamel RAL 1014 Tan SHW-85-NA-GHS-US PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue Not available. Liquid. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer :THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. E90HXA233-4371 E90HXA233-4371Product code : Product Information Telephone Number :Not available. Regulatory Information Telephone Number :(216) 566-2902 Transportation Emergency Telephone Number :(800) 424-9300 Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 1A SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Classification of the substance or mixture : Signal word :Danger Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 17.2% (oral), 17.2% (dermal), 32.5% (inhalation) OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 1/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 2. Hazards identification Precautionary statements Prevention :Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General :Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified :None known. Highly flammable liquid and vapor. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. May cause cancer. Causes damage to organs through prolonged or repeated exposure. (lungs) :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Adequate ventilation required when sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer's directions for respirator use. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica which has been shown to cause lung damage and cancer under long term exposure. : Section 3. Composition/information on ingredients Other means of identification :Not available. Substance/mixture CAS number/other identifiers :Mixture Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 2/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 3. Composition/information on ingredients Dimethyl Carbonate ≥10 - ≤25 616-38-6 Mica ≥10 - ≤25 12001-26-2 Acetone ≥10 - ≤25 67-64-1 Methyl n-Amyl Ketone ≥10 - ≤21 110-43-0 Epoxy Polymer ≤10 67989-52-0 Titanium Dioxide ≤10 13463-67-7 Methyl Ethyl Ketone ≤5 78-93-3 Epoxy Polymer ≤3 25068-38-6 Aluminum Triphosphate ≤3 13939-25-8 Barium Sulfate ≤3 7727-43-7 Aluminum Stearate ≤3 300-92-5 Crystalline Silica, non-respirable ≤1 14808-60-7 Methyl Isobutyl Ketone <1 108-10-1 Xylene, mixed isomers ≤0.3 1330-20-7 Ingredient name CAS number% by weight Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Causes serious eye irritation.:Eye contact Potential acute health effects Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 3/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments :No specific treatment. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :May cause an allergic skin reaction. Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide sulfur oxides phosphorus oxides halogenated compounds metal oxide/oxides Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Use dry chemical, CO₂, water spray (fog) or foam. Extinguishing media : : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 4/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 5/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Dimethyl Carbonate 616-38-6 None. Mica 12001-26-2 ACGIH TLV (United States, 1/2021). TWA: 0.1 mg/m³ 8 hours. Form: Respirable fraction NIOSH REL (United States, 10/2020). TWA: 3 mg/m³ 10 hours. Form: Respirable fraction OSHA PEL Z3 (United States, 6/2016). TWA: 20 mppcf 8 hours. Acetone 67-64-1 ACGIH TLV (United States, 1/2021). TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes. NIOSH REL (United States, 10/2020). TWA: 250 ppm 10 hours. TWA: 590 mg/m³ 10 hours. OSHA PEL (United States, 5/2018). TWA: 1000 ppm 8 hours. TWA: 2400 mg/m³ 8 hours. Methyl n-Amyl Ketone 110-43-0 ACGIH TLV (United States, 1/2021). TWA: 50 ppm 8 hours. TWA: 233 mg/m³ 8 hours. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 465 mg/m³ 10 hours. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 465 mg/m³ 8 hours. Epoxy Polymer 67989-52-0 None. Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 1/2021). TWA: 10 mg/m³ 8 hours. OSHA PEL (United States, 5/2018). TWA: 15 mg/m³ 8 hours. Form: Total dust Methyl Ethyl Ketone 78-93-3 ACGIH TLV (United States, 1/2021). TWA: 200 ppm 8 hours. TWA: 590 mg/m³ 8 hours. STEL: 300 ppm 15 minutes. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) CAS # Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 6/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection STEL: 885 mg/m³ 15 minutes. NIOSH REL (United States, 10/2020). TWA: 200 ppm 10 hours. TWA: 590 mg/m³ 10 hours. STEL: 300 ppm 15 minutes. STEL: 885 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 200 ppm 8 hours. TWA: 590 mg/m³ 8 hours. Epoxy Polymer 25068-38-6 None. Aluminum Triphosphate 13939-25-8 NIOSH REL (United States, 10/2020). TWA: 2 mg/m³, (as Al) 10 hours. Barium Sulfate 7727-43-7 ACGIH TLV (United States, 1/2021). TWA: 5 mg/m³ 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2020). TWA: 5 mg/m³ 10 hours. Form: Respirable fraction TWA: 10 mg/m³ 10 hours. Form: Total OSHA PEL (United States, 5/2018). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust Aluminum Stearate 300-92-5 ACGIH TLV (United States, 1/2021). TWA: 10 mg/m³ 8 hours. Form: Inhalable fraction TWA: 1 mg/m³ 8 hours. Form: Respirable fraction Crystalline Silica, non-respirable 14808-60-7 OSHA PEL (United States, 5/2018). TWA: 50 µg/m³ 8 hours. Form: Respirable dust OSHA PEL Z3 (United States, 6/2016). TWA: 30 mg/m³ / (%SiO2+2) 8 hours. Form: Total dust Methyl Isobutyl Ketone 108-10-1 ACGIH TLV (United States, 1/2021). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes. NIOSH REL (United States, 10/2020). TWA: 50 ppm 10 hours. TWA: 205 mg/m³ 10 hours. STEL: 75 ppm 15 minutes. STEL: 300 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 410 mg/m³ 8 hours. Xylene, mixed isomers 1330-20-7 ACGIH TLV (United States, 1/2021). TWA: 100 ppm 8 hours. TWA: 434 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours. Occupational exposure limits (Canada) Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 7/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection acetone 67-64-1 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 1200 mg/m³ 8 hours. 15 min OEL: 1800 mg/m³ 15 minutes. 8 hrs OEL: 500 ppm 8 hours. 15 min OEL: 750 ppm 15 minutes. CA British Columbia Provincial (Canada, 6/2021). TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 500 ppm 8 hours. TWAEV: 1190 mg/m³ 8 hours. STEV: 1000 ppm 15 minutes. STEV: 2380 mg/m³ 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 750 ppm 15 minutes. TWA: 500 ppm 8 hours. Methyl n-amyl ketone 110-43-0 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 233 mg/m³ 8 hours. 8 hrs OEL: 50 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 50 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 25 ppm 8 hours. TWA: 115 mg/m³ 8 hours. CA Quebec Provincial (Canada, 6/2021). TWAEV: 50 ppm 8 hours. TWAEV: 233 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 60 ppm 15 minutes. TWA: 50 ppm 8 hours. Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada, 6/2021). TWA: 10 mg/m³ 8 hours. Form: Total dust TWA: 3 mg/m³ 8 hours. Form: respirable fraction CA Quebec Provincial (Canada, 6/2021). TWAEV: 10 mg/m³ 8 hours. Form: Total dust. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 10 mg/m³ 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 10 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 20 mg/m³ 15 minutes. TWA: 10 mg/m³ 8 hours. Methyl ethyl ketone 78-93-3 CA Alberta Provincial (Canada, 6/2018). 15 min OEL: 300 ppm 15 minutes. 8 hrs OEL: 200 ppm 8 hours. Ingredient name Exposure limitsCAS # Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 8/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection 8 hrs OEL: 590 mg/m³ 8 hours. 15 min OEL: 885 mg/m³ 15 minutes. CA British Columbia Provincial (Canada, 6/2021). TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). TWA: 200 ppm 8 hours. STEL: 300 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 50 ppm 8 hours. TWAEV: 150 mg/m³ 8 hours. STEV: 100 ppm 15 minutes. STEV: 300 mg/m³ 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 300 ppm 15 minutes. TWA: 200 ppm 8 hours. Aluminum Triphosphate 13939-25-8 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 2 mg/m³, (as Al) 8 hours. CA Quebec Provincial (Canada, 6/2021). TWAEV: 2 mg/m³, (as Al) 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 4 mg/m³, (measured as Al) 15 minutes. TWA: 2 mg/m³, (measured as Al) 8 hours. Kaolin 1332-58-7 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 2 mg/m³ 8 hours. Form: Respirable CA British Columbia Provincial (Canada, 6/2021). TWA: 2 mg/m³ 8 hours. Form: Respirable CA Quebec Provincial (Canada, 6/2021). TWAEV: 2 mg/m³ 8 hours. Form: Respirable dust. CA Ontario Provincial (Canada, 6/2019). TWA: 2 mg/m³ 8 hours. Form: Respirable particulate matter. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 4 mg/m³ 15 minutes. Form: respirable fraction TWA: 2 mg/m³ 8 hours. Form: respirable fraction Quartz 14808-60-7 CA Quebec Provincial (Canada, 6/2021). TWAEV: 0.1 mg/m³ 8 hours. Form: Respirable dust. Methyl isobutyl ketone 108-10-1 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 205 mg/m³ 8 hours. 8 hrs OEL: 50 ppm 8 hours. 15 min OEL: 75 ppm 15 minutes. 15 min OEL: 307 mg/m³ 15 minutes. CA British Columbia Provincial (Canada, 6/2021). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes. Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 9/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. CA Ontario Provincial (Canada, 6/2019). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 20 ppm 8 hours. STEV: 75 ppm 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 75 ppm 15 minutes. TWA: 50 ppm 8 hours. Xylene 1330-20-7 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 100 ppm 8 hours. 15 min OEL: 651 mg/m³ 15 minutes. 15 min OEL: 150 ppm 15 minutes. 8 hrs OEL: 434 mg/m³ 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 100 ppm 8 hours. STEL: 150 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m³ 8 hours. STEV: 150 ppm 15 minutes. STEV: 651 mg/m³ 15 minutes. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. Environmental exposure controls : Acetone 67-64-1 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 500 ppm 8 hours. STEL: 750 ppm 15 minutes. Methyl n-Amyl Ketone 110-43-0 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 50 ppm 8 hours. Methyl Ethyl Ketone 78-93-3 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 200 ppm 8 hours. STEL: 300 ppm 15 minutes. Methyl Isobutyl Ketone 108-10-1 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 50 ppm 8 hours. STEL: 75 ppm 15 minutes. Exposure limits Occupational exposure limits (Mexico) CAS # Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 10/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Relative density Liquid. Not available. 1.25 2 [Air = 1] Not available.Odor pH Not available.Color Evaporation rate 5.6 (butyl acetate = 1) Flash point Closed cup: -3°C (26.6°F) [Pensky-Martens Closed Cup] Not applicable. Not available.Odor threshold : : : : : : : : : : : Appearance :55°C (131°F) :Not available. :Lower: 1.1% Upper: 12.8% Boiling point, initial boiling point, and boiling range Flammability Lower and upper explosion limit/flammability limit Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. 24 kPa (180 mm Hg) Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 11/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 9. Physical and chemical properties Solubility Not available. Auto-ignition temperature Not available. Not applicable. Viscosity Kinematic (40°C (104°F)): >20.5 mm2/s (>20.5 cSt) Partition coefficient: n- octanol/water : : : : Decomposition temperature :Not available. Heat of combustion :15.643 kJ/g Aerosol product Molecular weight :Not applicable. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Dimethyl Carbonate LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat 13 g/kg - Acetone LD50 Oral Rat 5800 mg/kg - Methyl n-Amyl Ketone LD50 Oral Rat 1600 mg/kg - Methyl Ethyl Ketone LD50 Dermal Rabbit 6480 mg/kg - LD50 Oral Rat 2737 mg/kg - Methyl Isobutyl Ketone LD50 Oral Rat 2080 mg/kg - Xylene, mixed isomers LC50 Inhalation Gas.Rat 6700 ppm 4 hours LD50 Oral Rat 4300 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Information on toxicological effects Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 12/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Acetone Eyes - Mild irritant Human -186300 ppm - Eyes - Mild irritant Rabbit -10 uL - Eyes - Moderate irritant Rabbit -24 hours 20 mg - Eyes - Severe irritant Rabbit -20 mg - Skin - Mild irritant Rabbit -24 hours 500 mg - Skin - Mild irritant Rabbit -395 mg - Methyl n-Amyl Ketone Skin - Mild irritant Rabbit -24 hours 14 mg - Titanium Dioxide Skin - Mild irritant Human -72 hours 300 ug I - Methyl Ethyl Ketone Skin - Mild irritant Rabbit -24 hours 14 mg - Skin - Moderate irritant Rabbit -24 hours 500 mg - Epoxy Polymer Eyes - Mild irritant Rabbit -100 mg - Skin - Moderate irritant Rabbit -24 hours 500 Ul - Skin - Severe irritant Rabbit -24 hours 2 mg - Methyl Isobutyl Ketone Eyes - Moderate irritant Rabbit -24 hours 100 uL - Eyes - Severe irritant Rabbit -40 mg - Skin - Mild irritant Rabbit -24 hours 500 mg - Xylene, mixed isomers Eyes - Mild irritant Rabbit -87 mg - Eyes - Severe irritant Rabbit -24 hours 5 mg - Skin - Mild irritant Rat -8 hours 60 uL - Skin - Moderate irritant Rabbit -24 hours 500 mg - Skin - Moderate irritant Rabbit -100 %- Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Classification Titanium Dioxide -2B - Crystalline Silica, non- respirable -1 Known to be a human carcinogen. Methyl Isobutyl Ketone -2B - Xylene, mixed isomers -3 - Product/ingredient name NTPIARCOSHA Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 13/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 11. Toxicological information Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Acetone Category 3 -Respiratory tract irritation Category 3 Narcotic effects Methyl n-Amyl Ketone Category 3 -Respiratory tract irritation Category 3 Narcotic effects Methyl Ethyl Ketone Category 3 -Respiratory tract irritation Category 3 Narcotic effects Methyl Isobutyl Ketone Category 3 -Respiratory tract irritation Category 3 Narcotic effects Xylene, mixed isomers Category 3 -Respiratory tract irritation Name Category Name Category Mica Category 1 inhalation lungs Acetone Category 2 -- Methyl n-Amyl Ketone Category 2 -- Methyl Ethyl Ketone Category 2 -- Methyl Isobutyl Ketone Category 2 -- Xylene, mixed isomers Category 2 -- Aspiration hazard Name Result Xylene, mixed isomers ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs Information on the likely routes of exposure Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness :Not available. Potential acute health effects Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 14/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 11. Toxicological information Not available. Causes damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :No known significant effects or critical hazards. Skin contact Ingestion unconsciousness No specific data. Adverse symptoms may include the following: irritation redness : : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 10595.99 mg/kg Inhalation (vapors)71.6 mg/l Route ATE value Acute toxicity estimates Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Section 12. Ecological information Toxicity Acetone Acute EC50 7200000 µg/l Fresh water Algae - Selenastrum sp.96 hours Acute LC50 4.42589 ml/L Marine water Crustaceans - Acartia tonsa - Copepodid 48 hours Acute LC50 7460000 µg/l Fresh water Daphnia - Daphnia cucullata 48 hours Acute LC50 5600 ppm Fresh water Fish - Poecilia reticulata 96 hours Chronic NOEC 4.95 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - Neonate 21 days Chronic NOEC 5 µg/l Marine water Fish - Gasterosteus aculeatus - Larvae 42 days Methyl n-Amyl Ketone Acute LC50 131000 µg/l Fresh water Fish - Pimephales promelas 96 hours Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours Product/ingredient name SpeciesResult Exposure Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 15/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name Epoxy Polymer -31 low Xylene, mixed isomers -8.1 to 25.9 low Product/ingredient name Aquatic half-life Photolysis Biodegradability Acetone --Readily Methyl n-Amyl Ketone --Readily Methyl Ethyl Ketone --Readily Methyl Isobutyl Ketone --Readily Xylene, mixed isomers --Readily Methyl Ethyl Ketone Acute EC50 >500000 µg/l Marine water Algae - Skeletonema costatum 96 hours Acute EC50 5091000 µg/l Fresh water Daphnia - Daphnia magna - Larvae 48 hours Acute LC50 3220000 µg/l Fresh water Fish - Pimephales promelas 96 hours Barium Sulfate Acute EC50 634 mg/l Fresh water Crustaceans - Cypris subglobosa 48 hours Acute EC50 32 mg/l Fresh water Daphnia - Daphnia magna 48 hours Methyl Isobutyl Ketone Acute LC50 505000 µg/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 78 mg/l Fresh water Daphnia - Daphnia magna 21 days Chronic NOEC 168 mg/l Fresh water Fish - Pimephales promelas - Embryo 33 days Xylene, mixed isomers Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours Persistence and degradability Soil/water partition coefficient (KOC) :Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 16/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 14. Transport information PAINT 3 II PAINT. Marine pollutant (Zinc Phosphate, Epoxy Polymer) 3 II UN1263 UN1263 -The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg. Emergency schedules F-E, S- E DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to IMO instruments No.Yes. Not available. : Proper shipping name : Not available. : TDG Classification UN1263 PAINT 3 II No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). Mexico Classification UN1263 PAINT 3 II No. - Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. IATA UN1263 PAINT 3 II Yes. The environmentally hazardous substance mark is not required. The environmentally hazardous substance mark may appear if required by other transportation regulations. 128 ERG No. 128 128 ERG No.ERG No. Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 17/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 15. Regulatory information SARA 313 SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International regulations International lists : Section 16. Other information 8/3/2022 History Date of printing Date of issue/Date of revision Version Date of previous issue : : : : 8/3/2022 6/9/2022 5.01 Hazardous Material Information System (U.S.A.) 3 3 0 *Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. FLAMMABLE LIQUIDS - Category 2 On basis of test data SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method SKIN SENSITIZATION - Category 1 Calculation method CARCINOGENICITY - Category 1A Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Calculation method Procedure used to derive the classification Classification Justification Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 18/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Indicates information that has changed from previously issued version. Key to abbreviations : Notice to reader ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision :8/3/2022 Date of previous issue :6/9/2022 Version :5.01 19/19 E90HXA233-4371 PERFORMANCE COATINGS FINISHES 2.8 epoxy primer part a Blue SHW-85-NA-GHS-US Polane 8910 Polyurethane Enamel Star BLue Not available. Liquid. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer :THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. F63GXL33693-4371 F63GXL33693-4371Product code : Product Information Telephone Number :Not available. Regulatory Information Telephone Number :(216) 566-2902 Transportation Emergency Telephone Number :(800) 424-9300 Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 3 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Classification of the substance or mixture : Signal word :Warning Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 7.6% (oral), 17.7% (dermal), 18.9% (inhalation) OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 1/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US Section 2. Hazards identification Precautionary statements Prevention :Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General :Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified :None known. Flammable liquid and vapor. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Section 3. Composition/information on ingredients Other means of identification :Not available. Substance/mixture CAS number/other identifiers :Mixture Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 2/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US Section 3. Composition/information on ingredients Methyl n-Amyl Ketone ≥10 - ≤26 110-43-0 p-Chlorobenzotrifluoride ≥10 - ≤25 98-56-6 Titanium Dioxide ≤10 13463-67-7 Aspartic Ester ≤10 136210-32-7 n-Butyl Acetate ≤10 123-86-4 2-Ethyl-1,3-hexanediol ≤1.2 94-96-2 2,4-Pentanedione ≤1.1 123-54-6 UV Light Absorber ≤1 104810-48-2 Benzotriazole Hydroxyphenyl Polymer ≤1 104810-47-1 Bis(pentamethyl-4-piperidyl)sebacate ≤1 41556-26-7 Butyl Methacrylate ≤0.3 97-88-1 Xylene, mixed isomers ≤0.3 1330-20-7 2-Hydroxyethyl Methacrylate ≤0.3 868-77-9 Methyl Methacrylate ≤0.3 80-62-6 Ingredient name CAS number% by weight Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Causes serious eye irritation.:Eye contact Potential acute health effects Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 3/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments :No specific treatment. Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Use dry chemical, CO₂, water spray (fog) or foam. Extinguishing media Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 4/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides halogenated compounds carbonyl halides metal oxide/oxides Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 5/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Methyl n-Amyl Ketone 110-43-0 ACGIH TLV (United States, 1/2021). TWA: 50 ppm 8 hours. TWA: 233 mg/m³ 8 hours. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 465 mg/m³ 10 hours. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 465 mg/m³ 8 hours. p-Chlorobenzotrifluoride 98-56-6 None. Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 1/2021). TWA: 10 mg/m³ 8 hours. OSHA PEL (United States, 5/2018). TWA: 15 mg/m³ 8 hours. Form: Total dust Aspartic Ester 136210-32-7 None. n-Butyl Acetate 123-86-4 NIOSH REL (United States, 10/2020). TWA: 150 ppm 10 hours. TWA: 710 mg/m³ 10 hours. STEL: 200 ppm 15 minutes. STEL: 950 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 150 ppm 8 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) CAS # Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 6/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection TWA: 710 mg/m³ 8 hours. ACGIH TLV (United States, 1/2021). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. 2-Ethyl-1,3-hexanediol 94-96-2 None. 2,4-Pentanedione 123-54-6 ACGIH TLV (United States, 1/2021). Absorbed through skin. TWA: 25 ppm 8 hours. UV Light Absorber 104810-48-2 None. Benzotriazole Hydroxyphenyl Polymer 104810-47-1 None. Bis(pentamethyl-4-piperidyl)sebacate 41556-26-7 None. Butyl Methacrylate 97-88-1 None. Xylene, mixed isomers 1330-20-7 ACGIH TLV (United States, 1/2021). TWA: 100 ppm 8 hours. TWA: 434 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours. 2-Hydroxyethyl Methacrylate 868-77-9 None. Methyl Methacrylate 80-62-6 ACGIH TLV (United States, 1/2021). Skin sensitizer. TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 410 mg/m³ 10 hours. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 410 mg/m³ 8 hours. Methyl n-amyl ketone 110-43-0 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 233 mg/m³ 8 hours. 8 hrs OEL: 50 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 50 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 25 ppm 8 hours. TWA: 115 mg/m³ 8 hours. CA Quebec Provincial (Canada, 6/2021). TWAEV: 50 ppm 8 hours. TWAEV: 233 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 60 ppm 15 minutes. TWA: 50 ppm 8 hours. Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada, 6/2021). TWA: 10 mg/m³ 8 hours. Form: Total dust TWA: 3 mg/m³ 8 hours. Form: respirable fraction CA Quebec Provincial (Canada, 6/2021). Ingredient name Exposure limits Occupational exposure limits (Canada) CAS # Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 7/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection TWAEV: 10 mg/m³ 8 hours. Form: Total dust. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 10 mg/m³ 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 10 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 20 mg/m³ 15 minutes. TWA: 10 mg/m³ 8 hours. n-butyl acetate 123-86-4 CA Alberta Provincial (Canada, 6/2018). 15 min OEL: 200 ppm 15 minutes. 15 min OEL: 950 mg/m³ 15 minutes. 8 hrs OEL: 150 ppm 8 hours. 8 hrs OEL: 713 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 200 ppm 15 minutes. TWA: 150 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA Quebec Provincial (Canada, 6/2021). STEV: 150 ppm 15 minutes. TWAEV: 50 ppm 8 hours. pentane-2,4-dione 123-54-6 CA Ontario Provincial (Canada, 6/2019). Absorbed through skin. TWA: 25 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). Absorbed through skin. Butyl Methacrylate 97-88-1 CA British Columbia Provincial (Canada, 6/2021). TWA: 50 ppm 8 hours. Xylene 1330-20-7 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 100 ppm 8 hours. 15 min OEL: 651 mg/m³ 15 minutes. 15 min OEL: 150 ppm 15 minutes. 8 hrs OEL: 434 mg/m³ 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 100 ppm 8 hours. STEL: 150 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m³ 8 hours. STEV: 150 ppm 15 minutes. STEV: 651 mg/m³ 15 minutes. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 8/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Methyl methacrylate 80-62-6 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 205 mg/m³ 8 hours. 8 hrs OEL: 50 ppm 8 hours. 15 min OEL: 410 mg/m³ 15 minutes. 15 min OEL: 100 ppm 15 minutes. CA British Columbia Provincial (Canada, 6/2021). Skin sensitizer. TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). Skin sensitizer. TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). Skin sensitizer. TWAEV: 50 ppm 8 hours. STEV: 100 ppm 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). Skin sensitizer. STEL: 100 ppm 15 minutes. TWA: 50 ppm 8 hours. Environmental exposure controls : Methyl n-Amyl Ketone 110-43-0 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 50 ppm 8 hours. n-Butyl Acetate 123-86-4 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 150 ppm 8 hours. STEL: 200 ppm 15 minutes. pentane-2,4-dione 123-54-6 NOM-010-STPS-2014 (Mexico, 4/2016). Absorbed through skin. TWA: 20 ppm 8 hours. Exposure limits Occupational exposure limits (Mexico) CAS # Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 9/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Respiratory protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Relative density Solubility Liquid. Not available. 1.09 3.5 [Air = 1] Not available. Not available.Odor pH Not available.Color Evaporation rate 1 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 34°C (93.2°F) [Pensky-Martens Closed Cup] Not applicable. Not applicable. Viscosity Kinematic (40°C (104°F)): <20.5 mm2/s (<20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance :123°C (253.4°F) :Not available. :Lower: 0.9% Upper: 11.4% Decomposition temperature :Not available. Heat of combustion :18.147 kJ/g Aerosol product Molecular weight :Not applicable. Boiling point, initial boiling point, and boiling range Flammability Lower and upper explosion limit/flammability limit Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. 1.3 kPa (10 mm Hg) Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 10/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Methyl n-Amyl Ketone LD50 Oral Rat 1600 mg/kg - p-Chlorobenzotrifluoride LD50 Oral Rat 13 g/kg - n-Butyl Acetate LD50 Dermal Rabbit >17600 mg/kg - LD50 Oral Rat 10768 mg/kg - 2-Ethyl-1,3-hexanediol LD50 Dermal Rabbit 2 g/kg - LD50 Oral Rat 1400 mg/kg - 2,4-Pentanedione LD50 Oral Rat 55 mg/kg - Butyl Methacrylate LC50 Inhalation Gas.Rat 4910 ppm 4 hours LD50 Oral Rat 16 g/kg - Xylene, mixed isomers LC50 Inhalation Gas.Rat 6700 ppm 4 hours LD50 Oral Rat 4300 mg/kg - 2-Hydroxyethyl Methacrylate LD50 Oral Rat 5050 mg/kg - Methyl Methacrylate LC50 Inhalation Vapor Rat 78000 mg/m³4 hours LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat 7872 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Methyl n-Amyl Ketone Skin - Mild irritant Rabbit -24 hours 14 mg - Titanium Dioxide Skin - Mild irritant Human -72 hours 300 ug I - n-Butyl Acetate Eyes - Moderate irritant Rabbit -100 mg - Skin - Moderate irritant Rabbit -24 hours 500 mg - 2-Ethyl-1,3-hexanediol Eyes - Severe irritant Rabbit -20 mg - Skin - Mild irritant Rabbit -500 mg - 2,4-Pentanedione Eyes - Severe irritant Rabbit -20 mg - Skin - Mild irritant Rabbit -488 mg - Skin - Mild irritant Rabbit -6 hours 11.2 Ml I - Skin - Moderate irritant Rabbit -48 hours 11.2 - Product/ingredient name Result Score Exposure ObservationSpecies Information on toxicological effects Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 11/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Ml I Skin - Moderate irritant Rabbit -6 hours 33.6 Ml I - Butyl Methacrylate Skin - Mild irritant Rabbit -500 uL - Xylene, mixed isomers Eyes - Mild irritant Rabbit -87 mg - Eyes - Severe irritant Rabbit -24 hours 5 mg - Skin - Mild irritant Rat -8 hours 60 uL - Skin - Moderate irritant Rabbit -24 hours 500 mg - Skin - Moderate irritant Rabbit -100 %- Sensitization Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Methyl n-Amyl Ketone Category 3 -Respiratory tract irritation Category 3 Narcotic effects p-Chlorobenzotrifluoride Category 3 -Respiratory tract irritation n-Butyl Acetate Category 3 -Narcotic effects 2-Ethyl-1,3-hexanediol Category 3 -Respiratory tract irritation Category 3 Narcotic effects 2,4-Pentanedione Category 3 -Respiratory tract irritation Category 3 Narcotic effects Butyl Methacrylate Category 3 -Respiratory tract irritation Xylene, mixed isomers Category 3 -Respiratory tract irritation Methyl Methacrylate Category 3 -Respiratory tract irritation Name Category Route of exposure Target organs Classification p-Chlorobenzotrifluoride -2B - Titanium Dioxide -2B - Xylene, mixed isomers -3 - Methyl Methacrylate -3 - Product/ingredient name NTPIARCOSHA Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 12/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US Section 11. Toxicological information Name Category Methyl n-Amyl Ketone Category 2 -- 2-Ethyl-1,3-hexanediol Category 2 -- 2,4-Pentanedione Category 2 -- Xylene, mixed isomers Category 2 -- Aspiration hazard Name Result Xylene, mixed isomers ASPIRATION HAZARD - Category 1 Route of exposure Target organs Information on the likely routes of exposure Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Delayed and immediate effects and also chronic effects from short and long term exposure :Not available. Potential acute health effects Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 13/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US Section 11. Toxicological information Not available. May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :Suspected of damaging fertility. Potential chronic health effects Numerical measures of toxicity Oral 5355.38 mg/kg Dermal 20230.91 mg/kg Inhalation (gases)54294.31 ppm Inhalation (vapors)30.74 mg/l Route ATE value Acute toxicity estimates Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Section 12. Ecological information Toxicity Methyl n-Amyl Ketone Acute LC50 131000 µg/l Fresh water Fish - Pimephales promelas 96 hours Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours n-Butyl Acetate Acute LC50 32 mg/l Marine water Crustaceans - Artemia salina 48 hours Acute LC50 18000 µg/l Fresh water Fish - Pimephales promelas 96 hours 2-Ethyl-1,3-hexanediol Acute LC50 624000 µg/l Fresh water Fish - Ictalurus punctatus - Fingerling 96 hours 2,4-Pentanedione Acute EC50 75000 µg/l Fresh water Crustaceans - Ceriodaphnia reticulata - Larvae 48 hours Acute LC50 47600 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 60100 µg/l Fresh water Fish - Lepomis macrochirus 96 hours Butyl Methacrylate Chronic NOEC 2.6 mg/l Fresh water Daphnia - Daphnia magna - Neonate 21 days Xylene, mixed isomers Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours 2-Hydroxyethyl Methacrylate Acute LC50 227000 µg/l Fresh water Fish - Pimephales promelas - Juvenile (Fledgling, Hatchling, Weanling) 96 hours Methyl Methacrylate Acute LC50 130000 µg/l Fresh water Fish - Pimephales promelas - Adult 96 hours Product/ingredient name SpeciesResult Exposure Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 14/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name Aspartic Ester -0.25 low Xylene, mixed isomers -8.1 to 25.9 low Product/ingredient name Aquatic half-life Photolysis Biodegradability Methyl n-Amyl Ketone --Readily n-Butyl Acetate --Readily Xylene, mixed isomers --Readily Persistence and degradability Soil/water partition coefficient (KOC) :Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 14. Transport information PAINT 3 III PAINT 3 III UN1263 UN1263 DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No.No. TDG Classification UN1263 PAINT 3 III No. Mexico Classification UN1263 PAINT 3 III No. IATA UN1263 PAINT 3 III No. Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 15/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US Section 14. Transport information -Emergency schedules F-E, S- E Additional information Special precautions for user Transport in bulk according to IMO instruments Not available. : Proper shipping name : Not available. : Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). - Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. - 128 ERG No. 128 128 ERG No.ERG No. Section 15. Regulatory information SARA 313 TSCA 5(a)2 proposed significant new use rules: 2,4-Pentanedione SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International regulations International lists : Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 16/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US Section 16. Other information 8/3/2022 History Date of printing Date of issue/Date of revision Version Date of previous issue : : : : Indicates information that has changed from previously issued version. Key to abbreviations : 8/3/2022 4/15/2022 2 Hazardous Material Information System (U.S.A.) 2 3 0 *Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. FLAMMABLE LIQUIDS - Category 3 On basis of test data SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method SKIN SENSITIZATION - Category 1 Calculation method CARCINOGENICITY - Category 2 Calculation method TOXIC TO REPRODUCTION - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method Procedure used to derive the classification Classification Justification Notice to reader ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 17/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of issue/Date of revision :8/3/2022 Date of previous issue :4/15/2022 Version :2 18/18 F63GXL33693-4371 Polane 8910 Polyurethane Enamel Star BLue SHW-85-NA-GHS-US F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced) Not available. Liquid. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer :THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. F63GXG32596-4371 F63GXG32596-4371Product code : Product Information Telephone Number :Not available. Regulatory Information Telephone Number :(216) 566-2902 Transportation Emergency Telephone Number :(800) 424-9300 Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 3 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Classification of the substance or mixture : Signal word :Warning Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 6.9% (oral), 18.3% (dermal), 18.3% (inhalation) OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 1/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Section 2. Hazards identification Precautionary statements Prevention :Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General :Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified :None known. Flammable liquid and vapor. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Section 3. Composition/information on ingredients Other means of identification :Not available. Substance/mixture CAS number/other identifiers :Mixture Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 2/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Section 3. Composition/information on ingredients Methyl n-Amyl Ketone ≥10 - ≤25 110-43-0 p-Chlorobenzotrifluoride ≥10 - ≤25 98-56-6 Aspartic Ester ≤10 136210-32-7 n-Butyl Acetate ≤10 123-86-4 2-methoxy-1-methylethyl acetate ≤5 108-65-6 2,4-Pentanedione ≤1.2 123-54-6 UV Light Absorber ≤1 104810-48-2 Carbon Black ≤1 1333-86-4 Benzotriazole Hydroxyphenyl Polymer ≤1 104810-47-1 Bis(pentamethyl-4-piperidyl)sebacate ≤1 41556-26-7 Butyl Methacrylate ≤0.3 97-88-1 Titanium Dioxide ≤0.3 13463-67-7 Xylene, mixed isomers ≤0.3 1330-20-7 Ingredient name CAS number% by weight Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Causes serious eye irritation.:Eye contact Potential acute health effects Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 3/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments :No specific treatment. Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Use dry chemical, CO₂, water spray (fog) or foam. Extinguishing media Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 4/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides halogenated compounds carbonyl halides Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 5/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Methyl n-Amyl Ketone 110-43-0 ACGIH TLV (United States, 1/2021). TWA: 50 ppm 8 hours. TWA: 233 mg/m³ 8 hours. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 465 mg/m³ 10 hours. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 465 mg/m³ 8 hours. p-Chlorobenzotrifluoride 98-56-6 None. Aspartic Ester 136210-32-7 None. n-Butyl Acetate 123-86-4 NIOSH REL (United States, 10/2020). TWA: 150 ppm 10 hours. TWA: 710 mg/m³ 10 hours. STEL: 200 ppm 15 minutes. STEL: 950 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 150 ppm 8 hours. TWA: 710 mg/m³ 8 hours. ACGIH TLV (United States, 1/2021). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) CAS # Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 6/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection 2-methoxy-1-methylethyl acetate 108-65-6 OARS WEEL (United States, 1/2021). TWA: 50 ppm 8 hours. 2,4-Pentanedione 123-54-6 ACGIH TLV (United States, 1/2021). Absorbed through skin. TWA: 25 ppm 8 hours. UV Light Absorber 104810-48-2 None. Carbon Black 1333-86-4 ACGIH TLV (United States, 1/2021). TWA: 3 mg/m³ 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2020). TWA: 3.5 mg/m³ 10 hours. TWA: 0.1 mg of PAHs/cm³ 10 hours. OSHA PEL (United States, 5/2018). TWA: 3.5 mg/m³ 8 hours. Benzotriazole Hydroxyphenyl Polymer 104810-47-1 None. Bis(pentamethyl-4-piperidyl)sebacate 41556-26-7 None. Butyl Methacrylate 97-88-1 None. Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 1/2021). TWA: 10 mg/m³ 8 hours. OSHA PEL (United States, 5/2018). TWA: 15 mg/m³ 8 hours. Form: Total dust Xylene, mixed isomers 1330-20-7 ACGIH TLV (United States, 1/2021). TWA: 100 ppm 8 hours. TWA: 434 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours. Methyl n-amyl ketone 110-43-0 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 233 mg/m³ 8 hours. 8 hrs OEL: 50 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 50 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 25 ppm 8 hours. TWA: 115 mg/m³ 8 hours. CA Quebec Provincial (Canada, 6/2021). TWAEV: 50 ppm 8 hours. TWAEV: 233 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 60 ppm 15 minutes. TWA: 50 ppm 8 hours. n-butyl acetate 123-86-4 CA Alberta Provincial (Canada, 6/2018). 15 min OEL: 200 ppm 15 minutes. 15 min OEL: 950 mg/m³ 15 minutes. 8 hrs OEL: 150 ppm 8 hours. 8 hrs OEL: 713 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 200 ppm 15 minutes. Ingredient name Exposure limits Occupational exposure limits (Canada) CAS # Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 7/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection TWA: 150 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA Quebec Provincial (Canada, 6/2021). STEV: 150 ppm 15 minutes. TWAEV: 50 ppm 8 hours. pentane-2,4-dione 123-54-6 CA Ontario Provincial (Canada, 6/2019). Absorbed through skin. TWA: 25 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). Absorbed through skin. Carbon black 1333-86-4 CA British Columbia Provincial (Canada, 6/2021). TWA: 3 mg/m³ 8 hours. Form: Inhalable CA Ontario Provincial (Canada, 6/2019). TWA: 3 mg/m³ 8 hours. Form: Inhalable particulate matter. CA Quebec Provincial (Canada, 6/2021). TWAEV: 3 mg/m³ 8 hours. Form: inhalable dust CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 3.5 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 7 mg/m³ 15 minutes. TWA: 3.5 mg/m³ 8 hours. Butyl Methacrylate 97-88-1 CA British Columbia Provincial (Canada, 6/2021). TWA: 50 ppm 8 hours. Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada, 6/2021). TWA: 10 mg/m³ 8 hours. Form: Total dust TWA: 3 mg/m³ 8 hours. Form: respirable fraction CA Quebec Provincial (Canada, 6/2021). TWAEV: 10 mg/m³ 8 hours. Form: Total dust. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 10 mg/m³ 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 10 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 20 mg/m³ 15 minutes. TWA: 10 mg/m³ 8 hours. Xylene 1330-20-7 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 100 ppm 8 hours. 15 min OEL: 651 mg/m³ 15 minutes. 15 min OEL: 150 ppm 15 minutes. 8 hrs OEL: 434 mg/m³ 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 100 ppm 8 hours. Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 8/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection : : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection STEL: 150 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m³ 8 hours. STEV: 150 ppm 15 minutes. STEV: 651 mg/m³ 15 minutes. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. Environmental exposure controls : Methyl n-Amyl Ketone 110-43-0 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 50 ppm 8 hours. n-Butyl Acetate 123-86-4 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 150 ppm 8 hours. STEL: 200 ppm 15 minutes. pentane-2,4-dione 123-54-6 NOM-010-STPS-2014 (Mexico, 4/2016). Absorbed through skin. TWA: 20 ppm 8 hours. Exposure limits Occupational exposure limits (Mexico) CAS # Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 9/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Respiratory protection : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Relative density Solubility Liquid. Not available. 1.04 3.5 [Air = 1] Not available. Not available.Odor pH Not available.Color Evaporation rate 1 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 33°C (91.4°F) [Pensky-Martens Closed Cup] Not applicable. Not applicable. Viscosity Kinematic (40°C (104°F)): <20.5 mm2/s (<20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance :123°C (253.4°F) :Not available. :Lower: 0.9% Upper: 13.1% Decomposition temperature :Not available. Heat of combustion :19.973 kJ/g Aerosol product Molecular weight :Not applicable. Boiling point, initial boiling point, and boiling range Flammability Lower and upper explosion limit/flammability limit Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. 1.3 kPa (10 mm Hg) Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 10/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Methyl n-Amyl Ketone LD50 Oral Rat 1600 mg/kg - p-Chlorobenzotrifluoride LD50 Oral Rat 13 g/kg - n-Butyl Acetate LD50 Dermal Rabbit >17600 mg/kg - LD50 Oral Rat 10768 mg/kg - 2-methoxy-1-methylethyl acetate LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat 8532 mg/kg - 2,4-Pentanedione LD50 Oral Rat 55 mg/kg - Carbon Black LD50 Oral Rat >15400 mg/kg - Butyl Methacrylate LC50 Inhalation Gas.Rat 4910 ppm 4 hours LD50 Oral Rat 16 g/kg - Xylene, mixed isomers LC50 Inhalation Gas.Rat 6700 ppm 4 hours LD50 Oral Rat 4300 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Methyl n-Amyl Ketone Skin - Mild irritant Rabbit -24 hours 14 mg - n-Butyl Acetate Eyes - Moderate irritant Rabbit -100 mg - Skin - Moderate irritant Rabbit -24 hours 500 mg - 2,4-Pentanedione Eyes - Severe irritant Rabbit -20 mg - Skin - Mild irritant Rabbit -488 mg - Skin - Mild irritant Rabbit -6 hours 11.2 Ml I - Skin - Moderate irritant Rabbit -48 hours 11.2 Ml I - Skin - Moderate irritant Rabbit -6 hours 33.6 Ml I - Butyl Methacrylate Skin - Mild irritant Rabbit -500 uL - Titanium Dioxide Skin - Mild irritant Human -72 hours 300 ug I - Product/ingredient name Result Score Exposure ObservationSpecies Information on toxicological effects Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 11/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Xylene, mixed isomers Eyes - Mild irritant Rabbit -87 mg - Eyes - Severe irritant Rabbit -24 hours 5 mg - Skin - Mild irritant Rat -8 hours 60 uL - Skin - Moderate irritant Rabbit -24 hours 500 mg - Skin - Moderate irritant Rabbit -100 %- Sensitization Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Methyl n-Amyl Ketone Category 3 -Respiratory tract irritation Category 3 Narcotic effects p-Chlorobenzotrifluoride Category 3 -Respiratory tract irritation n-Butyl Acetate Category 3 -Narcotic effects 2-methoxy-1-methylethyl acetate Category 3 -Narcotic effects 2,4-Pentanedione Category 3 -Respiratory tract irritation Category 3 Narcotic effects Butyl Methacrylate Category 3 -Respiratory tract irritation Xylene, mixed isomers Category 3 -Respiratory tract irritation Name Category Name Category Methyl n-Amyl Ketone Category 2 -- 2,4-Pentanedione Category 2 -- Xylene, mixed isomers Category 2 -- Aspiration hazard Route of exposure Target organs Route of exposure Target organs Classification p-Chlorobenzotrifluoride -2B - Carbon Black -2B - Titanium Dioxide -2B - Xylene, mixed isomers -3 - Product/ingredient name NTPIARCOSHA Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 12/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Section 11. Toxicological information Name Result Xylene, mixed isomers ASPIRATION HAZARD - Category 1 Not available. Information on the likely routes of exposure Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure :Not available. Potential acute health effects Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 13/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Section 11. Toxicological information May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :Suspected of damaging fertility. Numerical measures of toxicity Oral 5796.23 mg/kg Dermal 22207.34 mg/kg Inhalation (gases)51817.13 ppm Inhalation (vapors)31.96 mg/l Route ATE value Acute toxicity estimates Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Product/ingredient name Aspartic Ester -0.25 low Xylene, mixed isomers -8.1 to 25.9 low Product/ingredient name Aquatic half-life Photolysis Biodegradability Methyl n-Amyl Ketone --Readily n-Butyl Acetate --Readily Xylene, mixed isomers --Readily Toxicity Methyl n-Amyl Ketone Acute LC50 131000 µg/l Fresh water Fish - Pimephales promelas 96 hours n-Butyl Acetate Acute LC50 32 mg/l Marine water Crustaceans - Artemia salina 48 hours Acute LC50 18000 µg/l Fresh water Fish - Pimephales promelas 96 hours 2,4-Pentanedione Acute EC50 75000 µg/l Fresh water Crustaceans - Ceriodaphnia reticulata - Larvae 48 hours Acute LC50 47600 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 60100 µg/l Fresh water Fish - Lepomis macrochirus 96 hours Butyl Methacrylate Chronic NOEC 2.6 mg/l Fresh water Daphnia - Daphnia magna - Neonate 21 days Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours Xylene, mixed isomers Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 14/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Section 12. Ecological information Other adverse effects :No known significant effects or critical hazards. Soil/water partition coefficient (KOC) :Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 14. Transport information PAINT 3 III PAINT 3 III UN1263 UN1263 -Emergency schedules F-E, S- E DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No.No. TDG Classification UN1263 PAINT 3 III No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). Mexico Classification UN1263 PAINT 3 III No. - IATA UN1263 PAINT 3 III No. - 128 ERG No. 128 128 ERG No.ERG No. Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 15/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Section 14. Transport information Special precautions for user Transport in bulk according to IMO instruments Not available. : Proper shipping name : Not available. :Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. Section 15. Regulatory information SARA 313 TSCA 5(a)2 proposed significant new use rules: 2,4-Pentanedione SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International regulations International lists : Section 16. Other information Hazardous Material Information System (U.S.A.) 2 3 0 *Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 16/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Section 16. Other information 7/21/2022 History Date of printing Date of issue/Date of revision Version It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of previous issue : : : : Indicates information that has changed from previously issued version. Key to abbreviations : 7/21/2022 7/6/2022 8 FLAMMABLE LIQUIDS - Category 3 On basis of test data SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method SKIN SENSITIZATION - Category 1 Calculation method CARCINOGENICITY - Category 2 Calculation method TOXIC TO REPRODUCTION - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method Procedure used to derive the classification Classification Justification Notice to reader ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 17/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Date of issue/Date of revision :7/21/2022 Date of previous issue :7/6/2022 Version :8 18/18 F63GXG32596-4371 F63GX/GP POLANE G PLUS 8910 POLYURETHANE WITH OPTICOLOR XP GREEN RAL 6009 (Pre-Reduced)SHW-85-NA-GHS-US Polane 8910 Polyurethane Enamel RAL 6003 Superior Green Not available. Liquid. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer :THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. F63GXG33703-4371 F63GXG33703-4371Product code : Product Information Telephone Number :Not available. Regulatory Information Telephone Number :(216) 566-2902 Transportation Emergency Telephone Number :(800) 424-9300 Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 3 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Classification of the substance or mixture : Signal word :Warning Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 7.6% (oral), 18.6% (dermal), 19.6% (inhalation) OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 1/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Section 2. Hazards identification Precautionary statements Prevention :Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General :Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified :None known. Flammable liquid and vapor. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Section 3. Composition/information on ingredients Other means of identification :Not available. Substance/mixture CAS number/other identifiers :Mixture Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 2/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Section 3. Composition/information on ingredients Methyl n-Amyl Ketone ≥10 - ≤26 110-43-0 p-Chlorobenzotrifluoride ≥10 - ≤25 98-56-6 Aspartic Ester ≤10 136210-32-7 n-Butyl Acetate ≤10 123-86-4 2-methoxy-1-methylethyl acetate ≤3 108-65-6 Titanium Dioxide ≤3 13463-67-7 2,4-Pentanedione ≤1.2 123-54-6 2-Ethyl-1,3-hexanediol ≤1.1 94-96-2 UV Light Absorber ≤1 104810-48-2 Benzotriazole Hydroxyphenyl Polymer ≤1 104810-47-1 Bis(pentamethyl-4-piperidyl)sebacate ≤1 41556-26-7 Carbon Black ≤0.3 1333-86-4 Butyl Methacrylate ≤0.3 97-88-1 Xylene, mixed isomers ≤0.3 1330-20-7 2-Hydroxyethyl Methacrylate ≤0.3 868-77-9 Methyl Methacrylate ≤0.3 80-62-6 Ingredient name CAS number% by weight Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Potential acute health effects Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 3/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments :No specific treatment. Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Use dry chemical, CO₂, water spray (fog) or foam. Extinguishing media Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 4/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides halogenated compounds carbonyl halides metal oxide/oxides Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 5/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Methyl n-Amyl Ketone 110-43-0 ACGIH TLV (United States, 1/2021). TWA: 50 ppm 8 hours. TWA: 233 mg/m³ 8 hours. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 465 mg/m³ 10 hours. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 465 mg/m³ 8 hours. p-Chlorobenzotrifluoride 98-56-6 None. Aspartic Ester 136210-32-7 None. n-Butyl Acetate 123-86-4 NIOSH REL (United States, 10/2020). TWA: 150 ppm 10 hours. TWA: 710 mg/m³ 10 hours. STEL: 200 ppm 15 minutes. STEL: 950 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 150 ppm 8 hours. TWA: 710 mg/m³ 8 hours. ACGIH TLV (United States, 1/2021). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) CAS # Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 6/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection 2-methoxy-1-methylethyl acetate 108-65-6 OARS WEEL (United States, 1/2021). TWA: 50 ppm 8 hours. Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 1/2021). TWA: 10 mg/m³ 8 hours. OSHA PEL (United States, 5/2018). TWA: 15 mg/m³ 8 hours. Form: Total dust 2,4-Pentanedione 123-54-6 ACGIH TLV (United States, 1/2021). Absorbed through skin. TWA: 25 ppm 8 hours. 2-Ethyl-1,3-hexanediol 94-96-2 None. UV Light Absorber 104810-48-2 None. Benzotriazole Hydroxyphenyl Polymer 104810-47-1 None. Bis(pentamethyl-4-piperidyl)sebacate 41556-26-7 None. Carbon Black 1333-86-4 ACGIH TLV (United States, 1/2021). TWA: 3 mg/m³ 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2020). TWA: 3.5 mg/m³ 10 hours. TWA: 0.1 mg of PAHs/cm³ 10 hours. OSHA PEL (United States, 5/2018). TWA: 3.5 mg/m³ 8 hours. Butyl Methacrylate 97-88-1 None. Xylene, mixed isomers 1330-20-7 ACGIH TLV (United States, 1/2021). TWA: 100 ppm 8 hours. TWA: 434 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours. 2-Hydroxyethyl Methacrylate 868-77-9 None. Methyl Methacrylate 80-62-6 ACGIH TLV (United States, 1/2021). Skin sensitizer. TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 410 mg/m³ 10 hours. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 410 mg/m³ 8 hours. Methyl n-amyl ketone 110-43-0 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 233 mg/m³ 8 hours. 8 hrs OEL: 50 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 50 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 25 ppm 8 hours. TWA: 115 mg/m³ 8 hours. CA Quebec Provincial (Canada, 6/2021). TWAEV: 50 ppm 8 hours. TWAEV: 233 mg/m³ 8 hours. Ingredient name Exposure limits Occupational exposure limits (Canada) CAS # Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 7/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection CA Saskatchewan Provincial (Canada, 7/2013). STEL: 60 ppm 15 minutes. TWA: 50 ppm 8 hours. n-butyl acetate 123-86-4 CA Alberta Provincial (Canada, 6/2018). 15 min OEL: 200 ppm 15 minutes. 15 min OEL: 950 mg/m³ 15 minutes. 8 hrs OEL: 150 ppm 8 hours. 8 hrs OEL: 713 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 200 ppm 15 minutes. TWA: 150 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA Quebec Provincial (Canada, 6/2021). STEV: 150 ppm 15 minutes. TWAEV: 50 ppm 8 hours. Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada, 6/2021). TWA: 10 mg/m³ 8 hours. Form: Total dust TWA: 3 mg/m³ 8 hours. Form: respirable fraction CA Quebec Provincial (Canada, 6/2021). TWAEV: 10 mg/m³ 8 hours. Form: Total dust. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 10 mg/m³ 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 10 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 20 mg/m³ 15 minutes. TWA: 10 mg/m³ 8 hours. pentane-2,4-dione 123-54-6 CA Ontario Provincial (Canada, 6/2019). Absorbed through skin. TWA: 25 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). Absorbed through skin. Carbon black 1333-86-4 CA British Columbia Provincial (Canada, 6/2021). TWA: 3 mg/m³ 8 hours. Form: Inhalable CA Ontario Provincial (Canada, 6/2019). TWA: 3 mg/m³ 8 hours. Form: Inhalable particulate matter. CA Quebec Provincial (Canada, 6/2021). TWAEV: 3 mg/m³ 8 hours. Form: inhalable dust CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 3.5 mg/m³ 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 7 mg/m³ 15 minutes. Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 8/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection TWA: 3.5 mg/m³ 8 hours. Butyl Methacrylate 97-88-1 CA British Columbia Provincial (Canada, 6/2021). TWA: 50 ppm 8 hours. Xylene 1330-20-7 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 100 ppm 8 hours. 15 min OEL: 651 mg/m³ 15 minutes. 15 min OEL: 150 ppm 15 minutes. 8 hrs OEL: 434 mg/m³ 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 100 ppm 8 hours. STEL: 150 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m³ 8 hours. STEV: 150 ppm 15 minutes. STEV: 651 mg/m³ 15 minutes. CA Ontario Provincial (Canada, 6/2019). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. Methyl methacrylate 80-62-6 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 205 mg/m³ 8 hours. 8 hrs OEL: 50 ppm 8 hours. 15 min OEL: 410 mg/m³ 15 minutes. 15 min OEL: 100 ppm 15 minutes. CA British Columbia Provincial (Canada, 6/2021). Skin sensitizer. TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). Skin sensitizer. TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). Skin sensitizer. TWAEV: 50 ppm 8 hours. STEV: 100 ppm 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). Skin sensitizer. STEL: 100 ppm 15 minutes. TWA: 50 ppm 8 hours. Occupational exposure limits (Mexico) Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 9/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Environmental exposure controls : Methyl n-Amyl Ketone 110-43-0 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 50 ppm 8 hours. n-Butyl Acetate 123-86-4 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 150 ppm 8 hours. STEL: 200 ppm 15 minutes. pentane-2,4-dione 123-54-6 NOM-010-STPS-2014 (Mexico, 4/2016). Absorbed through skin. TWA: 20 ppm 8 hours. Exposure limitsCAS # Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 10/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Relative density Solubility Liquid. Not available. 1.04 3.5 [Air = 1] Not available. Not available.Odor pH Not available.Color Evaporation rate 1 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 33°C (91.4°F) [Pensky-Martens Closed Cup] Not applicable. Not applicable. Viscosity Kinematic (40°C (104°F)): <20.5 mm2/s (<20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance :123°C (253.4°F) :Not available. :Lower: 0.9% Upper: 13.1% Decomposition temperature :Not available. Heat of combustion :19.656 kJ/g Aerosol product Molecular weight :Not applicable. Boiling point, initial boiling point, and boiling range Flammability Lower and upper explosion limit/flammability limit Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. 1.3 kPa (10 mm Hg) Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 11/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Section 11. Toxicological information Acute toxicity Methyl n-Amyl Ketone LD50 Oral Rat 1600 mg/kg - p-Chlorobenzotrifluoride LD50 Oral Rat 13 g/kg - n-Butyl Acetate LD50 Dermal Rabbit >17600 mg/kg - LD50 Oral Rat 10768 mg/kg - 2-methoxy-1-methylethyl acetate LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat 8532 mg/kg - 2,4-Pentanedione LD50 Oral Rat 55 mg/kg - 2-Ethyl-1,3-hexanediol LD50 Dermal Rabbit 2 g/kg - LD50 Oral Rat 1400 mg/kg - Carbon Black LD50 Oral Rat >15400 mg/kg - Butyl Methacrylate LC50 Inhalation Gas.Rat 4910 ppm 4 hours LD50 Oral Rat 16 g/kg - Xylene, mixed isomers LC50 Inhalation Gas.Rat 6700 ppm 4 hours LD50 Oral Rat 4300 mg/kg - 2-Hydroxyethyl Methacrylate LD50 Oral Rat 5050 mg/kg - Methyl Methacrylate LC50 Inhalation Vapor Rat 78000 mg/m³4 hours LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat 7872 mg/kg - Product/ingredient name Result Species Dose Exposure Mutagenicity Not available. Irritation/Corrosion Methyl n-Amyl Ketone Skin - Mild irritant Rabbit -24 hours 14 mg - n-Butyl Acetate Eyes - Moderate irritant Rabbit -100 mg - Skin - Moderate irritant Rabbit -24 hours 500 mg - Titanium Dioxide Skin - Mild irritant Human -72 hours 300 ug I - 2,4-Pentanedione Eyes - Severe irritant Rabbit -20 mg - Skin - Mild irritant Rabbit -488 mg - Skin - Mild irritant Rabbit -6 hours 11.2 Ml I - Skin - Moderate irritant Rabbit -48 hours 11.2 Ml I - Skin - Moderate irritant Rabbit -6 hours 33.6 Ml I - 2-Ethyl-1,3-hexanediol Eyes - Severe irritant Rabbit -20 mg - Skin - Mild irritant Rabbit -500 mg - Butyl Methacrylate Skin - Mild irritant Rabbit -500 uL - Xylene, mixed isomers Eyes - Mild irritant Rabbit -87 mg - Eyes - Severe irritant Rabbit -24 hours 5 mg - Skin - Mild irritant Rat -8 hours 60 uL - Skin - Moderate irritant Rabbit -24 hours 500 mg - Skin - Moderate irritant Rabbit -100 %- Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Information on toxicological effects Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 12/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Section 11. Toxicological information Carcinogenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Methyl n-Amyl Ketone Category 3 -Respiratory tract irritation Category 3 Narcotic effects p-Chlorobenzotrifluoride Category 3 -Respiratory tract irritation n-Butyl Acetate Category 3 -Narcotic effects 2-methoxy-1-methylethyl acetate Category 3 -Narcotic effects 2,4-Pentanedione Category 3 -Respiratory tract irritation Category 3 Narcotic effects 2-Ethyl-1,3-hexanediol Category 3 -Respiratory tract irritation Category 3 Narcotic effects Butyl Methacrylate Category 3 -Respiratory tract irritation Xylene, mixed isomers Category 3 -Respiratory tract irritation Methyl Methacrylate Category 3 -Respiratory tract irritation Name Category Name Category Methyl n-Amyl Ketone Category 2 -- 2,4-Pentanedione Category 2 -- 2-Ethyl-1,3-hexanediol Category 2 -- Xylene, mixed isomers Category 2 -- Aspiration hazard Name Result Xylene, mixed isomers ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs Classification p-Chlorobenzotrifluoride -2B - Titanium Dioxide -2B - Carbon Black -2B - Xylene, mixed isomers -3 - Methyl Methacrylate -3 - Product/ingredient name NTPIARCOSHA Information on the likely routes of exposure :Not available. Potential acute health effects Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 13/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Section 11. Toxicological information Not available. Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 14/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Section 11. Toxicological information Fertility effects :Suspected of damaging fertility. Numerical measures of toxicity Oral 5256.69 mg/kg Dermal 18690.23 mg/kg Inhalation (gases)49163.16 ppm Inhalation (vapors)29.73 mg/l Route ATE value Acute toxicity estimates Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Product/ingredient name Aspartic Ester -0.25 low Xylene, mixed isomers -8.1 to 25.9 low Product/ingredient name Aquatic half-life Photolysis Biodegradability Methyl n-Amyl Ketone --Readily n-Butyl Acetate --Readily Xylene, mixed isomers --Readily Toxicity Methyl n-Amyl Ketone Acute LC50 131000 µg/l Fresh water Fish - Pimephales promelas 96 hours n-Butyl Acetate Acute LC50 32 mg/l Marine water Crustaceans - Artemia salina 48 hours Acute LC50 18000 µg/l Fresh water Fish - Pimephales promelas 96 hours Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours 2,4-Pentanedione Acute EC50 75000 µg/l Fresh water Crustaceans - Ceriodaphnia reticulata - Larvae 48 hours Acute LC50 47600 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 60100 µg/l Fresh water Fish - Lepomis macrochirus 96 hours 2-Ethyl-1,3-hexanediol Acute LC50 624000 µg/l Fresh water Fish - Ictalurus punctatus - Fingerling 96 hours Butyl Methacrylate Chronic NOEC 2.6 mg/l Fresh water Daphnia - Daphnia magna - Neonate 21 days Xylene, mixed isomers Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours 2-Hydroxyethyl Methacrylate Acute LC50 227000 µg/l Fresh water Fish - Pimephales promelas - Juvenile (Fledgling, Hatchling, Weanling) 96 hours Methyl Methacrylate Acute LC50 130000 µg/l Fresh water Fish - Pimephales promelas - Adult 96 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability Mobility in soil Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 15/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Section 12. Ecological information Other adverse effects :No known significant effects or critical hazards. Soil/water partition coefficient (KOC) :Not available. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 14. Transport information PAINT 3 III PAINT 3 III UN1263 UN1263 -Emergency schedules F-E, S- E DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No.No. TDG Classification UN1263 PAINT 3 III No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). Mexico Classification UN1263 PAINT 3 III No. - IATA UN1263 PAINT 3 III No. - 128 ERG No. 128 128 ERG No.ERG No. Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 16/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Section 14. Transport information Special precautions for user Transport in bulk according to IMO instruments Not available. : Proper shipping name : Not available. :Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. Section 15. Regulatory information SARA 313 TSCA 5(a)2 proposed significant new use rules: 2,4-Pentanedione SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International regulations International lists : Section 16. Other information Hazardous Material Information System (U.S.A.) 2 3 0 *Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 17/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Section 16. Other information 8/2/2022 History Date of printing Date of issue/Date of revision Version It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of previous issue : : : : Indicates information that has changed from previously issued version. Key to abbreviations : 8/2/2022 4/18/2022 2 FLAMMABLE LIQUIDS - Category 3 On basis of test data SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method SKIN SENSITIZATION - Category 1 Calculation method CARCINOGENICITY - Category 2 Calculation method TOXIC TO REPRODUCTION - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method Procedure used to derive the classification Classification Justification Notice to reader ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 18/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US Date of issue/Date of revision :8/2/2022 Date of previous issue :4/18/2022 Version :2 19/19 F63GXG33703-4371 Polane 8910 Polyurethane Enamel RAL 6003 Superior Green SHW-85-NA-GHS-US 2K Epoxy Hardener Not available. Liquid. US / Canada: (216) 566-2917 Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer :THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. V66VC304 V66VC304Product code : Product Information Telephone Number :US / Canada: 1-844-290-6044 Mexico: Not Available Regulatory Information Telephone Number :US / Canada: (216) 566-2902 Mexico: Not Available Transportation Emergency Telephone Number :US / Canada: (216) 566-2917 Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 3 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 SKIN SENSITIZATION - Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Classification of the substance or mixture : Signal word :Danger Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute inhalation toxicity: 28.2% OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision :6/23/2022 Date of previous issue :3/14/2022 Version :2 1/15 V66VC304 2K Epoxy Hardener SHW-85-NA-GHS-US Section 2. Hazards identification Precautionary statements Prevention :Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response :Get medical advice or attention if you feel unwell. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor. Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified :None known. Flammable liquid and vapor. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. May cause respiratory irritation. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure. :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains a chemical known to the State of California to cause cancer. FOR INDUSTRIAL USE ONLY. This product must be mixed with other components before use. Before opening the packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS. : Section 3. Composition/information on ingredients 1-Butanol ≥10 - ≤29 71-36-3 2-Propanol ≥10 - ≤25 67-63-0 Triethylene Tetramine ≤1.7 112-24-3 Tri(dimethylaminomethyl)phenol ≤1.6 90-72-2 Triethyoxysilyl Propylamine ≤1.6 919-30-2 Ingredient name CAS number% by weight Other means of identification :Not available. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Date of issue/Date of revision :6/23/2022 Date of previous issue :3/14/2022 Version :2 2/15 V66VC304 2K Epoxy Hardener SHW-85-NA-GHS-US Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Get medical attention immediately. Call a poison center or physician. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage.:Eye contact Over-exposure signs/symptoms Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness : Eye contact :Adverse symptoms may include the following: pain watering redness Potential acute health effects Date of issue/Date of revision :6/23/2022 Date of previous issue :3/14/2022 Version :2 3/15 V66VC304 2K Epoxy Hardener SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments :No specific treatment. Skin contact Ingestion Adverse symptoms may include the following: stomach pains Adverse symptoms may include the following: pain or irritation redness blistering may occur : : See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO₂, water spray (fog) or foam. Extinguishing media : : : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For non-emergency personnel Date of issue/Date of revision :6/23/2022 Date of previous issue :3/14/2022 Version :2 4/15 V66VC304 2K Epoxy Hardener SHW-85-NA-GHS-US Section 6. Accidental release measures Environmental precautions Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. :Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Date of issue/Date of revision :6/23/2022 Date of previous issue :3/14/2022 Version :2 5/15 V66VC304 2K Epoxy Hardener SHW-85-NA-GHS-US 1-Butanol 71-36-3 ACGIH TLV (United States, 1/2021). TWA: 20 ppm 8 hours. NIOSH REL (United States, 10/2020). Absorbed through skin. CEIL: 50 ppm CEIL: 150 mg/m³ OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 300 mg/m³ 8 hours. 2-Propanol 67-63-0 ACGIH TLV (United States, 1/2021). TWA: 200 ppm 8 hours. STEL: 400 ppm 15 minutes. NIOSH REL (United States, 10/2020). TWA: 400 ppm 10 hours. TWA: 980 mg/m³ 10 hours. STEL: 500 ppm 15 minutes. STEL: 1225 mg/m³ 15 minutes. OSHA PEL (United States, 5/2018). TWA: 400 ppm 8 hours. TWA: 980 mg/m³ 8 hours. Triethylene Tetramine 112-24-3 OARS WEEL (United States, 1/2021). Absorbed through skin. TWA: 1 ppm 8 hours. Tri(dimethylaminomethyl)phenol 90-72-2 None. Triethyoxysilyl Propylamine 919-30-2 None. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) Normal butyl alcohol 71-36-3 CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 60 mg/m³ 8 hours. 8 hrs OEL: 20 ppm 8 hours. CA British Columbia Provincial (Canada, 6/2021). TWA: 15 ppm 8 hours. C: 30 ppm CA Ontario Provincial (Canada, 6/2019). TWA: 20 ppm 8 hours. CA Quebec Provincial (Canada, 6/2021). Absorbed through skin. STEV: 50 ppm 15 minutes. STEV: 152 mg/m³ 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 30 ppm 15 minutes. TWA: 20 ppm 8 hours. Isopropyl alcohol 67-63-0 CA Alberta Provincial (Canada, 6/2018). 15 min OEL: 984 mg/m³ 15 minutes. 8 hrs OEL: 200 ppm 8 hours. 15 min OEL: 400 ppm 15 minutes. 8 hrs OEL: 492 mg/m³ 8 hours. CA British Columbia Provincial (Canada, 6/2021). Ingredient name Exposure limits Occupational exposure limits (Canada) CAS # CAS # Date of issue/Date of revision :6/23/2022 Date of previous issue :3/14/2022 Version :2 6/15 V66VC304 2K Epoxy Hardener SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Eye/face protection : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection TWA: 200 ppm 8 hours. STEL: 400 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). TWA: 200 ppm 8 hours. STEL: 400 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). TWAEV: 400 ppm 8 hours. TWAEV: 983 mg/m³ 8 hours. STEV: 500 ppm 15 minutes. STEV: 1230 mg/m³ 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 400 ppm 15 minutes. TWA: 200 ppm 8 hours. Triethylenetetramine 112-24-3 CA Ontario Provincial (Canada, 6/2019). Absorbed through skin. TWA: 3 mg/m³ 8 hours. TWA: 0.5 ppm 8 hours. Environmental exposure controls : 1-Butanol 71-36-3 NOM-010-STPS-2014 (Mexico, 4/2016). Absorbed through skin. TWA: 20 ppm 8 hours. 2-Propanol 67-63-0 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 200 ppm 8 hours. STEL: 400 ppm 15 minutes. Exposure limits Occupational exposure limits (Mexico) CAS # Date of issue/Date of revision :6/23/2022 Date of previous issue :3/14/2022 Version :2 7/15 V66VC304 2K Epoxy Hardener SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Respiratory protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Relative density Solubility Liquid. Not available. 0.91 2.07 [Air = 1] Not available. Not available.Odor pH Not available.Color Evaporation rate 1.44 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 23°C (73.4°F) [Pensky-Martens Closed Cup] Not applicable. Not applicable. Viscosity Kinematic (40°C (104°F)): >20.5 mm2/s (>20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance :81°C (177.8°F) :Not available. :Lower: 1.4% Upper: 12.7% Decomposition temperature :Not available. Heat of combustion :17.5 kJ/g Aerosol product Molecular weight :Not applicable. Boiling point, initial boiling point, and boiling range Flammability Lower and upper explosion limit/flammability limit Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. 4.4 kPa (33 mm Hg) Date of issue/Date of revision :6/23/2022 Date of previous issue :3/14/2022 Version :2 8/15 V66VC304 2K Epoxy Hardener SHW-85-NA-GHS-US Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity 1-Butanol LC50 Inhalation Vapor Rat 24000 mg/m³4 hours LD50 Dermal Rabbit 3400 mg/kg - LD50 Oral Rat 790 mg/kg - 2-Propanol LD50 Dermal Rabbit 12800 mg/kg - LD50 Oral Rat 5000 mg/kg - Triethylene Tetramine LD50 Dermal Rabbit 805 mg/kg - LD50 Oral Rat 2500 mg/kg - Tri(dimethylaminomethyl) phenol LD50 Dermal Rat 1280 mg/kg - LD50 Oral Rat 1200 mg/kg - Triethyoxysilyl Propylamine LD50 Dermal Rabbit 4.29 g/kg - LD50 Oral Rat 1.57 g/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion 1-Butanol Eyes - Severe irritant Rabbit -24 hours 2 mg - Eyes - Severe irritant Rabbit -0.005 Ml - Skin - Moderate irritant Rabbit -24 hours 20 mg - 2-Propanol Eyes - Moderate irritant Rabbit -24 hours 100 mg - Eyes - Moderate irritant Rabbit -10 mg - Eyes - Severe irritant Rabbit -100 mg - Skin - Mild irritant Rabbit -500 mg - Triethylene Tetramine Eyes - Moderate irritant Rabbit -24 hours 20 mg - Eyes - Severe irritant Rabbit -49 mg - Skin - Severe irritant Rabbit -24 hours 5 mg - Skin - Severe irritant Rabbit -490 mg - Tri(dimethylaminomethyl)Eyes - Severe irritant Rabbit -24 hours 50 - Product/ingredient name Result Score Exposure ObservationSpecies Information on toxicological effects Date of issue/Date of revision :6/23/2022 Date of previous issue :3/14/2022 Version :2 9/15 V66VC304 2K Epoxy Hardener SHW-85-NA-GHS-US Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. phenol ug Skin - Mild irritant Rat -0.025 Ml - Skin - Severe irritant Rat -0.25 Ml - Skin - Severe irritant Rabbit -24 hours 2 mg - Triethyoxysilyl Propylamine Eyes - Mild irritant Rabbit -100 mg - Eyes - Severe irritant Rabbit -24 hours 750 ug - Skin - Severe irritant Rabbit -24 hours 5 mg - Sensitization Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) 1-Butanol Category 3 -Respiratory tract irritation Category 3 Narcotic effects 2-Propanol Category 3 -Narcotic effects Name Category Name Category 1-Butanol Category 2 -- Aspiration hazard Not available. Route of exposure Target organs Route of exposure Target organs Classification 2-Propanol -3 - Product/ingredient name NTPIARCOSHA Information on the likely routes of exposure Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage.:Eye contact :Not available. Potential acute health effects Date of issue/Date of revision :6/23/2022 Date of previous issue :3/14/2022 Version :2 10/15 V66VC304 2K Epoxy Hardener SHW-85-NA-GHS-US Section 11. Toxicological information Not available. May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Adverse symptoms may include the following: stomach pains Adverse symptoms may include the following: pain or irritation redness blistering may occur : : : Eye contact :Adverse symptoms may include the following: pain watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 2320.81 mg/kg Dermal 9368.58 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Date of issue/Date of revision :6/23/2022 Date of previous issue :3/14/2022 Version :2 11/15 V66VC304 2K Epoxy Hardener SHW-85-NA-GHS-US Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name Triethyoxysilyl Propylamine -3.4 low Product/ingredient name Aquatic half-life Photolysis Biodegradability 1-Butanol --Readily 2-Propanol --Readily Toxicity 1-Butanol Acute EC50 1983 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 1730000 µg/l Fresh water Fish - Pimephales promelas 96 hours 2-Propanol Acute EC50 7550 mg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 1400000 µg/l Marine water Crustaceans - Crangon crangon 48 hours Acute LC50 4200 mg/l Fresh water Fish - Rasbora heteromorpha 96 hours Triethylene Tetramine Acute LC50 33900 µg/l Fresh water Daphnia - Daphnia magna 48 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability Soil/water partition coefficient (KOC) :Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 14. Transport information Date of issue/Date of revision :6/23/2022 Date of previous issue :3/14/2022 Version :2 12/15 V66VC304 2K Epoxy Hardener SHW-85-NA-GHS-US Section 14. Transport information PAINT RELATED MATERIAL 3 III PAINT RELATED MATERIAL 3 III UN1263 UN1263 -Emergency schedules F-E, S- E DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to IMO instruments No.No. Not available. : Proper shipping name : Not available. : TDG Classification UN1263 PAINT RELATED MATERIAL 3 III No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). Mexico Classification UN1263 PAINT RELATED MATERIAL 3 III No. - Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. IATA UN1263 PAINT RELATED MATERIAL 3 III No. - 128 ERG No. 128 128 ERG No.ERG No. Section 15. Regulatory information SARA 313 SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. WARNING: This product contains a chemical known to the State of California to cause cancer. California Prop. 65 International regulations Date of issue/Date of revision :6/23/2022 Date of previous issue :3/14/2022 Version :2 13/15 V66VC304 2K Epoxy Hardener SHW-85-NA-GHS-US Section 15. Regulatory information Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International lists : Section 16. Other information 6/23/2022 History Date of printing Date of issue/Date of revision Version Date of previous issue : : : : Key to abbreviations : 6/23/2022 3/14/2022 2 Hazardous Material Information System (U.S.A.) 3 3 0 *Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. FLAMMABLE LIQUIDS - Category 3 On basis of test data SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Calculation method SKIN SENSITIZATION - Category 1 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method Procedure used to derive the classification Classification Justification ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) Date of issue/Date of revision :6/23/2022 Date of previous issue :3/14/2022 Version :2 14/15 V66VC304 2K Epoxy Hardener SHW-85-NA-GHS-US Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Indicates information that has changed from previously issued version. Notice to reader N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision :6/23/2022 Date of previous issue :3/14/2022 Version :2 15/15 V66VC304 2K Epoxy Hardener SHW-85-NA-GHS-US 5 of 5 Highway 61 South, P.O. Box 249 Cleveland, MS 38732 Tel: (800) 345-2495 Fax: (662) 843-4048 Attachment C Best Available Control Technology (BACT) Review Best Available Control Technology (BACT) Review Quality Steel – West Jordan, Utah BACT Rules: Utah Administrative Codes and Rules (UACR) Rule R307-401-6: "The executive Secretary shall issue an approval order if he determines through plan review that the following conditions have been met: A. The degree of pollution control for emissions, to include fugitive emissions and fugitive dust, is at least best available control technology (BACT) except as otherwise provided in these regulations." Definition of BACT from Rule R307-101-2: "BACT means an emission limitation and/or other controls to include design, equipment, work practice, operation standard or combination thereof, based on a maximum degree of reduction of each pollutant subject to regulation under the Clean Air Act and/or the Utah Air Conservation Act emitted from or which results from any emitting installation, which the Air Quality Board, on a case-by-case basis taking into account energy, environmental and economic impacts and other costs, determines is achievable for such installation through application of production process and available methods, systems and techniques, including fuel cleaning or treatment or innovative fuel combustion techniques for control of each such pollutant. In no event shall application of BACT result in emission of pollutants which will exceed the emissions allowed by section 111 or 112 of the Clean Air Act." As the rule states, the source is obligated to base its proposed BACT on the most effective engineering techniques and control equipment to minimize emission of air contaminants into the outside environment from its process. The Utah Department of Environmental Quality (DEQ) requires the industry to identify the most technically feasible and efficient pollution control devices available. Process Description: Quality Steel (the facility) submits this BACT evaluation as supplemental information to the application submitted on June 13, 2022 to evaluate control technologies and control costs for the volatile organic compounds (VOCs) emissions from a proposed increase in production from approximately 2,500 hours per year to approximately 4,500 hours per year, resulting in an increase of VOCs of 20 tons per year, to a new permit limit of 65.01 tons per year, for the primer and top coat paint booths. VOC emissions are associated with the application and curing of the VOC-containing coating materials on steel tanks. This analysis will evaluate technically feasible options to control the additional 20 tons of captured stack VOC emissions per year over 2,000 additional hours of operation. Detailed emission calculations are presented in the above-referenced application and the results are provided in Table 1. Table 1: VOC Potential-to-Emit (PTE) Summary Proposed Production Increase Total VOC PTE Increase Due to 2,000 hr Operating Hour Increase (lbs/hr) Total VOC PTE Increase Due to 2,000 hr Operating Hour Increase (tons/yr) Estimated Total Add-on Controls VOC PTE @ w/ 98% Control Efficiency (tons/yr) Primer Coat Booth (2,500 to 4,500 hours) 7.5 7.5 0.15 Top Coat Booth (2,500 to 4,500 hours) 12.5 12.5 0.25 VOC PTE 20.0 20.0 0.40 Note: Estimated Potential-to-Emit based on VOC limit increase of 20.0 tons VOC per year, over 2,000 additional operating hours per year, and 98% control efficiency for thermal oxidation control options. Regulatory Analysis: There are no New Source Performance Standard (NSPS) or National Emissions Standards for Hazardous Air Pollutants (NESHAP) for the subject emission units which would set the floor for the level of the proposed BACT emission limitation. Accordingly, Quality Steel has prepared this BACT evaluation according to R307-401-6. Since the BACT definition contained in R307-101-2 is nearly identical to the federal definition under the Prevention of Significant Deterioration (PSD) program, and the Utah DEQ has not provided a guidance document prescribing how BACT analyses should be conducted, the facility has chosen to conduct a qualitative, five-step “top-down” BACT analysis for the surface coating operation emissions, in general conformance with EPA guidance under the PSD program. Under the top-down approach, the most stringent control available for a similar or identical source or source category is identified. This control option is used to establish the BACT emission limitation unless the applicant can demonstrate (and the permitting authority agrees) that it is not “achievable” due to technical or economic infeasibility or other adverse environmental or energy consequences of implementing the technology. If the top control alternative is eliminated, then the next most stringent level of control is evaluated. This process continues until the control option under consideration cannot be eliminated by any source-specific adverse environmental, energy, or economic impacts. Each of the five-steps conducted in a top-down BACT analysis are presented in the following subsections. Step 1 – Identify All Add-on Control Technologies In determining whether a technology is available for controlling VOC emissions associated with this operation, the following resources were consulted: 1) Reasonably Available Control Technology (RACT)/BACT/Lowest Achievable Emission Reduction (LAER) Clearinghouse (RBLC) database, 2) EPA’s Clean Air Technology Center (CATC) fact sheets, and 3) an internet search for permits for similar manufacturing operations across the U.S. The RBLC database was searched to identify any comparable sources that have implemented BACT for similar manufacturing facilities. The following searches were conducted for RBLC permits issued on or after January 2000: • An advanced search was conducted by querying all sources within the RBLC database in which the “SIC Code” contains the number “3443”, which applies to fabricated plate work. No results were returned for this search. • Advanced searches were conducted by querying all sources within the RBLC database in which the “Process Name” contains the words “steel tank painting”, “steel plate painting”, and the “Pollutant” contains the word “VOC”. This search returned no results of facilities meeting such descriptions which are employing BACT add-on control technologies. • In addition to the RBLC database review, the facility performed on-line research by using the aforementioned key words to identify possible state-level permits for similar facilities that were required to install add-on control technologies to meet SIP-based emission standards. o Approval order DAQE-AN160580001-21 Apache Global Painting, located in Salt Lake County, issued August 11, 2021 has similar painting operations with VOC emissions of 21.08 tons per year. Apache submitted a BACT analysis that was approved by DAQ as best available control technology (BACT) without add-on controls. While there is no additional information available regarding emission control technologies imposed by permitting authorities as BACT within the past ten years for the subject process or industry, the facility has identified the following add-on control technologies as the commercially-available controls for general VOC-emitting processes, regardless of the industrial sector or process to be controlled. The control technologies identified in the USEPA’s Air Pollution Control Technology Fact Sheets were considered in order of decreasing emission reduction potential. Detailed discussions and consideration of add-on control technologies are discussed below: Thermal Oxidation A thermal oxidizer supplies sufficient combustion air and supplemental fuel at a suitable temperature to allow for oxidation of VOC and other combustible compounds present in the exhaust stream within the combustion chamber. Oxidizers are categorized by either a thermal or catalytic design and can be further subdivided into units with and without exhaust gas heat recovery. Straight thermal oxidizers without heat recovery are reserved for applications where the heating value of the exhaust streams routed to the oxidizer is high enough that large amounts of supplemental fuel combustion or high levels of heat recovery are not necessary to bring the exhaust gases to oxidation reaction temperatures. In order to provide VOC control in a practical and cost-effective manner, straight thermal oxidizers require a VOC inlet concentration of greater than 1,500 ppmv, because at this concentration, the heat of combustion produced from oxidizing VOC present in the exhaust gas is sufficient to sustain adequate operating temperatures without the addition of large quantities of expensive auxiliary fuel.1 Oxidizers with heat recovery are either considered recuperative or regenerative depending on the design of the incoming process gas to exhaust gas heat exchange system. Recuperative thermal oxidizers (labeled herein as a TO) use plate-to-plate or shell-and-tube gas heat exchangers to recover up to 70 percent of the sensible heat present in the hot exhaust to transfer it to the incoming process gas. EPA expects that a TO can achieve a destruction/removal efficiency (DRE) of greater than 98 percent depending on the system requirements and 1 EPA, Air Pollution Control Technology Fact Sheet – Recuperative Incinerator. EPA-452/F-03-020. characteristics of the air contaminant stream.2 A regenerative thermal oxidizer (RTO) uses a high-density packed heat transfer media, typically ceramic random saddle packing or honeycomb monolith structures, to preheat incoming waste gas streams and to achieve 85 to 95 percent heat recovery. The RTO consists of at least two (2) modules that are cycled between inlet and outlet service to maintain appropriate operating temperatures and to conserve as much thermal energy as possible. The high level of heat integration offered by RTOs is particularly suited for high flow rate and low VOC concentration waste gas streams that do not vary in composition or flow rate over time. When necessary, the feed gas stream in an RTO can also be further heated to the oxidizer’s operating temperatures (1,400 to 2,000oF) through supplemental fuel combustion. RTOs have been used effectively in applications where the inlet VOC concentration is as low as 100 ppmv, and therefore, they are the preferred oxidizer design for low VOC concentration exhaust streams.3 EPA expects that an RTO can achieve a DRE of greater than 95 percent depending on the system’s requirements and the characteristics of the contaminated stream.4 Thermal oxidation systems designed to pass the gas stream over a catalyst bed (usually a noble metal such as palladium or platinum), where combustible compounds can be oxidized at a faster rate and at a lower temperature than is possible with a TO or RTO, are called catalytic oxidation systems (CatOx). This process requires temperatures of 600 to 1,000oF to achieve high destruction efficiencies for VOC.5,6 Below this temperature range, the reaction rate drops sharply, and effective oxidation of VOC is no longer feasible. Above this temperature, conventional oxidation catalysts break down and are unable to perform their desired functions. Aside from the need to operate within a specific temperature window, the exhaust gases must be relatively free of sulfur, particulate matter, and other catalyst poisons for catalytic oxidation to operate effectively. Alternate variations on the standard CatOx system include the use of additional heat recovery systems or heat-transfer media to improve thermal efficiency. The use of a CatOx system to control low-VOC emissions streams from process operations will typically achieve the same VOC DRE as recuperative or regenerative oxidation systems, greater than 95 percent.7 Adsorption Regenerative adsorption systems are typically a batch operation involving two or more fixed adsorption beds. One or more of the beds operates in adsorption mode while the others operate in regeneration mode. Several adsorbent materials with substantial surface area per unit volume can be used in adsorbers including activated carbon, organic resin polymers, and inorganic materials such as zeolite. An induced draft fan is typically used to force the VOC-laden gas through the adsorption bed where the VOC molecules are physically bound to the pore space in the adsorbent by Van der Waals nuclear attraction forces. There are many types of carbon, polymer, and zeolite adsorbents available with different affinities for adsorbing various VOCs. A key selection criteri on for determining 2 Ibid. 3 EPA, Air Pollution Control Technology Fact Sheet – Regenerative Incinerator. EPA-452/F-03-021. 4 Ibid. 5 EPA, Air Pollution Control Technology Fact Sheet – Catalytic Incinerator. EPA-452/F-03-018. 6 David A. Lewandowski. Design of Thermal Oxidation Systems for Volatile Organic Compounds. Lewis Publishers, Boca Raton, Fl. p. 198. 7 EPA, Air Pollution Control Technology Fact Sheet – Catalytic Incinerator. EPA-452/F-03-018. the appropriate adsorbent is the range of pore sizes relative to the largest molecular size of the VOC(s) to be adsorbed. The batch nature of the adsorption process concludes when the adsorbent bed becomes saturated with VOC and must be regenerated. The gas-solid interface within the bed at which adsorption is occurring is referred to as the mass transfer zone (MTZ), and the location of this MTZ within the bed determines its level of bed saturation and the time at which it must be regenerated. When the MTZ nears the end of the bed, the VOC concentration of the exhaust gas will increase producing a phenomenon referred to as “breakthrough”. After breakthrough has occurred in an adsorbent bed, it must be regenerated using a thermal swing or vacuum process. Thermal swing regeneration uses steam to raise the temperature of the loaded adsorbent bed to the boiling point of the VOC at which point the VOC is desorbed and is discharged from the bed with the steam. The VOC- laden steam is then routed to a condenser to produce a liquid water-VOC mixture. The VOC is then separated from the water using a decantation or distillation process and can be recycled back to the process from which it was generated or routed to an appropriate disposal site. Vacuum regeneration lowers the pressure of the adsorbent bed to below the vapor pressure of the adsorbed VOC at the ambient temperature of the bed. At this reduced pressure, the VOC boils off of the adsorbent and can be collected in a condenser or routed to an oxidizer. Adsorbers capture VOC from relatively dilute concentration streams and release these VOC into a higher concentration stream that can be readily controlled using another VOC destruction or recovery technology. Once the regeneration cycle is completed, the fresh adsorbent bed is ready for capturing additional VOC in another adsorption cycle.8 The typical VOC inlet concentration required for effective adsorption falls in the range of 400 to 2,000 ppmv and adsorbers and their associated follow-on devices (i.e., condenser or decanter) are typically capable of achieving VOC control efficiencies greater than 95 percent.9 UV Oxidation In a UV oxidation system, an exhaust stream is mixed with a photochemical oxidant such as ozone or peroxide and irradiated with UV light to produce reactive hydroxyl or oxygen radicals which oxidize the VOC present in the exhaust. The chemistry of the process is similar to the atmospheric reactions that occur when VOCs are degraded when exposed to sunlight. The usefulness of UV oxidation as a VOC control technology is contingent upon the target VOC being receptive to photo-oxidation. Condensation Condensers operate by lowering the temperature of exhaust gas streams containing condensable VOC to a temperature at which the target VOC’s vapor pressure is lower than its entering partial pressure or a condition referred to as the saturation point. Before the VOC can condense, any sensible heat present in the exhaust gas above the saturation point must be removed. Cooling the exhaust stream to a temperature below the saturation point removes the latent heat from the exhaust and allows the VOC to condense on the surface of the condenser 8 EPA Clean Air Technology Center, Technical Bulletin Choosing an Adsorption System for VOC: Carbon, Zeolite, or Polymer?, EPA 456/F-99-004, May 1999. 9 Ibid. tubes for collection and recycling to the process or disposal to an appropriate location. The tubes located within the condenser contain recirculating cooling fluid that provides a heat sink for rejecting both sensible and latent heat from the hot exhaust gas stream. Available cooling fluids (depending on the necessary outlet temperature of the exhaust stream to achieve high levels of recovery for the condensable VOC) include chilled water, brine, or refrigerants. Once the cooling fluid is passed through the condenser, it is chilled to the required condenser inlet temperature and recycled to the condenser. 10 The VOC control efficiency achieved by a condenser is a function of: 1) the heat capacity and temperature of the inlet exhaust stream, 2) the heat transfer characteristics of the condenser (including the heat transfer area and the heat transfer coefficient), 3) and the outlet temperature of the exhaust gas exiting the condenser. Conde nsers are most effective in single component systems involving emissions streams with a high percentage of a condensable VOC, because less heat must be removed from the exhaust gas to reduce the sensible heat of non-condensable gases, and the required condenser temperature to achieve high levels of recovery approaches the boiling point of the pure VOC. Unlike other VOC control devices for which quantifying control efficiency can require emission testing, only the outlet exhaust gas temperature is required to estimate the VOC control efficiency of a condenser if the temperature, VOC concentration, and flow rate of the non-condensables in the inlet exhaust stream are all known. Since the control efficiency of a condenser is dynamic based on the outlet temperature and inlet concentration of VOC in the exhaust stream, condensers exhibit a wide range of VOC control efficiency that can be as low as 50 percent and as high as 99 percent. 11, 12 Flares Flares are a VOC combustion control process in which VOCs are piped to a remote, usually elevated location, and burned in an open flame in the open air. Flares use a specially designed burner tip, auxiliary fuel, and air to promote mixing and temperatures for proper VOC destruction. Completeness of combustion in a flare is governed by flame temperature, residence time in the combustion zone, turbulent mixing of the gas stream components to complete the oxidation reaction, and available oxygen for free radical formation. Combustion is complete if all VOC emissions are converted to carbon dioxide (CO2) and water. Incomplete combustion results in some of the VOCs being unaltered or converted to other organic compounds such as aldehydes or organic acids. Biofiltration In biofiltration, off-gases containing biodegradable organic compounds are vented, under controlled temperature and humidity, through a biologically active material. The process uses a biofilm containing a population of microorganisms immobilized on a porous substrate such as peat, soil, sand, wood, compost, or numerous synthetic media. As an air stream passes through the biofilter, the contaminants in the air stream partition from the gaseous phase to the liquid phase of the biofilm. Once contaminants pass into the liquid phase, they become bioavailable for the complex oxidative process by the microorganisms inhabiting the biofilm. 10 EPA Office of Air Quality Planning and Standards, Control of Volatile Organic Compound Emissions from Batch Processes – Alternative Control Technique Information Document, EPA-450/R-94-020, February 1994, available at http://www.epa.gov/ttnnaaqs/ozone/ctg_act/199402_voc_epa453_r-93-017_batch_processes.pdf. 11 Ibid. 12 EPA Clean Air Technology Center, Technical Bulletin Refrigerated Condensers for Control of Organic Air Emissions, EPA 456/F-99-004, May 1999. Membrane Separation Technologies Membrane separation technology involves the preferential transport of organic vapors through a non-porous gas separation membrane via a diffusion process. The feed stream is compressed to approximately 150 psig and sent to a condenser where the liquid solvent is recovered. The condenser bleed is sent to the membrane module where it is concentrated and returned to the compressor for further recovery in the condenser. Non-Thermal Plasma (NTP) Technology NTP technology consists of an electrically neutral form of gas containing substantial concentrations of electrons, ions, and other highly reactive free radicals with may be generated in the gas stream by application of electrical energy. In theory, the sequential chemical reactions result in the destruction of the air contaminants. The U.S. Navy sought to be one of the first to install and use NTP technology for controlling paint booth VOC emissions. Step 2 – Eliminate Technically Infeasible Options The following subsections document the feasibility of each of the identified control options specifically applied to the control of the VOC emissions from the coating operations. Table 2 provides a summary of VOC control technologies and their feasibility for this project. Table 2. Summary of RBLC Listed VOC Control Technologies Option: Control Technology Feasibility Comments 1a Inherently Lower-Emitting Process / Practice: Substitute Material: Good Design/Operation The process equipment is good design and operated as required by the current approval, using industry standard materials which meet DEQ Miscellaneous Metal Parts and Products Coatings (R307-350) requirements and are necessary to meet customer criteria. HVLP spray guns are used for efficient application of coatings to the substrate. Vertical stacks disperse VOC-related air pollutants. 1b Inherently Lower-Emitting Process / Practice: Substitute Material: Use low VOC materials Lower VOC material does not meet product / consumer performance and quality criteria. Not feasible at this time. 1c Inherently Lower-Emitting Process / Practice: Substitute Material: Use water-based coating materials Using water-based material would not meet product / consumer performance criteria. Not feasible at this time. 1d Inherently Lower-Emitting Process / Practice: Substitute Material: Use less material per unit Using less material would not meet product / consumer performance criteria. Not feasible at this time. 1e Inherently Lower-Emitting Process / Practice: Substitute Material: Use powder coatings Facility is evaluating whether this class of coatings could be installed and meet product / consumer performance criteria. Would require substantial investment in equipment. Not feasible at this time. 2 Add-on VOC Control: Regenerative Thermal Oxidation (RTO) Feasible 3 Add-on VOC Control: Fixed-bed Catalytic thermal oxidizer (CatOx) Feasible 4 Add-on VOC Control: Regenerative Catalytic Oxidation (RCO) Feasible 5 Add-on VOC Control: Condensers Not considered feasible due to low concentrations of VOC in exhaust gases. 6 Add-on VOC Control: Adsorption Not considered feasible due to low VOC concentration in exhaust gases and the potential for fouling of adsorption media with various hydrocarbon constituents. 7 Add-on VOC Control: UV Oxidation Not considered feasible due to potential for fouling of catalyst media with hydrocarbon emissions. 8 Add-on VOC Control: Flares Not considered feasible due to excess emissions of other pollutants and very low VOC concentration. 9 Add-on VOC Control: Biofiltration Not considered feasible due to potential fouling of the media. 10 Add-on VOC Control: Membrane Separation Technologies Not considered feasible due to potential fouling of membrane. 11 Add-on VOC Control: Non-Thermal Plasma (NTP) Technology Not considered feasible, immature technology. Thermal Oxidation Thermal oxidation systems are specifically designed for handling low VOC concentration emissions streams. Because of the required booth exhaust air flow rates to maintain a safe atmosphere and capture of overspray, the exhaust streams from the metal parts coating operations will have very low VOC concentrations that could present a technical challenge when designing an oxidation system. Despite the technical concerns associated with designing an oxidizer to control VOCs in an exhaust stream with such a low concentration that will vary significantly over time between shifts or production runs, the facility has retained thermal oxidation as a technically feasible control option for further consideration in the remaining steps of the BACT analysis. Adsorption Adsorbers are typically designed for treating emissions streams with a single VOC or a small number of VOCs with similar adsorption isotherms. The sporadic and low concentrations of VOCs emitted by the batch coating operations exhaust are expected to be largely comprised of various hydrocarbon fractions and, as such, adsorption is not a realistic control option for this system. A carbon-bed adsorber is not considered to be a technically feasible control option for reducing VOC emissions from this operation because of the very low pollutant loading and potential for premature fouling of the media. Condensation Condensers are only considered to be effective VOC control devices in applications involving high VOC concentration emissions streams that are at or near complete saturation of the VOC in the exhaust air. The drawing compound related exhaust is expected to contain a very dilute VOC concentration such that the control effectiveness of a condenser would be very low. Additionally, condensed moisture from ambient air would be included with the organic compounds, and the resulting liquid would be a waste that would require disposal. Therefore, condensation is not considered a technically feasible control option for this operation. UV UV light frequency must be selected for maximum VOC removal based on inlet stream constituents. The effectiveness of the control method is greatly diminished for a matrix of volatile constituents with variable photolytic destruction isotherms. Additionally, the interaction between chemical constituents, preferential destruction, and potential fouling of the titanium dioxide catalyst from inlet stream containing ambient moisture limit the effectiveness of UV oxidation. Therefore, UV oxidation is not considered a technically feasible control option for this operation. Flares Flares are not a technically feasible control option for VOC emissions from the facility operations. The large volume of air flow and the small VOC loading in the exhaust stream exclude the flare as an appropriate control device. Additionally, flares are primarily safety devices that deal with flows of short duration, such as an upset condition or accidental release from a process, rather than a control device used to treat a batch or semi-continuous emissions stream. Therefore, flares are not considered a technically feasible control option for this operation. Biofiltration Biofiltration systems are typically used for odor control in clearly speciated air streams. These control devices typically have large footprints and operate in narrow bands of temperature and pressure requiring expensive gas conditioning. The possible list of constituents and irregular concentrations in the exhaust of the coating operations (i.e., medium to heavy hydrocarbon fractions) may foul the system, requiring expensive replacement of the microorganisms and/or the biofilm. Therefore, biofiltration is not considered to be a technically-feasible control option. Membrane Separation Technologies Membrane separation technologies are not a technically-feasible option for this operation. These technologies for removal of VOCs from a gas stream are in use for product recovery, and also for certain environmental remediation applications. However, membrane systems are sensitive to mixture concentrations and conditions, and may not effectively accommodate fluctuations and low VOC concentrations in the gas stream, making them impractical for pollution control in many industrial applications. Therefore, membrane separation is not considered to be a technically-feasible control option. NTP Technology NTP Technology is not available commercially and has not yet been proven as effective. Therefore, based on availability, this is not a technically-feasible control option. Step 3 – Rank Remaining Add-on Control Technologies by Control Effectiveness The thermal oxidation systems are the only remaining available and technically feasible add-on control technologies. At 98+ percent control efficiency, thermal oxidation systems are expected to provide higher levels of VOC control, even at low pollutant concentrations. As such, RTO, TO, and CatOx, in that order, are remaining add-on control options that will be evaluated in Step 4 of the BACT evaluation process. Step 4 – Top Down Evaluation of Capture and Add-on Control Options The remaining technically feasible control options are evaluated in the following subsections based on economic, energy, and environmental considerations. The following key assumptions support the basis of this VOC BACT analysis: o The facility’s paint booth induced-draft fans have sufficient air flow to capture 100% of the VOC emissions during normal operation. The primer and spray booths each have a design air flow rate of 49,200 actual standard cubic feet per minute (acfm), which is required to maintain a safe atmosphere inside the paint booths while capturing emissions, which are discharged vertically above the roofline. o The facility’s primer and top-coat paint booths may operate on somewhat different schedules, which could result in wasted fuel should a single add-on control system be installed. The US EPA Air Pollution Control Cost Manual, Section 3.2 Chapter 2 Incinerators, Section 2.5.1.1 Equipment Costs, indicates that thermal oxidation units are rarely built for air flow rates greater than 50,000 scfm, though it may be possible to acquire larger units for custom application. Therefore, for the purposes of this evaluation, it is assumed each booth would require a separate pollution control system rather than sharing a common control system. o The add-on control device(s) must be capable of effectively destroying the VOC emissions at very low concentrations, as calculated below: ▪ The average hourly VOC emission rate from the primer paint booth is 7.5 lb/hr. Hence, the average VOC concentration delivered to the control device would be 7.5 lb/hr x 453,593 mg/lb / (49,200 cfm x 60 min /hr x 0.028317 cf/m3) = 40.7 mg/m3. ▪ The total hourly VOC emission rate from the topcoat paint booth is 12.5 lb/hr. Hence, the average VOC concentration delivered to a control device would be 12.5 lb/hr x 453,593 mg/lb / (49,200 cfm x 60 min /hr / 0.028317 cf/m3) = 67.8 mg/m3. Although these low VOC concentrations make control methods technically challenging and economically prohibitive, thermal oxidation is considered to be a technically feasible option for this BACT evaluation. Construction year, Producer price index (PPI), and equipment capture data are provided in Table 3.0 for the cost estimates provided in Tables 3.1 through 3.3 below: Table 3.0: Cost estimate Data for TO systems Tables 3.1 through 3.3 Description and Assumptions Primer Booth Topcoat Booth Construction Year for Quality Steel Project 2022 2022 PPI for construction year (2022) Producer Price Index (PPI) for -Power Boiler and Heat Exchanger Manufacturing: Fabricated Heat Exchangers and Steam Condensers, (PCU3324103324101) 493.3 493.3 PPI for Reference year (1999) Producer Price Index (PPI) for - Power Boiler and Heat Exchanger Manufacturing: Fabricated Heat Exchangers and Steam Condensers, (PCU3324103324101) 206 206 Capture of Paint Booth Systems at 49,200 acfm 100% 100% Note: Bureau of Labor Statistics Producer Price Indices for fabricated metal products :https://download.bls.gov/pub/time.series/pc/pc.data.18.FabricatedMetalProduct Recuperative Thermal Oxidizer (TO) It is estimated that 100% of the VOC emissions are captured in the paint booths and recuperative TOs can achieve a VOC control efficiency of up to 98 percent. Given the low VOC concentration in the combined exhaust stream from the ovens and booths, the exhaust cannot sustain combustion in a recuperative TO without the addition of a large amount of supplemental natural gas. Combusting large amounts of natural gas in a recuperative TO to achieve a 98 percent emissions reduction would have the negative environmental consequences of emissions of the by-products of combustion, including oxides of nitrogen and carbon dioxide. Cost estimates for recuperative TO systems for each paint booth are provided in Table 3 below: Table 3.1: Cost estimate for recuperative TO systems Description and Assumptions Primer Booth Topcoat Booth Estimated Cost of Recuperative TO @ 70% ER ( EPA 453/b-96-001, OAQPS Control Cost Manual, Section 2 Fig. 2.4); See link for reference: $325,000 $325,000 PPI for construction year 2022 (PCU3324103324101- Power Boiler and Heat Exchanger Manufacturing: Fabricated Heat Exchangers and Steam Condensers ) 493.3 493.3 Reference year PPI (1999) 206 206 Estimated Purchased Cost of Recuperative TO (2022) $778,342 $778,265 Estimated Cost of Recuperative TO Installation, Taxes, Freight, Foundations & sitework (75% of TO Purchase Cost) $583,756.40 $583,698.42 Estimated Cost of Recuperative TO, Installed (2022) $1,362,098.27 $1,361,962.99 Capital recovery factor 0.0710 0.0710 Indirect Annual Capital Recovery Cost $96,644.22 $96,634.62 Power - electricity consumption (KW). (Ref: US EPA Air Pollution Control Cost Manual, Section 3.2 Chapter 2 Incinerators, 2.5.2.1 Direct Annual Costs, Equation 2.42) 221.0 221.0 Direct Annual Electricity Cost (assumes electricity cost = $0.13 / KW-hr; 8760 hrs/yr) $57,447.71 $57,447.71 Direct Annual Maintenance Labor Cost, 1 operator per hour per day, or 365 m-h/yr x $25/hr) $9,125.00 $9,125.00 Direct Annual Maintenance Cost = 100% of maintenance labor $9,125.00 $9,125.00 Direct Annual Natural Gas Cost; assumes 2.0 mmBtu/hr burner per 10,000 acfm at 50% capacity, at $8.5 per mmBTU gas cost (engineering estimates). $83,640.00 $83,640.00 Indirect Annual Cost (overhead, admin, taxes, insurance)=15% of Direct Annual Costs $23,900.66 $23,900.66 Total Annualized Direct & Indirect Cost of Recuperative TO System (25-yr life span). $279,882.58 $279,872.99 Total Tons VOC Controlled. Assumes 98% control efficiency. (Tons VOC per year) 7.35 12.25 Total Cost Per Ton VOC Controlled ($/ton) $38,079 $22,847 Ref: US EPA Air Pollution Control Cost Manual Section 3.2 Chapter 2 Incinerators https://www.epa.gov/sites/production/files/2020-07/documents/cs3-2ch2.pdf and Bureau of Labor Statistics Producer Price Indices for fabricated metal products: https://download.bls.gov/pub/time.series/pc/pc.data.18.FabricatedMetalProduct The control cost for recuperative TO systems would be economically prohibitive and would have other negative, unintended environmental consequences, including excessive carbon dioxide, a greenhouse gas, emissions. Regenerative Thermal Oxidation (RTO) It is estimated 100% of the VOC emissions would be captured in the paint booths, and that the two (2) RTOs can achieve a VOC control efficiency of up to 98 percent. Besides being economically prohibitive, other adverse energy and environmental impacts would be involved with its implementation. Given the low VOC concentration in the combined exhaust stream from the booths and ovens, the exhaust cannot sustain combustion in an RTO without the addition of a large amount of supplemental natural gas. Combusting large amounts of natural gas in an RTO to achieve a 98 percent emissions reduction would have the negative environmental consequences of emissions of the by-products of combustion, including oxides of nitrogen and carbon dioxide. Cost estimates for regenerative TO systems for each paint booth, are provided in Table 4 below: Table 3.2: Cost estimate for regenerative TO systems Description and Assumptions Primer Booth Topcoat Booth Estimated Cost of Regenerative TO 95% ER ( EPA 453/b-96-001, OAQPS Control Cost Manual, Section 2, Fig. 2.5) $ 800,000 $ 800,000 PPI for construction year (2022) 493.3 493.3 Reference year PPI (1999) 206 206 Estimated Purchased Cost of Regenerative TO (2022) $ 1,915,918 $ 1,915,918 Estimated Cost of Regenerative TO Installation, Taxes, Freight, Foundations & sitework (75% of TO Purchase Cost) $ 1,436,939 $ 1,436,939 Estimated Cost of Regenerative TO, Installed (2022) $ 3,352,857 $ 3,352,857 Indirect Annual Capital Recovery Cost $ 237,893 $ 237,893 Power - electricity consumption (KW). (Ref: US EPA Air Pollution Control Cost Manual, Section 3.2 Chapter 2 Incinerators, 2.5.2.1 Direct Annual Costs, Equation 2.42) 221.0 221.0 Direct Annual Electricity Cost (assumes electricity cost = $0.13 / KW-hr; 8760 hrs/yr) $ 57,448 $ 57,448 Direct Annual Maintenance Labor Cost (365 m-h/year x $25/hr) $ 9,125 $ 9,125 Direct Annual Maintenance Cost = 100% of maintenance labor $ 9,125 $ 9,125 Direct Annual Natural Gas Cost $ 83,640 $ 83,640 Indirect Annual Cost (overhead, admin, taxes, insurance) $ 23,900 $ 23,900 Total Annualized Direct & Indirect Cost of Regenerative TO System (25-yr life span) $ 421,131 $ 421,131 Total Tons VOC Controlled 7.35 12.25 Total Cost Per Ton VOC Controlled ($/ton) $ 57,297 $ 34,378 Ref: US EPA Air Pollution Control Cost Manual Section 3.2 Chapter 2 Incinerators: https://www.epa.gov/sites/production/files/2020-07/documents/cs3-2ch2.pdf and Bureau of Labor Statistics Producer Price Indices for fabricated metal products: https://download.bls.gov/pub/time.series/pc/pc.data.18.FabricatedMetalProduct The facility submits that the annualized control cost for regenerative TO systems would be economically prohibitive and would have other negative, unintended environmental consequences. Catalytic Oxidation (CatOx) It is estimated 100% of the VOC emissions from each booth will be captured in the spray booths and ovens, and that the CatOx can achieve a VOC control efficiency of up to 98 percent. At the required system air flow rate, a bed of 100 cubic feet of catalyst is estimated to be required and replaced annually. Fouling of the catalyst is a concern that would need to be addressed for the specific application and specific pollutants during engineering design. Given the low VOC concentrations in the combined exhaust stream, the CatOx can destruct the pollutants with some supplemental natural gas to maintain bed temperature, but would still have the negative environmental consequences of emissions of the combustion by-products, including oxides of nitrogen and carbon dioxide. Cost estimates for CatOx systems for each booth, are provided in Table 5 below: Table 3.3: Cost estimate for CatOx TO systems Description and Assumptions Primer Booth Topcoat Booth Estimated Cost of Fixed Bed Catalytic TO (EPA 453/b-96-001, OAQPS Control Cost Manual, Section 2 Fig. 2.6) $575,000 $575,000 PPI for construction year 2022 (PCU3324103324101-Power Boiler and Heat Exchanger Manufacturing: Fabricated Heat Exchangers and Steam Condensers) 493.3 493.3 Reference year PPI (1999) 206 206 Estimated Purchased Cost of Catalytic TO (2022) $1,377,066 $1,377,066 Estimated Cost of Catalytic TO Installation, Taxes, Freight, Foundations & sitework (75% of TO Purchase Cost) $1,032,800 $1,032,800 Estimated Cost of Catalytic TO, Installed (2022) $2,409,866 $2,409,866 Capital recovery factor, assumes 25-yr lifespan at 5% interest 0.071 0.071 Indirect Annual Capital Recovery Cost $170,986 $170,986 Power - electricity consumption (KW). (Ref: US EPA Air Pollution Control Cost Manual, Section 3.2 Chapter 2 Incinerators, 2.5.2.1 Direct Annual Costs, Equation 2.42) 267.5 267.5 Direct Annual Electricity Cost (assumes electricity cost = $0.13 / KW-hr; 8760 hrs/yr) $69,542 $69,542 Direct Annual Maintenance Labor Cost (365 m-h/year x $25/hr) $9,125 $9,125 Direct Annual Maintenance Cost = 100% of maintenance labor $9,125 $9,125 Direct Annual Catalyst Replacement Cost ($650/cu ft x 100 cu ft x PPI 2022/PPI 1999) $155,668 $155,668 Direct Annual Natural Gas Cost (assumes 0.5 MMBtu/hr per 10,000 acfm at 50% capacity at $8.5 per million BTU) $20,910 $20,910 Indirect Annual Cost (overhead, admin, taxes, insurance) = 15% of Direct Annual costs $39,656 $39,656 Total Annualized Direct & Indirect Cost of Catalytic TO System (25-yr life span) $ 475,012 $ 475,012 Total Tons VOC Controlled (assumes 90% VOC capture in spray booths and ovens) 7.35 12.25 Total Cost-effectiveness Per Ton VOC Controlled ($/ton) $ 64,833 $ 38,982 Ref: US EPA Air Pollution Control Cost Manual Section 3.2 Chapter 2 Incinerators https://www.epa.gov/sites/production/files/2020-07/documents/cs3-2ch2.pdf and Bureau of Labor Statistics Producer Price Indices for fabricated metal products: https://download.bls.gov/pub/time.series/pc/pc.data.18.FabricatedMetalProduct While the most cost-effective option in this scenario, Quality Steel believes the annualized control cost for CatOx systems would be economically prohibitive and would have other negative, unintended environmental consequences, including excessive greenhouse gas emissions. Step 5 – Select BACT Based on effective control efficiency and the least economic impact of all control options, the facility believes the current painting operations, equipment, and materials used to achieve the customer-specified finish specifications inherently minimize VOC emissions and comply with BACT according to R307-401-6. The facility proposes that existing VOC operating practices and controls are equivalent to, or better than, the control technologies currently being utilized at similar facilities in the US. Thus, the use of any of the feasible add-on control technologies for the proposed 20.0 tpy increase in VOC emissions control for the painting operations would exceed currently acceptable BACT for similar operations. Additionally, thermal oxidation destruction strategies for the low VOC concentrations in the booth exhaust are considered to be technically challenging. While technically feasible, as demonstrated in this BACT evaluation, the currently available control technologies would be cost-prohibitive, and would have significant negative unintended environmental consequences, including significant emissions of greenhouse gases. Finally, the financial and administrative burden of VOC add-on controls would diminish the facility’s competitive position in the industry, when compared to peers that do not have VOC add-on controls on similar coating systems. Quality Steel respectfully requests the Utah Department of Environmental Quality apply BACT to the increased operating hours for the facility’s painting operations, with current coating limitations and application procedures, and without add-on controls. CAS #110-43-0 123-86-4 64742-95-6763-69-9 71-36-3 108-65-6 67-63-0 78-93-3 Aromatic N Butyl Petroleum Butyl PM Isopropyl Butyl Digly Year Month M.A.K.Acetate Distillates EEP Alcohol Acetate Alcohol Acetate 2021 January 3087 971 42 1173 37 0 127 119 2021 February 3618 884 105 1089 60 0 115 96 2021 March 4059 954 132 1183 68 0 151 101 2021 April 3416 802 126 963 37 0 147 102 2021 May 3081 867 117 968 52 0 133 87 2021 June 3379 954 122 1071 53 0 156 99 2021 July 3092 828 118 907 52 0 129 78 2021 August 3633 1331 141 1048 49 0 108 125 2021 September 4128 1035 138 1242 68 0 146 108 2021 October 3312 982 137 1051 52 0 172 95 2021 November 3024 915 141 1100 54 0 169 99 2021 December 2721 715 98 776 44 0 104 69 2500 hrs 95-63-6 112-07-2 2500 hrs 110-43-0 123-86-4 64742-95-6 763-69-9 1,2,4,VOC 12 Month Aromatic Trimethyl 2-ButoxyetTotal Total VOC Rolling N Butyl Petroleum benzene Acetate Pounds Tons Total M.A.K.Acetate Distillates EEP 42 69 5667 2.8335 31.024 5556.6 1747.8 75.6 2111.4 22 55 6044 3.022 31.261 6512.4 1591.2 189 1960.2 24 58 6730 3.365 31.452 7306.2 1717.2 237.6 2129.4 23 53 5669 2.8345 31.5815 6148.8 1443.6 226.8 1733.4 21 53 5379 2.6895 31.8285 5545.8 1560.6 210.6 1742.4 22 60 5916 2.958 32.6195 6082.2 1717.2 219.6 1927.8 48 57 5309 2.6545 32.924 5565.6 1490.4 212.4 1632.6 62 70 6567 3.2835 33.6725 6539.4 2395.8 253.8 1886.4 55 60 6980 3.49 33.9195 7430.4 1863 248.4 2235.6 60 53 5914 2.957 33.958 5961.6 1767.6 246.6 1891.8 54 57 5613 2.8065 35.476 5443.2 1647 253.8 1980 22 43 4592 2.296 35.19 4897.8 1287 176.4 1396.8 71-36-3 108-65-6 67-63-0 78-93-3 95-63-6 112-07-2 4500 hrs 1,2,4,VOC Butyl PM Isopropyl Butyl Diglycol Trimethyl 2-Butoxyethyl Total Total Alcohol Acetate Alcohol Acetate benzene Acetate Pounds Tons 66.6 0 228.6 214.2 75.6 124.2 10200.6 5.1003 108 0 207 172.8 39.6 99 10879.2 5.4396 122.4 0 271.8 181.8 43.2 104.4 12114 6.057 66.6 0 264.6 183.6 41.4 95.4 10204.2 5.1021 93.6 0 239.4 156.6 37.8 95.4 9682.2 4.8411 95.4 0 280.8 178.2 39.6 108 10648.8 5.3244 93.6 0 232.2 140.4 86.4 102.6 9556.2 4.7781 88.2 0 194.4 225 111.6 126 11820.6 5.9103 122.4 0 262.8 194.4 99 108 12564 6.282 93.6 0 309.6 171 108 95.4 10645.2 5.3226 97.2 0 304.2 178.2 97.2 102.6 10103.4 5.0517 79.2 0 187.2 124.2 39.6 77.4 8265.6 4.1328 63.342 65.01 20.00 4500 hrs Estimated tons VOC/12-mo. Rolling Requested Permit Limit Requested Permit Limit Increase 1 of 2 Highway 61 South, P.O. Box 249 Cleveland, MS 38732 Tel: (800) 345-2495 Fax: (662) 843-4048 June 7, 2022 Via U.S. Mail Mr. Bryce Bird, Director Utah Division of Air Quality 195 North 1950 West P.O. Box 144820 Salt Lake City, UT 84114-4820 Subject: Proposed Production Increase for Approval Order DAQE-AN115980008-18 Quality Steel Corporation, 5520 W. Old Bingham Highway, West Jordan, UT Dear Mr. Bird: Pursuant to Utah Administrative Code (UAC) Rule R307-415, Permits, this letter is to request an increase in our volatile organic compound (VOC) permit limit increase for our Quality Steel Corporation (QSC) propane tank manufacturing facility in West Jordan, UT. Below is a written description of the project, along with the requested changes to the above-referenced approval order for this facility. 1)QSC needs to increase production of propane tanks at the West Jordan facility due to near-term contracts. QSC proposes to add an additional shift of operation, so as to increase operating hours from 2,500 pear year to 4,500 per year. We expect this will increase actual emissions from approximately 35 tpy to 65 tpy, on a rolling 12- month basis. The above-referenced approval order currently has an annual VOC limitation of 45.01 tons per rolling 12-month period (or annually). Hence, QSC requests the restricted permitted VOC limit be increased to 65.01 tons per rolling 12-month period. 2)QSC proposes no physical changes to emission units or pollution control equipment at the facility. 3)This change has no impact on the potential-to-emit (PTE) of any other air pollutant, nor will additional pollutants be emitted. Form 1 Date __________________ Notice of Intent (NOI) Application Checklist Company __________________ Utah Division of Air Quality New Source Review Section Source Identification Information [R307-401-5] 1. Company name, mailing address, physical address and telephone number  2. Company contact (Name, mailing address, and telephone number) 3.Name and contact of person submitting NOI application (if different than 2) 4.Source Universal Transverse Mercator (UTM) coordinates  5. Source Standard Industrial Classification (SIC) code  6.Area designation (attainment, maintenance, or nonattainment) 7.Federal/State requirement applicability (NAAQS, NSPS, MACT, SIP, etc.) 8.Source size determination (Major, Minor, PSD) 9. Current Approval Order(s) and/or Title V Permit numbers  NOI Application Information: [R307-401]           N/A  N/A  A.Air quality analysis (air model, met data, background data, source impact analysis) N/A  1.Detailed description of the project and source process 2.Discussion of fuels, raw materials, and products consumed/produced 3.Description of equipment used in the process and operating schedule 4.Description of changes to the process, production rates, etc. 5.Site plan of source with building dimensions, stack parameters, etc. 6.Best Available Control Technology (BACT) Analysis [R307-401-8] A.BACT analysis for all new and modified equipment 7.Emissions Related Information: [R307-401-2(b)] A.Emission calculations for each new/modified unit and site-wide (Include PM10, PM2.5, NOx, SO2, CO, VOCs, HAPs, and GHGs) B.References/assumptions, SDS, for each calculation and pollutant C.All speciated HAP emissions (list in lbs/hr) 8.Emissions Impact Analysis – Approved Modeling Protocol [R307-410] A.Composition and physical characteristics of effluent (emission rates, temperature, volume, pollutant types and concentrations) 9.Nonattainment/Maintenance Areas – Major NSR/Minor (offsetting only) [R307-403] A.NAAQS demonstration, Lowest Achievable Emission Rate, Offset requirements B.Alternative site analysis, Major source ownership compliance certification 10.Major Sources in Attainment or Unclassified Areas (PSD) [R307-405, R307-406] B.Visibility impact analysis, Class I area impact 11.Signature on Application N/A  Note: The Division of Air Quality will not accept documents containing confidential information or data. Documents containing confidential information will be returned to the Source submitting the application. Form 2 Date 61112022 Company Information/Notice of Intent (NOi) Utah Division of Air Quality New Source Review Section AIR OUAL!TY Application for: lv'ltnitial Approval Order Iv'\ Approval Order Modification General Owner and Source Information 1.Company name and mailing address:2.Company** contact for environmental matters:Quality Steel Corporation Charles D. Smiley P.O. Box 249 Phone no.: ((801) 280-1133 2914 U.S. Highway 61, Clm Email: charles.smilet@Qro12anetar 3. 5. 7. 8. Phone No.: «801)) 280-1133 Fax No.: ( )•• Company contact only; consultant or independent contractor contact information can be provided in a cover letter Source name and physical address (if different from 4.Source Property Universal Transverse Mercatorabove): . . Quality Steel Corporation -I 5520 W. Old Bingham Hwy West Jordan, UT 84084 Phone no.: ( Fax no.: ( ) The Source is located in: Salt Lake If request for modification, AO# to be modified: Brief (50 words or less) description of process. County coordinates (UTM), including System and Datum: UTM: 12 X: 413,558 E Y: 4,491,920 N 6.Standard Industrial Classification Code (SIC)�A.Ll1 DAQE #AN115980008-18 DATED:11/19/2018 QSC makes large propane tanks. QSC conducts cutting, welding, tank priming, and prime and top coating operations. This NOi pertains to a planned increase of operations from 2,500 hrs/yr to 4,500 hrs/yr, and a resulting increase in VOC emissions from the current permit limit of 45.01 tons/yr to a requested limit of 65.01 tons/yr. Electronic NOi 9.A complete and accurate electronic NOi submitted to DAQ Permitting Mangers Jon Black (jlblack@utah.gov) or AlanHumpherys (ahumpherys@utah.gov) can expedite review process. Please mark application type. Hard Copy Submittal D Electronic Copy Submittal D Bothlv'I Authorization/Signature I hereby certify that the information and data sub · ed in and with this application is completely true, accurate and complete, based on reaso-"7,ui77 me and to the best of my knowledge and belief. Signatur� Title: Director of Health, Safety & � ,- ,_ c----7 Telephone Number: Charles D. Smiley ((801) 280-1133 Email: Name (Type or print) charles.smiley@propanetar 1 of 1 Date: 6/7/2022 Page 1 of 1 Form 3 Company____________________ Process Information Site________________________ Utah Division of Air Quality New Source Review Section Process Information - For New Permit ONLY 1.Name of process:2.End product of this process: 3.Process Description*: Operating Data 4.Maximum operating schedule: __________ hrs/day __________days/week __________weeks/year 5.Percent annual production by quarter: Winter ________ Spring _______ Summer ________ Fall _______ 6.Maximum Hourly production (indicate units.): _____________ 7.Maximum annual production (indicate units): ________________ 8.Type of operation: Continuous Batch Intermittent 9.If batch, indicate minutes per cycle ________ Minutes between cycles ________ 10. Materials and quantities used in process.* Material Maximum Annual Quantity (indicate units) 11.Process-Emitting Units with pollution control equipment* Emitting Unit(s) Capacity(s) Manufacture Date(s) *If additional space is required, please create a spreadsheet or Word processing document and attach to form. Page 1 of 1 Form 4 Company____________________________ Project Information Site ______________________________ Utah Division of Air Quality New Source Review Section Process Data - For Modification/Amendment ONLY 1. Permit Number_______________________________ If submitting a new permit, then use Form 3 Requested Changes 2. Name of process to be modified/added: _______________________________ End product of this process: _______________________________ 3. Permit Change Type: New Increase* Equipment Process Condition Change ____________________ Other ______________________________ Other ______________________________ Other ______________________________ 4. Does new emission unit affect existing permitted process limits? Yes No 5. Condition(s) Changing: 6. Description of Permit/Process Change** 7. New or modified materials and quantities used in process. ** Material Quantity Annually 8. New or modified process emitting units ** Emitting Unit(s) Capacity(s) Manufacture Date(s) *If the permit being modified does not include CO2e or PM2.5, the emissions need to be calculated and submitted to DAQ, which may result in an emissions increase and a public comment period. **If additional space is required, please generate a document to accommodate and attach to form. Page 1 of 1 Company___________________________ Site _____________________________ Form 5 Emissions Information Criteria/GHGs/ HAP’s Utah Division of Air Quality New Source Review Section Potential to Emit* Criteria Pollutants & GHGs Criteria Pollutants Permitted Emissions (tons/yr) Emissions Increases (tons/yr) Proposed Emissions (tons/yr) PM10 Total PM10 Fugitive PM2.5 NOx SO2 CO VOC VOC Fugitive NH3 Greenhouse Gases CO2e CO2e CO2e CO2 CH4 N2O HFCs PFCs SF6 Total CO2e *Potential to emit to include pollution control equipment as defined by R307-401-2. Hazardous Air Pollutants** (**Defined in Section 112(b) of the Clean Air Act ) Hazardous Air Pollutant*** Permitted Emissions (tons/yr) Emission Increase (tons/yr) Proposed Emission (tons/yr) Emission Increase (lbs/hr) Total HAP *** Use additional sheets for pollutants if needed