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HomeMy WebLinkAboutDAQ-2024-0051721 DAQC-177-24 Site ID 11974 (B4) MEMORANDUM TO: STACK TEST FILE – BOUNTIFUL CITY CORPORATION – Landfill THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Robert Sirrine, Environmental Scientist DATE: February 26, 2024 SUBJECT: Location: 1350 West Pages Lane West Bountiful, Davis County, Utah Contact: Bountiful, Todd G. Christensen 801-298-6125 Tester: Hansen, Allen & Luce, Inc. Kate Herbert, 801-566-5599 Source: Landfill Tier II testing FRS ID#: UT0000004901100113 Permit# Title V operating permit 1100113004 dated February 27, 2019 Action Code: Tr Subject: Review of Tier II NMOC test report and annual NMOC Emissions Estimate report dated January 29, 2024, and February 13, 2024. On January 30, 2024, and February 13, 2024, the Utah Division of Air Quality (DAQ) received a Tier II test report and 5-year NMOC amended Emissions Estimate for landfill gas emissions testing conducted at the Bountiful City Landfill located in West Bountiful, Davis County, Utah. Testing was performed on November 30 through December 1, 2023, to determine compliance with Title V operating permit condition II.B.1.a, II.B.1.a.1(c), 40 CFR 60 Subpart WWW, Sections 60.750-60.759, and 40CFR Part 62, Subpart OOO for NMOC emissions. Test samples were collected from 32 sites 5-15 feet below the landfill cover using a hydraulic, direct push drilling platform. Samples were extracted from each of the 32 sampling probes and composited into eight Summa canisters. The sites were in landfill areas that have contained waste for two years or longer. Bountiful City Landfill is an active Class I MSW landfill. The landfill emissions testing report and annual NMOC emissions estimate appear to use the specified formulas and testing methods as outlined in the Tier II testing requirements in the above regulations. The DAQ test report evaluation is as follows: The concentrations of nitrogen and oxygen in the gas stream appear to be acceptable. RM 25C was used to determine NMOC emissions. Annual emissions were currently reported to be 4.704 Mg for the calendar year 2023. Calculations used EPA LandGEM version 3.02, the test result for NMOC concentration of 98 ppmv as Hexane and an estimated waste acceptance rate of 100,000 Mg/year for the next five years (2023-2027) with the following tabulated results. Source Test Date RM/Pollutant Test Result/Emissions Factor Limit Landfill 11/27-12/1/23 25C/NMOC 590 ppmv as Carbon N/A 98 ppmv as Hexane 2 Pollutant 5-Year Estimated Emissions Year Trigger Value NMOC 4.704 Mg/year 2023 34/50 Mg/year* NMOC 4.776 Mg/year 2024 34/50 Mg/year* NMOC 4.918 Mg/year 2025 34/50 Mg/year* NMOC 5.058 Mg/year 2026 34/50 Mg/year* NMOC 5.194 Mg/year 2027 34/50 Mg/year* All samples had either O2 <5% and/or N2 <20% or an N2/O2 ratio >3.71 for landfills receiving < 20 inches of annual precipitation. *Subpart OOO 3-year and Subpart WWW 5-year limits that activate installation of a control device DEVIATIONS: No deviations were noted. CONCLUSION: The estimated NMOC emissions are projected to be below 50 Mg/year (Subpart WWW's threshold) and below 34 Mg/year (Subpart OOO's threshold) for the years 2023 through 2027. Actual waste acceptance over the next five years is not expected to exceed 100,000 Mg/year, as stated in their report. Based on the results, Bountiful City Landfill plans to repeat the Tier II testing in calendar year 2028, and another five-year estimate of NMOC emissions report will be generated. The NMOC emissions factor appears to be acceptable. Testing appears to have been in compliance with the applicable test methods and QC requirements at the time of testing. Projected emissions are less than the 34/50 Mg/year triggers. RECOMMENDATION: The test result for NMOC of 98 ppmv as Hexane appears to be acceptable. HPV: No. ATTACHMENTS: Bountiful City Landfill Tier II test report dated January 29, 2024 Bountiful City Landfill revised NMOC rate report and 5-year estimate KENDALYN HARRIS MAYOR CITY COUNCIL JESSE BELL KATE BRADSHAW RICHARD HIGGINSON MATT MURRI CECILEE PRICE-HUISH CITY MANAGER GARY R. HILL Bou,lyIpur January 29,2024 Bryce Bird, Director Utah Division of Air Quality 195 North 1950 West salt Lake city, UT 84116 BOUNTIFUL UTAH DEPARTMENT OF EIWIROT{MENTAL OI.iAUTV JAN 3 0 2424 DIVISION OF AIR QUALTTY l-lor.rXIverEt SUBJECT:2023 TIER II TEST REPORT BOUNTIFUL SANITARY LAN DFI LL Dear Mr. Bird: According to the Utah Administrative Code and Bountiful City's Title V Operating Permit the city has chosen determine the site-specific non-methane organic carbon (NMOC) emission rate using the Tier ll process. The mass NMOC emission rate has been determined to be substantially less than 50 Mg per year and much less than the pending threshold of 34 Mg per year, therefore the site-specific NMOC emission rate is being re-tested every five years. The city contracted with Hansen Allen & Luce Engineers to prepare a test protocol and perform the sampling and testing. The Sampling Workplan for Tier ll Landfill Gas Testing was submitted to the Division of Air Quality. The workplan was reviewed and found acceptable by the Division as explained in a letter dated November L6,2023. The sampling was performed at the facility November 30 - December 1, 2023 according to EPA Methods 25C and 3C. During the sampling, the facility was operating under normal operating conditions and in accordance with requirements of the city's Title V Operating Permit. The site-specific NMOC concentration found through this Tier ll sampling and testing event is 98 ppmv as hexane. This value for NMOC concentration will be used for estimating emissions from the facility. A complete report of the Tier ll testing results is attached. A certification by a responsible official is also included. Todd G, Christensen, P. E. Bountiful City Engineering Department 795 South Main St. . Bountiful, Utah 84010 . (801) 298-6 125 . toddc@bountiful.gov January 29,2024 Page 2 of 2 lf you have any questions, or if I can be of additional assistance, please feel free to contact me. Sincerely, BOUNTIFUL CIW ENGINEERING DEPT. -Zz"r (/J"i,*-o-( Todd Christensen, P.E. Assistant City Engineer attachment as stated CERTIF!CAT!ON In accordance with Operating Permit Provision I.K. and UAC R307-415-5d, I hereby certifu that Tier 2 testing was conducted while processes at the facility were representative of normal operations and the facility was operating according to requirements of the facility's Title V Operating Permit. I also certift that the information and data submitted in and with this Tier 2 Test Report are true, accurate and complete, based on information and belief formed after reasonable inquiry. signature: fu t \t/h Title: City Manager, City of Bountiful Name: Gary Hill Telephone Number: ( 801 ) 298-6L42 Date:tlzt/ro"7 IITAH DEPARTMENT OF etlVtnONMeNTAL OUAUTY J A il il ii 'ti'i.\ BOUNTIFUL CIW BOUNTI FUL SAN ITARY LAN DFI LL TIER II LANDFILL GAS TESTING TEST REPORT December 2023 BOUNTIFUL CITY BOUNTIFUL $ANITARY LANDFILL TIER II LANDFILL GAS TESTING TEST REPORT (HAL Project No.: 374.03.100) Kate Herbert Projoct Manager Andrew Alvaro Environmenhl Services Director HgnsEn f,u-En E,,LUGE,," Et.GII'EER6 December 2023 TABLE OF CONTENTS APPENDICES APPENDIX A TEST PROTOCOL APPENDIX B FIELD DATA APPENDIX C LABORATORY ANALYTICAL DATA Bountiful Sanitary Landfill Tier llTest Report Table 1 Table 2 Table 3 Figure 1 LIST OF TABLES Vacuum Measurements in lnches of Mercury .............. 3-1 Nitrogen and Oxygen Contents in Percent Volume ......3-2 NMOG Content in ppmv..... .,....3-2 LISTOF FIGURES Tier ll Landfill Gas Sampling Locations................ After F-1 Bountiful Sanitary Landfi ll Tier ll Test Report CHAPTER 1 . INTRODUCTION !NTRODUCTION Bountiful City selected Hansen, Allen, & Luce, lnc. (HAL) to conduct the Tier ll landfill gas testing services for the Bountiful Sanitary Landfill. Under the New Source Performance Standards (NSPS) federal regulations (40 CFR Part 60, Subpart W1/VW), the Bountiful Sanitary Landfill is currently required to test and estimate the non-methane organic compound (NMOC) rate every five years. The results of this Tier ll landfill gas test will be used by Bountiful City Engineering to calculate the annual NMOC emissions rate to determine if the threshold emission rate for installing a landfill gas collection and control system is triggered. HAL completed the Tier ll landfill gas testing on December 1,2023 and received preliminary analytical results on December 22, 2023. Chapter 2 contains descriptions of the field activities and Chapter 3 contains analytical and quality control results for this testing event. LANDFILL DESCRIPTION The Bountiful Sanitary Landfill is a Class I landfill operating under a Title V Operating Permit (#1100113004 dated February 27,2019) located at 1300 West Page Lane in West Bountiful, Utah. The Landfill has been in operation for 37 years, having first accepted waste in 1987 and becoming permitted in 2000. The historic and active landfill area is about 100 acres. About 40 acres (16 hectares) of the landfill contains waste of age greater than two years. About 59 acres of the historic landfill contains primarily ash from historic open burning of waste, which is mostly located in the South Cell. This material has been tested and shown to produce no methane, so NMOC rate testing is not appropriate in this portion of the landfill (40 CFR 60.754(aX3)). The Bountiful Sanitary Landfill and the portions which are not methane-producing are shown in Figure 1. Bountiful Sanitary Landfill 1-1 Tier ll Test Report CHAPTER 2 - FIELD ACTIVITIES SAMPLING LOCATIONS 32 locations within the area of the landfill containing waste for 2 or more years were sampled for the Tier ll Testing. Sample locations were laid out in a grid pattern over a current contour map of the landfill. Actual collection points were occasionally adjusted by field representatives to compensate for poor access, low quality gas, or safety concerns, as necessary. These locations are shown in Figure 1. SAMPLING PROCEDURES Samples were collected according to EPA methods 25C and 3C. HAL utilized a hydraulic, direct- push drilling platform to place landfill gas sampling probes to depths of 5-15 feet below the existing ground level. The probes were sealed against ambient air intrusion into the sampling space. The landfill gas samples were collected through a post-run tubing system. A hollow steel drive rod with a sampli4g head was advanced to the desired depth by direct-push methods, the expendable drive point was ejected, and the probe was retracted approximately six to twelve inches to create an airtight headspace . ATe-inch polyethylene tube was inserted through the hollow steel drive rod and connected to the sampling head with an airtight threaded fitting. The pre-screening was performed by using a Landtec GEM5000 portable landfill gas analyzer. The landfill gas analyzer was be connected to the %-inch polyethylene tubing via a stainless-steel flow control manifold having a pressure gauge, fine adjustment needle valve, rotameter, and three'way purge/sample valve. The landfill gas analyzer drew a minimum of two sampling tubing volumes prior to screening and sampling. lf the screened gas contents were below 20 percent nitrogen or below 5 percent oxygen, then a landfill gas sample could be collected. Where these field quality controlcriteria were not met, the probe was removed and reinstalled in a new location before re-screening. All collected samples collected in the field met the pre-screening parameter requirements listed in methods 25C and 3C. After field quality control criteria were met, the probe was attached to an evacuated Summa@ canister and sampling train. The sampling train was purged with helium prior to sample collection as a precaution against cross-canister contamination. The vacuum measurement of the Summa@ canister was recorded. A measured volume of soil gas was drawn into the canister at a rate of approximately 0.5 liters per minute or less. Flow into the canister was regulated with a needle valve and the flow rate was monitored using a calibrated rotameter. Atthe completion of sampling, the vacuum measurement was recorded again. Sample gas from four discrete sampling locations was composited into a single Summa@ canister such that 32 discrete sample locations were composited into 8 separate Summa@ canisters. Before shipping, the final vacuum of the Summa@ canisters were recorded. The samples were shipped to Air Technology Laboratories, lnc. (ATL) located in City of lndustry, CA under chain of custody documentation. Bountiful Sanitary Landfill 2-1 Tier ll Test Report CHAPTER 3 - ANALYTICAL RESULTS ANALYTICAL PROCEDURES HAL measured and recorded the vacuum readings of the Summa@ canisters upon receipt. The vacuum results are shown in Table 1. No Summa canister was found to lose more than 3 inches of mercury from the initial laboratory labeled pressure. Based on the elevation difference between the lab location and sample location, these results assure that no atmospheric intrusion to any of the received Summa@ canisters occurred during transit. The laboratory pressure measurements were not available at the time of report production. HAL assumes that there were no issues noted by the laboratory. lf additional information becomes available that changes this assumption, the data will be provided under separate cover. Table 1 acuum Measurements rn lnc Sample ID Canister # !nitia! Pressure at 4,500 feet Final Pressure at 4,500 feet Final Pressure at 150 feet BSL-1 1343 -18 -1 -5.2 BSL-2 1451 18 -1 -5.2 BSL-3 1 396 -18 -1 -5.2 BSL-4 5474 -18 -1 -5.2 BSL-5 1286 -18 -1 -5.2 BSL-6 5470 -18 -1 -5.2 BSL-7 1450 -18 -1 -5.2 BSL-8 3743 -18 -1 -5.2 Measurements in lnches of Merc Each Summa@ canister was analyzed by ATL by EPA Methods 25C and 3C for NMOC, nitrogen, and oxygen contents in triplicate. These methods require the nitrogen content to be less than 20 percent, or alternatively the oxygen content to be less than 5 percent. The quality control results are shown in Table 2. The average of the triplicate analytical runs are shown. All Summa@ canisters except BSL-2 were found to meet the quality control criteria of <20o/o nitrogen or <5o/o oxygen. The sample locations comprising BSL-2 often suffered from refusaldue to gas rejection. However, this sample met the quality control criteria of a nitrogen to oxygen ratio of greater than 3.71 for landfills with 3-year average rainfalls equal to or less than 20 inches. The nearest station with >90% available precipitation data, BOUNTIFUL 0.8 SE, UT US, had a 3-year (2020-2022) average rainfall of 18.4 inches. V Bountiful Sanitary Landfill 3-1 Tier ll Test Report Table 2 and Ox Gontents an Percent volume Sample lD Canister #Sites Nitrogen Oxygen BSL.1 1343 L-20, L-21, L-22, L-23 <3.0 <1.5 BSL-2 1451 L-24, L-26, L-28, L-32 43 5.7 BSL-3 1396 L-27,L-29, L-30, L-31 23 <1.8 BSL-4 5474 L-17,L-18, L-19, L-25 5.7 <1.8 BSL-5 1286 L-12, L-14, L-15, L-16 7.8 <1.7 BSL-6 5470 L-9, L-10, L-1 1, L-13 <3.2 <1.6 BSL-7 1450 L-5, L-6, L-7, L-8 <3.2 <1.6 BSL-8 3743 L-1,L-2,L-3,L-4 3.5 <1.5 The NMOC contents are reported in Table 3. The average of the triplicate analytical runs are shown. The average NMOC concentration is 98 parts per million (volume) as hexane. Table 3 NMOC Content in CONCLUSION All collected samples passed quality control criteria of <20o/o nitrogen, <5% oxygen, or a nitrogen to oxygen ratio of > 3.71for landfills receiving <20 inches of annual precipitation over a 3-year average. The average NMOC laboratory analytical result of landfill gas at Bountiful Sanitary Landfill is 98 ppmv as hexane. This NMOC value may be used by Bountiful City for estimation of landfill emissions for the next five years. Sample lD Canister #Sites Cxuoc OS Carbon Cxmoc ?s Hexane BSL-1 1343 L-20, L-21, L-22, L-23 630 105 BSL-2 1451 l-24, L-26, L-28, L-32 360 60 BSL-3 1 396 t-27.L-29, L-30, L-31 560 93 BSL-4 5474 L-17,L-18, L-19, L-25 700 117 BSL-5 1286 t-12, L-14, L-15, L-16 680 113 BSL-6 5470 L-9, L-10, L-1 1, L-13 650 108 BSL-7 1450 L-5, L-6, L-7,L-8 570 95 BSL-8 3743 L-1.t-2. L-3, L-4 570 95 Average:590 98 Bountiful Sanitary Landfill 3-2 Tier ll Test Report REFERENCES Geoprob@ Systems. "Soil Vapor lmplants and Post Run Tubing" https://geoprobe.com/sites/defaulUfiles/pdfs/Geoprobeo/oC2%AE%20Soilo/o29Yaporo/o20l mplants%20and%20Post%20Run%2OTubingo/o20-o/o20Direct%20Push. pdf Environmental Protection Agency. (2023). Method 25C-Determination of Nonmethane Organic Compounds (NMOC) in Landfill Gases. Retrieved November 7, 2023 from https.//www.epa.gov/sites/defaulUfiles/2017-08/documents/method_25c.pdf. Environmental Protection Agency. (2023). Method 3C-Determination of Carbon Dioxide, Methane, Nitrogen, and Oxygen from Stationary Sources. Retrieved November 7,2023 from https://www.epa.gov/sites/defaulUfiles/2017-08/documents/method_3c.pdf. Bountiful Sanitary Landfill F-1 Tier ll Test Report FIGURES Bountiful Sanitary Landfi ll F-1 Tier ll Test Report EZ O Z | q Z I Z L '- A I E Q APPENDlX A Test Protocol BOUNTIFUL CITY TIER II LANDFILL GAS TESTING TEST PROTOGOL (FIAL Project No.: 374.G.f 00) November 2023 BOUNIIFUL CITY BOUNTIFUL $ANITARY LANDFILL TIER II LANDFILL GAS TESTING TEST PROTOCOL (HAL Project No.: 374.03.100) Kate Herbert Project Manager Andrew Alvaro Environmental Services Director ENGII{EENS November 2023 TABLE OF CONTENTS LIST OF FIGURES Figure 1 -Tier ll LandfillGas Sampling Locations APPENDICES Appendix A - Soil Gas Sampling Tools - PostRun Tubing System Appendix B - EPA Reference Method 25c Appendix C - EPA Reference Method 3c Bountiful Sanitary Landfill Tier ll Testing Protocol CHAPTER 1 - INTRODUCTION INTRODUCTION Bountiful City has selected Hansen, Allen, & Luce, lnc. (HAL) to conduct the Tier ll landfill gas testing services for the Bountiful Sanitary Landfill. Under the New Source Performance Standards (NSPS) federal regulations (40 CFR Part 60, Subpart \A M y'), the Bountiful Sanitary Landfill is currently required to test and estimate the non-methane organic compound (NMOC) rate every five years. The results of this Tier ll landfill gas test will be used to calculate the annual NMOC emissions rate to determine if the threshold emission rate for installing a landfill gas collection and control system is triggered. LANDFILL DESCRIPTION The Bountiful Sanitary Landfill is a Class I landfill operating under a Title V Operating Permit (#1100113004 dated February 27,2019) located at 1300 West Page Lane in West Bountiful, Utah. The Landfill has been in operation for 37 years, having first accepted waste in 1987 and becoming permitted in 2000. The historic and active landfill area is about 100 acres. About 42 acres of the landfill contains waste of age greater than two years. About 59 acres of the historic landfill contains primarily ash from historic open burning of waste, which is mostly located in the South Cell. This material has been tested and shown to produce no methane, so NMOC rate testing is not appropriate in this portion of the landfill (40 CFR 60.754(aX3)). The Bountiful Sanitary Landfill and the portions which are not methane-producing are shown in Figure 1. TESTING LOCATION Bountiful Sanitary Landfill 1300 West Page Lane West Bountiful, Utah 84087 PROPOSED TEST DATES HAL anticipates that testing will be performed on the week of November 27th, 2023, and will require two 1O-hour workdays. CONTACTS Facility Representative Todd G. Christensen, P.E., Assistant City Engineer BountifulCity 795 South Main Street Bountiful, UT 84010 801-298-6125 toddc@bountiful.gov Bountiful Sanitary Landfi ll 1-1 Tier ll Testing Protocol CHAPTER 1 - INTRODUCTION . CONTINUED State Representative Harold Burge, Major Source Compliance Section Manager Division of Air Quality, Utah Department of Environmental Quality 150 North 1950 West Salt Lake City, Utah 84114 385-306-6509 hburge@utah.gov HAL (Testing) Representative Kate Herbert, Project Manager Hansen, Allen, and Luce, lnc. 859 West South Jordan Parkway Suite 200 South Jordan, Utah 84095 801-566-5599 kate@halengineers. com Analytical Laboratory Air Technology Laboratories, lnc. 18501 E Gale Ave, Suite 130 City of lndustry, CA 917482655 626-964-4032 Bountiful Sanitary Landfill 1-2 Tier ll Testing Protocol CHAPTER 2 - TESTING PROTOGOL GENERAL SAMPLING PROCEDURES NARRATIVE HAL will utilize a hydraulic, direct-push drilling platform to place landfill gas sampling probes to depths of 10-20 feet below the existing ground level. The probes will be sealed against ambient air intrusion into the sampling space. Each soil gas probe will be purged of two sampling tubing volumes and screened using a portable landfill gas analyzer. Specifically, gas from each probe location will be screened for methane, carbon dioxide, oxygen, and nitrogen content. The quality control criteria of EPA Method 25Cl3C requires oxygen content in gas samples analyzed by the laboratory to be less than 5 percent or nitrogen to be less than 20 percent. These criteria are used by the laboratory to verify that ambient air was not drawn into the landfill gas sample and that gas was sampled from an appropriate location. HAL will apply these same criteria in the field to maximize the potential for laboratory quality control requirements to be met. lf these field quality control criteria are not met, then the probe will be removed and reinstalled in a new location where a viable sample can be collected. After purging and pre-screening the probe, the probe will be attached to an evacuated Summa@ canister and sampling train. The sampling train will be purged with helium prior to sample collection as a precaution against cross-canister contamination. A measured volume of soil gas will then be drawn into the canister at a rate of approximately 0.5 liters per minute or less. Flow into the canister will be regulated with a needle valve and the flow rate will be monitored using a calibrated rotameter. Sample gas from four discrete sampling locations will be composited into one Summa@ canister and submitted as one composite sample to the Laboratory, i.e. 32 discrete sample locations will be composited into 8 separate Summa@ canisters. The last two sampling locations will be composited into one Summa@ canister for a total of 34 geoprobe locations composited into 9 Summa@ cannisters. After samples have been collected the probe will be removed, and the hole will be backfilled with bentonite chips. SAMPLING LOCATIONS Subpart requires two sample locations per hectare (up to 50 total sample locations) and that sample locations must be located where waste is at least two years old. Based on the information provided by Bountiful City Engineering, the landfill currently has approximately 42 acres (17 hectares) of area with waste of age greater than two years. Therefore, 34 locations within this area of the landfill will be sampled for the Tier ll Testing. According to Bountiful City Engineering, approximately 2.8 hectares in this area is covered with stockpiled soil. ln the area stockpiled with soil, sample probes will be installed to depths up to 20 feet below landfill surface cover. Sample probes in the remaining sampling area (14.2 hectares) will be installed to depths up to 10 feet below landfill cover surface. Sample locations will be laid out in a grid pattern over a current contour map of the landfill and will be marked in the field using survey lathe and flagging tape. Actual collection points may be adjusted by field representatives to compensate for poor access, low quality gas, or safety concerns, as necessary. Bountiful Sanitary Landfill 2-1 Tier ll Testing Protocol METHOD 25G EPA Method 25C provides the methods for use in sample collection and analysis of landfill gas. The landfill gas samples will be collected through a post-run tubing system, as shown in the Appendix A attachment. A hollow steeldrive rod with a sampling head is advanced to the desired depth by direct-push methods, the expendable drive point is ejected, and the probe is pulled up approximately six to twelve inches to create an airtight headspace. ATo-inch polyethylene tube is inserted through the hollow steel drive rod and connected to the sampling head with an airtight threaded fitting. Gas can then be sampled from the tubing and pre-screened to ensure minimal intrusion of ambient air. The pre-screening will be performed by using a Landtec GEM5000 portable landfill gas analyzer. The landfill gas analyzer will be connected to the la-inch polyethylene tubing via a stainless-steel flow control manifold having a pressure gauge, fine adjustment needle valve, rotameter, and three-way purge/sample valve. The landfill gas analyzer will be on the purge side of the manifold to draw a minimum of two sampling tubing volumes priorto screening and sampling. The screened gas contents must be below 20 percent; however, if nitrogen below 20 percent cannot be obtained a sample may still be collected if oxygen content of less than 5 percent is observed under the alternative QC requirement of EPA Method 25C. After purging and pre-screening the probe, the probe will be attached to an evacuated Summa@ canister and sampling train. The sampling train will be purged with helium prior to sample collection as a precaution against cross-canister contamination. A measured volume of soil gas will then be drawn into the canister at a rate of approximately 0.5 liters per minute or less. Flow into the canister will be regulated with a needle valve and the flow rate will be monitored using a calibrated rotameter. Summa@ canisters have a volume of six liters at sea level: however, the effective canister volume at the elevation of the Landfill is reduced to approximately five liters. In addition, the canisters will be preloaded by the laboratory with one liter of helium, which reduces the effective volume of the canister to approximately four liters. Helium is added to reduce the potential explosivity hazard of the methane containing canisters: this eliminates costly hazardous shipment procedures that would otherwise be required. Nine Summa@ cannisters will be used to composite samples from 34 sample locations. To complete the sample collection at the elevation of the Landfill (approximately 4,250 feet msl) while adjusting for the available Summa@ canister volume impacts of altitude, sample gas from 4 discrete sampling locations will be composited into one Summa@ canister and submitted as one composite sample to the Laboratory, i.e. 32 discrete sample locations will be composited into 8 separate Summa@ canisters. The last two sampling locations will be composited into one Summa@ canister for a total of 9 landfill gas samples. The leak-check protocol for the Summa@ canisters is to record the vacuum just prior and immediately after sampling at each location, and to record a final vacuum just prior to shipping the Summa@ canisters back to the laboratory. The laboratory will measure the vacuum readings upon receipt and compare the readings to the pre-shipment readings to ensure the absence of leaks. Each Summa@ canister will be analyzed by the laboratory for NMOC in triplicate. The average result will be the estimate of the average NMOC concentration (as carbon) of the landfill gas. The NMOC concentration (as carbon) will be divided by six as required in Subpart \ A AlV regulations to be reported as hexane. Bountiful Sanitary Landfill 2-2 Tier ll Testing Protocol EPA METHOD 3C EPA Method 3C is used to measure the of nitrogen and orygen in the Summa@ canister composite samples. The nitrogen must be less than 20 percent to meet EPA Method 25C requirements. lf the nitrogen is above 20 percent, EPA Method 25C allows an alternative requirement of less than five oxygen. The field screening of the landfill gas by the landfill gas analyzerwill assist in ng that acceptable landfill gas samples are collected and minimizing the risk of sample QC Bountiful Sanitary Landfi ll Tier ll Testing Protocol CHAPTER 3 - QUALITY ASSURANCE AND QUALITY CONTROL GALIBRATION The landfill gas analyzer will be calibrated every sampling day for methane and oxygen. The calibration results will be shown in the test report. SUMMA CANISTERS Summa canisters are certified clean before shipment due to their reusable nature. The laboratory documents cannister cleanliness and conducts regular blank test audits of the process. The canisters are shipped under approximately -30 inches of mercury (Hg) vacuum, which corresponds to about -25 to -26.5 inches Hg at the Bountiful Sanitary Landfill altitude. Upon receipt of the canisters and just prior to sampling, the vacuum in the cannisters will be checked and recorded to ensure the absence of leaks in transit. The cannister vacuum will be checked and recorded again after each sample collection, and just prior to shipping back to the laboratory. The laboratory will check the vacuum upon receipt and compare the readings to the pre-shipment readings to ensure the absence of leaks in transit. The Summa canisters will be shipped on the same day of sampling if possible, or the next morning. lf the Summa canisters are shipped the next morning, the vacuums will be rechecked and re-recorded prior to shipping. All data will be recorded on field data sheets with the cannister serial number and on the chain- of-custody form. FIELD DATA The following data will be recorded at each sample location: The boring number or the boring location (if it was necessary to move the boring to an unnamed position), the landfill gas screening results, the Summa canister vacuum readings just before and just after sample collection, the Summa canister serial number, and the sampling start and end times. The ambient air temperature and general weather conditions will be noted throughout each sampling day. The collected samples will be handled according to best practice general sampling and chain of custody procedures and specific laboratory instructions (if any). LABORATORY ANALYSIS The Quality Assurance and Quality Control (OA/OC) procedures of EPA Methods 25C and 3C will be observed by the laboratory for instrument operation, calibration, and calibration verification. The QfuQC data will be included in the test report. BACKUP SUMMA CANISTERS The laboratory will ship one extra Summa canister required for this Tier ll test. lf a cannister is found to have a leak during the pre-sampling vacuum check, one replacement cannister will be used. Bountiful Sanitary Landfill 3-1 Tier ll Testing Protocol REFERENCES Geoprobe@ Systems. 'Soil lmplants and Post Run Tubing' https://geoprobe.'aporo/o?0\ mplants%2Oand%20Post%20R o/o20Di eclo/o2 0 P u s h. pdf Environmental Protection Agency. (2023).25C-Determination of Nonmethane Organic Compounds (NMOC) in Gases. Retrieved November 7, 2023 from https://www.epa 7-08/docu mentVmethod_25c. pdf . Environmental Protection Agency.Method 3C-Determination of Carbon Dioxide, Stationary Sources. Retrieved November 7, 2023Methane, Nitrogen, and Oxygen from https:/lwww 7-08/docu mentdmethod_3c. pdf . Bountiful Sanitary Landfill Tier ll Testing Protocol FIGURES UTAH DEPARTMENT ENVIRONMENTAL QUALITY JAN 3 0 2024 DIVISION OF AIR QUALITY Bountiful Sanitary Landfi ll F-1 Tier ll Testing Protocol APPENDIX A Bountiful Sanitary Landfill F-2 Tier ll Testing Protocol Directpushmachineswere ntallydesignedspecifrcallyfcrsoil gassampling.OurfLrstsetoftoolsrryeremanufacturedtoextract vapor samples. Before Geoprobe'tools and equipment were available, most soi gas sampling was done by manua ly advanc ng NPT p pe into the qround surface usinq a slam bar, often fol owed by usrng a bumper-stylelackto removethe NPT pipe We then developed a simple, quick, cost-effect ve method for conduct ng soi gas sampltng - Post Bun Tub nq (PBf) Systems and Soil Vapor mp ants. The PRT method decreased labor costs, t me requ rements, and decontamrnation fluids generated for sample co lectron. PRT Systems 'ee toble on next poge Seetable on next page Seetoble on nert poge N 'ir\,i I, r!U\'\\ Seetoble on next poqe Seetoble on next poqe Seetoble on next poge 785-825-1842 Post Run Tubing (PRT) Systern allows the user to collect soil vapor samples quickly and easily at the desired sampling depth WITHOUT the time-consuming complications associated with rod leakage and contami- nation. O-ring connections enable the PRT system to deliver a vacuum-tight seal that prevents sample contamination from UP hole, and assures that the sample is taken from the desired depth at the BOTTOM of the hole. The resulting time savings translates into a higher productivity rate for you and your client. ^t".<F E 204179 -F F*,,,,., seetobteonnextposr=.P $.- seetobteonnextpose geoprobe. com Probe Rods Probe Rods 201682 60 in. 202248 ,18 in. 207261 36 in. 202715 24 in. 202714 12 in. 205222 6in. 203193 I m 25 lbs. 20 lbs. 15 lbs. 10 lbs. 5 lbs. 2.5 lbs. 16.4 lbs 213773 213769 28762 21 t758 2,l751 213752 21J761 1.5 in. 0.625 in. 60 in. 15.5 lbs. t8in. 12.41bs. 35 in. 9.1 lbs. 24in. 6.2 lbs. 1.25 in. 0.625 in 12 in. 3.1 lbs. 6 in. 1.55 lbs. 1 m 10.171bs. a a a I aI $s 1.5 in, Expendable Point Holdei PRT 1.0 in. ErDcnd.ble Steel Point 1.0 in. Expendable Steel Point PII Erpendable hint Popper 204179 213778 , 1.1in.00 213781 l,],'l;,$1,* 214207 1.25 in. Expendable Point Holder PRT 1.0 in. Ependable Steel Point 1.0 in. Expendable Steel Point PRt Expendable Point Popper 214202 213778 1.'l in.0D ,,rrsl 'lJaliii?1oo 214207 g $s Expendable Points / Holders Expendable Points / Holders PBT Adapters ! t o# od#'PRI Adapter PRTAdaptel ;d PRTAdaptet 21.4208 For3/l6in.lDTubing 21 421 1, tot ll4in.l}Iubing 214203 For 1/8 in. lDlubing ffi|063 l/4 in. 0D x 3/16 in. lD x 500 ft. 3/8 in. 0D x l/4 in. lD x5ff)ft. 1/4 in. 0D x 3/1 6 in. lDx50ft. 5/16 in. 00 x l/4 in. tDxs0ft. 1/4 in. 0D x 1/8 in. l0 x 50 ft. 3/8 in.0D x 1/4 in. lD x 10$ft. 21053 @d o-Ring (illBP AdapteB)214210 Quantity:25 -89 0-Ring (Gs Sampling (ap i.ziiii- -"'-' 2tt776 Quantity:2s o6€ 0-Rin9(l'0in'ExDendable il3782' Quantiry:2s Gas Sampling (ap.b,ri raL., (:'l) r'i {-'y LDPETubing PE Tubing Ieflon Tubing Iefonlublng Tefon Tubing llylonTubing .C D.\r-' O-Rings Tubing Accessories €"q@ 78s'82s-r842 Soil Vapor Implants geoprobe.com/vapor-implants Soil Vapor lmplants are convenient and inexpensive devices for both long-term soil gas monitoring, air sparging, and groundwater sampling. The double woven, stainless steel wire screens can be inserted down the bore hole of a probe rod and anchored at depth and are available in a variety of lengths. @ 78*825-1842 I - a a Seetoileon nutpoge Seetoileon nqtNge lntenolthrcods- seetohle on nut page i - i & i $ SeetobleMnqtNge SeetotleunutWe geoprobe.com @ Probe Rods Expendable Points / Holders 201682 60 in. 202248 48 in. 207261 16 in. 202715 24in. 202714 12 in. 205222 6in. 203193 'l m 25 lbs. ZOth. 15 lbs. l0 lbs. 5 lbs. 2.5 lbs. '16.4 lbs. I o6€ 21J755 201895 214205 ; 213782 1.5 in. 0.625 in. t t 1.25 in. Expendable Point Holder 1.5 in. Expendable Point Holder 1 in. Expendable Point Soil Gas lmplantAndrol 0-nfrU (1.0 frr. E eend.ble Polnt) 1.25 in.0D 0.625 in. lD 1.5 in.0D 0.625 in. lD lntemal threads Quantity:25 -/ ./ J,, f*) 601067 , 60lMJ 601062 fi|057 214253 | 6Lfi64 6@144 214252 213746 g iiifl *. PETubing PEIubing [DPt Tubing Tefoolublng Tefion Tubing Tefmlublng Nylon Tubing Silirone Tubing Adapter 1/2 in. 0D x 3/8 in. lD x 500 ft. I 3/8in.0Dx1/4in.lD I x500ft. l/4 in.0D x 3/16 in. lD x500ft. 1/4 in.0Dx 1/8 in. lD x 50ft. 1/4 in. 0D x 3/,l6 in. lD x 50 ft. 5ll6 in.0D x ll4 in. tD x 50fr 3/8 in.0D x l/4 in. lD x 100 ft. l/4in.0D x 3/16 in. lD x 100ft. Quantity:'10 Glass Bead 611100 tlesh Glrss Bead / Brmtonih llix Glass Bead 60- l 00 Mesh Glass Ecad / Eentonite llir 213849 250Ml 213851 | 250M1 I 600995 50 lb. Pail 211875 50 lb. Pail SoilGs lmplant ,a' SoilGaslmplant Soil Gas lmplant Soil Gas lmplant 2|3STT / SoilGasspargelmphnt 2t3Ltg 213859 Soil Gas 273861 Soil Gas,ShallowGrounduater 213865 Soil Gas .17 in. lD (4.1mm lD) .25 in. lD (6.4mm lD) .25 in. lD (6.4 mm ID) 60 1062 601063 6 in. (152 mm) o rn. I (t52mm) 6 in. (152 mm) '12 in. (305 mm) l2 in. (305 mm) Barbed 8a6ed Swagelokil SoilGas,5hallowGroundwater Anyplastirtubing .25 in. lD to .4375 in. l0 SoilGas,ShalloivGroundwater, (6.4mm lDto 1l mm lD) Sparqing 601067 601067 Tapered krew Thread Tapercd Screw Ihread G/ass SeadsTubing ffi tEPTuHns tr) 'ril I lC=L\s-' I l)i1\ , .)l 6 SorT Gas lmplants Sol/ Gas lmplants 0.25 in & 1.5 in. Probe Rods Only) @ 78s'825-r842 APPENDIX B Bountiful Sanitary Landfill F-3 Tier ll Testing Protocol Method 25C 0sl30/2023 lAhile we hove taken steps to ensure the accuracy of this Internet version of the document, it is not the ofJicial version. The most recent edits to this method were published here: httos://www.soo,sov/fdsvs/oks/FR-2016-08-30/odf/2016-19642.odf, To see a complete version including any recent edits, visit: httos://www.ecfr.eov/cei-bit/ECFR?oase=browse and search under Title 40, Protection of Environment. Mrrnoo 2SC-DnrER.rvrrNATroN oF NoNMETHANE Onclxrc Corupouxos (NMOC) rN Laxoru.l Glsps Nors: This method does not include all of the specifications (e.g., equipment and supplies) and procedures (e.g., sampling and analytical) essential to its performance. Some material is incorporated by reference from other methods in this part. Therefore, to obtain reliable results, persons using this method should also have a thorough knowledge of EPA Method 25. 1.0 Scope and Application LI Analytes. Analyte AS No. ),lonmethane organic compounds (NMOC)t{o CAS number assigned. 1.2 Applicability. This method is applicable to the sampling and measurement of NMOC as carbon in landfill gases (LFG). 1.3 Data Quality Objectives. Adherence to the requirements of this method will enhance the quality of the data obtained from air pollutant sampling methods. 2.0 Summary of Method 2.1 A sample probe that has been perforated at one end is driven or augured to a depth of 0.9 m (3 ft) below the bottom of the landfill cover. A sample of the landfill gas is extracted with an evacuated cylinder. The NMOC content of the gas is determined by injecting a portion of the gas into a gas chromatographic column to separate the NMOC from carbon monoxide (CO), carbon dioxide (COz), and methane (CH+); the NMOC are oxidized to COz, reduced to CH+, and measured by a flame ionization detector (FID). In this manner, the variable response of the FID associated with different types of organics is eliminated. j.0 Definitions [ReservedJ 4. 0 Interfe re nc e s I Re s erve d] 5.0 Safety 5.1 Since this method is complex, only experienced personnel should perform this test. LFG contains methane, therefore explosive mixtures may exist on or near the landfill. It is advisable Method 25C os/30/2023 to take appropriate safety precautions when testing landfills, such as refraining from smoking and installing explosion-proof equipment. 6.0 Equipment and Supplies 6.1 Sample Probe. Stainless steel, with the bottom third perforated. Teflon probe liners and sampling lines are also allowed. Non-perforated probes are allowed as long as they are withdrawn to create a gap equivalent to having the bottom third perforated. The sample probe must be capped at the bottom and must have a threaded cap with a sampling attachment at the top. The sample probe must be long enough to go through and extend no less than 0.9 m (3 ft) below the landfill cover. If the sample probe is to be driven into the landfill, the bottom cap should be designed to facilitate driving the probe into the landfill. 6.2 Sampling Train. 6.2.1 Rotameter with Flow ControlValve. Capable of measuring a sample flow rate of 100 +10 ml/min. The control valve must be made of stainless steel. 6.2.2 Sampling Valve. Stainless steel. 6.2.3 Pressure Gauge. U-tube mercury manometer, or equivalent, capable of measuring pressure to within I mm Hg (0.5 in HzO) in the range of 0 to I,100 mm Hg (0 to 590 in HzO). 6.2.4 Sample Tank. Stainless steel or aluminum cylinder, equipped with a stainless steel sample tank valve. 6.3 Vacuum Pump. Capable of evacuating to an absolute pressure of 10 mm Hg (5.4 in HzO). 6.4 Purging Pump. Portable, explosion proof, and suitable for sampling NMOC. 6.5 Pilot Probe Procedure. The following are needed only if the tester chooses to use the procedure described in section 8.2.1. 6.5.1 Pilot Probe. Tubing of sufficient strength to withstand being driven into the landfill by a post driver and an outside diameter of at least 6 mm (0.25 in.) smaller than the sample probe. The pilot probe shall be capped on both ends and long enough to go through the landfill cover and extend no less than 0.9 m (3 ft) into the landfill. 6.5.2 Post Driver and Compressor. Capable of driving the pilot probe and the sampling probe into the landfill. The Kitty Hawk portable post driver has been found to be acceptable. 6.6 Auger Procedure. The following are needed only if the tester chooses to use the procedure described in section 8.2.2. 6.6.1 Auger. Capable of drilling through the landfill cover and to a depth of no less than 0.9 m (3 ft) into the landfill. Method 25C 6.6.2Pea Gravel. 6.6.3 Bentonite. 6.7 NMOC Analyzer, Barometer, Thermometer, 6.33, and 6.2.10, respectively, of Method 25. 7.0 Reagents and Standards 0s130/2023 and Syringes. Same as in sections 6.3.1,6.3.2, 7.1 NMOC Analysis. Same as in Method 25, section7.2. 7.2 Calibration. Same as in Method 25, section7.4, except omit section 7.4.3. 8.0 Sample Collection, Preservation, Storage, and Transport 8.1 Sample Tank Evacuation and Leak-Check. Conduct the sample tank evacuation and leak- check either in the laboratory or the field. Connect the pressure gauge and sampling valve to the sample tank. Evacuate the sample tank to 10 mm Hg (5.a in HzO) absolute pressure or less. Close the sampling valve, and allow the tank to sit for 30 minutes. The tank is acceptable if no change more than *2 mm is noted. Include the results of the leak-check in the test report. 8.2 Sample Probe Installation. The tester may use the procedure in section 8.2.1 or 8.2.2. 8.2.1 Pilot Probe Procedure. Use the post driver to drive the pilot probe at least 0.9 m (3 ft) below the landfill cover. Altemative procedures to drive the probe into the landfill may be used subject to the approval of the Administrator's designated representative. 8.2.1.1 Remove the pilot probe and drive the sample probe into the hole left by the pilot probe. The sample probe shall extend at least 0.9 m (3 ft) below the landfill cover and shall protrude about 0.3 m (l ft) above the landfill cover. Seal around the sampling probe with bentonite and cap the sampling probe with the sampling probe cap. 8.2.2 Auger Procedure. Use an auger to drill a hole to at least 0.9 m (3 ft) below the landfill cover. Place the sample probe in the hole and backfill with pea gravel to a level 0.6 m (2 ft) from the surface. The sample probe shall protrude at least 0.3 m (1 ft) above the landfill cover. Seal the remaining area around the probe with bentonite. Allow 24 hours for the landfill gases to equilibrate inside the augured probe before sampling. 8.2.3 Driven Probes. Closed-point probes may be driven directly into the landfill in a single step. This method may not require backfilling if the probe is adequately sealed by its insertion. Unperforated probes that are inserted in this manner and withdrawn at a distance from a detachable tip to create an open space are also acceptable. 8.3 Sample Train Assembly. Just before assembling the sample train, measure the sample tank vacuum using the pressure gauge. Record the vacuum, the ambient temperature, and the Method 25C osl30l2023 barometric pressure at this time. Assemble the sampling probe purging system as shown in Figure 25C-1. 8.4 Sampling Procedure. Open the sampling valve and use the purge pump and the flow control valve to evacuate at least two sample probe volumes from the system at a flow rate of 500 ml/min or less. Close the sampling valve and replace the purge pump with the sample tank apparatus as shown in Figure 25C-2. Open the sampling valve and the sample tank valve and, using the flow control valve, sample at a flow rate of 500 ml/min or less until either a constant flow rate can no longer be maintained because of reduced sample tank vacuum or the appropriate composite volume is attained. Disconnect the sampling tank apparatus and pressurize the sample cylinder to approximately 1,060 mm Hg (567 in. HzO) absolute pressure with helium, and record the final pressure. Alternatively, the sample tank may be pressurized in the lab. 8.4.1 The following restrictions apply to compositing samples from different probe sites into a single cylinder: (1) Individual composite samples per cylinder must be of equal volume; this must be verified by recording the flow rate, sampling time, vacuum readings, or other appropriate volume measuring data, (2) individual composite samples must have a minimum volume of 1 liter unless data is provided showing smaller volumes can be accurately measured, and (3) composite samples must not be collected using the final cylinder vacuum as it diminishes to ambient pressure. 8.4.2 Use Method 3C to determine the percent Nz and Oz in each cylinder. The presence of Nz and Oz indicates either infiltration of ambient air into the landfill gas sample or an inappropriate testing site has been chosen where anaerobic decomposition has not begun. The landfill gas sample is acceptable if the concentration ofNz is less than 20 percent. Alternatively, the oxygen content of each cylinder must be less than 5 percent. Landfills with 3-year average annual rainfalls equal to or less than 20 inches annual rainfalls samples are acceptable when the N2 to 02 concentration ratio is greater than3.7l. 9.0 Quality Control 9.1 Miscellaneous Quality Control Measures. Section Oualitv control measure Effect 3.4.2 lf the 3-year average annual rainfall is greater than20 inches, verifu that landfill gas sample contains less than 20 percent Nz or 5 percent Oz. Landfills with 3- year average annual rainfalls equal to or less than 20 inches annual rainfalls samples are acceptable when the Nz to Oz concentration ratio is greater than 3.71. lnsures that ambient air was not drawn into the andfill gas sample and gas nas sampled from an rppropriate location. 10.1, 10.2 NMOC analyzer initial and daily performance checks Snsures precision of malytical results. I 0.0 Calibration and Standardization Method 25C 0s/3012023 Notp: Maintain a record of performance of each item. 10.1 Initial NMOC Analyzer Performance Test. Same as in Method 25, section 10.1, except omit the linearity checks for COz standards. 10.2 NMOC Analyzer Daily Calibration. 10.2.1NMOC Response Factors. Same as in Method 25, section 10.2.2. 10.3 Sample Tank Volume. The volume of the gas sampling tanks must be determined. Determine the tank volumes by weighing them empty and then filled with deionized water; weigh to the nearest 5 g, and record the results. Alternatively, measure the volume of water used to fill them to the nearest 5 ml. I 1.0 Analytical Procedures I 1.1 The oxidation, reduction, and measurement of NMOC's is similar to Method 25. Before putting the NMOC analyzer into routine operation, conduct an initial performance test. Start the analyzer, and perform all the necessary functions in order to put the analyzer into proper working order. Conduct the performance test according to the procedures established in section 10.1. Once the performance test has been successfully completed and the NMOC calibration response factor has been determined, proceed with sample analysis as follows: I 1.1.1 Daily Operations and Calibration Checks. Before and immediately after the analysis of each set of samples or on a daily basis (whichever occurs first), conduct a calibration test according to the procedures established in section 10.2. If the criteria of the daily calibration test cannot be met, repeat the NMOC analyzer performance test (Section l0.l) before proceeding. ll.l.2 Operating Conditions. Same as in Method 25, section ll.2.l. I l.l .3 Analysis of Sample Tank. Purge the sample loop with sample, and then inject the sample. Under the specified operating conditions, the COz in the sample will elute in approximately 100 seconds. As soon as the detector response returns to baseline following the COz peak, switch the carrier gas flow to backflush, and raise the column oven temperature to 195 'C (383 oF) as rapidly as possible. A rate of 30 "C/min (54 'F/min) has been shown to be adequate. Record the value obtained for any measured NMOC. Return the column oven temperature to 85 oC (185 "F) in preparation for the next analysis. Analyze each sample in triplicate, and report the average as Ctr. I 1.2 Audit Sample Analysis. When the method is used to analyze samples to demonstrate compliance with a source emission regulation, an audit sample, if available, must be analyzed. I2.0 Data Analysis and Calculations Norp: All equations are written using absolute pressure; absolute pressures are determined by adding the measured barometric pressure to the measured gauge or manometer pressure. Method 25C 12.1 Nomenclature osl3012023 B*: Moisture content in the sample, fraction. CNz : Nz concentration in the landfill gas sample. CmN2 : Measured Nz concentration, diluted landfill gas sample. Cmox: Measured Oxygen concentration, fraction in landfill gas. Co*: Oxygen concentration in the diluted sample gas. Ct: Calculated NMOC concentration, ppmv C equivalent. Ctm: Measured NMOC concentration, ppmv C equivalent. Pu: Barometric pressure, mm Hg. Pt : Gas sample tank pressure after sampling, but before pressurizing, mm Hg absolute. Ptr = Final gas sample tank pressure after pressurizing, mm Hg absolute. Pti = Gas sample tank pressure after evacuation, mm Hg absolute. P*: Vapor pressure of HzO (from Table 25C-l), mm Hg. r : Total number of analyzer injections of sample tank during analysis (where j : injection number, 1...r). Tt: Sample tank temperature at completion of sampling, oK. Tt: Sample tank temperature before sampling, oK. Ttr: Sample tank temperature after pressuring, oK. l2.2Water Correction. Use Table 25C-1 (Section 17.0), the LFG temperature, and barometric pressure at the sampling site to calculate Bw. Eq.25C-l 12.3 Nitrogen Concentration in the landfill gas. Use equation25C-2 to calculate the measured concentration of nitrogen in the original landfill gas.[ /ru\ I cN, = lffilr*, Eq.25c-2 LF;i-riltl 12.4 Oxygen Concentration in the landfill gas. Use equation 25C-3 to calculate the measured concentration of oxygen in the original landfill gas. I ('-u\ I co, =lffil,^r, Eq'25c-3 [\tr/-rGt] B* _x Method 25C 0s13012023 12.5 You must correct the NMOC Concentration for the concentration of nitrogen or oxygen based on which gas or gases passes the requirements in section 9.1 or based on the 3-year average annual rainfall based on the closest NOAA land-based station. 12.5.1NMOC Concentration with nitrogen correction. Use Equation25C-4 to calculate the concentration of NMOC for each sample tank when the nitrogen concentration is less than 20 percent. Ptf r rtf 1s, r "_v-W|L,j=,Ltmu)Eq.25C-4 12.5.2 NMOC Concentration with oxygen correction. Use Equation25C-5 to calculate the concentration of NMOC for each sample tank if the landfill gas oxygen is less than 5 percent and the landfill gas nitrogen concentration is greater than 20 percent, or 3-year average annual rainfall based annual rainfall ofless than 20 inches. ?t_1 sT=r c r*{ilct:ffi;L',i Eq.25C-5 I 3. 0 Method P erformance [ReservedJ I 4. 0 Pollution Prevention [ReservedJ I5.0 Waste Management [ReservedJ 16.0 References 1. Salo, Albert E., Samuel Witz, and Robert D. MacPhee. Determination of Solvent Vapor Concentrations by Total Combustion Analysis: A Comparison of Infrared with Flame Ionization Detectors. Paper No. 75-33.2. (Presented at the 68th Annual Meeting of the Air Pollution Control Association. Boston, Massachusetts. June 15-20, 1975.) 14 p. 2. Salo, Albert E., William L. Oaks, and Robert D. MacPhee. Measuring the Organic Carbon Content of Source Emissions for Air Pollution Control. Paper No. 74- 190. (Presented at the 67th Annual Meeting of the Air Pollution Control Association. Denver, Colorado. June 9-13, 1974.) 25 p. 17.0 Tables, Diagrams, Flowcharts, and Validation Data Ptf Method 25C lnlEhlntOi fr{fihtr I*nerf ffi llgun l3(-l. ga!illBt+ $!?fiD. 8EryEE W, tigrurr !!G-I. Sckltio 3q,1l,lrd lrrla. 0s13012023 Method 25C Tanln 25C-l-Morsrunp ConnrcrroN 0s13012023 femperature, )c Vapor Pressure of IfzO, mm [Is Iemperature,rc Vapor Pressure of IIzO, min [Ie 5.1 18 15.5 7.0 z0 17.5 3.0 )-2 19.8 10 ,.2 L4 /2.4 t2 10.5 L6 /5.2 t4 12.0 z8 28.3 t6 13.6 ]0 31.8 APPENDIX C Bountiful Sanitary Landfill F4 Tier ll Testing Protocol Method 3C 812/20t7 lYhile we have taken steps to ensure the accuracy of this Internet version of the document, it is not the official version. The most recent edits to this method were published here: https://www.gpo.gov/fdsys/pkg/FR-2016-08-30/pdf/2016-196a2.pdf To see a complete version including any recent edils, visit: https://www.ecfr.gou/cgi-bitt/ECFR?page=browse and search under Title 40, Protection of Environment, MBTTToo 3C-DTTnRMINATIoN oF CARBoN DIoxTon, METHANE, NTTROCBN, AND OXYGEN Fnou Sr.c,rroNaRY SoURCES 1. Applicability and Principle 1.1 Applicability. This method applies to the analysis of carbon dioxide (COz), methane (CH+), nitrogen (Nz), and oxygen (Oz) in samples from municipal solid waste landfills and other sources when specified in an applicable subpart. 1.2 Principle. A portion of the sample is injected into a gas chromatograph (GC) and the COz, CH+, Nz, and Oz concentrations are determined by using a thermal conductivity detector (TCD) and integrator. 2. Range and Sensitivity 2.1 Range. The range of this method depends upon the concentration of samples. The analytical range of TCD's is generally between approximately 10 ppmv and the upper percent range. 2.2 Sensitivity. The sensitivity limit for a compound is defined as the minimum detectable concentration of that compound, or the concentration that produces a signal-to-noise ratio of three to one. For COz, CHq, Nz, and Oz, the sensitivity limit is in the low ppmv range. 3. Interferences Since the TCD exhibits universal response and detects all gas components except the carrier, interferences may occur. Choosing the appropriate GC or shifting the retention times by changing the column flow rate may help to eliminate resolution interferences. To assure consistent detector response, helium is used to prepare calibration gases. Frequent exposure to samples or carrier gas containing oxygen may gradually destroy filaments. 4. Apparatus 4.1 Gas Chromatograph. GC having at least the following components: 4.1 .1 Separation Column. Appropriate column(s) to resolve COz, CH+, Nz, Oz, and other gas components that may be present in the sample. 4.1.2 Sample Loop. Teflon or stainless steel tubing of the appropriate diameter. Method 3C 8/2/2017 Norp: Mention of trade names or specific products does not constitute endorsement or recommendation by the U. S. Environmental Protection Agency. 4.1.3 Conditioning System. To maintain the column and sample loop at constant temperature. 4. 1.4 Thermal Conductivity Detector. 4.2 Recorder. Recorder with linear strip chart. Electronic integrator (optional) is recommended. 4.3 Teflon Tubing. Diameter and length determined by connection requirements of cylinder regulators and the GC. 4.4 Regulators. To control gas cylinder pressures and flow rates. 4.5 Adsorption Tubes. Applicable traps to remove any Oz from the carrier gas. 5. Reagents 5.1 Calibration and Linearity Gases. Standard cylinder gas mixtures for each compound of interest with at least three concentration levels spanning the range of suspected sample concentrations. The calibration gases shall be prepared in helium. 5.2 Carrier Gas. Helium, high-purity. 6. Analysis 6.1 Sample Collection. Use the sample collection procedures described in Methods 3 or 25C to collect a sample of landfill gas (LFG). 6.2 Preparation of GC. Before putting the GC analyzer into routine operation, optimize the operational conditions according to the manufacturer's specifications to provide good resolution and minimum analysis time. Establish the appropriate carrier gas flow and set the detector sample and reference cell flow rates at exactly the same levels. Adjust the column and detector temperatures to the recommended levels. Allow sufficient time for temperature stabilization. This may typically require I hour for each change in temperature. 6.3 Analyzer Linearity Check and Calibration. Perform this test before sample analysis. 6.3.1 Using the gas mixtures in section 5.1, verify the detector linearity over the range of suspected sample concentrations with at least three concentrations per compound of interest. This initial check may also serve as the initial instrument calibration. 6.3.2 You may extend the use of the analyzer calibration by performing a single-point calibration verification. Calibration verifications shall be performed by triplicate injections of a single-point standard gas. The concentration of the single-point calibration must either be at the midpoint of Method 3c 812120L7 the calibration curve or at approximately the source emission concentration measured during operation of the analyzer. 6.3.3 Triplicate injections must agree within 5 percent of their mean, and the average calibration verification point must agree within l0 percent of the initial calibration response factor. If these calibration verification criteria are not met, the initial calibration described in section 6.3.1, using at Ieast three concentrations, must be repeated before analysis of samples can continue. 6.3.4 For each instrument calibration, record the carrier and detector flow rates, detector filament and block temperatures, attenuation factor, injection time, chart speed, sample loop volume, and component concentrations. 6.3.5 Plot a linear regression of the standard concentrations versus area values to obtain the response factor of each compound. Alternatively, response factors of uncorrected component concentrations (wet basis) may be generated using instrumental integration. Nots: Peak height may be used instead of peak area throughout this method. 6.4 Sample Analysis. Purge the sample loop with sample, and allow to come to atmospheric pressure before each injection. Analyze each sample in duplicate, and calculate the average sample area (A). The results are acceptable when the peak areas for two consecutive injections agree within 5 percent of their average. If they do not agree, run additional samples until consistent area data are obtained. Determine the tank sample concentrations according to section 7.2. 7. Calculations Carry out calculations retaining at least one extra decimal figure beyond that of the acquired data. Round off results only after the final calculation. 7.1 Nomenclature. B*: Moisture content in the sample, fraction. Cuz : Measured Nz concentration (by Method 3C), fraction. CN2co'.: Measured Nz concentration corrected only for dilution, fraction. Ct: Calculated NMOC concentration, ppmv C equivalent. Ctm : Measured NMOC concentration, ppmv C equivalent. Pu: Barometric pressure, mm Hg. Pt: Gas sample tank pressure after sampling, but before pressurizing, mm Hg absolute. Ptr: Final gas sample tank pressure after pressurizing, mm Hg absolute. Pti: Gas sample tank pressure after evacuation, mm Hg absolute. Method 3C 812120L7 P*: Vapor pressure of HzO (from Table 25C-l), mm Hg. r : Total number of analyzer injections of sample tank during analysis (where j : injection number, 1...r). R: Mean calibration response factor for specific sample component, area./ppm. Tt = Sample tank temperature at completion of sampling, oK. Tr : Sample tank temperature before sampling, oK. Ttr: Sample tank temperature after pressurizing, oK. 7.2 Concentration of Sample Components. Calculate C for each compound using Equations 3C-1 and3C-2. Use the temperature and barometric pressure at the sampling site to calculate Bw. If the sample was diluted with helium using the procedures in Method 25C, use Equation 3C-3 to calculate the concentration. D D - tw tis 3C-7 3C -2A[-=-R[1-B*) D,{ e: + "r.-:.- - -E-----E-ri _ri fi(1-B*) T- r, 7.3 Measured Nz Concentration Correction. Calculate the reported Nz correction for Method 25-C using Eq. 3C-4. If oxygen is determined in place of Nz, substitute the oxygen concentration for the nitrogen concentration in the equation. Prrr& ctr,con = u!!orlc*,) Eq.rc - + f-{ 8. Bibliography 1. McNair, H.M., and E.J. Bonnelli. Basic Gas Chromatography. Consolidated Printers, Berkeley, CA. 1969. APPENDIX B Field Data H[_nsEn rflt[E];fiTil-. - $ Project lltannger: \<al'* *l' Drte: Project fl: Tier II NMOC Sampling Field Form Sample lD:Cunistcr lD: I Leak Checlt lnfo End Tirnc:Final Pressure:D.rtc: 1 lnitral prcssurc: T4-ln\ - \l'eather Condirions: C1oyo1j ",-'-'"t' t " Sg Boring Location: L'1, - l{ 6o.t1 , B1.t sotes:1 /V.o.l4L 3r'tt-L /o lo/ Boring Locationr L- Ll WArv* 1r'/J, f,1itk4- t5'- IL 55.y,s7.o l"iii"t 'i cfiP.i coryoi or'toPrcsure: I ! _ q ii tl.l \oe o\l 1 0, o to:3t -S _ rores: I e(t$ To '1r,, BoringLocation: L-U - 5 l".o 36.1 o.L I o:961 * t QA Srgn;rtur*" ffi tl/s"/zg [roject lltannger: t4 o\f+- H ' Tieltl Pcrsonn 11' CtLnr ''in'o'rt L 'Proj*t p 3?l,o3.loo "l'ier II NNTOC Sampling Field Form lianrpl,: lD: B5'to,El Finrl Prcssurc:End Timc:Datc: lfl 13 I I -J I lnitiul Prcssurc: t* d from: 1! tr/ at a 'I'cntP: i 3 Boring Location: l^U lniriat --j-- Pre*urc: I cllr% i ?rittc.g r. la'if- eaf<f, {rnK SuPPIU-XT 5'- Boring Locarion: L -Z-C, \otes: I eaS f-,l1ci-n, i*ou+J; 5' N, Drillr4 5' Boring Location: L'L$ - t,l l/?,6 I l.?6,t frj{l t3:tt \ - 560.1 '3q.0I o,x \nres: Qo$ r€rtrlri,30'Nw, to'drit Boring Location: L -9L \ores: tyCfq,r g1f tO' CIlr%iCOfhlofh Z.o)i 21,91 0.6 lLl'. o L Q.\ Signature. ffiBH 'l'icr II Nlll0c Snnrpling fiicld liorm l)nte:/ /go Projccl *z a?1, O r,l oo Project ltlanagtr: J<o$1a H ' Fi*t,t Personn rr, (Lr iliA.n l- ' Clnister llf Santplc ta: 951-- - lt;n{q I 17 ' ,Jlc; ' lnitial Pressurc: I start timu: \\"ttther ('ondirions: LtO<lJrl1 win,f fro*, A/W ,, 3 ]lcnlP: I L-3 Lo,'o I C0r7.Ott/o NrTo Sanrple Stort Tlmc:llon ,Llil.z o.6 7..0 l{:z- o fo Final l'rersure: ritl*-L f" lo' Boring Locurion: l-ge lnitial : Prerrur.,: rclll9; -lL Io.7 15:lt l;; ,-(A9 rl(t*,l lo' { Boring Location: bq iCtL% samPle End i tinar Pressurc:I lnle: l zf:t1- : *o s te [eg *vioY/\,tes: ' Jrit(<l Tn lo'* aT '?.s i[z,) r o. Boring Location: L* Z t, cfir./o 1c'o* i or"L ;o-a\C rtl N \ 0 QA Signllurr:. ffi Tier ll NfllOC Sampling Ficld Form Dntc: Projecr #: 3.7q. o3J oe Projcct Nlannger: W?*' Vl ' *'icttt Personnet: Cl"tif ?tL n I-' Canistcr tD: SI Date: i l,r,t,rl pr..rur., . i-----------i_.--.-.-_ ll lzqlzs 1 -tn.-t l'?-/ al l<-*z-7 l\'tather Condirions: d"rli rvind flgna_Sil at 7 Tcmp: Boring Location: L^L, Initial Proxurt:cth%CO:%ofA Nr%Sample Start Timc:Florv Rutr Sanplc flnd Timc:['inel Prcssurc: -lL 6t.l 76.9 o.q o.a b'3* )5n" I U.Z!:--!-3 \otes:lo's. ta' trikJ- Boring Locetion: L-11 Initial Pre*sure:Clft'y'o COflo 0f/o NtTo Sample Starl Time:lilow Rnte Snmplc f nd 'l'ime:Final Pressurr: 'lL ',5/.1 41, b f.o oa X:5o 9ao 8:r-^8 \ote!: 1 Orfi k) fo V' BoringLocation: L- t{ lnitial Prersure:Cllils COfh OtY.NlTo Samptc Start Tinre:lilou llate Samplr End Time:finll Prcssure: -g fc.c tf?^tl t.0 p.O oqio{{o o1 :to I -I{ '**," Dri[!* Tu lo' BoringLocation: L- t7 _ lnitial , Cfiry.rrelSure:COfA Ozoh ititTo Sonple Slnrt Timu t"low Rnre I srlPr rn0 | tinat t,rcssrrrc: -'Ll 57.9 'll,lie,1 o.0 1',25 sool q,,zli * \ \otes: A Sisnnture. tri/r tm Yc /O HANSEN EflutE* aXOtr!(r! Tier II NlvlOC SrnrPling Field Form S*pr.-ro, B,U- fClnistcr lD: t Final Pr*surc: -f- Entj Timc: -18 in Hq- 1 t7: oe Starl timc:Dutc: l tnitiol prsssurc:1"" - --t"".".." lltzq / zti - ta ia t)srr: tl-l ol l'?-7 Project Manrger: Kat< l'/. Field Personncl:7a\. o1. lo o \\'erthcr Conditions: Sstowl lYind from: $ Ul ot 3 Tcntp: 3 Boring Location: L-tt, Drilt t ro lo' Boring Location: L-tl q?-.61 o.7 lolj f)1itr-t lo' - Initirl , cllroznYressure: lo: lj Boring Location: L-lt _ luitirl , Cnr,/o|,re$ure:Final Pressure: -1 ilt { lu o i5.6 Drito/ ?- /o' Boring Location: L- ltl ^lnitial crtr?.: co:.to1 ofhrrerture: : - , ,//.zl l|1.?j o,z I o,o l, lo'.5fi ['r'rr Rnrr I samPle lind I I rme: {eo .ut I ll: o o rores: , Dfiilzl lo, , Z, Q.{ Sisnoture: H[n$En flu"En ELUCE* Ticr ll NMOC Snnrpling fiield Form $umme Cenlrter Canisrcr to: $ll o Sanrplc ta: BIL - L Leak Check Info Datc lnilial Prcssurc:Start timc:Final Pressurr:End Timc: filL1/L3 'lx r'n il ay lb i€z -|fl in H*lb,.5q Drrr: tZ /ol I tZ Project #:3?1. oJ.lo o Project lflrnager: KaT z H , l"ielrl PersonneY Clntilrienn L , \\'eather Condifions: $N"W Windfrom: J I at Z Tcmp: Q.{ Signature: I Boring Locrtion: L-t I lnitid Prgrurc:CIL%COze/"ofh NrTu Sample Stnrt Timr:Flow Rate $rmple f,nd Tintct Final Pressure: _tg 51.1'Llz'\o,l o.o ll:Ll {o" *t ll:L?*lz Iotes:)rittc L lo' Boring Locetion: L- lo lnitial Presure:ClL7.C0:Y,Of/o Nr%Sample Strrl Time:Flow Rrle Sample lind 'l'lmc:Iilnal Pressure: - lr-51.5 ?'51 o.l o,o ll:qt 5* *t ll :Ll7 -8 \otcs: Boring Location: /'lt lnitiel Pressure:CHt"h COf/o ofh Itir7,Sampk {itnrt Time:Florr Rate Sample End Time:Finnl Prrssurr: -8 flq 1l,b o.3 o,o lz:otr {a.'*t lZi Lo -Ll Notes:Prir.+ L lo' BoringLocetion: L - q I[irirl Presgure:CHenh COtoh Ot'h N:7o Srnrple Slrrl 'l'imel Horv Rnte Sample End Time:Final Prcssurc: -q ,1.?17,L o.l o,o tz"z+fa.ut 17:701 *l Iotts:DriiloL l.' Hf,N$ENIu"En ELUGE* llorttttl 'ticr ll NMOC Sampling Field Form Project Mantger: Kot<- H. Projcct u:3?4,o?, lco Fleld Personn el: ()trign a.a /' Suhm Crnlrtcr Canisrnr ID: l1S,Sampte rD: lTSt- _ 7 Lelk Chectr tnfo l; Drtrr lnitirl Prcssurc:Starl time:Iinal Prcssurc:End Time: lllz7l23 -tR H*tn l(o:'ll -,6 tn f(+lL:4c \Ycather Conditions: 5 ttt ow \Yind from: $ly' ot 6 - Tcmp: 7 1 Boring Locrtion: L-g Inltirl Frcsrure:Cllrtlo CQf/t Ot/.NrTo Srmpte Surt Tlmc:Flow llrtc Srmple End Tlmo:Finrl Pressure: -tb 5E.z Il.'o.l o.o lz'{z Joo *t n:rLt *t3 Notc':prittol tu /o' Boring Locrtion: L'7 lnitirl Prxnrre .CHt'h cofh ofh Nre/.Sample Slrrl Timc:Flow Rrte Srmple End Time:final }ressuro: -13 56.f qr,l a,It o.o 17'. ltl {a ur 17:tc -6 Iotcs:pritro) ?a lo' Boring Locrtlon: L- G lnitirl Pmreure:Clltoh cafh Of/o Nr%Srmple Strrt Time:Flow Rate Srmple f,nd Time:Final Pressure: -q 5t.t t12.1 o.t o.o 13:77 ln *t t3:ts -1 !{ole3:DriloS P /o' Boring Locetion: L-, lnltid Prcrsnrt:Cllr%cofh 0fh Nr7"Sample Iilart '[ime:Flon Rale Sample End Timel finrl Pressurc: -{,fl {r fl o.l o.o t7i5 q fao u. r /7:Ec -/ l{otel:)rt'tt<L fe lo' O\Srgnarure: % ";;;;; flu-En *tllQfirxtrst{{tn$ 'I'ier ll N[IOC g66pling Ficld Form Projccr lllanager: f qP<- H. Projcct *ffi-o?.1a0 t._ictd personnrl, ot"ri St)o"t_ L. linurPlc to: 139 7 -Cnnistcr lD: ffifi(hock lnfo I:inal l,rcssur".--T n,r,l rim.;: -tfl i"h i )i:s$ ^-lnitrll l'ressurc; ll ltl I tt I)arc: lU ol/L \\eathrrCondirions: Cl*Lrt Nintl from: $ly' t_ 17 jjl,Ot ;l-s;ipt" srorr I a llue:r*ll':t5 of o lo' Florr Rott :s1: final Pressure: Sanrple Enrl _.1_i_ntsi l4)4o g \orrs:, DC,tl4L Boring Location: L,Z _ lnirirl i C,1,",frellurc: I \otes: i Df i I rc--b o{ la-nc..L -la NITo 3-I Boring Locrtion: U L___-- .j"-,nr --I.*rl *r;f-r*, l5i ( QA Srgn.rturc ":vEq'r. APPENDIX C Laboratory Analytica! Data ECHNOLOGY Laboratar ies, December 27.?023 [{ansen. Allen & Luce ATTN: Kate Herberl 859 W. South Jordan Pkw,v. Suite 200 South Jordan. UT. 84095 L,{. Cert #04140 EPA liretho{,s nO3, TOt4A, IO15. 25Cr3C. ASTM Dr946. RSI(.I75 TX Cert Tt04704450-146 EPA Methods TO14A. fots UT Cert CA0133332015-3 EPA Mothods TO3. TO14A. 1O1 5. RSt(-l 75 LABORATORY TES T RESUI,TS Project Reference: Bountitirl Sanitary Landfill- Tier II 2023 ProjectNumber: 374.03.100 Lab Number:P120606-0r/08 Enclosed are results tbr sample(s) received 12/06/23 by Air Technology Laboratories. Samples were received inlact. Analyses were perfonned according to specifications on the chain of custody provided with the sample(s). Report Narrative: lJnless otherwise noted in the report. sample analyses were perfonned within method perfcrrmance criteria and meet all requirenrents of the TNI Standards. The enclosed results relate only to the sample(s). Prelirninary results were e-mailed to Kate Herbert on 12122123. ATl, appreciates the opportunity to provide testing services to your cotnpany. lf you have any questions regarding these results, please call me at (626) 9644A32. Sincerely. /7 i i) -,'-"\.' ..- n Lt t,r*-u'o if*" "[<Y' tr '"ot- --/' Mark Johnson Operations Manager MJohnson@A i rTech I-abs. conl Note: 'l"he cover letter is an integral part ol'this analytical report. 18501 F. Ga/* rlvcntrrr. Sttrtr,t 1.:J0 t Cttl'of lnrlrtslry, C/l 9I/.18 t Ph (6?{i} .16,t 4()32 t Fx. 1626) g54 5g'-i2 Page l of 4P120606 o zutE =oo ic\IC N tq oco lto o il coo lto ct6c)llo L:o .EG Eo() 0)gozIz u !!( f a( LtcI zEo!IEoI UI oFz 9ts NEoIF5 It EF o & :Eoo tooaJaI -" b.' ;{-o o oU:Ul)U cff, =oI() t ,a Jc ( R-.-:i\ f.r( I) UI hF o &o g UoUG o o =F 0) foo (n TLf xt!EoIL g .YE = oco .co:(, FGo A.oz E l!o Jor llE e .o (U a 0)o(l, L oo() o Eoa,() l( .g(L o .9oo() -o6J ;o o 06 o E3 2otrfo EFa !! I;! u =hls E.f,o' 9-.\ :a 6; rr | ,t- ,0oU:c.2 o2:a gt D ts(o a!outo:oz J0 ncc U 1! tr trcFg (,: lr =I (.) llo [io o. iln"E ooDzzl I Itrtr Ioqlool gIHE :6==-o:c6(,()o o €co Fou,3o ETtro6 z ul a trlrl uI trDiltr JJ_ trj [!OL\\ TJL]UUI1JUJJJ 13t Y ryl?Yy ?r y\tryv u,l = oz3o G ztr trtrtr9ec.::,ooor=taoN(or t"' (,, trtrtr o-Eas? i.ccFO#,BH I o2 JJ E 'lo: ci q. o t0 ldAl u3Nrv.r.N0a , xtulwl L 31,!ll1 3ldnvs $ut sil ir. p c 3IVO 3'1dt1lVS bit *\-; ;! i'r r..l .\ .{ .) t-. \- N l6 :\j iJ 1\ s\\ $ oIss:, t-15 E5"us. EV 33€$H t!:o<o 5EE36 >\.. ..P5f,r (?),,, osJ,;o':z*-i(rt lll - l_I c.fls l=t\lrl=il\t t] t;I -tl q.-l SG "Jtq-q id O{E:=(, (,o0}'d' 'ts' tq r *) +l sl -s, s+ Jaj oFto a-ot J + {a* \ II r ( -\)Xr3:! i otr Eoo I${ rltt, & * t\ -s\ d -lt4 "tqrt oo 6 I :Jr{s.i 1".1slj N :x 5 G v, B 6 J "xl -l $-i d f; cao tro 0- a! E o Zo tr Ile Fzltl e lrlJ o. =a r:. C'1 I J i ,i, { /' (', I J t4 q.Y: :r" I I i /" \,, t- I ,,. t" I J \. ,r'l ld llr' I Jzo tuof tr J a t stU,a o €c'li' Ts \$r ts'o ) s Y ? ,s T > Client: Attn: Project Name: Project No.: Drte Received: Matrix: Hansen, Allen & Luce Kate Herbert Bountiful Sanitary Landfill - Tier II 2023 374.03.100 t2t6t2023 Air TNMOC by EPA METHOD 2sC Fixed Gases by EPA METHOD 3C Lab No.;P120606-01 P120606-02 Pr20606-03 P120606-0{ Client Sample I.D.:BSL.I BSL.2 BSL-3 BSL-4 Date/Time Sampledl I l/30123 9:21 I l/30/23 ll:28 ll/30/23 I4:20 t2/l/23 8:30 Date/Time Analyzed:l2ll9E3 21235 l2ll9l2l22:33 l2ll9l23 23231 12120123 0:29 QC Batch No.: 23r2l9GC8At 23t2t9GC8At 23r2r9CC8Al 23t220GC8Ar Analyst Initials:RC RC RC RC Dilution Factor:3.0 3.4 3.6 3.6 ANALYTE (Units)Result RL Result RL Result RL Result RL INMOC N2 corrected (oomy-C)630 30 s90 3{710 36 700 36 INMOC O2 corected (nnmv-C)630 30 360 3{560 36 680 36 INMOC uncorrected (onmv-C)600 30 250 31 510 36 630 36 Yitrogen (o/o vlv\ND 3.0 {3 3..1 23 3.6 s./3.6 Dxygen/Argon (7o v/v)ND t.5 5.7 1.7 ND 1.8 ND r.8 RL = Reporting Limit ND = Not detected at or above thc RL. TNMOC = Total Non-lltethane Organic Compounds ppmv-C = parts per million by volume as carbon TIIMOC N2 corrected (applicable if N2 < 20%) TNMOC 02 corrected (applicable if N2 > 20% and 02 < S%) TNMOC uncorrected = not corrected for N2, 02 or moisturr NA = Nitrogen/oxygen/moisture correction causes division by zero. Reviewed/Approved By: Thc covcr letler is an integral part ofthis analyrical rcporr UTAH DEPAHTI,,/iENT OF ENVIRONMENTAL OUALITY r ! tl I DIVISION OF AIR QUALIT\ Operations Manager taTTECHNOI-OGY Labaratorics, lnc Date 1l Ll L) EEe3 of 4 Client: Attn: Project Name: Project No.: Date Received: Matrix: I'he cover lelcr is an intcgral pan of this analytica! rcpon Hansen, Allen & Luce Kate Herbert Bountiful Sanitary Landfill - Tier ll2023 374.03.100 w6n023 Air RL = Reporting Liurit ND = Not detected at or above the RL. TNMOC: Total Non-Methane Organic Compounds ppmv-C - parts per million by volume as carbon TNMOC N2 correcred (appticabte if N2 < 20%) TNMOC 02 corrected (appticabte if N2 > 20yo anrl OI < S%) TNMOC uncorrected = not corrected for N2, O2 or moisture NA = Nitrogen/oxygen/moisture correction causes division by zero. Rcviewed/Approved By: Mark Johnson Operations Manager \g : *a Drtc l( /L L) lnc. - 40f4 .,.'l .:a:.:' r t, li.illll jrri.i"i:ili'i:' Laboratorics ,: lJi + /r1j r/:l..il TNMOC by EPA METHOD 2sC Fixed Gases by EPA METHOD 3C Lab No.:P120606-05 Pr20606-06 Pr2060G07 P120606-08 Client Sample I.D.:BSL-5 BSL-6 BSL.7 I}SL-8 Date/Time Sampled:l2/l/23 9:S0 l2lll23ll:21 l2ll/2312;32 t2l1123 l{:15 Date/Time Analyzed:l2l20l23l:27 12120123 2:25 t2120123 3:23 l2l2ll/23 4z2t QC Batch No.:23r220GC8Ar 23t220GC8At 23t220GC8Ar ?3r220GC8At Analyst Initials:RC RC RC RC Dilution Factor:3.5 3.2 3.2 J.l ANALYTE (Units)Result RL Result RL Result RL Result RL INMOC N2 corrected (oomv-C)680 35 650 32 570 32 5?0 3t INMOC 02 corrected (nomv-Cl 660 3s 650 32 570 32 560 3t INMOC uncorrected (oomv-C)590 35 610 32 5{0 32 5t0 3rllitrogen {o/o vtvl 7.8 J.s ND 3.2 NT)l,J.5 3.rOxygen/Argon (7o v/v)ND 1.1 ND t.6 ND 1"6 ND 1.5 ,.rrouoM tirrECHNoLocY A Bou.NIIrur February L3,2024 Utah Division of Air Quality ATTN: Emission lnventory 195 North 1950 West salt Lake city, UT 84116 BOUNTIFUL UTAH DEPAHTMENT OF ENVIRONMENTAL OUATJTY FEB 1 3 2A24 *o*A Dr\il eftd DIVISION OF AIR QUALTN: SUBJECT:2023-2027 REVISED NMOC EMISSION RATE RPT - 5 YEAR ESTIMATE BOUNTIFUL SANITARY LANDFILL Dear Sir or Madam: According to the Utah Administrative Code and Bountiful City's Title V Operating Permit I have completed and enclosed a revised five-year estimate of the Non-Methane Organic Compounds (NMOC) Emission Rate Report for 2023-2Q27 for the BountifulSanitary Landfill. A previous five- year estimate was submitted to the Division of Air Quality on March 26,20L9. Each previous report has shown the NMOC Emission Rate to be less than 34 Mg/year. Thus, according to the city's Title V Operating Permit the city is eligible to submit an estimate of the NMOC emission rate for a five year period in lieu of annual NMOC reports. The report again shows the NMOC emission rate to be much less than 50 Mg/year, and much less than the pending threshold of 34 Mg/yr. The report is completed on a form provided by the Utah Division of Air Quality. The data, calculations, spreadsheets, and computer model outputs which were used to calculate the required information are attached. The landfill NMOC emissions were calculated using the Landfill Gas Emissions Model "LandcEM". We used arid climate defaults with user-specified NMOC concentration. The NMOC concentration data was determined for the Bountiful Sanitary Landfill from site specific landfill gas collection and testing (Tier ll) in compliance with EPA Method 25C and EPA Method 3C. This sampling and testing was completed in December 2023. A summary of the Tier ll testing results is attached. Todd G. Christensen, P. E. Bountiful City Engineering Department 795 South Main St. . Bountiful, Utah 84010 . (801) 298-6125 . toddc@bountiful.gov KENDALYN HARRIS MAYOR CITY COUNCIL JESSE BELL KATE BMDSHAW RICHARD HIGGINSON MATT MURRI CECILEE PRICE.HUISH CITY MANAGER GARY R. HI February 13,2024 Page 2 of 2 lf you have any questions, or if I can be of additional assistance, please feel free to contact me. Sincerely, BOUNTIFUL CITY ENGINEERING DEPT. ._./2"/A#,q Todd Christensen, P.E. Assistant City Engineer attachments as stated Or: CERT!FICAT!ON ln accordance with Operating Permit Provision l.K. and UAC R307-415-5d, I hereby certifythat the information and data submitted in and with this NMOC Emission Rate Report are true, accurate and complete, based on information and belief formed after reasonable inquiry. Signature:Title: Mayor, City of Bountiful Name: Kendalyn Harris Telephone Number: ( 801 ) 2e8-6L42 Date: CERTIFICATION ln accordance with Operating Permit Provision LK. and UAC R307-415-5d, I hereby certifythat the information and data submitted in and with this NMOC Emission Rate Report are true, accurate and complete, based on information and belief formed after reasonable inquiry. Signature: *t)Wu^Title: City Manager, City of Bountiful Name: Gary Hil!Telephone Number: ( 801 ) 298-6L42 Date: zltrlztzl NMOC EMISSION RATE REPORT DATE: Feb 13 . LOZI _ Initial / emenaea l. Landfill Name State of Utah Deparunent of Environmental Quality Division of Air Qualiry PO. Box 144820 Salt Lake city, uT 84114-4820 Telephone: (801) 5364000 2. Landfill Owner/Operator Name: Bo,^.ContactName: T"ll Streer 7ol 5 S.Title: E City, State, Zip:Telephone: tol Fax: 3. ffi Please check if mailing address for this landfill is the same as the mailing address given above. If different mailing address for this landfill, please complete the following: Site Address:Name: Street: City, State: 4. Location information: Latitude: q0' 5q' 30" ^lLongitude: lll' 55' OO" Ul County: Drrvr: UTMEast L|ZZSoo UTM Nortlr: 45 Z9L oo Year landfill began accepting waste l) (o Year landfill closea N/A Tlpe of collection systan (i.e., active vedical) zip: 5. 7. [ ] Tonst Ive [ ]m' t\) t\1 tq7 M1 ,n3 t4 1 x j v-L lxn v Ltx xL 6. Total amount of refuse in place as of December 3f f "[X1 Ufg313os, lbo Approximate amount of refuse received each yearloo, ooo Control device (i.e., flare, IC engine) Control Code 9. Values Used in Calculation if other than 40 CFR Part 60 Subpart WWW defaults k o.o2 ".'l Lo (r.rl a',..............._rl. nf."tt) NMOC Concentration _ (Submit test results with form) 11. Name (type orprint) Todcl CLr;stcr,sc'{Title: E rtc inc a f Date:7e? zoLs Ll.1oL{ Zo"Li t-1.17l" ZozS Ll.1tb LozL 5.o5%7oz7 9.t1|t AIa*e 10. Total NMOC ernission from January 1,Decernber 31,*o 21 11.13 [ ]tone/year t lMe/Gar (Use of 40 CFR Part 60 Subpart WWW defaults required for initial reports. Tier II and III testing can be used for amended r€,ports if DAQ approved) ATTACH CALCULATIONS OR MODEL RT}N S J+>r as {: *z-[c bX .l Lz.{ landgem-Bountiful 2023.xlsm Summary Report Landfill Name or ldentifier: Bountiful Sanitary Landfill Date: Tuesday, February 13,2024 Description/Comments : About LandGEM: n I 2t1312024 First-Order Decomposition Rate Equation: Where, Qcll4 = ?nDU?l methane generation in the year of the calculation (m3 fiear) i = 1-year time increment n = (year ofthe calculation) - (initial year ofwaste acceptance) j = 0.1-year time increment k = methane qeneration rale (vear'1 ) Lo = potential methane generation capacity (m'tUg\ Mi = rTroSS of waste accepted in the ith yeat (Mg) tij = age of the jth section of waste mass M| accepted in the ith year (decimal years, e.9., 3.2 years) Q"_FS//H4 .1-t .1-/j=l J=0.1 *.1#),-*" LandGEM is based on a firstorder decomposition rate equation for quantifying emissions from the decomposition of landfilled waste in municipal solid waste (MSW) landfills. The software provides a relatively simple approach to estimating landfill gas emissions. Model defaults are based on empirical data from U.S. landfills. Field test data can also be used in place of model defaults when available. Further guidance on EPA test methods, Clean Air Act (CAA) regulations, and other guidance regarding landfill gas emissions and control technology requirements can be found at http:/Aamw.epa.gov/ttnahr/O1/landfi ll/landfl pg.html. LandGEM is considered a screening tool - the better the input data, the better the estimates. Often, there are limitations with the available data regarding waste quantity and composition, variation in design and operating practices over time, and changes occurring over time that impact the emissions potential. Changes to landfill operation, such as operating under wet conditions through leachate recirculation or other liquid additions, will result in generating more gas at a faster rate. Defaults for estimating emissions for this type of operation are being developed to include in LandGEM along with defaults for convential landfills (no leachate or liquid additions) for developing emission inventories and determining CAA applicability. Refer to the Web site identified above for future updates. LandGEM Landfill Gas Emissions Model Yercion 3.O2 U.S. Erwironmeatal Protectiou Agency office of Research and Development National Risk Mmagernent Resea'ch Laboratory (NRMRL) and Clea: Air Technology Center (CATC) Reserch Triangle Parlg North Carolina REPORT - 1 landgem-Bountiful 2023.xlsm lnput Review LANDFILL CHARACTERISTICS Landfill Open Year 1960 Landfill Closure Year (with 8O-year limit) 2039 Landfill Closure Year entered exceeds the 80-year waste Actual Closure Year (without limit) 2056 acceptance limit. See Section 2.6 of the User's Manual. Have Model Calculate Closure Year? No Waste Design Capacity short tons MODEL PARAMETERS Methane Generation Rate, k 0.020 year'l Potential Methane Generation Capacity, Lo 170 m, /Mg NMOC Concentration 98 ppmv as hexane Methane Content 50 % byvolume GASES / POLLUTANTS SELECTED Gas / Pollutant #1: Total landfill gas Gas / Pollutant #2: Iliethane Gas / Pollutant #3: Carbon dioxide Gas / Pollutant #4: NMOC WASTE ACCEPTANCE RATES Year Waste AcceDted Waste-ln.Place (Mo/vear)/sho/,tons/veart (Mq)Ghorttonst 1960 35,760 39,336 0 1961 35,760 39,336 35,760 39,33€ 't962 35,760 39,336 71,520 78,672 1963 1964 53,640 53.640 s9,004 59.004 107,280 160,920 1 18,008 177,0't2 1965 53,640 59,004 214.560 2?6 n16 1966 53.640 59,004 268,200 295,O20 1967 53,640 59,004 321.840 3il.024 1968 53,64(59,004 375,480 413.028 1969 53,64(s9,004 429,120 472,032 1 970 53,64(59,004 482,760 531,03€ 197 1 53.64(59,004 536,400 590,040 1972 53.64(59,004 590,040 649,044 1 973 53 59,004 643.68C 708.048 1974 53,64(59 004 697.32C 767.052 1975 53,64(59.004 750.960 826.05€ 1 976 53,64(59,004 804,600 885,06C 1977 1 978 53,6.4( 53.64( 59,004 59,004 858,240 911,880 944,064 1.003.068 't 979 53.64(59.004 965,520 't.062.072 1 980 53.64 59.004 1.019.160 1.121 .07e 1 981 53,64(59.004 1.072.80C 't.18( 1 982 53,64(59,004 1,126.440 1.239.084 1 983 53,64(59,004 1 ,'t 80,080 1.298.088 1 984 53,64(59,004 1.233.720 1.357,092 1985 53,6,4(59,004 1,287,360 1,416,09€ 1S86 53,64(59.004 1,341,000 1,475,10C 1987 53.64(59.004 1,394,640 1,534,104 1988 25,44C 27,984 1.448.280 1.593.'t08 1989 25 44(27.984 1.473.720 1.621.O92 1990 25,44C 27,984 't,49S,160 1,649,07€ 1991 25.44(27,984 1,524,600 1,677,06C 1992 :z5,44L 27.984 1,550,040 1,705,U4 1993 ?5 44(27.984 1,575,48C 't,733,02e 1994 54,54(59.994 1.600.92C 1,761,01 1995 t4,55(60,00s 1,655,460 1,821,00€ 1996 u,54C 59,994 1,710,010 't,881,0'l 1997 14,55(60,005 1,764,550 1,941,00€ 1998 59,51(65,461 1 ,81 9,1 00 2,001 ,01c 1999 42.60C 46,860 1,878,610 2,066,471 2t1312024 REPORT - 2 landgem-Bountiful 2023.xlsm 2t13t2024 WASTE ACCEPTANCE RATE Year waste Accc Waste-ln-Place (Mq/vear)khorT lons/vear)(Md)GhotT tons 2000 41.800 19lqq 44.605 1,921,21 2.113.331 2001 noz 2oo5 2004 40,550 1.963.01 2.159.311 q,ryg 4',1.780 !4387 45,9q8 57,068 2,003,56! 2,040,73C 2.082.51C 2,203,916 2.244.803 51.880 2,290,76 2005 48,040 52,844 2,134,39C 2,182,43C 2,347,825 2006 59,1 80 65,qe! 75,691 64,680 2,400,673 2007 68,810 2,241 ,6',1 2,465,77 2008 58,800 2,310,42C 2.541.462 2009 45,170 49,687 2,369,22t 2,606,142 201 41,240 43,364 54,197 55,429 2.414.39C 2,655,829 2011 ls,219 50,390 50_rq10 62.540 2.455.63C 2.701 .193 20't2 2.504,90C 2,755,390 2013 2014 55,561 68,794 2,555.29C 2,810,819 2,605,80(2,866,380 2011 201e 7x,ry9 66,920 81,114 73,612 2,668,34(2,935,174 2,742,08C Q,q1ql!! 3,089,900201772,620 79,882 2,809,00c 201 I 89,070 89,730 97,977 2,881,62C 3,169,782 2019 98,703 2.970.69(3,267,759 202C 99,990 109,989 3,060,42(q.396162 3.476,45120281,370 89.507 3,160,41( 2022 61,400 67,540 3.241.78(.3,565,958 2023 69,890 76.87S 3,303,1 80 3,633,498 2024 00,000 110.000 9.32?,029 3,473,070 3,710,377 3,820,377202500,000 110,000 2026 00.000 110,000 3,573,070 3,930,377 2027 00.00c 110,000 110.000 3,673,070 4.O40. 2028 00,00c 3,773,070 4.150.37 2029 00,00c 110,000 3,873,070 4,260,37 2030 00,00c 1ll g,00_Q 110,000 l1qqqQ 110,000 3pz3,qzq 4,073,070 4,173,070 4,370,37 2031 2032 00,000 00,000 4,480,377 4,590,377 2033 00,000 4,273,070 4,700,377 2034 00.000 110,00q 110,000 I10,00Q 1 10,000 4,373,070 4.473.070 4,810,377 2035 00,000 4.920.377 2036 00,000 4,573,O70 5,030,377 2037 00.000 4.673.070 5,'t40,37 2038 00,000 r 10,000 1 10,000 4,773.O70 5,250,37 2039 00.000 4,873,070 5,360,377 REPORT.3 landgem-Bountiful 2023.xlsm Pollutant Parameters 2t't3t2024 Gas / Pollutant Default Parameters: Compound Concentration bPmv\Molecular Weiqht concentration (ppmv\Molecular Weioht oogt ago Total landtill gas Methane 0.00 16.04 44.O1 86.'18 Carbon dioxide NMOC 4.000 o co =o o- 1, 1, 1 -Trichloroethane (methyl chloroform) - HAP 0.48 1.1 133.4'l 1,1,2,2- Tetrachloroethane - HAPA/OC 167.85 1 , 1-Dichloroethane (ethylidene dichloride) - HAPA/OC 2.4 98.97 1 , 1-Dichloroethene (vinylidene chloride) - HAPA/OC 0.20 96.94 1 ,2-Dichloroethane (ethylene dichloride) - HAPA/OC 0.41 98.96 1 ,2-Dichloropropane (propylene dichloride) - HAPA/OC 0.'18 112.99 2-Propanol (isopropyl alcohol) - VOC 50 60.1'1 Acetone 7.0 58.08 Acrylonitrile - HAPA/OC 6.3 53.06 Benzene - No or Unknown Co-disposal - HAPA/OC 1.9 11 73.]4 78.11 Benzene - Co-disposal - HAPA/OC Bromodichloromethane VOC 3.'l 163.83 Butane - VOC C'aroon o-iiuttioe - HAPA/OC 5.0 0.58 58.12 76.13 Carbon monoxide 140 28.01 Carbon tetrachloride - HAPA/OC 4.0E-03 153.84 Carbonyl sulfide - HAPA/OC 0.49 !q.q7 112.56 96.47 64.52 r t 9.3s 50.49 147 120.91 Chlorobenzene - HAPruOC 0.25 lhlorodifluoromethane 1.3 lhloroethane (ethyl :hloride) - HAPA/OC 1.3 lhloroform - HAPA/OC 0.21 '!6 2,6 14 7.8 890 27 Jnlorometnane - vou Jichlorobenzene - (HAP br para isomerA/OC) )ichlorodifl uoromethane )ichlorofl uoromethane -r'oc _ __. fichloromethane imethylene chloride) - {AP 1023? 84.94 imethyl sulfide (methyl rlfide) - VOC thane thanol - VOC 62.13 50"07 46.08 REPORT.4 landgem-Bountifu I 2023.xlsm Pollutant Parameters (Continued) 2t13t2024 Gas / Pallutant Delault Parameters : Methyl ethyl ketone - HAPA/OC Methyl isobutyl ketone - HAPA/OC Toluene.- No or Unknown Co-disposal - HAPA/OC REPORT - 5 landgem-Bountifu I 2023.xlsm Graphs 2113t2024 lleg.grams Por Year 2.500E+04 2.0O0E+04 1.500E+04 1.000E+04 5.000E+03 0.000E+00 .d "d $.t .4." C .re .d .f .f ,"s ,$t ,S "&t .pr9 ,"8 "^d Year -Totallandfll gas -Mothan6 -carbon dioxid6 -NMcc Gubic MeteE Per Year 2.000E+07 1.800E+07 1.600E+07 '1,400E+07 1.200E+07 1.000E+07 8.000E+06 6.000E+06 4.000E+06 2.000E+06 0.000E+00 ^S "d .4t .d'" .S ^"# .S d ""f .pe ,$t ,$t drt .p.t ,.s8 .r"f Yeal -Totellendfill gas -Msthans -Carbon dioxide Usor€peclflod Unit (units shown in legend below) 7.000E+08 6.000E+08 5.000E+08 4.000E+08 3.000E+08 2.000E+08 '1.000E+08 0.000E+00 .ft ."t ^d." .d" .s" ^.tr ^"f .rf "S "-r" "$" ""f ,&" "^sr9 ".S ".SYe!r -Totral landfi I ga6 (ltl3ry€ar) -Carbon dioxid6 (lt^3ry6a0 -M6thane (tt^3/yoar) -NM@ (fi^3/year) REPORT - 6 landgem-Bountiful 2023.xlsm Results 2113t2024 Year Total landfill oas Methane (Mo/vear)(m'/vear)(ft 3/vear)(Mq/year)(mr /vear)(ft 3/vear) 1960 rqq 196? 1 963 0 Z.+toi+os 0 0 0 0 4.255E+06 A.aZOE*OO 1-251E+07 _ 3.01qE1ql 5.960E+02 fuslE*02 8.5'1 '1E+06 8.039E+01 1.205E+05 4.772E+05 7.088E+05 1.685E+07 2.503E+07 1.592e+02 2.364E+02 2.386E+05 -3.s44E+os1 964 1 .319E+03 '1.056E+06 3.730E+07 3.523E+02 5.281E+05 '1.865E+07 1 965 1.7aa!+W 2.161 E+03 't.397E+06 4.933E+07 4.659E+02 6.984E+05 2.466E+07 1 966 1.731E+06 6.112E+07 5.773E+02 8.653E+05 3.056E+07 1 967 2.570E+03 2.058E+06 7.267E+07 6.864E+02 1.0298+06 3.634E+07 1 968 1969 2.970E+03 3363E+03 2.379E+06 2.ossE+06 8.400E+07 9.510E*07 7.934E+02 1.1 89E+06 4.200E+07 8.983E+02 1.346E+06 4.755E+07 1970 3.748E+03 3.09t1E4q 3.303E+06 1.060E+08 1 r 67E;08 1 .001E+03 1.501 E+06 5.2998+07 197 1 4.125E+03 1 .1 02E+03 1.652E+06 5.833E+07 't972 4.495E+03 3.599E+06 1.271E+08 'l .20'l E+03 .800E+06 6.355E+07 1973 4.857E+03 3.890E+06 1.374E+08 1.297E+03 945E+06 6.868E+07 1974 1575 5.213E+03 4.174E+06 1.474E+08 1.392E+03 2.087E+06 7.370E+07 5.561 E+03 4.453E+06 1.573E+08 1.485E+03 2.226E+OB 7.863E+07 1 976 5.902E+03 4.726E+06 1.669E+08 1.577E+03 2.363E+06 8.345E+07 1977 6.237E+03 4.994E+06 '1.764E+08 1.666E+03 2.497E+06 8.81 8E+07 't 978 1 979 6.565E+03 5.257E+06 1.856E+08 1.753E+03 2.628E+06 2.7s7E*oo 9.282E+07 6.886E+03 5.514E+06 1.947E+08 1.839E+03 9.736E+07 1 980 7.201E+03 5.766E+06 2.036E+08 1.924E+O3 2.883E+06 1 .018E+08 1981 7.510E+03 6.014E+06 2:124E+08 +03 3.007E+06 1.062E+08 1982 1983 7.813E+03 8.1 09E+03 6.256E+06 6.494E+06 2.209E+08 2.293E+08 2.087E+03 2.166E+03 3.1 28E+06 3.247E+OB 1.1 05E+08 1.1 47E+08 1984 8.400E+03 6.727E+06 2.375E+08 2.244E+03 3.363E+06 '1.188E+08 1 985 8.685E+03 6.955E+06 2.456E+08 2.320E+03 3.477E+06 1.228E+OB 1 986 8.965E+03 7.'l7gE+06 2.535E+08 2.395E+03 3.589E+06 1.268E+08 1987 1 988 7.398E+06 2.6't 3E+08 2.468E+03 3.699Er06 1.306E+08 9.507E+03 7.613E+06 2.689E+08 2.539E+03 3.806E+06 1.344E+08 989 9.533E+03 7.634E+06 2.696E+08 2.546E+03 3.81 7E+06 1.348E+08 1 990 9.558E+03 7.654E+06 2.703E+08 2.553E+03 3.827E+06 1.352E+08 199'1 9.583E+03 7.6748+06 2.7'l0E+08 2.560E+03 3.837E+06 '1.355E+08 1992 1993 9.608E+03 7.693E+06 2.717E+08 2.566E+03 3.847E+06 1.358E+08 9.632E+03 7.712E+OG 2.724E+08 2.573E+03 3.856E+06 't.362E+08 1994 9.655E+03 7.731E+06 2.730E+08 2.579E+03 3.866E+06 1.365E+08 1995 1 996 '1997 9.923E+03 1 .019E+04 1.044E+04 7.946E+06 8J 56E+06 8.362E+06 2.806E+08 2380E+08 2.953E+08 2.650E+03 2721E+03 2.789E+03 3.973E+06 4J78E+Oo 4.'181E+06 1.403E+08 1 /4OE+08 1.477E+08 998 8.5648+06 &796E+06 &908E+06 3.024E+08 2.857E+03 4.282E+06 1.512E+08 999 1.098E+04 1 I 1 3E+04 3.1 06E+08 2.934E+03-2972E+O3 4.398E+06 1.553E+08 2000 3.'146E+08 4.454E+06 1.573E+08 2001 1.126E+04 9.0'l4E+06 3.1 83E+08 3.007E+03 4.507E+06 1.592E+08 2002 2003 1.137E+04 9.1 09E+06 3.217E+08 3.038E+03 4.554E+06 1.608E+08 1.146E+04 9.1 79E+06 3.241E+O8 3.062E+03 4.589E+06 1.6218+08 2004 2005 aqqq 2007 2008 zoos 1 .1 59E+04 t . t zsE+0a 9.278E+06 3.277E+08 3.095E+03 4.639E+06 '1.638E+08 i.668E+089.444E+06 9581 E+06 9.790E+06 3.335E+08 3.'t +03 4.722E+06 4791 E+06 4395E*06 1.197E+04 14'?3E.94 1.256E+04 1 .281E+O4 - 3.384E+08 3.457E+08 qJq6qqq 3.266E+03 3356E*03 3A22E+03 1.692E+08 1.006E+07 1n26E*07 3.553E+08 !622E+08 5.030 {.tN E+06 E+06 1.776E+08 1 31 1 E*OS REPORT - 7 landgem-Bountiful 2023.xlsm Results (Continued) 2t13t2024 Year Total landfill qas Methane (Mo/vear)(m3 /vear)(ft 3/vear)(Molvear)(m" /year)(ft^3/vear) 2010 2011 2012 1.294E+04 1 303E+04 1.036E+07 3.658E+08 3.455E+03 5.1 79E+06 s.2toE+oo s.2zar+06 '1.829E+08 1.8A2Ei081.043E+07 3.684E+08 3.480E+03 1 .31 8E+04 1.056E+07 3.728E+08 3.521 E+03 '1.864E+08 zu1 1.335E+04 1.069E+07 3.774E+08 3.565E+03 5.344E+06 '1.887E+08 2014 1.351E+04 1.082E+07 3 q20-,E4q 3.893E+08 3.608E+03 5.408E+06 1 .910E+08 2015 't:3ry.9!91 '1.411E+04 't.102E+07 3.677E+03 5.512E+06 1,946E+08 2016 1 .1 30E+07 3.991 E+08 3.770E+03 5.651 E+06 1.996E+08 2017 1.440E+04 '1.153E+07 4.072E+OB 3.846E+03 5.765E+06 2.036E+08 2018 1.472E+04 1.179E+07 4.1 64E+08 3.933E+03 5.895E+06 2.082E+08 2019 1 .518E+04 1.216E+07 4.293E+08 4.055E+03 6.079E+06 2.147E+08 2020 1.564E+04 1.252E+07 4.422E+08 4.177E+O3 6.261 E+06 2.211E+08 2021 1 .617E+04 1.295E+07 4.572E+08 4.31 9E+03 6.474E+06 2.286E+08 2022 1.653E+04 1.324E+07 4.675E+08 4.416E+03 6.620E+06 2.338E+08 2023 1.672E+04 t.ogaE+oa 1.339E+07 4.729E+08 4.467E+03 6.695E+06 2.364E+08 2024 1.360E+07 4.802E+08 4.535E+03 6.798E+06 2.4O1E+08 2021 1.749E+04 1.400E+07 4.945E+08 4.670E+03 7.001 E+06 2.472E+08 2026 20n 1.798E+04 l.-Wi+O+ 1.440E+07 5.085E+08 4.803E+03 4.932E+03 7.1998+06 7393E+06 2.542E+08 1.479E+07 5.222E+O8 2.611E+08 2028 zo?3 1.894E+04 l.gqte*Oq 1.517E+07 1 554E+07 1.591E+07 5.357E+08 Sr+g8E*08 5.060E+03 5.1 84E+03 7.584E+06 7.77',tE+06 2.678E+08 2.744E+08 203C 1.987E+04 5.618E+08 5.306E+03 7.954E+06 2.809E+08 2031 2.031E+04 1.627E+07 5.745E+08 5.426E+03 8.1 33E+06 2.872E+08 2032 2033 2.075E+04 2.'118E+04 '1.662E+07 1.696E+07 5.869E+08 5.991 E+08 5.543E+03 5.658E+03 8.309E+06 8.482E+06 2.934E+08 2.995E+08 2034 2.161E+04 1.73OE+o7 6.'l 1 0E+08 5.77'l E+03 8.651 E+06 3.055E+08 2035 2.202E+04 '1.763E+07 6.227E+O8 5.882E+03 8.81 6E+06 3.'l 13E+08 2036 2.243E+04 2.282E+W 2.321E+04 1.796E+07 1.828E+07 '1.859E+07 6.342E+08 5.990E+03 8.979E+06 3.1 71 E+08 2037 2038 6.454E+08 6.564E+08 6.096E+03 9.1 38E+06 ti.igZE*oo 3.227E+08 6.200E+03 3.282E+08 2039 2.359E+04 1.889E+07 6.672E+08 6.302E+03 9.2147E+06 3.336E+08 2040 2.397E+04 1.919E+07 6.778E+08 6.402E+03 9.597E+06 3.389E+08 7o,41 2.349E+04 '1.881E+07 6.644E+08 6.276E+03 9.407E+06 3.322E+08 2042 2.303E+04 1.844E+07 6.51 2E+08 6.'1 5'l E+03 9.220E+06 3.256E+08 2043 2.257E+04 +07 6.383E+08 6.030E+03 9.038E+06 3.1 92E+08 2044 2045 2.213E+04 7.riie+04 1.772E+07 l.ttte+w 6.257E+08 5.91 0E+03 8.859E+06 3.1 29E+08 3.067Ei0S6.1 33E+08 5.793E+03 8.683E+06 2046 2047 2.126E+04 2.084E+04 .702E+07 .669E+07 6.012E+08 5.893E+08 5.678E+03 5.566E+03 8.5't 1E+06 8.343E+06 3.006E+08 2.946E+08 2048 2.043E+04 1.636E+07 5.776E+08 5.456E+03 8.'178E+06 2.888E+08 2049 2050 2.002E+04 1.603E+07 5.662E+08 5.348E+03 8.016E+06 2.831 E+08 't.962E+04 1.571E+07 t S+Oe+07 15oE;07t. *oz 5.549E+08 5,440E]08 5332E.08 5226E*08 5.242E+03 7.857E+06 7.702E+Oo 7.549E;06 7.400E+06 2.775E+08 2051 2052 2053 1.924E!04 1.885E+04 1.848E+04 5.1 38E+03 5.036Ei0q 4.937E+03 2.720E+08 -rlqqEqs2.613E+08 2054 2055 2056 1.776E+04 1.706E+04 1.451E+07 5.1 23E+08 4 +03 7.253E+O6 2.561 E+08 1.422E+07 t:9aE*07 5.021E+08 4.743E+03 4.649E+05 7.1 09E+06 6.969E+06 2.511E+08 2.461E+084.922E+08 2057 2058 L366E+07 '1.339E+07 4.824E+08 4.729E+08 1.5!ZE{3 4.467E+03 6.831 E+06 2.412E+O8 1.672E+04 6.695E+06 2.364E+08 2059 2060 '1.639E+04 rcqZElqL 1.3'l3E+07 1.287E+07 4.635E+08 +S++E*OU 4.378E+03 +zszE*03 6.563E+06 6.433E*06 2.318E+08 2-272E*O8 REPORT. S landgem-Bountiful 2023.xlsm Results (Continued) 2113t2024 Year Total landfill oas Methane (Ms/vear)(m3 /vear)(ft^3/vear)(Ms/vear)(m" /year)(ft^3/vear) 2061 2062 1.575E+04 1.261E+O7 4.454E+O8 4.365E+08 4.2O7E+O3 6.305E+06 2.227E+08 1.544E+04 1.236E+07 4.'123E+03 6.1 81 E+06 2.1 83E+08 2063 1 .513E+04 1.212E+07 4.279E+08 4.O42E+03 6.058E+06 2.1 39E+08 2064 1.483E+04 1 .1 88E+07 4.1 94E+08 3.962E+03 5.938E+06 2.097E+08 2065 1.454E+O4 1 .'1 6,4E+07 4.'t'l 1E+08 3.883E+03 5.821 E+06 2.056E+08 zu6t 206i 1.425E+O4 1.'141E+07 4.030E+08 3.806E+03 3.731 E+03 5.705E+06 2.015E+08 1.397E+04 1.1 18E+07 3.950E+08 5.592E+06 '1.975E+08 2068 2069 'l .369E+04 1.096E+07 'l.O75E+07 3.872E+08 3.657E+03 5.482E+06 '1.936E+08 1.342E+04 3.795E+08 3.585E+03 5.373E+06 t.ebaE+os 20 7C 2071 'r .3"t5E+04 1.289E+04 1.053E+07 1.032E+07 3.720E+08 3.646E+08 3.514E+03 3.444E+03 5.267E+06 5.162E+06 't.860E+08 1.823E+08 2072 1.2UE+04 1.012E+07 3.574E+08 3.376E+03 5.060E+06 1.787E+08 2073 1.239E+04 9.920E+06 3.503E+08 3.309E+03 4.960E+06 1.752E+08 2074 1.214E+04 9.724E+06 3.434E+08 3.244E+03 4.862E+06 1.717E+08 2075 1.190E+04 9.531 E+06 3.366E+08 3.1 79E+03 4.766E+06 1.683E+08 2076 1.167E+04 9.342E+06 3.299E+08 3.1 16E+03 4.67 t E+06 1.650E+08 2077 1.144E+04 9.1 57E+06 3.234E+08 3.055E+03 4.579E+06 'l .6'17E+08 2078 1121E+O4 8.976E+06 3.1 70E+08 2.994E+03 4.488E+06 '1.585E+08 2079 1.099E+04 8.798E+06 3.1 07E+08 2.935E+03 4.399E+06 t ss+e*oa 2080 1.077E+04 8.624E+06 3.046E+08 2.877E+03 4.31 2E+06 '1.523E+08 2081 1.056E+04 8.453E+06 2.985E+08 2.820E+03 4.227E+06 1.493E+08 2082 1.035E+04 8.2868+06 2.926E+08 2.764E+03 4.143E+06 1.463E+08 2083 1.014E+O4 8.122E+06 2.868E+08 2.709E+03 4.061E+06 1.434E+08 2084 208s 9.942E+03 9.745E+03 7.961 E+06 7.803E+06 2.81 1E+08 2.756E+08 2.656E+03 2.603E+03 3.981 E+06 3.902E+06 1.406E+08 1.378E+08 2086 9.552E+03 7.649E+06 2.701E+08 2.551 E+03 3.824E+06 'l .351E+08 2087 9.363E+03 7.497E+06 2.648E+08 2.501 E+03 3.749E+06 1.324E+08 2088 9.1 78E+03 7.349E+06 2.595E+08 2.451E+03 3.674E+06 1.298E+08 2089 8.996E+03 7.203E+06 2.544E+O8 2.403E+03 3.602E+06 1.272E+08 2090 8.818E+03 7.061 E+06 2.494E+08 2.355E+03 3.530E+06 1.247E+08 2091 8.643E+03 6.921 E+06 2.444E+08 2.309E+03 3.46'1E+06 1.222E+08 2092 8.472E+O3 6.784E+06 2.396E+08 2.263E+03 3.392E+06 1 .1 98E+08 2093 8.304E+03 6.650E+06 2.348E+08 2.218E+03 3.325E+06 1.1748+08 2094 8.'140E+03 6.5'l8E+06 2.302E+08 2.174E+03 3.259E+06 1 .151 E+08 2095 7.979E+03 6.389E+06 2.256E+08 2.1 31 E+03 3.1 94E+06 1 .1 28E+08 2096 7.821E+03 6.262E+06 6J 38E+06 2.2'l2E+08 2.089E+03 3.'131E+06 1 .1 06E+08 2097 7.666E+03 2.168E+08 2.048E+03 3.069E+06 1.084E+08 2098 7.514E+03 6.01 7E+06 2.125E+O8 2.007E+03 3.008E+06 'l.062E+08 2099 7.365E+03 5.898E+06 2.083E+08 1.967E+03 2.949E+06 1.041 E+08 2100 7.219E+O3 5.78'l E+06 2.042E+08 1.928E+03 2.890E+06 1 .021 E+08 REPORT - 9 landgem-Bountiful 2023.xlsm Results (Continued) 2t13t2024 Year Carbon dioxide NMOC (Mo/vear)(mr /vear)(ft 3/vear)(Mo/vear)(mr /vear)(ft^3/vear) lsqq 1961 Z2OOE*02 0 0 0 0 0 830E+o-1.205E+05 4.255E+06 8.466E-02 2.362E+01 1962 4.368E+02 2.386E+05 8.426E+06 1.676E-01 4.677E+01 '1.652E+03 1963 1964 6.487E+O2 si567E+02 3.544E+05 5.281 E+05 1.251E+07 t.tio5e+b1 2.490E-01 s.z1oE-or 6.946E+01 2.453E+03 3'655E+03 i.fu4E;oC 1.035E+02 1965 1.278E+O3 6.984E+05 2.466E+O7 4.S07E-01 1.369E+02 196e 1.584E+03 8.653E+05 3-056E+07 6.079E-0'1 '1.696E+02 5.989E+03 1967 1968 1.883E+03 1.029E+06 r . r e9Eio6 3.634E+07 +.zooe*07 7.229E-O1 a355E4a -2.017E+02 ZSYe*OZ 7.122E+03 2.'177E+03 8.232E+03 1 969 2.465E+03 1.346E+06 4.755E+07 9.460E-01 2.639E+02 9.320E+03 197C 2.747E+03 1.501E+06 5.2998+07 1.054E+00 2.94'lE+02 1.039E+04 1971 3.023E+03 1.652E+06 5.833E+07 1.160E+00 3.237E+02 1j43E+04 1972 3.294E+03 1.800E+06 6.355E+07 1.264E+00 3.527E+02 1.246E+04 1973 3.560E+03 1.945E+06 6.868E+07 1.366E+00 3.812E+02 'l.346E+04 1974 3.820E+03 2.087E+06 7.370E+07 1.466E+00 4.090E+02 1.445E+O4 1971 4.0758+03 2.2268+06 7.863E+07 1,564E+00 4.364E+O2 1.541E+O4 197e 4.326E+03 2.363E+06 8.345E+07 '1.660E+00 4.632E+O2 '1.636E+04 1977 4.571 E+03 2.497E+06 8.81 8E+07 1.754E+O0 4.894E+02 1.728E+04 1 978 4.8'l 't E+03 2.628E+06 9.282E+07 1.847E+00 5.152E+O2 1 .819E+04 197e 5.047E+03 2.757E+06 9.736E+07 1.937E+00 5.404E+02 't.908E+04 1 98C 5.278E+03 2.883E+06 .018E+08 2.026E+00 5.651 E+02 1.996E+04 1 981 5.504E+03 3.007E+06 .062E+08 2.112E+00 5.893E+02 2.081E+04 1982 1 S83 5.726E+03 5.943E+03 3.'128E+06 3.247E+OB 1 05E+08 147E+08 2.1 98E+00 2.281E+00 6.1 31 E+02 6.364E+02 2.'t 65E+04 2.247E+04,:rlil041 984 6.1 57E+03 3.363E+06 '188E+08 2.353E+00 6.592E+02 1 985 t e8o 6.365E+03 6.570E;03 3.477E+06 3589E+06 .228E+08 2.443E+O0 6.816E+02 2.407E+O4 .268E+08 .906E;08 .Sa-+f*OA 2.522E+00 2.isgE+oo 7.035E+02 2.484E+04 -2560E+041 987 6.771E+03 3.699E+06 7.250E+02 1 gEt 6.968E+03 3.806E+06 2.674E+00 7.461E+02 2.635E+04 1 g8g 6.987E+03 3.817E+06 .348E+08 .fSZe+OA 2.682E+00 7.481E+02 2.642E+04 1 99C 7.005E+03 3.827E+06 2.689E+00 7.501E+02 2.649E+04 19S'l 7.O24E+O3 3.837E+06 355E+08 2.696E+00 7.520E+02 2.656E+04 1992 7.04'l E+03 3.847E+06 .358E+08 2.703E+00 7.539E+02 2.663E+04 1 993 7.059E+03 3.856E+06 .362E+08 2.709E+00 7.558E+02 2.669E+04 1 994 7.076E+03 3.866E+06 .365E+08 2.716E+00 7.577E+02 2.676E+04 1 ggs 7.272E+03 3.973E+06 .403E+08 2.791E+00 7.787E+02 2.750E+04 1 996 1 997 7.465E+03 7.653E+03 4.078E+06 4.1 81 E+06 .440E+08 .477E+08 2.865E+00 2.937E+00 7.993E+02 8.1 95E+02 2.823E+04 2.894E+04 '19S8 7.838E+03 4.282E+06 51 2E+08 3.008E+00 8.393E+02 2.964E+04 1 g9S 8.050E+03 4.398E+06 553E+08 3.090E+00 8.620E+02 3.O44E+04 200c 8.153E+03 4.454E+06 .573E+08 3.129E+00 8.730E+02 3.083E+04 2001 8.250E+03 4.507E+06 .592E+08 3.'166E+00 8.833E+02 3.'120E+04 2002 8.337E+03 4.554E+06 .608E+08 3.200E+00 8.926E+02 3.152E+04 2003 8.401E+03 4.589E+06 .621E+08 3.224E+00 8.995E+02 3.177E+04 2004 8.492E+03 4.639E+06 .638E+08 3.259E+00 9.093E+02 3.211E+04 2005 8.644E+03 4.722E+06 .668E+08 3.31 8E+00 9.255E+02 3.269E+04 2006 8.769E+03 4.791 E+06 .692E+08 3.366E+00 9.390E+02 3.3'l6E+04 2007 8.961E+03 4.895E+06 112eEl9e 1.776E+08 1 3i 1 E+os 3.439E+00 9.5948+02 3.388E+04 2008 9.207E+03 5.030E+06 3.534E+00 iso3E+oo 9.859E+02 3.482E+04 2009 I +03 5.129E+06 1.005E+03 3.550E+04 REPORT - 1O landgem-Bountiful 2023.xlsm Results (Continued) 1.497E+O4 '1.467E+O4 1.438E+04 '1.410E+04 1.3828+04 1.354E+04 1.328E+04 'l .30'l E+04 1.276E+O4 1.25OE+04 1.rr6E!91 1.201E+04 7.17eE+o4 5.216E+06 5.278E+06 5.344E+06 5.408E+06 5.51 2E+06 5.651E+gq 5.765E+06 5.895E+06 6.079E+06 6.261 E+06 6.474E+06 6.620E+06 6.695E+06 6.798E+06 7.001 E+06 71 99E+06 z.assr*o6 z.EaaE+06 1.i71E+06 7.954E+06 8.1 33E+06 8.309E+06 8.482E+06 8.651E+06 8.816E+06 8.979E+06 9.1 38E+06 9.294E*06 8.859E+06 8.683E+06 eSt t e*OO 8.343E+06 8.1 78E+06 !!]!E{q 7.857E+06 7.702E*06 7549E*06 7.400E+06 7.253E+06 7.1 09E+06 6,.96gE*06 6.831 E+06 6.695E+06 6.563E+06 6.433E+06 2.995E+08 3.055E+08 3.'1 1 3E+08 3.1 71 E+08 L227E+08 3.282E+08 3.336E+089.447E+06 9.597E+06 3.389E+08 9.407E+06 3.322E+08 9.220E+06 3.256E+08 2.946E+08 2.888E+08 2.83'l E+08 2.775E+08 2.72OE+OB 2.666E+08 2.613E+08 2.561 E+08 2.51 1E+08 2.461E+08 2.412E+08 2.364E+08 2.31 8E+08 5.4'1 1E+00 13!1E1q0 5.1 99E+00 sos6Eioo 4.995E+00 6.256E+04 6.1 32E+04 6.01 0E+04 5.891 E+04 5.775E+O4 5.660E+04 5548E;04 5.438E+04 5331 E+04 ,225E+04 5122E+O4 5.020E+04 4.921E+04 +.923E+04 4.728E+04 3.192E+08 3J29E*08 3.067E+08 3.006E+08 6.224E+O0 6.1 01 E+00 5'SeOE*00 5.861 E+00 5.745E+00 5.632E+00 5.520E+00 4.896E+00 4.799E+00 4.704E+00 4.61 1E+00 as19E*oo 1 .312E+03 1.286E+03 1.26't E+03 4.634E+04 4.543E+04 4.453E+04 2t13t2024 9.481E+03 1.009E+04 t.Oa+E*O+ 1.079E+04 t .i t sE+oa 1 .1 85E+04 1.212E+04 '1.226E+04 1.244E+04 1.n1E+04 1.318E+04 1.353E+04 1 38SE+04 1.422E+04 1.456E+04 1.489E+04 1.521E+O4 1.553E+04 1.583E+04 1.6'14E+04 1.644E+04 1.7UE+04 1.757E+04 1.722E+04 1.622E+04 1 .59OE*04 't.829E+08 1.842E+08 '1.864E+08 1.887E+08 lsloE+08 1.946E+08 1.996E+08 2.036E+08 2.og2E+08 2147E+Oa 2.211E+08 2.286E+08 2.338E+08 1.015E+03 1.O22E+O3 1.035E+03 1.047E+03 t OOOr*OS 1 -080E+03 1 .1 08E+03 't .1 30E+03 '1 .1 55E+03 't .1 91 E+03 1.227E+03 1 269E-O3 1.297E+03 3.585E+04 36'1 OE+04 3.654E+04 3.699E+04 3.815E+04 aSrt e+Oa 3.990E+04 4.080E+04 4.207E+O4 4.333E+04 4.481E+04 3.799E+00 3372E*OO 3.970E+00 4.050E+00 4.142E+00 4.398E+00 4.548E*00 +SStE*OO 4.704E+00 2017 zola 2019 2020 2023 ,o24 4.776E+00 4.91 8E+00 5.058E+00 5.'194E+00 8328E+oo 5.459E+00 5.588E+00 5.7148+bO 5.838E+00 5.959E+00 6.078E+00 6l%E+00 6.308E+00 2.472E+08 2.542E+O8 2.61 1E+08 2.678E+08 2J44E+08 2.809E+08 ?,872E+OB 2934E+08 5.117E+04 5.249E+O4 5.379E+04 5.505E+04 5.630E+04 ,751E+U 5371 E+04 5.988E+04 6.1 02E+04 2033 2034 1 .791 E+03 6-.5i1E+04 2037 2038 2039 6.637E+00 6.742E+00 6.478E+00 63508+00 1.852E+03 1.881E+03 't.844E+03 1.807E+03 1,771E+03 1.736E+03 1.702E*O3 1.668E+03 i.i;ssE+03 '1.603E+03 1.571 E+03 1.540E+03 2048 ioiie 2052 ,053 1.480E+03 1.450E+03 2060 REPORT - 1 1 landgem-Bountiful 2023.xlsm Results (Continued) 2t13t2024 Year Carbon dioxide NMOC (Mo/vear)(m" /year)(ft^3/vear)(Mq/vear)(m3 /vear)(ft^s/vear) 2061 2062 zooa 1.154E+04 1.131E+04 6.305E+06 2.227E+08 4.430E+00 1.236E+03 4.364E+04 6.1 81 E+06 2.1 83E+08 4.342E+00 1.211E+03 4.278E+04 I .1 09E+04 6.058E+06 2.1 398+08 4.256E+00 1 .1 87E+03 4.1 93E+04 2064 1.087E+04 5.938E+06 2.097E+08 4.172E+OO 1.1 64E+03 4.110E+04 2065 1.065E+04 5.82'l E+06 2.056E+08 4.089E+00 1.141 E+03 4.029E+O4 2066 1.044E+04 5.705E+06 2.015E+08 4.008E+00 1.'1 '18E+03 3.949E+04 2067 1.024E+04 5.592E+06 975E+08 3.929E+00 1.096E+03 3-871E+O4 2068 '1.003E+04 5.482E+06 936E+08 3.851 E+00 1.074E+03 3.794E+04 2069 ,o7o 9.836E+03 5.373E+06 .898E+08 3.775E+00 1.053E+03 3.7'l9E+04 9.64'1E+03 5.267E+06 .860E+08 3.700E+00 1.032E+03 3.646E+04 2071 2on 9.450E+03 5.'t62E+06 .823E+08 3.627E+00 1 .012E+03 3.573E+04 9.263E+03 5.060E+06 787E+08 3.555E+00 9.91 8E+02 3.503E+04 2073 9.079E+03 4.960E+06 752E+OB 3.485E+00 9.722E+02 3.433E+04 2074 8.900E+03 4.862E+06 717E+OB 3.416E+00 9.529E+02 3.365E+04 2075 8.723E+03 4.766E+06 .683E+08 3.348E+00 9.34'1E+02 3.299E+04 2076 8.551E+03 4.671E+06 .650E+08 3.282E+00 9.1 56E+02 3.233E+04 207i 8.381 E+03 4.579E+06 .617E+08 3.217E+O0 8.974E+02 3.1 69E+04 207e 8.21 5E+03 4.488E+06 585E+08 3.1 53E+00 8.797E+02 3.1 07E+04 2079 8.053E+03 4.399E+06 554E+08 3.09'l E+00 8.622E+02 3.045E+04 208C 7.893E+03 4.312E+06 523E+08 3.029E+00 8.452E+02 2.985E+04 2081 na2 7.737E+03 4.227E+06 1.493E+08 2.969E+00 8.284E+02 2.926E+04 7.584E+03 4.'143E+06 1.463E+08 2.91 1 E+00 8.120E+02 2.868E+04 2083 2084 7.434E+03 7.286E+03 4.061 E+06 3.981 E+06 1.434E+08 1.406E+08 2.853E+00 2.797E+Oo 7.959E+02 7.802E+02 2.811E+04 2.755E+04 2085 2086 7.142E+03 3.902E+06 1.378E+08 2.741E+Oo 7.647E+02 2.701E+04 7.001 E+03 3.824E+06 1 .351E+08 2.687E+00 7.496E+02 2.647E+04 2087 6.862E+03 3.749E+06 1.324E+08 2.634E+00 7.348E+02 2.595E+04 2088 6.726E+03 3.674E+06 1.298E+08 2.582E+00 7.202E+02 2.543E+04 2089 6.593E+03 3.602E+06 '1.2728+08 2.530E+00 7.059E+02 2.493E+04 2090 6.462E+03 3.530E+06 1.247E+O8 2.480E+00 6.920E+02 2.444E+04 2091 6.334E+03 3.461E+06 1.222E+08 2.431E+Oo 6.783E+02 2.395E+04 2092 6.209E+03 3.392E+06 '1.198E+08 2.383E+00 6.648E+02 2.348E+0q 2093 6.086E+03 3.325E+06 1.174E+O8 2.336E+00 6.517E+O2 2.301 E+04 2094 2oe5 5.966E+03 3.259E+06 1 .1 51 E+08 2.290E+00 6.388E+02 2.256E+04 5.847E+03 3.1 94E+06 1 .1 28E+08 2.244E+00 6.2618+O2 2.211E+O4 2096 5.7328+03 3.1 31 E+06 1 .1 06E+08 2.2O0E+00 6.137E+02 2.167E+O4 2097 2098 5.618E+03 5.507E+03 3.069E+06 3.008E+06 'l.084E+08 1.062E+08 2.1 56E+00 2.114E+00 6.0'16E+02 5.897E+02 2.124E+04 2.082E+04 2099 5.398E+03 2.949E+06 1 .041E+08 2.07ZE+OO 5.780E+02 2.041E+04 21 00 5.291 E+03 2.890E+06 1.02'lE+08 2.03'l E+00 5.665E+02 2.0o1E+o4 REPORT - 12 ffi FrB 1 3 2024 DIVISION OF AIR OUALITY BOUNTIFUL CITY BOU NTI FUL SAN ITARY LAN DFI LL TIER II LANDFILL GAS TESTING TEST REPORT December 2023 BOUNTIFUL GITY BOUNTIFUL $ANITARY LANDFILL TIER II LANDFILL GAS TESTING TEST REPORT (HAL Project No.: 374.03.100) Kate Herbert Project Manager Andrew Alvaro Environmental Services Director HInsEnIu-En ELUGE,," ENGIilEENS December 2023 TABLE OF CONTENTS APPENDICES APPENDIXA TEST PROTOCOL APPENDIX B FIELD DATA APPENDIX C LABORATORY ANALYTICAL DATA Bountiful Sanitary Landfill Tier ll Test Report Table 1 Table 2 Table 3 Figure 1 LIStr OF TABLES Vacuum Measurements in lftches of Mercury .............. 3-1 Nitrogen and Oxygen Contents in Percent Volume ......3-2 LIST OF FIGURES Tier ll LandfillGas Sampling Locations....,......,.... After F-1 Bountiful Sanitary Landfi ll Tier ll Test Report CHAPTER 1 . INTRODUCTION INTRODUCTION Bountiful City selected Hansen, Allen, & Luce, lnc. (HAL) to conduct the Tier ll landfill gas testing services for the Bountiful Sanitary Landfill. Under the New Source Performance Standards (NSPS) federal regulations (40 CFR Part 60, Subpart the Bountiful Sanitary Landfill is currently required to test and estimate the non-methane organic compound (NMOC) rate every five years. The results of this Tier ll landfill gas test will be used by Bountiful City Engineering to calculate the annual NMOC emissions rate to determine if the threshold emission rate for installing a landfill gas collection and control system is triggered. HAL completed the Tier ll landfill gas testing on December 1,2023 and received preliminary analytical results on December 22, 2023. Chapter 2 contains descriptions of the field activities and Chapter 3 contains analytical and quality control results for this testing event. LANDFILL DESCRIPTION The Bountiful Sanitary Landfill is a Class I landfill operating under a Title V Operating Permit (#1100113004 dated February 27,2019) located at 1300 West Page Lane in West Bountiful, Utah. The Landfill has been in operation for 37 years, having first accepted waste in 1987 and becoming permitted in 2000. The historic and active landfill area is about 100 acres. About 40 acres ('t6 hectares) of the landfill containswaste of age greaterthan two years. About 59 acres of the historic landfill contains primarily ash from historic open burning of waste, which is mostly located in the South Cell. This material has been tested and shown to produce no methane, so NMOC rate testing is not appropriate in this portion of the landfill (40 CFR 60.754(aX3)). The Bountiful Sanitary Landfill and the portions which are not methane-producing are shown in Figure 1. Bountiful Sanitary Landfill 1-1 Tier ll Test Report CHAPTER 2 - FIELD ACTIVITIES SAMPLING LOCATIONS 32 locations within the area of the landfill containing waste for 2 or more years were sampled for the Tier ll Testing. Sample locations were laid out in a grid pattern over a current contour map of the landfill. Actual collection points were occasionally adjusted by field representatives to compensate for poor access, low quality gas, or safety concerns, as necessary. These locations are shown in Figure 1. SAMPLING PROCEDURES Samples were collected according to EPA methods 25C and 3C. HAL utilized a hydraulic, direct- push drilling platform to place landfill gas sampling probes to depths of 5-15 feet below the existing ground level. The probes were sealed against ambient air intrusion into the sampling space. The landfill gas samples were collected through a post-run tubing system. A hollow steel drive rod with a sampling head was advanced to the desired depth by directpush methods, the expendable drive point was ejected, and the probe was retracted approximately six to twelve inches to create an airtight headspace . A/+-inch polyethylene tube was inserted through the hollow steel drive rod and connected to the sampling head with an airtight threaded fitting. The pre-screening was performed by using a Landtec GEM5000 portable landfill gas analyzer. The landfill gas analyzer was be connected to the le-inch polyethylene tubing via a stainless-steel flow control manifold having a pressure gauge, fine adjustment needle valve, rotameter, and three.way purge/sample valve. The landfill gas analyzer drew a minimum of two sampling tubing volumes prior to screening and sampling. !f the screened gas contents were below 20 percent nitrogen or below 5 percent oxygen, then a landfill gas sample could be collected. Where these field quality controlcriteria were not met, the probe was removed and reinstalled in a new location before re-screening. All collected samples collected in the field met the pre-screening parameter requirements listed in methods 25C and 3C. After field quality control criteria were met, the probe was attached to an evacuated Summa@ canister and sampling train. The sampling train was purged with helium prior to sample collection as a precaution against cross-canister contamination. The vacuum measurement of the Summa@ canister was recorded. A measured volume of soil gas was drawn into the canister at a rate of approximately 0.5 liters per minute or less. Flow into the canister was regulated with a needle valve and the flow rate was monitored using a calibrated rotameter. At the completion of sampling, the vacuum measurement was recorded again. Sample gas from four discrete sampling locations was composited into a single Summa@ canister such that 32 discrete sample locations were composited into 8 separate Summa@ canisters. Before shipping, the final vacuum of the Summa@ canisters were recorded. The samples were shipped to Air Technology Laboratories, lnc. (ATL) located in City of lndustry, CA under chain of custody documentation. Bountiful Sanitary Landfi ll 2-1 Tier ll Test Report CHAPTER 3 - ANALYTICAL RESULTS ANALYTICAL PROGEDURES HAL measured and recorded the vacuum readings of the Summa@ canisters upon receipt. The vacuum results are shown in Table 1. No Summa canister was found to lose more than 3 inches of mercury from the initial laboratory labeled pressure. Based on the elevation difference between the lab location and sample location, these results assure that no atmospheric intrusion to any of the received Summa@ canisters occurred during transit. The laboratory pressure measurements were not available at the time of report production. HAL assumes that there were no issues noted by the laboratory. lf additional information becomes available that changes this assumption, the data will be provided under separate cover. Table 1 acuum u Sample ID Canister # lnitia! Pressure at 4,500 feet Final Pressure at 4,500 feet Final Pressure at 1 50 feet BSL-1 1343 -18 -1 -5.2 BSL-2 1451 -18 -1 -5.2 BSL-3 1396 -18 -1 -5.2 BSL-4 5474 -18 -1 -5.2 BSL-5 1286 -18 -1 -5.2 BSL-6 5470 -18 -1 -5.2 BSL-7 1450 -18 -1 -5.2 BSL-8 3743 -18 -1 -5.2 V Measurements in lnches of Merc Each Summa@ canister was analyzed by ATL by EPA Methods 25C and 3C for NMOC, nitrogen, and oxygen contents in triplicate. These methods require the nitrogen content to be less than 20 percent, or alternatively the oxygen content to be less than 5 percent. The quality control results are shown in Table 2. The average of the triplicate analytical runs are shown. All Summa@ canisters except BSL-2 were found to meet the quali$ control criteria of <20%o nitrogen or <5o/o oxygen. The sample locations comprising BSL-2 often suffered from refusaldue to gas rejection. However, this sample met the quality control criteria of a nitrogen to oxygen ratio of greater than 3.71 for landfills with 3-year average rainfalls equal to or less than 20 inches. The nearest station with >90% available precipitation data, BOUNTIFUL 0.8 SE, UT US, had a 3-year (2020-2022) average rainfall of 18.4 inches. Bountiful Sanitary Landfill 3-1 Tier ll Test Report Table 2 and Contents in Percent Volume Sample lD Canister #Sites Nitrogen Oxygen BSL-1 1343 L-20, L-21, L-22,1-23 <3.0 <1.5 BSL-2 1451 L-24, L-26, L-28, L-32 43 5.7 BSL-3 1396 L-27,L-29, L-30, L-31 23 <1.8 BSL-4 5474 L-17,L-18, L-19, L-25 5.7 <1.8 BSL-5 1286 L-12, L-14, L-15, L-16 7.8 <'1.7 BSL-6 5470 L-9, L-10, L-11, L-13 <3.2 <1.6 BSL-7 1450 L-5, L-6, L-7, L-8 <3.2 <1.6 BSL-8 3743 L-1, L-2, L-3, L-4 3.5 <1.5 The NMOC contents are reported in Table 3. The average of the triplicate analytical runs are shown. The average NMOC concentration is 98 parts per million (volume) as hexane. Table 3 NMOC Content i CONCLUSION All collected samples passed quality control criteria of <20Yo nitrogen, <5% oxygen, or a nitrogen to oxygen ratio of > 3.71 for landfills receiving <20 inches of annual precipitation over a 3-year average. The average NMOC laboratory analytical result of landfill gas at Bountiful Sanitary Landfill is 98 ppmv as hexane. This NMOC value may be used by Bountiful City for estimation of landfill emissions for the next five years. n Sample lD Canister #Sites Cuoc os Carbon Cnmoc ?s Hexane BSL-1 1343 L-20, L-21, L-22, L-23 630 105 BSL-2 1451 L-24, L-26, L-28, L-32 360 60 BSL.3 1 396 L-27,L-29, L-30, L-31 560 93 BSL-4 5474 L-17,L-18, L-19, L-25 700 117 BSL-5 1286 L-12,L-14, L-15, L-16 680 113 BSL-6 5470 L-9, L-10, L-11, L-13 650 108 BSL-7 1450 L-5, L-6, L-7, L-8 570 95 BSL-8 3743 l-1, L-2, L-3, L-4 570 95 Average:590 98 Bountiful Sanitary Landfill 3-2 Tier ll Test Report REFERENCES Geoprob@ Systems. "Soil Vapor lmplants and Post Run Tubing" https://geoprobe.com/sites/defaulUfiles/pdfs/Geoprobeo/oC2%AE%20Soil%2OVapor%2Ol mplants%2Oando/o29Post%20Run%2OTu bingo/o20-o/o20Direct%20Push. pdf Environmental Protection Agency. (2023). Method 25C-Determination of Nonmethane Organic Compounds (NMOC) in Landfill Gases. Retrieved November 7, 2023 from https://www.epa.gov/sites/defaulVfiles/2017-08/documents/method_25c.pdf. Environmental Protection Agency. (2023). Method 3C-Determination of Carbon Dioxide, Methane, Nitrogen, and Oxygen from Stationary Sources. Retrieved November 7, 2023 from https://www.epa.gov/sites/defaulUfilesl2}lT-0Sldocuments/method_3c.pdf. Bountiful Sanitary Landfill F-1 Tier ll Test Report FIGURES Bountiful Sanitary Landfill F-1 Tier ll Test Report tz o z l s z l z L .o l B o APPENDIX A Test Protocol BOUNTIFUL CITY TIER II LANDFILL GAS TESTING TEST PROTOCOL (HAL Proiect No.: 374.03.100) November 2023 BOU FUL CITY BOUNTIFUL TIER II LAN ITARY LANDFILL FILL GAS TESTING PROTOCOL No.:374.03.100) Herbert Manager rew Alvaro Services Director TABLE OF GONTENTS LIST OF FIGURES Figure 1 - Tier ll Landfill Gas Sampling Locations APPENDICES Appendix A - Soil Gas Sampling Tools - Post-Run Tubing System Appendix B - EPA Reference Method 25c Appendix C - EPA Reference Method 3c Bountiful Sanitary Landfi ll Tier ll Testing Protocol CHAPTER 1 . INTRODUCTION !NTRODUCTION Bountiful City has selected Hansen, Allen, & Luce, lnc. (HAL) to conduct the Tier ll landfill gas testing services for the Bountiful Sanitary Landfill. Under the New Source Performance Standards (NSPS) federal regulations (40 CFR Part 60, Subpart VWVW), the Bountiful Sanitary Landfill is currently required to test and estimate the non-methane organic compound (NMOC) rate every five years. The results of this Tier ll landfill gas test will be used to calculate the annual NMOC emissions rate to determine if the threshold emission rate for installing a landfill gas collection and control system is triggered. LANDFILL DESCRIPTION The Bountiful Sanitary Landfill is a Class I landfill operating under a Title V Operating Permit (#1100113004 dated February 27,2019) located at 1300 West Page Lane in West Bountiful, Utah. The Landfill has been in operation lor 37 years, having first accepted waste in 1987 and becoming permitted in 2000. The historic and active landfill area is about 100 acres. About 42 acres of the landfill contains waste of age greater than two years. About 59 acres of the historic landfill contains primarily ash from historic open burning of waste, which is mostly located in the South Cell. This material has been tested and shown to produce no methane, so NMOC rate testing is not appropriate in this portion of the landfill (40 CFR 60.754(a)(3)). The Bountiful Sanitary Landfill and the portions which are not methane-producing are shown in Figure 1. TESTING LOCATION Bountiful Sanitary Landfi ll 1300 West Page Lane West Bountiful, Utah 84087 PROPOSED TEST DATES HAL anticipates that testing will be performed on the week of November 27th, 2023, and will require two 1O-hour workdays. CONTACTS Facility Representative Todd G. Christensen, P.E., Assistant City Engineer Bountiful City 795 South Main Street Bountiful, UT 84010 801-298-6125 toddc@bountiful.gov Bountiful Sanitary Landfi ll 1-1 Tier ll Testing Protocol CHAPTER 1 - INTRODUCTION - CONTINUED State Representative Harold Burge, Major Source Compliance Section Manager Division of Air Quality, Utah Department of Environmental Quality 150 North 1950 West Salt Lake City, Utah 84114 385-306-6509 hburge@utah.gov HAL (Testing) Representative Kate Herbert, Project Manager Hansen, Allen, and Luce, lnc. 859 West South Jordan Parkway Suite 200 South Jordan, Utah 84095 801-566-5599 kate@halengineers. com Analytical Laboratory Air Technology Laboratories, lnc. 18501 E Gale Ave, Suite 130 City of lndustry, CA 917482655 626-964-4032 Bountiful Sanitary Landfi ll 1-2 Tier ll Testing Protocol CHAPTER 2 - TESTING PROTOCOL GENERAL SAMPLING PROCEDURES NARRATIVE HAL will utilize a hydraulic, direct-push drilling platform to place landfill gas sampling probes to depths of 10-20 feet below the existing ground level. The probes will be sealed against ambient air intrusion into the sampling space. Each soil gas probe will be purged of two sampling tubing volumes and screened using a portable landfill gas analyzer. Specifically, gas from each probe location will be screened for methane, carbon dioxide, oxygen, and nitrogen content. The quality controlcriteria of EPA Method 25Cl3C requires oxygen content in gas samples analyzed by the laboratory to be less than 5 percent or nitrogen to be less than 20 percent. These criteria are used by the laboratory to verify that ambient air was not drawn into the landfill gas sample and that gas was sampled from an appropriate location. HAL will apply these same criteria in the field to maximize the potential for laboratory quality control requirements to be met. lf these field quality control criteria are not met, then the probe will be removed and reinstalled in a new location where a viable sample can be collected. After purging and pre-screening the probe, the probe will be attached to an evacuated Summa@ canister and sampling train. The sampling train will be purged with helium prior to sample collection as a precaution against cross-canister contamination. A measured volume of soil gas will then be drawn into the canister at a rate of approximately 0.5 liters per minute or less. Flow into the canister will be regulated with a needle valve and the flow rate will be monitored using a calibrated rotameter. Sample gas from four discrete sampling locations will be composited into one Summa@ canister and submitted as one composite sample to the Laboratory, i.e.32 discrete sample locations will be composited into 8 separate Summa@ canisters. The last two sampling locations will be composited into one Summa@ canister for a total of 34 geoprobe locations composited into 9 Summa@ cannisters. After samples have been collected the probe will be removed, and the hole will be backfilled with bentonite chips. SAMPLING LOCATIONS Subpart V1A AlV requires two sample locations per hectare (up to 50 total sample locations) and that sample locations must be located where waste is at least two years old. Based on the information provided by Bountiful City Engineering, the landfill currently has approximately 42 acres (17 hectares) of area with waste of age greater than two years. Therefore, 34 locations within this area of the landfill will be sampled for the Tier ll Testing. According to Bountiful City Engineering, approximately 2.8 hectares in this area is covered with stockpiled soil. ln the area stockpiled with soil, sample probes will be installed to depths up to 20 feet below landfill surface cover. Sample probes in the remaining sampling area (14.2 hectares) will be installed to depths up to 10 feet below landfill cover surface. Sample locations will be laid out in a grid pattern over a current contour map of the landfill and will be marked in the field using survey lathe and flagging tape. Actual collection points may be adjusted by field representatives to compensate for poor access, low quality gas, or safety concerns, as necessary. Bountiful Sanitary Landfi ll 2-1 Tier ll Testing Protocol METHOD 25C EPA Method 25C provides the methods for use in sample collection and analysis of landfill gas. The landfill gas samples will be collected through a post-run tubing system, as shown in the Appendix A attachment. A hollow steel drive rod with a sampling head is advanced to the desired depth by direct-push methods, the expendable drive point is ejected, and the probe is pulled up approximately six to twelve inches to create an airtight headspace . Ala-inch polyethylene tube is inserted through the hollow steel drive rod and connected to the sampling head with an airtight threaded fitting. Gas can then be sampled from the tubing and pre-screened to ensure minimal intrusion of ambient air. The pre-screening will be performed by using a Landtec GEM5000 portable landfill gas analyzer. The landfill gas analyzer will be connected to the Yo-inch polyethylene tubing via a stainless-steel flow control manifold having a pressure gauge, fine adjustment needle valve, rotameter, and three-way purge/sample valve. The landfill gas analyzer will be on the purge side of the manifold to draw a minimum of two sampling tubing volumes priorto screening and sampling. The screened gas contents must be below 20 percent; however, if nitrogen below 20 percent cannot be obtained a sample may still be collected if oxygen content of less than 5 percent is observed under the alternative QC requirement of EPA Method 25C. After purging and pre-screening the probe, the probe will be attached to an evacuated Summa@ canister and sampling train. The sampling train will be purged with helium prior to sample collection as a precaution against cross-canister contamination. A measured volume of soil gas will then be drawn into the canister at a rate of approximately 0.5 liters per minute or less. Flow into the canister will be regulated with a needle valve and the flow rate will be monitored using a calibrated rotameter. Summa@ canisters have a volume of six liters at sea level: however, the effective canister volume at the elevation of the Landfill is reduced to approximately five liters. ln addition, the canisters will be preloaded by the laboratory with one liter of helium, which reduces the effective volume of the canister to approximately four liters. Helium is added to reduce the potential explosivity hazard of the methane containing canisters: this eliminates costly hazardous shipment procedures that would otherurise be required. Nine Summa@ cannisters will be used to composite samples from 34 sample locations. To complete the sample collection at the elevation of the Landfill (approximately 4,250 feet msl) while adjusting for the available Summa@ canister volume impacts of altitude, sample gas from 4 discrete sampling locations will be composited into one Summa@ canister and submitted as one composite sample to the Laboratory, i.e. 32 discrete sample locations will be composited into 8 separate Summa@ canisters. The last two sampling locations will be composited into one Summa@ canister for a total of 9 landfill gas samples. The leak-check protocol for the Summa@ canisters is to record the vacuum just prior and immediately after sampling at each location, and to record a final vacuum just prior to shipping the Summa@ canisters back to the laboratory. The laboratory will measure the vacuum readings upon receipt and compare the readings to the pre-shipment readings to ensure the absence of leaks. Each Summa@ canister will be analyzed by the laboratory for NMOC in triplicate. The average result will be the estimate of the average NMOC concentration (as carbon) of the landfill gas. The NMOC concentration (as carbon) will be divided by six as required in Subpart regulations to be reported as hexane. Bountiful Sanitary Landfi ll 2-2 Tier ll Testing Protocol EPA METHOD 3C EPA Method 3C is used to measure the of nitrogen and orygen in the Summa@ canister composite samples. The content must be less than 20 percent to meet EPA Method 25C requirements. lf the nitrogen is above 20 percent, EPA Method 25C allows an altemative requirement of less than by the landfill gas analyzer will assist in orygen. The field screening of the landfill gas that acceptable landfill gas samples are collected and minimizing the risk of sample QC Bountiful Sanitary Landfill Tier ll Testing Protocol CHAPTER 3 - QUALITY ASSURANCE AND QUALITY CONTROL CAL!BRAT!ON The landfill gas analyzer will be calibrated every sampling day for methane and oxygen. The calibration results will be shown in the test report. SUMMA CANISTERS Summa canisters are certified clean before shipment due to their reusable nature. The laboratory documents cannister cleanliness and conducts regular blank test audits of the process. The canisters are shipped under approximately -30 inches of mercury (Hg) vacuum, which corresponds to about -25to -26.5 inches Hg at the Bountiful Sanitary Landfill altitude. Upon receipt of the canisters and just prior to sampling, the vacuum in the cannisters will be checked and recorded to ensure the absence of leaks in transit. The cannister vacuum will be checked and recorded again after each sample collection, and just prior to shipping back to the laboratory. The laboratory will check the vacuum upon receipt and compare the readings to the pre-shipment readings to ensure the absence of leaks in transit. The Summa canisters will be shipped on the same day of sampling if possible, or the next morning. lf the Summa canisters are shipped the next morning, the vacuums will be rechecked and re.recorded prior to shipping. All data will be recorded on field data sheets with the cannister serial number and on the chain- of-custody form. FIELD DATA The following data will be recorded at each sample location: The boring number or the boring location (if it was necessary to move the boring to an unnamed position), the landfill gas screening results, the Summa canister vacuum readings just before and just after sample collection, the Summa canister serial number, and the sampling start and end times. The ambient air temperature and general weather conditions will be noted throughout each sampling day. The collected samples will be handled according to best practice general sampling and chain of custody procedures and specific laboratory instructions (if any). LABORATORY ANALYSIS The Quality Assurance and Quality Control (OA/OC) procedures of EPA Methods 25C and 3C will be observed by the laboratory for instrument operation, calibration, and calibration verification. The QA/QC data will be included in the test report. BACKUP SUMMA CANISTERS The laboratory will ship one extra Summa canister required for this Tier ll test. lf a cannister is found to have a leak during the pre-sampling vacuum check, one replacement cannister will be used. Bountiful Sanitary Landfill 3-1 Tier ll Testing Protocol REFERENCES Geoprob@ Systems. "Soil lmplants and Post Run Tubing" apoto/o20l o/o20Dir edo/o2 0 P u s h. pdf Environmental Protection Agency.Method 25C-Determination of Nonmethane Organic Compounds (NMOC) in Gases. Retrieved November 7, 2023 from https:/lwww 7-08/documents/method 2Sc.pdf. Environmental Protection Agency.Method 3C-Determination of Carbon Dioxide, Stationary Sources. Retrieved November 7, 2023Methane, Nitrogen, and Oxygen from https://www 7-08/docu ments/method_3c. pdf . Bountiful Sanitary Landfill Tier ll Testing Protocol FIGURES Bountiful Sanitary Landfill F-1 Tier ll Testing Protocol APPENDIX A Bountiful Sanitary Landfill F-2 Tier ll Testing Protocol Direct push machines were inrtrally des gned specifrcally for soil gas sampling. Our flrst set of tools were manufactured to extract vapor samples. Before Geoprobet'tools and equipment w'ere available, most soil gas sampling was done by manualiy advancing NPT pipe into the ground surface usrng a slam bar, often followed by us ng a bumper-style lack to remove the NPT pipe We then developed a simpie, quick, cost-effective methoc for conducting soil gas sampling - Post Run fubing (PRT) Systems and SoilVapor lmplants. The PRT method decreased labor costs, time requ rements, and decontamination fluids generated for sample collection. PRT Systems 785-825-1842 Seetoble on next poge See toble on next poge See toble on next page Seetoble on next page Seetable on next poge Seetoble on next poge -ffi ffi*,,.,., teet.bteonnextp.sr-P e.- seetobteonnextpose I I $ I FrE Post Run Tubinq (PRT) System allows the user to collect soil vapor samples quickly and easily at the desired sampling depth W ITH 0UT the time-consum i ng compl ic ation s associated with rod leakage and contami- nation. O-ring connections enable the PRT system to deliver a vacuum-tight seal that prevents sample contamination from UP hole, and assures that the sample is taken from the desired depth at the B)TTOM of the hole. The resulting time savings translates into a higher productivity rate for you and your client. geoprobe.com Probe /Jods Prohe Rads 201682 60 in. 202248 ,18 in. 207261 36 in. 202715 24in. 202714 12 in. 205222 6 in. 203193 1 m 25 lbs. 20 lbs. 1 5 lbs. 10 lbs. 5 lbs. 2.5 lbs. 15.4 lbs. '1.5 in 0.525 in. 21 3773 21J769 213762 213758 213753 213752 213763 60 in. l5.5 lbs. 48 in. 12.4 lbs. 36 in. 9.3 lbs. 24in. 6.2 lbs. 1.25 in. 0.625 in. 12 in. 3.1 lbs. 6 in. 1.55 lbs. 1 m 10.171bs. I &.' 1.5 in. Expendable Point Holder PRT 1.0 in. trpendable Steel Point 1.0 in. Expendable Steel Point PRT Erpendable Point Popper 204179 213778 1.1 in.0D 2137, l,],1;,i,1,oo 214207 1.25 in. Erpendable Point Holder PRT 1.0 in. Eryend.ble Steel Point 1.0 in. Expendable Steel Point PRT Erpendable Point Popper 214202 213778 1.1 in.0D 2t37Bt lJJl,,i:,* 214207 E $*, ) Lxpendable Pntnts Holders Expendable Points ,/ Holders PRT Adapters O-Rings o# -e PRT Adaptel o,# PRTAdaptel PRT Adapter 214208 tor3/l6in.lDTubing 214211 Forl/4in.lDTubing 214203 For 1/8 in. lDTubing 1/4 in. 0D x 3/1 6 in. lD x 500 ft. 3/8 in. 0D x 1/4 in. lD x 500 ft. l/4 in. 0D x 3/'16 in. lDx50ft. 5/1 6 in. 0D x 1/4 in. tD x 50ft. l/4 in. 0D x l/8 in. lD x50ft. 3/8 in. 0D x l/4 in. lD x 100 ft. d .6ry 0-Rin9 (MBPAdapter) 0-Ring (1.0 in. Erpendable Point) 0-Ring (Gas Sampling (ap 1.25 in.) 214210 Quantity:25 213782 Quantity:25 213776 Quantity:25-as \'*-"., {5.."\J IDPE Tubing PETubing Teflon Tubing TeflonTubing Teflon Tubing Nylon Tubing Gas Sampling (ap 213775 liiJ;flt""^ fl") r-"'.q .d 1)'t"* ' Tubing Accessones (_eoprobe) 785-825-1842 Soil Vapor Implants geoprobe.com/vapor-i mplants SoilVapor lmplants are convenient and inexpensive devices for both long-term soil gas monitoring, air sparging, and groundwater sampling. The double wovea staln/ess stee/ wire screens can be inserted down the bore hole of a probe rod and anchored at depth and are available in a variety of lengths. @ 785-825-1842 SatableonnqtW Setubleonnutpag Setoblemna,tpag Sutobhonnatpay lntenollhrads- wtdleonnutNqe geoprobe.com @ Probe Rods Expendable Points / Holders 201682 60 in. 202248 'B in. 207261 36 in. 20271t 24in. 202714 12 in. 205222 6 in. 203193 1 m 1.5 in 0.625 in. 1.25 in. Expendable Point Holder 1.5 h. Erpendable Point llolder 'l in, Erpendable PointSoil Gas lmplantAndor 2titsi l:llli;|fl 2038s5 lljl,lh 214205 lnternalthreads 213782 Quantity:25oS4 o-Rinsv (l,0in.ExpcndablePoint) 25 lbs. 20 lbs. 15 lbs. 10 lbs. 5 lbs. 2.5 lbs. 16.4 lbs. T t I d&\J f-l PETubing PETubing IDPE Tubing Tef,orlublng Teffonlubing Tefonlublng l{y'on Tubing fEPTuHng Silkone Tubing Adapter 1/2 in.0D x 3/8 in. lD x 500 ft. 3/8 in.0D x 1/4 in. lD x 500 ft. 1/4 in. 0D x 3/16 in. lDx500ft. I/4 in.0D x 1/8 in. ID x 50ft. 1/4 in. 0D x 3/16 in. lDx50ft. 5/16 in.0D x 1/4in. tD x50ft. 3/8 in. 0D x 1/4 in. lD x 100 ft. l/4 in.0D x 3/16 in. lD x 100 ft. Quantity:10 Glass Bead fl!-100 Merh Glass Bead / Bentonite Mix Glass Bead 6l!,100 Mesh Glas Bead / Bentonite llix 213849 250M1 213851 :250M1 I 600995 50 lb. Pail 2,JS7, I 50lb.Pail 601067 fr|06J 601062 @1057 214253 601064 600144 214252 21 3746 r*t f,t Glass BeadsTubing r) du\r-' -- - .a2 SoilGas lmplant 213877 Jr, SoilGarsprgelmplant 213878 213859 Soil Gas i 2rJ86, r soil Gas,Shallow6roundwater 213865 Soil Gas Sol/ Gas lmplants Soil Gas lmplant ,a' soilGaslmplant SoilGas lmplant .17 in. lD (4.3 mm lD) .25 in. lD (6.4mm lD) .25 in. lD (6.4 mm lD) 601062 601063 601 067 601067 6 in. (152 mm) 6 in. (152 mm) 6 in. (152 mm) 12 in. (105 mm) l2 in. (305 mm) Barbed i Barbed Swagelokn Soil Gas, Shallow Gtoundwatet Any plasti(tubing .25 in. lD to .4175 in. lD Soil Gas,Shallow Groundwater, (6.4mm lD to 1 I mm lD) Sparging Tapered Soew Thread Tapered Saew Thread Soi/ Gas lmplants (1 .25 in & 1.5 in. Probe Rods Only) CL@78s-825-r842 APPENDIX B Bountiful Sanitary Landfi ll Tier ll Testing Protocol FEB 1 3 202[ DIVISION OFAIR OUATITY Method 25C osl30l2o23 ll/hile we have taken steps to ensure the accuracy of this Internet version of the document, it is not the ofJicial version. The most recent edits to this method were published here: httos://www.eoo.sou/fdsvs/oke/FR-2016-08-30/pdf/2016-19642.odf, To see a complete version including any recent edits, visit: httos://www.ecfr.sou/csi-bin/ECFR?pase:browse and search under Title 40, Protection of Environment. Mnrnoo 2SC-DprERMrNATroN oF NoNMETHANE ORcaNtc Courouxos (NMOC) IN Lmmprlr, GasBs Notp: This method does not include all of the specifications (e.g., equipment and supplies) and procedures (e.g., sampling and analytical) essential to its performance. Some material is incorporated by reference from other methods in this part. Therefore, to obtain reliable results, persons using this method should also have a thorough knowledge of EPA Method 25. 1.0 Scope and Application l.l Analytes. A,nalyte CAS No. \onmethane orsanic comDounds INMOC)\o CAS number assigned. 1.2 Applicability. This method is applicable to the sampling and measurement of NMOC as carbon in landfill gases (LFG). 1.3 Data Quality Objectives. Adherence to the requirements of this method will enhance the quality of the data obtained from air pollutant sampling methods. 2.0 Summary of Method 2.1 A sample probe that has been perforated at one end is driven or augured to a depth of 0.9 m (3 ft) below the bottom of the landfill cover. A sample of the landfill gas is extracted with an evacuated cylinder. The NMOC content of the gas is determined by injecting a portion of the gas into a gas chromatographic column to separate the NMOC from carbon monoxide (CO), carbon dioxide (COz), and methane (CH+); the NMOC are oxidized to COz, reduced to CH+, and measured by a flame ionization detector (FID). In this manner, the variable response of the FID associated with different types of organics is eliminated. 3.0 Definitions [ReservedJ 4. 0 Interferenc es I ReservedJ 5.0 Safety 5.1 Since this method is complex, only experienced personnel should perform this test. LFG contains methane, therefore explosive mixtures may exist on or near the landfill. It is advisable Method 25C osl30l2023 to take appropriate safety precautions when testing landfills, such as refraining from smoking and installing explosion-proof equipment. 6.0 Equipment and Supplies 6.1 Sample Probe. Stainless steel, with the bottom third perforated. Teflon probe liners and sampling lines are also allowed. Non-perforated probes are allowed as long as they are withdrawn to create a gap equivalent to having the bottom third perforated. The sample probe must be capped at the bottom and must have a threaded cap with a sampling affachment at the top. The sample probe must be long enough to go through and extend no less than 0.9 m (3 ft) below the landfill cover. If the sample probe is to be driven into the landfill, the bottom cap should be designed to facilitate driving the probe into the landfill. 6.2 Sampling Train. 6.2.1 Rotameter with Flow Control Valve. Capable of measuring a sample flow rate of 100 +10 ml/min. The control valve must be made of stainless steel. 6.2.2 Sampling Valve. Stainless steel. 6.2.3 Pressure Gauge. U-tube mercury manometer, or equivalent, capable of measuring pressure to within 1 mm Hg (0.5 in HzO) in the range of 0 to 1,100 mm Hg (0 to 590 in HzO). 6.2.4 Sample Tank. Stainless steel or aluminum cylinder, equipped with a stainless steel sample tank valve. 6.3 Vacuum Pump. Capable of evacuating to an absolute pressure of 10 mm Hg (5.a in HzO). 6.4 Purging Pump. Portable, explosion proof, and suitable for sampling NMOC. 6.5 Pilot Probe Procedure. The following are needed only if the tester chooses to use the procedure described in section 8.2.1. 6.5.1 Pilot Probe. Tubing of sufficient strength to withstand being driven into the landfill by a post driver and an outside diameter of at least 6 mm (0.25 in.) smaller than the sample probe. The pilot probe shall be capped on both ends and long enough to go through the landfill cover and extend no less than 0.9 m (3 ft) into the landfill. 6.5.2 Post Driver and Compressor. Capable of driving the pilot probe and the sampling probe into the landfill. The Kitty Hawk portable post driver has been found to be acceptable. 6.6 Auger Procedure. The following are needed only if the tester chooses to use the procedure described in section 8.2.2. 6.6.1 Auger. Capable of drilling through the landfill cover and to a depth of no less than 0.9 m (3 ft) into the landfill. Method 25C 6.6.2Pea Gravel. 6.6.3 Bentonite. 6.7 NMOC Analyzer, Barometer, Thermometer, and 6.33, and 6.2.10, respectively, of Method 25. 7.0 Reagents and Standards 0s/3012023 Syringes. Same as in sections 6.3.1,6.3.2, 7.1 NMOC Analysis. Same as in Method 25, section7.2. 7.2 Calibration. Same as in Method 25, section 7.4, except omit section 7.4.3. 8.0 Sample Collection, Preservation, Storage, and Transport 8.1 Sample Tank Evacuation and Leak-Check. Conduct the sample tank evacuation and leak- check either in the laboratory or the field. Connect the pressure gauge and sampling valve to the sample tank. Evacuate the sample tank to l0 mm Hg (5.a in HzO) absolute pressure or less. Close the sampling valve, and allow the tank to sit for 30 minutes. The tank is acceptable if no change more than t2 mm is noted. Include the results of the leak-check in the test report. 8.2 Sample Probe Installation. The tester may use the procedure in section 8.2.1 or 8.2.2. 8.2.1 Pilot Probe Procedure. Use the post driver to drive the pilot probe at least 0.9 m (3 ft) below the landfill cover. Alternative procedures to drive the probe into the landfill may be used subject to the approval of the Administrator's designated representative. 8.2.1 .l Remove the pilot probe and drive the sample probe into the hole left by the pilot probe. The sample probe shall extend at least 0.9 m (3 ft) below the landfill cover and shall protrude about 0.3 m (l ft) above the landfill cover. Seal around the sampling probe with bentonite and cap the sampling probe with the sampling probe cap. 8.2.2 Auger Procedure. Use an auger to drill a hole to at least 0.9 m (3 ft) below the landfill cover. Place the sample probe in the hole and backfill with pea gravel to a level 0.6 m (2 ft) from the surface. The sample probe shall protrude at least 0.3 m (l ft) above the landfill cover. Seal the remaining area around the probe with bentonite. Allow 24 hours for the landfill gases to equilibrate inside the augured probe before sampling. 8.2.3 Driven Probes. Closed-point probes may be driven directly into the landfill in a single step. This method may not require backfilling if the probe is adequately sealed by its insertion. Unperforated probes that are inserted in this manner and withdrawn at a distance from a detachable tip to create an open space are also acceptable. 8.3 Sample Train Assembly. Just before assembling the sample train, measure the sample tank vacuum using the pressure gauge. Record the vacuum, the ambient temperature, and the Method 25C osl30l2023 barometric pressure at this time. Assemble the sampling probe purging system as shown in Figure 25C-1. 8.4 Sampling Procedure. Open the sampling valve and use the purge pump and the flow control valve to evacuate at least two sample probe volumes from the system at a flow rate of 500 ml/min or less. Close the sampling valve and replace the purge pump with the sample tank apparatus as shown in Figure 25C-2. Open the sampling valve and the sample tank valve and, using the flow control valve, sample at a flow rate of 500 ml/min or less until either a constant flow rate can no longer be maintained because of reduced sample tank vacuum or the appropriate composite volume is attained. Disconnect the sampling tank apparatus and pressurize the sample cylinder to approximately 1,060 mm Hg (567 in. HzO) absolute pressure with helium, and record the final pressure. Alternatively, the sample tank may be pressurized in the lab. 8.4.1 The following restrictions apply to compositing samples from different probe sites into a single cylinder: (l) Individual composite samples per cylinder must be of equal volume; this must be verified by recording the flow rate, sampling time, vacuum readings, or other appropriate volume measuring data, (2) individual composite samples must have a minimum volume of I liter unless data is provided showing smaller volumes can be accurately measured, and (3) composite samples must not be collected using the final cylinder vacuum as it diminishes to ambient pressure. 8.4.2 Use Method 3C to determine the percent Nz and Oz in each cylinder. The presence of Nz and Oz indicates either infiltration of ambient air into the landfill gas sample or an inappropriate testing site has been chosen where anaerobic decomposition has not begun. The landfill gas sample is acceptable if the concentration of Nz is less than 20 percent. Alternatively, the oxygen content of each cylinder must be less than 5 percent. Landfills with 3-year average annual rainfalls equal to or less than20 inches annual rainfalls samples are acceptable when the N2 to 02 concentration ratio is greater than3.7l. 9.0 Quality Control 9.1 Miscellaneous Quality Control Measures. Section Oualitv control measure Effect t.4.2 If the 3-year average annual rainfall is greater than20 inches, verify that landfill gas sample contains less than 20 percent Nz or 5 percent Oz. Landfills with 3- year average annual rainfalls equal to or less than 20 inches annual rainfalls samples are acceptable when the Nz to Oz concentration ratio is greater than 3.71. Ensures that ambient air ivas not drawn into the landfill gas sample and gas was sampled from an lppropriate location. 10.1, 10.2 VMOC analyzer initial and daily performance checks Ensures precision of lnalytical results. I 0.0 Calibration and Standordizotion Method 25C 0sl30l2023 Norp: Maintain a record of performance of each item. 10.1 Initial NMOC Analyzer Performance Test. Same as in Method 25, section 10.1, except omit the linearity checks for COz standards. 10.2 NMOC Analyzer Daily Calibration. 10.2.1NMOC Response Factors. Same as in Method 25, section 10.2.2. 10.3 Sample Tank Volume. The volume of the gas sampling tanks must be determined. Determine the tank volumes by weighing them empty and then filled with deionized water; weigh to the nearest 5 g, and record the results. Alternatively, measure the volume of water used to fill them to the nearest 5 ml. I 1.0 Anolytical Procedures 1 l.l The oxidation, reduction, and measurement of NMOC's is similar to Method 25. Before putting the NMOC analyzer into routine operation, conduct an initial performance test. Start the analyzer, and perform all the necessary functions in order to put the analyzer into proper working order. Conduct the performance test according to the procedures established in section 10.1. Once the performance test has been successfully completed and the NMOC calibration response factor has been determined, proceed with sample analysis as follows: I I .l .l Daily Operations and Calibration Checks. Before and immediately after the analysis of each set of samples or on a daily basis (whichever occurs first), conduct a calibration test according to the procedures established in section 10.2. If the criteria of the daily calibration test cannot be met, repeat the NMOC analyzer performance test (Section l0.l ) before proceeding. ll.l.2 Operating Conditions. Same as in Method 25, section ll.2.l. I I .1.3 Analysis of Sample Tank. Purge the sample loop with sample, and then inject the sample. Under the specified operating conditions, the COz in the sample will elute in approximately 100 seconds. As soon as the detector response returns to baseline following the COz peak, switch the carrier gas flow to backflush, and raise the column oven temperature to 195 "C (383 oF) as rapidly as possible. A rate of 30 'Clmin (54 'F/min) has been shown to be adequate. Record the value obtained for any measured NMOC. Retum the column oven temperature to 85 oC (185 'F) in preparation for the next analysis. Analyze each sample in triplicate, and report the average as Ct.. I 1.2 Audit Sample Analysis. When the method is used to analyze samples to demonstrate compliance with a source emission regulation, an audit sample, if available, must be analyzed. I2.0 Data Analysis and Calculations Norp: All equations are written using absolute pressure; absolute pressures are determined by adding the measured barometric pressure to the measured gauge or manometer pressure. Method 25C l2.l Nomenclature 0s13012023 B*: Moisture content in the sample, fraction. CNz : Nz concentration in the landfill gas sample. CmN2 : Measured Nz concentration, diluted landfill gas sample. Cmox: Measured Oxygen concentration, fraction in landfill gas. Co*: Oxygen concentration in the diluted sample gas. Ct: Calculated NMOC concentration, ppmv C equivalent. Ct : Measured NMOC concentration, ppmv C equivalent. Pu: Barometric pressure, mm Hg. Pt : Gas sample tank pressure after sampling, but before pressurizing, mm Hg absolute. Ptr: Final gas sample tank pressure after pressurizing, mm Hg absolute. Pti : Gas sample tank pressure after evacuation, mm Hg absolute. P*: Vapor pressure of HzO (from Table 25C-l), mm Hg. r : Total number of analyzer injections of sample tank during analysis (where j : injection number, 1...r). Tt: Sample tank temperature at completion of sampling, oK. Tti: Sample tank temperature before sampling, oK. Ttr: Sample tank temperature after pressuring, oK. 12.2 Water Correction. Use Table 25C-l (Section 17.0), the LFG temperature, and barometric pressure at the sampling site to calculate B,". ^ P* Eq.25c-ln*:i 12.3 Nitrogen Concentration in the landfill gas. Use equation25C-2 to calculate the measured concentration of nitrogen in the original landfill gas. I ('-!r\ I cx,= lffilt-r, Eq.25c-2 [\rrl t?r il_l 12.4 Oxygen Concentration in the landfill gas. Use equation 25C-3 to calculate the measured concentration of oxygen in the original landfill gas. I P-u\ I co, =lffilr*, Eq.25c-3 [\?t/-t7-rJ] Method 25C 0s/3012023 12.5 You must correct the NMOC Concentration for the concentration of nitrogen or oxygen based on which gas or gases passes the requirements in section 9.1 or based on the 3-year average annual rainfall based on the closest NOAA land-based station. 12.5.1NMOC Concentration with nitrogen correction. Use Equation25C-4 to calculate the concentration of NMOC for each sample tank when the nitrogen concentration is less than 20 percent. ct: Urtf )z1=rc r*rit Eq.25C-4(+-I#)u-H,,,)-,* Eq.25C-5 12.5.2 NMOC Concentration with oxygen correction. Use Equation25C-5 to calculate the concentration of NMOC for each sample tank if the landfill gas oxygen is less than 5 percent and the landfill gas nitrogen concentration is greater than20 percent, or 3-year average annual rainfall based annual rainfall ofless than 20 inches. Ptf rtf )Ei=rc r*{i) 1 3. 0 Method Performonce [ReservedJ 1 4. 0 P ollution Prevention [ReservedJ 15.0 Waste Management [ReservedJ 16.0 References l. Salo, Albert E., Samuel Witz, and Robert D. MacPhee. Determination of Solvent Vapor Concentrations by Total Combustion Analysis: A Comparison of Infrared with Flame Ionization Detectors. Paper No. 75-33.2. (Presented at the 68th Annual Meeting of the Air Pollution Control Association. Boston, Massachusetts. June 15-20,1975.) A p. 2. Salo, Albert E., William L. Oaks, and Robert D. MacPhee. Measuring the Organic Carbon Content of Source Emissions for Air Pollution Control. Paper No. 74-190. (Presented atthe 67th Annual Meeting of the Air Pollution Control Association. Denver, Colorado. June 9-13, 1974.) 25 p. 17.0 Tables, Diagroms, Flowcharts, and Validation Datq Method 25C I t-,.*. r'r -*.""-f[ o+ dhr HYdrr ,.#*--%J tl|rtF r llgrurl !tU-1" Pelrtrtls nlu rre,b. Dlrt'gt-E Ay't;a, llgurl llC-t. Ushrlatro srylr;re trrb. 0s13012023 Method 25C T.lnln 2sc-l-MorsruRr Connrcuox asB0l2023 Iemperature, )c Vapor Pressure of IIzO, mm [Is femperature,)c Yapor Pressure of HzO, mm lIe i.l 18 15.5 7.0 z0 17.5 3.0 22 19.8 l0 ).2 7.4 )-2.4 t2 10.5 26 15.2 t4 12.0 z8 28.3 l6 13.6 ]0 ] 1.8 APPENDIX C Bou ntiful Sanitary Landfill F-4 Tier ll Testing Protocol Method 3C 8l2l2OL7 l{hile we have taken steps to ensure the accuracy of this Internet version of the document, it is not the official version. The most recent edits to this method were published here: https://www.gpo.gov/fdsys/pkg/FR-2016-08-30/pdf/2016-196a2.pdf, To see a complete version including any recent edits, visit: https://www.ecfr.gov/cgi-bin/ECFR?page=browse and search under Title 40, Protection of Environment. MBrnou 3C-DnrnRMrNATIoN oF CARBoN Droxrur, Mornexr, NrtRocrN, AND OxycEN Fnou Sr.q,rroNmY SoURCES 1. Applicability and Principle l.l Applicability. This method applies to the analysis of carbon dioxide (COz), methane (CH+), nitrogen (Nz), and oxygen (Oz) in samples from municipal solid waste landfills and other sources when specified in an applicable subpart. 1.2 Principle. A portion of the sample is injected into a gas chromatograph (GC) and the COz, CH+, Nz, and Oz concentrations are determined by using a thermal conductivity detector (TCD) and integrator. 2. Range and Sensitivity 2.1 Range. The range of this method depends upon the concentration of samples. The analytical range of TCD's is generally between approximately 10 ppmv and the upper percent range. 2.2 Sensitivity. The sensitivity limit for a compound is defined as the minimum detectable concentration of that compound, or the concentration that produces a signal-to-noise ratio of three to one. For COz, CH+, N2, and Oz, the sensitivity limit is in the low ppmv range. 3. Interferences Since the TCD exhibits universal response and detects all gas components except the carrier, interferences may occur. Choosing the appropriate GC or shifting the retention times by changing the column flow rate may help to eliminate resolution interferences. To assure consistent detector response, helium is used to prepare calibration gases. Frequent exposure to samples or carrier gas containing oxygen may gradually destroy filaments. 4. Apparatus 4.1 Gas Chromatograph. GC having at least the following components: 4.1.1 Separation Column. Appropriate column(s) to resolve COz, CH+, Nz, Oz, and other gas components that may be present in the sample. 4.1.2 Sample Loop. Teflon or stainless steel tubing of the appropriate diameter. Method 3C 812120L7 Nore: Mention of trade names or specific products does not constitute endorsement or recommendation by the U. S. Environmental Protection Agency. 4.1.3 Conditioning System. To maintain the column and sample loop at constant temperature. 4. 1.4 Thermal Conductivity Detector. 4.2 Recorder. Recorder with linear strip chart. Electronic integrator (optional) is recommended. 4.3 Teflon Tubing. Diameter and length determined by connection requirements of cylinder regulators and the GC. 4.4 Regulators. To control gas cylinder pressures and flow rates. 4.5 Adsorption Tubes. Applicable traps to remove any Oz from the carrier gas. 5. Reagents 5.1 Calibration and Linearity Gases. Standard cylinder gas mixtures for each compound of interest with at least three concentration levels spanning the range of suspected sample concentrations. The calibration gases shall be prepared in helium. 5.2 Carrier Gas. Helium, high-purity. 6. Analysis 6.1 Sample Collection. Use the sample collection procedures described in Methods 3 or 25C to collect a sample of landfill gas (LFG). 6.2Preparation of GC. Before putting the GC analyzer into routine operation, optimize the operational conditions according to the manufacfurer's specifications to provide good resolution and minimum analysis time. Establish the appropriate carrier gas flow and set the detector sample and reference cell flow rates at exactly the same levels. Adjust the column and detector temperatures to the recommended levels. Allow sufficient time for temperature stabilization. This may typically require I hour for each change in temperature. 6.3 Analyzer Linearity Check and Calibration. Perform this test before sample analysis. 6.3.1 Using the gas mixtures in section 5.1, verify the detector linearity over the range of suspected sample concentrations with at least three concentrations per compound of interest. This initial check may also serye as the initial instrument calibration. 6.3.2You may extend the use of the analyzer calibration by performing a single-point calibration verification. Calibration verifications shall be performed by triplicate injections of a single-point standard gas. The concentration of the single-point calibration must either be at the midpoint of Method 3C 81212017 the calibration curve or at approximately the source emission concentration measured during operation of the analyzer. 6.3.3 Triplicate injections must agree within 5 percent of their mean, and the average calibration verification point must agree within I 0 percent of the initial calibration response factor. If these calibration verification criteria are not met, the initial calibration described in section 6.3.1, using at least three concentrations, must be repeated before analysis of samples can continue. 6.3.4 For each instrument calibration, record the carrier and detector flow rates, detector filament and block temperatures, attenuation factor, injection time, chart speed, sample loop volume, and component concentrations. 6.3.5 Plot a linear regression of the standard concentrations versus area values to obtain the response factor of each compound. Alternatively, response factors of uncorrected component concentrations (wet basis) may be generated using instrumental integration. Nots: Peak height may be used instead of peak area throughout this method. 6.4 Sample Analysis. Purge the sample loop with sample, and allow to come to atmospheric pressure before each injection. Analyze each sample in duplicate, and calculate the average sample area (A). The results are acceptable when the peak areas for two consecutive injections agree within 5 percent of their average. If they do not agree, run additional samples until consistent area data are obtained. Determine the tank sample concentrations according to section 7.2. 7. Calculations Carry out calculations retaining at least one extra decimal figure beyond that of the acquired data. Round off results only after the final calculation. 7.1 Nomenclature. B*: Moisture content in the sample, fraction. CNz : Measured Nz concentration (by Method 3C), fraction. CNzco., : Measured Nz concentration corrected only for dilution, fraction. Ct : Calculated NMOC concentration, ppmv C equivalent. Ctm: Measured NMOC concentration, ppmv C equivalent. Pu: Barometric pressure, mm Hg. Pt : Gas sample tank pressure after sampling, but before pressurizing, mm Hg absolute. Ptr: Final gas sample tank pressure after pressurizing, mm Hg absolute. Pti : Gas sample tank pressure after evacuation, mm Hg absolute. Method 3C 8/2120L7 P* = Vapor pressure of HzO (from Table 25C-l), mm Hg. r : Total number of analyzer injections of sample tank during analysis (where j : injection number, 1...r). R: Mean calibration response factor for specific sample component, area./ppm. Tt: Sample tank temperature at completion of sampling, oK. Tti = Sample tank temperature before sampling, oK. Ttr: Sample tank temperature after pressurizing, oK. 7.2 Concentration of Sample Components. Calculate C for each compound using Equations 3C-l and3C-2. Use the temperature and barometric pressure at the sampling site to calculate Bw. If the sample was diluted with helium using the procedures in Method 25C, use Equation 3C-3 to calculate the concentration. F - Pn 3C-luw - -r_-tls c =---!- 3c-2R[1-B*) D,ff c: + .A , 3c-3u - -E---D-tt _ tr fi [1- A"):-:lr ld 7.3 Measured Nz Concentration Correction. Calculate the reported Nz correction for Method 25-C using Eq.3C-4.If oxygen is determined in place of Nz, substitute the oxygen concentration for the nitrogen concentration in the equation. Prr i'.,. c*,ron: {o1r*,} Eq.{ - + f-fr 8. Bibliography l. McNair, H.M., and E.J. Bonnelli. Basic Gas Chromatography. Consolidated Printers, Berkeley, CA. 1969. APPENDlX B Field Data ffi!rOl\{rsS Ticr ll NMOC Sampling Field Form lrrr*. ll I S o/ Loz-j Project #:3fl, o},(eo Project lllanager:\<af- a4. Canistt'r lD: Final Pressure:Slarl lime:Dltc: I lnitral prcssure: 23" \\'eather Conditions: 1]l Boring Location: L-Zt - ld I 6p.t1 i Bq .t 5oo lo/\otcs: 1 /\ov4L 3o' Nw CIL% ICO:% Boring Location: L- Ll lo:o(-lL',,5r.gl\t.o \otes:, q* fu(44,7 Aovtl lo' tJ ).1ittt4- t5' - ? 151.7-Y::1-L!:o- roter: qdtw ro u, ^tnitial i cilr,t ' cofhi, oft,Prersurc: I t BoringLocalion: L-U Iinll Prcssurt:-lnitirl cilf,'. r cofhi oz'/ofr6turr: I i QA Signrture ffi Tier ll NNIOC Sampling Field Form $arrrple lD: BSL-canistcr ru jIE Final Pressurc:Datc: I l.it"l prcssurc:Stort timc: D*e: ll/3a/73 Project s, 3?l,o3.loo Proiect lflrnrger: tlo\?-.€- t4 ' Field pcrsonn 6. CtLnr t9n'url L. \\'cather Conditions: Cl tcl.{\Yind from: J U./ at 1-Temp: 3 3 Boring Location: l^U lnitiol Prcmurr:Cllr%cof/"Nr% Sample Stlrt Tlme:ilon Rote Sample f,nd f ime: Finrl Prcssure: - ry [to 3t.l o.4 L,5 5o, I Ir:30 -ru'{ \otes:0ril ...o(-r.lo hif saTSt 't"oK $o vtaPfu AT 5' BoringLocation: L-Z-Cn Initirl Pressure:Cllf/.cofh ofh N:%Srmple Start Timp:Flow Ratc Sample End Time:Finrl Prcssure: - te{ll.6 1.1 o.t ?8,t 1L"15 5ou \L',.17 -g Notes:Caat f-,l1csi-n, tv.ot,v,JL 5' N, Dri[trJ- 5' Boring Location: L'L$ Initiel Prosure:Cllt"/"COflo o{/"N:%Srmplc Stlrt Time:Flon Ratc Srmplc lind Time:!'inal Prcssure: -q (oo.q 31.0 o,x 1.3 frt{l loo 13t13 -, \otes:Qo* f<tJzoVicn . 30' NW, to'dritttl Boring Location: L -tL lnitill Pressure:Cllt'h cofh Of/o NrTo sanrPle start I Flo.r ltarr I tme: I Samplc End 'l'inre:[-inll Prcssure: -9 7t.il "t,0.c t.r ltl'.-Ll 5r,l4;.;11 4 \ores: i t rq?Uz ASrgnarure % to'ct7 5afl* r,.r oS ToW aT ct r ffiH I 'l'icr ll N[tOC Sampling Field form / /go ?44, o t.l oo Project iltanager: KqY* H ' rietrt Perronn rl, (Lr ilixn L ' Crnlstet Sanrplc tO: 951--canisrcr itI t7 ,01 | -10;^ \\'trthcr Conditions: LtO<tL\ lvind frontt A/wt u, 3 T"tP: (ll N\ 0 Ff tion: L-3 Srmple Start 'I'ime:Clho'i I C0:9i'ofh !\ir7' i 6:.elgt.o.c 7.,o l{:z-o t'{,94j - L-- \otm: j Dritk-L r" lo' Boring Locarion: L-ge lCIlr%(10:or'i O:%N:7o Srmple Slart Time:['lor' Rate I *u I o.7 17,2.q ?s?16:oq 9o, I ls (raS t"r4. cot"rt, Pril!*,Ll3Z Boring Location: b Frorr Rlrt, i t"i',ji.:"d rinrl pressurr: LI {y_g__1_9g'1) r_- -Irotcs: I Jrilt<l f, lo' g;r/ww lecu;ricY? .j:j:11'., crrrei i co,x i5?.3 i[z,)i o Boring Location: L- Z Fro* Rarr ; t'To,l:.:"d I rinur lrcssure: !c,tf l - Icofh I of/" fl.t'L,l l?. Sisnature: ffi Tier ll NIIIOC Sampling Ficld Form oZ -l oc Project lllrnager: YJ\?4- Vl ' tietd Personn.l: Clarif ?to' rl L' Cunistcr lD:Sarnplc lD: Final Prcssurc:[:nd Tirnc:f)atc: I l.irirl hcssure: I tt l2q l?3 '?-/ ol lU-z-7 3?lr. \\'eatherConditions: O"rll Wind from: 5E nt Boring Location: L^L9 Initial Prerlure:CIL%CO:%ofh Nr% Sample Start Time:Flon Rrte lionrplc f,nd Time:F innl Prcssure: -TL 6l.l Vii.s o.q o.o lb'3:-l5r ff'-tt - [-- ,\otts:lo'5. \a' l tlal- Boring Location: L-tol Initial Pressure:Cllt'/"cofh Ozo/o NrYo llnnrplc Stnrt Tirnc:Flow Rlte Sample End Time:Finll Pressuru: 11,,11 i4t, b l.o oo X:5o fou I fi:f*l ^g rotes: I orfi *l fo lo' Initial Pressure:ClLt/"cofh o{h NrTo Sample Starl Time:Florr lLatc Sanrplr Ind 'l'inre:Finll Prossurc: -6 5c.c Ll?^l t.0 o.O ot:o({w 01 :tc) I -t{ f oter:D(i tPl- Td ld' BoringLocation: L" l7 Initirl Pressure:CILY.cofh ofh NrTo Sample Stnrt Timcl l'low Rntc lirmple l)nd Tinre:I Tinnl I'rcssure: - Ll ]'lq tll,Tie ,t1 o-0 1',25 5oo q:z7i - \ \ores: hft il tL y /o ( 1/4 {signrrurc ry# /' HANSENffi{lSttdf,r} Tier II NlvtOC SanrPling Field Form vample tD: $5L- ICanisrcr tI): n$C ffi-check lnfo Final Pressurc:lintl Timc: 17: oG fhrc: i tniri.rl prcssure: ___ _-1 Ulzq/zl', - lA ia Dare: t?-l ol l'2-7 Projecr * 9?1. o 1. lo o Project l\lanager: Kat< 11. l"ietd Personnclz Arigiaa L. \\'erthrr Conditions: Stto'.l $ind from: $ W !t J I'emp: 3 Boring Location: L- t t, :t! lSJ*lllqkr soter: i priil.r ro la' 1t5z | - tz Boring Locarion: l-tA loitg | - E \otcs: [)1itt- t lo' ra ,C.542.61 ,.1 lo:17 Boring Location: L-\5 , cllr'h I Corxii rorsi: I Dritto.( Boring Locstion: L- 11 Cllfh i COt'h', Ofh samPlc End I tinat prcssurc: I lnlc: I lo'.5fi soru: i Dfil.L ll:oo | -l Q.\ Srgnature: HANSEn[[r"En &LUGE* Tier ll NMOC Sampling Field Form Sunmr Carlrter Canisrcr tO: $ll o $nnrple ta: lJ{1. - L Leak Check Info Datc Initiul Pressure:Start time:Final Pressure:Ilnd Timc: ttlLl/L7 'tx in H+lb lCz -|fl in H*l6\59 Project #:3?^. Projecr l\lanager: Katc H ' Fietd Personne* CLt iSrio,n L .oJ.loo \\'eather Conditions: SNoW Windtrom: J I at Z Temp: QA Signature: /r Boring Locetion: L-tg Initirl Pressurc:CIL%COtt/"0l'/o Nr%Srmplc Start Time:Flow Rete Srmple f,nd Timc:Finrl Pressurc: _tg 51.b t{?.\o.l o.o ll:Ll {o" *t ll :23 -12- Iotes:Vrittt L lo' Boring Locrdon: L- to Inithl Pre$urc:ClLt/,COfh ofh Nr%Sample Strrt Tlme:Flow Rrte Sample End Time:Final Pressure: -lr 51.5 !|53 o.l o,o ll:q5 5* ut It :t17 -8 :iole!: Boring Locrtion: L' ll lnitiel Prprsurc:CHt'h COzt/o ofh NrTn Sample Start Time:Florv Rnlc Sample fnd Time:Final Pressure: -8 57.q 1[6 o.3 o,o lz: otr {a.*t l7-l Lo *Ll Notec:Prin+ L lo' BoringLocation: L - q lDithl Presrurr.'CllrTo c0!%OrYo NrTo Srnrple Slrrt Time:Flou Rate Sample f,nd Tlmo:final Pressure: -t{51.?17.L o.l o,o lz'.77 {o*t 17:701 *l Notrc:Drltt*L l.' mnsmIu.En E LUGE* Srorrttta Tier ll NMOC Sampling f'ield Form $u mr Crnlrtcr Canistcr tD: l45o Samprc rD: 175t _ 7 Le:k Check lufo Ditlc lnilial Pressure:Starl timc:Final Prcssure:[ntlTime; iltzqlz)-lt irr H*lb: 'll -lE in lt+tbi4c tTl ol / z3 Projmt * 374. o?. lc o Project lllanager: K at+ H, Iiirld ferronn*l: Utrilna,a L' \\'cother Conditions: S t't ow Wind from: $ \e/ ot 0 Tcmp: 3 tl Boring Locrtion: L-g lniriel Prssurr:CHr%cafh of/o NrTo Srmple Start Time:Flow Rate lirmpb f,nd Time:$inrl Prcuure: -tb 5E.z tll .,o,l o.o lz'{z Joo *t t2:{1 -t3 Nolerl Qritttt tu /o' Boriog Locetion: L'7 lnitial Prerrure:CIL%COr%afh NrTo Srmple Strrt Time:Slow Rrte Srmple fnd '[imr:Final Pressure: -lf 5t.'w,t ar{o.o 17" l1 {a r*t 17:tL -5 Notes:piilol ?o lo' Boring Locetion: L- G lnltirl ?rrtcurr:CHto/.cofh ofh NrTo Srmple litrrl Time:Iflow Rlle Sample f,nd Time:Final Pressure: -q 5t,t lz,z o.t o.o t3i 77 fu-t ll:ts -t Note$:Dri1rS ro /o' Boring Location: L-, lnitid Prmcure:Clh/o cofh ofh NlTo Srmple Start Timr:Flow Raie Srmple End Time:Finrl Pressurel -I{,il { r.fl o,l o.o t7i5.l fao u, r /7: E c -t !{oter:Drt'lt+L fe lo' UIQ.{ Signature: .%.SS.SW$:(;i {iiii\-\... "- s..;; HflNSENAil Fn E LUGE* W 'l'ier ll NilIOC gxpplinfi F'icld Form froject #:? - or. rrO t,"ictrt personnrt Ct^ri Stloc_ L. $umma Crnhter SamPlc lD:Canisrcr llr, ??tl3 lrinul I'rcssurc.I r,n.l Timc: 3l -tfl;" otP<_ \\'eather Conditions: Cl-<tll lVinrl fronr: $td il 7 'f cmpt 3 14}15 lr/ - t-l_lt.?o.0 It llj4o Final Pressurc: i et.ti% \otes:r lTrilt*9 otr lunA,<* ')d Boring Location: (;i lnitial cfifh: ('(tro,'. i ofh Sarr,pt. St,,.t I'l'inrc: I );"1? I051_3|t.c_l?r_o'l2;0 Q.\ Sign;rturc. t; --r *:r-+r.1 ,-!I?ir]-4 APPENDIX C La boratory Ana lytica ! Data ECHNOLOGY Laborator ies, December 27.?A23 llansen. Allen & Luce ATTN: Kate Herbert 859 W. South Jordan Pkny, Suite 200 South Jordan. UT. 84095 LA Cert #04140 EPA l{elhods TO3. TOIIA TO15. 25CAC. ASTM 019C6. RSl(-r75 TX CerlT10470445S146 EPA Merhode TO14A" IO15 UT Gert CA0133332015-3 EPA lr6rhods TO3_ rotiA. TOI 5. RSr(.r 75 I-ABORATORY TEST RESULTS Project Refbrence: Bountil'ul Sanitary Landfill - Tier 112023 Project Numher: 374.03.100 Lab Number:P120606-0t/08 Enclosed are results fbr sample(s) received 12/06/23 by Air Technology Laboratories. Samples *ere received intact. Analyses were perfonned according to specifications on the chain of custody provided with the sample(s). Report Narrative: lJnless otheru'ise noted in the report, sample analyses were performed within method perfbrmance criteria and meet all requirements of the TNI Standards. The enclosed results relate only to the sample(s). Prelirninary results were e-mailed to Kate Herbert on 12122123. ATL appreciates the opporlunity to provide testing services to your company. lf you have any questiolts regarding these results, please call me at (626) 964-4032. Sincerely. n t \)*7''\. -- .a Ll t,io &'''acY '/"2./ Mark Johnson Operations Manager MJohnson@A i rTechLabs.com Note: 'l'he cover letter is an integral part of this analytical report. Paoe 1 of4(6?il,J644tt32 t F.x. (62il 964 583? P120606 18501 E. Gale Avcnua Suirn f :J0 r Ctf"r'crf /ndrislry. CA 91 7-18 t Ph ozEI==oo o\Ri!qoc6ItooltE(!C) ltoo(E(ltloiioc'dco()ocozI2Joril-Eooto0(l , o-o.oo0,Eoof,o.: ( iIta .o )ooo.o(5J3-9E!6o.=s32IFlcoEFa UIb(o2GTooYco,TGeau!.otszotr!tcoIF, g-EUFoza-o()'.oouJI= U' I>tr . 1 ; 5. Eor!uu. . u ., , - clo sJ=f rQ(f ro-9 .\s. (*l}t\ r- - 0oU niTu, o!6JF"9fooaTL)xtI JEoTLcldt3oCogot,GoEozElro UIsFoaoa0Ig,o2Ju& uIbl F i- \ o' 9- }brr !. - ! - oouTqfo3EE stbFoa0oUTg.,o2)0 ctrC(. ) lI ] trccFgCLrCz{Ic llolr . l .5o. nn E oo D zz l I tr t r I o@ l oo l fr E E E ;6 - - = -o l c 6( , ) ( ) o, ,g!o(1 l-oluoutEaoz v,ulotr lr ,Julo tr D t r D (r 3 )Jtr j ul UJ UJ JJ Ou - oo Il J U 1s t Y *t f i y )E y \{ r y \ / ul=oz3oOEztr tr t r t r ep z :3 1 oo o .c E r .o t \ r ( o ri t' - o) Dn n E3 s E H: S U) ( , N L ) (,zJJfi d=ciE. oa Sd A t U3 N I V 1 N O 3 ') xr u l v l l t L.J lF { r - l 3' l d n v s s+ ft $ ir . ' J a- . i f. !a{c fl - v o 3' t d n v s b(\ ,+ -- _ . 1 = f i\ ] -" 1 .] :- " :. . 1 :6:\ J l-a\ sss Esg fF .@- 5 $5 . u s O EV 3 3€ $ H :; 8 8 lf ) > . . .. P5 f . I (! ) , , os J, ;oi z: .t sC' t ll l - l_ I Fl l IRl=It l l= ! t] tnts q. - { q] il E .1 q u OG t e=EE oo 'd 'a . q. a. 1llll -1 l +itl \r 1 -s l sqi l llJ -1joFoa.ot J+{*( \ .( I1ls:d :f , it!aoo It{td&{*t\ -s\c .t r \4>cr, l "io0, lh II rlI:J r{sI1* lI{$atGth>ts iddft raotroa- I$s-E lq$BEo zoF() lrtrzlr JoUIJo.=a I ,' . r lt r. , IJ1 ., f ( ,' \ t.J t/ \ t- { -F " i .J ir -u t-t" \t , li . rN I i_ ,' ' r. i ! JzoUIaoJ at.. 5 ,4 o4r\fl co\I ? r 1$oI *sI ? sT Client: Attn: Project Name: Project No.: Date Received: Matrix: Hansen, Allen & Luce Kate Herbert Bountiful Sanitary Lanrlfill - Tier II 2023 374.03.r00 tzt6t2023 Air TNMOC by EPA METHOD 25C Fixed Gases by EPA METHOD 3C Lab No.:P120606-01 P120606-02 P120605-03 P120606-04 Client Sample I.D.:BSL.I BSL.2 BSL.3 BSL-4 Date/Time Sampled:ll/30D3 9:21 lll30l23ll:28 It/30/23 l4:20 I2llOI8:30 Date/Time Analyzed:l2lt9l23 2l:35 l2l19l23 22:33 l2l19l2323zll 12120123 0:29 QC Batch No.:23r2t9CC8Ar 23t2t9GC8At 23t2l9CC8Al ?3r220CC8Ar Analyst Initials:RC RC RC RC Dilution Factor:3.0 3.4 3.6 3.6 ANALYTE (Units)Result RL Resull RL Result RL Result RL INMOC N2 corrected (nnmv-Cl 630 30 590 3{740 36 700 36 INMOC 02 corrected (oomv-C)630 30 360 3{560 36 680 36 TNMOC uncorrected (opmv-C)600 30 250 34 510 36 630 36 \itrogen (o/o vlvl ND 3.0 43 3.4 23 3.6 5.7 3.6 )xvsen/Argon (Yo vlvl ND I.5 5.7 1.7 ND 1.8 ND t.8 RL = Reporting Limit ND = Not detected at or aboye the RL. TNMOC = Total Non-Methane Organic Compounds ppmv-C = parts per million by volume as carbon TNMOC N2 corected (applicable if N2 < 20%) TNMOC O2 corrected (applicabte if N2 > 207o and 02 < S%) TNMOC uncorrected = not corrcctcd for N2, 02 or moisture NA = Nitrogen/oxygen/moisture correction causes division by zero. Reviewed/Approved By: Thc cot'er lener is an integral pan ofthis analytical report tir TECHNOLOGY Laboratories, lnc L'TAH DEPARTMENT OF ENVIRONh,IENTAL QUAUTY --i.' : " DIVISION OF AIR QUALIT\ .-- Dare ll /-/ L) Operrtions Manager ,rr*o l:l$ r {,'il},fllnCr."iry. t;rl ,r/'JS r Prr iri?f,r !;ri.l-,il"iJr' r I-x liiijrl} ijfl.t-$,S}} 3 of 4 Client: Attn: Project Name: Project No.: Date Received: Matrix: Hansen, Allen & Luce Kate Herbert Bountiful Sanitary Lnndfill - Tier lt2023 374.03.100 tzt6no23 Air TNMOC by EPA METHOD 25C Fixed Gases by EPA METHOD 3C Lab No.:P120606-05 P120606-06 Pr20606-07 Pr2CI606-08 Client Sample I.D.:BSL.5 BSL-6 BSL-7 BSL-8 Date/Time Sampled:l2l1/23 9:50 l2lll23ll:21 l2lll2312:32 l2lt/23 l4:15 Date/Time Analyzed:l2l20l23l:27 l2l20l23 2:25 12120123 3:23 12120/23 4:21 QC Batch No.:23t220CC8At 23r220CC8At 23t220GC8Ar 23r220CC8At Analyst lnitials:RC RC RC RC Dilution Factor:3.5 3.2 3.2 3.1 ANALYTE (Units)Result RL Result RL Result RL Resull RL TNMOC N2 corrected (oomv-C)680 35 650 32 570 11 570 3t [NMOC O2 corrected (ppmv-C)660 35 650 32 570 32 560 3t INMOC uncorrected (oomv-C)59CI JJ 6r0 32 5{0 32 5!tt 3IlliEqgen (vo vltl 7.8 3.5 ND t,ND 3.2 3.5 3.rOxygen/Argon (o/a vlvl ND 1.1 ND 1.6 ND t.6 ND t.5 Rl, = Reporting Limit ND = Not detected at or above the RL. TNMOC = Total Non-Methane Organic Conrpounds ppmv-C = parls per million by volume as rarbon TNMOC N2 corrected (appticable if N2 < 20%) TNMOC 02 corrected (appticabte if N2 > 20% and 02 < S%) TNMOC uncorrected = not correctcd for lrl2,02 or moisture NA = Nitrogen/oxygen/moisture correction causes division by zero. Rcviewed/Approved By: I'hc covcr lettcr is an integral part of this aml!{ical L*porl ,',r*offi tir TECHNOLOGY l.lf r {l;f,,,t'llilrlr;":1r,,'. ilr'j i Mark Johnson Operations Manager il:;')1 fi Cirrr,.4r'r:rrrrrr Sr|lr l-aboratories, lnc >'L Dare /{ /L L)