Loading...
The URL can be used to link to this page
Your browser does not support the video tag.
Home
My WebLink
About
DAQ-2024-005145
1 DAQC-100-24 Site ID 10007 (B4) MEMORANDUM TO: STACK TEST FILE – HOLCIM (US) INC. THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Paul Morris, Environmental Scientist DATE: February 20, 2024 SUBJECT: Source: Rotary Kiln, Clinker Cooler, Crusher Baghouse, and Transfer Baghouse Contact: Clint Badger: 801-829-2122 Location: 6055 East Croyden Road, Morgan, Utah Test Contractor: Mostardi Platt FRS ID#: UT0000004902900001 Permit: 2900001004, November 18, 2021 Date of Last Revision: March 25, 2022 Action Code: TR Subject: Review of Revised Stack Test Reports dated February 2, 2024 On January 18, 2024, the Utah Division of Air Quality (DAQ) received a test report for the Holcim (US) Inc. Main Kiln Stack, Clinker Cooler Stack, Crusher Baghouse, and Transfer Baghouse in Croyden, Utah. A revised test report was received on February 2, 2024. Testing was performed July 18-21, 2023, to demonstrate compliance with emission limits found in Conditions II.B.4.e, II.B.6.h, II.B.6.j, II.B.6.l, and II.B.7.c. The DAQ-calculated test results are: Source Test Date RM/Pollutant DAQ Result Test Result Limit Kiln Stack 7/18/2023 RM 5/PM 0.006* 0.006* 0.07* (Mill on) 0.58 lb/hr 0.58 lb/hr 14 lb/hr 7/18/2023 RM 18/oHAP 2.42§ 2.45§ 12§ 7/18&20/2023 RM 23/D&F 0.002⁑ 0.002⁑ 0.40⁑ Kiln Stack 7/19/2023 RM 5/PM 0.002* 0.002* 0.07* (Mill off) 0.24 lb/hr 0.24 lb/hr 14 lb/hr 7/19/2023 RM 18/oHAP 2.91§ 2.84§ 12§ 7/19&21/2023 RM 23/D&F 0.002⁑ 0.002⁑ 0.2⁑ Clinker Cooler 7/18/2023 RM 5/PM 0.002* 0.002* 0.07* Crusher 7/21/2023 RM 5/PM 0.0001 gr/dscf 0.0001 gr/dscf 0.022 gr/dscf Baghouse Transfer 7/21/2023 RM 5/PM 0.0004 gr/dscf 0.0004 gr/dscf 0.022 gr/dscf Baghouse * lb/ton clinker ⁑ ng/dscm TEQ @ 7% O2 6 , 3 2 § ppmvd @7%O2 DEVIATIONS: Holcim has deviated from permit conditions: II.B.4.e.3, II.B.6.h.1, II.B.6.h.3, II.B.6.j.1, II.B.6.j.3, II.B.6.l.1, II.B.6.l.3, II.B.7.c.1, II.B.7.c.3, and I.S.2.c. The pretest protocol was not received 60 days before testing and the test report was not received within 60 days after testing. In addition, Holcim has not notified the DAQ through a deviation report of the deviations listed above. CONCLUSION: The stack test report appears acceptable. RECOMMENDATION: The sources should be considered operating in compliance with the emission limits evaluated at the time of testing. Issue an NOV for the deviations. HPV: No ATTACHMENTS: Revised test report received February 2, 2024 UDAQ spreadsheets, email Compliance Particulate Emissions Test Report Holcim (US) Inc. Devil’s Slide Cement Manufacturing Facility Rotary Kiln Exhaust and Clinker Cooler Stack Baghouse #211-AF1 Baghouse #291-BFx Morgan, Utah Project No. M232904B Revision 1 July 18 through 21, 2023 Crown Point, IN I Mendota Heights, MN I Denver, CO | Henderson, NV Corporate Headquarters 888 Industrial Drive Elmhurst, Illinois 60126 630-993-2100 Compliance Particulate Emissions Test Report Holcim (US) Inc. Devil’s Slide Cement Manufacturing Facility Rotary Kiln Exhaust and Clinker Cooler Stack Morgan, Utah July 18 through 21, 2023 Report Submittal Date February 2, 2024 © Copyright 2024 All rights reserved in Mostardi Platt Project No. M232904B Rev. 1 TABLE OF CONTENTS 1.0 EXECUTIVE SUMMARY ............................................................................................................................... 1 1.1 Kiln PM SSOL Test Results .............................................................................................................. 2 1.2 Kiln PM SSOL Test Results .............................................................................................................. 2 1.3 Baghouse PM Test Results .............................................................................................................. 2 1.4 oHAP Test Results ........................................................................................................................... 2 1.5 D/F Test Results ............................................................................................................................... 2 1.6 Revisions .......................................................................................................................................... 2 2.0 TEST METHODOLOGY ................................................................................................................................ 3 Method 1 Sample and Velocity Traverse Determination ........................................................................ 3 Method 2 Volumetric Flow Rate Determination ...................................................................................... 4 Method 3A Oxygen (O2)/Carbon Dioxide (CO2) Determination .............................................................. 4 Method 5 Filterable Particulate Matter (FPM) Determination ................................................................. 4 Method 18 oHAP Determination ............................................................................................................. 5 Method 23 Dioxin and Furan Determination ........................................................................................... 5 Method 320 Fourier Transform Infrared (FTIR) Detector Formaldehyde and Acetaldehyde Determination ......................................................................................................................................... 6 3.0 TEST RESULT SUMMARIES ....................................................................................................................... 8 4.0 CERTIFICATION.......................................................................................................................................... 17 APPENDICES Appendix A - Test Section Diagram ..................................................................................................... 19 Appendix B - Sample Train Diagrams .................................................................................................. 24 Appendix C - Calculation Nomenclature and Formulas ....................................................................... 31 Appendix D - Laboratory Analysis Data ............................................................................................... 50 Appendix E - Reference Method Test Data ........................................................................................ 411 Appendix F - Plant Operating Data..................................................................................................... 480 Appendix G - Field Data Sheets ......................................................................................................... 527 Appendix H - Calibration and Response Time Data ........................................................................... 572 Appendix I - Calibration Gas Cylinder Data ........................................................................................ 628 Appendix J – FTIR Quality Assurance Data ....................................................................................... 633 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx i ©Mostardi Platt 1.0 EXECUTIVE SUMMARY Mostardi Platt conducted a compliance particulate test program for Holcim (US) Inc. at the Devil’s Slide Cement Manufacturing Facility in Morgan, Utah, on the Clinker Cooler Stack (CC-1) and Rotary Kiln Exhaust (K-1) from July 19 through 21, 2022. This report summarizes the results of the test program and test methods. The test locations, test dates, and test parameter are summarized below. TEST INFORMATION Test Locations Test Dates Test Parameter K-1 July 18 and 19, 2023 Filterable Particulate Matter (FPM), and organic hazardous air pollutants (oHAP) July 18-21, 2023 Dioxin/Furan (D/F) CC-1 July 18, 2023 FPM Crusher Baghouse July 21, 2023 Transfer Baghouse July 21, 2023 The purpose of the test program was to demonstrate compliance with Title 40, Code of Federal Regulations, Part 60 (40CFR60), and 40CFR63, Subpart LLL “National Emission Standards for Hazardous Air Pollutants (NESHAP) for the Portland Cement Manufacturing Industry and Standards of Performance for Portland Cement Plants.” PM test results were also used to determine the Site-Specific Operating Limit (SSOL). In addition to the test results, values recorded by the plant Continuous Parametric Monitoring System (CPMS) were utilized as well as a zero-calibration value performed prior to testing. To perform the zero-calibration the sender diode is switched off for zero-point control so that no signal is received. The digital equivalent to the instrument zero output for both analyzers was equal to zero. CPMS information for each location is as follows: Location Make Model Serial Measurement Principal Range CC-1 Sick SP 100 10418596 Scattered Light 0-50 mg/m3 K-1 Sick SP 100 10418597 Scattered Light 0-45 mg/m3 The SSOL was calculated per the equations from 40CFR63 Subpart LLL, § 63.1349(b)(1)(iii)(B). Complete SSOL calculations can be found in Appendix C. A summary of the results is provided below. Detailed results follow the narrative portion of this report. Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 1 of 640 ©Mostardi Platt 1.1 Kiln PM SSOL Test Results Location Date Parameter Emission Rate 1 Emission Limit SSOL K-1 7/18/23 and 7/19/23 FPM 0.006 lb/ton 0.13 lb/ton 15.57 mg/m3 1.3 Kiln PM SSOL Test Results Location Date Parameter Emission Rate Emission Limit SSOL CC-1 7/18/23 FPM 0.002 lb/ton 0.07 lb/ton 0.27 mg/m3 1.4 Baghouse PM Test Results Location Date Parameter Emission Rate Emission Limit Crusher Baghouse 7/18/23 FPM 0.0001 gr/dscf 0.022gr/dscf Transfer Baghouse 7/21/23 0.0004 gr/dscf 0.022gr/dscf 1.5 oHAP Test Results Test Location Date Parameter Emission Rate 2 Emission Limit SSOL K-1 7/18/23 oHAP 2.47 ppmvd @7% O2 ≤12 ppmvd @7% O2 24.14 ppmvw 1.6 D/F Test Results Location Date Parameter Emission Results Emission Limits Temperature Limit K-1 Mill On 7/18/23 & 7/20/23 D/F ≤0.002 ng/dscm TEQ @7% O2 0.4 ng/dscm TEQ @ 7% O2 Kiln Inlet 188.6 °C Alkali Bypass 199.1 °C K-1 Mill Off 7/19/23 and 7/21/23 ≤0.0018ng/dscm TEQ @7% O2 0.2 ng/dscm TEQ @ 7% O2 Kiln Inlet 231.7 °C Alkali Bypass 201.6 °C 1.7 Revisions Additional supporting laboratory data have been added to Appendix D; Pages 51-57 to show raw pg catch for D/F compounds and the TEQ conversions. 1 Kiln Stack emission reported as the time-weighted average during “raw mill on” and “raw mill off” conditions. 2 Kiln Stack emission reported as the time-weighted average during “raw mill on” and “raw mill off” conditions. Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 2 of 640 ©Mostardi Platt The identifications of the individuals associated with the test program are summarized below. TEST PERSONNEL INFORMATION Location Address Contact Test Supervisor Holcim (US) Inc. 15900 Dooley Road Addison, TX 75001 Mark Miller Director of Land and Environment (719) 285-5762 mark.miller@holcim.com Facility Contact Holcim (US) Inc. 6055 East Croydon Road Morgan, UT 84050 Clinton Badger Area Manager, Environment and Public Affairs-Devil Slide (801)-829-2122 clinton.badger@holcim.com Testing Company Supervisor Mostardi Platt 888 Industrial Drive Elmhurst, Illinois 60126 Richard J. Sollars II Regional Manager (630) 993-2100 (phone) rsollars@mp-mail.com The test crew consisted of R. Bocanegra, B. Alba, A. Sorce, K. Jones, and R. Sollars of Mostardi Platt. 2.0 TEST METHODOLOGY Emission testing was conducted following the United States Environmental Protection Agency (USEPA) methods specified in 40CFR60, Appendix A in addition the Mostardi Platt Quality Manual. Schematics of the test section diagrams and sampling trains used are included in Appendix A and B respectively. Calculation nomenclature are included in Appendix C. Laboratory analysis for each test run are included in Appendix D. CEM data and process data as provided by Holcim (US) Inc. are also included in Appendix F. The following methodologies were used during the test program: Method 1 Sample and Velocity Traverse Determination Test measurement points were selected in accordance with USEPA Method 1, 40CFR60, Appendix A. The characteristics of the measurement location are summarized below. Test Location Duct Diameter Upstream Distance Downstream Distance Test Parameters Number of Sampling Points CC-1 71 Inches 2.1 Diameters 9.0 Diameters PM 12 K-1 131.5 Inches 2.5 Diameters 10.9 Diameters PM 12 Primary Crusher BH 2.2 Inches 8.7 Diameters 33 Diameters PM 12 Transfer BH 12.25 Inches 7.3 Diameters 19.6 Diameters PM 12 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 3 of 640 ©Mostardi Platt Method 2 Volumetric Flow Rate Determination Gas velocity was measured following USEPA Method 2, 40CFR60, Appendix A, for purposes of calculating stack gas volumetric flow rate and emission rates on a lb/hr basis. A 5 foot and 9-foot- long S-type pitot tube, 0-10” differential pressure gauge, and K-type thermocouple and temperature readout were used to determine gas velocity at each sample point. CC-1 stack gas O2 and CO2 concentrations were determined per section 8.6 of USEPA Method 2 – “for processes emitting essentially air, an analysis need not be conducted; use a dry molecular weight of 29.0” – the oxygen and carbon dioxide concentrations will be assumed to be ambient. All of the equipment used was calibrated in accordance with the specifications of the Method. Copies of field data sheets are included in Appendix G. Calibration data are presented in Appendix H. This testing met the performance specifications as outlined in the Method. Method 3A Oxygen (O2)/Carbon Dioxide (CO2) Determination K-1 stack gas O2 and CO2 concentrations were determined in accordance with USEPA Method 3A. An ECOM or Servomex analyzer was used to determine the O2 and CO2 concentrations in the manner specified in the Method. The O2 instrument operates in the nominal range of 0% to 25% with the specific range determined by the high-level calibration gas. The CO2 instrument operates in the nominal range of 0% to 20% with the specific range determined by the high-level calibration gas. High and mid-range calibrations were performed using USEPA Protocol gas. Zero nitrogen (a low ppm pollutant in balance nitrogen calibration gases) was introduced during other instrument calibrations to check instrument zero. Zero and mid-range calibrations were performed using USEPA Protocol gas after each test run. Copies of the gas cylinder certifications are found in Appendix I. This testing met the performance specifications as outlined in the Method. Method 5 Filterable Particulate Matter (FPM) Determination Stack gas filterable PM concentrations and emission rates were determined in accordance with Method 5. The probe and filter housing were maintained at a temperature of 248oF +/- 25oF. An Environmental Supply Company, Inc. sampling train was used to sample stack gas at an isokinetic rate. Four impingers were utilized, the first two each containing 100ml of deionized water, the third was empty, and the fourth contained approximately 200 grams of silica gel. The impingers were weighed prior to and after each test run in order to determine moisture content of the stack gas. The total sample time was 60 minutes, with twelve (12) sample points being utilized (3 points per port, 4 total ports). A minimum of 1 dscm was sampled for each run. PM in the sample probe was recovered utilizing acetone; a minimum of three passes of the probe brush through the entire probe was performed, followed by a visual inspection of the acetone exiting the probe. If the acetone solution exiting the probe was clear, the wash was considered complete, if not, another pass of the brush through the probe was made and inspected until the solution was clear. The nozzle was then removed from the probe and cleaned in a similar manner, utilizing an appropriately sized nozzle brush. The probe wash and filter catch were analyzed by Mostardi Platt personnel. Laboratory analysis data are found in Appendix D. Calibration data are presented in Appendix H. Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 4 of 640 ©Mostardi Platt Method 18 oHAP Determination Stack gas oHAP concentrations and emission rates were determined in accordance with Method 18. Paired stainless-steel probes with teflon lines were used to draw sample at a rate of 0.5 lpm through a knockout impinger to remove condensate prior to oHAP being collected on a two section XAD trap followed by a two-section charcoal trap. Silica gel was placed after the charcoal trap (immediately prior to the dry gas meter) to remove any remaining moisture prior to reaching the dry gas meter. One sample train for each run was unspiked, designated the “A” traps, while the 2nd sample train, designated the “B” traps, were spiked with approximately 50ug spikes of each benzene, m- Xylene, Naphthalene, o-Xylene, p-Xylene, Styrene, toluene, and ethylbenzene. The table below shows approximate ppm values for each parameter, based upon the above spike level, 24.056 is the molar volume at 68F liters/mole, and molecular weight of each compound: SPIKED CONCENTRATIONS Parameter Molecular Weight ppmvd Benzene 78.11 0.22 m-Xylene 106.16 ≤ 0.01 Naphthalene 128.17 ≤ 0.01 o-Xylene 106.16 ≤ 0.01 p-Xylene 106.16 ≤ 0.01 Styrene 104.15 ≤ 0.01 Toluene 92.14 ≤ 0.03 Condensate collected in the knockout impinger was recovered and collected in nominal 15 mL vials. Vials were filled with Type I deionized water to remove any headspace in order to prevent any volatilization of compounds prior to analysis. XAD “B” trap sections were spiked before field use. The final section of the charcoal trap was analyzed to demonstrate breakthrough did not occur during testing. The water fraction and breakthrough fraction were analyzed and are reported in the detailed laboratory report in Appendix D. Method 23 Dioxin and Furan Determination Stack gas dioxin and furan concentrations and emission rates were determined in accordance with Method 23, 40 CFR, Part 60, Appendix A. An Environmental Supply Company sampling train was used to sample for concentrations of dioxins and furans, in the manner specified in the Method. After recovery, samples were analyzed by Bureau Veritas Laboratories following the procedures specified in the Method. Laboratory analysis data are found in Appendix E. All of the equipment used was calibrated in accordance with the specifications of the Method. Calibration data are presented in Appendix H. Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 5 of 640 ©Mostardi Platt Method 320 Fourier Transform Infrared (FTIR) Detector Formaldehyde and Acetaldehyde Determination FTIR data was collected using an MKS MultiGas 2030 FTIR spectrometer. The FTIR was equipped with a temperature-controlled, 5.11-meter multi-pass gas cell maintained at 191°C. Gas flows and sampling system pressures were monitored using a rotameter and pressure transducer. All data was collected at 0.5 cm-1 resolution. Each spectrum was derived from the coaddition of 64 scans, with a new data point generated approximately every one minute. Analyzer data for each run is presented in Appendix E. QA/QC procedures followed US EPA Method 320. See below for QA/QC procedure details and list of calibration gas standards. All calibration gases were introduced to the analyzer and the sampling system using an instrument grade stainless steel rotameter. All QA/QC procedures were within the acceptance criteria allowance of the applicable EPA methodology. See Appendix J for FTIR QA/QC Data. FTIR QA/QC Procedures QA/QC Specification Purpose Calibration Gas Analyte Delivery Frequency Acceptance Criteria Result M320: Zero Verify that the FTIR is free of contaminants & zero the FTIR Nitrogen (zero) Direct to FTIR pre/post test < MDL or Noise Pass M320: Calibration Transfer Standard (CTS) Direct Verify FTIR stability, confirm optical path length Ethylene Direct to FTIR pretest +/- 5% cert. value Pass M320: CTS Response Verify system stability, recovery, response time Ethylene Sampling System Daily, pre/post test +/- 5% of Direct Measurement Pass M320: Zero Response Verify system is free of contaminants, system bias Nitrogen (zero) Sampling System pretest Bias correct data Pass M320: Analyte Spike Verify system ability to deliver and quantify analyte of interest in the presence of other effluent gases Acetaldehyde/ Methanol Dynamic Addition to Sampling System, 1:10 effluent Throughout testing – daily +/- 30% theoretical recovery Pass Note: The determined concentrations from direct analyses were used in all system/spike recovery calculations. Analyte Spiking Acetaldehyde spiking was performed prior to testing to verify the ability of the sampling system to quantitatively deliver a sample containing acetaldehyde and formaldehyde from the base of the probe to the FTIR. Analyte spiking assures the ability of the FTIR sampling system to recover acid gases in the presence of effluent gas. As part of the spiking procedure, samples were measured to determine native acetaldehyde concentrations to be used in the spike recovery calculations. The analyte spiking gases contained a low concentration of sulfur hexafluoride (SF6). The determined SF6 concentration in the spiked sample was used to calculate the dilution factor of the spike and thus used to calculate the concentration of the spiked acetaldehyde. The spike target dilution ratio was 1:10 or less. Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 6 of 640 ©Mostardi Platt The following equation illustrates the percent recovery calculation. 𝐷𝐷𝐷𝐷 =𝑆𝑆𝑆𝑆6(𝑠𝑠𝑠𝑠𝑠𝑠)𝑆𝑆𝑆𝑆6(𝑑𝑑𝑑𝑑𝑑𝑑𝑑𝑑𝑑𝑑𝑑𝑑) (Sec. 9.2.3 (3) USEPA Method 320) 𝐶𝐶𝐶𝐶 =𝐷𝐷𝐷𝐷∗𝐶𝐶𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆(𝑑𝑑𝑆𝑆𝑑𝑑)+ 𝑈𝑈𝑈𝑈𝑈𝑈𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆(1 −𝐷𝐷𝐷𝐷) (Sec. 9.2.3 (4) USEPA Method 320) DF = Dilution factor of the spike gas SF6(dir) = SF6 concentration measured directly in undiluted spike gas SF6(spk) = Diluted SF6 concentration measured in a spiked sample Spikedir = Concentration of the analyte in the spike standard measure by the FTIR directly CS = Expected concentration of the spiked samples Unspike = Native concentration of analytes in unspiked samples Post Collection Data Validation As part of the data validation procedure, reference spectra are manually fit to that of the sample spectra and a concentration is determined. The reference spectra are scaled to match the peak amplitude of the sample, thus providing a scale factor. The scale factor multiplied by the reference spectra concentration is used to determine the concentration value for the sample spectra. Sample pressure and temperature corrections are then applied to compute the final sample concentration. The manually calculated results are then compared with the software-generated results. The data is then validated if the two concentrations are within ± 20% agreement. If there is a difference greater than ± 20% the spectra are reviewed for possible spectra interferences or any other possible causes leading to incorrectly quantified data. Detection Limit The detection limit of each analyte was calculated following Annex A2 of ASTM D6348-12 procedure using spectra that contained similar amounts of moisture. FTIR DETECTION LIMITS Analyte Detection Limit (ppmv wet) Detection Limit (%v) Detection Limit (%v wet) Formaldehyde 0.2 − − Acetaldehyde 0.5 − − Water − 0.1 − Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 7 of 640 ©Mostardi Platt 3.0 TEST RESULT SUMMARIES Client: Facility: Test Location: Test Method: Normal Normal Normal 7/21/23 7/21/23 7/21/23 7:05 8:30 9:55 8:19 9:44 11:09 Run 1 Run 2 Run 3 Average 62.0 63.0 66.0 63.7 1.2% 1.3% 1.3% 1.3% 24.95 24.95 24.95 24.95 87.59 87.551 87.637 87.593 45.462 45.032 45.438 45.311 16,202 16,048 16,193 16,148 13,508 13,342 13,385 13,412 13,666 13,512 13,555 13,578 102.1 103.3 103.1 102.8 0.00040 0.00040 0.00040 0.00040 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 Stack Conditions End Time Isokinetic Variance Flue Gas Moisture, percent by volume grains/dscf Gas Volumetric Flow Rate, scfm grams collected Date Start Time Average Gas Temperature, °F Gas Volumetric Flow Rate, acfm Gas Volumetric Flow Rate, dscfm Average Flue Pressure, in. Hg Gas Sample Volume, dscf Filterable Particulate Matter (Method 5) grains/acf Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Primary Crusher Baghouse Average Gas Velocity, ft/sec Source Condition 5 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 8 of 640 ©Mostardi Platt Client: Facility: Test Location: Test Method: Normal Normal Normal 7/21/23 7/21/23 7/21/23 7:05 8:30 9:55 8:19 9:44 11:09 Run 1 Run 2 Run 3 Average 60.5 69.1 73.1 67.6 1.4% 1.5% 1.5% 1.5% 25.19 25.19 25.19 25.19 70.215 69.695 69.387 69.766 48.993 49.406 49.590 49.330 2,406 2,426 2,435 2,422 2,026 2,008 2,001 2,012 2,055 2,039 2,031 2,042 102.1 102.3 102.2 102.2 0.00449 0.00040 0.00040 0.00176 0.0008 0.0001 0.0001 0.0003 0.0010 0.0001 0.0001 0.0004 Stack Conditions End Time Isokinetic Variance Flue Gas Moisture, percent by volume grains/dscf Gas Volumetric Flow Rate, scfm grams collected Date Start Time Average Gas Temperature, °F Gas Volumetric Flow Rate, acfm Gas Volumetric Flow Rate, dscfm Average Flue Pressure, in. Hg Gas Sample Volume, dscf Filterable Particulate Matter (Method 5) grains/acf Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Transfer Baghouse Average Gas Velocity, ft/sec Source Condition 5 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 9 of 640 ©Mostardi Platt Client: Facility: Test Location: Test Method: Mill On Mill On Mill On 7/18/23 7/18/23 7/18/23 8:55 10:30 11:45 10:01 11:36 12:51 Run 1 Run 2 Run 3 Average 267.6 265.8 280.6 271.3 10.5% 11.8% 12.5% 11.6% 24.61 24.61 24.61 24.61 40.874 38.656 38.045 39.192 57.887 57.084 57.104 57.358 327,576 323,032 323,146 324,585 175,006 170,480 165,886 170,457 195,555 193,330 189,524 192,803 17.2 17.4 17.1 17.2 10.9 10.9 11.1 11.0 106.1 103.0 104.1 104.4 ton/hr 100.6 100.6 100.6 100.6 0.00208 0.00040 0.00059 0.00102 0.0004 0.0001 0.0001 0.0002 0.0008 0.0002 0.0002 0.0004 1.178 0.233 0.340 0.584 0.012 0.002 0.003 0.006 Stack Conditions End Time Isokinetic Variance Flue Gas Moisture, percent by volume grains/dscf Average %O2 by volume, dry basis Gas Volumetric Flow Rate, scfm Average %CO2 by volume, dry basis grams collected lb/ton of clinker Date Start Time Average Gas Temperature, °F Gas Volumetric Flow Rate, acfm Gas Volumetric Flow Rate, dscfm Average Flue Pressure, in. Hg Gas Sample Volume, dscf Filterable Particulate Matter (Method 5) lb/hr grains/acf Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) Average Gas Velocity, ft/sec Source Condition 5 Clinker Production Rate, Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 10 of 640 ©Mostardi Platt Client: Facility: Test Location: Test Method: Mill Off Mill Off Mill Off 7/19/23 7/19/23 7/19/23 9:45 11:10 13:05 10:51 12:16 14:11 Run 1 Run 2 Run 3 Average 339.6 352.7 368.0 353.4 9.9% 9.2% 9.1% 9.4% 24.88 24.88 24.88 24.88 35.991 36.239 35.811 36.014 57.920 58.260 58.481 58.220 327,762 329,686 330,936 329,461 162,249 161,802 159,480 161,177 180,000 178,142 175,506 177,883 18.7 18.7 19.9 19.1 10.4 10.4 10.1 10.3 100.7 101.7 102.0 101.5 ton/hr 100.6 100.6 100.6 100.6 0.00040 0.00040 0.00040 0.00040 0.0001 0.0001 0.0001 0.0001 0.0002 0.0002 0.0002 0.0002 0.238 0.236 0.236 0.237 0.002 0.002 0.002 0.002 Stack Conditions End Time Isokinetic Variance Flue Gas Moisture, percent by volume grains/dscf Average %O2 by volume, dry basis Gas Volumetric Flow Rate, scfm Average %CO2 by volume, dry basis grams collected lb/ton of clinker Date Start Time Average Gas Temperature, °F Gas Volumetric Flow Rate, acfm Gas Volumetric Flow Rate, dscfm Average Flue Pressure, in. Hg Gas Sample Volume, dscf Filterable Particulate Matter (Method 5) lb/hr grains/acf Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) Average Gas Velocity, ft/sec Source Condition 5 Clinker Production Rate, Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 11 of 640 ©Mostardi Platt Client: Facility: Test Location: Test Method: Normal Normal Normal 7/18/23 7/18/23 7/18/23 2:10 3:25 14:40 3:12 4:27 15:42 Run 1 Run 2 Run 3 Average 226.0 215.4 209.4 216.9 1.4% 2.3% 1.8% 1.8% 24.46 24.46 24.46 24.46 45.03 43.72 43.626 44.125 57.788 55.402 54.753 55.981 95,330 91,394 90,325 92,350 59,112 57,038 57,217 57,789 59,977 58,402 58,236 58,872 101.7 102.3 101.7 101.9 ton/hr 100.6 100.6 100.6 100.6 0.00197 0.00044 0.00040 0.00094 0.0004 0.0001 0.0001 0.0002 0.0007 0.0002 0.0001 0.0003 0.342 0.076 0.069 0.162 0.003 0.001 0.001 0.002 Stack Conditions End Time Isokinetic Variance Flue Gas Moisture, percent by volume grains/dscf Gas Volumetric Flow Rate, scfm grams collected lb/ton of clinker Date Start Time Average Gas Temperature, °F Gas Volumetric Flow Rate, acfm Gas Volumetric Flow Rate, dscfm Average Flue Pressure, in. Hg Gas Sample Volume, dscf Filterable Particulate Matter (Method 5) lb/hr grains/acf Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Clinker Cooler Stack (CC-1) Average Gas Velocity, ft/sec Source Condition 5 Clinker Production Rate, Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 12 of 640 ©Mostardi Platt Client: Facility: Test Location: Test Method: Mill On Mill On Mill On Mill On 7/18/23 7/18/23 7/18/23 7/20/23 9:10 12:35 15:55 10:00 12:16 15:41 19:01 13:06 Run 1 Run 2 Run 3 Run 4 Average 270.3 278.7 275.8 282.7 279.1 11.0% 7.0% 10.9% 10.6% 9.5% 24.61 24.61 24.61 24.92 24.71 104.158 103.826 103.897 103.519 103.747 58.048 57.914 58.349 53.361 56.541 328,484 327,726 330,192 301,964 319,961 173,926 179,185 173,749 159,840 170,925 195,374 192,695 194,921 178,822 188,813 17.6 18.2 17.0 17.7 17.6 10.6 11.1 11.2 10.9 11.1 93.6 90.6 93.5 101.2 95.1 345.6 381.2 377.8 381.1 371.4 174.2 194.0 192.1 194.0 188.6 ≤0.02 ≤0.01 ≤0.02 ≤0.02 ≤0.02 ≤0.001 ≤0.002 ≤0.001 ≤0.001 ≤0.001 ng/dscm TEQ @ 7% O2 Dry ≤0.002 ≤0.002 ≤0.002 ≤0.002 ≤0.002 ≤2.01E-08 ≤1.05E-08 ≤2.13E-08 ≤2.07E-08 ≤1.75E-08 lb/hr ≤2.87E-10 ≤3.42E-10 ≤2.88E-10 ≤2.66E-10 ≤2.99E-10 *Run 1 has been exluded from the averages due to low inlet temperature. PCDD/PCDF Emissions ng/dscm Gas Volumetric Flow Rate, dscfm ng/dscm TEQ End Time Stack Conditions Average %CO2 by volume, dry basis Average %O2 by volume, dry basis Gas Volumetric Flow Rate, scfm Flue Gas Moisture, percent by volume Gas Sample Volume, dscf Average Gas Velocity, ft/sec Gas Volumetric Flow Rate, acfm mg/nm3 @ 10% O2 Average Flue Pressure, in. Hg Isokinetic Variance Baghouse Inlet Temperature, °F Baghouse Inlet Temperature, °C Start Time Average Gas Temperature, °F Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) 23 Source Condition Date Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 13 of 640 ©Mostardi Platt Client: Facility: Test Location: Test Method: Mill Off Mill Off Mill Off 7/19/23 7/19/23 7/21/23 9:45 13:05 13:30 12:51 16:11 16:36 Run 1 Run 2 Run 3 Average 346.3 368.9 364.5 359.9 8.8%9.2% 8.9% 9.0% 24.88 24.88 25.01 24.92 131.071 130.074 130.780 130.642 57.994 58.731 58.416 58.380 328,182 332,353 330,568 330,368 163,038 159,960 161,254 161,417 178,722 176,074 176,980 177,259 18.7 19.9 19.1 19.2 10.4 10.1 10.1 10.2 101.4 102.6 102.3 102.1 447.8 448.1 451.4 449.1 231.0 231.2 233.0 231.7 ≤0.19 ≤0.28 ≤0.16 ≤0.21 ≤0.001 ≤0.001 ≤0.002 ≤0.001 ng/dscm TEQ @ 7% O2 Dry ≤0.0016 ≤0.0015 ≤0.0023 ≤0.0018 ≤1.87E-07 ≤2.68E-07 ≤1.53E-07 ≤2.03E-07 lb/hr ≤1.97E-10 ≤1.95E-10 ≤2.94E-10 ≤2.29E-10 PCDD/PCDF Emissions ng/dscm Gas Sample Volume, dscf Average Gas Velocity, ft/sec Gas Volumetric Flow Rate, acfm Gas Volumetric Flow Rate, dscfm Baghouse Inlet Temperature, °F ng/dscm TEQ Start Time Average Gas Temperature, °F Average Flue Pressure, in. Hg Isokinetic Variance End Time Stack Conditions Average %CO2 by volume, dry basis Average %O2 by volume, dry basis Gas Volumetric Flow Rate, scfm Flue Gas Moisture, percent by volume mg/nm3 @ 10% O2 Baghouse Inlet Temperature, °C Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) 23 Source Condition Date Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 14 of 640 ©Mostardi Platt Benzene ppmvd @ 7% O2 0.25 0.20 0.20 0.22 m-Xylene ppmvd @ 7% O2 ≤0.01 ≤0.01 ≤0.01 ≤0.01 Naphthalene ppmvd @ 7% O2 ≤0.01 ≤0.01 ≤0.01 ≤0.01 o-Xylene ppmvd @ 7% O2 ≤0.01 ≤0.01 ≤0.01 ≤0.01 p-Xylene ppmvd @ 7% O2 ≤0.01 ≤0.01 ≤0.01 ≤0.01 Styrene ppmvd @ 7% O2 ≤0.01 ≤0.01 ≤0.01 ≤0.01 Toluene ppmvd @ 7% O2 ≤0.06 ≤0.01 ≤0.01 ≤0.03 Formaldehyde ppmvd @ 7% O2 1.63 1.64 1.64 1.64 Acetaldehyde ppmvd @ 7% O2 0.16 0.52 0.88 0.52 Total oHAP ppmvd @ 7% O2 ≤2.15 ≤2.42 ≤2.78 ≤2.45 Mill On Organic HAP Results Summary Holcim Devil's Slide Kiln Stack Run No. 1 2 3 Average Date 7/18/2023 7/18/2023 7/18/2023 Start Time 8:55 10:30 11:45 End Time 9:54 11:29 12:45 O2, % (dry)10.60 10.50 10.70 10.60 Moisture, %11.59 11.43 11.29 11.44 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 15 of 640 ©Mostardi Platt Benzene ppmvd @ 7% O2 0.18 0.21 0.18 0.19 m-Xylene ppmvd @ 7% O2 ≤0.01 ≤0.01 ≤0.01 ≤0.01 Naphthalene ppmvd @ 7% O2 ≤0.01 ≤0.01 ≤0.01 ≤0.01 o-Xylene ppmvd @ 7% O2 ≤0.01 ≤0.01 ≤0.01 ≤0.01 p-Xylene ppmvd @ 7% O2 ≤0.01 ≤0.01 ≤0.01 ≤0.01 Styrene ppmvd @ 7% O2 ≤0.01 ≤0.01 ≤0.01 ≤0.01 Toluene ppmvd @ 7% O2 ≤0.01 ≤0.01 ≤0.10 ≤0.04 Formaldehyde ppmvd @ 7% O2 1.53 1.50 1.44 1.49 Acetaldehyde ppmvd @ 7% O2 0.72 1.40 1.12 1.08 Total oHAP ppmvd @ 7% O2 ≤2.48 ≤3.16 ≤2.89 ≤2.84 Holcim Devil's Slide Kiln Stack Organic HAP Results Summary Mill Off Run No. 1 2 3 Average Date 7/19/2023 7/19/2023 7/19/2023 Start Time 9:45 11:10 13:05 End Time 10:45 12:10 14:05 O2, % (dry)10.80 10.00 10.20 10.33 Moisture, %9.51 9.92 9.76 9.73 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 16 of 640 ©Mostardi Platt 4.0 CERTIFICATION Mostardi Platt is pleased to have been of service to Holcim (US) Inc. If you have any questions regarding this test report, please do not hesitate to contact us at 630-993-2100. As the program manager, I hereby certify that this test report represents a true and accurate summary of emissions test results and the methodologies employed to obtain those results. The test program was performed in accordance with the test methods and the Mostardi Platt Quality Manual, as applicable. MOSTARDI PLATT ______________________________________ Project Manager Richard J. Sollars II ______________________________________ Quality Assurance Eric Ehlers Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 17 of 640 ©Mostardi Platt APPENDICES Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 18 of 640 ©Mostardi Platt Appendix A - Test Section Diagram Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 19 of 640 ©Mostardi Platt EQUAL AREA TRAVERSE FOR ROUND DUCTS 3 2 1 3 2 1 2 3 1 2 3 3 2 1 4 Disturbance Measurement Site Length >2 Dia. Length >8 Dia.Disturbance1 Job: Holcim (US) Inc. Devil’s Slide Cement Manufacturing Facility Morgan, UT Date: July 18, 2023 Test Location: CC-1 Duct Diameter: 71.0 Inches Duct Area: 27.49 Square Feet No. Points Across Diameter: 6 No. of Ports: 4 Port Length: 4.13 Inches Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 20 of 640 ©Mostardi Platt EQUAL AREA TRAVERSE FOR ROUND DUCTS 3 2 1 3 2 1 2 3 1 2 3 3 2 1 4 Disturbance Measurement Site Length >2 Dia. Length >8 Dia.Disturbance1 Job: Holcim (US) Inc. Devil’s Slide Cement Manufacturing Facility Morgan, UT Date: July 18 through 21, 2023 Test Location: K-1 Duct Diameter: 131.5 Inches Duct Area: 94.31 Square Feet No. Points Across Diameter: 6 No. of Ports: 4 Port Length: 12 Inches Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 21 of 640 ©Mostardi Platt 2 2 2 o o o 2oooooo22 o o o Client: Facility:1 2 Test Location:3 4 Date:5 6 Diameter (Feet): Port Length (In): Ports Sampled: Points/Port: 29.60 70.40 85.40 95.60 Point Markings 1.45 4.82 9.77 23.23 28.18 31.55 4.40 14.60 From inside wall (in.) EQUAL AREA TRAVERSE FOR ROUND DUCTS % of Diameter Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Primary Crusher Baghouse 07/21/23 2.75 4.00 2 6 2.2 Dia. 8.7 Dia. Disturbance Disturbance Measurement Site Page 1 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 22 of 640 ©Mostardi Platt 2 2 2 o o o 2oooooo22 o o o Client: Facility:1 2 Test Location:3 4 Date:5 6 Diameter (Feet): Port Length (In): Ports Sampled: Points/Port:6 From inside wall (in.) EQUAL AREA TRAVERSE FOR ROUND DUCTS % of Diameter Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Transfer Baghouse 07/21/23 1.02 4.00 2 Point Markings 0.54 1.79 3.63 8.62 10.46 11.71 4.40 14.60 29.60 70.40 85.40 95.60 7.34 Dia. 19.59 Disturbance Disturbance Measurement Site Page 1 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 23 of 640 ©Mostardi Platt Appendix B - Sample Train Diagrams Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 24 of 640 ©Mostardi Platt ATD-001 USEPA Method 2 Rev. 1.1 8/17/2015 USEPA Method 2 – Type S Pitot Tube Manometer Assembly 1.90-2.54 cm (0.75 -1.0 in.)* 7.62 cm (3 in.)* Temperature Sensor Manometer Leak-Free Connections *Suggested (Interference Free) Pitot tube/ Thermocouple Spacing Ga s F l o w Flexible Tubing (0.25 in.) Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 25 of 640 ©Mostardi Platt USEPA Method 3A - Integrated Oxygen/Carbon Dioxide Sample Train Diagram Utilizing ECOM To Measure from Sample Exhaust Vacuum Line Air Tight Pump Dry Gas Vacuum Gauge Calibration ECOM Analyze Sample Gas From Impinger Train Sample Exhaust Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 26 of 640 ©Mostardi Platt USEPA Method 5- Particulate Matter Sample Train Diagram Nozzle S-Type Pitot Heated Probe Sheath Filter Holder Oven Box Temperature Sensors Ice Bath Silica Gel Empty 100 mL each DI H2O Temperature Sensors Manometer/Orifice Incline Gauge Vacuum Gauge Vacuum Line Dry Gas Meter Air Tight Pump Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 27 of 640 ©Mostardi Platt USEPA Method 18 – Midget Impinger and Adsorbent Tube Sampling (Top View) (Side View) Teflon Probe Line Midget Impinger w/15ml DI H2O Ice Bath Adsorbent Tubes Spiked Tubes Unspiked Tubes B-Side Train A-Side Train Vacuum Gauge Flow Totalizer Flow Control Valves Flow Meter Teflon Unheated Sample Lines Control Box with Vacuum Pumps Spiked Impinger Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 28 of 640 ©Mostardi Platt Method 23 - Determination of Polychlorinated Dibenzo-p-dioxins and Polychlorinated Dibenzofurans from Municipal Waste Combustors Glass or Quartz Nozzle Teflon Coated Union Heated Probe Sheath Glass or Quartz Liner S-Type Pitot Filter Holder with M23 Prepared Filter Temperature Sensor Temperature Sensors To “S” Bend From Filter Holder Condenser Coil Oven Box “S” Bend Recirculation Pump XAD-2 Resin Trap Empty Large Knockout Impinger 100 mL each HPLC H2O Empty Impinger Silica Ice Bath Vacuum Line Temperature Sensors Dry Gas Meter Manometer/Orifice Incline Gauge Vacuum Gauge Air Tight Pump Ice Water Should Remain Below Trap Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 29 of 640 ©Mostardi Platt USEPA Method 320 – Ammonia Emissions by Extractive Fourier Transform Infrared (FTIR) Spectroscopy Sample Train Diagram Heated Wet Sample Line Heated Area Extractive Probe Initial Particulate Filter Calibration Gases Data Acquisition System FTIR Cell FTIR Analyzer Heated Pump Secondary Filter Heated Manifold Orifice Liquid Nitrogen Reservoir Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 30 of 640 ©Mostardi Platt Appendix C - Calculation Nomenclature and Formulas Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 31 of 640 ©Mostardi Platt Client: Facility: Test Location: Run:1 Date:7/18/2023 Method: Source Condition: Dry Molecular Weight Md = 0.44 x (%CO2) + 0.32 x (%O2) + 0.28 x %N2 %CO2 = 17.2 %O2 = 10.9 %N2 = 71.9 Md = 31.188 Wet Molecular Weight Ms = Md x (1-Bws) + (18.0 x Bws) Md = 31.188 Bws = 0.105 Ms = 29.802 Meter Volume at Standard Conditions Vm(std) = 17.647 x Y x Vm x (Pbar +DH/13.6) Tm Y = 0.997 Vm = 51.520 Pbar = 24.65 DH = 1.85 Tm = 549.7 Vm(std) =40.874 Volume of Water Vapor Condensed Vw(std) =0.0471 x (net H2O gain) Net H2O = 101.9 Vw(std) = 4.799 Moisture Content Bws = Vw(std) = 4.799 Vm(std) = 40.874 Bws = 0.105 Vw(std) Vw(std) + Vm(std) 5 Mill On Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) Page 1 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 32 of 640 ©Mostardi Platt Client: Facility: Test Location: Run:1 Date:7/18/2023 Method: Source Condition: 5 Mill On Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) Average Duct Velocity Vs = 85.49 x Cp x Sqrt DP (avg) x (Ts (avg) + 460/ (Ps x Ms)) 1/2 Cp = 0.840 Ts (avg) = 267.6 Sqrt DP (avg): 0.809 Ps = 24.61 Ms = 29.802 Vs = 57.887 Volumetric Flow Rate (Actual Basis) Q = Vs x A x 60 Vs = 57.887 A = 94.315 Q = 327,576 Volumetric Flow Rate (Standard Basis) Qstd = 17.647 x Q x Ps Ts (avg) + 460 Q = 327,576 Ps = 24.61 Ts (avg) = 267.6 Qstd = 195,555 Volumetric Flow Rate (Standard Dry Basis) Qstd(dry) = Qstd x (1-Bws) Qstd = 195,555 Bws = 0.105 Qstd(dry) = 175,006 Isokinetic Variation: %ISO = Ts = 267.6 Vm(std) = 40.874 Vs = 57.887 An = 0.0003354 θ = 60 Ps = 24.61 Bws = 0.105 %ISO = 109.5 0.0945 x (Ts +460) x Vm(std) Vs x θ x An x Ps x (1-Bws) Page 2 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 33 of 640 ©Mostardi Platt Client: Facility: Test Location: Run:1 Date:7/18/2023 Method: Source Condition: 5 Mill On Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) PM Concentration: Co = mn x 15.43 Vm(std) mn (g) = 0.00208 Vm(std) = 40.874 Co = 0.0008 gr/dscf PM Emission Rate: Emission Rate lb/hr = Co x Qstd(dry) x 60 7,000 Co = 0.0008 Qstd(dry) = 175,006 Emission Rate lb/hr = 1.178 lb/hr This example represents the filterable fraction. For other fractions, use the obtained mn for that particulate fraction. Page 3 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 34 of 640 ©Mostardi Platt Client: Facility: Test Location: Run:1 Date:7/18/2023 Method: Source Condition: Dry Molecular Weight Md = 0.44 x (%CO2) + 0.32 x (%O2) + 0.28 x %N2 %CO2 = 17.60 %O2 = 10.6 %N2 = 71.8 Md = 31.240 Wet Molecular Weight Ms = Md x (1-Bws) + (18.0 x Bws) Md = 31.240 Bws = 0.110 Ms = 29.787 Meter Volume at Standard Conditions Vm(std) = 17.647 x Y x Vm x (Pbar +DH/13.6) Tm Y = 1.000 Vm = 130.132 Pbar = 24.65 DH = 2.32 Tm = 547.2 Vm(std) =104.158 Volume of Water Vapor Condensed Vw(std) = 0.0471 x (net H2O gain) Net H2O = 272.7 Vw(std) = 12.844 Moisture Content Bws = Vw(std) = 12.844 Vm(std) = 104.158 Bws = 0.110 Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) Vw(std) Vw(std) + Vm(std) 23 Mill On Page 1 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 35 of 640 ©Mostardi Platt Client: Facility: Test Location: Run:1 Date:7/18/2023 Method: Source Condition: Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) 23 Mill On Average Duct Velocity Vs = 85.49 x Cp x Sqrt DP (avg) x (Ts (avg) + 460/ (Ps x Ms)) 1/2 Cp = 0.840 Ts (avg) = 270.3 Sqrt DP (avg): 0.810 Ps = 24.61 Ms = 29.79 Vs = 58.048 Volumetric Flow Rate (Actual Basis) Q = Vs x A x 60 Vs = 58.048 A = 94.315 Q = 328484 Volumetric Flow Rate (Standard Basis) Qstd = 17.647 x Q x Ps Ts (avg) + 460 Q = 328,484 Ps = 24.61 Ts (avg) = 270.3 Qstd = 195,374 Volumetric Flow Rate (Standard Dry Basis) Qstd(dry) = Qstd x (1-Bws) Qstd = 195,374 Bws = 0.110 Qstd(dry) = 173,926 Isokinetic Variation: %ISO = Ts = 270.3 Vm(std) = 104.158 Vs = 58.048 An = 0.0003354 θ = 180.0 Ps = 24.61 Bws = 0.110 %ISO = 93.6 0.0945 x (Ts + 460) x Vm(std) Vs x θ x An x Ps x (1-Bws) Page 2 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 36 of 640 ©Mostardi Platt Client: Facility: Test Location: Run:1 Date:7/18/2023 Method: Source Condition: Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) 23 Mill On PCDD/PCDF Concentration: ng/m3= ng= 0.05 Vm(std) = 104.158 ng/m3=0.02 O2% =10.6 ng/m3 @ 7% O2 = ng/m3 @ 7% O2 = 0.00 ng of PCDD/PCDF Vm(std) x 0.02832 m3/ft3 ng/m3 * (20.9-7.0) (20.9-O2%) Page 3 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 37 of 640 ©Mostardi Platt Client:Test Location: Facility:Date: Project #: 10.54 % - 0.03 % x 17.60 % - -0.01 % x Cgas = (C - Co) x Cma Cm - Co where: Cgas = Effluent gas concentration, dry basis, % C = Average gas concentration indicated by gas analyzer, dry basis, % Co = Average of initial and final system calibration bias check responses for the zero gas, % Cm = Average of initital and final system calibration bias check responses for the upscale calibration gas, % Cma = Actual concentration of the upscale calibration gas, % Holcim (US) Inc. Rotary Kiln Exhaust (K-1 Devil's Slide Cement Manufacturing Facility 7/18/23 Rotary Kiln Exhaust (K-1) Sample Calculations O2 % (dry) 11.080 %10.6 %11.02 % - 0.03 % CO2 % (dry) 11.180 %17.6 %11.19 % - -0.01 % = = Page 1 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 38 of 640 ©Mostardi Platt Client: Plant: Test Location: Run:1 Date:7/18/2023 Vwc(std) = (Vf - Vi)*Pw*R*Tstd Pstd*Mw Vwsg(std) = (Wf - Wi)*Pw*R*Tstd Pstd*Mw ΔH Vm(std) = 17.64*Vm*Y* Pbar + 13.6 Tm Bws = Vf =2829.2 Wf = 914.9 Vi =2589.5 Wi = 881.9 Vwc(std) = 11.28 Vwsg(std) = 1.56 Vm = 130.132 Y =1 Pbar = 24.65 Δ H =1.703 Tm =547 Vm(std) = 104.158 Bws = 0.110 =0.04715 (Vf - Vi) Vwc(std) + Vwsg(std) Vwc(std) + Vwsg(std) + Vm(std) Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) Moisture Calculations = 0.04707 (Vf - Vi) Page 1 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 39 of 640 ©Mostardi Platt Client: Facility: Test Location: Run:2 Date:7/18/2023 Method: Source Condition: Recovery % with Certified Transfer Standard System Purge Rcts =Syscts x 100 Dcts Syscts =101.7 Dcts = 99.8 Rcts =102%% Dilution Factor for Analyte Spiking DF =Spksf6 Dsf6 Spksf6 =0.338 Dsf6 = 4.780 DF = 0.07 Recovery % for Analyte Spike With Acetaldehyde Rx = Spkx =15.1 Nx = 0.1 DF = 0.07 Dx = 209.8 Rx =101 % Conversion of perrcent volume Acetaldehyde wet (ppmvw) to dry (ppmvd) AcetaldehydeD = AcetaldehydeW (1-%H2O/100) AcetaldehydeW =0.11 %H2O = 11.59 AcetaldehydeD =0.12 Correction of Acetaldehyde to 7% O2 Acetaldehyde @ 7% O2 = AcetaldehydeD * (20.9 ‐ 7) (20.9 - %O2 dry) AcetaldehydeD =0.12 %O2 dry = 10.60 Acetaldehyde @ 7% O2 =0.16 O2% Volume Drift Correction Cx = (C - Co)Cma Cm - Co where: Cgas = Effluent gas concentration, dry basis, ppm C = Average gas concentration indicated by gas analyzer, dry basis, ppm Co = Average of initial and final system calibration bias check responses for the zero gas, ppm Cm = Average of initital and final system calibration bias check responses for the upscale calibration gas, ppm Cma = Actual concentration of the upscale calibration gas, ppm Holcim (US), Inc. Devil's Slide Cement Plant Main Kiln Stack 320 Normal Spkx (Nx x (1-DF) + Dx x DF) x Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 40 of 640 ©Mostardi Platt MOSTARDI PLATT Volumetric Air Flow Calculations 𝑉𝑉 (𝑠𝑠𝑠) =17.647 × 𝑉𝑉× ��𝑃𝑏𝑏𝑏+�𝐷𝐷13.6��(460 +𝑇𝑉)�× 𝑌 𝑉𝑉 (𝑠𝑠𝑠)= 0.0471 × 𝑉𝑉𝑉 𝐵𝑉𝑠=�𝑉𝑉 (𝑠𝑠𝑠)𝑉𝑉 (𝑠𝑠𝑠)+𝑉𝑉 (𝑠𝑠𝑠)� 𝑀𝑠=(0.44 × %𝐶𝐶2)+(0.32 × %𝐶2 )+[0.28 × (100 −%𝐶𝐶2 −%𝐶2 )] 𝑀𝑠=𝑀𝑠× (1 −𝐵𝑉𝑠)+(18 × 𝐵𝑉𝑠) 𝑉𝑠=�(𝑇𝑠+460)𝑀𝑠× 𝑃𝑠× √𝐷𝑃× 𝐶𝐶× 85.49 𝐴𝑉𝐴𝑉=𝑉𝑠× 𝐴𝐴𝐴𝐴 (𝑜𝐴 𝑠𝑠𝐴𝑉𝑠 𝑜𝐴 𝑠𝑑𝑉𝑠) × 60 𝑆𝑉𝐴𝑉=𝐴𝑉𝐴𝑉× 17.647 × �𝑃𝑠(460 +𝑇𝑠)� 𝑆𝑉𝐴ℎ=𝑆𝑉𝐴𝑉× 60 𝑉𝑚𝑚ℎ𝐴 𝐷𝑠𝑉𝐴𝑉=𝑆𝑉𝐴𝑉× (1 −𝐵𝑉𝑠) Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 41 of 640 ©Mostardi Platt MOSTARDI PLATT Volumetric Flow Nomenclature A = Cross-sectional area of stack or duct, ft2 Bws = Water vapor in gas stream, proportion by volume Cp = Pitot tube coefficient, dimensionless Md = Dry molecular weight of gas, lb/lb-mole Ms = Molecular weight of gas, wet basis, lb/lb-mole Mw = Molecular weight of water, 18.0 lb/lb-mole Pbar = Barometric pressure at testing site, in. Hg Pg = Static pressure of gas, in. Hg (in. H2O/13.6) DH= Static pressure of gas, in.H2O Ps = Absolute pressure of gas, in. Hg = Pbar + Pg Pstd = Standard absolute pressure, 29.92 in. Hg Acfm = Actual volumetric gas flow rate Scfm= Volumetric gas flow rate, corrected to standard conditions Dscfm = Standard volumetric flow rate, corrected to dry conditions R = Ideal gas constant, 21.85 in. Hg-ft3/°R-lb-mole Ts = Average stack gas temperature, °F Tm = Average dry gas meter temperature, oF Tstd = Standard absolute temperature, 528°R vs = Gas velocity, ft/sec Vm(std)= Volume of gas sampled, corrected to standard conditions, scf Vw(std) = Volume of water vapor in gas sample, corrected to standard conditions, scf Vlc= Volume of liquid collected Y = Dry gas meter calibration factor ∆p = Velocity head of gas, in. H2O K1 = 17.647 °R/in. Hg %EA = Percent excess air %CO2 = Percent carbon dioxide by volume, dry basis %O2 = Percent oxygen by volume, dry basis %N2 = Percent nitrogen by volume, dry basis 0.264 = Ratio of O2 to N2 in air, v/v 0.28 = Molecular weight of N2 or CO, divided by 100 0.32 = Molecular weight of O2 divided by 100 0.44 = Molecular weight of CO2 divided by 100 13.6 = Specific gravity of mercury (Hg) Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 42 of 640 ©Mostardi Platt MOSTARDI PLATT Moisture Calculations 𝑉𝑤𝑤(𝑠𝑠𝑠)=�𝑉𝑓− 𝑉𝑖�𝜌𝑤𝑅𝑇𝑠𝑠𝑠𝑃𝑠𝑠𝑠𝑀𝑤= 0.04707�𝑉𝑓− 𝑉𝑖� 𝑉𝑤𝑠𝑤(𝑠𝑠𝑠)=�𝑊𝑓− 𝑊𝑖�𝜌𝑤𝑅𝑇𝑠𝑠𝑠𝑃𝑠𝑠𝑠𝑀𝑤= 0.04715�𝑊𝑓− 𝑊𝑖� 𝑉𝑚(𝑠𝑠𝑠)=17.64 𝑉𝑚𝑌𝑃𝑏𝑏𝑏+∆𝐻13.6𝑇𝑚 𝐵𝑤𝑠=𝑉𝑤𝑤(𝑠𝑠𝑠)+𝑉𝑤𝑠𝑤(𝑠𝑠𝑠)𝑉𝑤𝑤(𝑠𝑠𝑠)+𝑉𝑤𝑠𝑤(𝑠𝑠𝑠)+𝑉𝑚(𝑠𝑠𝑠) Where: B ws = Water vapor in gas stream, proportion by volume M w = Molecular weight of water, 18.015 lb/lb-mole P bar = Barometric pressure at the testing site, in. Hg Pstd = Standard absolute pressure, 29.92 in. Hg R = Ideal gas constant, 0.048137 (in. Hg)(ft3)/(g-mole)(°R) = [21.8348(in. Hg)(ft3)/(lb-mole)(°R)]/453.592 g-mole/lb-mole Tm = Absolute average dry gas meter temperature, °R T std = Standard absolute temperature, 528 °R V f = Final volume of condenser water, ml Vi = Initial volume of condenser water, ml Vm = Dry gas volume measured by dry gas meter, dcf Vm(std) = Dry gas volume measured by dry gas meter, corrected to standard conditions, scf Vwc(std) = Volume of condensed water vapor, corrected to standard conditions, scf V wsg(std) = Volume of water vapor collected in silica gel, corrected to standard conditions, scf W f = Final weight of silica gel, g W i = Initial weight of silica gel, g Y = Dry gas meter calibration factor ∆H = Average pressure exerted on dry gas meter outlet by gas sample bag, in. H 2O ρ w = Density of water, 0.9982 g/ml 13.6 = Specific gravity of mercury (Hg) 17.64 = T std /P std 0.04707 = ft3/ml 0.04715 = ft3/g Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 43 of 640 ©Mostardi Platt MOSTARDI PLATT Isokinetic Calculation Formulas 1. lc2std std w wlcw(std)VKP RT MVV = =ρ 2. m bar m1std bar m stdmm(std)T ))13.6 H((P Y VK P ))13.6 H((P T TY VV ∆+ = ∆+ = 3. )V(V VB w(std)m(std) w(std)ws += 4. )0.28(%N)0.32(%O)0.44(%COM 222d++= 5. )18.0(B)B(1MM wswsds+−= 6. aa aaV mCρ= 7. aawaaVCWρ= 8. += sm(std)w(std) sniacf T VV Pm15.43KC 9. )Vm( )gramgrains 15.43(C m(std)nS= 10. ss sppsMP T PCKv∆= 11. )A(60vQ sec/minsacfm= 12. A PT PT v )B)(1(3600Q stds sstdswssec/hrsd −= 13. ()lbgrains 7000CQ )hrlbs rate, (emission E sstd= 14. ( )( )wsnss m(std)s4wssnsstd stdm(std)s B1AvP VTKB160PAvT PVTIKV −=−=θθ 15. 100%CO) 0.5(%O%N 0.264 %CO) (0.5%O%EA 22 2 × −− −= Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 44 of 640 ©Mostardi Platt MOSTARDI PLATT Isokinetic Nomenclature A = Cross-sectional area of stack or duct, square feet An = Cross-sectional area of nozzle, square feet Bws = Water vapor in gas stream, by volume Ca = Acetone blank residue concentration, g/g Cacf = Concentration of particulate matter in gas stream at actual conditions, gr/acf Cp = Pitot tube coefficient Cs = Concentration of particulate matter in gas stream, dry basis, corrected to standard conditions, gr/dscf IKV = Isokinetic sampling variance, must be 90.0 % ≤ IKV ≤ 110.0% Md = Dry molecular weight of gas, lb/lb-mole Ms = Molecular weight of gas, wet basis, lb/lb-mole Mw = Molecular weight of water, 18.0 lb/lb-mole ma = Mass of residue of acetone after evaporation, grams Pbar = Barometric pressure at testing site, inches mercury Pg = Static pressure of gas, inches mercury (inches water/13.6) Ps = Absolute pressure of gas, inches mercury = Pbar + Pg Pstd = Standard absolute pressure, 29.92 inches mercury Qacfm = Actual volumetric gas flow rate, acfm Qsd = Dry volumetric gas flow rate corrected to standard conditions, dscfh R = Ideal gas constant, 21.85 inches mercury cubic foot/°R-lb-mole Tm = Dry gas meter temperature, °R Ts = Gas temperature, °R Tstd = Absolute temperature, 528°R Va = Volume of acetone blank, ml Vaw = Volume of acetone used in wash, ml Wa = Weight of residue in acetone wash, grams mn = Total amount of particulate matter collected, grams V1c = Total volume of liquid collected in impingers and silica gel, ml Vm = Volume of gas sample as measured by dry gas meter, dcf Vm(std) = Volume of gas sample measured by dry gas meter, corrected to standard conditions, dscf vs = Gas velocity, ft/sec Vw(std) = Volume of water vapor in gas sample, corrected to standard conditions, scf Y = Dry gas meter calibration factor ∆H = Average pressure differential across the orifice meter, inches water ∆p = Velocity head of gas, inches water ρa = Density of acetone, 0.7855 g/ml (average) ρw = Density of water, 0.002201 lb/ml θ = Total sampling time, minutes K1 = 17.647 °R/in. Hg K2 = 0.04707 ft3/ml K4 = 0.09450/100 = 0.000945 Kp = Pitot tube constant, 85.49 𝑓𝑓𝑓𝑓𝑠𝑠𝑠𝑠𝑠𝑠�(𝑙𝑙𝑙𝑙𝑙𝑙𝑙𝑙⁄−𝑚𝑚𝑚𝑚𝑙𝑙𝑠𝑠)(𝑖𝑖𝑖𝑖. 𝐻𝐻𝐻𝐻)(°𝑅𝑅)(𝑖𝑖𝑖𝑖. 𝐻𝐻2𝑂𝑂)�1 2� %EA = Percent excess air %CO2 = Percent carbon dioxide by volume, dry basis %O2 = Percent oxygen by volume, dry basis %CO = Percent carbon monoxide by volume, dry basis %N2 = Percent nitrogen by volume, dry basis 0.264 = Ratio of O2 to N2 in air, v/v 28 = Molecular weight of N2 or CO 32 = Molecular weight of O2 44 = Molecular weight of CO2 13.6 = Specific gravity of mercury (Hg) Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 45 of 640 ©Mostardi Platt CN&F-047 SSOL Calculations Rev. 0.1 1/1/2021 MOSTARDI PLATT Site Specific Operating Limit (SSOL) Calculation Formulas 1. P E K lb/ton K,E 2. zX Y 1 1R 3. R L0.75O1 z 4. P EEE CBKCm E Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 46 of 640 ©Mostardi Platt CN&F-046 SSOL Nomenclature Rev. 0.1 1/1/2021 MOSTARDI PLATT Site Specific Operating Limit (SSOL) Nomenclature ECm = Combined hourly emission rate of PM from the kiln and bypass stack and/or inline coal mill, lb/ton of kiln clinker production EK = Hourly emissions of PM emissions from the kiln, lb EB = Hourly PM emissions from the alkali bypass stack, lb EC = Hourly PM emissions from the inline coal mill stack, lb Ol = The operating limit for your PM CPMS on a 30-day rolling average, in milliamps or the digital equivalent. L = Your source emission limit expressed in lb/ton clinker P = Hourly clinker production, tons R = The relative lb/ton-clinker per milliamp or digital equivalent for your PM CPMS Y1 = The three run average lb/ton-clinker PM concentration X1 = The three run average milliamp or digital equivalent output from the PM CPMS z = The milliamp or digital equivalent of instrument zero determined Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 47 of 640 ©Mostardi Platt MOSTARDI PLATT Benzene Sample Calculations Concentration 𝜇𝜇𝑚3 =𝜇𝜇 𝑜𝑜 𝑏𝑏𝑏𝑏𝑏𝑏𝑏𝑑𝑑𝑑𝑜 𝑣𝑜𝑣𝑣𝑚𝑏 𝑑𝑠𝑚𝑠𝑣𝑏𝑑× 0.02832 𝑚3𝑜𝑓3 Emission Rate 𝜇𝜇 𝑜𝑜 𝑑𝑠𝑚𝑠𝑣𝑏× 1 × 10−6𝜇𝑔𝑠𝑚𝑑𝑏𝜇453.6 𝜇𝑔𝑣𝑏⁄=𝑣𝑏𝑑 𝑜𝑜 𝑏𝑏𝑏𝑏𝑏𝑏𝑏 𝑣𝑏𝑑 𝑜𝑜 𝑏𝑏𝑏𝑏𝑏𝑏𝑏𝑉𝑚 (𝑑𝑓𝑑)𝑑𝑠𝑚𝑠𝑣𝑏× 𝑑𝑑𝑑𝑜𝑚× 60 𝑚𝑚𝑏ℎ𝑔=𝑣𝑏𝑑 𝑜𝑜 𝑏𝑏𝑏𝑏𝑏𝑏𝑏/ℎ𝑔 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 48 of 640 ©Mostardi Platt MOSTARDI PLATT Pollutant Concentration Correction 7% for Percent Oxygen 𝐶𝐶𝑎𝑎𝑎𝑎𝑎𝑎=𝐶𝐶𝑎𝑎20.9 −7%20.9 −%𝑂𝑂2 where: Cadj = Pollutant concentration corrected to percent O2 20.9 - 7% = Percent O2, the defined O2 correction value, percent 20.9 = Percent O2 in air %O2 = Measured O2 concentration dry basis, percent Cd = Pollutant concentration measured, dry basis, ppm. Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 49 of 640 ©Mostardi Platt Appendix D – Laboratory Analysis Data Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 50 of 640 ©Mostardi Platt Concentration Emissions Blank TEQ (pg) (pg-Blank) (ug) (ug/dcsm) (ug/hr) (lbs/mmBtu) TEQ Factor (ug/dscm) (ug/hr) (pg) (pg) 2378-TCDD 1.04 1.04 1.04E-06 3.53E-07 0.10 0.00E+00 1.0 3.53E-07 0.10 0 1.04 12378-PeCDD 1.18 1.18 1.18E-06 4.00E-07 0.12 0.00E+00 1.0 4.00E-07 0.12 0 1.18 123478-HxCDD 3.08 3.08 3.08E-06 1.04E-06 0.31 0.00E+00 0.1 1.04E-07 0.03 0 0.308 123678-HxCDD 1.81 1.81 1.81E-06 6.14E-07 0.18 0.00E+00 0.1 6.14E-08 0.02 0 0.181 123789-HxCDD 0.96 0.96 9.60E-07 3.25E-07 0.10 0.00E+00 0.1 3.25E-08 0.01 0 0.096 1234678-HpCDD 4.28 4.28 4.28E-06 1.45E-06 0.43 0.00E+00 0.01 1.45E-08 0.00 0 0.0428 OCDD 13.80 13.80 1.38E-05 4.68E-06 1.38 0.00E+00 0.0003 1.40E-09 0.00 0 0.00414 2378 -TCDF 1.00 1.00 1.00E-06 3.39E-07 0.10 0.00E+00 0.1 3.39E-08 0.01 0 0.1 12378-PeCDF 1.22 1.22 1.22E-06 4.14E-07 0.12 0.00E+00 0.03 1.24E-08 0.00 0 0.0366 23478-PeCDF 1.33 1.33 1.33E-06 4.51E-07 0.13 0.00E+00 0.3 1.35E-07 0.04 0 0.399 123478-HxCDF 1.12 1.12 1.12E-06 3.80E-07 0.11 0.00E+00 0.1 3.80E-08 0.01 0 0.112 123678-HxCDF 1.06 1.06 1.06E-06 3.59E-07 0.11 0.00E+00 0.1 3.59E-08 0.01 0 0.106 234678-HxCDF 1.02 1.02 1.02E-06 3.46E-07 0.10 0.00E+00 0.1 3.46E-08 0.01 0 0.102 123789-HxCDF 1.30 1.30 1.30E-06 4.41E-07 0.13 0.00E+00 0.1 4.41E-08 0.01 0 0.13 1234678-HpCDF 1.79 1.79 1.79E-06 6.07E-07 0.18 0.00E+00 0.01 6.07E-09 0.00 0 0.0179 1234789-HpCDF 2.33 2.33 2.33E-06 7.90E-07 0.23 0.00E+00 0.01 7.90E-09 0.00 0 0.0233 OCDF 1.26 1.26 1.26E-06 4.27E-07 0.13 0.00E+00 0.0003 1.28E-10 0.00 0 0.000378 Total TCDD 4.12 4.12 4.12E-06 1.40E-06 0.41 0.00E+00 0 Total PeCDD 4.92 4.92 4.92E-06 1.67E-06 0.49 0.00E+00 0 Total HxCDD 8.66 8.66 8.66E-06 2.94E-06 0.87 0.00E+00 0 Total HpCDD 9.84 9.84 9.84E-06 3.34E-06 0.99 0.00E+00 0 Total OCDD 13.80 13.80 1.38E-05 4.68E-06 1.38 0.00E+00 0 Total TCDF 1.64 1.64 1.64E-06 5.56E-07 0.16 0.00E+00 0 Total PeCDF 1.27 1.27 1.27E-06 4.31E-07 0.13 0.00E+00 0 Total HxCDF 5.06 5.06 5.06E-06 1.72E-06 0.51 0.00E+00 0 Total HpCDF 2.06 2.06 2.06E-06 6.98E-07 0.21 0.00E+00 0 Total OCDF 1.26 1.26 1.26E-06 4.27E-07 0.13 0.00E+00 0 Total PCDD/PCDF 52.63 5.26E-05 1.78E-05 5.27 0.00E+00 TEQ Total 3.879118 1.32E-06 0.39 Sample volume (Vmstd, dscf)104.16 Volumetric Air Flow (DSCFM)173,925.92 Fd-Factor dscf/MMBtu 0.0 Average % CO2 by volume, dry 17.60 Average % O2 by volume, dry 10.60 PCDD/PCDF TEST RESULTS SUMMARY Run 1 Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) July 18, 2023 Source Condition: Mill On Analytes Sample Catch TEQ Factor Results Page 1 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 51 of 640 ©Mostardi Platt Concentration Emissions Blank TEQ (pg) (pg-Blank) (ug) (ug/dcsm) (ug/hr) (lbs/mmBtu) TEQ Factor (ug/dscm) (ug/hr) (pg) (pg) 2378-TCDD 1.00 1.00 9.97E-07 3.39E-07 0.10 0.00E+00 1.0 3.39E-07 0.10 0 0.997 12378-PeCDD 1.43 1.43 1.43E-06 4.86E-07 0.15 0.00E+00 1.0 4.86E-07 0.15 0 1.43 123478-HxCDD 4.08 4.08 4.08E-06 1.39E-06 0.42 0.00E+00 0.1 1.39E-07 0.04 0 0.408 123678-HxCDD 1.81 1.81 1.81E-06 6.16E-07 0.19 0.00E+00 0.1 6.16E-08 0.02 0 0.181 123789-HxCDD 1.82 1.82 1.82E-06 6.19E-07 0.19 0.00E+00 0.1 6.19E-08 0.02 0 0.182 1234678-HpCDD 3.04 3.04 3.04E-06 1.03E-06 0.31 0.00E+00 0.01 1.03E-08 0.00 0 0.0304 OCDD 8.58 8.58 8.58E-06 2.92E-06 0.89 0.00E+00 0.0003 8.75E-10 0.00 0 0.002574 2378 -TCDF 0.96 0.96 9.63E-07 3.28E-07 0.10 0.00E+00 0.1 3.28E-08 0.01 0 0.0963 12378-PeCDF 1.24 1.24 1.24E-06 4.22E-07 0.13 0.00E+00 0.03 1.27E-08 0.00 0 0.0372 23478-PeCDF 1.29 1.29 1.29E-06 4.39E-07 0.13 0.00E+00 0.3 1.32E-07 0.04 0 0.387 123478-HxCDF 1.33 1.33 1.33E-06 4.52E-07 0.14 0.00E+00 0.1 4.52E-08 0.01 0 0.133 123678-HxCDF 1.22 1.22 1.22E-06 4.15E-07 0.13 0.00E+00 0.1 4.15E-08 0.01 0 0.122 234678-HxCDF 1.29 1.29 1.29E-06 4.39E-07 0.13 0.00E+00 0.1 4.39E-08 0.01 0 0.129 123789-HxCDF 1.58 1.58 1.58E-06 5.37E-07 0.16 0.00E+00 0.1 5.37E-08 0.02 0 0.158 1234678-HpCDF 1.76 1.76 1.76E-06 5.99E-07 0.18 0.00E+00 0.01 5.99E-09 0.00 0 0.0176 1234789-HpCDF 2.01 2.01 2.01E-06 6.84E-07 0.21 0.00E+00 0.01 6.84E-09 0.00 0 0.0201 OCDF 1.65 1.65 1.65E-06 5.61E-07 0.17 0.00E+00 0.0003 1.68E-10 0.00 0 0.000495 Total TCDD 4.30 4.30 4.30E-06 1.46E-06 0.45 0.00E+00 0 Total PeCDD 3.44 3.44 3.44E-06 1.17E-06 0.36 0.00E+00 0 Total HxCDD 8.86 8.86 8.86E-06 3.01E-06 0.92 0.00E+00 0 Total HpCDD 7.94 7.94 7.94E-06 2.70E-06 0.82 0.00E+00 0 Total OCDD 8.58 8.58 8.58E-06 2.92E-06 0.89 0.00E+00 0 Total TCDF 2.26 2.26 2.26E-06 7.69E-07 0.23 0.00E+00 0 Total PeCDF 1.26 1.26 1.26E-06 4.29E-07 0.13 0.00E+00 0 Total HxCDF 2.78 2.78 2.78E-06 9.46E-07 0.29 0.00E+00 0 Total HpCDF 1.76 1.76 1.76E-06 5.99E-07 0.18 0.00E+00 0 Total OCDF 1.65 1.65 1.65E-06 5.61E-07 0.17 0.00E+00 0 Total PCDD/PCDF 42.83 4.28E-05 1.46E-05 4.43 0.00E+00 TEQ Total 4.331669 1.47E-06 0.45 Sample volume (Vmstd, dscf)103.83 Volumetric Air Flow (DSCFM)179,185.07 Fd-Factor dscf/MMBtu 0.0 Average % CO2 by volume, dry 18.20 Average % O2 by volume, dry 11.10 Analytes Sample Catch TEQ Factor Results PCDD/PCDF TEST RESULTS SUMMARY Run 2 Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) July 18, 2023 Source Condition: Mill On Page 2 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 52 of 640 ©Mostardi Platt Concentration Emissions Blank TEQ (pg) (pg-Blank) (ug) (ug/dcsm) (ug/hr) (lbs/mmBtu) TEQ Factor (ug/dscm) (ug/hr) (pg) (pg) 2378-TCDD 0.93 0.93 9.29E-07 3.16E-07 0.09 0.00E+00 1.0 3.16E-07 0.09 0 0.929 12378-PeCDD 1.43 1.43 1.43E-06 4.86E-07 0.14 0.00E+00 1.0 4.86E-07 0.14 0 1.43 123478-HxCDD 3.62 3.62 3.62E-06 1.23E-06 0.36 0.00E+00 0.1 1.23E-07 0.04 0 0.362 123678-HxCDD 1.55 1.55 1.55E-06 5.27E-07 0.16 0.00E+00 0.1 5.27E-08 0.02 0 0.155 123789-HxCDD 1.64 1.64 1.64E-06 5.57E-07 0.16 0.00E+00 0.1 5.57E-08 0.02 0 0.164 1234678-HpCDD 4.04 4.04 4.04E-06 1.37E-06 0.41 0.00E+00 0.01 1.37E-08 0.00 0 0.0404 OCDD 12.40 12.40 1.24E-05 4.21E-06 1.24 0.00E+00 0.0003 1.26E-09 0.00 0 0.00372 2378 -TCDF 0.90 0.90 9.00E-07 3.06E-07 0.09 0.00E+00 0.1 3.06E-08 0.01 0 0.09 12378-PeCDF 1.12 1.12 1.12E-06 3.81E-07 0.11 0.00E+00 0.03 1.14E-08 0.00 0 0.0336 23478-PeCDF 1.18 1.18 1.18E-06 4.01E-07 0.12 0.00E+00 0.3 1.20E-07 0.04 0 0.354 123478-HxCDF 0.96 0.96 9.60E-07 3.26E-07 0.10 0.00E+00 0.1 3.26E-08 0.01 0 0.096 123678-HxCDF 0.66 0.66 6.56E-07 2.23E-07 0.07 0.00E+00 0.1 2.23E-08 0.01 0 0.0656 234678-HxCDF 0.71 0.71 7.09E-07 2.41E-07 0.07 0.00E+00 0.1 2.41E-08 0.01 0 0.0709 123789-HxCDF 0.81 0.81 8.14E-07 2.77E-07 0.08 0.00E+00 0.1 2.77E-08 0.01 0 0.0814 1234678-HpCDF 2.01 2.01 2.01E-06 6.82E-07 0.20 0.00E+00 0.01 6.82E-09 0.00 0 0.02006 1234789-HpCDF 1.32 1.32 1.32E-06 4.49E-07 0.13 0.00E+00 0.01 4.49E-09 0.00 0 0.0132 OCDF 1.48 1.48 1.48E-06 5.03E-07 0.15 0.00E+00 0.0003 1.51E-10 0.00 0 0.000444 Total TCDD 7.24 7.24 7.24E-06 2.46E-06 0.73 0.00E+00 0 Total PeCDD 6.04 6.04 6.04E-06 2.05E-06 0.61 0.00E+00 0 Total HxCDD 11.60 11.60 1.16E-05 3.94E-06 1.16 0.00E+00 0 Total HpCDD 9.24 9.24 9.24E-06 3.14E-06 0.93 0.00E+00 0 Total OCDD 12.40 12.40 1.24E-05 4.21E-06 1.24 0.00E+00 0 Total TCDF 4.02 4.02 4.02E-06 1.37E-06 0.40 0.00E+00 0 Total PeCDF 1.54 1.54 1.54E-06 5.23E-07 0.15 0.00E+00 0 Total HxCDF 3.74 3.74 3.74E-06 1.27E-06 0.38 0.00E+00 0 Total HpCDF 2.06 2.06 2.06E-06 7.00E-07 0.21 0.00E+00 0 Total OCDF 1.48 1.48 1.48E-06 5.03E-07 0.15 0.00E+00 0 Total PCDD/PCDF 59.36 5.94E-05 2.02E-05 5.96 0.00E+00 0 TEQ Total 3.909324 1.33E-06 0.39 Sample volume (Vmstd, dscf)103.90 Volumetric Air Flow (DSCFM)173,748.79 Fd-Factor dscf/MMBtu 0.0 Average % CO2 by volume, dry 17.00 Average % O2 by volume, dry 11.20 Analytes Sample Catch TEQ Factor Results PCDD/PCDF TEST RESULTS SUMMARY Run 3 Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) July 18, 2023 Source Condition: Mill On Page 3 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 53 of 640 ©Mostardi Platt Concentration Emissions Blank TEQ (pg) (pg-Blank) (ug)(ug/dcsm) (ug/hr)(lbs/mmBtu) TEQ Factor (ug/dscm) (ug/hr) (pg) (pg) 2378-TCDD 0.78 0.78 7.81E-07 2.66E-07 0.07 0.00E+00 1.0 2.66E-07 0.07 0 0.781 12378-PeCDD 1.44 1.44 1.44E-06 4.91E-07 0.13 0.00E+00 1.0 4.91E-07 0.13 0 1.44 123478-HxCDD 3.30 3.30 3.30E-06 1.13E-06 0.31 0.00E+00 0.1 1.13E-07 0.03 0 0.33 123678-HxCDD 1.33 1.33 1.33E-06 4.54E-07 0.12 0.00E+00 0.1 4.54E-08 0.01 0 0.133 123789-HxCDD 1.21 1.21 1.21E-06 4.13E-07 0.11 0.00E+00 0.1 4.13E-08 0.01 0 0.121 1234678-HpCDD 3.15 3.15 3.15E-06 1.07E-06 0.29 0.00E+00 0.01 1.07E-08 0.00 0 0.0315 OCDD 8.90 8.90 8.90E-06 3.04E-06 0.82 0.00E+00 0.0003 9.11E-10 0.00 0 0.00267 2378 -TCDF 0.88 0.88 8.78E-07 3.00E-07 0.08 0.00E+00 0.1 3.00E-08 0.01 0 0.0878 12378-PeCDF 0.80 0.80 7.99E-07 2.73E-07 0.07 0.00E+00 0.03 8.18E-09 0.00 0 0.02397 23478-PeCDF 1.24 1.24 1.24E-06 4.23E-07 0.11 0.00E+00 0.3 1.27E-07 0.03 0 0.372 123478-HxCDF 0.88 0.88 8.79E-07 3.00E-07 0.08 0.00E+00 0.1 3.00E-08 0.01 0 0.0879 123678-HxCDF 0.74 0.74 7.35E-07 2.51E-07 0.07 0.00E+00 0.1 2.51E-08 0.01 0 0.0735 234678-HxCDF 0.77 0.77 7.67E-07 2.62E-07 0.07 0.00E+00 0.1 2.62E-08 0.01 0 0.0767 123789-HxCDF 1.39 1.39 1.39E-06 4.74E-07 0.13 0.00E+00 0.1 4.74E-08 0.01 0 0.139 1234678-HpCDF 1.49 1.49 1.49E-06 5.08E-07 0.14 0.00E+00 0.01 5.08E-09 0.00 0 0.0149 1234789-HpCDF 0.74 0.74 7.43E-07 2.53E-07 0.07 0.00E+00 0.01 2.53E-09 0.00 0 0.00743 OCDF 1.19 1.19 1.19E-06 4.06E-07 0.11 0.00E+00 0.0003 1.22E-10 0.00 0 0.000357 Total TCDD 6.35 6.35 6.35E-06 2.17E-06 0.59 0.00E+00 0 Total PeCDD 6.73 6.73 6.73E-06 2.30E-06 0.62 0.00E+00 0 Total HxCDD 12.20 12.20 1.22E-05 4.16E-06 1.13 0.00E+00 0 Total HpCDD 8.11 8.11 8.11E-06 2.77E-06 0.75 0.00E+00 0 Total OCDD 8.90 8.90 8.90E-06 3.04E-06 0.82 0.00E+00 0 Total TCDF 14.20 14.20 1.42E-05 4.84E-06 1.32 0.00E+00 0 Total PeCDF 3.55 3.55 3.55E-06 1.21E-06 0.33 0.00E+00 0 Total HxCDF 5.61 5.61 5.61E-06 1.91E-06 0.52 0.00E+00 0 Total HpCDF 1.49 1.49 1.49E-06 5.08E-07 0.14 0.00E+00 0 Total OCDF 1.19 1.19 1.19E-06 4.06E-07 0.11 0.00E+00 0 Total PCDD/PCDF 68.33 6.83E-05 2.33E-05 6.33 0.00E+00 TEQ Total 3.722727 1.27E-06 0.34 Sample volume (Vmstd, dscf)103.52 Volumetric Air Flow (DSCFM)159,840.27 Fd-Factor dscf/MMBtu 0.0 Average % CO2 by volume, dry 17.70 Average % O2 by volume, dry 10.90 Analytes Sample Catch TEQ Factor Results PCDD/PCDF TEST RESULTS SUMMARY Run 4 Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) July 20, 2023 Source Condition: Mill On Page 4 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 54 of 640 ©Mostardi Platt Concentration Emissions Blank TEQ (pg) (pg-Blank) (ug) (ug/dcsm) (ug/hr) (lbs/mmBtu) TEQ Factor (ug/dscm) (ug/hr) (pg) (pg) 2378-TCDD 1.20 1.20 1.20E-06 3.23E-07 0.09 0.00E+00 1.0 3.23E-07 0.09 0 1.2 12378-PeCDD 1.24 1.24 1.24E-06 3.34E-07 0.09 0.00E+00 1.0 3.34E-07 0.09 0 1.24 123478-HxCDD 3.50 3.50 3.50E-06 9.43E-07 0.26 0.00E+00 0.1 9.43E-08 0.03 0 0.35 123678-HxCDD 1.86 1.86 1.86E-06 5.01E-07 0.14 0.00E+00 0.1 5.01E-08 0.01 0 0.186 123789-HxCDD 1.91 1.91 1.91E-06 5.15E-07 0.14 0.00E+00 0.1 5.15E-08 0.01 0 0.191 1234678-HpCDD 3.60 3.60 3.60E-06 9.70E-07 0.27 0.00E+00 0.01 9.70E-09 0.00 0 0.036 OCDD 8.04 8.04 8.04E-06 2.17E-06 0.60 0.00E+00 0.0003 6.50E-10 0.00 0 0.002412 2378 -TCDF 4.14 4.14 4.14E-06 1.12E-06 0.31 0.00E+00 0.1 1.12E-07 0.03 0 0.414 12378-PeCDF 1.12 1.12 1.12E-06 3.02E-07 0.08 0.00E+00 0.03 9.05E-09 0.00 0 0.0336 23478-PeCDF 1.17 1.17 1.17E-06 3.15E-07 0.09 0.00E+00 0.3 9.46E-08 0.03 0 0.351 123478-HxCDF 1.13 1.13 1.13E-06 3.04E-07 0.08 0.00E+00 0.1 3.04E-08 0.01 0 0.113 123678-HxCDF 0.71 0.71 7.07E-07 1.90E-07 0.05 0.00E+00 0.1 1.90E-08 0.01 0 0.0707 234678-HxCDF 0.77 0.77 7.69E-07 2.07E-07 0.06 0.00E+00 0.1 2.07E-08 0.01 0 0.0769 123789-HxCDF 1.42 1.42 1.42E-06 3.83E-07 0.11 0.00E+00 0.1 3.83E-08 0.01 0 0.142 1234678-HpCDF 1.76 1.76 1.76E-06 4.74E-07 0.13 0.00E+00 0.01 4.74E-09 0.00 0 0.0176 1234789-HpCDF 0.87 0.87 8.71E-07 2.35E-07 0.07 0.00E+00 0.01 2.35E-09 0.00 0 0.00871 OCDF 1.19 1.19 1.19E-06 3.21E-07 0.09 0.00E+00 0.0003 9.62E-11 0.00 0 0.000357 Total TCDD 11.30 11.30 1.13E-05 3.04E-06 0.84 0.00E+00 0 Total PeCDD 11.90 11.90 1.19E-05 3.21E-06 0.89 0.00E+00 0 Total HxCDD 12.20 12.20 1.22E-05 3.29E-06 0.91 0.00E+00 0 Total HpCDD 7.66 7.66 7.66E-06 2.06E-06 0.57 0.00E+00 0 Total OCDD 8.04 8.04 8.04E-06 2.17E-06 0.60 0.00E+00 0 Total TCDF 634.00 634.00 6.34E-04 1.71E-04 47.32 0.00E+00 0 Total PeCDF 15.50 15.50 1.55E-05 4.18E-06 1.16 0.00E+00 0 Total HxCDF 3.28 3.28 3.28E-06 8.84E-07 0.24 0.00E+00 0 Total HpCDF 1.76 1.76 1.76E-06 4.74E-07 0.13 0.00E+00 0 Total OCDF 1.19 1.19 1.19E-06 3.21E-07 0.09 0.00E+00 0 Total PCDD/PCDF 706.83 7.07E-04 1.90E-04 52.75 0.00E+00 TEQ Total 4.433279 1.19E-06 0.33 Sample volume (Vmstd, dscf)131.07 Volumetric Air Flow (DSCFM)163,038.31 Average % CO2 by volume, dry 18.70 Average % O2 by volume, dry 10.40 Source Condition: Mill Off Analytes Sample Catch TEQ Factor Results PCDD/PCDF TEST RESULTS SUMMARY Run 1 Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) July 19, 2023 Page 1 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 55 of 640 ©Mostardi Platt Concentration Emissions Blank TEQ (pg) (pg-Blank) (ug) (ug/dcsm) (ug/hr) (lbs/mmBtu) TEQ Factor (ug/dscm) (ug/hr) (pg) (pg) 2378-TCDD 1.08 1.08 1.08E-06 2.93E-07 0.08 0.00E+00 1.0 2.93E-07 0.08 0 1.08 12378-PeCDD 1.47 1.47 1.47E-06 3.99E-07 0.11 0.00E+00 1.0 3.99E-07 0.11 0 1.47 123478-HxCDD 1.76 1.76 1.76E-06 4.78E-07 0.13 0.00E+00 0.1 4.78E-08 0.01 0 0.176 123678-HxCDD 1.80 1.80 1.80E-06 4.89E-07 0.13 0.00E+00 0.1 4.89E-08 0.01 0 0.18 123789-HxCDD 1.72 1.72 1.72E-06 4.67E-07 0.13 0.00E+00 0.1 4.67E-08 0.01 0 0.172 1234678-HpCDD 6.00 6.00 6.00E-06 1.63E-06 0.44 0.00E+00 0.01 1.63E-08 0.00 0 0.06 OCDD 15.00 15.00 1.50E-05 4.07E-06 1.11 0.00E+00 0.0003 1.22E-09 0.00 0 0.0045 2378 -TCDF 4.46 4.46 4.46E-06 1.21E-06 0.33 0.00E+00 0.1 1.21E-07 0.03 0 0.446 12378-PeCDF 1.07 1.07 1.07E-06 2.91E-07 0.08 0.00E+00 0.03 8.72E-09 0.00 0 0.0321 23478-PeCDF 1.14 1.14 1.14E-06 3.10E-07 0.08 0.00E+00 0.3 9.29E-08 0.03 0 0.342 123478-HxCDF 1.01 1.01 1.01E-06 2.74E-07 0.07 0.00E+00 0.1 2.74E-08 0.01 0 0.101 123678-HxCDF 0.86 0.86 8.59E-07 2.33E-07 0.06 0.00E+00 0.1 2.33E-08 0.01 0 0.0859 234678-HxCDF 0.91 0.91 9.07E-07 2.46E-07 0.07 0.00E+00 0.1 2.46E-08 0.01 0 0.0907 123789-HxCDF 1.06 1.06 1.06E-06 2.88E-07 0.08 0.00E+00 0.1 2.88E-08 0.01 0 0.106 1234678-HpCDF 4.07 4.07 4.07E-06 1.10E-06 0.30 0.00E+00 0.01 1.10E-08 0.00 0 0.0407 1234789-HpCDF 0.98 0.98 9.76E-07 2.65E-07 0.07 0.00E+00 0.01 2.65E-09 0.00 0 0.00976 OCDF 2.39 2.39 2.39E-06 6.49E-07 0.18 0.00E+00 0.0003 1.95E-10 0.00 0 0.000717 Total TCDD 18.00 18.00 1.80E-05 4.89E-06 1.33 0.00E+00 0 Total PeCDD 7.70 7.70 7.70E-06 2.09E-06 0.57 0.00E+00 0 Total HxCDD 13.50 13.50 1.35E-05 3.67E-06 1.00 0.00E+00 0 Total HpCDD 13.20 13.20 1.32E-05 3.58E-06 0.97 0.00E+00 0 Total OCDD 15.00 15.00 1.50E-05 4.07E-06 1.11 0.00E+00 0 Total TCDF 950.00 950.00 9.50E-04 2.58E-04 70.10 0.00E+00 0 Total PeCDF 7.04 7.04 7.04E-06 1.91E-06 0.52 0.00E+00 0 Total HxCDF 0.96 0.96 9.57E-07 2.60E-07 0.07 0.00E+00 0 Total HpCDF 4.07 4.07 4.07E-06 1.10E-06 0.30 0.00E+00 0 Total OCDF 2.39 2.39 2.39E-06 6.49E-07 0.18 0.00E+00 0 Total PCDD/PCDF 1,031.86 1.03E-03 2.80E-04 76.14 0.00E+00 TEQ Total 4.397377 1.19E-06 0.32 Sample volume (Vmstd, dscf)130.07 Volumetric Air Flow (DSCFM)159,960.11 Fd-Factor dscf/MMBtu 0.0 Average % CO2 by volume, dry 19.90 Average % O2 by volume, dry 10.10 Analytes Sample Catch TEQ Factor Results PCDD/PCDF TEST RESULTS SUMMARY Run 2 Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) July 19, 2023 Source Condition: Mill Off Page 2 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 56 of 640 ©Mostardi Platt Concentration Emissions Blank TEQ (pg) (pg-Blank) (ug) (ug/dcsm) (ug/hr) (lbs/mmBtu) TEQ Factor (ug/dscm) (ug/hr) (pg) (pg) 2378-TCDD 1.93 1.93 1.93E-06 5.21E-07 0.14 0.00E+00 1.0 5.21E-07 0.14 0 1.93 12378-PeCDD 2.58 2.58 2.58E-06 6.97E-07 0.19 0.00E+00 1.0 6.97E-07 0.19 0 2.58 123478-HxCDD 4.36 4.36 4.36E-06 1.18E-06 0.32 0.00E+00 0.1 1.18E-07 0.03 0 0.436 123678-HxCDD 1.06 1.06 1.06E-06 2.86E-07 0.08 0.00E+00 0.1 2.86E-08 0.01 0 0.106 123789-HxCDD 1.24 1.24 1.24E-06 3.35E-07 0.09 0.00E+00 0.1 3.35E-08 0.01 0 0.124 1234678-HpCDD 4.58 4.58 4.58E-06 1.24E-06 0.34 0.00E+00 0.01 1.24E-08 0.00 0 0.0458 OCDD 8.66 8.66 8.66E-06 2.34E-06 0.64 0.00E+00 0.0003 7.02E-10 0.00 0 0.002598 2378 -TCDF 2.40 2.40 2.40E-06 6.48E-07 0.18 0.00E+00 0.1 6.48E-08 0.02 0 0.24 12378-PeCDF 2.29 2.29 2.29E-06 6.18E-07 0.17 0.00E+00 0.03 1.86E-08 0.01 0 0.0687 23478-PeCDF 2.49 2.49 2.49E-06 6.72E-07 0.18 0.00E+00 0.3 2.02E-07 0.06 0 0.747 123478-HxCDF 1.30 1.30 1.30E-06 3.51E-07 0.10 0.00E+00 0.1 3.51E-08 0.01 0 0.13 123678-HxCDF 1.15 1.15 1.15E-06 3.11E-07 0.09 0.00E+00 0.1 3.11E-08 0.01 0 0.115 234678-HxCDF 1.29 1.29 1.29E-06 3.48E-07 0.10 0.00E+00 0.1 3.48E-08 0.01 0 0.129 123789-HxCDF 1.36 1.36 1.36E-06 3.67E-07 0.10 0.00E+00 0.1 3.67E-08 0.01 0 0.136 1234678-HpCDF 1.66 1.66 1.66E-06 4.48E-07 0.12 0.00E+00 0.01 4.48E-09 0.00 0 0.0166 1234789-HpCDF 1.49 1.49 1.49E-06 4.02E-07 0.11 0.00E+00 0.01 4.02E-09 0.00 0 0.0149 OCDF 3.80 3.80 3.80E-06 1.03E-06 0.28 0.00E+00 0.0003 3.08E-10 0.00 0 0.00114 Total TCDD 12.90 12.90 1.29E-05 3.48E-06 0.95 0.00E+00 0 Total PeCDD 14.00 14.00 1.40E-05 3.78E-06 1.04 0.00E+00 0 Total HxCDD 20.70 20.70 2.07E-05 5.59E-06 1.53 0.00E+00 0 Total HpCDD 9.32 9.32 9.32E-06 2.52E-06 0.69 0.00E+00 0 Total OCDD 8.66 8.66 8.66E-06 2.34E-06 0.64 0.00E+00 0 Total TCDF 526.00 526.00 5.26E-04 1.42E-04 38.91 0.00E+00 0 Total PeCDF 3.54 3.54 3.54E-06 9.56E-07 0.26 0.00E+00 0 Total HxCDF 4.04 4.04 4.04E-06 1.09E-06 0.30 0.00E+00 0 Total HpCDF 1.66 1.66 1.66E-06 4.48E-07 0.12 0.00E+00 0 Total OCDF 3.80 3.80 3.80E-06 1.03E-06 0.28 0.00E+00 0 Total PCDD/PCDF 604.62 6.05E-04 1.63E-04 44.73 0.00E+00 0 TEQ Total 6.822738 1.84E-06 0.50 Sample volume (Vmstd, dscf)130.78 Volumetric Air Flow (DSCFM)161,253.60 Fd-Factor dscf/MMBtu 0.0 Average % CO2 by volume, dry 19.10 Average % O2 by volume, dry 10.10 Analytes Sample Catch TEQ Factor Results PCDD/PCDF TEST RESULTS SUMMARY Run 3 Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility Rotary Kiln Exhaust (K-1) July 21, 2023 Source Condition: Mill Off Page 3 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 57 of 640 ©Mostardi Platt Mostardi Platt Environmental - Elmhurst 888 Industrial Drive Elmhurst, IL 60126 LH- DS Kiln Stack Client Project# M232904 Samples Received: 7/25/2023 Analytical Report 0623-876 EPA Method 23 PCDD/PCDF Report Issue Date: 8/22/2023 I certify that to the best of my knowledge all analytical data presented in this report have been checked for completeness, accuracy, errors and legibility in addition to having been conducted in accordance with approved protocol, and that all deviations and analytical problems are summarized in the appropriate narrative(s). This analytical report was prepared in Portable Document Format (.PDF) and contains ___33____ pages. This report shall not be reproduced except in full without approval of the laboratory. This will provide assurance that parts of the report are not taken out of context. Signature: Amendments: Laura Boivin, QA Associate II Enthalpy Analytical, LLC – Ultratrace Mark Hager, Project Manager O: 910-876-6894/ F: 910-212-6886 mark.hager@enthalpy.com / www.enthalpy.com 2714 Exchange Drive, Wilmington, NC 28405 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 58 of 640 ©Mostardi Platt Summary of Results Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 59 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack Compound CAS TCDD 2378-TCDD (S) 1746-01-6 ND U ND U ND U ND U PeCDD 12378-PeCDD (S) 40321-76-4 ND U ND U ND U ND U 123478-HxCDD (S) 39227-28-6 3.08 J 4.08 J 3.62 J 3.50 J 123678-HxCDD (S) 57653-85-7 ND U ND U ND U ND U 123789-HxCDD (S) 19408-74-3 0.960 J-EMPC ND U ND U ND U HpCDD 1234678-HpCDD (S) 35822-46-9 4.28 J 3.04 J-EMPC 4.04 J 3.60 J-EMPC OCDD OCDD (S) 3268-87-9 13.8 J 8.58 J 12.4 J 8.04 J-EMPC TCDF 2378-TCDF (S) 51207-31-9 ND U ND U ND U 4.14 J 12378-PeCDF (S) 57117-41-6 ND U ND U ND U ND U 23478-PeCDF (S) 57117-31-4 ND U ND U ND U ND U 123478-HxCDF (S) 70648-26-9 1.12 J ND U 0.960 J ND U 123678-HxCDF (S) 57117-44-9 1.06 J-EMPC ND U ND U ND U 234678-HxCDF (S) 60851-34-5 ND U ND U ND U ND U 123789-HxCDF (S) 72918-21-9 1.30 J-EMPC ND U ND U 1.42 J-EMPC 1234678-HpCDF (S) 67562-39-4 ND U 1.76 J-EMPC 2.06 J-EMPC 1.76 J 1234789-HpCDF (S) 55673-89-7 ND U ND U ND U ND U OCDF OCDF (S) 39001-02-0 1.26 J ND U ND U ND U 41903-57-5 4.12 4.30 7.24 11.3 36088-22-9 4.92 3.44 6.04 11.9 34465-46-8 8.66 8.86 11.6 12.2 37871-00-4 9.84 7.94 9.24 7.66 13.8 8.58 12.4 8.04 55722-27-5 1.64 2.26 4.02 634 30402-15-4 ND ND 1.54 15.5 55684-94-1 5.06 2.78 3.74 3.28 38998-75-3 ND 1.76 2.06 1.76 1.26 ND ND ND 0.478 0.417 0.511 0.782 2.06 2.15 1.98 2.39 3.64 3.89 3.46 4.00 0.810 0.465 0.531 0.968 2.20 2.18 2.00 2.52 3.58 3.90 3.47 4.07 0.467 0.411 0.502 0.782 2.20 2.36 2.20 2.57 3.93 4.31 3.90 4.36 0.799 0.459 0.523 0.962 2.33 2.39 2.22 2.70 3.87 4.33 3.91 4.43 OCDF group total TEQ ITEQ (ND=0; EMPC=0) ITEQ (ND=1/2EDL;EMPC=1/2EDL) ITEQ (ND=EDL EMPC=EDL) ITEQ (ND=0; EMPC=EMPC) ITEQ (ND=1/2EDL; EMPC=EMPC) ITEQ (ND=EDL; EMPC=EMPC) WTEQ (ND=0; EMPC=0) WTEQ (ND=1/2EDL;EMPC=1/2EDL) WTEQ (ND=EDL EMPC=EDL) WTEQ (ND=0; EMPC=EMPC) WTEQ (ND=1/2EDL; EMPC=EMPC) WTEQ (ND=EDL; EMPC=EMPC) OCDD group total TCDF group total PeCDF group total HxCDF group total HpCDF group total HpCDF TCDD group total PeCDD group total HxCDD group total HpCDD group total PeCDF HxCDF Mill On Run 1 pg Mill On Run 2 pg Mill On Run 3 pg Summary HxCDD Mill Off Run 1 pg Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 60 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stac Compound CAS TCDD 2378-TCDD (S)1746-01-6 PeCDD 12378-PeCDD (S)40321-76-4 123478-HxCDD (S)39227-28-6 123678-HxCDD (S)57653-85-7 123789-HxCDD (S)19408-74-3 HpCDD 1234678-HpCDD (S)35822-46-9 OCDD OCDD (S)3268-87-9 TCDF 2378-TCDF (S)51207-31-9 12378-PeCDF (S)57117-41-6 23478-PeCDF (S)57117-31-4 123478-HxCDF (S)70648-26-9 123678-HxCDF (S)57117-44-9 234678-HxCDF (S)60851-34-5 123789-HxCDF (S)72918-21-9 1234678-HpCDF (S)67562-39-4 1234789-HpCDF (S)55673-89-7 OCDF OCDF (S)39001-02-0 41903-57-5 36088-22-9 34465-46-8 37871-00-4 55722-27-5 30402-15-4 55684-94-1 38998-75-3 OCDF group total TEQ ITEQ (ND=0; EMPC=0) ITEQ (ND=1/2EDL;EMPC=1/2EDL) ITEQ (ND=EDL EMPC=EDL) ITEQ (ND=0; EMPC=EMPC) ITEQ (ND=1/2EDL; EMPC=EMPC) ITEQ (ND=EDL; EMPC=EMPC) WTEQ (ND=0; EMPC=0) WTEQ (ND=1/2EDL;EMPC=1/2EDL) WTEQ (ND=EDL EMPC=EDL) WTEQ (ND=0; EMPC=EMPC) WTEQ (ND=1/2EDL; EMPC=EMPC) WTEQ (ND=EDL; EMPC=EMPC) OCDD group total TCDF group total PeCDF group total HxCDF group total HpCDF group total HpCDF TCDD group total PeCDD group total HxCDD group total HpCDD group total PeCDF HxCDF Summary HxCDD ND U ND U ND U ND U ND U ND U ND U 4.36 J 3.30 J ND U 1.06 J-EMPC ND U ND U 1.24 J-EMPC ND U 6.00 J 4.58 J 3.15 J-EMPC 15.0 J-EMPC 8.66 J 8.90 J-EMPC 4.46 J-EMPC 2.40 J-EMPC ND U ND U ND U ND U ND U ND U 1.24 J ND U ND U 0.879 J ND U ND U 0.735 J ND U ND U ND U ND U 1.36 J-EMPC 1.39 J-EMPC 4.07 J-EMPC 1.66 J 1.49 J-EMPC ND U ND U ND U ND U ND U 1.19 J-EMPC 18.0 12.9 6.35 7.70 14.0 6.73 13.5 20.7 12.2 13.2 9.32 8.11 15.0 8.66 8.90 950 526 14.2 7.04 3.54 3.55 ND 4.04 5.61 4.07 1.66 1.49 ND ND 1.19 0.0600 0.507 1.11 1.83 3.38 2.15 3.61 6.26 3.19 0.561 1.11 1.31 2.24 3.60 2.29 3.93 6.08 3.28 0.0600 0.501 0.864 2.07 3.75 2.26 4.09 6.99 3.65 0.551 1.11 1.05 2.48 3.96 2.39 4.40 6.82 3.73 Mill Off Run 3 pg Mill On Run 4 pg Mill Off Run 2 pg Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 61 of 640 ©Mostardi Platt Detailed Results Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 62 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack Enthalpy ID 0623-876-001-1 Prep Batch EU15750 N/A Sample Name Mill On Run 1 Prep Date 0.02 Matrix Air Analysis Date 2 Sampling Date 2023-07-18 00:00 Analyst jemunoz WM-001 Received Date 2023-07-25 Instrument Gandalf Sample Compound CAS Formatted Result pg LOD pg LOQ pg EDL pg Recovery Limits Recovery Flags TCDD 2378-TCDD (S)1746-01-6 ND 3.46 5.00 1.04 U PeCDD 12378-PeCDD (S)40321-76-4 ND 2.35 25.0 1.18 U 123478-HxCDD (S) 39227-28-6 3.08 4.97 25.0 1.77 J 123678-HxCDD (S) 57653-85-7 ND 4.62 25.0 1.81 U 123789-HxCDD (S) 19408-74-3 0.960 5.78 25.0 1.75 J-EMPC HpCDD 1234678-HpCDD (S) 35822-46-9 4.28 6.85 25.0 1.81 J OCDD OCDD (S)3268-87-9 13.8 6.82 50.0 1.68 J TCDF 2378-TCDF (S)51207-31-9 ND 1.47 5.00 1.00 U 12378-PeCDF (S)57117-41-6 ND 3.24 25.0 1.22 U 23478-PeCDF (S)57117-31-4 ND 2.53 25.0 1.33 U 123478-HxCDF (S) 70648-26-9 1.12 3.55 25.0 1.13 J 123678-HxCDF (S) 57117-44-9 1.06 3.24 25.0 0.939 J-EMPC 234678-HxCDF (S) 60851-34-5 ND 3.87 25.0 1.02 U 123789-HxCDF (S) 72918-21-9 1.30 3.12 25.0 1.22 J-EMPC 1234678-HpCDF (S) 67562-39-4 ND 2.68 25.0 1.79 U 1234789-HpCDF (S) 55673-89-7 ND 1.99 25.0 2.33 U OCDF OCDF (S)39001-02-0 1.26 11.7 50.0 1.45 J 13C-2378-TCDD (ES) 76523-40-5 4.18 40-135% 78.2% 13C-12378-PeCDD (ES) 109719-79-1 7.26 40-135% 71.9% 13C-123478-HxCDD (ES) 109719-80-4 10.4 40-135% 69.1% 13C-123678-HxCDD (ES) 109719-81-5 9.67 40-135% 68.5% 13C-123789-HxCDD (ES) 109719-82-6 9.67 40-135% 69.7% 13C-1234678-HpCDD (ES) 109719-83-7 9.81 40-135% 71.1% 13C-OCDD (ES)114423-97-1 9.47 40-135% 67.9% 13C-2378-TCDF (ES) 89059-46-1 6.29 40-135% 78.6% 13C-12378-PeCDF (ES) 109719-77-9 12.2 40-135% 83.7% 13C-23478-PeCDF (ES) 116843-02-8 12.6 40-135% 81.5% 13C-123478-HxCDF (ES) 114423-98-2 14.4 40-135% 70.1% 13C-123678-HxCDF (ES) 116843-03-9 13.1 40-135% 66.8% 13C-234678-HxCDF (ES) 116843-05-1 14.2 40-135% 69.4% 13C-123789-HxCDF (ES) 116843-04-0 15.8 40-135% 71.0% 13C-1234678-HpCDF (ES) 109719-84-8 13.2 40-135% 64.8% 13C-1234789-HpCDF (ES) 109719-94-0 15.1 40-135% 68.5% 13C-OCDF (ES)109719-78-0 5.16 40-135% 63.0% 37Cl-2378-TCDD (SS)1.04 70-130% 70.2% 13C-12347-PeCDD (SS)10.8 70-130% 78.9% 13C-12346-PeCDF (SS)13.5 70-130% 74.8% 13C-123469-HxCDF (SS)22.3 70-130% 73.8% 13C-1234689-HpCDF (SS)20.7 70-130% 72.2% AS 13C-1368-TCDD (AS)3.97 20-150% 93.4% PeCDF HxCDF HpCDF ES SS 2023-07-31 11:50 2023-08-05 01:09 HxCDD Sample Vol (mL) Extract Vol (mL) Split Factor Method Code Sample Type Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 63 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack AS 13C-1368-TCDF (AS)5.52 20-150% 104.3% TCDD group total:41903-57-5 4.12 1.04 PeCDD group total:36088-22-9 4.92 1.18 HxCDD group total:34465-46-8 8.66 1.78 HpCDD group total:37871-00-4 9.84 1.81 OCDD group total:13.8 1.68 TCDF group total:55722-27-5 1.64 1.00 PeCDF group total:30402-15-4 ND 1.27 HxCDF group total:55684-94-1 5.06 1.08 HpCDF group total:38998-75-3 ND 2.06 OCDF group total:1.26 1.45 0.478 2.06 3.64 0.810 2.20 3.58 0.467 2.20 3.93 0.799 2.33 3.87 TEQ ITEQ (ND=0; EMPC=0) ITEQ (ND=1/2EDL;EMPC=1/2EDL) ITEQ (ND=EDL EMPC=EDL) ITEQ (ND=0; EMPC=EMPC) ITEQ (ND=1/2EDL; EMPC=EMPC) ITEQ (ND=EDL; EMPC=EMPC) WTEQ (ND=0; EMPC=0) WTEQ (ND=1/2EDL;EMPC=1/2EDL) WTEQ (ND=EDL EMPC=EDL) WTEQ (ND=0; EMPC=EMPC) WTEQ (ND=1/2EDL; EMPC=EMPC) WTEQ (ND=EDL; EMPC=EMPC) Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 64 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack Enthalpy ID 0623-876-002-1 Prep Batch EU15750 N/A Sample Name Mill On Run 2 Prep Date 0.02 Matrix Air Analysis Date 2 Sampling Date 2023-07-18 00:00 Analyst jemunoz WM-001 Received Date 2023-07-25 Instrument Gandalf Sample Compound CAS Formatted Result pg LOD pg LOQ pg EDL pg Recovery Limits Recovery Flags TCDD 2378-TCDD (S)1746-01-6 ND 3.46 5.00 0.997 U PeCDD 12378-PeCDD (S)40321-76-4 ND 2.35 25.0 1.43 U 123478-HxCDD (S) 39227-28-6 4.08 4.97 25.0 1.73 J 123678-HxCDD (S) 57653-85-7 ND 4.62 25.0 1.81 U 123789-HxCDD (S) 19408-74-3 ND 5.78 25.0 1.82 U HpCDD 1234678-HpCDD (S) 35822-46-9 3.04 6.85 25.0 1.69 J-EMPC OCDD OCDD (S)3268-87-9 8.58 6.82 50.0 1.76 J TCDF 2378-TCDF (S)51207-31-9 ND 1.47 5.00 0.963 U 12378-PeCDF (S)57117-41-6 ND 3.24 25.0 1.24 U 23478-PeCDF (S)57117-31-4 ND 2.53 25.0 1.29 U 123478-HxCDF (S) 70648-26-9 ND 3.55 25.0 1.33 U 123678-HxCDF (S) 57117-44-9 ND 3.24 25.0 1.22 U 234678-HxCDF (S) 60851-34-5 ND 3.87 25.0 1.29 U 123789-HxCDF (S) 72918-21-9 ND 3.12 25.0 1.58 U 1234678-HpCDF (S) 67562-39-4 1.76 2.68 25.0 1.44 J-EMPC 1234789-HpCDF (S) 55673-89-7 ND 1.99 25.0 2.01 U OCDF OCDF (S)39001-02-0 ND 11.7 50.0 1.65 U 13C-2378-TCDD (ES) 76523-40-5 5.49 40-135% 79.9% 13C-12378-PeCDD (ES) 109719-79-1 9.45 40-135% 80.5% 13C-123478-HxCDD (ES) 109719-80-4 12.4 40-135% 75.2% 13C-123678-HxCDD (ES) 109719-81-5 11.5 40-135% 73.9% 13C-123789-HxCDD (ES) 109719-82-6 11.5 40-135% 74.5% 13C-1234678-HpCDD (ES) 109719-83-7 14.9 40-135% 76.7% 13C-OCDD (ES)114423-97-1 9.15 40-135% 72.5% 13C-2378-TCDF (ES) 89059-46-1 6.30 40-135% 78.4% 13C-12378-PeCDF (ES) 109719-77-9 11.9 40-135% 84.0% 13C-23478-PeCDF (ES) 116843-02-8 12.3 40-135% 82.9% 13C-123478-HxCDF (ES) 114423-98-2 13.9 40-135% 77.0% 13C-123678-HxCDF (ES) 116843-03-9 12.7 40-135% 76.9% 13C-234678-HxCDF (ES) 116843-05-1 13.8 40-135% 75.2% 13C-123789-HxCDF (ES) 116843-04-0 15.3 40-135% 76.3% 13C-1234678-HpCDF (ES) 109719-84-8 20.0 40-135% 73.6% 13C-1234789-HpCDF (ES) 109719-94-0 22.9 40-135% 71.2% 13C-OCDF (ES)109719-78-0 6.79 40-135% 66.9% 37Cl-2378-TCDD (SS)1.06 70-130% 67.9% Q 13C-12347-PeCDD (SS)13.0 70-130% 70.9% 13C-12346-PeCDF (SS)14.0 70-130% 72.5% 13C-123469-HxCDF (SS)20.1 70-130% 72.2% 13C-1234689-HpCDF (SS)30.0 70-130% 71.9% AS 13C-1368-TCDD (AS)5.21 20-150% 102.0% PeCDF HxCDF HpCDF ES SS 2023-07-31 11:50 2023-08-05 02:00 HxCDD Sample Vol (mL) Extract Vol (mL) Split Factor Method Code Sample Type Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 65 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack AS 13C-1368-TCDF (AS)5.52 20-150% 111.1% TCDD group total:41903-57-5 4.3 0.997 PeCDD group total:36088-22-9 3.44 1.43 HxCDD group total:34465-46-8 8.86 1.78 HpCDD group total:37871-00-4 7.94 1.69 OCDD group total:8.58 1.76 TCDF group total:55722-27-5 2.26 0.963 PeCDF group total:30402-15-4 ND 1.26 HxCDF group total:55684-94-1 2.78 1.35 HpCDF group total:38998-75-3 1.76 1.72 OCDF group total:ND 1.65 0.417 2.15 3.89 0.465 2.18 3.90 0.411 2.36 4.31 0.459 2.39 4.33 TEQ ITEQ (ND=0; EMPC=0) ITEQ (ND=1/2EDL;EMPC=1/2EDL) ITEQ (ND=EDL EMPC=EDL) ITEQ (ND=0; EMPC=EMPC) ITEQ (ND=1/2EDL; EMPC=EMPC) ITEQ (ND=EDL; EMPC=EMPC) WTEQ (ND=0; EMPC=0) WTEQ (ND=1/2EDL;EMPC=1/2EDL) WTEQ (ND=EDL EMPC=EDL) WTEQ (ND=0; EMPC=EMPC) WTEQ (ND=1/2EDL; EMPC=EMPC) WTEQ (ND=EDL; EMPC=EMPC) Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 66 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack Enthalpy ID 0623-876-003-1 Prep Batch EU15750 N/A Sample Name Mill On Run 3 Prep Date 0.02 Matrix Air Analysis Date 2 Sampling Date 2023-07-18 00:00 Analyst jemunoz WM-001 Received Date 2023-07-25 Instrument Gandalf Sample Compound CAS Formatted Result pg LOD pg LOQ pg EDL pg Recovery Limits Recovery Flags TCDD 2378-TCDD (S)1746-01-6 ND 3.46 5.00 0.929 U PeCDD 12378-PeCDD (S)40321-76-4 ND 2.35 25.0 1.43 U 123478-HxCDD (S) 39227-28-6 3.62 4.97 25.0 1.52 J 123678-HxCDD (S) 57653-85-7 ND 4.62 25.0 1.55 U 123789-HxCDD (S) 19408-74-3 ND 5.78 25.0 1.64 U HpCDD 1234678-HpCDD (S) 35822-46-9 4.04 6.85 25.0 1.92 J OCDD OCDD (S)3268-87-9 12.4 6.82 50.0 1.29 J TCDF 2378-TCDF (S)51207-31-9 ND 1.47 5.00 0.900 U 12378-PeCDF (S)57117-41-6 ND 3.24 25.0 1.12 U 23478-PeCDF (S)57117-31-4 ND 2.53 25.0 1.18 U 123478-HxCDF (S) 70648-26-9 0.960 3.55 25.0 0.745 J 123678-HxCDF (S) 57117-44-9 ND 3.24 25.0 0.656 U 234678-HxCDF (S) 60851-34-5 ND 3.87 25.0 0.709 U 123789-HxCDF (S) 72918-21-9 ND 3.12 25.0 0.814 U 1234678-HpCDF (S) 67562-39-4 2.06 2.68 25.0 1.03 J-EMPC 1234789-HpCDF (S) 55673-89-7 ND 1.99 25.0 1.32 U OCDF OCDF (S)39001-02-0 ND 11.7 50.0 1.48 U 13C-2378-TCDD (ES) 76523-40-5 5.96 40-135% 81.1% 13C-12378-PeCDD (ES) 109719-79-1 7.82 40-135% 81.0% 13C-123478-HxCDD (ES) 109719-80-4 12.9 40-135% 76.8% 13C-123678-HxCDD (ES) 109719-81-5 12.1 40-135% 76.8% 13C-123789-HxCDD (ES) 109719-82-6 12.1 40-135% 77.3% 13C-1234678-HpCDD (ES) 109719-83-7 13.4 40-135% 77.5% 13C-OCDD (ES)114423-97-1 7.82 40-135% 71.3% 13C-2378-TCDF (ES) 89059-46-1 5.30 40-135% 78.4% 13C-12378-PeCDF (ES) 109719-77-9 10.5 40-135% 84.0% 13C-23478-PeCDF (ES) 116843-02-8 10.8 40-135% 81.4% 13C-123478-HxCDF (ES) 114423-98-2 13.3 40-135% 80.4% 13C-123678-HxCDF (ES) 116843-03-9 12.1 40-135% 80.1% 13C-234678-HxCDF (ES) 116843-05-1 13.1 40-135% 78.1% 13C-123789-HxCDF (ES) 116843-04-0 14.6 40-135% 79.7% 13C-1234678-HpCDF (ES) 109719-84-8 16.1 40-135% 72.1% 13C-1234789-HpCDF (ES) 109719-94-0 18.5 40-135% 74.8% 13C-OCDF (ES)109719-78-0 7.12 40-135% 69.0% 37Cl-2378-TCDD (SS)1.23 70-130% 67.3% Q 13C-12347-PeCDD (SS)10.9 70-130% 72.3% 13C-12346-PeCDF (SS)12.2 70-130% 70.8% 13C-123469-HxCDF (SS)19.0 70-130% 70.4% 13C-1234689-HpCDF (SS)24.4 70-130% 70.3% AS 13C-1368-TCDD (AS)5.66 20-150% 116.4% PeCDF HxCDF HpCDF ES SS 2023-07-31 11:50 2023-08-05 02:52 HxCDD Sample Vol (mL) Extract Vol (mL) Split Factor Method Code Sample Type Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 67 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack AS 13C-1368-TCDF (AS)4.65 20-150% 111.9% TCDD group total:41903-57-5 7.24 0.929 PeCDD group total:36088-22-9 6.04 1.43 HxCDD group total:34465-46-8 11.6 1.57 HpCDD group total:37871-00-4 9.24 1.92 OCDD group total:12.4 1.29 TCDF group total:55722-27-5 4.02 0.900 PeCDF group total:30402-15-4 1.54 1.15 HxCDF group total:55684-94-1 3.74 0.731 HpCDF group total:38998-75-3 2.06 1.18 OCDF group total:ND 1.48 0.511 1.98 3.46 0.531 2.00 3.47 0.502 2.20 3.90 0.523 2.22 3.91 TEQ ITEQ (ND=0; EMPC=0) ITEQ (ND=1/2EDL;EMPC=1/2EDL) ITEQ (ND=EDL EMPC=EDL) ITEQ (ND=0; EMPC=EMPC) ITEQ (ND=1/2EDL; EMPC=EMPC) ITEQ (ND=EDL; EMPC=EMPC) WTEQ (ND=0; EMPC=0) WTEQ (ND=1/2EDL;EMPC=1/2EDL) WTEQ (ND=EDL EMPC=EDL) WTEQ (ND=0; EMPC=EMPC) WTEQ (ND=1/2EDL; EMPC=EMPC) WTEQ (ND=EDL; EMPC=EMPC) Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 68 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack Enthalpy ID 0623-876-004-1 Prep Batch EU15750 N/A Sample Name Mill Off Run 1 Prep Date 0.02 Matrix Air Analysis Date 2 Sampling Date 2023-07-19 00:00 Analyst jemunoz WM-001 Received Date 2023-07-25 Instrument Gandalf Sample Compound CAS Formatted Result pg LOD pg LOQ pg EDL pg Recovery Limits Recovery Flags TCDD 2378-TCDD (S)1746-01-6 ND 3.46 5.00 1.20 U PeCDD 12378-PeCDD (S)40321-76-4 ND 2.35 25.0 1.24 U 123478-HxCDD (S) 39227-28-6 3.50 4.97 25.0 1.87 J 123678-HxCDD (S) 57653-85-7 ND 4.62 25.0 1.86 U 123789-HxCDD (S) 19408-74-3 ND 5.78 25.0 1.91 U HpCDD 1234678-HpCDD (S) 35822-46-9 3.60 6.85 25.0 1.87 J-EMPC OCDD OCDD (S)3268-87-9 8.04 6.82 50.0 1.40 J-EMPC TCDF 2378-TCDF (S)51207-31-9 4.14 1.47 5.00 0.839 J 12378-PeCDF (S)57117-41-6 ND 3.24 25.0 1.12 U 23478-PeCDF (S)57117-31-4 ND 2.53 25.0 1.17 U 123478-HxCDF (S) 70648-26-9 ND 3.55 25.0 1.13 U 123678-HxCDF (S) 57117-44-9 ND 3.24 25.0 0.707 U 234678-HxCDF (S) 60851-34-5 ND 3.87 25.0 0.769 U 123789-HxCDF (S) 72918-21-9 1.42 3.12 25.0 0.935 J-EMPC 1234678-HpCDF (S) 67562-39-4 1.76 2.68 25.0 0.681 J 1234789-HpCDF (S) 55673-89-7 ND 1.99 25.0 0.871 U OCDF OCDF (S)39001-02-0 ND 11.7 50.0 1.19 U 13C-2378-TCDD (ES) 76523-40-5 5.34 40-135% 83.3% 13C-12378-PeCDD (ES) 109719-79-1 8.13 40-135% 82.7% 13C-123478-HxCDD (ES) 109719-80-4 11.6 40-135% 79.9% 13C-123678-HxCDD (ES) 109719-81-5 10.8 40-135% 77.4% 13C-123789-HxCDD (ES) 109719-82-6 10.8 40-135% 80.6% 13C-1234678-HpCDD (ES) 109719-83-7 9.39 40-135% 84.3% 13C-OCDD (ES)114423-97-1 7.90 40-135% 77.9% 13C-2378-TCDF (ES) 89059-46-1 6.42 40-135% 90.8% 13C-12378-PeCDF (ES) 109719-77-9 13.1 40-135% 94.2% 13C-23478-PeCDF (ES) 116843-02-8 13.5 40-135% 93.6% 13C-123478-HxCDF (ES) 114423-98-2 12.5 40-135% 82.3% 13C-123678-HxCDF (ES) 116843-03-9 11.4 40-135% 82.5% 13C-234678-HxCDF (ES) 116843-05-1 12.4 40-135% 81.8% 13C-123789-HxCDF (ES) 116843-04-0 13.7 40-135% 85.7% 13C-1234678-HpCDF (ES) 109719-84-8 18.1 40-135% 78.8% 13C-1234789-HpCDF (ES) 109719-94-0 20.8 40-135% 80.1% 13C-OCDF (ES)109719-78-0 6.87 40-135% 78.5% 37Cl-2378-TCDD (SS)1.27 70-130% 94.7% 13C-12347-PeCDD (SS)11.2 70-130% 101.8% 13C-12346-PeCDF (SS)12.6 70-130% 98.0% 13C-123469-HxCDF (SS)17.6 70-130% 98.5% 13C-1234689-HpCDF (SS)27.2 70-130% 100.7% AS 13C-1368-TCDD (AS)5.06 20-150% 119.1% PeCDF HxCDF HpCDF ES SS 2023-07-31 11:50 2023-08-05 03:43 HxCDD Sample Vol (mL) Extract Vol (mL) Split Factor Method Code Sample Type Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 69 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack AS 13C-1368-TCDF (AS)5.64 20-150% 135.7% TCDD group total:41903-57-5 11.3 1.20 PeCDD group total:36088-22-9 11.9 1.24 HxCDD group total:34465-46-8 12.2 1.88 HpCDD group total:37871-00-4 7.66 1.87 OCDD group total:8.04 1.40 TCDF group total:55722-27-5 634 0.839 PeCDF group total:30402-15-4 15.5 1.14 HxCDF group total:55684-94-1 3.28 0.884 HpCDF group total:38998-75-3 1.76 0.776 OCDF group total:ND 1.19 0.782 2.39 4.00 0.968 2.52 4.07 0.782 2.57 4.36 0.962 2.70 4.43 TEQ ITEQ (ND=0; EMPC=0) ITEQ (ND=1/2EDL;EMPC=1/2EDL) ITEQ (ND=EDL EMPC=EDL) ITEQ (ND=0; EMPC=EMPC) ITEQ (ND=1/2EDL; EMPC=EMPC) ITEQ (ND=EDL; EMPC=EMPC) WTEQ (ND=0; EMPC=0) WTEQ (ND=1/2EDL;EMPC=1/2EDL) WTEQ (ND=EDL EMPC=EDL) WTEQ (ND=0; EMPC=EMPC) WTEQ (ND=1/2EDL; EMPC=EMPC) WTEQ (ND=EDL; EMPC=EMPC) Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 70 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack Enthalpy ID 0623-876-005-1 Prep Batch EU15750 N/A Sample Name Mill Off Run 2 Prep Date 0.02 Matrix Air Analysis Date 2 Sampling Date 2023-07-19 00:00 Analyst jemunoz WM-001 Received Date 2023-07-25 Instrument Gandalf Sample Compound CAS Formatted Result pg LOD pg LOQ pg EDL pg Recovery Limits Recovery Flags TCDD 2378-TCDD (S)1746-01-6 ND 3.46 5.00 1.08 U PeCDD 12378-PeCDD (S)40321-76-4 ND 2.35 25.0 1.47 U 123478-HxCDD (S) 39227-28-6 ND 4.97 25.0 1.76 U 123678-HxCDD (S) 57653-85-7 ND 4.62 25.0 1.80 U 123789-HxCDD (S) 19408-74-3 ND 5.78 25.0 1.72 U HpCDD 1234678-HpCDD (S) 35822-46-9 6.00 6.85 25.0 1.66 J OCDD OCDD (S)3268-87-9 15.0 6.82 50.0 1.78 J-EMPC TCDF 2378-TCDF (S)51207-31-9 4.46 1.47 5.00 1.70 J-EMPC 12378-PeCDF (S)57117-41-6 ND 3.24 25.0 1.07 U 23478-PeCDF (S)57117-31-4 ND 2.53 25.0 1.14 U 123478-HxCDF (S) 70648-26-9 ND 3.55 25.0 1.01 U 123678-HxCDF (S) 57117-44-9 ND 3.24 25.0 0.859 U 234678-HxCDF (S) 60851-34-5 ND 3.87 25.0 0.907 U 123789-HxCDF (S) 72918-21-9 ND 3.12 25.0 1.06 U 1234678-HpCDF (S) 67562-39-4 4.07 2.68 25.0 0.747 J-EMPC 1234789-HpCDF (S) 55673-89-7 ND 1.99 25.0 0.976 U OCDF OCDF (S)39001-02-0 ND 11.7 50.0 2.39 U 13C-2378-TCDD (ES) 76523-40-5 4.69 40-135% 89.6% 13C-12378-PeCDD (ES) 109719-79-1 10.5 40-135% 87.1% 13C-123478-HxCDD (ES) 109719-80-4 12.2 40-135% 78.6% 13C-123678-HxCDD (ES) 109719-81-5 11.4 40-135% 85.0% 13C-123789-HxCDD (ES) 109719-82-6 11.4 40-135% 83.9% 13C-1234678-HpCDD (ES) 109719-83-7 14.3 40-135% 85.8% 13C-OCDD (ES)114423-97-1 10.9 40-135% 79.5% 13C-2378-TCDF (ES) 89059-46-1 6.73 40-135% 86.9% 13C-12378-PeCDF (ES) 109719-77-9 12.1 40-135% 96.6% 13C-23478-PeCDF (ES) 116843-02-8 12.5 40-135% 99.2% 13C-123478-HxCDF (ES) 114423-98-2 15.6 40-135% 86.9% 13C-123678-HxCDF (ES) 116843-03-9 14.2 40-135% 83.4% 13C-234678-HxCDF (ES) 116843-05-1 15.5 40-135% 84.3% 13C-123789-HxCDF (ES) 116843-04-0 17.1 40-135% 89.1% 13C-1234678-HpCDF (ES) 109719-84-8 18.2 40-135% 80.1% 13C-1234789-HpCDF (ES) 109719-94-0 20.9 40-135% 83.6% 13C-OCDF (ES)109719-78-0 8.51 40-135% 77.1% 37Cl-2378-TCDD (SS)1.30 70-130% 93.6% 13C-12347-PeCDD (SS)13.1 70-130% 103.8% 13C-12346-PeCDF (SS)10.5 70-130% 99.6% 13C-123469-HxCDF (SS)21.3 70-130% 98.6% 13C-1234689-HpCDF (SS)25.1 70-130% 99.0% AS 13C-1368-TCDD (AS)4.45 20-150% 72.8% PeCDF HxCDF HpCDF ES SS 2023-07-31 11:50 2023-08-05 04:34 HxCDD Sample Vol (mL) Extract Vol (mL) Split Factor Method Code Sample Type Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 71 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack AS 13C-1368-TCDF (AS)5.90 20-150% 80.7% TCDD group total:41903-57-5 18 1.08 PeCDD group total:36088-22-9 7.7 1.47 HxCDD group total:34465-46-8 13.5 1.76 HpCDD group total:37871-00-4 13.2 1.66 OCDD group total:15 1.78 TCDF group total:55722-27-5 950 1.70 PeCDF group total:30402-15-4 7.04 1.11 HxCDF group total:55684-94-1 ND 0.957 HpCDF group total:38998-75-3 4.07 0.861 OCDF group total:ND 2.39 0.0600 1.83 3.61 0.561 2.24 3.93 0.0600 2.07 4.09 0.551 2.48 4.40 TEQ ITEQ (ND=0; EMPC=0) ITEQ (ND=1/2EDL;EMPC=1/2EDL) ITEQ (ND=EDL EMPC=EDL) ITEQ (ND=0; EMPC=EMPC) ITEQ (ND=1/2EDL; EMPC=EMPC) ITEQ (ND=EDL; EMPC=EMPC) WTEQ (ND=0; EMPC=0) WTEQ (ND=1/2EDL;EMPC=1/2EDL) WTEQ (ND=EDL EMPC=EDL) WTEQ (ND=0; EMPC=EMPC) WTEQ (ND=1/2EDL; EMPC=EMPC) WTEQ (ND=EDL; EMPC=EMPC) Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 72 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack Enthalpy ID 0623-876-006-1 Prep Batch EU15750 N/A Sample Name Mill Off Run 3 Prep Date 0.02 Matrix Air Analysis Date 2 Sampling Date 2023-07-21 00:00 Analyst jemunoz WM-001 Received Date 2023-07-25 Instrument Gandalf Sample Compound CAS Formatted Result pg LOD pg LOQ pg EDL pg Recovery Limits Recovery Flags TCDD 2378-TCDD (S)1746-01-6 ND 3.46 5.00 1.93 U PeCDD 12378-PeCDD (S)40321-76-4 ND 2.35 25.0 2.58 U 123478-HxCDD (S) 39227-28-6 4.36 4.97 25.0 1.72 J 123678-HxCDD (S) 57653-85-7 1.06 4.62 25.0 1.79 J-EMPC 123789-HxCDD (S) 19408-74-3 1.24 5.78 25.0 1.83 J-EMPC HpCDD 1234678-HpCDD (S) 35822-46-9 4.58 6.85 25.0 1.80 J OCDD OCDD (S)3268-87-9 8.66 6.82 50.0 3.05 J TCDF 2378-TCDF (S)51207-31-9 2.40 1.47 5.00 2.78 J-EMPC 12378-PeCDF (S)57117-41-6 ND 3.24 25.0 2.29 U 23478-PeCDF (S)57117-31-4 ND 2.53 25.0 2.49 U 123478-HxCDF (S) 70648-26-9 ND 3.55 25.0 1.30 U 123678-HxCDF (S) 57117-44-9 ND 3.24 25.0 1.15 U 234678-HxCDF (S) 60851-34-5 ND 3.87 25.0 1.29 U 123789-HxCDF (S) 72918-21-9 1.36 3.12 25.0 1.39 J-EMPC 1234678-HpCDF (S) 67562-39-4 1.66 2.68 25.0 1.14 J 1234789-HpCDF (S) 55673-89-7 ND 1.99 25.0 1.49 U OCDF OCDF (S)39001-02-0 ND 11.7 50.0 3.80 U 13C-2378-TCDD (ES) 76523-40-5 6.92 40-135% 68.1% 13C-12378-PeCDD (ES) 109719-79-1 9.34 40-135% 67.8% 13C-123478-HxCDD (ES) 109719-80-4 12.7 40-135% 63.0% 13C-123678-HxCDD (ES) 109719-81-5 11.8 40-135% 63.8% 13C-123789-HxCDD (ES) 109719-82-6 11.8 40-135% 64.4% 13C-1234678-HpCDD (ES) 109719-83-7 14.0 40-135% 69.1% 13C-OCDD (ES)114423-97-1 9.24 40-135% 63.6% 13C-2378-TCDF (ES) 89059-46-1 8.19 40-135% 70.7% 13C-12378-PeCDF (ES) 109719-77-9 13.6 40-135% 74.5% 13C-23478-PeCDF (ES) 116843-02-8 14.0 40-135% 73.9% 13C-123478-HxCDF (ES) 114423-98-2 16.7 40-135% 66.4% 13C-123678-HxCDF (ES) 116843-03-9 15.2 40-135% 63.7% 13C-234678-HxCDF (ES) 116843-05-1 16.5 40-135% 63.2% 13C-123789-HxCDF (ES) 116843-04-0 18.3 40-135% 67.7% 13C-1234678-HpCDF (ES) 109719-84-8 20.8 40-135% 59.1% 13C-1234789-HpCDF (ES) 109719-94-0 23.8 40-135% 63.8% 13C-OCDF (ES)109719-78-0 9.98 40-135% 58.4% 37Cl-2378-TCDD (SS)2.01 70-130% 85.7% 13C-12347-PeCDD (SS)15.1 70-130% 91.0% 13C-12346-PeCDF (SS)14.8 70-130% 89.8% 13C-123469-HxCDF (SS)28.2 70-130% 89.2% 13C-1234689-HpCDF (SS)37.6 70-130% 91.2% AS 13C-1368-TCDD (AS)6.57 20-150% 67.2% PeCDF HxCDF HpCDF ES SS 2023-07-31 11:50 2023-08-05 05:26 HxCDD Sample Vol (mL) Extract Vol (mL) Split Factor Method Code Sample Type Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 73 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack AS 13C-1368-TCDF (AS)7.19 20-150% 67.1% TCDD group total:41903-57-5 12.9 1.93 PeCDD group total:36088-22-9 14 2.58 HxCDD group total:34465-46-8 20.7 1.78 HpCDD group total:37871-00-4 9.32 1.80 OCDD group total:8.66 3.05 TCDF group total:55722-27-5 526 2.78 PeCDF group total:30402-15-4 3.54 2.39 HxCDF group total:55684-94-1 4.04 1.28 HpCDF group total:38998-75-3 1.66 1.31 OCDF group total:ND 3.80 0.507 3.38 6.26 1.11 3.60 6.08 0.501 3.75 6.99 1.11 3.96 6.82 TEQ ITEQ (ND=0; EMPC=0) ITEQ (ND=1/2EDL;EMPC=1/2EDL) ITEQ (ND=EDL EMPC=EDL) ITEQ (ND=0; EMPC=EMPC) ITEQ (ND=1/2EDL; EMPC=EMPC) ITEQ (ND=EDL; EMPC=EMPC) WTEQ (ND=0; EMPC=0) WTEQ (ND=1/2EDL;EMPC=1/2EDL) WTEQ (ND=EDL EMPC=EDL) WTEQ (ND=0; EMPC=EMPC) WTEQ (ND=1/2EDL; EMPC=EMPC) WTEQ (ND=EDL; EMPC=EMPC) Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 74 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack Enthalpy ID 0623-876-007-1 Prep Batch EU15750 N/A Sample Name Mill On Run 4 Prep Date 0.02 Matrix Air Analysis Date 2 Sampling Date 2023-07-24 00:00 Analyst jemunoz WM-001 Received Date 2023-07-25 Instrument Gandalf Sample Compound CAS Formatted Result pg LOD pg LOQ pg EDL pg Recovery Limits Recovery Flags TCDD 2378-TCDD (S)1746-01-6 ND 3.46 5.00 0.781 U PeCDD 12378-PeCDD (S)40321-76-4 ND 2.35 25.0 1.44 U 123478-HxCDD (S) 39227-28-6 3.30 4.97 25.0 1.27 J 123678-HxCDD (S) 57653-85-7 ND 4.62 25.0 1.33 U 123789-HxCDD (S) 19408-74-3 ND 5.78 25.0 1.21 U HpCDD 1234678-HpCDD (S) 35822-46-9 3.15 6.85 25.0 1.41 J-EMPC OCDD OCDD (S)3268-87-9 8.90 6.82 50.0 1.37 J-EMPC TCDF 2378-TCDF (S)51207-31-9 ND 1.47 5.00 0.878 U 12378-PeCDF (S)57117-41-6 ND 3.24 25.0 0.799 U 23478-PeCDF (S)57117-31-4 1.24 2.53 25.0 0.882 J 123478-HxCDF (S) 70648-26-9 0.879 3.55 25.0 0.811 J 123678-HxCDF (S) 57117-44-9 0.735 3.24 25.0 0.693 J 234678-HxCDF (S) 60851-34-5 ND 3.87 25.0 0.767 U 123789-HxCDF (S) 72918-21-9 1.39 3.12 25.0 0.905 J-EMPC 1234678-HpCDF (S) 67562-39-4 1.49 2.68 25.0 0.586 J-EMPC 1234789-HpCDF (S) 55673-89-7 ND 1.99 25.0 0.743 U OCDF OCDF (S)39001-02-0 1.19 11.7 50.0 1.02 J-EMPC 13C-2378-TCDD (ES) 76523-40-5 4.38 40-135% 88.1% 13C-12378-PeCDD (ES) 109719-79-1 5.92 40-135% 88.2% 13C-123478-HxCDD (ES) 109719-80-4 10.0 40-135% 82.9% 13C-123678-HxCDD (ES) 109719-81-5 9.36 40-135% 80.2% 13C-123789-HxCDD (ES) 109719-82-6 9.37 40-135% 82.2% 13C-1234678-HpCDD (ES) 109719-83-7 9.31 40-135% 83.8% 13C-OCDD (ES)114423-97-1 7.78 40-135% 72.6% 13C-2378-TCDF (ES) 89059-46-1 4.42 40-135% 78.6% 13C-12378-PeCDF (ES) 109719-77-9 9.60 40-135% 95.1% 13C-23478-PeCDF (ES) 116843-02-8 9.92 40-135% 95.2% 13C-123478-HxCDF (ES) 114423-98-2 12.1 40-135% 88.3% 13C-123678-HxCDF (ES) 116843-03-9 11.0 40-135% 85.2% 13C-234678-HxCDF (ES) 116843-05-1 12.0 40-135% 84.1% 13C-123789-HxCDF (ES) 116843-04-0 13.3 40-135% 87.5% 13C-1234678-HpCDF (ES) 109719-84-8 14.2 40-135% 75.2% 13C-1234789-HpCDF (ES) 109719-94-0 16.3 40-135% 82.6% 13C-OCDF (ES)109719-78-0 7.17 40-135% 71.7% 37Cl-2378-TCDD (SS)0.870 70-130% 86.2% 13C-12347-PeCDD (SS)7.67 70-130% 91.8% 13C-12346-PeCDF (SS)9.43 70-130% 89.8% 13C-123469-HxCDF (SS)14.6 70-130% 90.2% 13C-1234689-HpCDF (SS)18.3 70-130% 94.5% AS 13C-1368-TCDD (AS)4.15 20-150% 82.3% PeCDF HxCDF HpCDF ES SS 2023-07-31 11:50 2023-08-05 06:17 HxCDD Sample Vol (mL) Extract Vol (mL) Split Factor Method Code Sample Type Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 75 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack AS 13C-1368-TCDF (AS)3.88 20-150% 87.7% TCDD group total:41903-57-5 6.35 0.781 PeCDD group total:36088-22-9 6.73 1.44 HxCDD group total:34465-46-8 12.2 1.27 HpCDD group total:37871-00-4 8.11 1.41 OCDD group total:8.9 1.37 TCDF group total:55722-27-5 14.2 0.878 PeCDF group total:30402-15-4 3.55 0.841 HxCDF group total:55684-94-1 5.61 0.794 HpCDF group total:38998-75-3 1.49 0.665 OCDF group total:1.19 1.02 1.11 2.15 3.19 1.31 2.29 3.28 0.864 2.26 3.65 1.05 2.39 3.73 TEQ ITEQ (ND=0; EMPC=0) ITEQ (ND=1/2EDL;EMPC=1/2EDL) ITEQ (ND=EDL EMPC=EDL) ITEQ (ND=0; EMPC=EMPC) ITEQ (ND=1/2EDL; EMPC=EMPC) ITEQ (ND=EDL; EMPC=EMPC) WTEQ (ND=0; EMPC=0) WTEQ (ND=1/2EDL;EMPC=1/2EDL) WTEQ (ND=EDL EMPC=EDL) WTEQ (ND=0; EMPC=EMPC) WTEQ (ND=1/2EDL; EMPC=EMPC) WTEQ (ND=EDL; EMPC=EMPC) Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 76 of 640 ©Mostardi Platt QC Data Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 77 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack Enthalpy ID MB-15750-DF Prep Batch EU15750 N/A Sample Name MB-15750-DF Prep Date 0.02 Matrix air Analysis Date 2 Sampling Date Analyst jemunoz WM-001 Received Date Instrument Gandalf Blank Compound CAS Formatted Result pg LOD pg LOQ pg EDL pg Recovery Limits Recovery Flags TCDD 2378-TCDD (S)1746-01-6 ND 3.46 5.00 1.24 U PeCDD 12378-PeCDD (S)40321-76-4 ND 2.35 25.0 2.43 U 123478-HxCDD (S) 39227-28-6 3.24 4.97 25.0 1.87 J 123678-HxCDD (S) 57653-85-7 ND 4.62 25.0 1.96 U 123789-HxCDD (S) 19408-74-3 2.68 5.78 25.0 1.97 J HpCDD 1234678-HpCDD (S) 35822-46-9 3.16 6.85 25.0 2.83 J OCDD OCDD (S)3268-87-9 12.0 6.82 50.0 2.90 J TCDF 2378-TCDF (S)51207-31-9 ND 1.47 5.00 1.07 U 12378-PeCDF (S)57117-41-6 ND 3.24 25.0 1.35 U 23478-PeCDF (S)57117-31-4 ND 2.53 25.0 1.37 U 123478-HxCDF (S) 70648-26-9 ND 3.55 25.0 1.30 U 123678-HxCDF (S) 57117-44-9 ND 3.24 25.0 0.773 U 234678-HxCDF (S) 60851-34-5 ND 3.87 25.0 0.858 U 123789-HxCDF (S) 72918-21-9 1.72 3.12 25.0 0.979 J-EMPC 1234678-HpCDF (S) 67562-39-4 1.12 2.68 25.0 0.931 J 1234789-HpCDF (S) 55673-89-7 ND 1.99 25.0 1.40 U OCDF OCDF (S)39001-02-0 1.40 11.7 50.0 1.82 J 13C-2378-TCDD (ES) 76523-40-5 7.73 40-135% 94.8% 13C-12378-PeCDD (ES) 109719-79-1 11.1 40-135% 85.5% 13C-123478-HxCDD (ES) 109719-80-4 20.4 40-135% 89.3% 13C-123678-HxCDD (ES) 109719-81-5 19.0 40-135% 89.2% 13C-123789-HxCDD (ES) 109719-82-6 19.0 40-135% 87.6% 13C-1234678-HpCDD (ES) 109719-83-7 13.5 40-135% 86.8% 13C-OCDD (ES)114423-97-1 12.6 40-135% 77.5% 13C-2378-TCDF (ES) 89059-46-1 8.51 40-135% 104.7% 13C-12378-PeCDF (ES) 109719-77-9 14.0 40-135% 103.2% 13C-23478-PeCDF (ES) 116843-02-8 14.5 40-135% 99.1% 13C-123478-HxCDF (ES) 114423-98-2 19.7 40-135% 96.1% 13C-123678-HxCDF (ES) 116843-03-9 17.9 40-135% 96.1% 13C-234678-HxCDF (ES) 116843-05-1 19.5 40-135% 96.2% 13C-123789-HxCDF (ES) 116843-04-0 21.6 40-135% 99.5% 13C-1234678-HpCDF (ES) 109719-84-8 27.0 40-135% 89.3% 13C-1234789-HpCDF (ES) 109719-94-0 31.0 40-135% 84.9% 13C-OCDF (ES)109719-78-0 9.33 40-135% 79.5% 37Cl-2378-TCDD (SS)1.18 70-130% 105.7% 13C-12347-PeCDD (SS)15.4 70-130% 106.0% 13C-12346-PeCDF (SS)12.1 70-130% 110.0% 13C-123469-HxCDF (SS)21.4 70-130% 108.2% 13C-1234689-HpCDF (SS)31.8 70-130% 109.2% AS 13C-1368-TCDD (AS)7.34 20-150% 69.4% Sample Vol (mL) Extract Vol (mL) Split Factor Method Code Sample Type 2023-07-31 11:50 2023-08-08 13:07 HxCDD PeCDF HxCDF HpCDF ES SS Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 78 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack AS 13C-1368-TCDF (AS)7.47 20-150% 101.5% TCDD group total:41903-57-5 8.05 1.24 PeCDD group total:36088-22-9 8.59 2.43 HxCDD group total:34465-46-8 14.7 1.93 HpCDD group total:37871-00-4 6.77 2.83 OCDD group total:12 2.90 TCDF group total:55722-27-5 2.58 1.07 PeCDF group total:30402-15-4 1.1 1.36 HxCDF group total:55684-94-1 3.39 0.977 HpCDF group total:38998-75-3 1.12 1.17 OCDF group total:1.4 1.82 0.648 2.60 4.56 0.820 2.73 4.63 0.639 3.05 5.46 0.811 3.17 5.54 TEQ ITEQ (ND=0; EMPC=0) ITEQ (ND=1/2EDL;EMPC=1/2EDL) ITEQ (ND=EDL EMPC=EDL) ITEQ (ND=0; EMPC=EMPC) ITEQ (ND=1/2EDL; EMPC=EMPC) ITEQ (ND=EDL; EMPC=EMPC) WTEQ (ND=0; EMPC=0) WTEQ (ND=1/2EDL;EMPC=1/2EDL) WTEQ (ND=EDL EMPC=EDL) WTEQ (ND=0; EMPC=EMPC) WTEQ (ND=1/2EDL; EMPC=EMPC) WTEQ (ND=EDL; EMPC=EMPC) Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 79 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack Enthalpy ID BCS-15750-DF Prep Batch EU15750 N/A Sample Name BCS-15750-DF Prep Date 0.04 Matrix air Analysis Date N/A Sampling Date Analyst jemunoz WM-001 Received Date Instrument Gandalf Control Compound CAS Formatted Result pg LOD pg LOQ pg EDL pg Recovery Limits Recovery Flags TCDD 2378-TCDD (S)1746-01-6 343 6.92 10.0 2.06 70-130% 85.8% PeCDD 12378-PeCDD (S)40321-76-4 1980 4.70 50.0 5.92 70-130% 98.9% 123478-HxCDD (S) 39227-28-6 1970 9.94 50.0 8.20 70-130% 98.7% 123678-HxCDD (S) 57653-85-7 2070 9.24 50.0 8.54 70-130% 103.7% 123789-HxCDD (S) 19408-74-3 1960 11.6 50.0 8.27 70-130% 97.8% HpCDD 1234678-HpCDD (S) 35822-46-9 1770 13.7 50.0 12.1 70-130% 88.6% OCDD OCDD (S)3268-87-9 3740 13.6 100 13.5 70-130% 93.6% TCDF 2378-TCDF (S)51207-31-9 297 2.94 10.0 1.78 70-130% 74.1% 12378-PeCDF (S)57117-41-6 1740 6.48 50.0 5.50 70-130% 87.1% 23478-PeCDF (S)57117-31-4 1760 5.06 50.0 5.65 70-130% 88.1% 123478-HxCDF (S) 70648-26-9 1910 7.10 50.0 7.56 70-130% 95.4% 123678-HxCDF (S) 57117-44-9 1900 6.48 50.0 7.17 70-130% 95.2% 234678-HxCDF (S) 60851-34-5 1910 7.74 50.0 7.59 70-130% 95.4% 123789-HxCDF (S) 72918-21-9 1910 6.24 50.0 9.29 70-130% 95.4% 1234678-HpCDF (S) 67562-39-4 1860 5.36 50.0 6.70 70-130% 93.1% 1234789-HpCDF (S) 55673-89-7 1700 3.98 50.0 7.94 70-130% 84.9% OCDF OCDF (S)39001-02-0 3640 23.4 100 8.02 70-130% 91.0% 13C-2378-TCDD (ES) 76523-40-5 10.1 40-135% 105.7% 13C-12378-PeCDD (ES) 109719-79-1 18.5 40-135% 106.2% 13C-123478-HxCDD (ES) 109719-80-4 14.1 40-135% 104.3% 13C-123678-HxCDD (ES) 109719-81-5 13.2 40-135% 101.7% 13C-123789-HxCDD (ES) 109719-82-6 13.2 40-135% 105.8% 13C-1234678-HpCDD (ES) 109719-83-7 15.9 40-135% 111.5% 13C-OCDD (ES)114423-97-1 11.6 40-135% 115.6% 13C-2378-TCDF (ES) 89059-46-1 10.0 40-135% 106.8% 13C-12378-PeCDF (ES) 109719-77-9 20.3 40-135% 113.9% 13C-23478-PeCDF (ES) 116843-02-8 21.0 40-135% 114.2% 13C-123478-HxCDF (ES) 114423-98-2 18.9 40-135% 109.3% 13C-123678-HxCDF (ES) 116843-03-9 17.2 40-135% 107.2% 13C-234678-HxCDF (ES) 116843-05-1 18.7 40-135% 108.8% 13C-123789-HxCDF (ES) 116843-04-0 20.7 40-135% 111.2% 13C-1234678-HpCDF (ES) 109719-84-8 32.7 40-135% 95.8% 13C-1234789-HpCDF (ES) 109719-94-0 37.6 40-135% 104.7% 13C-OCDF (ES)109719-78-0 11.9 40-135% 105.2% 37Cl-2378-TCDD (SS)1.79 70-130% 99.0% 13C-12347-PeCDD (SS)18.1 70-130% 104.9% 13C-12346-PeCDF (SS)17.2 70-130% 106.2% 13C-123469-HxCDF (SS)21.1 70-130% 106.6% 13C-1234689-HpCDF (SS)39.8 70-130% 114.2% AS 13C-1368-TCDD (AS)9.58 20-150% 108.9% Sample Vol (mL) Extract Vol (mL) Split Factor Method Code Sample Type 2023-07-31 11:50 2023-08-04 22:35 HxCDD PeCDF HxCDF HpCDF ES SS Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 80 of 640 ©Mostardi Platt Enthalpy Analytical Job No.: 0623-876-1 EPA Method 23 Mostardi Platt Environmental - Elmhurst M232904 LH- DS Kiln Stack AS 13C-1368-TCDF (AS)8.79 20-150% 111.2% TCDD group total:41903-57-5 1410 2.06 PeCDD group total:36088-22-9 6590 5.92 HxCDD group total:34465-46-8 8830 8.34 HpCDD group total:37871-00-4 4160 12.1 OCDD group total:3740 13.5 TCDF group total:55722-27-5 1360 1.78 PeCDF group total:30402-15-4 6090 5.58 HxCDF group total:55684-94-1 11700 7.90 HpCDF group total:38998-75-3 3560 7.32 OCDF group total:3640 8.02 3750 3750 3750 3750 3750 3750 4350 4350 4350 4350 4350 4350 TEQ ITEQ (ND=0; EMPC=0) ITEQ (ND=1/2EDL;EMPC=1/2EDL) ITEQ (ND=EDL EMPC=EDL) ITEQ (ND=0; EMPC=EMPC) ITEQ (ND=1/2EDL; EMPC=EMPC) ITEQ (ND=EDL; EMPC=EMPC) WTEQ (ND=0; EMPC=0) WTEQ (ND=1/2EDL;EMPC=1/2EDL) WTEQ (ND=EDL EMPC=EDL) WTEQ (ND=0; EMPC=EMPC) WTEQ (ND=1/2EDL; EMPC=EMPC) WTEQ (ND=EDL; EMPC=EMPC) Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 81 of 640 ©Mostardi Platt Narrative Summary Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 82 of 640 ©Mostardi Platt Enthalpy Analytical Narrative Summary Company Job No. Client ID. Mostardi Platt Environmental - Elmhurst 0623-876-1 EPA Method 23 M232904 Site: LH- DS Kiln Stack 1. Custody Summer Banning received the samples on July 25, 2023 at 23.3 °C after being relinquished by Mostardi Platt Environmental - Elmhurst. The samples were received in good condition. Client confirmed that Blank filter and Blank Acetone/Toluene container received with the samples but not documented on the COC do not need to be analyzed. Sampling dates documented in the report were ascertained from the client sample labels. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, LLC. Table 1 - Sample Inventory EU Lab Sample ID Client Sample ID Matrix 0623-876-001-1 Mill On Run 1 Air 0623-876-002-1 Mill On Run 2 Air 0623-876-003-1 Mill On Run 3 Air 0623-876-004-1 Mill Off Run 1 Air 0623-876-005-1 Mill Off Run 2 Air 0623-876-006-1 Mill Off Run 3 Air 0623-876-007-1 Mill On Run 4 Air 2. Methods and Analytes A list of analytes of interest and corresponding methods of analysis is shown in Table 3. Abbreviations are defined in the listed Appendices. Table 3 - Methods and Analytes EU Method Analytes EU-045 PCDD/PCDF 3. Analysis The samples were analyzed using Agilent Technologies Model# 6890 High-Resolution GC/ Waters High-Resolution Mass-Spectrometer (HRGC/HRMS "Gandalf") After sampling by the client, the laboratory spiked the samples with Extraction Standard (ES) prior to extraction via Soxhlet procedure. After solvent exchange, each extract was spiked with Alternate Standard (AS). The extracts were divided into two parts. One-half of each extract was archived. Cleanup procedures were performed on the remaining half of each extract. Each final sample extract was transferred to an autosampler vial and spiked with 20 µL of Injection Standard (JS), prior to analysis. Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 83 of 640 ©Mostardi Platt Enthalpy Analytical Narrative Summary Company Job No. Client ID. Mostardi Platt Environmental - Elmhurst 0623-876-1 EPA Method 23 M232904 Site: LH- DS Kiln Stack 4. Calibration The Initial Calibration (ICAL), Initial Calibration Verification (ICV), and continuing calibration (concal) met acceptance method criteria. 5. QC Notes The HRMS system displayed mass resolving power of at least 10,000 during the analysis. Labeled standard recovery values in the Batch Control Sample (BCS) and method blank were acceptable. The analyte recovery values in the BCS were acceptable. Analytes were detected in the method blank (MB) below LOQ. The data is accepted without adverse impact. Initial MB analysis fell below method recovery limits for all ES. Arachived MB extract was analyzed and reported successfully. GC Resolution parameters were met for TCDD and TCDF. Samples were extracted within the 30-day collection holding time and analyzed within the 45- day from extraction to analysis holding time required by the method. XAD received above 6 °C, client notified in order acknowledgment documentation. 6. Reporting Notes The results presented in this report are representative of the samples as provided to the laboratory. 37Cl-2378-TCDD (SS) fell below method recovery criteria in samples Mill On Run 2 and Mill On Run 3. This sampling standard (SS) met method criteria in the MB and BCS. The data is accepted with no further action. The TEQ was calculated and reported using I-TEF and WHO-2005 TEF, calculated by multiplying the concentration for each 2,3,7,8-substituted PCDD/F by its toxic equivalency factor (TEF). The Totals and Detection Limits have been included in the report. The TEQ is reported with and without EMPCs included. Additionally, the TEQ may be reported with non-detects treated as having a concentration of zero, a concentration of one-half the EDL, and/or a concentration equal to the EDL. These analyses met the requirements of the TNI Standard. Any deviations from the requirements of the reference method or TNI Standard have been stated above. Enthalpy Analytical, LLC in Wilmington NC is accredited by the Louisiana Department of Environmental Quality to the 2009 TNI Standard under certificate number 05075. Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 84 of 640 ©Mostardi Platt General Reporting Notes – Data Qualifiers EU116_v7 (General Reporting Notes-Data Qualifiers) Enthalpy Analytical, LLC – Wilmington, NC The following are general reporting notes that are applicable to all Enthalpy Analytical, LLC - Wilmington, NC data reports, unless specifically noted otherwise. General Data Qualifiers B – The analyte was found in the method blank, at a concentration that was at least 10% of the amount in the sample. Cxx – Two or more congeners co-elute. In EDDs, C denotes the lowest IUPAC congener in a co- elution group and additional co-eluters for the group (‘xx’) are shown with the number of the lowest IUPAC co-eluter. E – The reported concentration exceeds the calibration range (upper point of the calibration curve). For HRMS data, this condition does not imply additional measurement uncertainty. For LC-MS/MS data, these values should be considered as having measurement uncertainty higher than values within the calibration range. EDL – Estimated Detection Level: The EDL is unique to isotope dilution methods and reflects the conditions of analysis at the time of analysis, including the equipment used. Where the MDL is a static value, the EDL is a dynamic value. EMPC – Estimated Maximum Possible Concentration: EMPC is specific to Dioxin/Furan tests to indicate the determined ion-abundance ratio was outside the allowed theoretical range (usually due to being near the detection limit, although it can very rarely be caused by a co-eluting interference). The EMPC concentration is adjusted to reflect the value at the theoretical ion- abundance ratio. IR – The ion ratio between the primary and secondary ions was observed to be outside the method criteria. The analyte concentration may be inaccurate due to interference. J – The analyte has a concentration below the minimum calibration level (LOQ value) but greater than the LOD. These values should be considered as having measurement uncertainty higher than values within the calibration range L - For reports containing PFAS analytes only, this flag indicates that an analyte has a concentration below the Minimum Detection Limit (MDL) . The reported concentration is not recommended for regulatory use as the analyte signal may have a signal-to-noise ratio less than the criteria deemed necessary to be considered a detected analyte. LOD – Limit of Detection: For reports conforming to the DOD ELAP QSM, this is the QSM- defined LOD. For reports conforming to TNI requirements (but not DOD ELAP QSM requirements), this value is the minimum detection limit (MDL). The LOD is adjusted for sample weight or volume. LOQ – Limit of Quantitation: For reports conforming to the DOD ELAP QSM, this is the QSM- defined LOQ. For reports conforming to TNI requirements (but not DOD ELAP QSM Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 85 of 640 ©Mostardi Platt General Reporting Notes – Data Qualifiers EU116_v7 (General Reporting Notes-Data Qualifiers) Enthalpy Analytical, LLC – Wilmington, NC requirements), this value is the reporting limit (RL). The LOQ is adjusted for sample weight or volume. <LOD() – Analyte was not found at a concentration high enough to be reported as detected. It is reported as less than the LOD, and the LOD is given in the parentheses. <LOQ() – Analyte was not found at a concentration high enough to be reported as above the QSM-defined LOQ or TNI defined Reporting Limit. It is reported as less than the LOQ, and the LOQ is given in the parentheses. ND – Indicates a non-detect. NR – Indicates a value that is not reportable due to issues observed in sample preparation or analysis. PR – The associated congener(s) is(are) poorly resolved. QI – Indicates the presence of a quantitative interference. RL – Reporting Limit. Lowest reportable value. The level is higher than the MDL. SI – Denotes “Single Ion Mode” and is utilized for PCBs where the secondary ion trace has a significantly elevated noise level due to background PFK. Responses for such peaks are calculated using an EMPC approach based solely on the primary ion area(s) and may be considered estimates. U – The analyte was not detected. V / Q – The labeled standard recovery is not within method control limits. X – Indicates the result is from re-injection/repeat/second-column analysis. Lab Identifiers/ Data Attributes AR – Indicates use of the archived portion of the sample extract. CU – Indicates a sample that required additional clean-up prior to HRMS injection/processing. D – Dilution Data. Result was obtained from the analysis of a dilution. The number that follows the “D” indicates the dilution factor. DE – Indicates a dilution performed with the addition of ES (Extraction Standard) solution. DUP – Designation for a duplicate sample. MS – Designation for a matrix spike. MSD – Designation for a matrix spike duplicate. R – Indicates a re-extraction of the sample. Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 86 of 640 ©Mostardi Platt General Reporting Notes – Data Qualifiers EU116_v7 (General Reporting Notes-Data Qualifiers) Enthalpy Analytical, LLC – Wilmington, NC RJ – Indicates a reinjection of the sample extract. S – Indicates a sample split. The number that follows the “S” indicates the split factor. SAT – Indicates an analyte saturated the detector. Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 87 of 640 ©Mostardi Platt Sample Custody Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 88 of 640 ©Mostardi Platt Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 89 of 640 ©Mostardi Platt This Is The Last Page Of This Report. Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 90 of 640 ©Mostardi Platt Mostardi Platt Environmental Elmhurst 888 Industrial Drive Elmhurst, IL 60126 LH DS Kiln Stack Client Project # M232904 Analytical Report (0623-247R) EPA Method 18 (Adsorbents) Benzene, Ethylbenzene, Toluene, Styrene, Naphthalene o-xylene, m-xylene, p-xylene Enthalpy Analytical, LLC Phone: (919) 850 - 4392 / Fax: (919) 850 - 9012 / www.enthalpy.com 800-1 Capitola Drive Durham, NC 27713-4385 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 91 of 640 ©Mostardi Platt I certify that to the best of my knowledge all analytical data presented in this report: Have been checked for completeness Are accurate, error-free, and legible Have been conducted in accordance with approved protocol, and that all deviations and analytical problems are summarized in the appropriate narrative(s) This analytical report was prepared in Portable Document Format (.PDF). This report shall not be reproduced except in full without approval of the laboratory. This will provide assurance that parts of a report are not taken out of context. Report Issued: 9/20/23 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 92 of 640 ©Mostardi Platt Summary of Results Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 93 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Summary Table Compound Benzene 28.6 20.9 22.5 Ethylbenzene 2.05 ND 2.03 ND 1.45 ND m-Xylene 1.96 ND 1.93 ND 1.38 ND Naphthalene 1.87 ND 1.85 ND 1.32 ND o-Xylene 2.03 ND 2.00 ND 1.43 ND p-Xylene 2.07 ND 2.05 ND 1.46 ND Styrene 2.03 ND 2.01 ND 1.44 ND Toluene 8.55 J 1.59 ND 1.13 ND Compound Benzene 19.8 23.4 21.5 Ethylbenzene 2.11 ND 2.11 ND 2.09 ND m-Xylene 2.01 ND 2.01 ND 1.99 ND Naphthalene 1.88 ND 1.88 ND 1.86 ND o-Xylene 2.07 ND 2.07 ND 2.05 ND p-Xylene 2.12 ND 2.12 ND 2.10 ND Styrene 2.08 ND 2.08 ND 2.05 ND Toluene 1.53 ND 1.53 ND 14.2 Mill OFF Run 1 Mill OFF Run 2 Mill OFF Run 3 Adj. Catch Weight (ug) Adj. Catch Weight (ug) Mill ON Run 1 Mill ON Run 2 Mill ON Run 3 0623-247 EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 94 of 640 ©Mostardi Platt Results Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 95 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Benzene Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill ON-R1A.EXT 056F0601.D 056F0602.D 056F0603.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1.417 5.00 1.86 90.5 2.06 ND Mill ON-R1A.XAD-FH 069F1901.D 069F1902.D 069F1903.D 2.98 1,055 0.263 0.82 0.82 0.82 0.0 1.83 1.95 1.83 4.5 1.87 1 5.00 9.35 90.5 10.3 J Mill ON-R1A.XAD-BH 070F2001.D 070F2002.D 070F2003.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 90.5 1.45 ND Mill ON-R1A.CT-FH 071F2101.D 071F2102.D 071F2103.D 2.98 1,055 0.263 0.82 0.82 0.82 0.0 3.33 3.29 3.29 0.7 3.30 1 5.00 16.5 90.5 18.3 Mill ON-R1A.CT-BH 073F2301.D 073F2302.D 073F2303.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 90.5 1.45 ND 25.9 28.6 Mill ON-R1B SPK.EXT 058F0801.D 058F0802.D 058F0803.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1.400 5.00 1.84 100 1.84 ND Mill ON-R1B SPK.XAD-FH 074F2401.D 074F2402.D 074F2403.D 2.98 1,055 0.263 0.82 0.82 0.82 0.0 2.83 2.79 2.90 2.2 2.84 1 5.00 14.2 100 14.2 J Mill ON-R1B SPK.XAD-BH 076F2601.D 076F2602.D 076F2603.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 100 1.31 ND Mill ON-R1B SPK.CT-FH 077F2701.D 077F2702.D 077F2703.D 2.98 1,055 0.263 0.82 0.82 0.82 0.0 10.7 10.7 10.8 0.3 10.7 1 5.00 53.6 100 53.6 Mill ON-R1B SPK.CT-BH 078F2801.D 078F2802.D 078F2803.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 100 1.31 ND 67.8 67.8 Mill ON-R2A.EXT 057F0701.D 057F0702.D 057F0703.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1.400 5.00 1.84 90.5 2.03 ND Mill ON-R2A.XAD-FH 079F2901.D 079F2902.D 079F2903.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 90.5 1.45 ND Mill ON-R2A.XAD-BH 080F3001.D 080F3002.D 080F3003.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 90.5 1.45 ND Mill ON-R2A.CT-FH 081F3101.D 081F3102.D 081F3103.D 2.98 1,055 0.263 0.82 0.82 0.82 0.0 3.87 3.72 3.74 2.4 3.78 1 5.00 18.9 90.5 20.9 Mill ON-R2A.CT-BH 082F3201.D 082F3202.D 082F3203.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 90.5 1.45 ND 18.9 20.9 Mill ON-R2B SPK.EXT 060F1001.D 060F1002.D 060F1003.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1.400 5.00 1.84 100 1.84 ND Mill ON-R2B SPK.XAD-FH 084F3401.D 084F3402.D 084F3403.D 2.98 1,055 0.263 0.82 0.82 0.82 0.1 1.80 1.83 1.75 2.3 1.79 1 5.00 8.97 100 8.97 J Mill ON-R2B SPK.XAD-BH 085F3501.D 085F3502.D 085F3503.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 100 1.31 ND Mill ON-R2B SPK.CT-FH 086F3601.D 086F3602.D 086F3603.D 2.98 1,055 0.263 0.82 0.82 0.82 0.0 11.8 12.0 11.9 0.6 11.9 1 5.00 59.5 100 59.5 Mill ON-R2B SPK.CT-BH 087F3701.D 087F3702.D 087F3703.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 100 1.31 ND 68.5 68.5 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 96 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Benzene Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill ON-R3A.XAD-FH 088F3801.D 088F3802.D 088F3803.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 90.5 1.45 ND Mill ON-R3A.XAD-BH 089F3901.D 089F3902.D 089F3903.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 90.5 1.45 ND Mill ON-R3A.CT-FH 090F4001.D 090F4002.D 090F4003.D 2.98 1,055 0.263 0.82 0.82 0.82 0.0 4.09 4.03 4.11 1.2 4.08 1 5.00 20.4 90.5 22.5 Mill ON-R3A.CT-BH 091F4101.D 091F4102.D 091F4103.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 90.5 1.45 ND 20.4 22.5 Mill ON-R3B SPK.EXT 062F1201.D 062F1202.D 062F1203.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1.167 5.00 1.53 100 1.53 ND Mill ON-R3B SPK.XAD-FH 092F4201.D 092F4202.D 092F4203.D 2.98 1,055 0.263 0.82 0.82 0.82 0.0 1.90 1.78 2.04 6.9 1.91 1 5.00 9.53 100 9.53 J Mill ON-R3B SPK.XAD-BH 093F4301.D 093F4302.D 093F4303.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 100 1.31 ND Mill ON-R3B SPK.CT-FH 095F4501.D 095F4502.D 095F4503.D 2.98 1,055 0.263 0.82 0.82 0.82 0.0 12.4 12.5 12.4 0.6 12.4 1 5.00 62.1 100 62.1 Mill ON-R3B SPK.CT-BH 096F4601.D 096F4602.D 096F4603.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 100 1.31 ND 71.6 71.6 MajorPageBreak Mill OFF-R1A.EXT 063F1301.D 063F1302.D 063F1303.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1.417 5.00 1.86 86.8 2.15 ND Mill OFF-R1A.XAD-FH 097F4701.D 097F4702.D 097F4703.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 86.8 1.51 ND Mill OFF-R1A.XAD-BH 098F4801.D 098F4802.D 098F4803.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 86.8 1.51 ND Mill OFF-R1A.CT-FH 099F4901.D 099F4902.D 099F4903.D 2.98 1,055 0.263 0.82 0.82 0.82 0.0 3.51 3.38 3.42 2.2 3.44 1 5.00 17.2 86.8 19.8 Mill OFF-R1A.CT-BH 100F5001.D 100F5002.D 100F5003.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 86.8 1.51 ND 17.2 19.8 Mill OFF-R1B SPK.EXT 066F1601.D 066F1602.D 066F1603.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1.400 5.00 1.84 100 1.84 ND Mill OFF-R1B SPK.XAD-FH 101F5101.D 101F5102.D 101F5103.D 2.98 1,055 0.263 0.82 0.82 0.82 0.0 2.44 2.56 2.40 3.9 2.47 1 5.00 12.3 100 12.3 J Mill OFF-R1B SPK.XAD-BH 102F5201.D 102F5202.D 102F5203.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 100 1.31 ND Mill OFF-R1B SPK.CT-FH 103F5301.D 103F5302.D 103F5303.D 2.98 1,055 0.263 0.82 0.81 0.81 0.1 9.70 9.52 9.58 1.1 9.60 1 5.00 48.0 100 48.0 Mill OFF-R1B SPK.CT-BH 104F5401.D 104F5402.D 104F5403.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 100 1.31 ND 60.3 60.3 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 97 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Benzene Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill OFF-R2A.EXT 064F1401.D 064F1402.D 064F1403.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1.417 5.00 1.86 86.8 2.15 ND Mill OFF-R2A.XAD-FH 106F5601.D 106F5602.D 106F5603.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 86.8 1.51 ND Mill OFF-R2A.XAD-BH 107F5701.D 107F5702.D 107F5703.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 86.8 1.51 ND Mill OFF-R2A.CT-FH 108F5801.D 108F5802.D 108F5803.D 2.98 1,055 0.263 0.82 0.82 0.82 0.0 4.04 4.02 4.13 1.6 4.07 1 5.00 20.3 86.8 23.4 Mill OFF-R2A.CT-BH 109F5901.D 109F5902.D 109F5903.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 86.8 1.51 ND 20.3 23.4 Mill OFF-R2B SPK.EXT 067F1701.D 067F1702.D 067F1703.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1.400 5.00 1.84 100 1.84 ND Mill OFF-R2B SPK.XAD-FH 110F6001.D 110F6002.D 110F6003.D 2.98 1,055 0.263 0.82 0.82 0.82 0.0 2.05 2.12 1.96 4.2 2.05 1 5.00 10.2 100 10.2 J Mill OFF-R2B SPK.XAD-BH 111F6101.D 111F6102.D 111F6103.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 100 1.31 ND Mill OFF-R2B SPK.CT-FH 112F6201.D 112F6202.D 112F6203.D 2.98 1,055 0.263 0.81 0.82 0.82 0.0 10.9 11.0 11.0 0.3 11.0 1 5.00 54.8 100 54.8 Mill OFF-R2B SPK.CT-BH 113F6301.D 113F6302.D 113F6303.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 100 1.31 ND 65.0 65.0 Mill OFF-R3A.EXT 065F1501.D 065F1502.D 065F1503.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1.400 5.00 1.84 86.8 2.12 ND Mill OFF-R3A.XAD-FH 114F6401.D 114F6402.D 114F6403.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 86.8 1.51 ND Mill OFF-R3A.XAD-BH 115F6501.D 115F6502.D 115F6503.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 86.8 1.51 ND Mill OFF-R3A.CT-FH 117F6701.D 117F6702.D 117F6703.D 2.98 1,055 0.263 0.81 0.82 0.82 0.1 3.81 3.69 3.69 2.1 3.73 1 5.00 18.7 86.8 21.5 Mill OFF-R3A.CT-BH 118F6801.D 118F6802.D 118F6803.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 86.8 1.51 ND 18.7 21.5 Mill OFF-R3B SPK.EXT 068F1801.D 068F1802.D 068F1803.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1.400 5.00 1.84 100 1.84 ND Mill OFF-R3B SPK.XAD-FH 119F6901.D 119F6902.D 119F6903.D 2.98 1,055 0.263 0.82 0.82 0.82 0.0 2.08 2.09 2.10 0.6 2.09 1 5.00 10.4 100 10.4 J Mill OFF-R3B SPK.XAD-BH 120F7001.D 120F7002.D 120F7003.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 100 1.31 ND Mill OFF-R3B SPK.CT-FH 122F7201.D 122F7202.D 122F7203.D 2.98 1,055 0.263 0.82 0.82 0.82 0.0 11.6 11.5 11.4 0.9 11.5 1 5.00 57.3 100 57.3 Mill OFF-R3B SPK.CT-BH 121F7101.D 121F7102.D 121F7103.D 2.98 1,055 0.263 NA NA NA NA 0.263 0.263 0.263 0.0 0.263 1 5.00 1.31 100 1.31 ND 67.8 67.8 MajorPageBreak 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 98 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill ON-R1A.EXT 056F0601.D 056F0602.D 056F0603.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.417 5.00 1.84 89.4 2.05 ND Mill ON-R1A.XAD-FH 069F1901.D 069F1902.D 069F1903.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 89.4 1.45 ND Mill ON-R1A.XAD-BH 070F2001.D 070F2002.D 070F2003.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 89.4 1.45 ND Mill ON-R1A.CT-FH 071F2101.D 071F2102.D 071F2103.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 89.4 1.45 ND Mill ON-R1A.CT-BH 073F2301.D 073F2302.D 073F2303.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 89.4 1.45 ND 1.84 2.05 ND Mill ON-R1B SPK.EXT 058F0801.D 058F0802.D 058F0803.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 100 1.81 ND Mill ON-R1B SPK.XAD-FH 074F2401.D 074F2402.D 074F2403.D 2.59 1,039 0.259 1.49 1.49 1.49 0.0 9.88 9.91 9.81 0.6 9.87 1 5.00 49.3 100 49.3 Mill ON-R1B SPK.XAD-BH 076F2601.D 076F2602.D 076F2603.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R1B SPK.CT-FH 077F2701.D 077F2702.D 077F2703.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R1B SPK.CT-BH 078F2801.D 078F2802.D 078F2803.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 49.3 49.3 Mill ON-R2A.EXT 057F0701.D 057F0702.D 057F0703.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 89.4 2.03 ND Mill ON-R2A.XAD-FH 079F2901.D 079F2902.D 079F2903.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 89.4 1.45 ND Mill ON-R2A.XAD-BH 080F3001.D 080F3002.D 080F3003.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 89.4 1.45 ND Mill ON-R2A.CT-FH 081F3101.D 081F3102.D 081F3103.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 89.4 1.45 ND Mill ON-R2A.CT-BH 082F3201.D 082F3202.D 082F3203.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 89.4 1.45 ND 1.81 2.03 ND Mill ON-R2B SPK.EXT 060F1001.D 060F1002.D 060F1003.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 100 1.81 ND Mill ON-R2B SPK.XAD-FH 084F3401.D 084F3402.D 084F3403.D 2.59 1,039 0.259 1.49 1.49 1.49 0.0 9.01 8.96 8.89 0.7 8.95 1 5.00 44.8 100 44.8 Mill ON-R2B SPK.XAD-BH 085F3501.D 085F3502.D 085F3503.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R2B SPK.CT-FH 086F3601.D 086F3602.D 086F3603.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R2B SPK.CT-BH 087F3701.D 087F3702.D 087F3703.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 44.8 44.8 Ethylbenzene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 99 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill ON-R3A.XAD-FH 088F3801.D 088F3802.D 088F3803.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 89.4 1.45 ND Mill ON-R3A.XAD-BH 089F3901.D 089F3902.D 089F3903.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 89.4 1.45 ND Mill ON-R3A.CT-FH 090F4001.D 090F4002.D 090F4003.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 89.4 1.45 ND Mill ON-R3A.CT-BH 091F4101.D 091F4102.D 091F4103.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 89.4 1.45 ND 1.30 1.45 ND Mill ON-R3B SPK.EXT 062F1201.D 062F1202.D 062F1203.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.167 5.00 1.51 100 1.51 ND Mill ON-R3B SPK.XAD-FH 092F4201.D 092F4202.D 092F4203.D 2.59 1,039 0.259 1.49 1.49 1.49 0.0 9.11 8.95 9.05 0.9 9.04 1 5.00 45.2 100 45.2 Mill ON-R3B SPK.XAD-BH 093F4301.D 093F4302.D 093F4303.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R3B SPK.CT-FH 095F4501.D 095F4502.D 095F4503.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R3B SPK.CT-BH 096F4601.D 096F4602.D 096F4603.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 45.2 45.2 MajorPageBreak Mill OFF-R1A.EXT 063F1301.D 063F1302.D 063F1303.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.417 5.00 1.84 87.0 2.11 ND Mill OFF-R1A.XAD-FH 097F4701.D 097F4702.D 097F4703.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 87.0 1.49 ND Mill OFF-R1A.XAD-BH 098F4801.D 098F4802.D 098F4803.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 87.0 1.49 ND Mill OFF-R1A.CT-FH 099F4901.D 099F4902.D 099F4903.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 87.0 1.49 ND Mill OFF-R1A.CT-BH 100F5001.D 100F5002.D 100F5003.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 87.0 1.49 ND 1.84 2.11 ND Mill OFF-R1B SPK.EXT 066F1601.D 066F1602.D 066F1603.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 100 1.81 ND Mill OFF-R1B SPK.XAD-FH 101F5101.D 101F5102.D 101F5103.D 2.59 1,039 0.259 1.49 1.49 1.49 0.0 9.01 9.06 8.95 0.7 9.01 1 5.00 45.0 100 45.0 Mill OFF-R1B SPK.XAD-BH 102F5201.D 102F5202.D 102F5203.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R1B SPK.CT-FH 103F5301.D 103F5302.D 103F5303.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R1B SPK.CT-BH 104F5401.D 104F5402.D 104F5403.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 45.0 45.0 Ethylbenzene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 100 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill OFF-R2A.EXT 064F1401.D 064F1402.D 064F1403.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.417 5.00 1.84 87.0 2.11 ND Mill OFF-R2A.XAD-FH 106F5601.D 106F5602.D 106F5603.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 87.0 1.49 ND Mill OFF-R2A.XAD-BH 107F5701.D 107F5702.D 107F5703.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 87.0 1.49 ND Mill OFF-R2A.CT-FH 108F5801.D 108F5802.D 108F5803.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 87.0 1.49 ND Mill OFF-R2A.CT-BH 109F5901.D 109F5902.D 109F5903.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 87.0 1.49 ND 1.84 2.11 ND Mill OFF-R2B SPK.EXT 067F1701.D 067F1702.D 067F1703.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 100 1.81 ND Mill OFF-R2B SPK.XAD-FH 110F6001.D 110F6002.D 110F6003.D 2.59 1,039 0.259 1.49 1.49 1.49 0.0 9.18 8.98 9.11 1.2 9.09 1 5.00 45.4 100 45.4 Mill OFF-R2B SPK.XAD-BH 111F6101.D 111F6102.D 111F6103.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R2B SPK.CT-FH 112F6201.D 112F6202.D 112F6203.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R2B SPK.CT-BH 113F6301.D 113F6302.D 113F6303.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 45.4 45.4 Mill OFF-R3A.EXT 065F1501.D 065F1502.D 065F1503.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 87.0 2.09 ND Mill OFF-R3A.XAD-FH 114F6401.D 114F6402.D 114F6403.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 87.0 1.49 ND Mill OFF-R3A.XAD-BH 115F6501.D 115F6502.D 115F6503.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 87.0 1.49 ND Mill OFF-R3A.CT-FH 117F6701.D 117F6702.D 117F6703.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 87.0 1.49 ND Mill OFF-R3A.CT-BH 118F6801.D 118F6802.D 118F6803.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 87.0 1.49 ND 1.81 2.09 ND Mill OFF-R3B SPK.EXT 068F1801.D 068F1802.D 068F1803.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 100 1.81 ND Mill OFF-R3B SPK.XAD-FH 119F6901.D 119F6902.D 119F6903.D 2.59 1,039 0.259 1.49 1.49 1.49 0.0 9.07 8.97 8.99 0.7 9.01 1 5.00 45.1 100 45.1 Mill OFF-R3B SPK.XAD-BH 120F7001.D 120F7002.D 120F7003.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R3B SPK.CT-FH 122F7201.D 122F7202.D 122F7203.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R3B SPK.CT-BH 121F7101.D 121F7102.D 121F7103.D 2.59 1,039 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 45.1 45.1 MajorPageBreak Ethylbenzene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 101 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill ON-R1A.EXT 056F0601.D 056F0602.D 056F0603.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1.417 5.00 1.83 93.5 1.96 ND Mill ON-R1A.XAD-FH 069F1901.D 069F1902.D 069F1903.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 93.5 1.38 ND Mill ON-R1A.XAD-BH 070F2001.D 070F2002.D 070F2003.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 93.5 1.38 ND Mill ON-R1A.CT-FH 071F2101.D 071F2102.D 071F2103.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 93.5 1.38 ND Mill ON-R1A.CT-BH 073F2301.D 073F2302.D 073F2303.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 93.5 1.38 ND 1.83 1.96 ND Mill ON-R1B SPK.EXT 058F0801.D 058F0802.D 058F0803.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1.400 5.00 1.81 100 1.81 ND Mill ON-R1B SPK.XAD-FH 074F2401.D 074F2402.D 074F2403.D 2.58 1,036 0.258 1.56 1.56 1.56 0.0 10.3 10.1 10.3 1.2 10.2 1 5.00 51.1 100 51.1 Mill ON-R1B SPK.XAD-BH 076F2601.D 076F2602.D 076F2603.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND Mill ON-R1B SPK.CT-FH 077F2701.D 077F2702.D 077F2703.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND Mill ON-R1B SPK.CT-BH 078F2801.D 078F2802.D 078F2803.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND 51.1 51.1 Mill ON-R2A.EXT 057F0701.D 057F0702.D 057F0703.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1.400 5.00 1.81 93.5 1.93 ND Mill ON-R2A.XAD-FH 079F2901.D 079F2902.D 079F2903.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 93.5 1.38 ND Mill ON-R2A.XAD-BH 080F3001.D 080F3002.D 080F3003.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 93.5 1.38 ND Mill ON-R2A.CT-FH 081F3101.D 081F3102.D 081F3103.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 93.5 1.38 ND Mill ON-R2A.CT-BH 082F3201.D 082F3202.D 082F3203.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 93.5 1.38 ND 1.81 1.93 ND Mill ON-R2B SPK.EXT 060F1001.D 060F1002.D 060F1003.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1.400 5.00 1.81 100 1.81 ND Mill ON-R2B SPK.XAD-FH 084F3401.D 084F3402.D 084F3403.D 2.58 1,036 0.258 1.56 1.56 1.56 0.0 9.51 9.35 9.42 0.9 9.43 1 5.00 47.1 100 47.1 Mill ON-R2B SPK.XAD-BH 085F3501.D 085F3502.D 085F3503.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND Mill ON-R2B SPK.CT-FH 086F3601.D 086F3602.D 086F3603.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND Mill ON-R2B SPK.CT-BH 087F3701.D 087F3702.D 087F3703.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND 47.1 47.1 m-Xylene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 102 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill ON-R3A.XAD-FH 088F3801.D 088F3802.D 088F3803.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 93.5 1.38 ND Mill ON-R3A.XAD-BH 089F3901.D 089F3902.D 089F3903.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 93.5 1.38 ND Mill ON-R3A.CT-FH 090F4001.D 090F4002.D 090F4003.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 93.5 1.38 ND Mill ON-R3A.CT-BH 091F4101.D 091F4102.D 091F4103.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 93.5 1.38 ND 1.29 1.38 ND Mill ON-R3B SPK.EXT 062F1201.D 062F1202.D 062F1203.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1.167 5.00 1.51 100 1.51 ND Mill ON-R3B SPK.XAD-FH 092F4201.D 092F4202.D 092F4203.D 2.58 1,036 0.258 1.56 1.56 1.56 0.0 9.43 9.37 9.42 0.4 9.41 1 5.00 47.0 100 47.0 Mill ON-R3B SPK.XAD-BH 093F4301.D 093F4302.D 093F4303.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND Mill ON-R3B SPK.CT-FH 095F4501.D 095F4502.D 095F4503.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND Mill ON-R3B SPK.CT-BH 096F4601.D 096F4602.D 096F4603.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND 47.0 47.0 MajorPageBreak Mill OFF-R1A.EXT 063F1301.D 063F1302.D 063F1303.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1.417 5.00 1.83 91.0 2.01 ND Mill OFF-R1A.XAD-FH 097F4701.D 097F4702.D 097F4703.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 91.0 1.42 ND Mill OFF-R1A.XAD-BH 098F4801.D 098F4802.D 098F4803.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 91.0 1.42 ND Mill OFF-R1A.CT-FH 099F4901.D 099F4902.D 099F4903.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 91.0 1.42 ND Mill OFF-R1A.CT-BH 100F5001.D 100F5002.D 100F5003.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 91.0 1.42 ND 1.83 2.01 ND Mill OFF-R1B SPK.EXT 066F1601.D 066F1602.D 066F1603.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1.400 5.00 1.81 100 1.81 ND Mill OFF-R1B SPK.XAD-FH 101F5101.D 101F5102.D 101F5103.D 2.58 1,036 0.258 1.56 1.56 1.56 0.0 9.47 9.33 9.41 0.8 9.41 1 5.00 47.0 100 47.0 Mill OFF-R1B SPK.XAD-BH 102F5201.D 102F5202.D 102F5203.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND Mill OFF-R1B SPK.CT-FH 103F5301.D 103F5302.D 103F5303.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND Mill OFF-R1B SPK.CT-BH 104F5401.D 104F5402.D 104F5403.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND 47.0 47.0 m-Xylene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 103 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill OFF-R2A.EXT 064F1401.D 064F1402.D 064F1403.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1.417 5.00 1.83 91.0 2.01 ND Mill OFF-R2A.XAD-FH 106F5601.D 106F5602.D 106F5603.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 91.0 1.42 ND Mill OFF-R2A.XAD-BH 107F5701.D 107F5702.D 107F5703.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 91.0 1.42 ND Mill OFF-R2A.CT-FH 108F5801.D 108F5802.D 108F5803.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 91.0 1.42 ND Mill OFF-R2A.CT-BH 109F5901.D 109F5902.D 109F5903.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 91.0 1.42 ND 1.83 2.01 ND Mill OFF-R2B SPK.EXT 067F1701.D 067F1702.D 067F1703.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1.400 5.00 1.81 100 1.81 ND Mill OFF-R2B SPK.XAD-FH 110F6001.D 110F6002.D 110F6003.D 2.58 1,036 0.258 1.56 1.56 1.56 0.0 9.41 9.39 9.55 1.1 9.45 1 5.00 47.2 100 47.2 Mill OFF-R2B SPK.XAD-BH 111F6101.D 111F6102.D 111F6103.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND Mill OFF-R2B SPK.CT-FH 112F6201.D 112F6202.D 112F6203.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND Mill OFF-R2B SPK.CT-BH 113F6301.D 113F6302.D 113F6303.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND 47.2 47.2 Mill OFF-R3A.EXT 065F1501.D 065F1502.D 065F1503.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1.400 5.00 1.81 91.0 1.99 ND Mill OFF-R3A.XAD-FH 114F6401.D 114F6402.D 114F6403.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 91.0 1.42 ND Mill OFF-R3A.XAD-BH 115F6501.D 115F6502.D 115F6503.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 91.0 1.42 ND Mill OFF-R3A.CT-FH 117F6701.D 117F6702.D 117F6703.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 91.0 1.42 ND Mill OFF-R3A.CT-BH 118F6801.D 118F6802.D 118F6803.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 91.0 1.42 ND 1.81 1.99 ND Mill OFF-R3B SPK.EXT 068F1801.D 068F1802.D 068F1803.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1.400 5.00 1.81 100 1.81 ND Mill OFF-R3B SPK.XAD-FH 119F6901.D 119F6902.D 119F6903.D 2.58 1,036 0.258 1.56 1.56 1.56 0.0 9.43 9.43 9.44 0.1 9.43 1 5.00 47.2 100 47.2 Mill OFF-R3B SPK.XAD-BH 120F7001.D 120F7002.D 120F7003.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND Mill OFF-R3B SPK.CT-FH 122F7201.D 122F7202.D 122F7203.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND Mill OFF-R3B SPK.CT-BH 121F7101.D 121F7102.D 121F7103.D 2.58 1,036 0.258 NA NA NA NA 0.258 0.258 0.258 0.0 0.258 1 5.00 1.29 100 1.29 ND 47.2 47.2 MajorPageBreak m-Xylene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 104 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill ON-R1A.EXT 056F0601.D 056F0602.D 056F0603.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.417 5.00 1.84 98.4 1.87 ND Mill ON-R1A.XAD-FH 069F1901.D 069F1902.D 069F1903.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 98.4 1.32 ND Mill ON-R1A.XAD-BH 070F2001.D 070F2002.D 070F2003.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 98.4 1.32 ND Mill ON-R1A.CT-FH 071F2101.D 071F2102.D 071F2103.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 98.4 1.32 ND Mill ON-R1A.CT-BH 073F2301.D 073F2302.D 073F2303.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 98.4 1.32 ND 1.84 1.87 ND Mill ON-R1B SPK.EXT 058F0801.D 058F0802.D 058F0803.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.82 100 1.82 ND Mill ON-R1B SPK.XAD-FH 074F2401.D 074F2402.D 074F2403.D 2.59 1,040 0.259 4.53 4.53 4.53 0.0 10.3 10.1 10.2 1.0 10.2 1 5.00 51.1 100 51.1 Mill ON-R1B SPK.XAD-BH 076F2601.D 076F2602.D 076F2603.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R1B SPK.CT-FH 077F2701.D 077F2702.D 077F2703.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R1B SPK.CT-BH 078F2801.D 078F2802.D 078F2803.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 51.1 51.1 Mill ON-R2A.EXT 057F0701.D 057F0702.D 057F0703.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.82 98.4 1.85 ND Mill ON-R2A.XAD-FH 079F2901.D 079F2902.D 079F2903.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 98.4 1.32 ND Mill ON-R2A.XAD-BH 080F3001.D 080F3002.D 080F3003.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 98.4 1.32 ND Mill ON-R2A.CT-FH 081F3101.D 081F3102.D 081F3103.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 98.4 1.32 ND Mill ON-R2A.CT-BH 082F3201.D 082F3202.D 082F3203.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 98.4 1.32 ND 1.82 1.85 ND Mill ON-R2B SPK.EXT 060F1001.D 060F1002.D 060F1003.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.82 100 1.82 ND Mill ON-R2B SPK.XAD-FH 084F3401.D 084F3402.D 084F3403.D 2.59 1,040 0.259 4.53 4.53 4.53 0.0 10.3 10.2 10.2 0.5 10.2 1 5.00 51.1 100 51.1 Mill ON-R2B SPK.XAD-BH 085F3501.D 085F3502.D 085F3503.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R2B SPK.CT-FH 086F3601.D 086F3602.D 086F3603.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R2B SPK.CT-BH 087F3701.D 087F3702.D 087F3703.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 51.1 51.1 Naphthalene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 105 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill ON-R3A.XAD-FH 088F3801.D 088F3802.D 088F3803.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 98.4 1.32 ND Mill ON-R3A.XAD-BH 089F3901.D 089F3902.D 089F3903.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 98.4 1.32 ND Mill ON-R3A.CT-FH 090F4001.D 090F4002.D 090F4003.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 98.4 1.32 ND Mill ON-R3A.CT-BH 091F4101.D 091F4102.D 091F4103.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 98.4 1.32 ND 1.30 1.32 ND Mill ON-R3B SPK.EXT 062F1201.D 062F1202.D 062F1203.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.167 5.00 1.51 100 1.51 ND Mill ON-R3B SPK.XAD-FH 092F4201.D 092F4202.D 092F4203.D 2.59 1,040 0.259 4.53 4.53 4.53 0.0 10.2 10.3 10.3 0.7 10.3 1 5.00 51.3 100 51.3 Mill ON-R3B SPK.XAD-BH 093F4301.D 093F4302.D 093F4303.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R3B SPK.CT-FH 095F4501.D 095F4502.D 095F4503.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R3B SPK.CT-BH 096F4601.D 096F4602.D 096F4603.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 51.3 51.3 MajorPageBreak Mill OFF-R1A.EXT 063F1301.D 063F1302.D 063F1303.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.417 5.00 1.84 97.7 1.88 ND Mill OFF-R1A.XAD-FH 097F4701.D 097F4702.D 097F4703.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 97.7 1.33 ND Mill OFF-R1A.XAD-BH 098F4801.D 098F4802.D 098F4803.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 97.7 1.33 ND Mill OFF-R1A.CT-FH 099F4901.D 099F4902.D 099F4903.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 97.7 1.33 ND Mill OFF-R1A.CT-BH 100F5001.D 100F5002.D 100F5003.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 97.7 1.33 ND 1.84 1.88 ND Mill OFF-R1B SPK.EXT 066F1601.D 066F1602.D 066F1603.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.82 100 1.82 ND Mill OFF-R1B SPK.XAD-FH 101F5101.D 101F5102.D 101F5103.D 2.59 1,040 0.259 4.53 4.53 4.53 0.0 10.0 10.0 10.0 0.0 10.0 1 5.00 50.1 100 50.1 Mill OFF-R1B SPK.XAD-BH 102F5201.D 102F5202.D 102F5203.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R1B SPK.CT-FH 103F5301.D 103F5302.D 103F5303.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R1B SPK.CT-BH 104F5401.D 104F5402.D 104F5403.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 50.1 50.1 Naphthalene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 106 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill OFF-R2A.EXT 064F1401.D 064F1402.D 064F1403.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.417 5.00 1.84 97.7 1.88 ND Mill OFF-R2A.XAD-FH 106F5601.D 106F5602.D 106F5603.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 97.7 1.33 ND Mill OFF-R2A.XAD-BH 107F5701.D 107F5702.D 107F5703.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 97.7 1.33 ND Mill OFF-R2A.CT-FH 108F5801.D 108F5802.D 108F5803.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 97.7 1.33 ND Mill OFF-R2A.CT-BH 109F5901.D 109F5902.D 109F5903.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 97.7 1.33 ND 1.84 1.88 ND Mill OFF-R2B SPK.EXT 067F1701.D 067F1702.D 067F1703.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.82 100 1.82 ND Mill OFF-R2B SPK.XAD-FH 110F6001.D 110F6002.D 110F6003.D 2.59 1,040 0.259 4.53 4.53 4.53 0.0 10.0 9.90 9.91 1.0 9.95 1 5.00 49.8 100 49.8 Mill OFF-R2B SPK.XAD-BH 111F6101.D 111F6102.D 111F6103.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R2B SPK.CT-FH 112F6201.D 112F6202.D 112F6203.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R2B SPK.CT-BH 113F6301.D 113F6302.D 113F6303.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 49.8 49.8 Mill OFF-R3A.EXT 065F1501.D 065F1502.D 065F1503.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.82 97.7 1.86 ND Mill OFF-R3A.XAD-FH 114F6401.D 114F6402.D 114F6403.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 97.7 1.33 ND Mill OFF-R3A.XAD-BH 115F6501.D 115F6502.D 115F6503.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 97.7 1.33 ND Mill OFF-R3A.CT-FH 117F6701.D 117F6702.D 117F6703.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 97.7 1.33 ND Mill OFF-R3A.CT-BH 118F6801.D 118F6802.D 118F6803.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 97.7 1.33 ND 1.82 1.86 ND Mill OFF-R3B SPK.EXT 068F1801.D 068F1802.D 068F1803.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.82 100 1.82 ND Mill OFF-R3B SPK.XAD-FH 119F6901.D 119F6902.D 119F6903.D 2.59 1,040 0.259 4.53 4.53 4.53 0.0 10.6 10.5 10.5 0.7 10.5 1 5.00 52.6 100 52.6 Mill OFF-R3B SPK.XAD-BH 120F7001.D 120F7002.D 120F7003.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R3B SPK.CT-FH 122F7201.D 122F7202.D 122F7203.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R3B SPK.CT-BH 121F7101.D 121F7102.D 121F7103.D 2.59 1,040 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 52.6 52.6 MajorPageBreak Naphthalene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 107 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill ON-R1A.EXT 056F0601.D 056F0602.D 056F0603.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1.417 5.00 1.86 91.5 2.03 ND Mill ON-R1A.XAD-FH 069F1901.D 069F1902.D 069F1903.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 91.5 1.43 ND Mill ON-R1A.XAD-BH 070F2001.D 070F2002.D 070F2003.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 91.5 1.43 ND Mill ON-R1A.CT-FH 071F2101.D 071F2102.D 071F2103.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 91.5 1.43 ND Mill ON-R1A.CT-BH 073F2301.D 073F2302.D 073F2303.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 91.5 1.43 ND 1.86 2.03 ND Mill ON-R1B SPK.EXT 058F0801.D 058F0802.D 058F0803.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1.400 5.00 1.83 100 1.83 ND Mill ON-R1B SPK.XAD-FH 074F2401.D 074F2402.D 074F2403.D 2.62 1,051 0.262 1.78 1.78 1.78 0.0 10.2 9.90 10.2 2.0 10.1 1 5.00 50.5 100 50.5 Mill ON-R1B SPK.XAD-BH 076F2601.D 076F2602.D 076F2603.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND Mill ON-R1B SPK.CT-FH 077F2701.D 077F2702.D 077F2703.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND Mill ON-R1B SPK.CT-BH 078F2801.D 078F2802.D 078F2803.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND 50.5 50.5 Mill ON-R2A.EXT 057F0701.D 057F0702.D 057F0703.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1.400 5.00 1.83 91.5 2.00 ND Mill ON-R2A.XAD-FH 079F2901.D 079F2902.D 079F2903.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 91.5 1.43 ND Mill ON-R2A.XAD-BH 080F3001.D 080F3002.D 080F3003.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 91.5 1.43 ND Mill ON-R2A.CT-FH 081F3101.D 081F3102.D 081F3103.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 91.5 1.43 ND Mill ON-R2A.CT-BH 082F3201.D 082F3202.D 082F3203.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 91.5 1.43 ND 1.83 2.00 ND Mill ON-R2B SPK.EXT 060F1001.D 060F1002.D 060F1003.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1.400 5.00 1.83 100 1.83 ND Mill ON-R2B SPK.XAD-FH 084F3401.D 084F3402.D 084F3403.D 2.62 1,051 0.262 1.78 1.78 1.78 0.0 9.50 9.26 9.45 1.5 9.41 1 5.00 47.0 100 47.0 Mill ON-R2B SPK.XAD-BH 085F3501.D 085F3502.D 085F3503.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND Mill ON-R2B SPK.CT-FH 086F3601.D 086F3602.D 086F3603.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND Mill ON-R2B SPK.CT-BH 087F3701.D 087F3702.D 087F3703.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND 47.0 47.0 o-Xylene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 108 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill ON-R3A.XAD-FH 088F3801.D 088F3802.D 088F3803.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 91.5 1.43 ND Mill ON-R3A.XAD-BH 089F3901.D 089F3902.D 089F3903.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 91.5 1.43 ND Mill ON-R3A.CT-FH 090F4001.D 090F4002.D 090F4003.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 91.5 1.43 ND Mill ON-R3A.CT-BH 091F4101.D 091F4102.D 091F4103.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 91.5 1.43 ND 1.31 1.43 ND Mill ON-R3B SPK.EXT 062F1201.D 062F1202.D 062F1203.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1.167 5.00 1.53 100 1.53 ND Mill ON-R3B SPK.XAD-FH 092F4201.D 092F4202.D 092F4203.D 2.62 1,051 0.262 1.78 1.78 1.78 0.0 9.40 9.31 9.26 0.8 9.32 1 5.00 46.6 100 46.6 Mill ON-R3B SPK.XAD-BH 093F4301.D 093F4302.D 093F4303.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND Mill ON-R3B SPK.CT-FH 095F4501.D 095F4502.D 095F4503.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND Mill ON-R3B SPK.CT-BH 096F4601.D 096F4602.D 096F4603.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND 46.6 46.6 MajorPageBreak Mill OFF-R1A.EXT 063F1301.D 063F1302.D 063F1303.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1.417 5.00 1.86 89.6 2.07 ND Mill OFF-R1A.XAD-FH 097F4701.D 097F4702.D 097F4703.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 89.6 1.46 ND Mill OFF-R1A.XAD-BH 098F4801.D 098F4802.D 098F4803.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 89.6 1.46 ND Mill OFF-R1A.CT-FH 099F4901.D 099F4902.D 099F4903.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 89.6 1.46 ND Mill OFF-R1A.CT-BH 100F5001.D 100F5002.D 100F5003.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 89.6 1.46 ND 1.86 2.07 ND Mill OFF-R1B SPK.EXT 066F1601.D 066F1602.D 066F1603.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1.400 5.00 1.83 100 1.83 ND Mill OFF-R1B SPK.XAD-FH 101F5101.D 101F5102.D 101F5103.D 2.62 1,051 0.262 1.78 1.78 1.78 0.0 9.42 9.22 9.38 1.3 9.34 1 5.00 46.7 100 46.7 Mill OFF-R1B SPK.XAD-BH 102F5201.D 102F5202.D 102F5203.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND Mill OFF-R1B SPK.CT-FH 103F5301.D 103F5302.D 103F5303.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND Mill OFF-R1B SPK.CT-BH 104F5401.D 104F5402.D 104F5403.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND 46.7 46.7 o-Xylene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 109 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill OFF-R2A.EXT 064F1401.D 064F1402.D 064F1403.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1.417 5.00 1.86 89.6 2.07 ND Mill OFF-R2A.XAD-FH 106F5601.D 106F5602.D 106F5603.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 89.6 1.46 ND Mill OFF-R2A.XAD-BH 107F5701.D 107F5702.D 107F5703.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 89.6 1.46 ND Mill OFF-R2A.CT-FH 108F5801.D 108F5802.D 108F5803.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 89.6 1.46 ND Mill OFF-R2A.CT-BH 109F5901.D 109F5902.D 109F5903.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 89.6 1.46 ND 1.86 2.07 ND Mill OFF-R2B SPK.EXT 067F1701.D 067F1702.D 067F1703.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1.400 5.00 1.83 100 1.83 ND Mill OFF-R2B SPK.XAD-FH 110F6001.D 110F6002.D 110F6003.D 2.62 1,051 0.262 1.78 1.78 1.78 0.0 9.35 9.42 9.50 0.8 9.42 1 5.00 47.1 100 47.1 Mill OFF-R2B SPK.XAD-BH 111F6101.D 111F6102.D 111F6103.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND Mill OFF-R2B SPK.CT-FH 112F6201.D 112F6202.D 112F6203.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND Mill OFF-R2B SPK.CT-BH 113F6301.D 113F6302.D 113F6303.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND 47.1 47.1 Mill OFF-R3A.EXT 065F1501.D 065F1502.D 065F1503.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1.400 5.00 1.83 89.6 2.05 ND Mill OFF-R3A.XAD-FH 114F6401.D 114F6402.D 114F6403.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 89.6 1.46 ND Mill OFF-R3A.XAD-BH 115F6501.D 115F6502.D 115F6503.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 89.6 1.46 ND Mill OFF-R3A.CT-FH 117F6701.D 117F6702.D 117F6703.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 89.6 1.46 ND Mill OFF-R3A.CT-BH 118F6801.D 118F6802.D 118F6803.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 89.6 1.46 ND 1.83 2.05 ND Mill OFF-R3B SPK.EXT 068F1801.D 068F1802.D 068F1803.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1.400 5.00 1.83 100 1.83 ND Mill OFF-R3B SPK.XAD-FH 119F6901.D 119F6902.D 119F6903.D 2.62 1,051 0.262 1.78 1.78 1.78 0.0 9.41 9.55 9.52 0.9 9.49 1 5.00 47.5 100 47.5 Mill OFF-R3B SPK.XAD-BH 120F7001.D 120F7002.D 120F7003.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND Mill OFF-R3B SPK.CT-FH 122F7201.D 122F7202.D 122F7203.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND Mill OFF-R3B SPK.CT-BH 121F7101.D 121F7102.D 121F7103.D 2.62 1,051 0.262 NA NA NA NA 0.262 0.262 0.262 0.0 0.262 1 5.00 1.31 100 1.31 ND 47.5 47.5 MajorPageBreak o-Xylene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 110 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill ON-R1A.EXT 056F0601.D 056F0602.D 056F0603.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.417 5.00 1.84 88.6 2.07 ND Mill ON-R1A.XAD-FH 069F1901.D 069F1902.D 069F1903.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 88.6 1.46 ND Mill ON-R1A.XAD-BH 070F2001.D 070F2002.D 070F2003.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 88.6 1.46 ND Mill ON-R1A.CT-FH 071F2101.D 071F2102.D 071F2103.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 88.6 1.46 ND Mill ON-R1A.CT-BH 073F2301.D 073F2302.D 073F2303.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 88.6 1.46 ND 1.84 2.07 ND Mill ON-R1B SPK.EXT 058F0801.D 058F0802.D 058F0803.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 100 1.81 ND Mill ON-R1B SPK.XAD-FH 074F2401.D 074F2402.D 074F2403.D 2.57 1,031 0.259 1.54 1.54 1.54 0.0 9.68 9.61 9.61 0.5 9.63 1 5.00 48.2 100 48.2 Mill ON-R1B SPK.XAD-BH 076F2601.D 076F2602.D 076F2603.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R1B SPK.CT-FH 077F2701.D 077F2702.D 077F2703.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R1B SPK.CT-BH 078F2801.D 078F2802.D 078F2803.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 48.2 48.2 Mill ON-R2A.EXT 057F0701.D 057F0702.D 057F0703.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 88.6 2.05 ND Mill ON-R2A.XAD-FH 079F2901.D 079F2902.D 079F2903.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 88.6 1.46 ND Mill ON-R2A.XAD-BH 080F3001.D 080F3002.D 080F3003.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 88.6 1.46 ND Mill ON-R2A.CT-FH 081F3101.D 081F3102.D 081F3103.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 88.6 1.46 ND Mill ON-R2A.CT-BH 082F3201.D 082F3202.D 082F3203.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 88.6 1.46 ND 1.81 2.05 ND Mill ON-R2B SPK.EXT 060F1001.D 060F1002.D 060F1003.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 100 1.81 ND Mill ON-R2B SPK.XAD-FH 084F3401.D 084F3402.D 084F3403.D 2.57 1,031 0.259 1.54 1.54 1.54 0.0 8.94 8.86 8.81 0.8 8.87 1 5.00 44.3 100 44.3 Mill ON-R2B SPK.XAD-BH 085F3501.D 085F3502.D 085F3503.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R2B SPK.CT-FH 086F3601.D 086F3602.D 086F3603.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R2B SPK.CT-BH 087F3701.D 087F3702.D 087F3703.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 44.3 44.3 p-Xylene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 111 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill ON-R3A.XAD-FH 088F3801.D 088F3802.D 088F3803.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 88.6 1.46 ND Mill ON-R3A.XAD-BH 089F3901.D 089F3902.D 089F3903.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 88.6 1.46 ND Mill ON-R3A.CT-FH 090F4001.D 090F4002.D 090F4003.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 88.6 1.46 ND Mill ON-R3A.CT-BH 091F4101.D 091F4102.D 091F4103.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 88.6 1.46 ND 1.30 1.46 ND Mill ON-R3B SPK.EXT 062F1201.D 062F1202.D 062F1203.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.167 5.00 1.51 100 1.51 ND Mill ON-R3B SPK.XAD-FH 092F4201.D 092F4202.D 092F4203.D 2.57 1,031 0.259 1.54 1.54 1.54 0.0 8.89 8.87 8.93 0.4 8.90 1 5.00 44.5 100 44.5 Mill ON-R3B SPK.XAD-BH 093F4301.D 093F4302.D 093F4303.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R3B SPK.CT-FH 095F4501.D 095F4502.D 095F4503.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill ON-R3B SPK.CT-BH 096F4601.D 096F4602.D 096F4603.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 44.5 44.5 MajorPageBreak Mill OFF-R1A.EXT 063F1301.D 063F1302.D 063F1303.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.417 5.00 1.84 86.5 2.12 ND Mill OFF-R1A.XAD-FH 097F4701.D 097F4702.D 097F4703.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 86.5 1.50 ND Mill OFF-R1A.XAD-BH 098F4801.D 098F4802.D 098F4803.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 86.5 1.50 ND Mill OFF-R1A.CT-FH 099F4901.D 099F4902.D 099F4903.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 86.5 1.50 ND Mill OFF-R1A.CT-BH 100F5001.D 100F5002.D 100F5003.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 86.5 1.50 ND 1.84 2.12 ND Mill OFF-R1B SPK.EXT 066F1601.D 066F1602.D 066F1603.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 100 1.81 ND Mill OFF-R1B SPK.XAD-FH 101F5101.D 101F5102.D 101F5103.D 2.57 1,031 0.259 1.54 1.54 1.54 0.0 8.90 8.91 8.85 0.4 8.89 1 5.00 44.4 100 44.4 Mill OFF-R1B SPK.XAD-BH 102F5201.D 102F5202.D 102F5203.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R1B SPK.CT-FH 103F5301.D 103F5302.D 103F5303.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R1B SPK.CT-BH 104F5401.D 104F5402.D 104F5403.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 44.4 44.4 p-Xylene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 112 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill OFF-R2A.EXT 064F1401.D 064F1402.D 064F1403.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.417 5.00 1.84 86.5 2.12 ND Mill OFF-R2A.XAD-FH 106F5601.D 106F5602.D 106F5603.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 86.5 1.50 ND Mill OFF-R2A.XAD-BH 107F5701.D 107F5702.D 107F5703.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 86.5 1.50 ND Mill OFF-R2A.CT-FH 108F5801.D 108F5802.D 108F5803.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 86.5 1.50 ND Mill OFF-R2A.CT-BH 109F5901.D 109F5902.D 109F5903.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 86.5 1.50 ND 1.84 2.12 ND Mill OFF-R2B SPK.EXT 067F1701.D 067F1702.D 067F1703.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 100 1.81 ND Mill OFF-R2B SPK.XAD-FH 110F6001.D 110F6002.D 110F6003.D 2.57 1,031 0.259 1.54 1.54 1.54 0.0 9.01 8.88 8.98 0.8 8.95 1 5.00 44.8 100 44.8 Mill OFF-R2B SPK.XAD-BH 111F6101.D 111F6102.D 111F6103.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R2B SPK.CT-FH 112F6201.D 112F6202.D 112F6203.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R2B SPK.CT-BH 113F6301.D 113F6302.D 113F6303.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 44.8 44.8 Mill OFF-R3A.EXT 065F1501.D 065F1502.D 065F1503.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 86.5 2.10 ND Mill OFF-R3A.XAD-FH 114F6401.D 114F6402.D 114F6403.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 86.5 1.50 ND Mill OFF-R3A.XAD-BH 115F6501.D 115F6502.D 115F6503.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 86.5 1.50 ND Mill OFF-R3A.CT-FH 117F6701.D 117F6702.D 117F6703.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 86.5 1.50 ND Mill OFF-R3A.CT-BH 118F6801.D 118F6802.D 118F6803.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 86.5 1.50 ND 1.81 2.10 ND Mill OFF-R3B SPK.EXT 068F1801.D 068F1802.D 068F1803.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 100 1.81 ND Mill OFF-R3B SPK.XAD-FH 119F6901.D 119F6902.D 119F6903.D 2.57 1,031 0.259 1.54 1.54 1.54 0.0 8.94 8.89 8.88 0.4 8.90 1 5.00 44.5 100 44.5 Mill OFF-R3B SPK.XAD-BH 120F7001.D 120F7002.D 120F7003.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R3B SPK.CT-FH 122F7201.D 122F7202.D 122F7203.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND Mill OFF-R3B SPK.CT-BH 121F7101.D 121F7102.D 121F7103.D 2.57 1,031 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.30 100 1.30 ND 44.5 44.5 MajorPageBreak p-Xylene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 113 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill ON-R1A.EXT 056F0601.D 056F0602.D 056F0603.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1.417 5.00 1.92 94.6 2.03 ND Mill ON-R1A.XAD-FH 069F1901.D 069F1902.D 069F1903.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 94.6 1.44 ND Mill ON-R1A.XAD-BH 070F2001.D 070F2002.D 070F2003.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 94.6 1.44 ND Mill ON-R1A.CT-FH 071F2101.D 071F2102.D 071F2103.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 94.6 1.44 ND Mill ON-R1A.CT-BH 073F2301.D 073F2302.D 073F2303.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 94.6 1.44 ND 1.92 2.03 ND Mill ON-R1B SPK.EXT 058F0801.D 058F0802.D 058F0803.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1.400 5.00 1.90 100 1.90 ND Mill ON-R1B SPK.XAD-FH 074F2401.D 074F2402.D 074F2403.D 2.72 1,090 0.272 2.16 2.16 2.16 0.0 10.8 10.7 10.7 0.5 10.7 1 5.00 53.7 100 53.7 Mill ON-R1B SPK.XAD-BH 076F2601.D 076F2602.D 076F2603.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND Mill ON-R1B SPK.CT-FH 077F2701.D 077F2702.D 077F2703.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND Mill ON-R1B SPK.CT-BH 078F2801.D 078F2802.D 078F2803.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND 53.7 53.7 Mill ON-R2A.EXT 057F0701.D 057F0702.D 057F0703.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1.400 5.00 1.90 94.6 2.01 ND Mill ON-R2A.XAD-FH 079F2901.D 079F2902.D 079F2903.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 94.6 1.44 ND Mill ON-R2A.XAD-BH 080F3001.D 080F3002.D 080F3003.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 94.6 1.44 ND Mill ON-R2A.CT-FH 081F3101.D 081F3102.D 081F3103.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 94.6 1.44 ND Mill ON-R2A.CT-BH 082F3201.D 082F3202.D 082F3203.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 94.6 1.44 ND 1.90 2.01 ND Mill ON-R2B SPK.EXT 060F1001.D 060F1002.D 060F1003.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1.400 5.00 1.90 100 1.90 ND Mill ON-R2B SPK.XAD-FH 084F3401.D 084F3402.D 084F3403.D 2.72 1,090 0.272 2.16 2.16 2.16 0.0 10.2 10.2 10.0 1.0 10.1 1 5.00 50.7 100 50.7 Mill ON-R2B SPK.XAD-BH 085F3501.D 085F3502.D 085F3503.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND Mill ON-R2B SPK.CT-FH 086F3601.D 086F3602.D 086F3603.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND Mill ON-R2B SPK.CT-BH 087F3701.D 087F3702.D 087F3703.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND 50.7 50.7 Styrene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 114 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill ON-R3A.XAD-FH 088F3801.D 088F3802.D 088F3803.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 94.6 1.44 ND Mill ON-R3A.XAD-BH 089F3901.D 089F3902.D 089F3903.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 94.6 1.44 ND Mill ON-R3A.CT-FH 090F4001.D 090F4002.D 090F4003.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 94.6 1.44 ND Mill ON-R3A.CT-BH 091F4101.D 091F4102.D 091F4103.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 94.6 1.44 ND 1.36 1.44 ND Mill ON-R3B SPK.EXT 062F1201.D 062F1202.D 062F1203.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1.167 5.00 1.59 100 1.59 ND Mill ON-R3B SPK.XAD-FH 092F4201.D 092F4202.D 092F4203.D 2.72 1,090 0.272 2.16 2.16 2.16 0.0 9.97 10.1 10.1 0.8 10.0 1 5.00 50.2 100 50.2 Mill ON-R3B SPK.XAD-BH 093F4301.D 093F4302.D 093F4303.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND Mill ON-R3B SPK.CT-FH 095F4501.D 095F4502.D 095F4503.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND Mill ON-R3B SPK.CT-BH 096F4601.D 096F4602.D 096F4603.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND 50.2 50.2 MajorPageBreak Mill OFF-R1A.EXT 063F1301.D 063F1302.D 063F1303.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1.417 5.00 1.92 92.6 2.08 ND Mill OFF-R1A.XAD-FH 097F4701.D 097F4702.D 097F4703.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 92.6 1.47 ND Mill OFF-R1A.XAD-BH 098F4801.D 098F4802.D 098F4803.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 92.6 1.47 ND Mill OFF-R1A.CT-FH 099F4901.D 099F4902.D 099F4903.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 92.6 1.47 ND Mill OFF-R1A.CT-BH 100F5001.D 100F5002.D 100F5003.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 92.6 1.47 ND 1.92 2.08 ND Mill OFF-R1B SPK.EXT 066F1601.D 066F1602.D 066F1603.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1.400 5.00 1.90 100 1.90 ND Mill OFF-R1B SPK.XAD-FH 101F5101.D 101F5102.D 101F5103.D 2.72 1,090 0.272 2.16 2.16 2.16 0.0 9.96 10.0 9.98 0.3 9.98 1 5.00 49.9 100 49.9 Mill OFF-R1B SPK.XAD-BH 102F5201.D 102F5202.D 102F5203.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND Mill OFF-R1B SPK.CT-FH 103F5301.D 103F5302.D 103F5303.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND Mill OFF-R1B SPK.CT-BH 104F5401.D 104F5402.D 104F5403.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND 49.9 49.9 Styrene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 115 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill OFF-R2A.EXT 064F1401.D 064F1402.D 064F1403.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1.417 5.00 1.92 92.6 2.08 ND Mill OFF-R2A.XAD-FH 106F5601.D 106F5602.D 106F5603.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 92.6 1.47 ND Mill OFF-R2A.XAD-BH 107F5701.D 107F5702.D 107F5703.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 92.6 1.47 ND Mill OFF-R2A.CT-FH 108F5801.D 108F5802.D 108F5803.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 92.6 1.47 ND Mill OFF-R2A.CT-BH 109F5901.D 109F5902.D 109F5903.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 92.6 1.47 ND 1.92 2.08 ND Mill OFF-R2B SPK.EXT 067F1701.D 067F1702.D 067F1703.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1.400 5.00 1.90 100 1.90 ND Mill OFF-R2B SPK.XAD-FH 110F6001.D 110F6002.D 110F6003.D 2.72 1,090 0.272 2.16 2.16 2.16 0.0 10.3 10.0 10.1 1.6 10.1 1 5.00 50.6 100 50.6 Mill OFF-R2B SPK.XAD-BH 111F6101.D 111F6102.D 111F6103.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND Mill OFF-R2B SPK.CT-FH 112F6201.D 112F6202.D 112F6203.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND Mill OFF-R2B SPK.CT-BH 113F6301.D 113F6302.D 113F6303.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND 50.6 50.6 Mill OFF-R3A.EXT 065F1501.D 065F1502.D 065F1503.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1.400 5.00 1.90 92.6 2.05 ND Mill OFF-R3A.XAD-FH 114F6401.D 114F6402.D 114F6403.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 92.6 1.47 ND Mill OFF-R3A.XAD-BH 115F6501.D 115F6502.D 115F6503.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 92.6 1.47 ND Mill OFF-R3A.CT-FH 117F6701.D 117F6702.D 117F6703.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 92.6 1.47 ND Mill OFF-R3A.CT-BH 118F6801.D 118F6802.D 118F6803.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 92.6 1.47 ND 1.90 2.05 ND Mill OFF-R3B SPK.EXT 068F1801.D 068F1802.D 068F1803.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1.400 5.00 1.90 100 1.90 ND Mill OFF-R3B SPK.XAD-FH 119F6901.D 119F6902.D 119F6903.D 2.72 1,090 0.272 2.16 2.16 2.16 0.0 10.3 10.1 10.1 1.6 10.2 1 5.00 50.8 100 50.8 Mill OFF-R3B SPK.XAD-BH 120F7001.D 120F7002.D 120F7003.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND Mill OFF-R3B SPK.CT-FH 122F7201.D 122F7202.D 122F7203.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND Mill OFF-R3B SPK.CT-BH 121F7101.D 121F7102.D 121F7103.D 2.72 1,090 0.272 NA NA NA NA 0.272 0.272 0.272 0.0 0.272 1 5.00 1.36 100 1.36 ND 50.8 50.8 MajorPageBreak Styrene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 116 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill ON-R1A.EXT 056F0601.D 056F0602.D 056F0603.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.417 5.00 1.83 114 1.61 ND Mill ON-R1A.XAD-FH 069F1901.D 069F1902.D 069F1903.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 1.94 2.05 1.87 4.8 1.95 1 5.00 9.76 114 8.55 J Mill ON-R1A.XAD-BH 070F2001.D 070F2002.D 070F2003.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 114 1.13 ND Mill ON-R1A.CT-FH 071F2101.D 071F2102.D 071F2103.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 114 1.13 ND Mill ON-R1A.CT-BH 073F2301.D 073F2302.D 073F2303.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 114 1.13 ND 9.76 8.55 J Mill ON-R1B SPK.EXT 058F0801.D 058F0802.D 058F0803.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 100 1.81 ND Mill ON-R1B SPK.XAD-FH 074F2401.D 074F2402.D 074F2403.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 9.59 9.60 9.46 1.0 9.55 1 5.00 47.8 100 47.8 Mill ON-R1B SPK.XAD-BH 076F2601.D 076F2602.D 076F2603.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 3.15 3.12 3.07 1.4 3.11 1 5.00 15.6 100 15.6 Mill ON-R1B SPK.CT-FH 077F2701.D 077F2702.D 077F2703.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 1.94 1.89 1.93 1.6 1.92 1 5.00 9.62 100 9.62 J Mill ON-R1B SPK.CT-BH 078F2801.D 078F2802.D 078F2803.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 100 1.29 ND 72.9 72.9 Mill ON-R2A.EXT 057F0701.D 057F0702.D 057F0703.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 114 1.59 ND Mill ON-R2A.XAD-FH 079F2901.D 079F2902.D 079F2903.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 114 1.13 ND Mill ON-R2A.XAD-BH 080F3001.D 080F3002.D 080F3003.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 114 1.13 ND Mill ON-R2A.CT-FH 081F3101.D 081F3102.D 081F3103.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 114 1.13 ND Mill ON-R2A.CT-BH 082F3201.D 082F3202.D 082F3203.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 114 1.13 ND 1.81 1.59 ND Mill ON-R2B SPK.EXT 060F1001.D 060F1002.D 060F1003.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 100 1.81 ND Mill ON-R2B SPK.XAD-FH 084F3401.D 084F3402.D 084F3403.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 6.06 6.34 6.08 3.0 6.16 1 5.00 30.8 100 30.8 Mill ON-R2B SPK.XAD-BH 085F3501.D 085F3502.D 085F3503.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 2.46 2.40 2.48 1.9 2.44 1 5.00 12.2 100 12.2 J Mill ON-R2B SPK.CT-FH 086F3601.D 086F3602.D 086F3603.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 2.51 2.51 2.49 0.6 2.50 1 5.00 12.5 100 12.5 J Mill ON-R2B SPK.CT-BH 087F3701.D 087F3702.D 087F3703.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 100 1.29 ND 55.5 55.5 Toluene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 117 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill ON-R3A.XAD-FH 088F3801.D 088F3802.D 088F3803.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 114 1.13 ND Mill ON-R3A.XAD-BH 089F3901.D 089F3902.D 089F3903.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 114 1.13 ND Mill ON-R3A.CT-FH 090F4001.D 090F4002.D 090F4003.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 114 1.13 ND Mill ON-R3A.CT-BH 091F4101.D 091F4102.D 091F4103.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 114 1.13 ND 1.29 1.13 ND Mill ON-R3B SPK.EXT 062F1201.D 062F1202.D 062F1203.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.167 5.00 1.51 100 1.51 ND Mill ON-R3B SPK.XAD-FH 092F4201.D 092F4202.D 092F4203.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 6.13 6.42 6.18 2.8 6.24 1 5.00 31.2 100 31.2 Mill ON-R3B SPK.XAD-BH 093F4301.D 093F4302.D 093F4303.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 2.32 2.22 2.21 2.9 2.25 1 5.00 11.3 100 11.3 J Mill ON-R3B SPK.CT-FH 095F4501.D 095F4502.D 095F4503.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 3.28 3.24 3.35 1.8 3.29 1 5.00 16.5 100 16.5 Mill ON-R3B SPK.CT-BH 096F4601.D 096F4602.D 096F4603.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 100 1.29 ND 58.9 58.9 MajorPageBreak Mill OFF-R1A.EXT 063F1301.D 063F1302.D 063F1303.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.417 5.00 1.83 120 1.53 ND Mill OFF-R1A.XAD-FH 097F4701.D 097F4702.D 097F4703.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 120 1.08 ND Mill OFF-R1A.XAD-BH 098F4801.D 098F4802.D 098F4803.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 120 1.08 ND Mill OFF-R1A.CT-FH 099F4901.D 099F4902.D 099F4903.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 120 1.08 ND Mill OFF-R1A.CT-BH 100F5001.D 100F5002.D 100F5003.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 120 1.08 ND 1.83 1.53 ND Mill OFF-R1B SPK.EXT 066F1601.D 066F1602.D 066F1603.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 100 1.81 ND Mill OFF-R1B SPK.XAD-FH 101F5101.D 101F5102.D 101F5103.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 8.60 8.87 8.64 1.9 8.71 1 5.00 43.5 100 43.5 Mill OFF-R1B SPK.XAD-BH 102F5201.D 102F5202.D 102F5203.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 2.17 2.18 2.26 2.5 2.20 1 5.00 11.0 100 11.0 J Mill OFF-R1B SPK.CT-FH 103F5301.D 103F5302.D 103F5303.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 2.52 2.47 2.50 1.1 2.50 1 5.00 12.5 100 12.5 J Mill OFF-R1B SPK.CT-BH 104F5401.D 104F5402.D 104F5403.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 100 1.29 ND 67.0 67.0 Toluene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 118 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Client's Sample Name Filename #1 Filename #2 Filename #3 Curve Min Curve Max MDL Ret Time (min) Ret Time (min) Ret Time (min) %dif RT Conc #1 (ug/mL) Conc #2 (ug/mL) Conc #3 (ug/mL) %dif conc Avg Conc (ug/mL) DF * Aliquot Factor Liquid Vol (mL) Catch Weight (ug) Rec Eff (%) Adj. Catch Weight (ug) Flag Mill OFF-R2A.EXT 064F1401.D 064F1402.D 064F1403.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.417 5.00 1.83 120 1.53 ND Mill OFF-R2A.XAD-FH 106F5601.D 106F5602.D 106F5603.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 120 1.08 ND Mill OFF-R2A.XAD-BH 107F5701.D 107F5702.D 107F5703.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 120 1.08 ND Mill OFF-R2A.CT-FH 108F5801.D 108F5802.D 108F5803.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 120 1.08 ND Mill OFF-R2A.CT-BH 109F5901.D 109F5902.D 109F5903.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 120 1.08 ND 1.83 1.53 ND Mill OFF-R2B SPK.EXT 067F1701.D 067F1702.D 067F1703.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 100 1.81 ND Mill OFF-R2B SPK.XAD-FH 110F6001.D 110F6002.D 110F6003.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 6.95 6.81 6.80 1.4 6.85 1 5.00 34.3 100 34.3 Mill OFF-R2B SPK.XAD-BH 111F6101.D 111F6102.D 111F6103.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 1.80 1.83 2.00 6.6 1.88 1 5.00 9.38 100 9.38 J Mill OFF-R2B SPK.CT-FH 112F6201.D 112F6202.D 112F6203.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 2.21 2.18 2.30 3.2 2.23 1 5.00 11.2 100 11.2 J Mill OFF-R2B SPK.CT-BH 113F6301.D 113F6302.D 113F6303.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 100 1.29 ND 54.8 54.8 Mill OFF-R3A.EXT 065F1501.D 065F1502.D 065F1503.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 120 1.51 ND Mill OFF-R3A.XAD-FH 114F6401.D 114F6402.D 114F6403.D 2.59 1,038 0.259 1.13 1.13 1.13 0.1 3.42 3.43 3.38 0.9 3.41 1 5.00 17.0 120 14.2 Mill OFF-R3A.XAD-BH 115F6501.D 115F6502.D 115F6503.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 120 1.08 ND Mill OFF-R3A.CT-FH 117F6701.D 117F6702.D 117F6703.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 120 1.08 ND Mill OFF-R3A.CT-BH 118F6801.D 118F6802.D 118F6803.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 120 1.08 ND 17.0 14.2 Mill OFF-R3B SPK.EXT 068F1801.D 068F1802.D 068F1803.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1.400 5.00 1.81 100 1.81 ND Mill OFF-R3B SPK.XAD-FH 119F6901.D 119F6902.D 119F6903.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 9.85 9.83 9.73 0.8 9.80 1 5.00 49.0 100 49.0 Mill OFF-R3B SPK.XAD-BH 120F7001.D 120F7002.D 120F7003.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 3.80 3.85 3.72 1.8 3.79 1 5.00 19.0 100 19.0 Mill OFF-R3B SPK.CT-FH 122F7201.D 122F7202.D 122F7203.D 2.59 1,038 0.259 1.13 1.13 1.13 0.0 2.73 2.74 2.73 0.2 2.73 1 5.00 13.7 100 13.7 Mill OFF-R3B SPK.CT-BH 121F7101.D 121F7102.D 121F7103.D 2.59 1,038 0.259 NA NA NA NA 0.259 0.259 0.259 0.0 0.259 1 5.00 1.29 100 1.29 ND 81.6 81.6 Toluene 0623-247R EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 119 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Analyte: Benzene Spike Amount Flag Catch (ug) Sample Volume Recovery (%) Mill ON Run 1 52.7 Spiked Train 67.8 47.300 Un-spiked Train 25.9 47.639 Spike Amount Flag Catch (ug)Recovery (%) Mill ON Run 2 52.7 Spiked Train 68.5 42.716 Un-spiked Train 18.9 42.979 Spike Amount Flag Catch (ug)Recovery (%) Mill ON Run 3 52.7 Spiked Train 71.6 46.248 Un-spiked Train 20.4 46.447 Analyte: Benzene Spike Amount Flag Catch (ug) Sample Volume Recovery (%) Mill OFF Run 1 52.7 Spiked Train 60.3 47.344 Un-spiked Train 17.2 47.636 Spike Amount Flag Recovery (%) Mill OFF Run 2 52.7 Spiked Train 65.0 47.383 Un-spiked Train 20.3 47.679 Spike Amount Flag Recovery (%) Mill OFF Run 3 52.7 Spiked Train 67.8 47.003 Un-spiked Train 18.7 47.294 Spike and Recovery Calculations 79.9% 94.2% 97.3% Average Recovery 90.5% 82.1% 85.0% 93.3% Average Recovery 86.8% 0623-247 EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 120 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Spike and Recovery Calculations Analyte: Ethylbenzene Spike Amount Flag Catch (ug) Sample Volume Recovery (%) Mill ON Run 1 52.0 Spiked Train 49.3 47.300 Un-spiked Train ND 1.84 47.639 Spike Amount Recovery (%) Mill ON Run 2 52.0 Spiked Train 44.8 42.716 Un-spiked Train ND 1.81 42.979 Spike Amount Recovery (%) Mill ON Run 3 52.0 Spiked Train 45.2 46.248 Un-spiked Train ND 1.30 46.447 Analyte: Ethylbenzene Spike Amount Flag Catch (ug) Sample Volume Recovery (%) Mill OFF Run 1 52.0 Spiked Train 45.0 47.344 Un-spiked Train ND 1.84 47.636 Spike Amount Recovery (%) Mill OFF Run 2 52.0 Spiked Train 45.4 47.383 Un-spiked Train ND 1.84 47.679 Spike Amount Recovery (%) Mill OFF Run 3 52.0 Spiked Train 45.1 47.003 Un-spiked Train ND 1.81 47.294 87.5% 94.9% 86.1% 87.0% Average Recovery 89.4% 86.7% 86.7% Average Recovery 87.0% 0623-247 EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 121 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Spike and Recovery Calculations Analyte: m-xylene Spike Amount Flag Catch (ug) Sample Volume Recovery (%) Mill ON Run 1 51.8 Spiked Train 51.1 47.300 Un-spiked Train ND 1.83 47.639 Spike Amount Recovery (%) Mill ON Run 2 51.8 Spiked Train 47.1 42.716 Un-spiked Train ND 1.81 42.979 Spike Amount Recovery (%) Mill ON Run 3 51.8 Spiked Train 47.0 46.248 Un-spiked Train ND 1.29 46.447 Analyte: m-xylene Spike Amount Flag Catch (ug) Sample Volume Recovery (%) Mill OFF Run 1 51.8 Spiked Train 47.0 47.344 Un-spiked Train ND 1.83 47.636 Spike Amount Recovery (%) Mill OFF Run 2 51.8 Spiked Train 47.2 47.383 Un-spiked Train ND 1.83 47.679 Spike Amount Recovery (%) Mill OFF Run 3 51.8 Spiked Train 47.2 47.003 Un-spiked Train ND 1.81 47.294 Average Recovery 91.0% 98.7% 91.0% 90.8% Average Recovery 93.5% 90.8% 91.2% 91.1% 0623-247 EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 122 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Spike and Recovery Calculations Analyte: Naphthalene Spike Amount Flag Catch (ug) Sample Volume Recovery (%) Mill ON Run 1 52.0 Spiked Train 51.1 47.300 Un-spiked Train ND 1.84 47.639 Spike Amount Recovery (%) Mill ON Run 2 52.0 Spiked Train 51.1 42.716 Un-spiked Train ND 1.82 42.979 Spike Amount Recovery (%) Mill ON Run 3 52.0 Spiked Train 51.3 46.248 Un-spiked Train ND 1.30 46.447 Analyte: Naphthalene Spike Amount Flag Catch (ug) Sample Volume Recovery (%) Mill OFF Run 1 52.0 Spiked Train 50.1 47.344 Un-spiked Train ND 1.84 47.636 Spike Amount Recovery (%) Mill OFF Run 2 52.0 Spiked Train 49.8 47.383 Un-spiked Train ND 1.84 47.679 Spike Amount Recovery (%) Mill OFF Run 3 52.0 Spiked Train 52.6 47.003 Un-spiked Train ND 1.82 47.294 98.3% 98.2% 98.6% Average Recovery 98.4% 96.3% 95.7% 101% Average Recovery 97.7% 0623-247 EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 123 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Spike and Recovery Calculations Analyte: o-xylene Spike Amount Flag Catch (ug) Sample Volume Recovery (%) Mill ON Run 1 52.5 Spiked Train 50.5 47.300 Un-spiked Train ND 1.86 47.639 Spike Amount Recovery (%) Mill ON Run 2 52.5 Spiked Train 47.0 42.716 Un-spiked Train ND 1.83 42.979 Spike Amount Recovery (%) Mill ON Run 3 52.5 Spiked Train 46.6 46.248 Un-spiked Train ND 1.31 46.447 Analyte: o-xylene Spike Amount Flag Catch (ug) Sample Volume Recovery (%) Mill OFF Run 1 52.5 Spiked Train 46.7 47.344 Un-spiked Train ND 1.86 47.636 Spike Amount Recovery (%) Mill OFF Run 2 52.5 Spiked Train 47.1 47.383 Un-spiked Train ND 1.86 47.679 Spike Amount Recovery (%) Mill OFF Run 3 52.5 Spiked Train 47.5 47.003 Un-spiked Train ND 1.83 47.294 89.5% 96.2% 88.7% Average Recovery 91.5% 88.9% 89.7% 90.3% Average Recovery 89.6% 0623-247 EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 124 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Spike and Recovery Calculations Analyte: p-xylene Spike Amount Flag Catch (ug) Sample Volume Recovery (%) Mill ON Run 1 51.6 Spiked Train 48.2 47.300 Un-spiked Train ND 1.84 47.639 Spike Amount Flag Recovery (%) Mill ON Run 2 51.6 Spiked Train 44.3 42.716 Un-spiked Train ND 1.81 42.979 Spike Amount Flag Recovery (%) Mill ON Run 3 51.6 Spiked Train 44.5 46.248 Un-spiked Train ND 1.30 46.447 Analyte: p-xylene Spike Amount Flag Catch (ug) Sample Volume Recovery (%) Mill OFF Run 1 51.6 Spiked Train 44.4 47.344 Un-spiked Train ND 1.84 47.636 Spike Amount Flag Recovery (%) Mill OFF Run 2 51.6 Spiked Train 44.8 47.383 Un-spiked Train ND 1.84 47.679 Spike Amount Flag Recovery (%) Mill OFF Run 3 51.6 Spiked Train 44.5 47.003 Un-spiked Train ND 1.81 47.294 Average Recovery 88.6% 93.4% 86.0% 86.3% 86.2% 86.8% 86.3% Average Recovery 86.5% 0623-247 EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 125 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Spike and Recovery Calculations Analyte: Styrene Spike Amount Flag Catch (ug) Sample Volume Recovery (%) Mill ON Run 1 54.5 Spiked Train 53.7 47.300 Un-spiked Train ND 1.92 47.639 Spike Amount Flag Recovery (%) Mill ON Run 2 54.5 Spiked Train 50.7 42.716 Un-spiked Train ND 1.90 42.979 Spike Amount Flag Recovery (%) Mill ON Run 3 54.5 Spiked Train 50.2 46.248 Un-spiked Train ND 1.36 46.447 Analyte: Styrene Spike Amount Flag Catch (ug) Sample Volume Recovery (%) Mill OFF Run 1 54.5 Spiked Train 49.9 47.344 Un-spiked Train ND 1.92 47.636 Spike Amount Flag Recovery (%) Mill OFF Run 2 54.5 Spiked Train 50.6 47.383 Un-spiked Train ND 1.92 47.679 Spike Amount Flag Recovery (%) Mill OFF Run 3 54.5 Spiked Train 50.8 47.003 Un-spiked Train ND 1.90 47.294 92.9% 98.6% 93.0% 92.2% Average Recovery 94.6% 91.6% 93.2% Average Recovery 92.6% 0623-247 EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 126 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack Spike and Recovery Calculations Analyte: Toluene Spike Amount Flag Catch (ug) Sample Volume Recovery (%) Mill ON Run 1 51.9 Spiked Train 72.9 47.300 Un-spiked Train J 9.76 47.639 Spike Amount Flag Recovery (%) Mill ON Run 2 51.9 Spiked Train 55.5 42.716 Un-spiked Train ND 1.8 42.979 Spike Amount Flag Recovery (%) Mill ON Run 3 51.9 Spiked Train 58.9 46.248 Un-spiked Train ND 1.29 46.447 Analyte: Toluene Spike Amount Flag Catch (ug) Sample Volume Recovery (%) Mill OFF Run 1 51.9 Spiked Train 67.0 47.344 Un-spiked Train ND 1.83 47.636 Spike Amount Flag Recovery (%) Mill OFF Run 2 51.9 Spiked Train 54.8 47.383 Un-spiked Train ND 1.83 47.679 Spike Amount Flag Recovery (%) Mill OFF Run 3 51.9 Spiked Train 81.6 47.003 Un-spiked Train 17.0 47.294 Average Recovery 120% 122% 107% 114% Average Recovery 114% 129% 106% 125% 0623-247 EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 127 of 640 ©Mostardi Platt Enthalpy Analytical Company: Mostardi Platt Environmental - Elmhurst Job No.: 0623-247 - EPA Method 18 (5-fraction) Analysis Client No.: M232904 Site: LH-DS Kiln Stack QC Samples QC Type QC Sample Name Benzene Ethylbenzene m-Xylene Naphthalene o-Xylene p-Xylene Styrene Toluene Spiked Blank Solvent gcprep5590 #LCS-EXT catch (ug)48.7 45.0 45.3 45.6 45.4 43.8 46.8 45.6 spiked:spike (ug)52.7 52.0 51.8 52.0 52.5 51.6 54.5 51.9 gcstds1971.6 * 50uL recovery 92.3% 86.7% 87.5% 87.7% 86.4% 85.0% 86.0% 87.8% Spiked Blank Tube gcprep5590 #LCS-XAD catch (ug)45.8 45.3 45.5 45.7 45.2 44.1 46.8 44.9 spiked:spike (ug)52.7 52.0 51.8 52.0 52.5 51.6 54.5 51.9 gcstds1971.6 * 50uL recovery 86.8% 87.1% 87.9% 88.0% 86.1% 85.5% 85.8% 86.5% Lab Dup 0623-247.ON-R1-SPK-LD.EXT ug/mL ND ND ND ND ND ND ND ND 0623-247.ON-R1-SPK.EXT ug/mL ND ND ND ND ND ND ND ND RD NA NA NA NA NA NA NA NA Lab Dup 0623-247.ON-R1-SPK-LD.FH-XAD ug/mL 2.77 9.82 10.2 10.2 10.0 9.64 10.7 9.50 0623-247.ON-R1-SPK.FH-XAD ug/mL 2.84 9.87 10.2 10.2 10.1 9.63 10.7 9.55 RD 2.6%0.5%0.5%0.5%0.6%0.0%0.7%0.6% Blank Solvent gcprep5590 #MB-EXT ug/mL ND ND ND ND ND ND ND ND Blank Media gcprep5590 #MB-CT ug/mL ND ND ND ND ND ND ND ND Blank Media gcprep5590 #MB-XAD ug/mL ND ND ND ND ND ND ND ND 0623-247 EPA Method 18 ResultsProject No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 128 of 640 ©Mostardi Platt Narrative Summary Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 129 of 640 ©Mostardi Platt Custody Alyssa Miller received the samples on 7/25/23 at 9.9 ºC after being relinquished by Mostardi Platt Environmental - Elmhurst. The condensate fraction of Sample Mill ON Run 3A was received with the lid off the container and was empty. The other samples were received in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, LLC. Analysis The samples were analyzed for benzene, ethylbenzene, toluene, styrene, naphthalene, o-xylene, m-xylene, and p-xylene using the analytical procedures in EPA Method 18, Measurement of Gaseous Organic Compound Emissions by Gas Chromatography (40 CFR Part 60, Appendix A). The standards and samples were analyzed following the procedures specified in section 8.2.4, Adsorption Tube Procedure. Each sample train consisted of one condensate, followed by one XAD-2 tube, followed by one charcoal tube, in series. Prior to extraction, 10 mL was archived from each condensate fraction. The remaining condensate was then extracted with 5 mL of carbon disulfide and shaken. To account for the removed volume, an aliquot factor was applied to the extract condensate fractions. Both the SKC XAD-2 (Cat #226-30-06) tubes and SKC charcoal (Cat # 226-16) tubes were desorbed in two fractions: front half (FH) and back half (BH). All fractions were desorbed using 5 mL of a solution and shaken. The tubes were desorbed on 7/25/23. The Gas Chromatograph "Mufasa" was equipped with a Flame Ionization Detector for these analyses. Calibration The calibration curve is located in the back of this report. For each calibration curve used, the first page of the curve contains all method specific parameters (i.e., curve type, origin, weight, etc.) used to quantify the samples. The calibration curve section also includes a table with the Retention Time (RetTime), Level (Lvl), Amount (corresponding units), Area, Response Factor (Amt/Area) and the analyte Name. The calibration table is used to identify (by retention time) and quantify each target compound. Chrom. Conditions The acquisition method (MUFASA219.M) may be made available upon request. Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 130 of 640 ©Mostardi Platt QC Notes None of the compounds of interest were identified at levels greater than their MDL in the analyses of the laboratory blanks. A Laboratory Duplicate (LD) was analyzed using aliquots of samples Mill ON Run 1 Spike (.EXT, and .XAD-FH). The original and duplicate analyses differed by no more than 0.7%. As required by section 8.4.3, Recovery Study for Adsorption Tube Sampling, a recovery study was performed for the compounds of interest during the field test. The laboratory prepared 20 XAD-2 tube spikes containing 52.7 µg of benzene, 52.0 µg of ethylbenzene, 51.9 µg of toluene, 54.5 µg of styrene, 52.0 µg of naphthalene, 52.5 µg of o-xylene, 51.8 µg of m-xylene, and 51.6 µg of p-xylene. Eighteen of the spikes were provided to the client prior to sample collection while two were retained by the lab to be used as Laboratory Control Samples (LCS). The train collection efficiencies (R) were calculated using equations 18- 7, 18-8, and 18-9 in EPA Method 18. The reported results have been adjusted using these recovery efficiency values, which all met the method-required limits of 70% to 130%. One of the retained LCS tubes was desorbed and analyzed with the samples and yielded percent recovery values between 85.5% and 88.0%. An aqueous LCS was also prepared and analyzed with the samples and yielded recovery values between 85.0% and 92.3%. Reporting Notes The sample Mill OFF-R3B SPK.CT was sampled backwards per client correspondance. The FH and BH fractions are swapped for reporting. These analyses met the requirements of the TNI Standard. Any deviations from the requirements of the reference method or TNI Standard have been stated above. The results presented in this report are representative of the samples as provided to the laboratory. Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 131 of 640 ©Mostardi Platt General Reporting Notes The following are general reporting notes that are applicable to all Enthalpy Analytical, LLC data reports, unless specifically noted otherwise. Any analysis which refers to the method as “Type” represents a planned deviation from the reference method. For instance a Hydrogen Sulfide assay from a Tedlar bag would be labeled as “EPA Method 16-Type” because Tedlar bags are not mentioned as one of the collection options in EPA Method 16. The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory cannot determine the presence of the analyte of interest reliably. The acronym LOQ represents the Limit of Quantification. Below this value the laboratory cannot quantitate the analyte of interest within the criteria of the method. The acronym ND following a value indicates a non-detect or analytical result below the MDL. The letter J in the Qualifier or Flag column in the results indicates that the value is between the MDL and the LOQ. The laboratory can positively identify the analyte of interest as present, but the value should be considered an estimate. The letter E in the Qualifier or Flag column indicates an analytical result exceeding 100% of the highest calibration point. The associated value should be considered as an estimate. Sample results are presented ‘as measured’ for single injection methodologies, or an average value if multiple injections are made. If all injections are below the MDL, the sample is considered non-detect and the ND value is presented. If one, but not all, are below the MDL, the MDL value is used for any injections that are below the MDL. For example, if the MDL is 0.500 and LOQ is 1.00, and the instrument measures 0.355, 0.620, and 0.442 - the result reported is the average of 0.500, 0.620, and 0.500 - - - i.e. 0.540 with a J flag. When a spike recovery (Bag Spike, Collocated Spike Train, or liquid matrix spike) is being calculated, the native (unspiked) sample result is used in the calculations, as long as the value is above the MDL. If a sample is ND, then 0 is used as the native amount (not the MDL value). The acronym DF represents Dilution Factor. This number represents dilution of the sample during the preparation and/or analysis process. The analytical result taken from a laboratory instrument is multiplied by the DF to determine the final undiluted sample results. The addition of MS to the Sample ID represents a Matrix Spike. An aliquot of an actual sample is spiked with a known amount of analyte so that a percent recovery value can be determined. The MS analysis indicates what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample matrix interferes with the analysis of the analyte(s). Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 132 of 640 ©Mostardi Platt General Reporting Notes (continued) The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same manner as a MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality by showing the consistency of results gained by performing the same steps multiple times. The addition of LD to the Sample ID represents a Laboratory Duplicate. The analyst prepares an additional aliquot of sample for testing and the results of the duplicate analysis are compared to the initial result. The result should have a difference value of within 10% of the initial result (if the results of the original analysis are greater than the LOQ). The addition of AD to the Sample ID represents an Alternate Dilution. The analyst prepares an additional aliquot at a different dilution factor (usually double the initial factor). This analysis helps confirm that no additional compound is present and coeluting or sharing absorbance with the analyte of interest, as they would have a different response/absorbance than the analyte of interest. The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample matrix, prepared and analyzed by the laboratory using the same reagents, spiking standards and procedures used for the client samples. The LCS is used to assess the control of the laboratory’s analytical system. Whenever spikes are prepared for our client projects, two spikes are retained as LCSs. The LCSs are labeled with the associated project number and kept in-house at the appropriate temperature conditions. When the project samples are received for analysis, the LCSs are analyzed to confirm that the analyte could be recovered from the media, separate from the samples which were used on the project and which may have been affected by source matrix, sample collection, and/or sample transport. Significant Figures: Where the reported value is much greater than unity (1.00) in the units expressed, the number is rounded to a whole number of units, rather than to 3 significant figures. For example, a value of 10,456.45 ug catch is rounded to 10,456 ug. There are five significant digits displayed, but no confidence should be placed on more than two significant digits. In the case of small numbers, generally 3 significant figures are presented, but still only 2 should be used with confidence. Many neat materials are only certified to 3 digits, and as the mathematically correct final result is always 1 digit less than all its pre-cursors - 2 significant figures are what are most defensible. Manual Integration: The data systems used for processing will flag manually integrated peaks with an “M”. There are several reasons a peak may be manually integrated. These reasons will be identified by the following two letter designations on sample chromatograms, if provided in the report. The peak was not integrated by the software “NI”, the peak was integrated incorrectly by the software “II” or the wrong peak was integrated by the software “WP”. These codes will accompany the analyst’s manual integration stamp placed next to the compound name on the chromatogram. Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 133 of 640 ©Mostardi Platt Sample Custody Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 134 of 640 ©Mostardi Platt Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 135 of 640 ©Mostardi Platt Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 136 of 640 ©Mostardi Platt Raw Data Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 137 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA220E ver.2 032F3601.D GC/2023/Mufasa/Quarter 2 7/28/2023 2:40 AM 7/28/2023 10:16 AM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 32 1 1 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/28/2023 9:17 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 1.80218 1.57496 12.6840 1 12.6840 ug/mL Toluene BB 1.13 1.72939 1.83449 12.2792 1 12.2792 ug/mL Ethylbenzene BB 1.49 1.76960 2.25828 12.4578 1 12.4578 ug/mL p-Xylene BV 1.54 1.66238 2.13892 12.0869 1 12.0869 ug/mL m-Xylene VB 1.56 1.81839 2.16137 12.4526 1 12.4526 ug/mL o-Xylene BB 1.78 1.72646 2.14874 12.3342 1 12.3342 ug/mL Styrene BB 2.16 1.80960 2.30859 12.9301 1 12.9301 ug/mL Naphthalene BB 4.53 1.91915 2.64753 12.7454 1 12.7454 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 138 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA220E ver.2 032F3602.D GC/2023/Mufasa/Quarter 2 7/28/2023 2:48 AM 7/28/2023 10:16 AM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 32 1 2 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/28/2023 9:17 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 1.80656 1.55535 12.7141 1 12.7141 ug/mL Toluene BB 1.13 1.71208 1.77695 12.1579 1 12.1579 ug/mL Ethylbenzene BB 1.49 1.75474 2.21179 12.3541 1 12.3541 ug/mL p-Xylene BV 1.54 1.64144 2.09034 11.9375 1 11.9375 ug/mL m-Xylene VB 1.56 1.79831 2.10415 12.3160 1 12.3160 ug/mL o-Xylene BB 1.78 1.70855 2.15413 12.2084 1 12.2084 ug/mL Styrene BB 2.16 1.78124 2.25838 12.7324 1 12.7324 ug/mL Naphthalene BB 4.53 1.88383 2.54521 12.5135 1 12.5135 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 139 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA220E ver.2 032F3603.D GC/2023/Mufasa/Quarter 2 7/28/2023 2:57 AM 7/28/2023 10:16 AM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 32 1 3 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/28/2023 9:17 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.78951 1.53251 12.5970 1 12.5970 ug/mL Toluene BB 1.13 1.70798 1.78374 12.1292 1 12.1292 ug/mL Ethylbenzene BB 1.49 1.74363 2.23933 12.2765 1 12.2765 ug/mL p-Xylene BV 1.54 1.63913 2.09352 11.9211 1 11.9211 ug/mL m-Xylene VB 1.56 1.81308 2.08870 12.4165 1 12.4165 ug/mL o-Xylene BB 1.78 1.74449 2.08896 12.4608 1 12.4608 ug/mL Styrene BB 2.16 1.77319 2.30978 12.6763 1 12.6763 ug/mL Naphthalene BB 4.53 1.89711 2.54065 12.6007 1 12.6007 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 140 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep5590 #MB-EXT MUFASA225 ver.1 051F0101.D GC/2023/Mufasa/Quarter 2 7/28/2023 4:37 PM 7/31/2023 10:51 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 51 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 141 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep5590 #MB-EXT MUFASA225 ver.1 051F0102.D GC/2023/Mufasa/Quarter 2 7/28/2023 4:45 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 51 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 142 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep5590 #MB-EXT MUFASA225 ver.1 051F0103.D GC/2023/Mufasa/Quarter 2 7/28/2023 4:54 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 51 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 143 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep5590 #LCS-EXT MUFASA225 ver.1 052F0201.D GC/2023/Mufasa/Quarter 2 7/28/2023 5:02 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 52 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.38365 1.21268 9.80974 1 9.80974 ug/mL Toluene BB 1.13 1.28503 1.35227 9.16626 1 9.16626 ug/mL Ethylbenzene BB 1.49 1.28254 1.65498 9.05817 1 9.05817 ug/mL p-Xylene BV 1.54 1.20016 1.51715 8.78980 1 8.78980 ug/mL m-Xylene VB 1.56 1.33609 1.53260 9.16911 1 9.16911 ug/mL o-Xylene BB 1.78 1.28719 1.52573 9.24956 1 9.24956 ug/mL Styrene BB 2.16 1.31614 1.61761 9.48957 1 9.48957 ug/mL Naphthalene BB 4.53 1.38178 1.86186 9.21672 1 9.21672 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 144 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep5590 #LCS-EXT MUFASA225 ver.1 052F0202.D GC/2023/Mufasa/Quarter 2 7/28/2023 5:11 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 52 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.36515 1.17974 9.68267 1 9.68267 ug/mL Toluene BB 1.13 1.26832 1.32140 9.04920 1 9.04920 ug/mL Ethylbenzene BB 1.49 1.27825 1.59041 9.02819 1 9.02819 ug/mL p-Xylene BV 1.54 1.19158 1.48847 8.72862 1 8.72862 ug/mL m-Xylene VB 1.56 1.29918 1.50363 8.91785 1 8.91785 ug/mL o-Xylene BB 1.78 1.23565 1.49585 8.88763 1 8.88763 ug/mL Styrene BB 2.16 1.27962 1.55884 9.23497 1 9.23497 ug/mL Naphthalene BB 4.53 1.35455 1.82380 9.03793 1 9.03793 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 145 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep5590 #LCS-EXT MUFASA225 ver.1 052F0203.D GC/2023/Mufasa/Quarter 2 7/28/2023 5:20 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 52 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 1.36769 1.22663 9.70015 1 9.70015 ug/mL Toluene BB 1.13 1.27789 1.34102 9.11624 1 9.11624 ug/mL Ethylbenzene BB 1.49 1.26364 1.68962 8.92621 1 8.92621 ug/mL p-Xylene BV 1.54 1.19746 1.54299 8.77056 1 8.77056 ug/mL m-Xylene VB 1.56 1.32488 1.52934 9.09277 1 9.09277 ug/mL o-Xylene BB 1.78 1.26607 1.50911 9.10120 1 9.10120 ug/mL Styrene BB 2.16 1.30021 1.63143 9.37853 1 9.37853 ug/mL Naphthalene BB 4.53 1.36751 1.86586 9.12300 1 9.12300 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 146 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep5590 #MB-XAD MUFASA225 ver.1 053F0301.D GC/2023/Mufasa/Quarter 2 7/28/2023 5:28 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 53 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 147 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep5590 #MB-XAD MUFASA225 ver.1 053F0302.D GC/2023/Mufasa/Quarter 2 7/28/2023 5:37 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 53 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 148 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep5590 #MB-XAD MUFASA225 ver.1 053F0303.D GC/2023/Mufasa/Quarter 2 7/28/2023 5:46 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 53 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 149 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep5590 #MB-CT MUFASA225 ver.1 054F0401.D GC/2023/Mufasa/Quarter 2 7/28/2023 5:55 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 54 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 150 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep5590 #MB-CT MUFASA225 ver.1 054F0402.D GC/2023/Mufasa/Quarter 2 7/28/2023 6:03 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 54 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 151 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep5590 #MB-CT MUFASA225 ver.1 054F0403.D GC/2023/Mufasa/Quarter 2 7/28/2023 6:12 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 54 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 152 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep5590 #LCS-XAD MUFASA225 ver.1 055F0501.D GC/2023/Mufasa/Quarter 2 7/28/2023 6:21 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 55 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.29320 1.14716 9.18853 1 9.18853 ug/mL Toluene BB 1.13 1.26339 1.34581 9.01462 1 9.01462 ug/mL Ethylbenzene BB 1.49 1.29599 1.64398 9.15205 1 9.15205 ug/mL p-Xylene BV 1.54 1.21590 1.55295 8.90207 1 8.90207 ug/mL m-Xylene VB 1.56 1.33621 1.57177 9.16992 1 9.16992 ug/mL o-Xylene BB 1.78 1.26097 1.53896 9.06541 1 9.06541 ug/mL Styrene BB 2.16 1.30793 1.54713 9.43232 1 9.43232 ug/mL Naphthalene BB 4.53 1.38282 1.90214 9.22358 1 9.22358 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 153 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep5590 #LCS-XAD MUFASA225 ver.1 055F0502.D GC/2023/Mufasa/Quarter 2 7/28/2023 6:29 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 55 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.28459 1.10222 9.12941 1 9.12941 ug/mL Toluene BB 1.13 1.25144 1.27171 8.93093 1 8.93093 ug/mL Ethylbenzene BB 1.49 1.27042 1.62958 8.97353 1 8.97353 ug/mL p-Xylene BV 1.54 1.19513 1.48449 8.75394 1 8.75394 ug/mL m-Xylene VB 1.56 1.32692 1.51151 9.10668 1 9.10668 ug/mL o-Xylene BB 1.78 1.27005 1.49053 9.12920 1 9.12920 ug/mL Styrene BB 2.16 1.29182 1.60273 9.32002 1 9.32002 ug/mL Naphthalene BB 4.53 1.36383 1.86144 9.09884 1 9.09884 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 154 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcprep5590 #LCS-XAD MUFASA225 ver.1 055F0503.D GC/2023/Mufasa/Quarter 2 7/28/2023 6:38 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 55 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.28879 1.10190 9.15827 1 9.15827 ug/mL Toluene BB 1.13 1.25999 1.30054 8.99085 1 8.99085 ug/mL Ethylbenzene BB 1.49 1.27781 1.62973 9.02511 1 9.02511 ug/mL p-Xylene BV 1.54 1.19992 1.50494 8.78810 1 8.78810 ug/mL m-Xylene VB 1.56 1.31549 1.53485 9.02885 1 9.02885 ug/mL o-Xylene BB 1.78 1.24184 1.53092 8.93109 1 8.93109 ug/mL Styrene BB 2.16 1.28939 1.55366 9.30306 1 9.30306 ug/mL Naphthalene BB 4.53 1.36789 1.88013 9.12554 1 9.12554 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 155 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1.EXT MUFASA225 ver.1 056F0601.D GC/2023/Mufasa/Quarter 2 7/28/2023 6:47 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 56 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 156 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1.EXT MUFASA225 ver.1 056F0602.D GC/2023/Mufasa/Quarter 2 7/28/2023 6:55 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 56 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 157 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1.EXT MUFASA225 ver.1 056F0603.D GC/2023/Mufasa/Quarter 2 7/28/2023 7:04 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 56 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 158 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2.EXT MUFASA225 ver.1 057F0701.D GC/2023/Mufasa/Quarter 2 7/28/2023 7:13 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 57 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 159 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2.EXT MUFASA225 ver.1 057F0702.D GC/2023/Mufasa/Quarter 2 7/28/2023 7:21 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 57 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 160 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2.EXT MUFASA225 ver.1 057F0703.D GC/2023/Mufasa/Quarter 2 7/28/2023 7:30 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 57 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 161 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK.EXT MUFASA225 ver.1 058F0801.D GC/2023/Mufasa/Quarter 2 7/28/2023 7:39 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 58 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 162 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK.EXT MUFASA225 ver.1 058F0802.D GC/2023/Mufasa/Quarter 2 7/28/2023 7:47 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 58 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 163 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK.EXT MUFASA225 ver.1 058F0803.D GC/2023/Mufasa/Quarter 2 7/28/2023 7:56 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 58 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 164 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK-LD.EXT MUFASA225 ver.1 059F0901.D GC/2023/Mufasa/Quarter 2 7/28/2023 8:05 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 59 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 165 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK-LD.EXT MUFASA225 ver.1 059F0902.D GC/2023/Mufasa/Quarter 2 7/28/2023 8:13 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 59 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 166 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK-LD.EXT MUFASA225 ver.1 059F0903.D GC/2023/Mufasa/Quarter 2 7/28/2023 8:22 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 59 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 167 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2-SPK.EXT MUFASA225 ver.1 060F1001.D GC/2023/Mufasa/Quarter 2 7/28/2023 8:30 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 60 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 168 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2-SPK.EXT MUFASA225 ver.1 060F1002.D GC/2023/Mufasa/Quarter 2 7/28/2023 8:39 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 60 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 169 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2-SPK.EXT MUFASA225 ver.1 060F1003.D GC/2023/Mufasa/Quarter 2 7/28/2023 8:48 PM 7/31/2023 10:52 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 60 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 170 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 061F1101.D GC/2023/Mufasa/Quarter 2 7/28/2023 8:56 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 61 1 1 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.81687 1.57573 12.7849 1 12.7849 ug/mL Toluene BB 1.13 1.73913 1.81221 12.3474 1 12.3474 ug/mL Ethylbenzene BB 1.49 1.77286 2.27319 12.4805 1 12.4805 ug/mL p-Xylene BV 1.54 1.66732 2.14179 12.1221 1 12.1221 ug/mL m-Xylene VB 1.56 1.82243 2.17283 12.4802 1 12.4802 ug/mL o-Xylene BB 1.78 1.72762 2.16666 12.3423 1 12.3423 ug/mL Styrene BB 2.16 1.81905 2.15653 12.9961 1 12.9961 ug/mL Naphthalene BB 4.53 1.90544 2.61904 12.6554 1 12.6554 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 171 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 061F1102.D GC/2023/Mufasa/Quarter 2 7/28/2023 9:05 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 61 1 2 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.79586 1.53704 12.6406 1 12.6406 ug/mL Toluene BB 1.13 1.72543 1.75849 12.2514 1 12.2514 ug/mL Ethylbenzene BV 1.49 1.73827 2.25034 12.2391 1 12.2391 ug/mL p-Xylene VV 1.54 1.65405 2.11114 12.0275 1 12.0275 ug/mL m-Xylene VB 1.56 1.82147 2.09756 12.4736 1 12.4736 ug/mL o-Xylene BB 1.78 1.75678 2.09723 12.5471 1 12.5471 ug/mL Styrene BB 2.16 1.77565 2.26330 12.6935 1 12.6935 ug/mL Naphthalene BB 4.53 1.88353 2.53446 12.5115 1 12.5115 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 172 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 061F1103.D GC/2023/Mufasa/Quarter 2 7/28/2023 9:14 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 61 1 3 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.78469 1.51775 12.5639 1 12.5639 ug/mL Toluene BB 1.13 1.70675 1.76310 12.1206 1 12.1206 ug/mL Ethylbenzene BV 1.49 1.73753 2.27109 12.2339 1 12.2339 ug/mL p-Xylene VV 1.54 1.64907 2.10329 11.9919 1 11.9919 ug/mL m-Xylene VB 1.56 1.81484 2.06980 12.4284 1 12.4284 ug/mL o-Xylene BB 1.78 1.73526 2.07754 12.3960 1 12.3960 ug/mL Styrene BB 2.16 1.76877 2.26091 12.6455 1 12.6455 ug/mL Naphthalene BB 4.53 1.87799 2.50001 12.4751 1 12.4751 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 173 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3-SPK.EXT MUFASA225 ver.1 062F1201.D GC/2023/Mufasa/Quarter 2 7/28/2023 9:31 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 62 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 174 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3-SPK.EXT MUFASA225 ver.1 062F1202.D GC/2023/Mufasa/Quarter 2 7/28/2023 9:40 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 62 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 175 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3-SPK.EXT MUFASA225 ver.1 062F1203.D GC/2023/Mufasa/Quarter 2 7/28/2023 9:48 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 62 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 176 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1.EXT MUFASA225 ver.1 063F1301.D GC/2023/Mufasa/Quarter 2 7/28/2023 9:57 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 63 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 177 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1.EXT MUFASA225 ver.1 063F1302.D GC/2023/Mufasa/Quarter 2 7/28/2023 10:06 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 63 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 178 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1.EXT MUFASA225 ver.1 063F1303.D GC/2023/Mufasa/Quarter 2 7/28/2023 10:14 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 63 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 179 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2.EXT MUFASA225 ver.1 064F1401.D GC/2023/Mufasa/Quarter 2 7/28/2023 10:23 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 64 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 180 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2.EXT MUFASA225 ver.1 064F1402.D GC/2023/Mufasa/Quarter 2 7/28/2023 10:32 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 64 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 181 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2.EXT MUFASA225 ver.1 064F1403.D GC/2023/Mufasa/Quarter 2 7/28/2023 10:40 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 64 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 182 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3.EXT MUFASA225 ver.1 065F1501.D GC/2023/Mufasa/Quarter 2 7/28/2023 10:49 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 65 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 183 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3.EXT MUFASA225 ver.1 065F1502.D GC/2023/Mufasa/Quarter 2 7/28/2023 10:58 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 65 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 184 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3.EXT MUFASA225 ver.1 065F1503.D GC/2023/Mufasa/Quarter 2 7/28/2023 11:06 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 65 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 185 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1-SPK.EXT MUFASA225 ver.1 066F1601.D GC/2023/Mufasa/Quarter 2 7/28/2023 11:15 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 66 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 186 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1-SPK.EXT MUFASA225 ver.1 066F1602.D GC/2023/Mufasa/Quarter 2 7/28/2023 11:23 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 66 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 187 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1-SPK.EXT MUFASA225 ver.1 066F1603.D GC/2023/Mufasa/Quarter 2 7/28/2023 11:32 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 66 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 188 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2-SPK.EXT MUFASA225 ver.1 067F1701.D GC/2023/Mufasa/Quarter 2 7/28/2023 11:41 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 67 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 189 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2-SPK.EXT MUFASA225 ver.1 067F1702.D GC/2023/Mufasa/Quarter 2 7/28/2023 11:49 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 67 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 190 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2-SPK.EXT MUFASA225 ver.1 067F1703.D GC/2023/Mufasa/Quarter 2 7/28/2023 11:58 PM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 67 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 191 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3-SPK.EXT MUFASA225 ver.1 068F1801.D GC/2023/Mufasa/Quarter 2 7/29/2023 12:07 AM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 68 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 192 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3-SPK.EXT MUFASA225 ver.1 068F1802.D GC/2023/Mufasa/Quarter 2 7/29/2023 12:15 AM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 68 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 193 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3-SPK.EXT MUFASA225 ver.1 068F1803.D GC/2023/Mufasa/Quarter 2 7/29/2023 12:24 AM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 68 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 194 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1.FH-XAD MUFASA225 ver.1 069F1901.D GC/2023/Mufasa/Quarter 2 7/29/2023 12:33 AM 7/31/2023 10:53 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 69 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.22180 0.18522 1.83066 1 1.83066 ug/mL Toluene BB 1.13 0.25331 0.24808 1.93856 1 1.93856 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 195 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1.FH-XAD MUFASA225 ver.1 069F1902.D GC/2023/Mufasa/Quarter 2 7/29/2023 12:41 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 69 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.23984 0.19610 1.95458 1 1.95458 ug/mL Toluene BB 1.13 0.26869 0.24816 2.04633 1 2.04633 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 196 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1.FH-XAD MUFASA225 ver.1 069F1903.D GC/2023/Mufasa/Quarter 2 7/29/2023 12:50 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 69 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.22127 0.17567 1.82703 1 1.82703 ug/mL Toluene BB 1.13 0.24383 0.23806 1.87217 1 1.87217 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 197 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1.BH-XAD MUFASA225 ver.1 070F2001.D GC/2023/Mufasa/Quarter 2 7/29/2023 12:59 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 70 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 198 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1.BH-XAD MUFASA225 ver.1 070F2002.D GC/2023/Mufasa/Quarter 2 7/29/2023 1:07 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 70 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 199 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1.BH-XAD MUFASA225 ver.1 070F2003.D GC/2023/Mufasa/Quarter 2 7/29/2023 1:16 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 70 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 200 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1.FH-CT MUFASA225 ver.1 071F2101.D GC/2023/Mufasa/Quarter 2 7/29/2023 1:24 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 71 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.43971 0.36760 3.32716 1 3.32716 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 201 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1.FH-CT MUFASA225 ver.1 071F2102.D GC/2023/Mufasa/Quarter 2 7/29/2023 1:33 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 71 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.43500 0.38563 3.29481 1 3.29481 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 202 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1.FH-CT MUFASA225 ver.1 071F2103.D GC/2023/Mufasa/Quarter 2 7/29/2023 1:42 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 71 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.43448 0.36661 3.29127 1 3.29127 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 203 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 072F2201.D GC/2023/Mufasa/Quarter 2 7/29/2023 1:50 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 72 1 1 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.80554 1.52879 12.7071 1 12.7071 ug/mL Toluene BB 1.13 1.74840 1.77539 12.4124 1 12.4124 ug/mL Ethylbenzene BB 1.49 1.77111 2.22308 12.4683 1 12.4683 ug/mL p-Xylene BV 1.54 1.65802 2.09811 12.0558 1 12.0558 ug/mL m-Xylene VB 1.56 1.82091 2.12197 12.4698 1 12.4698 ug/mL o-Xylene BB 1.78 1.74115 2.13528 12.4373 1 12.4373 ug/mL Styrene BB 2.16 1.79476 2.27267 12.8267 1 12.8267 ug/mL Naphthalene BB 4.53 1.89633 2.55549 12.5956 1 12.5956 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 204 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 072F2202.D GC/2023/Mufasa/Quarter 2 7/29/2023 1:59 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 72 1 2 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.81306 1.53858 12.7588 1 12.7588 ug/mL Toluene BB 1.13 1.76794 1.79816 12.5492 1 12.5492 ug/mL Ethylbenzene BB 1.49 1.77879 2.27370 12.5220 1 12.5220 ug/mL p-Xylene BV 1.54 1.67549 2.08918 12.1804 1 12.1804 ug/mL m-Xylene VB 1.56 1.83925 2.15299 12.5947 1 12.5947 ug/mL o-Xylene BB 1.78 1.73451 2.12783 12.3907 1 12.3907 ug/mL Styrene BB 2.16 1.81638 2.15594 12.9775 1 12.9775 ug/mL Naphthalene BB 4.53 1.91026 2.61452 12.6870 1 12.6870 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 205 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 072F2203.D GC/2023/Mufasa/Quarter 2 7/29/2023 2:08 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 72 1 3 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.80096 1.58178 12.6756 1 12.6756 ug/mL Toluene BB 1.13 1.73253 1.83355 12.3012 1 12.3012 ug/mL Ethylbenzene BB 1.49 1.75851 2.32122 12.3804 1 12.3804 ug/mL p-Xylene BV 1.54 1.67362 2.15104 12.1670 1 12.1670 ug/mL m-Xylene VB 1.56 1.84356 2.17504 12.6240 1 12.6240 ug/mL o-Xylene BB 1.78 1.77582 2.11935 12.6808 1 12.6808 ug/mL Styrene BB 2.16 1.79751 2.33103 12.8459 1 12.8459 ug/mL Naphthalene BB 4.53 1.91468 2.58198 12.7161 1 12.7161 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 206 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1.BH-CT MUFASA225 ver.1 073F2301.D GC/2023/Mufasa/Quarter 2 7/29/2023 2:25 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 73 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 207 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1.BH-CT MUFASA225 ver.1 073F2302.D GC/2023/Mufasa/Quarter 2 7/29/2023 2:34 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 73 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 208 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1.BH-CT MUFASA225 ver.1 073F2303.D GC/2023/Mufasa/Quarter 2 7/29/2023 2:42 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 73 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 209 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK.FH-XAD MUFASA225 ver.1 074F2401.D GC/2023/Mufasa/Quarter 2 7/29/2023 2:51 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 74 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.36710 0.31862 2.82852 1 2.82852 ug/mL Toluene BB 1.13 1.34561 1.38894 9.59065 1 9.59065 ug/mL Ethylbenzene BB 1.49 1.39981 1.85490 9.87666 1 9.87666 ug/mL p-Xylene BV 1.54 1.32481 1.69819 9.67893 1 9.67893 ug/mL m-Xylene VB 1.56 1.50386 1.74063 10.3113 1 10.3113 ug/mL o-Xylene BB 1.78 1.42666 1.70756 10.2289 1 10.2289 ug/mL Styrene BB 2.16 1.50390 1.89252 10.7987 1 10.7987 ug/mL Naphthalene BB 4.53 1.54931 2.07826 10.3168 1 10.3168 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 210 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK.FH-XAD MUFASA225 ver.1 074F2402.D GC/2023/Mufasa/Quarter 2 7/29/2023 3:00 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 74 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.36177 0.30271 2.79190 1 2.79190 ug/mL Toluene BB 1.13 1.34755 1.34967 9.60420 1 9.60420 ug/mL Ethylbenzene BB 1.49 1.40524 1.77149 9.91457 1 9.91457 ug/mL p-Xylene BV 1.54 1.31539 1.66746 9.61177 1 9.61177 ug/mL m-Xylene VB 1.56 1.47281 1.72001 10.0999 1 10.0999 ug/mL o-Xylene BB 1.78 1.37976 1.69202 9.89956 1 9.89956 ug/mL Styrene BB 2.16 1.49476 1.76605 10.7350 1 10.7350 ug/mL Naphthalene BB 4.53 1.51867 2.09562 10.1156 1 10.1156 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 211 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK.FH-XAD MUFASA225 ver.1 074F2403.D GC/2023/Mufasa/Quarter 2 7/29/2023 3:08 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 74 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.37797 0.30787 2.90315 1 2.90315 ug/mL Toluene BB 1.13 1.32708 1.35480 9.46081 1 9.46081 ug/mL Ethylbenzene BB 1.49 1.38961 1.81227 9.80548 1 9.80548 ug/mL p-Xylene BV 1.54 1.31522 1.66056 9.61053 1 9.61053 ug/mL m-Xylene VB 1.56 1.49508 1.71165 10.2515 1 10.2515 ug/mL o-Xylene BB 1.78 1.42093 1.69381 10.1887 1 10.1887 ug/mL Styrene BB 2.16 1.49140 1.88686 10.7116 1 10.7116 ug/mL Naphthalene BB 4.53 1.53615 2.09556 10.2304 1 10.2304 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 212 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK-LD.FH-XAD MUFASA225 ver.1 075F2501.D GC/2023/Mufasa/Quarter 2 7/29/2023 3:17 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 75 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.35704 0.30721 2.75943 1 2.75943 ug/mL Toluene BB 1.13 1.33064 1.37353 9.48576 1 9.48576 ug/mL Ethylbenzene BB 1.49 1.39051 1.79433 9.81180 1 9.81180 ug/mL p-Xylene BV 1.54 1.32316 1.67033 9.66716 1 9.66716 ug/mL m-Xylene VB 1.56 1.49337 1.72360 10.2399 1 10.2399 ug/mL o-Xylene BB 1.78 1.42144 1.71892 10.1923 1 10.1923 ug/mL Styrene BB 2.16 1.48715 1.88914 10.6820 1 10.6820 ug/mL Naphthalene BB 4.53 1.53277 2.07752 10.2082 1 10.2082 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 213 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK-LD.FH-XAD MUFASA225 ver.1 075F2502.D GC/2023/Mufasa/Quarter 2 7/29/2023 3:26 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 75 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.36122 0.30653 2.78815 1 2.78815 ug/mL Toluene BB 1.13 1.33560 1.38797 9.52047 1 9.52047 ug/mL Ethylbenzene BB 1.49 1.41507 1.80562 9.98318 1 9.98318 ug/mL p-Xylene BV 1.54 1.32710 1.67330 9.69526 1 9.69526 ug/mL m-Xylene VB 1.56 1.47705 1.74811 10.1288 1 10.1288 ug/mL o-Xylene BB 1.78 1.37845 1.72780 9.89039 1 9.89039 ug/mL Styrene BB 2.16 1.50143 1.80833 10.7815 1 10.7815 ug/mL Naphthalene BB 4.53 1.53307 2.07290 10.2102 1 10.2102 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 214 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK-LD.FH-XAD MUFASA225 ver.1 075F2503.D GC/2023/Mufasa/Quarter 2 7/29/2023 3:34 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 75 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.35619 0.30231 2.75359 1 2.75359 ug/mL Toluene BB 1.13 1.33076 1.35338 9.48662 1 9.48662 ug/mL Ethylbenzene BB 1.49 1.36737 1.79687 9.65021 1 9.65021 ug/mL p-Xylene BV 1.54 1.30710 1.63739 9.55259 1 9.55259 ug/mL m-Xylene VB 1.56 1.48008 1.68160 10.1494 1 10.1494 ug/mL o-Xylene BB 1.78 1.40229 1.65227 10.0578 1 10.0578 ug/mL Styrene BB 2.16 1.47000 1.82758 10.5623 1 10.5623 ug/mL Naphthalene BB 4.53 1.51415 2.09769 10.0859 1 10.0859 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 215 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK.BH-XAD MUFASA225 ver.1 076F2601.D GC/2023/Mufasa/Quarter 2 7/29/2023 3:43 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 76 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.42596 0.42707 3.14810 1 3.14810 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 216 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK.BH-XAD MUFASA225 ver.1 076F2602.D GC/2023/Mufasa/Quarter 2 7/29/2023 3:52 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 76 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.42151 0.42200 3.11687 1 3.11687 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 217 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK.BH-XAD MUFASA225 ver.1 076F2603.D GC/2023/Mufasa/Quarter 2 7/29/2023 4:00 AM 7/31/2023 10:54 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 76 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.41417 0.41013 3.06549 1 3.06549 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 218 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK.FH-CT MUFASA225 ver.1 077F2701.D GC/2023/Mufasa/Quarter 2 7/29/2023 4:09 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 77 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.51660 1.28654 10.7228 1 10.7228 ug/mL Toluene BB 1.13 0.25405 0.24475 1.94379 1 1.94379 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 219 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK.FH-CT MUFASA225 ver.1 077F2702.D GC/2023/Mufasa/Quarter 2 7/29/2023 4:18 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 77 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.51125 1.27466 10.6860 1 10.6860 ug/mL Toluene BB 1.13 0.24687 0.24895 1.89349 1 1.89349 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 220 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK.FH-CT MUFASA225 ver.1 077F2703.D GC/2023/Mufasa/Quarter 2 7/29/2023 4:26 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 77 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.52107 1.33913 10.7535 1 10.7535 ug/mL Toluene BB 1.13 0.25259 0.25662 1.93357 1 1.93357 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 221 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK.BH-CT MUFASA225 ver.1 078F2801.D GC/2023/Mufasa/Quarter 2 7/29/2023 4:35 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 78 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 222 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK.BH-CT MUFASA225 ver.1 078F2802.D GC/2023/Mufasa/Quarter 2 7/29/2023 4:44 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 78 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 223 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R1-SPK.BH-CT MUFASA225 ver.1 078F2803.D GC/2023/Mufasa/Quarter 2 7/29/2023 4:52 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 78 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 224 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2.FH-XAD MUFASA225 ver.1 079F2901.D GC/2023/Mufasa/Quarter 2 7/29/2023 5:01 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 79 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 225 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2.FH-XAD MUFASA225 ver.1 079F2902.D GC/2023/Mufasa/Quarter 2 7/29/2023 5:10 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 79 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 226 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2.FH-XAD MUFASA225 ver.1 079F2903.D GC/2023/Mufasa/Quarter 2 7/29/2023 5:18 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 79 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 227 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2.BH-XAD MUFASA225 ver.1 080F3001.D GC/2023/Mufasa/Quarter 2 7/29/2023 5:27 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 80 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 228 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2.BH-XAD MUFASA225 ver.1 080F3002.D GC/2023/Mufasa/Quarter 2 7/29/2023 5:36 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 80 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 229 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2.BH-XAD MUFASA225 ver.1 080F3003.D GC/2023/Mufasa/Quarter 2 7/29/2023 5:44 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 80 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 230 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2.FH-CT MUFASA225 ver.1 081F3101.D GC/2023/Mufasa/Quarter 2 7/29/2023 5:53 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 81 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.51908 0.42892 3.87225 1 3.87225 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 231 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2.FH-CT MUFASA225 ver.1 081F3102.D GC/2023/Mufasa/Quarter 2 7/29/2023 6:02 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 81 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.49761 0.41880 3.72478 1 3.72478 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 232 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2.FH-CT MUFASA225 ver.1 081F3103.D GC/2023/Mufasa/Quarter 2 7/29/2023 6:10 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 81 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.50042 0.41762 3.74407 1 3.74407 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 233 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2.BH-CT MUFASA225 ver.1 082F3201.D GC/2023/Mufasa/Quarter 2 7/29/2023 6:19 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 82 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 234 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2.BH-CT MUFASA225 ver.1 082F3202.D GC/2023/Mufasa/Quarter 2 7/29/2023 6:28 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 82 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 235 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2.BH-CT MUFASA225 ver.1 082F3203.D GC/2023/Mufasa/Quarter 2 7/29/2023 6:36 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 82 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 236 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 083F3301.D GC/2023/Mufasa/Quarter 2 7/29/2023 6:45 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 83 1 1 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.81916 1.53785 12.8006 1 12.8006 ug/mL Toluene BB 1.13 1.77093 1.81483 12.5702 1 12.5702 ug/mL Ethylbenzene BB 1.49 1.78419 2.27263 12.5597 1 12.5597 ug/mL p-Xylene BV 1.54 1.67904 2.13308 12.2057 1 12.2057 ug/mL m-Xylene VB 1.56 1.83816 2.14151 12.5872 1 12.5872 ug/mL o-Xylene BB 1.78 1.72903 2.15235 12.3522 1 12.3522 ug/mL Styrene BB 2.16 1.80799 2.27364 12.9189 1 12.9189 ug/mL Naphthalene BB 4.53 1.91512 2.67338 12.7189 1 12.7189 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 237 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 083F3302.D GC/2023/Mufasa/Quarter 2 7/29/2023 6:54 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 83 1 2 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.82126 1.52311 12.8151 1 12.8151 ug/mL Toluene BB 1.13 1.72858 1.77144 12.2735 1 12.2735 ug/mL Ethylbenzene BV 1.49 1.75221 2.27428 12.3364 1 12.3364 ug/mL p-Xylene VV 1.54 1.66041 2.09119 12.0728 1 12.0728 ug/mL m-Xylene VB 1.56 1.83246 2.07544 12.5484 1 12.5484 ug/mL o-Xylene BB 1.78 1.75170 2.10429 12.5114 1 12.5114 ug/mL Styrene BB 2.16 1.78199 2.29490 12.7376 1 12.7376 ug/mL Naphthalene BB 4.53 1.89356 2.58138 12.5774 1 12.5774 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 238 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 083F3303.D GC/2023/Mufasa/Quarter 2 7/29/2023 7:02 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 83 1 3 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.79659 1.52553 12.6456 1 12.6456 ug/mL Toluene BB 1.13 1.74490 1.76395 12.3878 1 12.3878 ug/mL Ethylbenzene BB 1.49 1.75695 2.23359 12.3695 1 12.3695 ug/mL p-Xylene BV 1.54 1.65042 2.10788 12.0016 1 12.0016 ug/mL m-Xylene VB 1.56 1.82121 2.11671 12.4719 1 12.4719 ug/mL o-Xylene BB 1.78 1.73228 2.16690 12.3750 1 12.3750 ug/mL Styrene BB 2.16 1.80075 2.16388 12.8685 1 12.8685 ug/mL Naphthalene BB 4.53 1.90086 2.59790 12.6253 1 12.6253 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 239 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2-SPK.FH-XAD MUFASA225 ver.1 084F3401.D GC/2023/Mufasa/Quarter 2 7/29/2023 7:20 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 84 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.21712 0.17093 1.79852 1 1.79852 ug/mL Toluene BB 1.13 0.84134 0.84431 6.05799 1 6.05799 ug/mL Ethylbenzene BB 1.49 1.27540 1.65022 9.00827 1 9.00827 ug/mL p-Xylene BV 1.54 1.22136 1.53135 8.94104 1 8.94104 ug/mL m-Xylene VB 1.56 1.38688 1.59171 9.51489 1 9.51489 ug/mL o-Xylene BB 1.78 1.32349 1.57443 9.50444 1 9.50444 ug/mL Styrene BB 2.16 1.41657 1.74114 10.1898 1 10.1898 ug/mL Naphthalene BB 4.53 1.54205 2.05299 10.2691 1 10.2691 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 240 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2-SPK.FH-XAD MUFASA225 ver.1 084F3402.D GC/2023/Mufasa/Quarter 2 7/29/2023 7:28 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 84 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene MM 0.82 0.22143 0.16978 1.82810 1 1.82810 ug/mL Toluene BB 1.13 0.88170 0.84721 6.34071 1 6.34071 ug/mL Ethylbenzene BB 1.49 1.26796 1.61218 8.95636 1 8.95636 ug/mL p-Xylene BV 1.54 1.20938 1.52633 8.85556 1 8.85556 ug/mL m-Xylene VB 1.56 1.36227 1.60390 9.34736 1 9.34736 ug/mL o-Xylene BB 1.78 1.28921 1.59123 9.26369 1 9.26369 ug/mL Styrene BB 2.16 1.41465 1.67074 10.1764 1 10.1764 ug/mL Naphthalene BB 4.53 1.53387 2.09789 10.2155 1 10.2155 ug/mL Analyst Peak Integration Comments 08:44:19 07/31/23 Brianna Berry ii Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 241 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2-SPK.FH-XAD MUFASA225 ver.1 084F3403.D GC/2023/Mufasa/Quarter 2 7/29/2023 7:37 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 84 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene MM 0.82 0.21041 0.16595 1.75241 1 1.75241 ug/mL Toluene BB 1.13 0.84377 0.82713 6.07501 1 6.07501 ug/mL Ethylbenzene BB 1.49 1.25833 1.62207 8.88912 1 8.88912 ug/mL p-Xylene BV 1.54 1.20266 1.50530 8.80763 1 8.80763 ug/mL m-Xylene VB 1.56 1.37350 1.56602 9.42380 1 9.42380 ug/mL o-Xylene BB 1.78 1.31610 1.57871 9.45252 1 9.45252 ug/mL Styrene BB 2.16 1.39487 1.74289 10.0385 1 10.0385 ug/mL Naphthalene BB 4.53 1.52528 2.02972 10.1591 1 10.1591 ug/mL Analyst Peak Integration Comments 08:45:01 07/31/23 Brianna Berry ii Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 242 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2-SPK.BH-XAD MUFASA225 ver.1 085F3501.D GC/2023/Mufasa/Quarter 2 7/29/2023 7:46 AM 7/31/2023 10:55 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 85 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.32718 0.33094 2.45608 1 2.45608 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 243 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2-SPK.BH-XAD MUFASA225 ver.1 085F3502.D GC/2023/Mufasa/Quarter 2 7/29/2023 7:54 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 85 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.31867 0.32712 2.39649 1 2.39649 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 244 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2-SPK.BH-XAD MUFASA225 ver.1 085F3503.D GC/2023/Mufasa/Quarter 2 7/29/2023 8:03 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 85 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.33025 0.32522 2.47759 1 2.47759 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 245 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2-SPK.FH-CT MUFASA225 ver.1 086F3601.D GC/2023/Mufasa/Quarter 2 7/29/2023 8:12 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 86 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.67966 1.40926 11.8426 1 11.8426 ug/mL Toluene BB 1.13 0.33485 0.33153 2.50982 1 2.50982 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 246 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2-SPK.FH-CT MUFASA225 ver.1 086F3602.D GC/2023/Mufasa/Quarter 2 7/29/2023 8:20 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 86 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.69805 1.48538 11.9689 1 11.9689 ug/mL Toluene BB 1.13 0.33519 0.33942 2.51216 1 2.51216 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 247 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2-SPK.FH-CT MUFASA225 ver.1 086F3603.D GC/2023/Mufasa/Quarter 2 7/29/2023 8:29 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 86 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.68612 1.45395 11.8870 1 11.8870 ug/mL Toluene BB 1.13 0.33163 0.33185 2.48727 1 2.48727 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 248 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2-SPK.BH-CT MUFASA225 ver.1 087F3701.D GC/2023/Mufasa/Quarter 2 7/29/2023 8:38 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 87 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 249 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2-SPK.BH-CT MUFASA225 ver.1 087F3702.D GC/2023/Mufasa/Quarter 2 7/29/2023 8:46 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 87 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 250 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R2-SPK.BH-CT MUFASA225 ver.1 087F3703.D GC/2023/Mufasa/Quarter 2 7/29/2023 8:55 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 87 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 251 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3.FH-XAD MUFASA225 ver.1 088F3801.D GC/2023/Mufasa/Quarter 2 7/29/2023 9:04 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 88 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 252 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3.FH-XAD MUFASA225 ver.1 088F3802.D GC/2023/Mufasa/Quarter 2 7/29/2023 9:12 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 88 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 253 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3.FH-XAD MUFASA225 ver.1 088F3803.D GC/2023/Mufasa/Quarter 2 7/29/2023 9:21 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 88 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 254 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3.BH-XAD MUFASA225 ver.1 089F3901.D GC/2023/Mufasa/Quarter 2 7/29/2023 9:30 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 89 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 255 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3.BH-XAD MUFASA225 ver.1 089F3902.D GC/2023/Mufasa/Quarter 2 7/29/2023 9:38 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 89 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 256 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3.BH-XAD MUFASA225 ver.1 089F3903.D GC/2023/Mufasa/Quarter 2 7/29/2023 9:47 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 89 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 257 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3.FH-CT MUFASA225 ver.1 090F4001.D GC/2023/Mufasa/Quarter 2 7/29/2023 9:56 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 90 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.55130 0.48710 4.09355 1 4.09355 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 258 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3.FH-CT MUFASA225 ver.1 090F4002.D GC/2023/Mufasa/Quarter 2 7/29/2023 10:04 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 90 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.54170 0.47168 4.02757 1 4.02757 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 259 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3.FH-CT MUFASA225 ver.1 090F4003.D GC/2023/Mufasa/Quarter 2 7/29/2023 10:13 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 90 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.55411 0.48015 4.11281 1 4.11281 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 260 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3.BH-CT MUFASA225 ver.1 091F4101.D GC/2023/Mufasa/Quarter 2 7/29/2023 10:22 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 91 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 261 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3.BH-CT MUFASA225 ver.1 091F4102.D GC/2023/Mufasa/Quarter 2 7/29/2023 10:31 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 91 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 262 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3.BH-CT MUFASA225 ver.1 091F4103.D GC/2023/Mufasa/Quarter 2 7/29/2023 10:39 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 91 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 263 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3-SPK.FH-XAD MUFASA225 ver.1 092F4201.D GC/2023/Mufasa/Quarter 2 7/29/2023 10:48 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 92 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene MM 0.82 0.23201 0.18017 1.90077 1 1.90077 ug/mL Toluene BB 1.13 0.85092 0.85607 6.12514 1 6.12514 ug/mL Ethylbenzene BB 1.49 1.28975 1.61810 9.10845 1 9.10845 ug/mL p-Xylene BV 1.54 1.21373 1.53220 8.88662 1 8.88662 ug/mL m-Xylene VB 1.56 1.37437 1.55812 9.42974 1 9.42974 ug/mL o-Xylene BB 1.78 1.30859 1.55500 9.39982 1 9.39982 ug/mL Styrene BB 2.16 1.38489 1.72551 9.96892 1 9.96892 ug/mL Naphthalene BB 4.53 1.52945 2.08020 10.1864 1 10.1864 ug/mL Analyst Peak Integration Comments 08:48:08 07/31/23 Brianna Berry ii Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 264 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3-SPK.FH-XAD MUFASA225 ver.1 092F4202.D GC/2023/Mufasa/Quarter 2 7/29/2023 10:57 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 92 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.21436 0.17024 1.77953 1 1.77953 ug/mL Toluene BB 1.13 0.89257 0.87170 6.41687 1 6.41687 ug/mL Ethylbenzene BB 1.49 1.26750 1.61276 8.95318 1 8.95318 ug/mL p-Xylene BV 1.54 1.21111 1.51615 8.86790 1 8.86790 ug/mL m-Xylene VB 1.56 1.36576 1.57953 9.37108 1 9.37108 ug/mL o-Xylene BB 1.78 1.29547 1.56270 9.30769 1 9.30769 ug/mL Styrene BB 2.16 1.40269 1.65793 10.0930 1 10.0930 ug/mL Naphthalene BB 4.53 1.54400 2.10083 10.2819 1 10.2819 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 265 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3-SPK.FH-XAD MUFASA225 ver.1 092F4203.D GC/2023/Mufasa/Quarter 2 7/29/2023 11:05 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 92 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene MM 0.82 0.25177 0.17828 2.03651 1 2.03651 ug/mL Toluene BB 1.13 0.85936 0.86372 6.18426 1 6.18426 ug/mL Ethylbenzene BB 1.49 1.28106 1.61310 9.04778 1 9.04778 ug/mL p-Xylene BV 1.54 1.22022 1.49340 8.93285 1 8.93285 ug/mL m-Xylene VB 1.56 1.37228 1.59473 9.41548 1 9.41548 ug/mL o-Xylene BB 1.78 1.28911 1.59332 9.26298 1 9.26298 ug/mL Styrene BB 2.16 1.40039 1.66764 10.0770 1 10.0770 ug/mL Naphthalene BB 4.53 1.54775 2.12148 10.3066 1 10.3066 ug/mL Analyst Peak Integration Comments 08:48:43 07/31/23 Brianna Berry ii Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 266 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3-SPK.BH-XAD MUFASA225 ver.1 093F4301.D GC/2023/Mufasa/Quarter 2 7/29/2023 11:14 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 93 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.30735 0.30231 2.31714 1 2.31714 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 267 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3-SPK.BH-XAD MUFASA225 ver.1 093F4302.D GC/2023/Mufasa/Quarter 2 7/29/2023 11:23 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 93 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.29389 0.29686 2.22288 1 2.22288 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 268 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3-SPK.BH-XAD MUFASA225 ver.1 093F4303.D GC/2023/Mufasa/Quarter 2 7/29/2023 11:31 AM 7/31/2023 10:56 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 93 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.29263 0.28911 2.21406 1 2.21406 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 269 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 094F4401.D GC/2023/Mufasa/Quarter 2 7/29/2023 11:40 AM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 94 1 1 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.81357 1.53073 12.7623 1 12.7623 ug/mL Toluene BB 1.13 1.76738 1.79127 12.5453 1 12.5453 ug/mL Ethylbenzene BB 1.49 1.80280 2.28196 12.6896 1 12.6896 ug/mL p-Xylene BV 1.54 1.69641 2.14233 12.3296 1 12.3296 ug/mL m-Xylene VB 1.56 1.86307 2.16573 12.7569 1 12.7569 ug/mL o-Xylene BB 1.78 1.75149 2.17627 12.5099 1 12.5099 ug/mL Styrene BB 2.16 1.82212 2.32720 13.0174 1 13.0174 ug/mL Naphthalene BB 4.53 1.94309 2.62533 12.9026 1 12.9026 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 270 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 094F4402.D GC/2023/Mufasa/Quarter 2 7/29/2023 11:49 AM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 94 1 2 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.79187 1.53143 12.6132 1 12.6132 ug/mL Toluene BB 1.13 1.72653 1.76717 12.2591 1 12.2591 ug/mL Ethylbenzene BV 1.49 1.74927 2.26952 12.3159 1 12.3159 ug/mL p-Xylene VV 1.54 1.66251 2.11280 12.0878 1 12.0878 ug/mL m-Xylene VB 1.56 1.83640 2.10987 12.5752 1 12.5752 ug/mL o-Xylene BB 1.78 1.75807 2.10431 12.5561 1 12.5561 ug/mL Styrene BB 2.16 1.80062 2.31893 12.8675 1 12.8675 ug/mL Naphthalene BB 4.53 1.91990 2.61853 12.7504 1 12.7504 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 271 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 094F4403.D GC/2023/Mufasa/Quarter 2 7/29/2023 11:57 AM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 94 1 3 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.80274 1.57071 12.6879 1 12.6879 ug/mL Toluene BB 1.13 1.73916 1.82120 12.3476 1 12.3476 ug/mL Ethylbenzene BB 1.49 1.77105 2.32970 12.4679 1 12.4679 ug/mL p-Xylene BV 1.54 1.68026 2.16007 12.2144 1 12.2144 ug/mL m-Xylene VB 1.56 1.86133 2.13700 12.7450 1 12.7450 ug/mL o-Xylene BB 1.78 1.78646 2.13748 12.7555 1 12.7555 ug/mL Styrene BB 2.16 1.81022 2.34466 12.9345 1 12.9345 ug/mL Naphthalene BB 4.53 1.93063 2.59353 12.8208 1 12.8208 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 272 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3-SPK.FH-CT MUFASA225 ver.1 095F4501.D GC/2023/Mufasa/Quarter 2 7/29/2023 12:15 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 95 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.75510 1.47098 12.3607 1 12.3607 ug/mL Toluene BB 1.13 0.44493 0.44907 3.28100 1 3.28100 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 273 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3-SPK.FH-CT MUFASA225 ver.1 095F4502.D GC/2023/Mufasa/Quarter 2 7/29/2023 12:23 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 95 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.77478 1.53426 12.4958 1 12.4958 ug/mL Toluene BB 1.13 0.43956 0.44942 3.24338 1 3.24338 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 274 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3-SPK.FH-CT MUFASA225 ver.1 095F4503.D GC/2023/Mufasa/Quarter 2 7/29/2023 12:32 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 95 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.76126 1.52157 12.4030 1 12.4030 ug/mL Toluene BB 1.13 0.45461 0.46048 3.34879 1 3.34879 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 275 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3-SPK.BH-CT MUFASA225 ver.1 096F4601.D GC/2023/Mufasa/Quarter 2 7/29/2023 12:41 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 96 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 276 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3-SPK.BH-CT MUFASA225 ver.1 096F4602.D GC/2023/Mufasa/Quarter 2 7/29/2023 12:49 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 96 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 277 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.ON-R3-SPK.BH-CT MUFASA225 ver.1 096F4603.D GC/2023/Mufasa/Quarter 2 7/29/2023 12:58 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 96 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 278 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1.FH-XAD MUFASA225 ver.1 097F4701.D GC/2023/Mufasa/Quarter 2 7/29/2023 1:07 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 97 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 279 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1.FH-XAD MUFASA225 ver.1 097F4702.D GC/2023/Mufasa/Quarter 2 7/29/2023 1:15 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 97 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 280 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1.FH-XAD MUFASA225 ver.1 097F4703.D GC/2023/Mufasa/Quarter 2 7/29/2023 1:24 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 97 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 281 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1.BH-XAD MUFASA225 ver.1 098F4801.D GC/2023/Mufasa/Quarter 2 7/29/2023 1:33 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 98 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 282 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1.BH-XAD MUFASA225 ver.1 098F4802.D GC/2023/Mufasa/Quarter 2 7/29/2023 1:41 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 98 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 283 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1.BH-XAD MUFASA225 ver.1 098F4803.D GC/2023/Mufasa/Quarter 2 7/29/2023 1:50 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 98 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 284 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1.FH-CT MUFASA225 ver.1 099F4901.D GC/2023/Mufasa/Quarter 2 7/29/2023 1:59 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 99 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.46650 0.39528 3.51117 1 3.51117 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 285 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1.FH-CT MUFASA225 ver.1 099F4902.D GC/2023/Mufasa/Quarter 2 7/29/2023 2:08 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 99 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.44682 0.38907 3.37602 1 3.37602 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 286 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1.FH-CT MUFASA225 ver.1 099F4903.D GC/2023/Mufasa/Quarter 2 7/29/2023 2:16 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 99 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.45353 0.39276 3.42205 1 3.42205 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 287 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1.BH-CT MUFASA225 ver.1 100F5001.D GC/2023/Mufasa/Quarter 2 7/29/2023 2:25 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 100 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 288 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1.BH-CT MUFASA225 ver.1 100F5002.D GC/2023/Mufasa/Quarter 2 7/29/2023 2:34 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 100 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 289 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1.BH-CT MUFASA225 ver.1 100F5003.D GC/2023/Mufasa/Quarter 2 7/29/2023 2:42 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 100 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 290 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1-SPK.FH-XAD MUFASA225 ver.1 101F5101.D GC/2023/Mufasa/Quarter 2 7/29/2023 2:51 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 101 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.31019 0.25360 2.43768 1 2.43768 ug/mL Toluene BB 1.13 1.20474 1.22452 8.60380 1 8.60380 ug/mL Ethylbenzene BB 1.49 1.27550 1.64476 9.00901 1 9.00901 ug/mL p-Xylene BV 1.54 1.21508 1.52847 8.89619 1 8.89619 ug/mL m-Xylene VB 1.56 1.38017 1.57386 9.46921 1 9.46921 ug/mL o-Xylene BB 1.78 1.31216 1.57214 9.42487 1 9.42487 ug/mL Styrene BB 2.16 1.38292 1.73265 9.95520 1 9.95520 ug/mL Naphthalene BB 4.53 1.50349 2.06796 10.0160 1 10.0160 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 291 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1-SPK.FH-XAD MUFASA225 ver.1 101F5102.D GC/2023/Mufasa/Quarter 2 7/29/2023 3:00 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 101 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.32857 0.25582 2.56388 1 2.56388 ug/mL Toluene BB 1.13 1.24284 1.24058 8.87067 1 8.87067 ug/mL Ethylbenzene BB 1.49 1.28311 1.63509 9.06211 1 9.06211 ug/mL p-Xylene BV 1.54 1.21761 1.51294 8.91430 1 8.91430 ug/mL m-Xylene VB 1.56 1.36040 1.59392 9.33459 1 9.33459 ug/mL o-Xylene BB 1.78 1.28335 1.57095 9.22255 1 9.22255 ug/mL Styrene BB 2.16 1.39101 1.64553 10.0116 1 10.0116 ug/mL Naphthalene BB 4.53 1.50401 2.01963 10.0193 1 10.0193 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 292 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1-SPK.FH-XAD MUFASA225 ver.1 101F5103.D GC/2023/Mufasa/Quarter 2 7/29/2023 3:08 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 101 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.30514 0.25029 2.40299 1 2.40299 ug/mL Toluene BB 1.13 1.20999 1.21720 8.64054 1 8.64054 ug/mL Ethylbenzene BB 1.49 1.26643 1.62533 8.94566 1 8.94566 ug/mL p-Xylene BV 1.54 1.20840 1.52685 8.84857 1 8.84857 ug/mL m-Xylene VB 1.56 1.37195 1.55506 9.41327 1 9.41327 ug/mL o-Xylene BB 1.78 1.30556 1.55632 9.37852 1 9.37852 ug/mL Styrene BB 2.16 1.38640 1.76239 9.97943 1 9.97943 ug/mL Naphthalene BB 4.53 1.50420 2.04907 10.0206 1 10.0206 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 293 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1-SPK.BH-XAD MUFASA225 ver.1 102F5201.D GC/2023/Mufasa/Quarter 2 7/29/2023 3:17 PM 7/31/2023 10:57 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 102 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.28662 0.29783 2.17193 1 2.17193 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 294 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1-SPK.BH-XAD MUFASA225 ver.1 102F5202.D GC/2023/Mufasa/Quarter 2 7/29/2023 3:26 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 102 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.28751 0.29154 2.17814 1 2.17814 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 295 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1-SPK.BH-XAD MUFASA225 ver.1 102F5203.D GC/2023/Mufasa/Quarter 2 7/29/2023 3:34 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 102 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.29902 0.31016 2.25883 1 2.25883 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 296 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1-SPK.FH-CT MUFASA225 ver.1 103F5301.D GC/2023/Mufasa/Quarter 2 7/29/2023 3:43 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 103 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.36824 1.15866 9.70394 1 9.70394 ug/mL Toluene BB 1.13 0.33674 0.34731 2.52304 1 2.52304 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 297 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1-SPK.FH-CT MUFASA225 ver.1 103F5302.D GC/2023/Mufasa/Quarter 2 7/29/2023 3:52 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 103 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 1.34179 1.17688 9.52225 1 9.52225 ug/mL Toluene BB 1.13 0.32960 0.34320 2.47301 1 2.47301 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 298 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1-SPK.FH-CT MUFASA225 ver.1 103F5303.D GC/2023/Mufasa/Quarter 2 7/29/2023 4:01 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 103 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 1.34994 1.15391 9.57823 1 9.57823 ug/mL Toluene BB 1.13 0.33373 0.33841 2.50195 1 2.50195 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 299 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1-SPK.BH-CT MUFASA225 ver.1 104F5401.D GC/2023/Mufasa/Quarter 2 7/29/2023 4:09 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 104 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 300 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1-SPK.BH-CT MUFASA225 ver.1 104F5402.D GC/2023/Mufasa/Quarter 2 7/29/2023 4:18 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 104 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 301 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R1-SPK.BH-CT MUFASA225 ver.1 104F5403.D GC/2023/Mufasa/Quarter 2 7/29/2023 4:27 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 104 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 302 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 105F5501.D GC/2023/Mufasa/Quarter 2 7/29/2023 4:35 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 105 1 1 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 1.80958 1.60224 12.7348 1 12.7348 ug/mL Toluene BB 1.13 1.75157 1.83354 12.4345 1 12.4345 ug/mL Ethylbenzene BB 1.49 1.76129 2.33114 12.3998 1 12.3998 ug/mL p-Xylene BV 1.54 1.67778 2.17918 12.1967 1 12.1967 ug/mL m-Xylene VB 1.56 1.84683 2.13803 12.6463 1 12.6463 ug/mL o-Xylene BB 1.78 1.78038 2.16149 12.7128 1 12.7128 ug/mL Styrene BB 2.16 1.80512 2.31217 12.8989 1 12.8989 ug/mL Naphthalene BB 4.53 1.93463 2.60173 12.8471 1 12.8471 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 303 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 105F5502.D GC/2023/Mufasa/Quarter 2 7/29/2023 4:44 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 105 1 2 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 1.80034 1.61356 12.6714 1 12.6714 ug/mL Toluene BB 1.13 1.74884 1.86269 12.4155 1 12.4155 ug/mL Ethylbenzene BB 1.49 1.78529 2.28767 12.5673 1 12.5673 ug/mL p-Xylene BV 1.54 1.67274 2.16770 12.1608 1 12.1608 ug/mL m-Xylene VB 1.56 1.82757 2.17526 12.5152 1 12.5152 ug/mL o-Xylene BB 1.78 1.75269 2.17194 12.5184 1 12.5184 ug/mL Styrene BB 2.16 1.81539 2.33194 12.9706 1 12.9706 ug/mL Naphthalene BB 4.53 1.92507 2.57883 12.7843 1 12.7843 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 304 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 105F5503.D GC/2023/Mufasa/Quarter 2 7/29/2023 4:53 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 105 1 3 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.81155 1.53157 12.7484 1 12.7484 ug/mL Toluene BB 1.13 1.71617 1.73988 12.1866 1 12.1866 ug/mL Ethylbenzene BB 1.49 1.72718 2.25863 12.1617 1 12.1617 ug/mL p-Xylene BV 1.54 1.64331 2.10237 11.9509 1 11.9509 ug/mL m-Xylene VB 1.56 1.80625 2.04418 12.3700 1 12.3700 ug/mL o-Xylene BB 1.78 1.74126 2.05947 12.4381 1 12.4381 ug/mL Styrene BB 2.16 1.76643 2.27879 12.6292 1 12.6292 ug/mL Naphthalene BB 4.53 1.89319 2.55986 12.5750 1 12.5750 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 305 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2.FH-XAD MUFASA225 ver.1 106F5601.D GC/2023/Mufasa/Quarter 2 7/29/2023 5:10 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 106 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 306 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2.FH-XAD MUFASA225 ver.1 106F5602.D GC/2023/Mufasa/Quarter 2 7/29/2023 5:19 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 106 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 307 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2.FH-XAD MUFASA225 ver.1 106F5603.D GC/2023/Mufasa/Quarter 2 7/29/2023 5:28 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 106 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 308 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2.BH-XAD MUFASA225 ver.1 107F5701.D GC/2023/Mufasa/Quarter 2 7/29/2023 5:36 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 107 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 309 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2.BH-XAD MUFASA225 ver.1 107F5702.D GC/2023/Mufasa/Quarter 2 7/29/2023 5:45 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 107 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 310 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2.BH-XAD MUFASA225 ver.1 107F5703.D GC/2023/Mufasa/Quarter 2 7/29/2023 5:54 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 107 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 311 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2.FH-CT MUFASA225 ver.1 108F5801.D GC/2023/Mufasa/Quarter 2 7/29/2023 6:03 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 108 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.54390 0.45482 4.04271 1 4.04271 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 312 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2.FH-CT MUFASA225 ver.1 108F5802.D GC/2023/Mufasa/Quarter 2 7/29/2023 6:11 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 108 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.54116 0.45662 4.02391 1 4.02391 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 313 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2.FH-CT MUFASA225 ver.1 108F5803.D GC/2023/Mufasa/Quarter 2 7/29/2023 6:20 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 108 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.55683 0.47807 4.13150 1 4.13150 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 314 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2.BH-CT MUFASA225 ver.1 109F5901.D GC/2023/Mufasa/Quarter 2 7/29/2023 6:29 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 109 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 315 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2.BH-CT MUFASA225 ver.1 109F5902.D GC/2023/Mufasa/Quarter 2 7/29/2023 6:37 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 109 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 316 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2.BH-CT MUFASA225 ver.1 109F5903.D GC/2023/Mufasa/Quarter 2 7/29/2023 6:46 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 109 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 317 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2-SPK.FH-XAD MUFASA225 ver.1 110F6001.D GC/2023/Mufasa/Quarter 2 7/29/2023 6:55 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 110 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.25402 0.19447 2.05196 1 2.05196 ug/mL Toluene BB 1.13 0.96841 0.94655 6.94816 1 6.94816 ug/mL Ethylbenzene BB 1.49 1.29980 1.62693 9.17859 1 9.17859 ug/mL p-Xylene BV 1.54 1.23038 1.51771 9.00533 1 9.00533 ug/mL m-Xylene VB 1.56 1.37096 1.61222 9.40648 1 9.40648 ug/mL o-Xylene BB 1.78 1.30159 1.58710 9.35063 1 9.35063 ug/mL Styrene BB 2.16 1.42919 1.69287 10.2778 1 10.2778 ug/mL Naphthalene BB 4.53 1.50856 2.05472 10.0492 1 10.0492 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 318 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2-SPK.FH-XAD MUFASA225 ver.1 110F6002.D GC/2023/Mufasa/Quarter 2 7/29/2023 7:04 PM 7/31/2023 10:58 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 110 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.26458 0.20497 2.12447 1 2.12447 ug/mL Toluene BB 1.13 0.94841 0.94157 6.80805 1 6.80805 ug/mL Ethylbenzene BB 1.49 1.27065 1.63435 8.97515 1 8.97515 ug/mL p-Xylene BV 1.54 1.21306 1.53294 8.88178 1 8.88178 ug/mL m-Xylene VB 1.56 1.36788 1.57238 9.38554 1 9.38554 ug/mL o-Xylene BB 1.78 1.31090 1.55880 9.41602 1 9.41602 ug/mL Styrene BB 2.16 1.38878 1.71302 9.99609 1 9.99609 ug/mL Naphthalene BB 4.53 1.48572 1.99693 9.89928 1 9.89928 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 319 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2-SPK.FH-XAD MUFASA225 ver.1 110F6003.D GC/2023/Mufasa/Quarter 2 7/29/2023 7:12 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 110 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.24072 0.20053 1.96059 1 1.96059 ug/mL Toluene BB 1.13 0.94769 0.96756 6.80299 1 6.80299 ug/mL Ethylbenzene BB 1.49 1.28985 1.68785 9.10913 1 9.10913 ug/mL p-Xylene BV 1.54 1.22636 1.56179 8.97671 1 8.97671 ug/mL m-Xylene VB 1.56 1.39251 1.59177 9.55323 1 9.55323 ug/mL o-Xylene BB 1.78 1.32244 1.57218 9.49703 1 9.49703 ug/mL Styrene BB 2.16 1.40190 1.75757 10.0875 1 10.0875 ug/mL Naphthalene BB 4.53 1.48715 1.95628 9.90867 1 9.90867 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 320 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2-SPK.BH-XAD MUFASA225 ver.1 111F6101.D GC/2023/Mufasa/Quarter 2 7/29/2023 7:21 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 111 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.23388 0.23717 1.80247 1 1.80247 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 321 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2-SPK.BH-XAD MUFASA225 ver.1 111F6102.D GC/2023/Mufasa/Quarter 2 7/29/2023 7:30 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 111 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.23720 0.23685 1.82576 1 1.82576 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 322 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2-SPK.BH-XAD MUFASA225 ver.1 111F6103.D GC/2023/Mufasa/Quarter 2 7/29/2023 7:38 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 111 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.26201 0.24304 1.99951 1 1.99951 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 323 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2-SPK.FH-CT MUFASA225 ver.1 112F6201.D GC/2023/Mufasa/Quarter 2 7/29/2023 7:47 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 112 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 1.54666 1.33307 10.9292 1 10.9292 ug/mL Toluene BB 1.13 0.29217 0.29570 2.21079 1 2.21079 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 324 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2-SPK.FH-CT MUFASA225 ver.1 112F6202.D GC/2023/Mufasa/Quarter 2 7/29/2023 7:56 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 112 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.55461 1.30448 10.9838 1 10.9838 ug/mL Toluene BB 1.13 0.28805 0.29254 2.18194 1 2.18194 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 325 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2-SPK.FH-CT MUFASA225 ver.1 112F6203.D GC/2023/Mufasa/Quarter 2 7/29/2023 8:04 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 112 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.55136 1.31510 10.9615 1 10.9615 ug/mL Toluene BB 1.13 0.30520 0.30003 2.30213 1 2.30213 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 326 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2-SPK.BH-CT MUFASA225 ver.1 113F6301.D GC/2023/Mufasa/Quarter 2 7/29/2023 8:13 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 113 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 327 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2-SPK.BH-CT MUFASA225 ver.1 113F6302.D GC/2023/Mufasa/Quarter 2 7/29/2023 8:22 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 113 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 328 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R2-SPK.BH-CT MUFASA225 ver.1 113F6303.D GC/2023/Mufasa/Quarter 2 7/29/2023 8:30 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 113 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 329 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3.FH-XAD MUFASA225 ver.1 114F6401.D GC/2023/Mufasa/Quarter 2 7/29/2023 8:39 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 114 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.46417 0.45321 3.41576 1 3.41576 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 330 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3.FH-XAD MUFASA225 ver.1 114F6402.D GC/2023/Mufasa/Quarter 2 7/29/2023 8:48 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 114 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.46590 0.46224 3.42788 1 3.42788 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 331 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3.FH-XAD MUFASA225 ver.1 114F6403.D GC/2023/Mufasa/Quarter 2 7/29/2023 8:57 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 114 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.45850 0.45671 3.37604 1 3.37604 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 332 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3.BH-XAD MUFASA225 ver.1 115F6501.D GC/2023/Mufasa/Quarter 2 7/29/2023 9:06 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 115 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 333 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3.BH-XAD MUFASA225 ver.1 115F6502.D GC/2023/Mufasa/Quarter 2 7/29/2023 9:14 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 115 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 334 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3.BH-XAD MUFASA225 ver.1 115F6503.D GC/2023/Mufasa/Quarter 2 7/29/2023 9:23 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 115 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 335 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 116F6601.D GC/2023/Mufasa/Quarter 2 7/29/2023 9:31 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 116 1 1 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.82186 1.53168 12.8192 1 12.8192 ug/mL Toluene BB 1.13 1.72849 1.78612 12.2729 1 12.2729 ug/mL Ethylbenzene BB 1.49 1.77306 2.24777 12.4820 1 12.4820 ug/mL p-Xylene BV 1.54 1.66366 2.09828 12.0960 1 12.0960 ug/mL m-Xylene VB 1.56 1.82422 2.14858 12.4923 1 12.4923 ug/mL o-Xylene BB 1.78 1.74006 2.13574 12.4296 1 12.4296 ug/mL Styrene BB 2.16 1.80503 2.26242 12.8983 1 12.8983 ug/mL Naphthalene BB 4.53 1.91052 2.61131 12.6888 1 12.6888 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 336 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 116F6602.D GC/2023/Mufasa/Quarter 2 7/29/2023 9:40 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 116 1 2 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.79847 1.54015 12.6585 1 12.6585 ug/mL Toluene BB 1.13 1.73350 1.78410 12.3080 1 12.3080 ug/mL Ethylbenzene BB 1.49 1.78261 2.25745 12.5486 1 12.5486 ug/mL p-Xylene BV 1.54 1.66613 2.11977 12.1137 1 12.1137 ug/mL m-Xylene VB 1.56 1.83668 2.13581 12.5771 1 12.5771 ug/mL o-Xylene BB 1.78 1.71687 2.14060 12.2668 1 12.2668 ug/mL Styrene BB 2.16 1.80227 2.28374 12.8791 1 12.8791 ug/mL Naphthalene BB 4.53 1.89919 2.61824 12.6143 1 12.6143 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 337 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 116F6603.D GC/2023/Mufasa/Quarter 2 7/29/2023 9:49 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 116 1 3 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.79320 1.50820 12.6223 1 12.6223 ug/mL Toluene BB 1.13 1.74620 1.77749 12.3969 1 12.3969 ug/mL Ethylbenzene BV 1.49 1.76165 2.27054 12.4023 1 12.4023 ug/mL p-Xylene VV 1.54 1.66827 2.10800 12.1289 1 12.1289 ug/mL m-Xylene VB 1.56 1.83479 2.08836 12.5643 1 12.5643 ug/mL o-Xylene BB 1.78 1.76031 2.09371 12.5719 1 12.5719 ug/mL Styrene BB 2.16 1.79656 2.27265 12.8392 1 12.8392 ug/mL Naphthalene BB 4.53 1.90163 2.61566 12.6304 1 12.6304 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 338 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3.FH-CT MUFASA225 ver.1 117F6701.D GC/2023/Mufasa/Quarter 2 7/29/2023 10:06 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 117 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 0.51009 0.47058 3.81054 1 3.81054 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 339 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3.FH-CT MUFASA225 ver.1 117F6702.D GC/2023/Mufasa/Quarter 2 7/29/2023 10:15 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 117 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.49290 0.40977 3.69248 1 3.69248 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 340 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3.FH-CT MUFASA225 ver.1 117F6703.D GC/2023/Mufasa/Quarter 2 7/29/2023 10:24 PM 7/31/2023 10:59 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 117 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.49238 0.41022 3.68887 1 3.68887 ug/mL Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 341 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3.BH-CT MUFASA225 ver.1 118F6801.D GC/2023/Mufasa/Quarter 2 7/29/2023 10:32 PM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 118 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 342 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3.BH-CT MUFASA225 ver.1 118F6802.D GC/2023/Mufasa/Quarter 2 7/29/2023 10:41 PM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 118 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 343 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3.BH-CT MUFASA225 ver.1 118F6803.D GC/2023/Mufasa/Quarter 2 7/29/2023 10:50 PM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 118 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 344 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3-SPK.FH-XAD MUFASA225 ver.1 119F6901.D GC/2023/Mufasa/Quarter 2 7/29/2023 10:58 PM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 119 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.25761 0.20533 2.07658 1 2.07658 ug/mL Toluene BB 1.13 1.38251 1.42700 9.84915 1 9.84915 ug/mL Ethylbenzene BB 1.49 1.28425 1.61229 9.07005 1 9.07005 ug/mL p-Xylene BV 1.54 1.22061 1.53179 8.93565 1 8.93565 ug/mL m-Xylene VB 1.56 1.37481 1.60497 9.43271 1 9.43271 ug/mL o-Xylene BB 1.78 1.30997 1.59954 9.40952 1 9.40952 ug/mL Styrene BB 2.16 1.43502 1.72483 10.3184 1 10.3184 ug/mL Naphthalene BB 4.53 1.59161 2.14188 10.5946 1 10.5946 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 345 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3-SPK.FH-XAD MUFASA225 ver.1 119F6902.D GC/2023/Mufasa/Quarter 2 7/29/2023 11:07 PM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 119 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.26022 0.21313 2.09453 1 2.09453 ug/mL Toluene BB 1.13 1.38038 1.39003 9.83422 1 9.83422 ug/mL Ethylbenzene BB 1.49 1.27031 1.64395 8.97280 1 8.97280 ug/mL p-Xylene BV 1.54 1.21448 1.52944 8.89194 1 8.89194 ug/mL m-Xylene VB 1.56 1.37393 1.57061 9.42676 1 9.42676 ug/mL o-Xylene BB 1.78 1.32944 1.59764 9.54620 1 9.54620 ug/mL Styrene BB 2.16 1.40462 1.74862 10.1065 1 10.1065 ug/mL Naphthalene BB 4.53 1.57447 2.14490 10.4820 1 10.4820 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 346 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3-SPK.FH-XAD MUFASA225 ver.1 119F6903.D GC/2023/Mufasa/Quarter 2 7/29/2023 11:16 PM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 119 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.26081 0.20526 2.09856 1 2.09856 ug/mL Toluene BB 1.13 1.36522 1.39354 9.72800 1 9.72800 ug/mL Ethylbenzene BB 1.49 1.27256 1.63442 8.98851 1 8.98851 ug/mL p-Xylene BV 1.54 1.21317 1.53446 8.88258 1 8.88258 ug/mL m-Xylene VB 1.56 1.37631 1.56286 9.44296 1 9.44296 ug/mL o-Xylene BB 1.78 1.32526 1.57162 9.51683 1 9.51683 ug/mL Styrene BB 2.16 1.39676 1.77062 10.0517 1 10.0517 ug/mL Naphthalene BB 4.53 1.57744 2.14480 10.5016 1 10.5016 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 347 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3-SPK.BH-XAD MUFASA225 ver.1 120F7001.D GC/2023/Mufasa/Quarter 2 7/29/2023 11:24 PM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 120 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.51937 0.51962 3.80247 1 3.80247 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 348 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3-SPK.BH-XAD MUFASA225 ver.1 120F7002.D GC/2023/Mufasa/Quarter 2 7/29/2023 11:33 PM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 120 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.52568 0.52135 3.84664 1 3.84664 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 349 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3-SPK.BH-XAD MUFASA225 ver.1 120F7003.D GC/2023/Mufasa/Quarter 2 7/29/2023 11:42 PM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 120 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene BB 1.13 0.50778 0.50130 3.72125 1 3.72125 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 350 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3-SPK.FH-CT MUFASA225 ver.1 121F7101.D GC/2023/Mufasa/Quarter 2 7/29/2023 11:50 PM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 121 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 BH Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 351 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3-SPK.FH-CT MUFASA225 ver.1 121F7102.D GC/2023/Mufasa/Quarter 2 7/29/2023 11:59 PM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 121 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 BH Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 352 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3-SPK.FH-CT MUFASA225 ver.1 121F7103.D GC/2023/Mufasa/Quarter 2 7/30/2023 12:08 AM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 121 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene (0.81)1 Toluene (1.12)1 Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 BH Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 353 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3-SPK.BH-CT MUFASA225 ver.1 122F7201.D GC/2023/Mufasa/Quarter 2 7/30/2023 12:16 AM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 122 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.63773 1.38614 11.5547 1 11.5547 ug/mL Toluene BB 1.13 0.36605 0.35242 2.72836 1 2.72836 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 FH Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 354 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3-SPK.BH-CT MUFASA225 ver.1 122F7202.D GC/2023/Mufasa/Quarter 2 7/30/2023 12:25 AM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 122 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.62532 1.37249 11.4694 1 11.4694 ug/mL Toluene BB 1.13 0.36737 0.36031 2.73761 1 2.73761 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 FH Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 355 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator 0623-247.OFF-R3-SPK.BH-CT MUFASA225 ver.1 122F7203.D GC/2023/Mufasa/Quarter 2 7/30/2023 12:34 AM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Sample Vial 122 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.60972 1.35999 11.3623 1 11.3623 ug/mL Toluene BB 1.13 0.36674 0.36966 2.73320 1 2.73320 ug/mL Ethylbenzene (1.49)1 p-Xylene (1.53)1 m-Xylene (1.56)1 o-Xylene (1.77)1 Styrene (2.15)1 Naphthalene (4.52)1 FH Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 356 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 123F7301.D GC/2023/Mufasa/Quarter 2 7/30/2023 12:42 AM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 123 1 1 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.84068 1.57939 12.9484 1 12.9484 ug/mL Toluene BB 1.13 1.79048 1.85771 12.7071 1 12.7071 ug/mL Ethylbenzene BB 1.49 1.82063 2.34689 12.8140 1 12.8140 ug/mL p-Xylene BV 1.54 1.72054 2.22486 12.5018 1 12.5018 ug/mL m-Xylene VB 1.56 1.88959 2.24298 12.9374 1 12.9374 ug/mL o-Xylene BB 1.78 1.79372 2.25275 12.8064 1 12.8064 ug/mL Styrene BB 2.16 1.86552 2.42045 13.3201 1 13.3201 ug/mL Naphthalene BB 4.53 1.97928 2.67295 13.1403 1 13.1403 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 357 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 123F7302.D GC/2023/Mufasa/Quarter 2 7/30/2023 12:51 AM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 123 1 2 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.81489 1.56913 12.7713 1 12.7713 ug/mL Toluene BB 1.13 1.74255 1.84620 12.3714 1 12.3714 ug/mL Ethylbenzene BB 1.49 1.81796 2.32594 12.7953 1 12.7953 ug/mL p-Xylene BV 1.54 1.71259 2.19845 12.4450 1 12.4450 ug/mL m-Xylene VB 1.56 1.88308 2.20957 12.8930 1 12.8930 ug/mL o-Xylene BB 1.78 1.77369 2.19842 12.6658 1 12.6658 ug/mL Styrene BB 2.16 1.86602 2.37792 13.3235 1 13.3235 ug/mL Naphthalene BB 4.53 1.97543 2.67535 13.1150 1 13.1150 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 358 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225 ver.1 123F7303.D GC/2023/Mufasa/Quarter 2 7/30/2023 1:00 AM 7/31/2023 11:00 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 123 1 3 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:02 AM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.82825 1.52971 12.8631 1 12.8631 ug/mL Toluene BB 1.13 1.75282 1.79377 12.4433 1 12.4433 ug/mL Ethylbenzene BV 1.49 1.78645 2.30966 12.5754 1 12.5754 ug/mL p-Xylene VV 1.54 1.69564 2.15934 12.3242 1 12.3242 ug/mL m-Xylene VB 1.56 1.86852 2.13651 12.7939 1 12.7939 ug/mL o-Xylene BB 1.78 1.80693 2.17872 12.8992 1 12.8992 ug/mL Styrene BB 2.16 1.83440 2.35866 13.1031 1 13.1031 ug/mL Naphthalene BB 4.53 1.96368 2.69836 13.0378 1 13.0378 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 359 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #6 MUFASA225A ver.1 001F0101.D GC/2023/Mufasa/Quarter 2 7/31/2023 11:44 AM 8/1/2023 3:43 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 1 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 149.367 129.853 1026.10 1 1026.10 ug/mL Toluene BB 1.13 147.047 163.610 1030.29 1 1030.29 ug/mL Ethylbenzene BV 1.49 146.887 182.107 1025.38 1 1025.38 ug/mL p-Xylene VV 1.54 144.417 198.504 1030.38 1 1030.38 ug/mL m-Xylene VB 1.57 147.823 212.161 1006.46 1 1006.46 ug/mL o-Xylene BB 1.78 148.822 212.410 1045.26 1 1045.26 ug/mL Styrene BB 2.15 154.978 238.759 1080.88 1 1080.88 ug/mL Naphthalene BB 4.52 158.315 231.746 1039.74 1 1039.74 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 360 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #6 MUFASA225A ver.1 001F0102.D GC/2023/Mufasa/Quarter 2 7/31/2023 11:53 AM 8/1/2023 3:43 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 1 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 146.799 130.239 1008.46 1 1008.46 ug/mL Toluene BB 1.13 144.612 161.123 1013.24 1 1013.24 ug/mL Ethylbenzene BV 1.49 144.628 184.404 1009.60 1 1009.60 ug/mL p-Xylene VV 1.54 142.120 190.559 1013.99 1 1013.99 ug/mL m-Xylene VB 1.56 145.757 214.215 992.396 1 992.396 ug/mL o-Xylene BB 1.78 146.683 215.106 1030.24 1 1030.24 ug/mL Styrene BB 2.15 152.573 238.119 1064.11 1 1064.11 ug/mL Naphthalene BB 4.52 156.202 232.915 1025.86 1 1025.86 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 361 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #6 MUFASA225A ver.1 001F0103.D GC/2023/Mufasa/Quarter 2 7/31/2023 12:01 PM 8/1/2023 3:43 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 1 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 144.456 128.316 992.370 1 992.370 ug/mL Toluene BB 1.12 142.652 162.899 999.502 1 999.502 ug/mL Ethylbenzene BV 1.49 142.638 188.595 995.719 1 995.719 ug/mL p-Xylene VV 1.53 140.260 196.960 1000.73 1 1000.73 ug/mL m-Xylene VB 1.56 143.688 215.752 978.312 1 978.312 ug/mL o-Xylene BB 1.78 144.549 206.669 1015.26 1 1015.26 ug/mL Styrene BB 2.15 150.480 233.123 1049.52 1 1049.52 ug/mL Naphthalene BB 4.52 154.049 229.563 1011.72 1 1011.72 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 362 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #5 MUFASA225A ver.1 002F0201.D GC/2023/Mufasa/Quarter 2 7/31/2023 12:10 PM 8/1/2023 3:43 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 2 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 49.7801 44.4404 342.175 1 342.175 ug/mL Toluene BB 1.13 48.8040 55.7749 342.058 1 342.058 ug/mL Ethylbenzene BV 1.49 48.8236 66.8195 340.894 1 340.894 ug/mL p-Xylene VV 1.53 47.7523 67.1621 340.854 1 340.854 ug/mL m-Xylene VB 1.56 49.6075 69.5163 337.804 1 337.804 ug/mL o-Xylene BB 1.78 49.2916 70.2691 346.344 1 346.344 ug/mL Styrene BB 2.15 51.4836 77.2062 359.276 1 359.276 ug/mL Naphthalene BB 4.52 52.5611 75.9839 345.291 1 345.291 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 363 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #5 MUFASA225A ver.1 002F0202.D GC/2023/Mufasa/Quarter 2 7/31/2023 12:19 PM 8/1/2023 3:43 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 2 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 49.6522 44.6164 341.297 1 341.297 ug/mL Toluene BB 1.13 48.8254 54.9915 342.208 1 342.208 ug/mL Ethylbenzene BV 1.49 48.6711 67.6176 339.829 1 339.829 ug/mL p-Xylene VV 1.53 47.5933 67.1827 339.720 1 339.720 ug/mL m-Xylene VB 1.56 49.4794 69.6359 336.932 1 336.932 ug/mL o-Xylene BB 1.78 49.1544 70.0565 345.381 1 345.381 ug/mL Styrene BB 2.15 51.3626 73.4775 358.432 1 358.432 ug/mL Naphthalene BB 4.52 52.3609 74.5863 343.976 1 343.976 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 364 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #5 MUFASA225A ver.1 002F0203.D GC/2023/Mufasa/Quarter 2 7/31/2023 12:27 PM 8/1/2023 3:43 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 2 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 49.6410 44.2947 341.220 1 341.220 ug/mL Toluene BB 1.13 48.7673 55.7099 341.800 1 341.800 ug/mL Ethylbenzene BV 1.49 48.7181 67.0002 340.157 1 340.157 ug/mL p-Xylene VV 1.53 47.6454 66.7200 340.091 1 340.091 ug/mL m-Xylene VB 1.56 49.5333 69.3119 337.299 1 337.299 ug/mL o-Xylene BB 1.78 49.1884 70.7608 345.619 1 345.619 ug/mL Styrene BB 2.15 51.4022 77.6515 358.708 1 358.708 ug/mL Naphthalene BB 4.52 52.4697 75.9871 344.690 1 344.690 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 365 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #4 MUFASA225A ver.1 003F0301.D GC/2023/Mufasa/Quarter 2 7/31/2023 12:36 PM 8/1/2023 3:43 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 3 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 6.95844 6.06910 48.0950 1 48.0950 ug/mL Toluene BB 1.13 6.69620 7.26854 47.0738 1 47.0738 ug/mL Ethylbenzene BV 1.49 6.74938 9.12323 47.2166 1 47.2166 ug/mL p-Xylene VV 1.53 6.49678 8.61398 46.5715 1 46.5715 ug/mL m-Xylene VB 1.56 6.97589 8.63420 47.5653 1 47.5653 ug/mL o-Xylene BB 1.78 6.74797 8.77612 47.5960 1 47.5960 ug/mL Styrene BB 2.15 7.12123 9.64054 49.9648 1 49.9648 ug/mL Naphthalene BB 4.53 7.30306 10.0929 48.0994 1 48.0994 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 366 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #4 MUFASA225A ver.1 003F0302.D GC/2023/Mufasa/Quarter 2 7/31/2023 12:45 PM 8/1/2023 3:43 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 3 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 6.92257 6.12690 47.8486 1 47.8486 ug/mL Toluene BB 1.13 6.72871 7.27545 47.3016 1 47.3016 ug/mL Ethylbenzene BV 1.49 6.73748 9.13193 47.1335 1 47.1335 ug/mL p-Xylene VV 1.53 6.48880 8.77543 46.5145 1 46.5145 ug/mL m-Xylene VB 1.56 6.98067 8.42440 47.5978 1 47.5978 ug/mL o-Xylene BB 1.78 6.80248 8.52305 47.9788 1 47.9788 ug/mL Styrene BB 2.15 7.02859 9.51705 49.3189 1 49.3189 ug/mL Naphthalene BB 4.53 7.26771 10.2724 47.8673 1 47.8673 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 367 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #4 MUFASA225A ver.1 003F0303.D GC/2023/Mufasa/Quarter 2 7/31/2023 12:53 PM 8/1/2023 3:43 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 3 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 6.87588 6.00600 47.5280 1 47.5280 ug/mL Toluene BB 1.13 6.65656 7.10797 46.7962 1 46.7962 ug/mL Ethylbenzene BV 1.49 6.70551 8.99180 46.9104 1 46.9104 ug/mL p-Xylene VV 1.53 6.44588 8.37985 46.2084 1 46.2084 ug/mL m-Xylene VB 1.56 6.92551 8.60982 47.2223 1 47.2223 ug/mL o-Xylene BB 1.78 6.72059 8.73608 47.4037 1 47.4037 ug/mL Styrene BB 2.15 7.06070 9.02091 49.5428 1 49.5428 ug/mL Naphthalene BB 4.53 7.24969 10.1292 47.7489 1 47.7489 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 368 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225A ver.1 004F0401.D GC/2023/Mufasa/Quarter 2 7/31/2023 1:02 PM 8/1/2023 3:44 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 4 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.80464 1.56989 12.7009 1 12.7009 ug/mL Toluene BB 1.13 1.72587 1.80437 12.2545 1 12.2545 ug/mL Ethylbenzene BB 1.49 1.75877 2.21811 12.3822 1 12.3822 ug/mL p-Xylene BV 1.54 1.64064 2.07619 11.9318 1 11.9318 ug/mL m-Xylene VB 1.56 1.80856 2.13382 12.3857 1 12.3857 ug/mL o-Xylene BB 1.78 1.71309 2.10202 12.2402 1 12.2402 ug/mL Styrene BB 2.16 1.79132 2.25687 12.8027 1 12.8027 ug/mL Naphthalene BB 4.53 1.87696 2.56178 12.4684 1 12.4684 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 369 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225A ver.1 004F0402.D GC/2023/Mufasa/Quarter 2 7/31/2023 1:11 PM 8/1/2023 3:44 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 4 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.79030 1.53725 12.6024 1 12.6024 ug/mL Toluene BB 1.13 1.71304 1.76824 12.1646 1 12.1646 ug/mL Ethylbenzene BB 1.49 1.72396 2.24178 12.1392 1 12.1392 ug/mL p-Xylene BV 1.54 1.63382 2.07856 11.8831 1 11.8831 ug/mL m-Xylene VB 1.56 1.81158 2.05734 12.4063 1 12.4063 ug/mL o-Xylene BB 1.78 1.73811 2.04914 12.4160 1 12.4160 ug/mL Styrene BB 2.16 1.78247 2.24531 12.7410 1 12.7410 ug/mL Naphthalene BB 4.53 1.87634 2.52180 12.4643 1 12.4643 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 370 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA225A ver.1 004F0403.D GC/2023/Mufasa/Quarter 2 7/31/2023 1:19 PM 8/1/2023 3:44 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 4 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 1.80728 1.53529 12.7191 1 12.7191 ug/mL Toluene BB 1.13 1.73184 1.78440 12.2963 1 12.2963 ug/mL Ethylbenzene BB 1.49 1.75632 2.20180 12.3651 1 12.3651 ug/mL p-Xylene BV 1.54 1.64677 2.07221 11.9756 1 11.9756 ug/mL m-Xylene VB 1.56 1.81429 2.11273 12.4247 1 12.4247 ug/mL o-Xylene BB 1.78 1.70540 2.10071 12.1863 1 12.1863 ug/mL Styrene BB 2.16 1.77841 2.08365 12.7127 1 12.7127 ug/mL Naphthalene BB 4.53 1.86126 2.55323 12.3653 1 12.3653 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 371 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #2 MUFASA225A ver.1 005F0501.D GC/2023/Mufasa/Quarter 2 7/31/2023 1:28 PM 8/1/2023 3:44 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 5 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.72063 0.61644 5.25642 1 5.25642 ug/mL Toluene BB 1.13 0.68383 0.70467 4.95454 1 4.95454 ug/mL Ethylbenzene BB 1.49 0.69658 0.88211 4.96814 1 4.96814 ug/mL p-Xylene BV 1.54 0.64703 0.79673 4.84424 1 4.84424 ug/mL m-Xylene VB 1.56 0.71511 0.82427 4.94145 1 4.94145 ug/mL o-Xylene BB 1.78 0.68907 0.80163 5.04940 1 5.04940 ug/mL Styrene BB 2.16 0.70023 0.80293 5.19523 1 5.19523 ug/mL Naphthalene BB 4.53 0.73741 0.99515 4.98540 1 4.98540 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 372 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #2 MUFASA225A ver.1 005F0502.D GC/2023/Mufasa/Quarter 2 7/31/2023 1:36 PM 8/1/2023 3:44 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 5 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.72764 0.61410 5.30458 1 5.30458 ug/mL Toluene BB 1.13 0.67645 0.69656 4.90286 1 4.90286 ug/mL Ethylbenzene BB 1.49 0.69723 0.86260 4.97266 1 4.97266 ug/mL p-Xylene BV 1.54 0.64204 0.79261 4.80860 1 4.80860 ug/mL m-Xylene VB 1.56 0.71040 0.81088 4.90940 1 4.90940 ug/mL o-Xylene BB 1.78 0.66858 0.80859 4.90553 1 4.90553 ug/mL Styrene BB 2.16 0.69979 0.80077 5.19218 1 5.19218 ug/mL Naphthalene BB 4.53 0.74795 0.96585 5.05460 1 5.05460 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 373 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #2 MUFASA225A ver.1 005F0503.D GC/2023/Mufasa/Quarter 2 7/31/2023 1:45 PM 8/1/2023 3:44 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 5 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.82 0.71414 0.61326 5.21185 1 5.21185 ug/mL Toluene BB 1.13 0.69882 0.69487 5.05956 1 5.05956 ug/mL Ethylbenzene BB 1.49 0.69467 0.86916 4.95480 1 4.95480 ug/mL p-Xylene BV 1.54 0.64085 0.76517 4.80011 1 4.80011 ug/mL m-Xylene VB 1.56 0.71492 0.81130 4.94012 1 4.94012 ug/mL o-Xylene BB 1.78 0.67228 0.80468 4.93154 1 4.93154 ug/mL Styrene BB 2.16 0.68213 0.81331 5.06902 1 5.06902 ug/mL Naphthalene BB 4.53 0.72485 0.95578 4.90294 1 4.90294 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 374 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #1 MUFASA225A ver.1 006F0601.D GC/2023/Mufasa/Quarter 2 7/31/2023 1:54 PM 8/1/2023 3:44 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 6 1 1 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene MM 0.82 0.36419 0.30992 2.80852 1 2.80852 ug/mL Toluene BB 1.13 0.34231 0.34749 2.56209 1 2.56209 ug/mL Ethylbenzene BB 1.49 0.34367 0.43417 2.50486 1 2.50486 ug/mL p-Xylene BV 1.54 0.31909 0.38757 2.50499 1 2.50499 ug/mL m-Xylene VB 1.56 0.35743 0.40033 2.50632 1 2.50632 ug/mL o-Xylene BB 1.78 0.33238 0.39688 2.54467 1 2.54467 ug/mL Styrene BB 2.16 0.34718 0.39497 2.73365 1 2.73365 ug/mL Naphthalene BB 4.53 0.36931 0.45841 2.56823 1 2.56823 ug/mL Analyst Peak Integration Comments 15:43:58 07/31/23 Remington Heathcoat ii Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 375 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #1 MUFASA225A ver.1 006F0602.D GC/2023/Mufasa/Quarter 2 7/31/2023 2:02 PM 8/1/2023 3:44 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 6 1 2 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene MM 0.82 0.35937 0.31976 2.77546 1 2.77546 ug/mL Toluene BB 1.13 0.34228 0.33469 2.56185 1 2.56185 ug/mL Ethylbenzene BB 1.49 0.36522 0.43867 2.65527 1 2.65527 ug/mL p-Xylene BV 1.54 0.32911 0.38351 2.57647 1 2.57647 ug/mL m-Xylene VB 1.56 0.36021 0.40544 2.52525 1 2.52525 ug/mL o-Xylene BB 1.78 0.33294 0.39109 2.54865 1 2.54865 ug/mL Styrene BB 2.16 0.33850 0.38816 2.67309 1 2.67309 ug/mL Naphthalene BB 4.53 0.37011 0.47148 2.57349 1 2.57349 ug/mL Analyst Peak Integration Comments 15:43:09 07/31/23 Remington Heathcoat ii Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 376 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #1 MUFASA225A ver.1 006F0603.D GC/2023/Mufasa/Quarter 2 7/31/2023 2:11 PM 8/1/2023 3:44 PM Mufasa Remington Heathcoat Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 6 1 3 of 3 MUFASA219.M MUFASA219_BTEXSN.M 8/1/2023 3:42 PM 8/2/2023 12:28 PM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 0 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene MM 0.82 0.36443 0.32098 2.81017 1 2.81017 ug/mL Toluene BB 1.13 0.35179 0.34883 2.62845 1 2.62845 ug/mL Ethylbenzene BB 1.49 0.34506 0.43133 2.51453 1 2.51453 ug/mL p-Xylene BV 1.54 0.32739 0.39388 2.56416 1 2.56416 ug/mL m-Xylene VB 1.56 0.36392 0.40410 2.55051 1 2.55051 ug/mL o-Xylene BB 1.78 0.34821 0.39776 2.65583 1 2.65583 ug/mL Styrene BB 2.16 0.35180 0.37402 2.76588 1 2.76588 ug/mL Naphthalene BB 4.53 0.37750 0.46156 2.62205 1 2.62205 ug/mL Analyst Peak Integration Comments 15:38:46 07/31/23 Remington Heathcoat ii 15:44:14 07/31/23 Remington Heathcoat ii Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 377 of 640 ©Mostardi Platt ===================================================================== Calibration Table ===================================================================== Calib. Data Modified : 7/19/2023 9:43:23 AM Rel. Reference Window : 0.000 % Abs. Reference Window : 0.080 min Rel. Non-ref. Window : 0.000 % Abs. Non-ref. Window : 0.030 min Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks Curve Type : Linear Origin : Ignored Weight : Quadratic (Amnt) Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75% Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket) Signal 1: FID1 A, Front Signal RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ug/mL] -------|--|--|----------|----------|----------|---|--|--------------- 0.811 1 1 2.62990 3.82720e-1 6.87160 Benzene 2 5.24670 7.44576e-1 7.04656 3 13.01960 1.82558 7.13178 4 50.21850 7.14389 7.02957 5 351.52900 51.40373 6.83859 6 1054.58904 154.57415 6.82254 1.123 1 1 2.58827 3.53691e-1 7.31788 Toluene 2 5.16366 6.96259e-1 7.41629 3 12.81350 1.72863 7.41253 4 49.42360 6.95080 7.11049 5 345.97000 50.64409 6.83140 6 1037.89600 152.66162 6.79867 1.489 1 1 2.59100 3.61083e-1 7.17563 Ethylbenzene 2 5.16930 7.14765e-1 7.23217 3 12.82770 1.76777 7.25644 4 49.47840 6.98640 7.08210 5 346.34900 50.59069 6.84610 Method C:\GC\2023\MUFASA\Q2\MUFASA219\MUFASA219_BTEXSN.M Mufasa 7/19/2023 10:02:17 AM Brianna Berry Page 1 of 6 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 378 of 640 ©Mostardi Platt RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ug/mL] -------|--|--|----------|----------|----------|---|--|--------------- 6 1039.00000 152.25499 6.82408 1.533 1 1 2.57140 3.36267e-1 7.64690 p-Xylene 2 5.13000 6.69216e-1 7.66569 3 12.73000 1.67525 7.59884 4 49.10100 6.73155 7.29416 5 343.71100 49.51391 6.94171 6 1031.13360 149.65548 6.89005 1.562 1 1 2.58280 3.70502e-1 6.97108 m-Xylene 2 5.15280 7.43763e-1 6.92801 3 12.78670 1.83857 6.95471 4 49.32000 7.19730 6.85257 5 345.24100 51.31292 6.72815 6 1035.72300 153.12841 6.76375 1.774 1 1 2.62020 3.49791e-1 7.49076 o-Xylene 2 5.22740 7.00552e-1 7.46183 3 12.97180 1.74341 7.44048 4 50.03428 7.00116 7.14657 5 350.24000 51.05578 6.85995 6 1050.72000 154.04396 6.82091 2.148 1 1 2.71720 3.52171e-1 7.71557 Styrene 2 5.42080 7.14339e-1 7.58856 3 13.45180 1.82042 7.38938 4 51.88570 7.30612 7.10167 5 363.20000 53.29813 6.81450 6 1089.60000 160.28038 6.79809 4.516 1 1 2.59350 3.76735e-1 6.88415 Naphthalene 2 5.17413 7.58107e-1 6.82506 3 12.83950 1.89856 6.76277 4 49.52380 7.45057 6.64698 5 346.66700 53.57668 6.47048 6 1040.00000 160.40530 6.48358 1 Warnings or Errors : Warning : Cal. table open and changed while report was generated. ===================================================================== Peak Sum Table ===================================================================== ***No Entries in table*** ===================================================================== Method C:\GC\2023\MUFASA\Q2\MUFASA219\MUFASA219_BTEXSN.M Mufasa 7/19/2023 10:02:17 AM Brianna Berry Page 2 of 6 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 379 of 640 ©Mostardi Platt ===================================================================== Calibration Curves ===================================================================== Amount[ug/mL] 0 500 1000 Area 0 20 40 60 80 100 120 140 123 4 5 6 Benzene at exp. RT: 0.811 FID1 A, Front Signal Correlation: 0.99976 Residual Std. Dev.: 1.53717 Formula: y = mx + b m: 1.43776e-1 b: 8.91960e-5 x: Amount y: Area Calibration Level Weights: Level 1 : 1 Level 2 : 0.25125 Level 3 : 0.040802 Level 4 : 0.002743 Level 5 : 0.000056 Level 6 : 6.21887e-006 Amount[ug/mL] 0 500 1000 Area 0 20 40 60 80 100 120 140 123 4 5 6 Toluene at exp. RT: 1.123 FID1 A, Front Signal Correlation: 0.99937 Residual Std. Dev.: 2.35424 Formula: y = mx + b m: 1.42746e-1 b: -2.34158e-2 x: Amount y: Area Calibration Level Weights: Level 1 : 1 Level 2 : 0.251249 Level 3 : 0.040802 Level 4 : 0.002743 Level 5 : 0.000056 Level 6 : 6.21887e-006 Amount[ug/mL] 0 500 1000 Area 0 20 40 60 80 100 120 140 123 4 5 6 Ethylbenzene at exp. RT: 1.489 FID1 A, Front Signal Correlation: 0.99967 Residual Std. Dev.: 1.77833 Formula: y = mx + b m: 1.43267e-1 b: -1.51918e-2 x: Amount y: Area Calibration Level Weights: Level 1 : 1 Level 2 : 0.25123 Level 3 : 0.040798 Level 4 : 0.002742 Level 5 : 0.000056 Method C:\GC\2023\MUFASA\Q2\MUFASA219\MUFASA219_BTEXSN.M Mufasa 7/19/2023 10:02:17 AM Brianna Berry Page 3 of 6 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 380 of 640 ©Mostardi Platt Level 6 : 6.21876e-006 Method C:\GC\2023\MUFASA\Q2\MUFASA219\MUFASA219_BTEXSN.M Mufasa 7/19/2023 10:02:17 AM Brianna Berry Page 4 of 6 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 381 of 640 ©Mostardi Platt Amount[ug/mL] 0 500 1000 Area 0 20 40 60 80 100 120 140 123 4 5 6 p-Xylene at exp. RT: 1.533 FID1 A, Front Signal Correlation: 0.99926 Residual Std. Dev.: 2.65602 Formula: y = mx + b m: 1.40190e-1 b: -3.20835e-2 x: Amount y: Area Calibration Level Weights: Level 1 : 1 Level 2 : 0.251249 Level 3 : 0.040802 Level 4 : 0.002743 Level 5 : 0.000056 Level 6 : 6.21884e-006 Amount[ug/mL] 0 500 1000 Area 0 20 40 60 80 100 120 140 123 4 5 6 m-Xylene at exp. RT: 1.562 FID1 A, Front Signal Correlation: 0.99993 Residual Std. Dev.: 0.59013 Formula: y = mx + b m: 1.46884e-1 b: -1.07100e-2 x: Amount y: Area Calibration Level Weights: Level 1 : 1 Level 2 : 0.251244 Level 3 : 0.0408 Level 4 : 0.002742 Level 5 : 0.000056 Level 6 : 6.21862e-006 Amount[ug/mL] 0 500 1000 Area 0 20 40 60 80 100 120 140 123 4 5 6 o-Xylene at exp. RT: 1.774 FID1 A, Front Signal Correlation: 0.99946 Residual Std. Dev.: 2.30400 Formula: y = mx + b m: 1.42406e-1 b: -3.00008e-2 x: Amount y: Area Calibration Level Weights: Level 1 : 1 Level 2 : 0.251245 Level 3 : 0.040801 Level 4 : 0.002742 Level 5 : 0.000056 Level 6 : 6.21863e-006 Method C:\GC\2023\MUFASA\Q2\MUFASA219\MUFASA219_BTEXSN.M Mufasa 7/19/2023 10:02:17 AM Brianna Berry Page 5 of 6 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 382 of 640 ©Mostardi Platt Amount[ug/mL] 0 500 1000 Area 0 20 40 60 80 100 120 140 123 4 5 6 Styrene at exp. RT: 2.148 FID1 A, Front Signal Correlation: 0.99953 Residual Std. Dev.: 2.12088 Formula: y = mx + b m: 1.43423e-1 b: -4.48867e-2 x: Amount y: Area Calibration Level Weights: Level 1 : 1 Level 2 : 0.251256 Level 3 : 0.040802 Level 4 : 0.002743 Level 5 : 0.000056 Level 6 : 6.21883e-006 Amount[ug/mL] 0 500 1000 Area 0 20 40 60 80 100 120 140 123 4 5 6 Naphthalene at exp. RT: 4.516 FID1 A, Front Signal Correlation: 0.99986 Residual Std. Dev.: 1.10200 Formula: y = mx + b m: 1.52286e-1 b: -2.17964e-2 x: Amount y: Area Calibration Level Weights: Level 1 : 1 Level 2 : 0.251245 Level 3 : 0.040802 Level 4 : 0.002742 Level 5 : 0.000056 Level 6 : 6.21879e-006 ===================================================================== Method C:\GC\2023\MUFASA\Q2\MUFASA219\MUFASA219_BTEXSN.M Mufasa 7/19/2023 10:02:17 AM Brianna Berry Page 6 of 6 Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 383 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #6 MUFASA219 ver.2 031F0102.D GC/2023/Mufasa/Quarter 2 7/18/2023 9:16 AM 7/19/2023 9:47 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 31 1 2 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 153.855 169.993 1070.10 1 1070.10 ug/mL Toluene BB 1.12 151.983 201.801 1064.87 1 1064.87 ug/mL Ethylbenzene BV 1.49 151.694 210.518 1058.93 1 1058.93 ug/mL p-Xylene VV 1.53 149.083 220.015 1063.66 1 1063.66 ug/mL m-Xylene VB 1.56 152.506 242.621 1038.35 1 1038.35 ug/mL o-Xylene BB 1.77 153.503 237.732 1078.13 1 1078.13 ug/mL Styrene BB 2.15 159.732 258.874 1114.03 1 1114.03 ug/mL Naphthalene BB 4.52 159.628 242.668 1048.36 1 1048.36 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 384 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #6 MUFASA219 ver.2 031F0103.D GC/2023/Mufasa/Quarter 2 7/18/2023 9:24 AM 7/19/2023 9:47 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 31 1 3 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 155.103 166.479 1078.78 1 1078.78 ug/mL Toluene BB 1.12 153.186 196.050 1073.30 1 1073.30 ug/mL Ethylbenzene BV 1.49 152.605 204.527 1065.29 1 1065.29 ug/mL p-Xylene VV 1.53 150.049 219.040 1070.55 1 1070.55 ug/mL m-Xylene VB 1.56 153.528 233.214 1045.30 1 1045.30 ug/mL o-Xylene BB 1.77 154.429 236.380 1084.64 1 1084.64 ug/mL Styrene BB 2.15 160.639 255.576 1120.35 1 1120.35 ug/mL Naphthalene BB 4.52 160.735 240.021 1055.62 1 1055.62 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 385 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #6 MUFASA219 ver.2 031F0104.D GC/2023/Mufasa/Quarter 2 7/18/2023 9:33 AM 7/19/2023 9:47 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 31 1 4 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 154.765 168.526 1076.43 1 1076.43 ug/mL Toluene BB 1.12 152.816 200.441 1070.70 1 1070.70 ug/mL Ethylbenzene BV 1.49 152.466 211.486 1064.31 1 1064.31 ug/mL p-Xylene VV 1.53 149.834 218.849 1069.02 1 1069.02 ug/mL m-Xylene VB 1.56 153.351 244.916 1044.10 1 1044.10 ug/mL o-Xylene BB 1.77 154.200 236.887 1083.03 1 1083.03 ug/mL Styrene BB 2.15 160.470 259.835 1119.17 1 1119.17 ug/mL Naphthalene BB 4.52 160.853 244.717 1056.40 1 1056.40 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 386 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #5 MUFASA219 ver.2 032F0201.D GC/2023/Mufasa/Quarter 2 7/18/2023 9:41 AM 7/19/2023 9:47 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 32 1 1 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 51.5081 56.6907 358.252 1 358.252 ug/mL Toluene BB 1.12 50.7176 66.8954 355.463 1 355.463 ug/mL Ethylbenzene BV 1.49 50.6278 75.5787 353.487 1 353.487 ug/mL p-Xylene VV 1.53 49.5617 74.9005 353.761 1 353.761 ug/mL m-Xylene VB 1.56 51.3425 76.4632 349.617 1 349.617 ug/mL o-Xylene BB 1.77 51.1133 76.8148 359.136 1 359.136 ug/mL Styrene BB 2.15 53.3400 82.2728 372.219 1 372.219 ug/mL Naphthalene BB 4.52 53.5474 79.6942 351.768 1 351.768 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 387 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #5 MUFASA219 ver.2 032F0202.D GC/2023/Mufasa/Quarter 2 7/18/2023 9:50 AM 7/19/2023 9:47 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 32 1 2 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 51.3391 55.9652 357.077 1 357.077 ug/mL Toluene BB 1.12 50.5635 66.6780 354.383 1 354.383 ug/mL Ethylbenzene BV 1.49 50.5353 75.5547 352.841 1 352.841 ug/mL p-Xylene VV 1.53 49.4461 72.7330 352.936 1 352.936 ug/mL m-Xylene VB 1.56 51.2521 76.7896 349.001 1 349.001 ug/mL o-Xylene BB 1.77 50.9674 76.1267 358.112 1 358.112 ug/mL Styrene BB 2.15 53.2201 78.9574 371.383 1 371.383 ug/mL Naphthalene BB 4.52 53.5192 80.1297 351.582 1 351.582 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 388 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #5 MUFASA219 ver.2 032F0203.D GC/2023/Mufasa/Quarter 2 7/18/2023 9:59 AM 7/19/2023 9:47 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 32 1 3 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 51.3640 56.2309 357.250 1 357.250 ug/mL Toluene BB 1.12 50.6512 67.0156 354.998 1 354.998 ug/mL Ethylbenzene BV 1.49 50.6089 75.6726 353.355 1 353.355 ug/mL p-Xylene VV 1.53 49.5340 73.1255 353.563 1 353.563 ug/mL m-Xylene VB 1.56 51.3441 77.0888 349.627 1 349.627 ug/mL o-Xylene BB 1.77 51.0867 76.8110 358.949 1 358.949 ug/mL Styrene BB 2.15 53.3343 78.9120 372.180 1 372.180 ug/mL Naphthalene BB 4.52 53.6634 80.1164 352.529 1 352.529 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 389 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #4 MUFASA219 ver.2 033F0301.D GC/2023/Mufasa/Quarter 2 7/18/2023 10:16 AM 7/19/2023 9:48 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 33 1 1 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 7.13077 7.56783 49.5958 1 49.5958 ug/mL Toluene BB 1.12 6.94024 8.23802 48.7835 1 48.7835 ug/mL Ethylbenzene BV 1.49 6.95957 10.1024 48.6837 1 48.6837 ug/mL p-Xylene VV 1.53 6.70983 9.57874 48.0911 1 48.0911 ug/mL m-Xylene VB 1.56 7.17066 9.52027 48.8913 1 48.8913 ug/mL o-Xylene BB 1.77 6.97638 9.49946 49.1999 1 49.1999 ug/mL Styrene BB 2.15 7.28079 9.46112 51.0773 1 51.0773 ug/mL Naphthalene BB 4.52 7.41382 10.3937 48.8267 1 48.8267 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 390 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #4 MUFASA219 ver.2 033F0302.D GC/2023/Mufasa/Quarter 2 7/18/2023 10:25 AM 7/19/2023 9:48 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 33 1 2 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 7.12391 7.43887 49.5481 1 49.5481 ug/mL Toluene BB 1.12 6.92384 8.42604 48.6686 1 48.6686 ug/mL Ethylbenzene BV 1.49 6.97884 9.85224 48.8182 1 48.8182 ug/mL p-Xylene VV 1.53 6.72836 9.66401 48.2234 1 48.2234 ug/mL m-Xylene VB 1.56 7.19717 9.30859 49.0717 1 49.0717 ug/mL o-Xylene BB 1.77 7.00012 9.17936 49.3666 1 49.3666 ug/mL Styrene BB 2.15 7.30662 9.97200 51.2574 1 51.2574 ug/mL Naphthalene BB 4.52 7.47133 10.0333 49.2043 1 49.2043 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 391 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #4 MUFASA219 ver.2 033F0303.D GC/2023/Mufasa/Quarter 2 7/18/2023 10:33 AM 7/19/2023 9:48 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 33 1 3 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 7.17700 7.37492 49.9173 1 49.9173 ug/mL Toluene BB 1.12 6.98833 8.25593 49.1204 1 49.1204 ug/mL Ethylbenzene BV 1.49 7.02079 10.1708 49.1110 1 49.1110 ug/mL p-Xylene VV 1.53 6.75647 9.55526 48.4239 1 48.4239 ug/mL m-Xylene VB 1.56 7.22409 9.47826 49.2550 1 49.2550 ug/mL o-Xylene BB 1.77 7.02699 9.31998 49.5554 1 49.5554 ug/mL Styrene BB 2.15 7.33096 9.69829 51.4271 1 51.4271 ug/mL Naphthalene BB 4.52 7.46658 10.6922 49.1732 1 49.1732 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 392 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA219 ver.2 034F0401.D GC/2023/Mufasa/Quarter 2 7/18/2023 10:51 AM 7/19/2023 9:48 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 34 1 1 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 1.82559 1.82588 12.6969 1 12.6969 ug/mL Toluene BB 1.13 1.72135 2.00676 12.2228 1 12.2228 ug/mL Ethylbenzene BB 1.49 1.76257 2.41002 12.4088 1 12.4088 ug/mL p-Xylene BV 1.53 1.67194 2.19845 12.1551 1 12.1551 ug/mL m-Xylene VB 1.56 1.83610 2.28414 12.5732 1 12.5732 ug/mL o-Xylene BB 1.77 1.73264 2.24000 12.3776 1 12.3776 ug/mL Styrene BB 2.15 1.82527 2.32288 13.0394 1 13.0394 ug/mL Naphthalene BB 4.52 1.90496 2.43571 12.6522 1 12.6522 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 393 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA219 ver.2 034F0402.D GC/2023/Mufasa/Quarter 2 7/18/2023 10:59 AM 7/19/2023 9:48 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 34 1 2 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 1.82894 1.82396 12.7201 1 12.7201 ug/mL Toluene BB 1.13 1.72271 2.00335 12.2324 1 12.2324 ug/mL Ethylbenzene BB 1.49 1.78103 2.37291 12.5376 1 12.5376 ug/mL p-Xylene BV 1.53 1.67672 2.27194 12.1892 1 12.1892 ug/mL m-Xylene VB 1.56 1.84176 2.24318 12.6117 1 12.6117 ug/mL o-Xylene BB 1.77 1.74606 2.18982 12.4718 1 12.4718 ug/mL Styrene BB 2.15 1.81008 2.34109 12.9335 1 12.9335 ug/mL Naphthalene BB 4.52 1.89060 2.56737 12.5579 1 12.5579 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 394 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3 MUFASA219 ver.2 034F0403.D GC/2023/Mufasa/Quarter 2 7/18/2023 11:08 AM 7/19/2023 9:48 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 34 1 3 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 1.82220 1.80979 12.6732 1 12.6732 ug/mL Toluene BB 1.13 1.74182 1.97963 12.3663 1 12.3663 ug/mL Ethylbenzene BB 1.49 1.75970 2.39885 12.3887 1 12.3887 ug/mL p-Xylene BV 1.53 1.67710 2.12207 12.1919 1 12.1919 ug/mL m-Xylene VB 1.56 1.83784 2.27819 12.5851 1 12.5851 ug/mL o-Xylene BB 1.77 1.75153 2.25043 12.5102 1 12.5102 ug/mL Styrene BB 2.15 1.82592 2.20544 13.0440 1 13.0440 ug/mL Naphthalene BB 4.52 1.90011 2.41241 12.6204 1 12.6204 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 395 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #2 MUFASA219 ver.2 035F0501.D GC/2023/Mufasa/Quarter 2 7/18/2023 11:25 AM 7/19/2023 9:48 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 35 1 1 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 0.74109 0.74874 5.15384 1 5.15384 ug/mL Toluene BB 1.13 0.69912 0.79449 5.06168 1 5.06168 ug/mL Ethylbenzene BB 1.49 0.70608 0.95274 5.03449 1 5.03449 ug/mL p-Xylene BV 1.53 0.67035 0.86052 5.01058 1 5.01058 ug/mL m-Xylene VB 1.56 0.74146 0.89128 5.12085 1 5.12085 ug/mL o-Xylene BB 1.78 0.70676 0.86108 5.17363 1 5.17363 ug/mL Styrene BB 2.15 0.71158 0.85440 5.27435 1 5.27435 ug/mL Naphthalene BB 4.53 0.75754 0.98073 5.11757 1 5.11757 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 396 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #2 MUFASA219 ver.2 035F0502.D GC/2023/Mufasa/Quarter 2 7/18/2023 11:34 AM 7/19/2023 9:48 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 35 1 2 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 0.74714 0.75356 5.19594 1 5.19594 ug/mL Toluene BB 1.13 0.70471 0.80058 5.10087 1 5.10087 ug/mL Ethylbenzene BB 1.49 0.71836 0.98167 5.12017 1 5.12017 ug/mL p-Xylene BV 1.53 0.66655 0.85399 4.98346 1 4.98346 ug/mL m-Xylene VB 1.56 0.74695 0.90445 5.15822 1 5.15822 ug/mL o-Xylene BB 1.78 0.69064 0.87575 5.06048 1 5.06048 ug/mL Styrene BB 2.15 0.70620 0.85143 5.23686 1 5.23686 ug/mL Naphthalene BB 4.52 0.76090 0.99588 5.13964 1 5.13964 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 397 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #2 MUFASA219 ver.2 035F0503.D GC/2023/Mufasa/Quarter 2 7/18/2023 11:42 AM 7/19/2023 9:48 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 35 1 3 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 0.74550 0.74763 5.18452 1 5.18452 ug/mL Toluene BB 1.13 0.68494 0.79096 4.96236 1 4.96236 ug/mL Ethylbenzene BB 1.49 0.71985 0.95235 5.13059 1 5.13059 ug/mL p-Xylene BV 1.53 0.67075 0.86450 5.01341 1 5.01341 ug/mL m-Xylene VB 1.56 0.74287 0.88687 5.13045 1 5.13045 ug/mL o-Xylene BB 1.78 0.70425 0.86269 5.15606 1 5.15606 ug/mL Styrene BB 2.15 0.72524 0.83964 5.36960 1 5.36960 ug/mL Naphthalene BB 4.53 0.75589 1.00585 5.10674 1 5.10674 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 398 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #1 MUFASA219 ver.2 036F0601.D GC/2023/Mufasa/Quarter 2 7/18/2023 12:00 PM 7/19/2023 9:48 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 36 1 1 of 8 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 0.38009 0.37919 2.64302 1 2.64302 ug/mL Toluene BB 1.13 0.35082 0.39919 2.62169 1 2.62169 ug/mL Ethylbenzene BB 1.49 0.36285 0.47737 2.63872 1 2.63872 ug/mL p-Xylene BV 1.53 0.33820 0.40983 2.64126 1 2.64126 ug/mL m-Xylene VB 1.56 0.36948 0.43173 2.58837 1 2.58837 ug/mL o-Xylene BB 1.78 0.35233 0.43026 2.68477 1 2.68477 ug/mL Styrene BB 2.15 0.35352 0.39487 2.77787 1 2.77787 ug/mL Naphthalene BB 4.53 0.37540 0.47423 2.60821 1 2.60821 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 399 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #1 MUFASA219 ver.2 036F0602.D GC/2023/Mufasa/Quarter 2 7/18/2023 12:08 PM 7/19/2023 9:48 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 36 1 2 of 8 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 0.38394 0.37411 2.66976 1 2.66976 ug/mL Toluene BB 1.13 0.34899 0.38375 2.60885 1 2.60885 ug/mL Ethylbenzene BB 1.49 0.36974 0.47042 2.68683 1 2.68683 ug/mL p-Xylene BV 1.53 0.33563 0.40611 2.62293 1 2.62293 ug/mL m-Xylene VB 1.56 0.37241 0.44173 2.60831 1 2.60831 ug/mL o-Xylene BB 1.78 0.35175 0.43064 2.68071 1 2.68071 ug/mL Styrene BB 2.16 0.34355 0.40419 2.70832 1 2.70832 ug/mL Naphthalene BB 4.53 0.38140 0.47620 2.64764 1 2.64764 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 400 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #1 MUFASA219 ver.2 036F0603.D GC/2023/Mufasa/Quarter 2 7/18/2023 12:17 PM 7/19/2023 9:48 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Calibration Vial 36 1 3 of 8 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 0.38413 0.37974 2.67112 1 2.67112 ug/mL Toluene BB 1.13 0.36127 0.39429 2.69487 1 2.69487 ug/mL Ethylbenzene BB 1.49 0.35066 0.48213 2.55362 1 2.55362 ug/mL p-Xylene BV 1.53 0.33498 0.42314 2.61832 1 2.61832 ug/mL m-Xylene VB 1.56 0.36962 0.43738 2.58928 1 2.58928 ug/mL o-Xylene BB 1.78 0.34530 0.42361 2.63539 1 2.63539 ug/mL Styrene BB 2.15 0.35944 0.42542 2.81911 1 2.81911 ug/mL Naphthalene BB 4.53 0.37341 0.47168 2.59514 1 2.59514 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 401 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3ss MUFASA219 ver.2 037F0701.D GC/2023/Mufasa/Quarter 2 7/18/2023 1:09 PM 7/19/2023 9:48 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Control Vial 37 1 1 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 4.32101 4.33013 30.0532 1 30.0532 ug/mL Toluene BB 1.12 4.12266 4.80767 29.0451 1 29.0451 ug/mL Ethylbenzene BV 1.49 4.20765 5.79042 29.4754 1 29.4754 ug/mL p-Xylene VV 1.53 4.06953 5.65659 29.2575 1 29.2575 ug/mL m-Xylene VB 1.56 4.34787 5.39955 29.6735 1 29.6735 ug/mL o-Xylene BB 1.77 4.24117 5.38583 29.9929 1 29.9929 ug/mL Styrene BB 2.15 4.35252 5.86875 30.6603 1 30.6603 ug/mL Naphthalene BB 4.52 4.30375 6.00720 28.4041 1 28.4041 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 402 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3ss MUFASA219 ver.2 037F0702.D GC/2023/Mufasa/Quarter 2 7/18/2023 1:17 PM 7/19/2023 9:48 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Control Vial 37 1 2 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 4.34008 4.37512 30.1858 1 30.1858 ug/mL Toluene BB 1.13 4.17223 4.92266 29.3923 1 29.3923 ug/mL Ethylbenzene BB 1.49 4.23468 5.94761 29.6640 1 29.6640 ug/mL p-Xylene BV 1.53 4.09858 5.71728 29.4647 1 29.4647 ug/mL m-Xylene VB 1.56 4.38899 5.64930 29.9535 1 29.9535 ug/mL o-Xylene BB 1.77 4.25940 5.58596 30.1209 1 30.1209 ug/mL Styrene BB 2.15 4.43029 5.96192 31.2026 1 31.2026 ug/mL Naphthalene BB 4.52 4.36530 6.15597 28.8083 1 28.8083 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 403 of 640 ©Mostardi Platt Chromatogram Report Enthalpy Analytical Sample Name Sequence Name Inj Data File File Location Injection Date File Modified Instrument Operator gcstds1971 #3ss MUFASA219 ver.2 037F0703.D GC/2023/Mufasa/Quarter 2 7/18/2023 1:26 PM 7/19/2023 9:48 AM Mufasa Brianna Berry Sample Type Vial Number Injection Volume Injection Acquisition Method Analysis Method Method Modified Printed Control Vial 37 1 3 of 4 MUFASA219.M MUFASA219_BTEXSN.M 7/19/2023 9:47 AM 7/19/2023 10:00 AM FID1A Be n z e n e To l u e n e Et h y l b e n z e n e p- X y l e n e m- X y l e n e o- X y l e n e St y r e n e Na p h t h a l e n e 1 2 3 4 5 5 10 15 20 25 30 35 40 45 50 55 60 Time (min) Re s p o n s e ( p A ) Compound Type RT Area Height Amount DF SampAmt Unit Benzene BB 0.81 4.33953 4.30119 30.1819 1 30.1819 ug/mL Toluene BB 1.13 4.16008 4.91059 29.3072 1 29.3072 ug/mL Ethylbenzene BB 1.49 4.21653 5.92856 29.5373 1 29.5373 ug/mL p-Xylene BV 1.53 4.08234 5.62739 29.3489 1 29.3489 ug/mL m-Xylene VB 1.56 4.37657 5.61348 29.8689 1 29.8689 ug/mL o-Xylene BB 1.77 4.24172 5.55498 29.9967 1 29.9967 ug/mL Styrene BB 2.15 4.40966 5.97800 31.0588 1 31.0588 ug/mL Naphthalene BB 4.52 4.34560 6.05880 28.6789 1 28.6789 ug/mL Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 404 of 640 ©Mostardi Platt This Is The Last Page Of This Report. Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 405 of 640 ©Mostardi Platt Client: Facility: Project Number: Test Location: Test Method:Filter Drying Temp oF: 220 Filterable Analysis Date: Analyst: LNT Sample Date ID# Initial Weight (grams) Final Weight (grams) Run 1 7/18/2023 Source Condition: Mill On M5 Filter 8359 0.46668 0.46851 0.00183 Acetone Wash (M5 Pans) 9285 55 mL 5.02294 5.02294 ≤0.00025 Acetone Blank ≤0.00025 Total Filterable Weight ≤0.00208 Run 2 7/18/2023 Source Condition: Mill On M5 Filter 9203 0.44971 0.44952 ≤0.00015 Acetone Wash (M5 Pans) 9286 60 mL 5.02169 5.02160 ≤0.00025 Acetone Blank ≤0.00025 Total Filterable Weight ≤0.00040 Run 3 7/18/2023 Source Condition: Mill On M5 Filter 8358 0.46487 0.46521 0.00034 Acetone Wash (M5 Pans) 9287 50 mL 5.03946 5.03953 ≤0.00025 Acetone Blank ≤0.00025 Total Filterable Weight ≤0.00059 Acetone Wash (M5 Pans)9284 100 mL 5.02318 5.02269 ≤0.00025 Media M5 Filter Acetone Wash (M5 Pans) Sample Vials (M202) Filterable Particulate Filterable Particulate Filterable Particulate Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility M232904 Rotary Kiln Exhaust (K-1) 5 7/31/2023 0.00008 0.00015 0.00025 0.00025 vol. (ml)Description Net Weight Gain (grams) Reagent Blank Summary 0.00008 RDL/MDL Summary MDL, grams RDL, grams 0.00005 Page 1 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 406 of 640 ©Mostardi Platt Client: Facility: Project Number: Test Location: Test Method:Filter Drying Temp oF: 220 Filterable Analysis Date: Analyst: LNT Sample Date ID# Initial Weight (grams) Final Weight (grams) Run 1 7/19/2023 Source Condition: Mill OFF M5 Filter 9200 0.45448 0.45423 ≤0.00015 Acetone Wash (M5 Pans) 9335 60 mL 4.98312 4.98285 ≤0.00025 Acetone Blank ≤0.00025 Total Filterable Weight ≤0.00040 Run 2 7/19/2023 Source Condition: Mill OFF M5 Filter 9195 0.45985 0.44944 ≤0.00015 Acetone Wash (M5 Pans) 9336 65 mL 4.95412 4.95429 ≤0.00025 Acetone Blank ≤0.00025 Total Filterable Weight ≤0.00040 Run 3 7/19/2023 Source Condition: Mill OFF M5 Filter 9201 0.45392 0.45370 ≤0.00015 Acetone Wash (M5 Pans) 9341 55 mL 4.98508 4.98485 ≤0.00025 Acetone Blank ≤0.00025 Total Filterable Weight ≤0.00040 Acetone Wash (M5 Pans)9284 100 mL 5.02318 5.02269 ≤0.00025 Media M5 Filter Acetone Wash (M5 Pans) Sample Vials (M202) 0.00008 RDL/MDL Summary MDL, grams RDL, grams 0.00005 0.00008 0.00015 0.00025 0.00025 vol. (ml)Description Net Weight Gain (grams) Reagent Blank Summary Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility M232904 Rotary Kiln Exhaust (K-1) 5 7/31/2023 Filterable Particulate Filterable Particulate Filterable Particulate Page 1 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 407 of 640 ©Mostardi Platt Client: Facility: Project Number: Test Location: Test Method:Filter Drying Temp oF: 220 Filterable Analysis Date: Analyst: LNT Sample Date ID# Initial Weight (grams) Final Weight (grams) Run 1 7/18/2023 Source Condition: Normal M5 Filter 9202 0.44991 0.44998 ≤0.00015 Acetone Wash (M5 Pans) 9288 70 mL 5.03876 5.04058 0.00182 Acetone Blank ≤0.00025 Total Filterable Weight ≤0.00197 Run 2 7/18/2023 Source Condition: Normal M5 Filter 9193 0.44967 0.44871 ≤0.00015 Acetone Wash (M5 Pans) 9333 65 mL 4.92147 4.92176 0.00029 Acetone Blank ≤0.00025 Total Filterable Weight ≤0.00044 Run 3 7/18/2023 Source Condition: Normal M5 Filter 9194 0.45053 0.45015 ≤0.00015 Acetone Wash (M5 Pans) 9334 70 mL 5.00441 5.00367 ≤0.00025 Acetone Blank ≤0.00025 Total Filterable Weight ≤0.00040 Acetone Wash (M5 Pans)9284 100 mL 5.02318 5.02269 ≤0.00025 Media M5 Filter Acetone Wash (M5 Pans) Sample Vials (M202) Filterable Particulate Filterable Particulate Filterable Particulate Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility M232904 Clinker Cooler Stack (CC-1) 5 7/31/2023 0.00008 0.00015 0.00025 0.00025 vol. (ml)Description Net Weight Gain (grams) Reagent Blank Summary 0.00008 RDL/MDL Summary MDL, grams RDL, grams 0.00005 Page 1 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 408 of 640 ©Mostardi Platt Client: Facility: Project Number: Test Location: Test Method:Filter Drying Temp oF: 220 Filterable Analysis Date: Analyst:LNT Sample Date ID#Initial Weight (grams) Final Weight (grams) Run 1 7/21/2023 Source Condition:Normal M5 Filter 9180 0.45380 0.45100 ≤0.00015 Acetone Wash (M5 Pans)9283 65 mL 5.02328 5.02297 ≤0.00025 Acetone Blank ≤0.00025 Total Filterable Weight ≤0.00040 Run 2 7/21/2023 Source Condition:Normal M5 Filter 9199 0.45309 0.45307 ≤0.00015 Acetone Wash (M5 Pans)9281 60 mL 5.04109 5.04051 ≤0.00025 Acetone Blank ≤0.00025 Total Filterable Weight ≤0.00040 Run 3 7/21/2023 Source Condition:Normal M5 Filter 9177 0.45574 0.45445 ≤0.00015 Acetone Wash (M5 Pans)9282 70 mL 5.03806 5.03752 ≤0.00025 Acetone Blank ≤0.00025 Total Filterable Weight ≤0.00040 Acetone Wash (M5 Pans)9284 100 mL 5.02318 5.02269 ≤0.00025 Media M5 Filter Acetone Wash (M5 Pans) Sample Vials (M202) 0.00008 RDL/MDL Summary MDL, grams RDL, grams 0.00005 0.00008 0.00015 0.00025 0.00025 vol. (ml)Description Net Weight Gain (grams) Reagent Blank Summary Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility M232904 Primary Crusher Baghouse 5 7/31/2023 Filterable Particulate Filterable Particulate Filterable Particulate Page 1 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 409 of 640 ©Mostardi Platt Client: Facility: Project Number: Test Location: Test Method:Filter Drying Temp oF: 220 Filterable Analysis Date: Analyst: LNT Sample Date ID# Initial Weight (grams) Final Weight (grams) Run 1 7/21/2023 Source Condition: Normal M5 Filter 9178 0.44969 0.45359 0.00390 Acetone Wash (M5 Pans) 9348 70 mL 4.99189 4.99248 0.00059 Acetone Blank ≤0.00025 Total Filterable Weight 0.00449 Run 2 7/21/2023 Source Condition: Normal M5 Filter 9179 0.45080 0.44901 ≤0.00015 Acetone Wash (M5 Pans) 9347 75 mL 4.98604 4.98591 ≤0.00025 Acetone Blank ≤0.00025 Total Filterable Weight ≤0.00040 Run 3 7/21/2023 Source Condition: Normal M5 Filter 9204 0.45286 0.45276 ≤0.00015 Acetone Wash (M5 Pans) 9346 55 mL 5.01498 5.01514 ≤0.00025 Acetone Blank ≤0.00025 Total Filterable Weight ≤0.00040 Acetone Wash (M5 Pans)9284 100 mL 5.02318 5.02269 ≤0.00025 Media M5 Filter Acetone Wash (M5 Pans) Sample Vials (M202) Filterable Particulate Filterable Particulate Filterable Particulate Holcim (US) Inc. Devil's Slide Cement Manufacturing Facility M232904 Transfer Baghouse 5 7/31/2023 0.00008 0.00015 0.00025 0.00025 vol. (ml)Description Net Weight Gain (grams) Reagent Blank Summary 0.00008 RDL/MDL Summary MDL, grams RDL, grams 0.00005 Page 1 AET-014 ISO Template V26 1-16-23.xls Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 410 of 640 ©Mostardi Platt Appendix E - Reference Method Test Data Project No. M232904B Revision 1 Clinker Cooler Stack, Baghouse #211-AF1, and Baghouse #291-BFx Page 411 of 640 ©Mostardi Platt Source Information Division of Air Quality Compliance Demonstration Source Information Company Name Holcim (US) Inc. - Kiln K-1 Company Contact:Clint Badger Contact Phone No.801-829-2122 Source Designation:Kiln K-1 Mill On Test & Review Dates Test Date: 7/18/2023 Review Date: 1/24/2024 Tabs Are Shown Observer: Reviewer:Paul Morris Particulate Emission Limits lbs/MMBtu lbs/hr gr/dscf Emission Rates - "Front Half" lbs/MMBtu lbs/hr gr/dscf 0.5837 0.0004 Test Information Stack_I.D._inches As ft^2 Y Dl H @ Cp Pbar Pq (static)Dn 131.50 94.31 0.9970 1.88 0.84 24.65 -0.5 0.252 Contractor Information Contracting Company: Mostardi Platt Contact: Hal Lee Phone No.: 801-716-2652 Project No.: Circular 10100 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 F factor usedF factors for Coal, Oil, and Gas Anthrocite 2 Lignite Natural Propane Butane COAL OIL GAS Bituminous 2 Fd Fw Fc scf/MMBtu scf/MMBtu scf/MMBtu O2 CO2 lbs/MMBtu Page 1 Summary Division of Air Quality Reference Methods 5 - TSP Compliance Demonstration of Holcim (US) Inc. - Kiln K-1 Testing Results Lab Data - grams collected Test Date 7/18/2023 7/18/2023 7/18/2023 7/18/2023 Lab Data Probe Filter Back Circular Run 1 Run 2 Run 3 Run 4 Run 1 0.00025 0.00183 100.6 As ft^2 94.31 94.31 94.31 Run 2 0.00025 0.00015 100.6 Pbar 24.65 24.65 24.65 Run 3 0.00025 0.00034 100.6 Pq (static)-0.50 -0.50 -0.50 Run 4 Ps 24.61 24.61 24.61 Avg. Ts F 267.58 265.75 280.50 Front Half Emissions Summary CO2 - FCO2 17.20 18.20 17.00 Run 1 Run 2 Run 3 Run 4 Avg. O2 10.90 11.10 11.20 gr./dscf 0.0008 0.0002 0.0002 0.0004 N2+C 71.90 70.70 71.80 lbs/hr 1.1787 0.2319 0.3406 0.5837 Md 31.19 31.36 31.17 lbs/MMBtu Ms 29.80 29.78 29.53 lb/ton 0.012 0.002 0.003 0.006 Y 1.00 1.00 1.00 Cp 0.84 0.84 0.84 Total Emissions Summary w/back half condensable Vm cf 51.52 49.75 48.93 Run 1 Run 2 Run 3 Run 4 Avg. Vlc 101.90 110.00 115.10 gr./dscf 0.0008 0.0002 0.0002 0.0004 AVG. Tm F 89.67 101.17 100.67 lbs/hr 1.1787 0.2319 0.3406 0.5837 Vm std 40.86 38.64 38.03 lbs/MMBtu Vw std 4.80 5.18 5.42 Bws 0.11 0.12 0.12 S Bws 1.00 1.00 1.00 Avg. Sqrt Dlp 0.81 0.79 0.79 Vs 57.89 56.69 57.12 F factor used scfm wet 195555.29 191991.98 189602.35 acfm 327574.63 320795.36 323241.21 Qsd dscfh 10500617.94 10158327.16 9957587.88 # Sample Points 12.00 12.00 12.00 Dn 0.252 0.252 0.252 An 3.46E-04 3.46E-04 3.46E-04 Start Time 0:00 0:00 0:00 End Time 0:00 0:00 0:00 Total Test time 60.00 60.00 60.00 Time @ point 5.00 5.00 5.00 Clinker ton/hr 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Points Run 1 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 2 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 3 PxP Isokinetic O2 CO2 lbs/MMBtu 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 Sample Points Run 4 PxP Isokinetic Page 1 Run 1 Holcim (US) Inc. - Kiln K-1 Flow & Moisture Test Date 7/18/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 94.31 24.65 -0.50 24.61 268 17.20 10.90 71.90 31.19 29.80 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 3.3577 0.9970 0.84 51.520 101.90 89.67 40.858 4.796 0.1051 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.809 57.89 195,555 327,575 1.05E+07 12 0.252 60 5.00 1.849167 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 19.135 0.65 1.83 267 82 82 Wt. (Final) Wt. (Initial) lc 2 23.350 0.67 1.89 268 82 82 728.60 657.90 70.7 3 27.800 0.71 2.00 268 84 84 760.10 748.80 11.3 4 32.263 0.65 1.83 268 88 88 675.30 670.00 5.3 5 36.440 0.70 1.98 267 89 89 899.30 884.70 14.6 6 40.850 0.72 2.03 267 91 91 0.0 7 44.991 0.65 1.83 267 92 92 8 49.550 0.67 1.89 267 93 93 Isokinetics 106.0 9 53.960 0.63 1.78 267 93 93 Test Date 7/18/2023 10 58.212 0.56 1.58 268 94 94 Start Time enter 11 62.556 0.60 1.69 268 94 94 End Time 12 66.890 0.66 1.86 269 94 94 Run 1 13 70.655 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 2 Holcim (US) Inc. - Kiln K-1 Flow & Moisture Test Date 7/18/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 94.31 24.65 -0.50 24.61 266 18.20 11.10 70.70 31.36 29.78 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 3.2563 0.9970 0.84 49.751 110.00 101 38.640 5.178 0.1182 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.793 56.69 191,992 320,795 1.02E+07 12 0.252 60 5.00 1.80 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 84.307 0.54 1.52 264.0 97.0 97.0 Wt. (Final) Wt. (Initial) lc 2 88.120 0.52 1.66 265.0 97.0 97.0 719.30 643.20 76.1 3 92.080 0.68 1.92 267.0 98.0 98.0 760.50 747.60 12.9 4 96.340 0.62 1.75 263.0 99.0 99.0 659.30 653.60 5.7 5 100.420 0.66 1.86 266.0 100.0 100.0 912.30 897.00 15.3 6 104.650 0.65 1.83 266.0 101.0 101.0 0.0 7 108.840 0.69 1.95 264.0 102.0 102.0 8 113.130 0.72 2.03 265.0 102.0 102.0 Isokinetics 103.6 9 117.600 0.67 1.89 267.0 103.0 103.0 Test Date 7/18/2023 10 121.860 0.56 1.58 268.0 104.0 104.0 Start Time 11 125.740 0.60 1.69 267.0 105.0 105.0 End Time 12 129.780 0.66 1.86 267.0 106.0 106.0 Run 2 13 134.058 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 3 Holcim (US) Inc. - Kiln K-1 Flow & Moisture Test Date 7/18/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 94.31 24.65 -0.50 24.61 281 17.00 11.20 71.80 31.17 29.53 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 4.1484 0.9970 0.84 48.929 115.10 101 38.030 5.418 0.1247 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.788 57.12 189,602 323,241 9.96E+06 12 0.252 60 5.00 1.75 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 538.494 0.59 1.54 268.0 102.0 102.0 Wt. (Final) Wt. (Initial) lc 2 542.423 0.59 1.66 270.0 103.0 103.0 821.7 738.6 83.1 3 546.478 0.64 1.80 278.0 103.0 103.0 773.2 760.1 13.1 4 550.552 0.54 1.52 283.0 100.0 100.0 679.3 675.3 4.0 5 554.319 0.57 1.60 282.0 99.0 99.0 914.2 899.3 14.9 6 558.234 0.62 1.74 283.0 99.0 99.0 0.0 7 562.223 0.63 1.77 282.0 99.0 99.0 8 566.121 0.63 1.88 282.0 99.0 99.0 Isokinetics 104.0 9 570.343 0.69 1.94 283.0 100.0 100.0 Test Date 7/18/2023 10 574.845 0.62 1.74 284.0 101.0 101.0 Start Time 11 578.917 0.66 1.85 285.0 101.0 101.0 End Time 12 583.142 0.68 1.91 286.0 102.0 102.0 Run 3 13 587.423 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Source Information Division of Air Quality Compliance Demonstration Source Information Company Name Holcim (US) Inc. - Kiln (Mill Off) Company Contact:Clint Badger Contact Phone No.801-821-6037 Source Designation:Kiln (Mill Off) Test & Review Dates Test Date: 7/19/2023 Review Date: 1/24/2024 Tabs Are Shown Observer: Reviewer:Paul Morris Particulate Emission Limits lbs/MMBtu lbs/hr gr/dscf - - - Emission Rates - "Front Half" lbs/MMBtu lbs/hr gr/dscf 0.2365 0.0002 Test Information Stack_I.D._inches As ft^2 Y Dl H @ Cp Pbar Pq (static)Dn 131.50 94.31 0.9970 1.88 0.84 24.92 -0.5 0.252 Contractor Information Contracting Company: Mostardi Platt Contact: Richard J Sollars Phone No.: 630-993-2100 Project No.: Circular 10100 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 F factor usedF factors for Coal, Oil, and Gas Anthrocite 2 Lignite Natural Propane Butane COAL OIL GAS Bituminous 2 Fd Fw Fc scf/MMBtu scf/MMBtu scf/MMBtu O2 CO2 lbs/MMBtu Page 1 Summary Division of Air Quality Reference Methods 5 - TSP Compliance Demonstration of Holcim (US) Inc. - Kiln (Mill Off) Testing Results Lab Data - grams collected Test Date 7/19/2023 7/19/2023 7/19/2023 7/19/2023 Lab Data Probe Filter Back ton/hr Circular Run 1 Run 2 Run 3 Run 4 Run 1 0.00025 0.00015 100.6 As ft^2 94.31 94.31 94.31 Run 2 0.00025 0.00015 100.6 Pbar 24.92 24.92 24.92 Run 3 0.00025 0.00015 100.6 Pq (static)-0.50 -0.50 -0.50 Run 4 Ps 24.88 24.88 24.88 Avg. Ts F 339.58 352.67 368.00 Front Half Emissions Summary CO2 - FCO2 18.70 18.70 19.90 Run 1 Run 2 Run 3 Run 4 Avg. O2 10.40 10.40 10.10 gr./dscf 0.0002 0.0002 0.0002 0.0002 N2+C 70.90 70.90 70.00 lbs/hr 0.2375 0.2361 0.2358 0.2365 Md 31.41 31.41 31.59 lbs/MMBtu Ms 30.09 30.18 30.35 lb/ton 0.002 0.002 0.002 0.002 Y 1.00 1.00 1.00 Cp 0.84 0.84 0.84 Total Emissions Summary w/back half condensable Vm cf 45.80 46.43 45.37 Run 1 Run 2 Run 3 Run 4 Avg. Vlc 83.60 77.70 76.40 gr./dscf 0.0002 0.0002 0.0002 0.0002 AVG. Tm F 100.42 105.58 98.08 lbs/hr 0.2375 0.2361 0.2358 0.2365 Vm std 35.98 36.15 35.79 lbs/MMBtu Vw std 3.94 3.66 3.60 Bws 0.10 0.09 0.09 S Bws 1.00 1.00 1.00 Avg. Sqrt Dlp 0.78 0.78 0.78 Vs 57.64 58.07 58.48 F factor used scfm wet 179127.63 177560.92 175505.97 acfm 326171.58 328609.14 330934.49 Qsd dscfh 9688006.28 9674761.93 9568991.13 # Sample Points 12.00 12.00 12.00 Dn 0.252 0.252 0.252 An 3.46E-04 3.46E-04 3.46E-04 Start Time 0:00 0:00 0:00 End Time 0:00 0:00 0:00 Total Test time 60.00 60.00 60.00 Time @ point 5.00 5.00 5.00 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Points Run 1 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 2 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 3 PxP Isokinetic O2 CO2 lbs/MMBtu 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 Sample Points Run 4 PxP Isokinetic Page 1 Run 1 Holcim (US) Inc. - Kiln (Mill Off)Flow & Moisture Test Date 7/19/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 94.31 24.92 -0.50 24.88 340 18.70 10.40 70.90 31.41 30.09 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 9.8126 0.9970 0.84 45.796 83.60 100.42 35.977 3.935 0.0986 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.777 57.64 179,128 326,172 9.69E+06 12 0.252 60 5.00 1.535833 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 91.328 0.55 1.39 334 98 98 Wt. (Final) Wt. (Initial) lc 2 94.960 0.61 1.54 336 98 98 736.8 674.2 62.6 3 98.750 0.66 1.67 337 98 98 712.9 703.6 9.3 4 102.724 0.57 1.44 339 99 99 636.7 634.1 2.6 5 106.420 0.63 1.52 339 99 99 880.4 871.3 9.1 6 110.280 0.66 1.67 340 100 100 0.0 7 114.246 0.52 1.31 340 101 101 8 117.780 0.60 1.52 341 101 101 Isokinetics 101.2 9 121.600 0.64 1.62 342 102 102 Test Date 7/19/2023 10 125.480 0.57 1.44 342 103 103 Start Time enter 11 129.200 0.56 1.59 342 103 103 End Time 12 133.050 0.68 1.72 343 103 103 Run 1 13 137.124 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 2 Holcim (US) Inc. - Kiln (Mill Off)Flow & Moisture Test Date 7/19/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 94.31 24.92 -0.50 24.88 353 18.70 10.40 70.90 31.41 30.18 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 11.6813 0.9970 0.84 46.430 77.70 106 36.147 3.657 0.0919 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.777 58.07 177,561 328,609 9.67E+06 12 0.252 60 5.00 1.59 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 37.692 0.56 1.46 345.0 101.0 101.0 Wt. (Final) Wt. (Initial) lc 2 41.310 0.60 1.56 346.0 102.0 102.0 802.60 736.80 65.8 3 45.140 0.67 1.74 347.0 102.0 102.0 714.00 712.90 1.1 4 49.189 0.54 1.41 348.0 103.0 103.0 638.60 636.70 1.9 5 52.840 0.62 1.61 350.0 103.0 103.0 889.30 880.40 8.9 6 56.750 0.63 1.77 352.0 104.0 104.0 0.0 7 60.842 0.54 1.41 354.0 106.0 106.0 8 64.520 0.62 1.61 355.0 108.0 108.0 Isokinetics 101.8 9 68.480 0.65 1.69 357.0 108.0 108.0 Test Date 7/19/2023 10 72.428 0.55 1.43 358.0 109.0 109.0 Start Time 11 76.130 0.63 1.64 359.0 110.0 110.0 End Time 12 80.100 0.65 1.69 361.0 111.0 111.0 Run 2 13 84.122 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 3 Holcim (US) Inc. - Kiln (Mill Off)Flow & Moisture Test Date 7/19/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 94.31 24.92 -0.50 24.88 368 19.90 10.10 70.00 31.59 30.35 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 14.2200 0.9970 0.84 45.372 76.40 98 35.794 3.596 0.0913 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.778 58.48 175,506 330,934 9.57E+06 12 0.252 60 5.00 1.55 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 86.012 0.53 1.38 364.0 102.0 102.0 Wt. (Final) Wt. (Initial) lc 2 86.690 0.59 1.54 365.0 100.0 100.0 804.9 742.1 62.8 3 93.370 0.64 1.67 365.0 99.0 99.0 718.0 714.0 4.0 4 97.284 0.55 1.43 367.0 98.0 98.0 639.6 638.6 1.0 5 100.900 0.62 1.61 368.0 97.0 97.0 897.9 889.3 8.6 6 104.710 0.65 1.69 368.0 97.0 97.0 0.0 7 108.624 0.54 1.10 368.0 97.0 97.0 8 112.210 0.63 1.64 370.0 97.0 97.0 Isokinetics 101.9 9 116.050 0.67 1.74 370.0 97.0 97.0 Test Date 7/19/2023 10 119.975 0.55 1.43 370.0 97.0 97.0 Start Time 11 123.670 0.64 1.67 370.0 98.0 98.0 End Time 12 127.420 0.66 1.72 371.0 98.0 98.0 Run 3 13 131.384 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Source Information Division of Air Quality Compliance Demonstration Source Information Company Name Holcim (US) Inc. - Kiln K-1 Company Contact:Clint Badger Contact Phone No.801-829-2122 Source Designation:Kiln K-1 Mill On Test & Review Dates Test Date: 7/18/2023 Review Date: 1/29/2024 Tabs Are Shown Observer: Reviewer:Paul Morris Particulate Emission Limits lbs/MMBtu lbs/hr gr/dscf Emission Rates - "Front Half" lbs/MMBtu lbs/hr gr/dscf 0.0266 0.0189 Test Information Stack_I.D._inches As ft^2 Y Dl H @ Cp Pbar Pq (static)Dn 131.50 94.31 1.0000 1.703 0.84 24.65 -0.5 0.248 Contractor Information Contracting Company: Mostardi Platt Contact: Hal Lee Phone No.: 801-716-2652 Project No.: Circular 10100 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 F factor usedF factors for Coal, Oil, and Gas Anthrocite 2 Lignite Natural Propane Butane COAL OIL GAS Bituminous 2 Fd Fw Fc scf/MMBtu scf/MMBtu scf/MMBtu O2 CO2 lbs/MMBtu Page 1 Summary Division of Air Quality Reference Methods 5 - TSP Compliance Demonstration of Holcim (US) Inc. - Kiln K-1 Testing Results Lab Data - picograms collected Test Date 7/18/2023 7/18/2023 7/18/2023 7/18/2023 Lab Data Catch TEQ Circular Run 1 Run 2 Run 3 Run 4 Run 1 As ft^2 94.31 94.31 94.31 94.31 Run 2 39.92 4.331669 Pbar 24.65 24.65 24.65 24.96 Run 3 57.88 3.909324 Pq (static)-0.50 -0.50 -0.50 -0.50 Run 4 68.33 3.722727 Ps 24.61 24.61 24.61 24.92 Avg. Ts F 270.28 278.78 275.78 282.69 PCDD/PCDF Emissions CO2 - FCO2 17.60 18.20 17.00 17.70 Run 1 Run 2 Run 3 Run 4 Avg. O2 10.60 11.10 11.20 10.90 ng/dscm 0.01 0.02 0.02 0.02 N2+C 71.80 70.70 71.80 71.40 ng/dscm 7% O2 0.0193 0.0282 0.0324 0.0266 Md 31.24 31.36 31.17 31.27 Ms 29.79 30.42 29.74 29.86 *Run I has been exluded from the averages due to low inlet temperature. Y 1.00 1.00 1.00 1.00 Cp 0.84 0.84 0.84 0.84 PCDD/PCDF Emissions TEQ Vm cf 130.13 131.97 132.03 129.40 Run 1 Run 2 Run 3 Run 4 Avg. Vlc 272.70 166.20 268.80 261.00 ng/dscm TEQ 0.001 0.001 0.001 0.001 AVG. Tm F 87.25 96.75 96.61 92.64 ng/dscm TEQ 7% O2 0.002 0.002 0.002 0.002 Vm std 104.11 103.79 103.86 103.48 lbs/MMBtu Vw std 12.84 7.82 12.65 12.29 Bws 0.11 0.07 0.11 0.11 S Bws 1.00 1.00 1.00 1.00 Avg. Sqrt Dlp 0.81 0.81 0.81 0.74 Vs 57.93 57.92 58.35 53.36 F factor used scfm wet 194964.96 192687.95 194921.25 178821.66 acfm 327795.21 327737.64 330189.91 301962.17 Qsd dscfh 10413977.35 10750905.74 10425207.26 9590679.44 # Sample Points 36.00 36.00 36.00 36.00 Dn 0.248 0.248 0.248 0.248 An 3.35E-04 3.35E-04 3.35E-04 3.35E-04 Start Time 0:00 0:00 0:00 End Time 0:00 0:00 0:00 Total Test time 180.00 180.00 180.00 180.00 Time @ point 5.00 5.00 5.00 5.00 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Points Run 1 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 2 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 3 PxP Isokinetic O2 CO2 lbs/MMBtu 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 Sample Points Run 4 PxP Isokinetic Page 1 Run 2 Holcim (US) Inc. - Kiln K-1 Flow & Moisture Test Date 7/18/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 94.31 24.65 -0.50 24.61 279 18.20 11.10 70.70 31.36 30.42 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 4.0349 1.0000 0.84 131.969 166.20 97 103.785 7.823 0.0701 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.812 57.92 192,688 327,738 1.08E+07 36 0.248 180 5.00 2.33 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 12.815 0.60 2.12 278.0 96.0 96.0 Wt. (Final) Wt. (Initial) lc 2 16.365 0.60 2.12 278.0 96.0 96.0 641.20 515.60 125.6 3 19.920 0.60 2.12 278.0 96.0 96.0 704.50 699.80 4.7 4 23.910 0.66 2.33 275.0 96.0 96.0 725.90 723.30 2.6 5 27.040 0.66 2.33 276.0 96.0 96.0 650.60 647.30 3.3 6 30.870 0.66 2.33 277.0 96.0 96.0 915.0 885.0 30.0 7 34.310 0.73 2.58 277.0 96.0 96.0 8 38.180 0.73 2.58 276.0 96.0 96.0 Isokinetics 90.5 9 41.990 0.73 2.58 275.0 96.0 96.0 Test Date 7/18/2023 10 45.895 0.61 2.15 280.0 96.0 96.0 Start Time 11 49.460 0.61 2.15 280.0 96.0 96.0 End Time 12 53.030 0.61 2.15 280.0 96.0 96.0 Run 2 13 56.610 0.67 2.37 281.0 96.0 96.0 14 60.110 0.67 2.37 281.0 96.0 96.0 15 63.940 0.67 2.37 281.0 96.0 96.0 16 67.610 0.72 2.54 279.0 96.0 96.0 17 71.380 0.72 2.54 279.0 96.0 96.0 18 75.140 0.72 2.54 278.0 96.0 96.0 19 78.983 0.59 2.08 280.0 96.0 96.0 20 82.540 0.59 2.08 280.0 96.0 96.0 21 85.980 0.59 2.08 280.0 96.0 96.0 22 89.450 0.65 2.30 281.0 96.0 96.0 23 93.040 0.65 2.30 281.0 96.0 96.0 24 97.100 0.65 2.30 281.0 96.0 96.0 25 100.450 0.70 2.47 279.0 96.0 96.0 26 104.120 0.70 2.47 279.0 96.0 96.0 27 107.910 0.70 2.47 278.0 96.0 96.0 28 111.578 0.62 2.19 276.0 98.0 98.0 29 115.210 0.62 2.19 276.0 98.0 98.0 30 118.740 0.62 2.19 277.0 98.0 98.0 31 122.410 0.66 2.33 278.0 99.0 99.0 32 125.990 0.66 2.33 278.0 99.0 99.0 33 129.660 0.66 2.33 280.0 99.0 99.0 34 133.340 0.71 2.51 280.0 100.0 100.0 35 137.220 0.71 2.51 281.0 100.0 100.0 36 140.970 0.71 2.51 282.0 100.0 100.0 37 144.784 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 3 Holcim (US) Inc. - Kiln K-1 Flow & Moisture Test Date 7/18/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 94.31 24.65 -0.50 24.61 276 17.00 11.20 71.80 31.17 29.74 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 3.8434 1.0000 0.84 132.029 268.80 97 103.856 12.652 0.1086 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.810 58.35 194,921 330,190 1.04E+07 36 0.248 180 5.00 2.32 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 45.625 0.60 2.12 270.0 98.0 98.0 Wt. (Final) Wt. (Initial) lc 2 49.240 0.60 2.12 270.0 98.0 98.0 636.3 414.9 221.4 3 52.770 0.60 2.12 271.0 98.0 98.0 719.9 704.6 15.3 4 56.250 0.65 2.30 271.0 97.0 97.0 728.2 726.3 1.9 5 59.950 0.65 2.30 277.0 97.0 97.0 651.9 649.3 2.6 6 63.550 0.65 2.30 277.0 97.0 97.0 906.8 879.2 27.6 7 67.130 0.70 2.47 278.0 97.0 97.0 8 70.970 0.70 2.47 278.0 97.0 97.0 Isokinetics 93.4 9 74.640 0.70 2.47 278.0 97.0 97.0 Test Date 7/18/2023 10 78.642 0.62 2.19 274.0 97.0 97.0 Start Time 11 82.220 0.62 2.19 274.0 97.0 97.0 End Time 12 85.910 0.62 2.19 274.0 97.0 97.0 Run 3 13 89.450 0.66 2.33 274.0 97.0 97.0 14 93.030 0.66 2.33 275.0 97.0 97.0 15 96.740 0.66 2.33 275.0 97.0 97.0 16 100.340 0.71 2.51 275.0 97.0 97.0 17 104.170 0.71 2.51 274.0 97.0 97.0 18 107.980 0.71 2.51 274.0 97.0 97.0 19 111.875 0.61 2.15 277.0 97.0 97.0 20 115.470 0.61 2.15 277.0 97.0 97.0 21 118.950 0.61 2.15 277.0 97.0 97.0 22 122.530 0.67 2.37 274.0 97.0 97.0 23 126.220 0.67 2.37 275.0 97.0 97.0 24 129.970 0.67 2.37 275.0 97.0 97.0 25 133.650 0.72 2.54 275.0 97.0 97.0 26 137.450 0.72 2.54 275.0 97.0 97.0 27 141.310 0.72 2.54 277.0 97.0 97.0 28 145.030 0.59 2.08 277.0 96.0 96.0 29 148.560 0.59 2.08 277.0 96.0 96.0 30 151.980 0.59 2.08 278.0 95.0 95.0 31 155.470 0.65 2.30 278.0 95.0 95.0 32 159.050 0.65 2.30 277.0 95.0 95.0 33 162.800 0.65 2.30 278.0 95.0 95.0 34 166.410 0.71 2.51 281.0 95.0 95.0 35 170.100 0.71 2.51 280.0 95.0 95.0 36 173.870 0.71 2.51 281.0 94.0 94.0 37 177.654 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 4 Holcim (US) Inc. - Kiln K-1 Flow & Moisture Test Date 7/18/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 94.31 24.96 -0.50 24.92 283 17.70 10.90 71.40 31.27 29.86 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 4.2432 1.0000 0.84 129.395 261.00 93 103.480 12.285 0.1061 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.744 53.36 178,822 301,962 9.59E+06 36 0.248 180 5.00 1.28 TRUE Mv@ Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 11.259 0.59 1.36 275.0 90.0 90.0 Wt. (Final) Wt. (Initial) lc 3.731 2 14.990 0.59 1.36 275.0 90.0 90.0 760.4 519.1 241.3 3.750 3 18.740 0.59 1.36 277.0 90.0 90.0 662.4 661.2 1.2 3.640 4 22.380 0.56 1.29 277.0 90.0 90.0 691.2 689.5 1.7 3.600 5 25.980 0.56 1.29 277.0 91.0 91.0 655.5 649.8 5.7 3.630 6 29.610 0.56 1.29 278.0 91.0 91.0 895.0 883.9 11.1 3.620 7 33.230 0.52 1.20 278.0 91.0 91.0 3.490 8 36.720 0.52 1.20 280.0 91.0 91.0 Isokinetics 101.2 3.490 9 40.210 0.52 1.20 280.0 91.0 91.0 Test Date 7/18/2023 3.513 10 43.723 0.61 1.40 280.0 92.0 92.0 Start Time enter 3.897 11 47.620 0.61 1.40 281.0 92.0 92.0 End Time enter 3.830 12 51.450 0.61 1.40 281.0 92.0 92.0 3.570 13 55.020 0.55 1.27 281.0 92.0 92.0 3.650 14 58.670 0.55 1.27 282.0 92.0 92.0 3.580 15 62.250 0.55 1.27 283.0 92.0 92.0 3.450 16 65.700 0.50 1.15 283.0 92.0 92.0 3.550 17 69.250 0.50 1.15 285.0 92.0 92.0 3.410 18 72.660 0.50 1.15 285.0 92.0 92.0 3.306 19 75.966 0.61 1.40 284.0 94.0 94.0 3.904 20 79.870 0.61 1.40 284.0 94.0 94.0 3.780 21 83.650 0.61 1.40 284.0 94.0 94.0 3.690 22 87.340 0.56 1.29 284.0 94.0 94.0 3.630 23 90.970 0.56 1.29 284.0 94.0 94.0 3.590 24 94.560 0.56 1.29 284.0 94.0 94.0 3.600 25 98.160 0.51 1.17 284.0 94.0 94.0 3.490 26 101.650 0.51 1.17 284.0 94.0 94.0 3.400 27 105.050 0.51 1.17 284.0 94.0 94.0 3.464 28 108.514 0.62 1.49 287.0 94.0 94.0 3.896 29 112.410 0.62 1.49 287.0 94.0 94.0 3.710 30 116.120 0.62 1.49 287.0 94.0 94.0 3.830 31 119.950 0.54 1.24 287.0 94.0 94.0 3.560 32 123.510 0.54 1..24 287.0 94.0 94.0 3.480 33 126.990 0.54 1.24 287.0 94.0 94.0 3.560 34 130.550 0.48 1.10 287.0 94.0 94.0 3.430 35 133.980 0.48 1.10 287.0 94.0 94.0 3.370 36 137.350 0.48 1.10 287.0 94.0 94.0 3.304 37 140.654 38 39 40 41 42 43 44 45 46 47 48 Page 1 Source Information Division of Air Quality Compliance Demonstration Source Information Company Name Holcim (US) Inc. - Kiln K-1 Company Contact:Clint Badger Contact Phone No.801-829-2122 Source Designation:Kiln K-1 Mill Off Test & Review Dates Test Date: 7/19/2023 Review Date: 1/30/2029 Tabs Are Shown Observer: Reviewer:Paul Morris Particulate Emission Limits lbs/MMBtu lbs/hr gr/dscf Emission Rates - "Front Half" lbs/MMBtu lbs/hr gr/dscf 0.2734 0.2106 Test Information Stack_I.D._inches As ft^2 Y Dl H @ Cp Pbar Pq (static)Dn 131.50 94.31 1.0000 1.703 0.84 24.92 -0.5 0.276 Contractor Information Contracting Company: Mostardi Platt Contact: Hal Lee Phone No.: 801-716-2652 Project No.: Circular 10100 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 F factor usedF factors for Coal, Oil, and Gas Anthrocite 2 Lignite Natural Propane Butane COAL OIL GAS Bituminous 2 Fd Fw Fc scf/MMBtu scf/MMBtu scf/MMBtu O2 CO2 lbs/MMBtu Page 1 Summary Division of Air Quality Reference Methods 5 - TSP Compliance Demonstration of Holcim (US) Inc. - Kiln K-1 Testing Results Lab Data - picograms collected Test Date 7/19/2023 7/19/2023 7/19/2023 7/19/2023 Lab Data Catch TEQ Circular Run 1 Run 2 Run 3 Run 4 Run 1 705.64 4.433349 As ft^2 94.31 94.31 94.31 Run 2 1028.51 4.397377 Pbar 24.92 24.92 25.05 Run 3 600.82 6.822738 Pq (static)-0.50 -0.50 -0.50 Run 4 Ps 24.88 24.88 25.01 Avg. Ts F 346.33 368.94 364.47 PCDD/PCDF Emissions CO2 - FCO2 18.70 19.90 19.10 Run 1 Run 2 Run 3 Run 4 Avg. O2 10.40 10.10 10.10 ng/dscm 0.1902 0.2793 0.1623 0.2106 N2+C 70.90 70.00 70.80 ng/dscm 7% O2 0.2518 0.3595 0.2089 0.2734 Md 31.41 31.59 31.46 Ms 30.23 30.34 30.26 Y 1.00 1.00 1.00 Cp 0.84 0.84 0.84 PCDD/PCDF Emissions TEQ Vm cf 164.69 164.53 162.34 Run 1 Run 2 Run 3 Run 4 Avg. Vlc 267.70 278.20 270.80 ng/dscm TEQ 0.001 0.001 0.002 0.0014 AVG. Tm F 95.86 99.58 92.00 ng/dscm TEQ 7% O2 0.0016 0.0015 0.0024 0.0018 Vm std 131.02 130.02 130.73 Vw std 12.60 13.09 12.75 Bws 0.09 0.09 0.09 S Bws 1.00 1.00 1.00 Avg. Sqrt Dlp 0.78 0.78 0.78 Vs 57.99 58.73 58.42 F factor used scfm wet 178722.45 176065.30 176980.52 acfm 328181.07 332367.84 330566.08 Qsd dscfh 9782518.12 9597347.12 9675435.28 # Sample Points 36.00 36.00 36.00 Dn 0.276 0.276 0.276 An 4.15E-04 4.15E-04 4.15E-04 Start Time 0:00 0:00 0:00 End Time 0:00 0:00 0:00 Total Test time 180.00 180.00 180.00 Time @ point 5.00 5.00 5.00 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Points Run 1 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 2 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 3 PxP Isokinetic O2 CO2 lbs/MMBtu 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 Sample Points Run 4 PxP Isokinetic Page 1 Run 1 Holcim (US) Inc. - Kiln K-1 Flow & Moisture Test Date 7/19/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 94.31 24.92 -0.50 24.88 346 18.70 10.40 70.90 31.41 30.23 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 10.7443 1.0000 0.84 164.690 267.70 95.86 131.019 12.601 0.0877 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.780 57.99 178,722 328,181 9.78E+06 36 0.276 180 5.00 2.023333 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 79.241 0.55 1.83 330 94 94 Wt. (Final) Wt. (Initial) lc 2 83.610 0.55 1.83 330 94 94 746.70 517.20 229.5 3 87.940 0.55 1.83 332 96 96 667.10 666.30 0.8 4 92.240 0.61 2.03 335 96 96 706.10 704.80 1.3 5 96.830 0.61 2.03 334 96 96 656.80 648.90 7.9 6 101.270 0.61 2.03 334 96 96 906.0 877.8 28.2 7 105.840 0.66 2.19 335 97 97 8 110.510 0.66 2.19 335 97 97 Isokinetics 101.4 9 115.190 0.66 2.19 336 97 97 Test Date 7/19/2023 10 119.924 0.56 1.86 331 95 95 Start Time enter 11 124.410 0.56 1.86 331 95 95 End Time 12 128.930 0.56 1.86 333 94 94 Run 1 13 133.400 0.60 1.99 333 94 94 14 137.910 0.60 1.99 334 94 94 15 142.420 0.60 1.99 334 94 94 16 147.020 0.67 2.23 336 94 94 17 151.920 0.67 2.23 337 94 94 18 156.720 0.67 2.23 338 94 94 19 161.531 0.57 1.89 347 96 96 20 166.020 0.57 1.89 350 96 96 21 170.530 0.57 1.89 352 96 96 22 174.940 0.62 2.06 353 96 96 23 179.570 0.62 2.06 354 96 96 24 184.170 0.62 2.06 355 96 96 25 188.750 0.65 2.16 356 97 97 26 193.540 0.65 2.16 359 97 97 27 198.220 0.65 2.16 359 97 97 28 202.974 0.56 1.86 360 97 97 29 207.410 0.56 1.86 361 97 97 30 211.820 0.56 1.86 363 97 97 31 216.100 0.60 1.99 363 97 97 32 220.690 0.60 1.99 365 97 97 33 225.240 0.60 1.99 365 97 97 34 229.710 0.66 2.19 366 97 97 35 234.500 0.66 2.19 366 97 97 36 239.230 0.66 2.19 366 97 97 37 243.931 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 2 Holcim (US) Inc. - Kiln K-1 Flow & Moisture Test Date 7/19/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 94.31 24.92 -0.50 24.88 369 19.90 10.10 70.00 31.59 30.34 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 14.3896 1.0000 0.84 164.531 278.20 100 130.023 13.095 0.0915 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.781 58.73 176,065 332,368 9.60E+06 36 0.276 180 5.00 2.03 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 44.567 0.57 1.89 365.0 96.0 96.0 Wt. (Final) Wt. (Initial) lc 2 48.990 0.57 1.89 366.0 96.0 96.0 634.80 416.60 218.2 3 53.410 0.57 1.89 366.0 96.0 96.0 715.80 714.70 1.1 4 57.840 0.61 2.03 367.0 96.0 96.0 721.60 720.00 1.6 5 62.340 0.61 2.03 367.0 96.0 96.0 651.80 648.60 3.2 6 66.890 0.61 2.03 368.0 96.0 96.0 917.9 863.8 54.1 7 71.390 0.66 2.19 368.0 96.0 96.0 8 76.120 0.66 2.19 368.0 96.0 96.0 Isokinetics 102.6 9 80.870 0.66 2.19 367.0 96.0 96.0 Test Date 7/19/2023 10 85.584 0.56 1.86 367.0 99.0 99.0 Start Time 11 89.980 0.56 1.86 367.0 99.0 99.0 End Time 12 94.540 0.56 1.86 368.0 99.0 99.0 Run 2 13 98.930 0.61 2.03 368.0 99.0 99.0 14 103.340 0.61 2.03 368.0 100.0 100.0 15 107.970 0.61 2.03 369.0 100.0 100.0 16 112.560 0.65 2.16 369.0 100.0 100.0 17 117.310 0.65 2.16 369.0 101.0 101.0 18 121.970 0.65 2.16 369.0 101.0 101.0 19 126.657 0.55 1.83 365.0 101.0 101.0 20 131.180 0.55 1.83 366.0 101.0 101.0 21 135.430 0.55 1.83 366.0 102.0 102.0 22 139.870 0.60 1.99 367.0 102.0 102.0 23 144.390 0.60 1.99 367.0 103.0 103.0 24 148.950 0.60 1.99 368.0 103.0 103.0 25 153.490 0.67 2.23 368.0 103.0 103.0 26 158.380 0.67 2.23 367.0 105.0 105.0 27 163.190 0.67 2.23 371.0 105.0 105.0 28 167.959 0.57 1.89 371.0 99.0 99.0 29 172.420 0.57 1.89 371.0 99.0 99.0 30 176.870 0.57 1.89 373.0 99.0 99.0 31 181.280 0.61 2.03 373.0 99.0 99.0 32 185.840 0.61 2.03 374.0 100.0 100.0 33 190.410 0.61 2.03 374.0 100.0 100.0 34 194.920 0.66 2.19 375.0 100.0 100.0 35 199.620 0.66 2.19 375.0 101.0 101.0 36 204.290 0.66 2.19 375.0 101.0 101.0 37 209.098 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 3 Holcim (US) Inc. - Kiln K-1 Flow & Moisture Test Date 7/19/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 94.31 25.05 -0.50 25.01 364 19.10 10.10 70.80 31.46 30.26 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 13.5299 1.0000 0.84 162.343 270.80 92 130.728 12.747 0.0888 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.779 58.42 176,981 330,566 9.68E+06 36 0.276 180 5.00 2.02 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 48.547 0.55 1.83 361.0 90.0 90.0 Wt. (Final) Wt. (Initial) lc 2 52.970 0.55 1.83 361.0 90.0 90.0 729.1 516.1 213.0 3 57.180 0.55 1.83 362.0 90.0 90.0 673.4 665.9 7.5 4 61.480 0.60 1.99 362.0 91.0 91.0 705.1 702.0 3.1 5 65.470 0.60 1.99 362.0 91.0 91.0 650.2 648.5 1.7 6 70.440 0.60 1.99 363.0 91.0 91.0 912.4 866.9 45.5 7 74.860 0.67 2.23 363.0 91.0 91.0 8 79.650 0.67 2.23 363.0 91.0 91.0 Isokinetics 102.3 9 84.340 0.67 2.23 363.0 91.0 91.0 Test Date 7/19/2023 10 88.995 0.55 1.83 362.0 91.0 91.0 Start Time 11 93.390 0.55 1.83 362.0 91.0 91.0 End Time 12 97.730 0.55 1.83 362.0 91.0 91.0 Run 3 13 101.970 0.61 2.03 362.0 91.0 91.0 14 106.620 0.61 2.03 363.0 91.0 91.0 15 110.970 0.61 2.03 363.0 91.0 91.0 16 115.610 0.66 2.19 363.0 92.0 92.0 17 120.260 0.66 2.19 364.0 92.0 92.0 18 124.920 0.66 2.19 364.0 92.0 92.0 19 129.493 0.57 1.89 364.0 92.0 92.0 20 133.980 0.57 1.89 364.0 92.0 92.0 21 138.370 0.57 1.89 365.0 92.0 92.0 22 142.690 0.61 2.03 365.0 92.0 92.0 23 147.160 0.61 2.03 365.0 92.0 92.0 24 151.730 0.61 2.03 366.0 93.0 93.0 25 156.400 0.66 2.19 366.0 93.0 93.0 26 160.890 0.66 2.19 366.0 93.0 93.0 27 165.650 0.66 2.19 366.0 93.0 93.0 28 170.334 0.56 1.86 366.0 93.0 93.0 29 174.840 0.56 1.86 366.0 93.0 93.0 30 179.000 0.56 1.86 367.0 93.0 93.0 31 183.620 0.60 1.99 367.0 93.0 93.0 32 187.980 0.60 1.99 368.0 94.0 94.0 33 192.610 0.60 1.99 368.0 94.0 94.0 34 196.790 0.66 2.19 369.0 94.0 94.0 35 201.490 0.66 2.19 369.0 94.0 94.0 36 206.220 0.66 2.19 369.0 94.0 94.0 37 210.890 38 39 40 41 42 43 44 45 46 47 48 Page 1 Source Information Division of Air Quality Compliance Demonstration Source Information Company Name Holcim (US) Inc. - Clinker Cooler Company Contact:Clint Badger Contact Phone No.801-829-2122 Source Designation:Clinker Cooler Test & Review Dates Test Date: 7/18/2023 Review Date: 1/26/2024 Tabs Are Shown Observer: Reviewer:Paul Morris Particulate Emission Limits lbs/MMBtu lbs/hr gr/dscf Emission Rates - "Front Half" lbs/MMBtu lbs/hr gr/dscf 0.1633 0.0003 Test Information Stack_I.D._inches As ft^2 Y Dl H @ Cp Pbar Pq (static)Dn 71.00 27.49 0.9930 1.746 0.84 24.45 0.1 0.251 Contractor Information Contracting Company: Mostardi Platt Contact: Hal Lee Phone No.: 801-716-2652 Project No.: Circular 10100 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 F factor usedF factors for Coal, Oil, and Gas Anthrocite 2 Lignite Natural Propane Butane COAL OIL GAS Bituminous 2 Fd Fw Fc scf/MMBtu scf/MMBtu scf/MMBtu O2 CO2 lbs/MMBtu Page 1 Summary Division of Air Quality Reference Methods 5 - TSP Compliance Demonstration of Holcim (US) Inc. - Clinker Cooler Testing Results Lab Data - grams collected Test Date 7/18/2023 7/18/2023 7/18/2023 7/18/2023 Lab Data Probe Filter Back ton/hr Circular Run 1 Run 2 Run 3 Run 4 Run 1 0.00182 0.00015 100.6 As ft^2 27.49 27.49 27.49 Run 2 0.00029 0.00015 100.6 Pbar 24.45 24.45 24.45 Run 3 0.00025 0.00015 100.6 Pq (static)0.10 0.10 0.10 Run 4 Ps 24.46 24.46 24.46 Avg. Ts F 225.83 215.50 209.42 Front Half Emissions Summary CO2 - FCO2 0.04 0.04 0.04 Run 1 Run 2 Run 3 Run 4 Avg. O2 20.90 20.90 20.90 gr./dscf 0.0007 0.0002 0.0001 0.0003 N2+C 79.06 79.06 79.06 lbs/hr 0.3441 0.0762 0.0695 0.1633 Md 28.84 28.84 28.84 lbs/MMBtu Ms 28.69 28.59 28.65 lb/ton 0.003 0.001 0.001 0.002 Y 0.99 0.99 0.99 Cp 0.84 0.84 0.84 Total Emissions Summary w/back half condensable Vm cf 58.33 56.97 56.90 Run 1 Run 2 Run 3 Run 4 Avg. Vlc 14.00 22.20 16.50 gr./dscf 0.0007 0.0002 0.0001 0.0003 AVG. Tm F 99.42 102.42 103.25 lbs/hr 0.3441 0.0762 0.0695 0.1633 Vm std 45.01 43.70 43.58 lbs/MMBtu Vw std 0.66 1.04 0.78 Bws 0.01 0.02 0.02 S Bws 1.00 1.00 1.00 Avg. Sqrt Dlp 0.82 0.79 0.78 Vs 58.08 55.55 54.77 F factor used scfm wet 60294.80 58555.51 58257.29 acfm 95811.06 91645.32 90357.45 Qsd dscfh 3565488.87 3431286.03 3434229.55 # Sample Points 12.00 12.00 12.00 Dn 0.251 0.251 0.251 An 3.44E-04 3.44E-04 3.44E-04 Start Time 0:00 0:00 0:00 End Time 0:00 0:00 0:00 Total Test time 60.00 60.00 60.00 Time @ point 5.00 5.00 5.00 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Points Run 1 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 2 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 3 PxP Isokinetic O2 CO2 lbs/MMBtu 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 Sample Points Run 4 PxP Isokinetic Page 1 Run 1 Holcim (US) Inc. - Clinker Cooler Flow & Moisture Test Date 7/18/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 27.49 24.45 0.10 24.46 226 0.04 20.90 79.06 28.84 28.69 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 1.6058 0.9930 0.84 58.334 14.00 99.42 45.012 0.659 0.0144 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.818 58.08 60,295 95,811 3.57E+06 12 0.251 60 5.00 2.624167 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 72.478 0.58 2.28 215 99 99 Wt. (Final) Wt. (Initial) lc 2 77.124 0.63 2.48 216 99 99 683.60 678.90 4.7 3 81.872 0.68 2.68 213 99 99 736.10 734.30 1.8 4 86.798 0.67 2.64 214 99 99 637.20 637.10 0.1 5 91.681 0.69 2.72 216 99 99 883.90 876.50 7.4 6 96.718 0.72 2.83 220 99 99 0.0 7 101.715 0.59 2.32 229 99 99 8 106.304 0.64 2.52 236 99 99 Isokinetics 101.1 9 111.025 0.69 2.72 239 100 100 Test Date 7/18/2023 10 115.924 0.71 2.64 240 100 100 Start Time enter 11 120.812 0.71 2.79 237 100 100 End Time 12 125.723 0.73 2.87 235 101 101 Run 1 13 130.812 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 2 Holcim (US) Inc. - Clinker Cooler Flow & Moisture Test Date 7/18/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 27.49 24.45 0.10 24.46 216 0.04 20.90 79.06 28.84 28.59 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 1.3148 0.9930 0.84 56.972 22.20 102 43.702 1.045 0.0234 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.787 55.55 58,556 91,645 3.43E+06 12 0.251 60 5.00 2.44 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 131.025 0.57 2.24 228.0 101.0 101.0 Wt. (Final) Wt. (Initial) lc 2 135.602 0.60 2.36 226.0 101.0 101.0 695.10 683.60 11.5 3 140.212 0.62 2.44 224.0 101.0 101.0 739.00 736.10 2.9 4 145.012 0.63 2.48 222.0 101.0 101.0 638.20 637.20 1.0 5 149.634 0.65 2.56 220.0 102.0 102.0 890.70 883.90 6.8 6 154.503 0.66 2.60 216.0 102.0 102.0 0.0 7 159.349 0.56 2.20 212.0 103.0 103.0 8 163.934 0.58 2.28 209.0 103.0 103.0 Isokinetics 102.0 9 168.913 0.61 2.40 209.0 103.0 103.0 Test Date 7/18/2023 10 173.324 0.63 2.48 207.0 104.0 104.0 Start Time 11 178.125 0.65 2.56 206.0 104.0 104.0 End Time 12 183.049 0.68 2.68 207.0 104.0 104.0 Run 2 13 187.997 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 3 Holcim (US) Inc. - Clinker Cooler Flow & Moisture Test Date 7/18/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 27.49 24.45 0.10 24.46 209 0.04 20.90 79.06 28.84 28.65 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 1.1650 0.9930 0.84 56.897 16.50 103 43.576 0.777 0.0175 0.9990 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.780 54.77 58,257 90,357 3.43E+06 12 0.251 60 5.00 2.41 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 188.013 0.50 2.20 215.0 107.0 107.0 Wt. (Final) Wt. (Initial) lc 2 192.604 0.58 2.28 215.0 102.0 102.0 701.2 695.1 6.1 3 197.125 0.60 2.36 214.0 102.0 102.0 741.0 739.0 2.0 4 201.832 0.62 2.44 212.0 102.0 102.0 638.3 638.2 0.1 5 206.612 0.65 2.52 210.0 102.0 102.0 893.2 884.9 8.3 6 211.401 0.67 2.64 209.0 102.0 102.0 0.0 7 216.329 0.55 2.16 206.0 103.0 103.0 8 220.838 0.59 2.24 204.0 103.0 103.0 Isokinetics 101.6 9 225.493 0.61 2.40 204.0 104.0 104.0 Test Date 7/18/2023 10 230.211 0.63 2.48 207.0 104.0 104.0 Start Time 11 235.112 0.65 2.56 208.0 104.0 104.0 End Time 12 239.857 0.67 2.64 209.0 104.0 104.0 Run 3 13 244.910 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Source Information Division of Air Quality Compliance Demonstration Source Information Company Name Holcim - Crusher Baghouse Company Contact:Clinton Badger Contact Phone No.801-829-2122 Source Designation:Crusher Baghouse Test & Review Dates Test Date: 7/21/2023 Review Date: 1/24/2024 Tabs Are Shown Observer: Reviewer:Paul Morris Particulate Emission Limits lbs/MMBtu lbs/hr gr/dscf 0.022 Emission Rates - "Front Half" lbs/MMBtu lbs/hr gr/dscf 0.0081 0.0001 Test Information Stack_I.D._inches As ft^2 Y Dl H @ Cp Pbar Pq (static)Dn 33.00 5.94 0.9900 1.559 0.84 25.23 -3.8 0.31 Contractor Information Contracting Company: Mostardi Platt Contact: Hal Lee Phone No.: 801-716-2652 Project No.: Circular 10100 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 F factor usedF factors for Coal, Oil, and Gas Anthrocite 2 Lignite Natural Propane Butane COAL OIL GAS Bituminous 2 Fd Fw Fc scf/MMBtu scf/MMBtu scf/MMBtu O2 CO2 lbs/MMBtu Page 1 Summary Division of Air Quality Reference Methods 5 - TSP Compliance Demonstration of Holcim - Crusher Baghouse Testing Results Lab Data - grams collected Test Date 7/21/2023 7/21/2023 7/21/2023 7/21/2023 Lab Data Probe Filter Back Circular Run 1 Run 2 Run 3 Run 4 Run 1 0.00025 0.00015 As ft^2 5.94 5.94 5.94 Run 2 0.00025 0.00015 Pbar 25.23 25.23 25.23 Run 3 0.00025 0.00015 Pq (static)-3.80 -3.80 -3.80 Run 4 Ps 24.95 24.95 24.95 Avg. Ts F 62.00 62.96 66.00 Front Half Emissions Summary CO2 - FCO2 0.04 0.04 0.04 Run 1 Run 2 Run 3 Run 4 Avg. O2 20.90 20.90 20.90 gr./dscf 0.0001 0.0001 0.0001 0.0001 N2+C 79.06 79.06 79.06 lbs/hr 0.0081 0.0081 0.0081 0.0081 Md 28.84 28.84 28.84 lbs/MMBtu Ms 28.72 28.71 28.71 Y 0.99 0.99 0.99 Cp 0.84 0.84 0.84 Total Emissions Summary w/back half condensable Vm cf 102.99 103.79 104.91 Run 1 Run 2 Run 3 Run 4 Avg. Vlc 21.70 23.70 23.60 gr./dscf 0.0001 0.0001 0.0001 0.0001 AVG. Tm F 60.50 68.71 74.92 lbs/hr 0.0081 0.0081 0.0081 0.0081 Vm std 88.36 87.67 87.60 lbs/MMBtu Vw std 1.02 1.12 1.11 Bws 0.01 0.01 0.01 S Bws 0.02 0.02 0.03 Avg. Sqrt Dlp 0.75 0.74 0.74 Vs 45.72 45.15 45.58 F factor used scfm wet 13743.38 13548.26 13596.27 acfm 16293.33 16091.50 16242.44 Qsd dscfh 815179.70 802681.75 805561.16 # Sample Points 24.00 24.00 24.00 Dn 0.310 0.310 0.310 An 5.24E-04 5.24E-04 5.24E-04 Start Time 0:00 0:00 0:00 End Time 0:00 0:00 0:00 Total Test time 72.00 72.00 72.00 Time @ point 3.00 3.00 3.00 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Points Run 1 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 2 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 3 PxP Isokinetic O2 CO2 lbs/MMBtu 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 Sample Points Run 4 PxP Isokinetic Page 1 Run 1 Holcim - Crusher Baghouse Flow & Moisture Test Date 7/21/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 5.94 25.23 -3.80 24.95 62 0.04 20.90 79.06 28.84 28.72 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.0226 0.9900 0.84 102.986 21.70 60.50 88.362 1.021 0.0114 0.0226 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.746 45.72 13,743 16,293 8.15E+05 24 0.31 72 3.00 4.658333 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 48.494 0.58 4.93 62 60 60 Wt. (Final) Wt. (Initial) lc 2 52.910 0.58 4.92 62 60 60 688.20 678.50 9.7 3 57.340 0.55 4.67 62 60 60 744.10 743.00 1.1 4 61.640 0.55 4.67 62 60 60 635.00 634.20 0.8 5 65.820 0.59 4.67 62 60 60 879.60 869.50 10.1 6 70.050 0.59 4.58 62 60 60 0.0 7 74.410 0.56 4.25 62 60 60 8 78.630 0.56 4.25 62 60 60 Isokinetics 102.4 9 82.940 0.55 4.67 62 60 60 Test Date 7/21/2023 10 87.120 0.55 4.67 62 60 60 Start Time enter 11 91.450 0.52 4.41 62 60 60 End Time 12 95.660 0.52 4.41 62 60 60 Run 1 13 99.754 0.59 5.01 62 60 60 14 104.340 0.59 5.01 62 60 60 15 108.690 0.56 4.75 62 60 60 16 112.980 0.56 4.75 62 60 60 17 117.290 0.53 4.67 62 60 60 18 121.630 0.55 4.67 62 60 60 19 125.840 0.57 4.84 62 62 62 20 130.190 0.57 4.84 62 62 62 21 134.640 0.56 4.75 62 62 62 22 138.790 0.56 4.75 62 62 62 23 143.220 0.51 4.33 62 62 62 24 147.380 0.51 4.33 62 62 62 25 151.480 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 2 Holcim - Crusher Baghouse Flow & Moisture Test Date 7/21/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 5.94 25.23 -3.80 24.95 63 0.04 20.90 79.06 28.84 28.71 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.0233 0.9900 0.84 103.790 23.70 69 87.669 1.116 0.0126 0.0233 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.736 45.15 13,548 16,091 8.03E+05 24 0.31 72 3.00 4.66 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 152.180 0.57 4.90 62.0 66.0 66.0 Wt. (Final) Wt. (Initial) lc 2 156.670 0.57 4.90 62.0 66.0 66.0 697.30 688.20 9.1 3 161.050 0.54 4.64 62.0 66.0 66.0 747.30 744.10 3.2 4 165.044 0.54 4.64 62.0 67.0 67.0 635.40 635.00 0.4 5 169.800 0.53 4.55 62.0 67.0 67.0 890.60 879.60 11.0 6 173.970 0.53 4.55 62.0 67.0 67.0 0.0 7 178.200 0.53 4.55 62.0 67.0 67.0 8 182.430 0.53 4.55 63.0 67.0 67.0 Isokinetics 103.2 9 186.550 0.55 4.73 63.0 68.0 68.0 Test Date 7/21/2023 10 190.980 0.55 4.73 63.0 68.0 68.0 Start Time 11 195.280 0.52 4.49 63.0 68.0 68.0 End Time 12 199.470 0.52 4.49 63.0 68.0 68.0 Run 2 13 203.846 0.58 4.98 63.0 69.0 69.0 14 208.390 0.58 4.98 63.0 69.0 69.0 15 212.980 0.56 4.81 63.0 69.0 69.0 16 217.520 0.56 4.81 63.0 69.0 69.0 17 221.830 0.55 4.73 63.0 70.0 70.0 18 225.970 0.55 4.73 63.0 70.0 70.0 19 230.240 0.54 4.64 64.0 70.0 70.0 20 234.580 0.54 4.64 64.0 71.0 71.0 21 238.890 0.52 4.47 64.0 71.0 71.0 22 243.120 0.52 4.47 64.0 72.0 72.0 23 247.360 0.51 4.38 64.0 72.0 72.0 24 251.670 0.51 4.38 64.0 72.0 72.0 25 255.970 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 3 Holcim - Crusher Baghouse Flow & Moisture Test Date 7/21/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 5.94 25.23 -3.80 24.95 66 0.04 20.90 79.06 28.84 28.71 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.0260 0.9900 0.84 104.913 23.60 75 87.603 1.111 0.0125 0.0260 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.741 45.58 13,596 16,242 8.06E+05 24 0.31 72 3.00 4.71 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 257.243 0.59 5.07 64.0 73.0 73.0 Wt. (Final) Wt. (Initial) lc 2 261.880 0.59 5.07 64.0 73.0 73.0 709.4 697.3 12.1 3 266.370 0.56 4.81 64.0 73.0 73.0 748.9 747.3 1.6 4 270.790 0.56 4.81 64.0 73.0 73.0 636.0 635.4 0.6 5 275.170 0.55 4.73 64.0 73.0 73.0 899.9 890.6 9.3 6 279.580 0.55 4.73 65.0 74.0 74.0 0.0 7 283.380 0.52 4.90 65.0 74.0 74.0 8 288.350 0.57 4.90 65.0 74.0 74.0 Isokinetics 102.7 9 292.250 0.56 4.81 65.0 74.0 74.0 Test Date 7/21/2023 10 297.240 0.56 4.81 66.0 74.0 74.0 Start Time 11 301.670 0.51 4.38 66.0 75.0 75.0 End Time 12 305.880 0.51 4.38 66.0 75.0 75.0 Run 3 13 309.985 0.57 4.90 66.0 75.0 75.0 14 314.580 0.57 4.90 66.0 75.0 75.0 15 318.980 0.57 4.64 66.0 75.0 75.0 16 323.370 0.57 4.64 67.0 76.0 76.0 17 327.680 0.53 4.55 67.0 76.0 76.0 18 331.990 0.53 4.55 67.0 76.0 76.0 19 336.270 0.53 4.55 67.0 76.0 76.0 20 340.590 0.53 4.55 68.0 76.0 76.0 21 344.870 0.55 4.73 68.0 77.0 77.0 22 349.360 0.55 4.73 68.0 77.0 77.0 23 353.570 0.52 4.47 68.0 77.0 77.0 24 357.790 0.52 4.47 68.0 77.0 77.0 25 362.156 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Source Information Division of Air Quality Compliance Demonstration Source Information Company Name Holcim - Transfer Baghouse Company Contact:Clinton Badger Contact Phone No.801-829-2122 Source Designation:Transfer Baghouse Test & Review Dates Test Date: 7/21/2023 Review Date: 1/25/2024 Tabs Are Shown Observer: Reviewer:Paul Morris Particulate Emission Limits lbs/MMBtu lbs/hr gr/dscf 0.022 Emission Rates - "Front Half" lbs/MMBtu lbs/hr gr/dscf 0.0067 0.0004 Test Information Stack_I.D._inches As ft^2 Y Dl H @ Cp Pbar Pq (static)Dn 12.24 0.82 0.9930 1.746 0.84 25.23 -0.5 0.266 Contractor Information Contracting Company: Mostardi Platt Contact: Hal Lee Phone No.: 801-716-2652 Project No.: Circular 10100 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 F factor usedF factors for Coal, Oil, and Gas Anthrocite 2 Lignite Natural Propane Butane COAL OIL GAS Bituminous 2 Fd Fw Fc scf/MMBtu scf/MMBtu scf/MMBtu O2 CO2 lbs/MMBtu Page 1 Summary Division of Air Quality Reference Methods 5 - TSP Compliance Demonstration of Holcim - Transfer Baghouse Testing Results Lab Data - grams collected Test Date 7/21/2023 7/21/2023 7/21/2023 7/21/2023 Lab Data Probe Filter Back Circular Run 1 Run 2 Run 3 Run 4 Run 1 0.00059 0.0039 As ft^2 0.82 0.82 0.82 Run 2 0.00025 0.00015 Pbar 25.23 25.23 25.23 Run 3 0.00025 0.00015 Pq (static)-0.50 -0.50 -0.50 Run 4 Ps 25.19 25.19 25.19 Avg. Ts F 60.54 69.08 73.13 Front Half Emissions Summary CO2 - FCO2 0.04 0.04 0.04 Run 1 Run 2 Run 3 Run 4 Avg. O2 20.90 20.90 20.90 gr./dscf 0.0010 0.0001 0.0001 0.0004 N2+C 79.06 79.06 79.06 lbs/hr 0.0172 0.0015 0.0015 0.0067 Md 28.84 28.84 28.84 lbs/MMBtu Ms 28.69 28.68 28.68 Y 0.99 0.99 0.99 Cp 0.84 0.84 0.84 Total Emissions Summary w/back half condensable Vm cf 81.51 83.47 84.01 Run 1 Run 2 Run 3 Run 4 Avg. Vlc 20.90 22.40 21.90 gr./dscf 0.0010 0.0001 0.0001 0.0004 AVG. Tm F 58.46 74.88 80.75 lbs/hr 0.0172 0.0015 0.0015 0.0067 Vm std 70.19 69.67 69.36 lbs/MMBtu Vw std 0.98 1.05 1.03 Bws 0.01 0.01 0.01 S Bws 0.02 0.03 0.03 Avg. Sqrt Dlp 0.81 0.81 0.81 Vs 49.13 49.54 49.72 F factor used scfm wet 2057.08 2040.92 2032.99 acfm 2408.51 2428.80 2437.85 Qsd dscfh 121718.71 120629.30 120193.25 # Sample Points 24.00 24.00 24.00 Dn 0.266 0.266 0.266 An 3.86E-04 3.86E-04 3.86E-04 Start Time 0:00 0:00 0:00 End Time 0:00 0:00 0:00 Total Test time 72.00 72.00 72.00 Time @ point 3.00 3.00 3.00 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Points Run 1 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 2 PxP Isokinetic 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 % I s o k i n e t i c Sample Points Run 3 PxP Isokinetic O2 CO2 lbs/MMBtu 80.00 90.00 100.00 110.00 120.00 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 Sample Points Run 4 PxP Isokinetic Page 1 Run 1 Holcim - Transfer Baghouse Flow & Moisture Test Date 7/21/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 0.82 25.23 -0.50 25.19 61 0.04 20.90 79.06 28.84 28.69 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.0212 0.9930 0.84 81.508 20.90 58.46 70.187 0.984 0.0138 0.0212 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.806 49.13 2,057 2,409 1.22E+05 24 0.266 72 3.00 3.497500 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 45.364 0.62 3.34 59 55 55 Wt. (Final) Wt. (Initial) lc 2 48.670 0.62 3.34 59 55 55 733.50 726.40 7.1 3 52.025 0.65 3.50 59 55 55 739.20 731.90 7.3 4 55.335 0.65 3.50 58 55 55 628.80 628.70 0.1 5 58.815 0.68 3.66 58 55 55 849.20 842.80 6.4 6 62.190 0.68 3.66 59 55 55 0.0 7 65.615 0.67 3.60 59 56 56 8 69.085 0.67 3.61 60 56 56 Isokinetics 101.8 9 72.470 0.65 3.50 60 56 56 Test Date 7/21/2023 10 75.895 0.65 3.50 60 56 56 Start Time enter 11 79.235 0.63 3.39 60 56 56 End Time 12 82.610 0.63 3.39 60 56 56 Run 1 13 85.933 0.63 3.39 61 59 59 14 89.270 0.63 3.39 61 59 59 15 92.670 0.64 3.40 61 60 60 16 96.005 0.64 3.45 61 60 60 17 99.440 0.66 3.55 61 61 61 18 102.828 0.66 3.55 62 61 61 19 106.295 0.68 3.66 62 62 62 20 109.745 0.68 3.66 62 62 62 21 113.155 0.65 3.50 62 63 63 22 116.670 0.65 3.50 63 63 63 23 120.040 0.64 3.45 63 63 63 24 123.495 0.64 3.45 63 64 64 25 126.872 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 2 Holcim - Transfer Baghouse Flow & Moisture Test Date 7/21/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 0.82 25.23 -0.50 25.19 69 0.04 20.90 79.06 28.84 28.68 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.0286 0.9930 0.84 83.465 22.40 75 69.667 1.054 0.0149 0.0286 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.806 49.54 2,041 2,429 1.21E+05 24 0.266 72 3.00 3.50 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 30.004 0.63 3.34 67.0 70.0 70.0 Wt. (Final) Wt. (Initial) lc 2 33.385 0.63 3.34 67.0 70.0 70.0 740.90 733.50 7.4 3 36.840 0.65 3.50 67.0 70.0 70.0 748.10 739.20 8.9 4 40.255 0.65 3.50 67.0 71.0 71.0 628.80 628.80 0.0 5 43.765 0.67 3.66 68.0 71.0 71.0 855.30 849.20 6.1 6 47.235 0.67 3.66 68.0 72.0 72.0 0.0 7 50.740 0.67 3.66 68.0 72.0 72.0 8 54.245 0.67 3.66 69.0 73.0 73.0 Isokinetics 101.9 9 57.695 0.64 3.50 69.0 73.0 73.0 Test Date 7/21/2023 10 61.205 0.64 3.50 69.0 73.0 73.0 Start Time 11 64.610 0.63 3.39 69.0 74.0 74.0 End Time 12 68.045 0.63 3.39 69.0 74.0 74.0 Run 2 13 71.517 0.64 3.39 69.0 76.0 76.0 14 74.975 0.64 3.39 69.0 76.0 76.0 15 78.470 0.65 3.40 69.0 77.0 77.0 16 81.915 0.65 3.45 69.0 77.0 77.0 17 85.430 0.66 3.55 70.0 77.0 77.0 18 88.945 0.66 3.55 70.0 78.0 78.0 19 92.455 0.67 3.66 70.0 78.0 78.0 20 95.995 0.67 3.66 71.0 78.0 78.0 21 99.475 0.65 3.50 71.0 79.0 79.0 22 103.040 0.65 3.50 71.0 79.0 79.0 23 106.480 0.64 3.45 71.0 79.0 79.0 24 109.985 0.64 3.45 71.0 80.0 80.0 25 113.469 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 Run 3 Holcim - Transfer Baghouse Flow & Moisture Test Date 7/21/2023 As ft^2 Pbar Pq (static) Ps Avg. Ts F CO2 - FCO2 O2 N2+C Md Ms 0.82 25.23 -0.50 25.19 73 0.04 20.90 79.06 28.84 28.68 Y Cp Vm cf Vlc Avg. Tm F Vm std Vw std Bws S Bws 0.0328 0.9930 0.84 84.010 21.90 81 69.360 1.031 0.0146 0.0328 0.999 Avg. Sqrt Dlp Vs scfm wet acfm Qsd dscfh # Sample Points Dn Total Test time (minutes) Time @ point (minutes)Avg. Dlh 0.806 49.72 2,033 2,438 1.20E+05 24 0.266 72 3.00 3.50 TRUE Point No.Meter (cf) dl "p" dl "h" ts F tm F (in) tm F (out) Imp. Liquid Collected 1 13.968 0.64 3.34 72.0 78.0 78.0 Wt. (Final) Wt. (Initial) lc 2 17.415 0.64 3.34 72.0 78.0 78.0 747.0 740.9 6.1 3 20.910 0.65 3.50 72.0 79.0 79.0 759.2 748.1 11.1 4 24.395 0.65 3.50 72.0 79.0 79.0 629.0 628.8 0.2 5 27.935 0.67 3.66 72.0 79.0 79.0 859.8 855.3 4.5 6 31.405 0.67 3.66 72.0 80.0 80.0 0.0 7 34.975 0.68 3.61 73.0 80.0 80.0 8 38.535 0.68 3.61 73.0 80.0 80.0 Isokinetics 101.9 9 42.065 0.66 3.50 73.0 79.0 79.0 Test Date 7/21/2023 10 45.648 0.66 3.50 73.0 79.0 79.0 Start Time 11 49.065 0.63 3.39 72.0 80.0 80.0 End Time 12 52.615 0.63 3.39 72.0 80.0 80.0 Run 3 13 55.888 0.62 3.39 73.0 80.0 80.0 14 59.315 0.62 3.39 73.0 80.0 80.0 15 62.780 0.64 3.45 73.0 81.0 81.0 16 66.190 0.64 3.45 74.0 81.0 81.0 17 69.735 0.66 3.55 74.0 82.0 82.0 18 73.190 0.66 3.55 74.0 82.0 82.0 19 76.750 0.67 3.66 74.0 83.0 83.0 20 80.300 0.67 3.66 74.0 83.0 83.0 21 83.820 0.65 3.50 74.0 83.0 83.0 22 87.370 0.65 3.50 74.0 84.0 84.0 23 90.840 0.63 3.45 75.0 84.0 84.0 24 94.355 0.63 3.45 75.0 84.0 84.0 25 97.978 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 Page 1 MW 78.11 Run A Vm (L) %02 (ug) ppmdv @ 7% O2 Run A Vm (L) %02 (ug) ppmdv @ 7% O2 On 1 47.668 10.6 28.6 0.25 Off 1 37.802 10.8 19.8 0.23 On 2 43.691 10.5 20.9 0.20 Off 2 34.715 10.0 23.4 0.27 On 3 47.661 10.7 22.5 0.20 Off 3 34.223 10.2 21.5 0.26 Run B Vm (L) %02 (ug) ppmdv @ 7% O2 Run B Vm (L) %02 (ug) ppmdv @ 7% O2 On 1 47.281 10.6 16.7 0.15 Off 1 37.338 10.8 8.8 0.10 On 2 43.343 10.5 17.5 0.17 Off 2 34.288 10.0 14.2 0.17 On 3 47.282 10.7 20.9 0.19 Off 3 36.806 10.2 17.4 0.19 AVG 0.19 AVG 0.20 MW 106.16 Run Vm (L) %02 (ug) ppmdv @ 7% O2 Run Vm (L) %02 (ug) ppmdv @ 7% O2 On 1 47.668 10.6 1.4 0.01 Off 1 37.802 10.8 1.4 0.01 On 2 43.691 10.5 1.4 0.01 Off 2 34.715 10.0 1.4 0.01 On 3 47.661 10.7 1.4 0.01 Off 3 34.223 10.2 1.4 0.01 Run B Vm (L) %02 (ug) ppmdv @ 7% O2 Run B Vm (L) %02 (ug) ppmdv @ 7% O2 On 1 47.281 10.6 0 0.00 Off 1 37.338 10.8 0 0.00 On 2 43.343 10.5 0 0.00 Off 2 34.288 10.0 0 0.00 On 3 47.282 10.7 0 0.00 Off 3 36.806 10.2 0 0.00 AVG 0.00 AVG 0.01 MW 128.17 Run Vm (L) %02 (ug) ppmdv @ 7% O2 Run Vm (L) %02 (ug) ppmdv @ 7% O2 On 1 47.668 10.6 1.3 0.01 Off 1 37.802 10.8 1.3 0.01 On 2 43.691 10.5 1.3 0.01 Off 2 34.715 10.0 1.3 0.01 On 3 47.661 10.7 1.3 0.01 Off 3 34.223 10.2 1.3 0.01 Run B Vm (L) %02 (ug) ppmdv @ 7% O2 Run B Vm (L) %02 (ug) ppmdv @ 7% O2 On 1 47.281 10.6 0 0.00 Off 1 37.338 10.8 0 0.00 On 2 43.343 10.5 0 0.00 Off 2 34.288 10.0 0 0.00 On 3 47.282 10.7 0 0.00 Off 3 36.806 10.2 0.6 0.01 AVG 0.00 AVG 0.01 MW 106.16 Run Vm (L) %02 (ug) ppmdv @ 7% O2 Run Vm (L) %02 (ug) ppmdv @ 7% O2 On 1 47.668 10.6 1.4 0.01 Off 1 37.802 10.8 1.5 0.01 On 2 43.691 10.5 1.4 0.01 Off 2 34.715 10.0 1.5 0.01 On 3 47.661 10.7 1.4 0.01 Off 3 34.223 10.2 1.5 0.01 Run B Vm (L) %02 (ug) ppmdv @ 7% O2 Run B Vm (L) %02 (ug) ppmdv @ 7% O2 On 1 47.281 10.6 0 0.00 Off 1 37.338 10.8 0 0.00 On 2 43.343 10.5 0 0.00 Off 2 34.288 10.0 0 0.00 On 3 47.282 10.7 0 0.00 Off 3 36.806 10.2 0 0.00 AVG 0.00 AVG 0.01 MW 106.16 Run Vm (L) %02 (ug) ppmdv @ 7% O2 Run Vm (L) %02 (ug) ppmdv @ 7% O2 On 1 47.668 10.6 1.5 0.01 Off 1 37.802 10.8 1.5 0.01 Benzene m-Xylene Naphthalene o-Xylene p-Xylene On 2 43.691 10.5 1.5 0.01 Off 2 34.715 10.0 1.5 0.01 On 3 47.661 10.7 1.5 0.01 Off 3 34.223 10.2 1.5 0.01 Run B Vm (L) %02 (ug) ppmdv @ 7% O2 Run B Vm (L) %02 (ug) ppmdv @ 7% O2 On 1 47.281 10.6 0 0.00 Off 1 37.338 10.8 0 0.00 On 2 43.343 10.5 0 0.00 Off 2 34.288 10.0 0 0.00 On 3 47.282 10.7 0 0.00 Off 3 36.806 10.2 0 0.00 AVG 0.01 AVG 0.01 MW 104.15 Run Vm (L) %02 (ug) ppmdv @ 7% O2 Run Vm (L) %02 (ug) ppmdv @ 7% O2 On 1 47.668 10.6 1.4 0.01 Off 1 37.802 10.8 1.5 0.01 On 2 43.691 10.5 1.4 0.01 Off 2 34.715 10.0 1.5 0.01 On 3 47.661 10.7 1.4 0.01 Off 3 34.223 10.2 1.5 0.01 Run B Vm (L) %02 (ug) ppmdv @ 7% O2 Run B Vm (L) %02 (ug) ppmdv @ 7% O2 On 1 47.281 10.6 0 0.00 Off 1 37.338 10.8 0 0.00 On 2 43.343 10.5 0 0.00 Off 2 34.288 10.0 0 0.00 On 3 47.282 10.7 0 0.00 Off 3 36.806 10.2 0 0.00 AVG 0.00 AVG 0.01 MW 92.14 Run Vm (L) %02 (ug) ppmdv @ 7% O2 Run Vm (L) %02 (ug) ppmdv @ 7% O2 On 1 47.668 10.6 8.6 0.06 Off 1 37.802 10.8 1.1 0.01 On 2 43.691 10.5 1.1 0.01 Off 2 34.715 10.0 1.1 0.01 On 3 47.661 10.7 1.1 0.01 Off 3 34.223 10.2 14.2 0.14 Run B Vm (L) %02 (ug) ppmdv @ 7% O2 Run B Vm (L) %02 (ug) ppmdv @ 7% O2 On 1 47.281 10.6 18.4 0.16 Off 1 37.338 10.8 12.6 0.15 On 2 43.343 10.5 3.2 0.03 Off 2 34.288 10.0 2.4 0.03 On 3 47.282 10.7 6.1 0.06 Off 3 36.806 10.2 24.8 0.27 AVG 0.06 AVG 0.10 MW 30.031 Run ppmv wet %02 %H2O ppmdv @ 7% O2 Run ppmv wet %02 %H2O ppmdv @ 7% O2 On 1 1.07 10.5 11.6 1.62 Off 1 1.01 10.8 9.51 1.54 On 2 1.08 10.4 11.4 1.61 Off 2 1.06 10.0 9.92 1.50 On 3 1.07 10.7 11.3 1.64 Off 3 1 10.2 9.76 1.44 AVG 1.63 AVG 1.49 MW 44.05 Run ppmv wet %02 %H2O ppmdv @ 7% O2 Run ppmv wet %02 %H2O ppmdv @ 7% O2 On 1 0.11 10.5 11.6 0.17 Off 1 0.47 10.8 9.5 0.71 On 2 0.34 10.4 11.4 0.51 Off 2 0.99 10.0 9.9 1.40 On 3 0.57 10.7 11.3 0.88 Off 3 0.78 10.2 9.8 1.12 AVG 0.52 AVG 1.08 2.42 2.91 Toluene Formaldehyde Acetaldehyde Mill on total oHAP @ 7% O2 Mill off total oHAP @ 7% O2 Styrene r, HoLcrM Holcim (US) lnc. 6055 E. Croydon Rd. Morgan, Utah 84050 Phone 801 8296821 www. holcim.com/us Dioxin Furan (DF) Test - Holcim Devil's Slide Rotary Kitn July 18-21,2023 Certification ln accordance with the testing protocol for the enclosed report, testing was conducted while the source was operating at the rate and or condition specified in the applicable approval order of 90% or greater production levels. During testing, the kiln operations were representative of normal conditions and operated under such conditions as specified in the permit by the Executive Secretary. I certify, based on information and belief formed by reasonable inquiry, the statements and information contained in the report are true, accurate and complete. Weston Frv Interim Plant Manager Print or type the name and title of Responsible Official -UTAH DEPABTMENT OFENVIRONMENTAL QUAI.ITY JAi\l i \ Z11Z;- DIVISION OF AR QUALITY Signature of a Responsible Official for the Source - lg -20L"[ Date C HoLcrM January 18,2024 State of Utah Utah Division of Air Quality P.O. Box 144820 Salt Lake City, UT 84116 Re: Holcim (US), lnc.'s Devil's Slide Cement Plant Title V Operating Permit No. 2900001004 Dioxin Furan 30 Month Compliance, OHAPs/ THC 30 Month Compliance Test and NESHAP PM Compliance Testing July 18-21,2023. To Whom lt May Concern, Holcim (US) lnc. ("Holcim") submits the enclosed information in relation to performance testing conducted July 18 to July 21,2023 at the Devil's Slide Cement Plant. Find enclosed the compliance test report and certification for Dioxin/Furan (DF) emission testing of the Kiln exhaust, oHAP testing of Kiln exhaust and the Particulate Matter testing at the Kiln exhaust, Clinker Cooler exhaust, Crusher and Transfer Baghouses. The 30 month DF compliance test was performed as required under 40 CFR 63.1349(b)(3). The new temperature for to Kiln Mill Off is 231.7"C, Kiln Mill On is 188.6'C and Alkali Bypass is 201.6'C. These new limits take effect on January 18, 2024. The 30 month THC compliance test was performed as required under 40 CFR 63.1349(b)(7). The new SSOL is 24.14 ppmvw. These new limits take effect on January 18,2024. The annual PM emissions test was performed as required under 40 CFR 63.1349(b)(1). The site specific operating limit (SSOL) established for the Kiln is 15.57 and the Clinker Cooler is 0.27 Enclosed within the test report are a copy of the SSOL calculations. The new SSOLs take effect on January 18, 2024 so this date will be the initial day of the new 30-day rolling average period. Should you have any questions, please contact me at 801-829-2122 or Mark Miller at 702-358- 7280. Enc. Compliance Particulate Emissions Test Report Phone 801 8296821 www. holcim.com/us Holcim (US) lnc. 6055 E. Croydon Rd Morgan, Utah 84050 I,TAH DEPABTMENT OF ETWIRONMENTAL OUALITY JAN 1 I 2024 DIVISION OF AIR OUALITY O HoLcrM Holcim (US) lnc. 6055 E. Croydon Rd Morgan, Utah 84050 Phone 801 8296821 www. holcim.com/us NESHAP Annual PM Testing - Holcim Devil's Slide Rotary Kiln and Clinker Cooler Exhaust July 18-21,2023 Certification !n accordance with the testing protocol for the enclosed report, testing was conducted while the source was operating at the rate and or condition specified in the applicable approval order of 90% or greater production levels. During testing, the kiln and cooler operations were representative of normal conditions and operated under such conditions as specified in the permit by the Executive Secretary. I certify, based on information and belief formed by reasonable inquiry, the statements and information contained in the report are true, accurate and complete. l-tt-2ot l Weston Fry Interim Plant Manager Print or type the name and title of Responsible Official -UTAH DEPABTMENT OFENVIRONMENTAL OUATITY JAN 1 q ?Atul DIV'SION OF AIR QUALITY Signature of a Responsible Official for the Source r, HoLcrM Weston Fry Interim Plant Manager Print or type the name and title of Responsible Official OHAPs/THC Gompliance Test - Holcim Devil's Slide Rotary Kiln July 18-21,2023 Certification ln accordance with the testing protocol for the enclosed report, testing was conducted while the source was operating at the rate and or condition specified in the applicable approval order of 90% or greater production levels. During testing, the kiln and operations were representative of normal conditions and operated under such conditions as specified in the permit by the Executive secretary. I certify, based on information and belief formed by reasonable inquiry, the statements and information contained in the report are true, accurate and complete. ...1---$-:?.e.?I Holcim (US) lnc. 6055 E. Croydon Rd. Morgan, Utah 84050 Date Phone 80'l 829 6821 www. holcim.com/us UTAH DEPARTMENT OF ENVIRONMENTAL OUAUTY JAN 1 I '.ti)?-l DIVISTON OF AIR QUALITY Official for the Source