HomeMy WebLinkAboutDERR-2024-007114Robin Keeler <rkeeler@utah.gov>
SARA 311: Pioneer Investments Corporation-Phillips 66 NSL Terminal
1 message
Bosch, Morgan N <Morgan.N.Bosch@p66.com>Tue, May 14, 2024 at 10:42 AM
To: "ahunt@sdmetrofire.org" <ahunt@sdmetrofire.org>, "em@co.davis.ut.us" <em@co.davis.ut.us>, "deqweb@utah.gov"
<deqweb@utah.gov>, "cmonroe@co.davis.ut.us" <cmonroe@co.davis.ut.us>, "alindgren@co.davis.ut.us"
<alindgren@co.davis.ut.us>, "eqderrtier2@utah.gov" <eqderrtier2@utah.gov>, Davis County LEPC <lepc@co.davis.ut.us>,
"pmcswain@silvereaglerefining.com" <pmcswain@silvereaglerefining.com>
Cc: "Bosch, Morgan N" <Morgan.N.Bosch@p66.com>
To whom it may concern,
In compliance with SARA 311 requirements, Pioneer Investments Corporation - Phillips 66
Company is submitting information to the Utah Department of Environmental Quality and Davis
County LEPC on two new hazardous chemicals now present at the North Salt Lake Terminal
located at 245 East 1100 North, North Salt Lake, UT 84054.
Chemicals added :
Renewable Diesel Fuel stored in two above ground storage tanks of 16,743 barrels
HiTEC 65522 Fuel Additive stored in an above ground storage tank of 12,925 gallons
Please see the attached Material Data Safety Sheets for the new chemicals. If you have any
questions concerning this notification or require more information, please contact me at 406-850-
5969 or morgan.n.bosch@p66.com.
Sincerely,
Morgan Bosch
Environmental Specialist
M: (+1) 406-850-5969
Northwest Region | 2626 Lilian Avenue | Billings, MT 59101
5/14/24, 12:01 PM State of Utah Mail - SARA 311: Pioneer Investments Corporation-Phillips 66 NSL Terminal
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2 attachments
Renewable diesel SDS.pdf
180K
HiTEC65522FuelAdditive_English.pdf
273K
5/14/24, 12:01 PM State of Utah Mail - SARA 311: Pioneer Investments Corporation-Phillips 66 NSL Terminal
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Safety Data Sheet
Renewable Diesel Fuel
SECTION 1 IDENTIFICATION
Product Name: Renewable Diesel Fuel
Synonyms:
Product Use: Diesel Fuel
Restrictions on Use: Use only as directed
Manufacturer:
Sinclair Oil Company
P.O. Box 30825
Salt Lake City, Utah 84130
Telephone: General Information: (801) 524-2777 Fax: (801) 524-2740
Contact Information: sds@sinclairoil.com
Emergency Telephone: 800-424-9300 (CHEMTREC) or (703) 527-3887
SDS Date of Preparation: August 11, 2021
SECTION 2: HAZARDS IDENTIFICATION
Classification:
Physical Health
Flammable Liquid Category 3 Acute Toxicity Category 4 (Oral)
Aspiration Toxicity Category 1
Skin Irritation Category 2
Specific Target Organ Toxicity Repeat Exposure Category 1
Carcinogen Category 2
Label Elements:
Danger!
Hazard Phrases:
Flammable liquid and vapor.
Harmful if inhaled.
May be fatal if swallowed and enters airways.
Causes skin irritation.
Suspected of causing cancer.
Causes damage to thymus, liver and bone marrow through prolonged or repeated exposure.
Precautionary Phrases:
Prevention
Renewable Diesel Fuel
August 11, 2021
Page 2 of 7
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat, sparks, open flames, and hot surfaces. No smoking.
Keep container tightly closed.
Ground and bond container and receiving equipment
Use explosion-proof electrical, ventilating and lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe mist, vapors or spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves, eye protection.
Response
IF SWALLOWED: Immediately call a POISON CENTER or doctor.
Do NOT induce vomiting.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
If skin irritation occurs: Get medical attention.
Take off contaminated clothing and wash it before reuse.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or doctor.
IF exposed or concerned: Get medical attention.
In case of fire: Use water fog, foam, carbon dioxide, or dry chemical to extinguish.
Storage and Disposal
Store in a well-ventilated place. Keep cool. Keep container tightly closed.
Store locked up.
Dispose of contents and container in accordance with local and national regulations.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Chemical name CAS No. Concentration
Alkanes, C10-20- branched and linear 928771-01-1 87-100%
Diesel Fuel 68476-34-6 0-10%
Naphthalene 91-20-3 0-3%
SECTION 4 EMERGENCY and FIRST AID PROCEDURES
Eye Contact: Immediately flush eyes with water for several minutes. Get medical attention if irritation persists.
Skin Contact: Remove contaminated clothing and flush skin with water for several minutes. Wash thoroughly with soap
and water. Get medical attention if irritation develops or persists. Launder clothing before reuse. Discard contaminated
shoes.
Inhalation: Remove to fresh air. If breathing is difficult have qualified personnel administer oxygen. If breathing has
stopped, administer artificial respiration. Get medical attention.
Ingestion: Do not induce vomiting. Rinse mouth with water. Never give anything by mouth to an unconsciousness
person. If vomiting occurs spontaneously, keep head below hips to prevent aspiration into the lungs. Get immediate
medical attention.
Renewable Diesel Fuel
August 11, 2021
Page 3 of 7
Most important symptoms/effects, acute and delayed: May cause eye irritation. Causes skin irritation with redness
and drying. Inhalation may cause respiratory irritation and central nervous system effects. Harmful or fatal if
swallowed. Aspiration during swallowing or vomiting may cause lung damage. May cause cancer based on animal
data.
Indication of immediate medical attention and special treatment, if necessary: Immediate medical attention is
required for ingestion.
SECTION 5 FIRE and EXPLOSION HAZARD DATA
Suitable extinguishing media: Use water fog, foam, carbon dioxide, or dry chemical. Do not use a steady stream of
water. Product may float on the surface of water and create a floating fire hazard.
Specific hazards arising from the chemical: This product is highly flammable and forms explosive mixtures with air.
Vapors are heavier than air and will travel along surfaces to remote ignition sources and flash back. Closed containers
may explode if exposed to extreme heat. Combustion may produce carbon oxides and other products of incomplete
combustion.
Special protective equipment and precautions for fire-fighters: Firefighters should wear full emergency
equipment and a NIOSH approved positive pressure self-contained breathing apparatus. Cool fire exposed container
with water. Do not allow run-off from firefighting to enter drains or water courses.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment, and emergency procedures: Wear appropriate protective
equipment. Eliminate ignitions sources and ventilate the area with explosion proof equipment. Wash thoroughly after
handling.
Environmental hazards: Avoid release into the environment. Report spill as required by local and federal
regulations.
Methods and materials for containment and cleaning up: Contain with an inert absorbent and place into a
closable container for disposal. Use non-sparking tools and equipment. If spill has not ignited, use water spray to
disperse the vapors and protect personnel attempting to stop leak. Prevent entry in storm sewers and waterways.
Runoff can cause a fire or explosion hazard in sewers.
SECTION 7 HANDLING and STORAGE
Precautions for safe handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapors. Wash
thoroughly after handling. Use only with adequate ventilation. Wash thoroughly with soap and water after handling.
Keep containers closed when not in use. Keep product away from heat, sparks, flames and all other sources of
ignition. Do not permit smoking in use or storage areas. Use with non-sparking tools and explosion proof equipment.
Electrically bond and ground containers for transfer
Do not cut, drill, grind or weld on or near containers, even empty containers. Empty containers retain product residues
can be hazardous. Follow all SDS precautions when handling empty containers.
Conditions for safe storage, including any incompatibilities: S Store in accordance with regulations for the
storage of flammable liquids. Store in a dry, well ventilated area away from heat, direct sunlight and all sources of
ignition. Store away from oxidizers and other incompatible materials. Protect containers from physical damage.
Renewable Diesel Fuel
August 11, 2021
Page 4 of 7
SECTION 8 EXPOSURE CONTROLS and PERSONAL PROTECTION
Exposure Guidelines:
INGREDIENTS EXPOSURE LIMITS
Diesel Fuel 100 mg/m3 TWA ACGIH TLV (inhalable fraction and vapor)
Naphthalene 10 ppm TWA OSHA PEL
10 ppm, skin TWA ACGIH TLV
Appropriate engineering controls: Use with local exhaust ventilation to maintain exposures below the occupational
exposure limits. Use explosion proof equipment where required
Respiratory protection: If exposures are exceeded, use a NIOSH approved organic vapor respirator appropriate for
the form and concentration of the contaminants should be used. Selection of respiratory protection depends on the
contaminant type, form and concentration. Select in accordance with OSHA 1910.134 and good Industrial Hygiene
practice.
Skin protection: Impervious gloves such as nitrile rubber recommended to prevent skin contact.
Eye protection: Wear chemical safety goggles to avoid eye contact.
Other: Impervious coveralls, apron and boots is required to prevent skin contact and contamination of personal
clothing. A safety shower and eye wash should be available in the immediate work area.
SECTION 9 PHYSICAL and CHEMICAL PROPERTIES
Appearance (physical state, color, etc.): Colored or clear liquid
Odor: Aromatic hydrocarbon odor.
Odor threshold: Not available pH: Not applicable
Melting point/Pourpoint: Not available Boiling Point: 320-700° F (160-371-1°C)
Flash point: 126-152°F (51.6-66.6°C) Evaporation rate: Not available
Flammability (solid, gas): Not applicable
Flammable limits: LEL: 0.6% UEL: 7.5%
Vapor pressure: <1 mmHg @ 60°F Vapor density: ~3
Relative density: 0.82-0.88 Solubility: Insoluble in water
Partition coefficient: n-ctanol/water: Not available Auto-ignition temperature: >490-545°F (>254.4-285°C)
Decomposition temperature: Not available Viscosity: Not applicable
SECTION 10 STABILITY and REACTIVITY
Reactivity: This product is not expected to be reactive.
Chemical stability: The product is stable.
Possibility of hazardous reactions: None known.
Conditions to avoid: Keep away from heat and all sources of ignition.
Incompatible materials: Avoid oxidizing agents, acids, alkalies and halogens.
Hazardous decomposition products: Thermal decomposition may yield carbon oxides and other products of
incomplete combustion.
Renewable Diesel Fuel
August 11, 2021
Page 5 of 7
SECTION 11 TOXICOLOGICAL INFORMATION
Health Hazards:
Inhalation: Vapors may cause respiratory irritation and central nervous system effect including headache, dizziness,
headaches, giddiness, euphoria, vertigo, blurred vision, nausea, numbne ss, drowsiness, anesthesia, and coma.
Skin Contact: Skin contact may cause irritation, redness and defatting of the skin.
Eye Contact: Eye contact may cause mild irritation with redness, tearing and pain.
Ingestion: Swallowing may cause gastrointestinal irritation, nausea, vomiting, diarrhea, vertigo, drowsiness, mental
confusion, staggering gait, slurred speech, convulsions, unconsciousness and death due to circulatory failure.
Aspiration during swallowing or vomiting may cause lung damage.
Chronic Effects of Overexposure: Prolonged occupational overexposure may cause dermatitis. Reports have
associated repeated and prolonged overexposure to petroleum distillates with adverse liver, kidney and bone marrow
effects and with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and
inhaling the product may be harmful or fatal.
Mutagenicity: Diesel fuel was negative in the AMES test and in an in vitro mouse lymphoma assay.
Reproductive Toxicity: In a developmental study with diesel fuel, rats were administered 100 and 400 ppm for 6
hours a day from day 6-15 of gestation. No adverse effects were seen on reproduction or developmental paramental
or in soft tissues or skeletons. NOEAL: 400 ppm
Carcinogenicity: Naphthalene is listed by IARC as “Possibly Carcinogenic to Humans”, Group 2B, as “Reasonably
Anticipated to be a Human Carcinogen” and as a “Confirmed Animal Carcinogen with Unknown Relevance to
Humans”, A3 by ACGIH.
Acute Toxicity Values: Acute Toxicity Estimate: Oral 14492 mg/kg
Diesel Fuel: Oral rat LD50 17900 mg/kg, Inhalation rat LC50 4.1 mg/L/4 hr, Dermal rabbit LD50 >4300 mg/kg
Naphthalene: Oral rat LD50 533 mg/kg, Inhalation rat LC0 0.4 mg/L (highest attainable concentration), Dermal rat LC50
>2500 mg/kg
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity:
Diesel Fuel: 96 hr LL50 Oncorhynchus mykiss 65 mg/kg, 48 hr EL50 > 1000, 72 hr EL50 Pseudokirchnerella subcapitata
10 mg/L
Naphthalene: 96 hr LC50 Pimephales promelas 6.08 mg/L, 48 hr EC50 daphnia magna 2.16 mg/L
Persistence and degradability: Diesel fuel is inherently biodegradable.
Bioaccumulative potential: The bioaccumulation potentials of the major components of diesel fuel range from low to
high. Some higher molecular weight components may be taken up by fish and domestic animals and bioconcentrated
if they persist in environment.
Mobility in soil: No data available.
Other adverse effects: None known.
SECTION 13: DISPOSAL INFORMATION
Renewable Diesel Fuel
August 11, 2021
Page 6 of 7
Waste Disposal Method: Dispose in accordance with all local, state and federal regulations.
SECTION 14: TRANSPORTATION INFORMATION
UN Number Proper shipping name Hazard
Class
Packing
Group
Environmental
Hazard
DOT UN1202 Diesel Fuel 3 PG III No
TDG UN1202 Diesel Fuel 3 PG III No
IMDG UN1202 Diesel Fuel 3 PG III No
IATA UN1202 Diesel Fuel 3 PG III No
Transport in bulk (according to Annex II of MARPOL 73/78 and the IBC Code): Not applicable.
Special precautions: None known.
SECTION 15: REGULATORY INFORMATION
Safety, health, and environmental regulations specific for the product in question.
CERCLA Hazardous Substances (Section 103)/RQ: This product has a Reportable Quantity (RQ) of 3,333 lbs.
(based on the RQ for Naphthalene of 100 lbs). Releases above the RQ must be reported to the National Response
Center. Many states have more stringent release reporting requirements. Report spills required under federal, state
and local regulations.
EPA SARA 311 Hazard Classification: Acute Health, Chronic Health, Fire Hazard
SARA 313: This product contains the following chemicals subject to Annual Release Reporting Requirements Under
SARA Title III, Section 313 (40 CFR 372):
Naphthalene 91-20-3 0-3%
CALIFORNIA PROPOSITION 65: This product contains the following chemicals known to the State of California to cause
cancer or reproductive toxicity.
Naphthalene 91-20-3 0-3% Cancer
WHMIS CLASSIFICATION: Class B, Division 3 (Combustible Liquid), Class D, Division 2A (Very Toxic Material Causing
Other Toxic Effects)
This product has been classified in accordance with the hazard criteria in the CPR and the SDS contains all the
information required by the CPR.
Australia AICS: All of the components are listed on the Australian Inventory of Chemical Substances.
Canada DSL: All of the components are listed on the Canadian Domestic Substances List.
China: All the components are listed on Inventory of Existing Chemical Substances in China.
European EINECS: All of the ingredients are listed on the EINECS inventory.
Korea: All the components are listed on the Korean Existing Chemical List.
Renewable Diesel Fuel
August 11, 2021
Page 7 of 7
New Zealand: All the components are listed on the New Zealand Inventory of Chemicals.
Philippines: All the components are listed on the Philippine Inventory of Chemical and Chemical Substances inventory.
US EPA Toxic Substances Control Act: All of the components of this product are listed on the TSCA inventory.
SECTION 16: OTHER INFORMATION
SDS Revision History: Converted to GHS format – all Sections revised; Updated UN Shipping Numbers
Date of current revision: August 11, 2021
Date of previous revision: July 19, 2018
National
Fire
Protection
Association
(U.S.A)
Health: 2*
Flammability : 2
Instability: 0
Specific Hazard:
Disclaimer: This product material safety data sheet provides health and safety information. The product should be
used in applications consistent with this product literature. For any other uses, exposures should be evaluated so that
appropriate handling practices and training programs can be established to ensure safe workplace operations.
This material safety data sheet is provided in good faith and meets the requirements of the hazardous communication
provisions of SARA TITLE III and 29 CFR 1910.1200(g) of the OSHA regulations. The above information is based on
review of available information Sinclair believes is reliable and is supplied for informational purposes only. Sinclair does not
guarantee its completeness or accuracy. Since conditions of use are outside the control of Sinclair, Sinclair disclaims all
warranties, express or implied, and any liability for damage or injury which results from the use of the above data. Nothing
herein is intended to permit infringement of valid patents and licenses.
HiTEC® 65522 Fuel AdditiveGHS product identifier
Section 1. Identification
:
HiTEC® 65522 Fuel Additive
Safety Data Sheet
SDS no.H65522
In case of emergency - Chemical
0800-70-77-022 (Brazil)
800-681-9531 (Mexico)
+1-703-527-3887 (International)
+1-703-741-5979 (Spanish language)
+1-800-424-9300 (US & Canada)
Manufacturer / Supplier
Afton Chemical Corporation
500 Spring St.
Richmond, VA 23219
USA
Non-Emergency Telephone: +1-804-788-5800
Product use Petrochemical industry: Fuel additive.:
Afton Chemical Canada Corporation
5045 South Service Road
Suite 101
Burlington, ON L7L 5Y7
905-631-5470
Date of issue/Date of revision 11/29/2023
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 3
SKIN IRRITATION - Category 2
CARCINOGENICITY - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
ASPIRATION HAZARD - Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
May be fatal if swallowed and enters airways.
Causes skin irritation.
May cause respiratory irritation.
May cause drowsiness or dizziness.
May cause cancer.
Hazard pictograms :
Precautionary statements
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
HiTEC® 65522 Fuel Additive In Case of Emergency +1-800-424-9300 (US/Canada) +1-703-527-3887 (Int'l)Page: 2/22
Section 2. Hazards identification
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or
in a well-ventilated area. Avoid breathing vapor. Wash thoroughly after handling.
Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or
doctor. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. IF ON SKIN: Wash with plenty of water.
If skin irritation occurs: Get medical advice or attention. In case of fire, use water spray
(fog), foam, dry chemical or CO₂.
Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep
cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Additional hazards :None known.
Section 3. Composition/information on ingredients
Substance/mixture :Mixture
Ingredient name CAS number Conc. (% w/w)US GHS Classification
Solvent naphtha (petroleum), light arom.64742-95-6 ≥35 - ≤45 FLAMMABLE LIQUIDS - Category
3
SPECIFIC TARGET ORGAN
TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) -
Category 3
SPECIFIC TARGET ORGAN
TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
ASPIRATION HAZARD -
Category 1
Polyolefin alkyl phenol alkyl amine (1)Proprietary ≥25 - ≤35 SKIN IRRITATION - Category 2
1,2,4-trimethylbenzene 95-63-6 ≥10 - ≤15 FLAMMABLE LIQUIDS - Category
3
ACUTE TOXICITY (inhalation) -
Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN
TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) -
Category 3
ASPIRATION HAZARD -
Category 1
2-ethylhexanol 104-76-7 ≥5 - ≤7.3 FLAMMABLE LIQUIDS - Category
4
ACUTE TOXICITY (inhalation) -
Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN
TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) -
Category 3
mesitylene 108-67-8 ≥5 - ≤7.1 FLAMMABLE LIQUIDS - Category
3
HiTEC® 65522 Fuel Additive In Case of Emergency +1-800-424-9300 (US/Canada) +1-703-527-3887 (Int'l)Page: 3/22
Section 3. Composition/information on ingredients
Any concentration shown as a range is to protect confidentiality or is due to batch variation. If specific chemical identify is
withheld, it is to protect confidentiality.
Proprietary HMIRA registration number:3541797. Exemption granted date: 25/8/2023
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN
TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) -
Category 3
ASPIRATION HAZARD -
Category 1
1,2,3-trimethylbenzene 526-73-8 ≥1 - ≤1.7 FLAMMABLE LIQUIDS - Category
3
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN
TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) -
Category 3
SPECIFIC TARGET ORGAN
TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
ASPIRATION HAZARD -
Category 1
xylene 1330-20-7 ≥1 - ≤1.7 FLAMMABLE LIQUIDS - Category
3
ACUTE TOXICITY (dermal) -
Category 4
ACUTE TOXICITY (inhalation) -
Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN
TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) -
Category 3
SPECIFIC TARGET ORGAN
TOXICITY (REPEATED
EXPOSURE) - Category 2
ASPIRATION HAZARD -
Category 1
cymene 25155-15-1 ≥0.5 - <1 FLAMMABLE LIQUIDS - Category
3
ACUTE TOXICITY (inhalation) -
Category 3
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
TOXIC TO REPRODUCTION -
Category 2
ASPIRATION HAZARD -
Category 1
cumene 98-82-8 ≥0.3 - ≤0.5 FLAMMABLE LIQUIDS - Category
3
CARCINOGENICITY - Category
1B
SPECIFIC TARGET ORGAN
TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) -
Category 3
ASPIRATION HAZARD -
Category 1
HiTEC® 65522 Fuel Additive In Case of Emergency +1-800-424-9300 (US/Canada) +1-703-527-3887 (Int'l)Page: 4/22
Section 3. Composition/information on ingredients
Occupational exposure limits, if available, are listed in Section 8.
Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting
the upper and lower eyelids. Check for and remove any contact lenses. Continue to
rinse for at least 10 minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly
before reuse. Continue to rinse for at least 15 minutes.
If inhaled, remove to fresh air. If it is suspected that fumes are still present, the rescuer
should wear an appropriate mask or self-contained breathing apparatus. If not
breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a
poison center or physician. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under medical
surveillance for 48 hours. If not breathing, give artificial respiration. If breathing is
difficult, administer oxygen.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.
:Ingestion
Skin contact :Causes skin irritation.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Adverse symptoms may include the following:
irritation
redness
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
HiTEC® 65522 Fuel Additive In Case of Emergency +1-800-424-9300 (US/Canada) +1-703-527-3887 (Int'l)Page: 5/22
Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments :No specific treatment.
Ingestion Adverse symptoms may include the following:
nausea or vomiting
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Runoff to sewer may
create fire or explosion hazard. Fire water contaminated with this material must be
contained and prevented from being discharged to any waterway, sewer or drain.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
In case of fire, use water spray (fog), foam, dry chemical or CO₂.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities.
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not swallow.
Avoid breathing vapor or mist. Avoid release to the environment. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended
exposure limit. At this time, the other constituents have no known exposure limits.
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Section 8. Exposure controls/personal protection
1,2,4-trimethylbenzene ACGIH TLV (United States, 1/2023).
TWA: 10 ppm 8 hours.
2-ethylhexanol ACGIH TLV (United States, 1/2023).
TWA: 5 ppm 8 hours.
mesitylene ACGIH TLV (United States, 1/2023).
[trimethyl benzene, isomers]
TWA: 10 ppm 8 hours.
1,2,3-trimethylbenzene ACGIH TLV (United States, 1/2023).
[trimethyl benzene, isomers]
TWA: 10 ppm 8 hours.
xylene OSHA PEL (United States, 5/2018).
[Xylenes (o-, m-, p-isomers)]
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.
ACGIH TLV (United States, 1/2023). [p-
xylene and mixtures containing p-xylene]
Ototoxicant.
TWA: 20 ppm 8 hours.
cumene ACGIH TLV (United States, 1/2023).
TWA: 5 ppm 8 hours.
OSHA PEL (United States, 5/2018).
Absorbed through skin.
TWA: 50 ppm 8 hours.
TWA: 245 mg/m³ 8 hours.
Ingredient name Exposure limits
Hand protection Hand Protection: Wear chemical resistant gloves. Nitrile gloves of minimum thickness
0.4 mm have an expected breakthrough time of 30 minutes or less when in frequent
contact with the product. Due to variable exposure conditions the user must consider
that the practical use of a chemical-protective glove in practice may be much shorter
than the permeation time above. Manufacturer’s directions for use, especially about the
minimum thickness and the minimum breakthrough time, must be observed. This
information does not replace suitability tests by the end user since glove protection
varies depending on the conditions under which the product is used.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
:
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
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Section 8. Exposure controls/personal protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Respiratory protection :
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Liquid. [Amber.]
Not available.
0.9009
Not available.
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 43°C (109.4°F) [Minimum Pensky-Martens]
Not applicable.
Not available.
Viscosity
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :Not available.
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
Density :0.8996 g/cm³ [60.1°F (15.6°C)]
Explosive properties :Not available.
Not available.:Oxidizing properties
Kinematic (40°C (104°F)): 10 mm2/s (10 cSt)Minimum
Solubility(ies):Not available.
Section 10. Stability and reactivity
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
The product is stable.Chemical stability :
:
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
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Section 10. Stability and reactivity
Hazardous decomposition
products
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Reactive or incompatible with the following materials:
oxidizing materials
:
Incompatible materials :
Section 11. Toxicological information
Acute toxicity
Solvent naphtha (petroleum),
light arom.
403 Acute
Inhalation
Toxicity
LC50 Inhalation
Vapor
Rat >6193 mg/m³4 hours -
402 Acute
Dermal Toxicity
LD50 Dermal Rabbit >3160 mg/kg --
None available.LD50 Oral Rat -
Female
3492 mg/kg --
None available.LD50 Oral Rat -
Male
6984 mg/kg --
1,2,4-trimethylbenzene None available.LC50 Inhalation
Vapor
Rat >10200 mg/m³4 hours Based on data
for a similar
substance.
None available.LD50 Dermal Rat >3440 mg/kg -Based on data
for a similar
substance.
None available.LD50 Oral Rat 6000 mg/kg --
2-ethylhexanol 403 Acute
Inhalation
Toxicity
LC50 Inhalation
Dusts and mists
Rat 1 to 5.3 mg/l 4 hours -
None available.LC50 Inhalation
Vapor
Rat >0.89 mg/l 4 hours -
None available.LD50 Dermal Rat 1970 mg/kg -WOE does not
support
classification
401 Acute Oral
Toxicity
LD50 Oral Rat 2047 mg/kg --
mesitylene None available.LC50 Inhalation
Vapor
Rat >10.2 mg/l 4 hours Based on data
for a similar
substance.
None available.LD50 Dermal Rat >3440 mg/kg -Based on data
for a similar
substance.
None available.LD50 Oral Rat >5000 mg/kg --
1,2,3-trimethylbenzene None available.LC50 Inhalation
Vapor
Rat 24 mg/l 4 hours -
None available.LD50 Oral Rat 5000 mg/kg --
xylene 403 Acute
Inhalation
Toxicity
LC50 Inhalation
Vapor
Rat 29 mg/l 4 hours -
None available.LD50 Dermal Rabbit 12126 mg/kg -Based on data
for a similar
substance.
None available.LD50 Oral Rat -
Male
3523 mg/kg --
cymene None available.LD50 Dermal Rabbit >5000 mg/kg -Based on data
for a similar
substance.
None available.LD50 Oral Rat 4750 mg/kg -Based on data
for a similar
substance.
Product/ingredient name Result Species Dose Exposure
Information on toxicological effects
RemarksTest
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Section 11. Toxicological information
cumene None available.LD50 Dermal Rabbit >10000 mg/kg --
None available.LD50 Oral Rat 2260 mg/kg --
Conclusion/Summary :
Irritation/Corrosion
Solvent naphtha (petroleum),
light arom.
405 Acute Eye
Irritation/Corrosion
Rabbit Eyes - Not irritant -
None available.Rabbit Skin - Mild irritant -
Polyolefin alkyl phenol alkyl
amine (1)
405 Acute Eye
Irritation/Corrosion
Rabbit Eyes - Not irritant Based on data for a
similar substance.
404 Acute Dermal
Irritation/Corrosion
Rabbit Skin - Irritant Based on data for a
similar substance.
1,2,4-trimethylbenzene None available.Rabbit Skin - Irritant Based on data for a
similar substance.
2-ethylhexanol 405 Acute Eye
Irritation/Corrosion
Rabbit Eyes - Irritant -
404 Acute Dermal
Irritation/Corrosion
Rabbit Skin - Irritant -
mesitylene 405 Acute Eye
Irritation/Corrosion
Rabbit Eyes - Irritant Based on data for a
similar substance.
None available.Rabbit Skin - Irritant -
xylene None available.Rabbit Eyes - Irritant -
None available.Rabbit Skin - Irritant -
cymene 405 Acute Eye
Irritation/Corrosion
Rabbit Eyes - Irritant Based on data for a
similar substance.
None available.Rabbit Skin - Irritant Based on data for a
similar substance.
cumene 405 Acute Eye
Irritation/Corrosion
Rabbit Eyes - Not irritant -
404 Acute Dermal
Irritation/Corrosion
Rabbit Skin - Not irritant -
Product/ingredient name Result
Conclusion/Summary
Skin :
Eyes :
Respiratory :
Sensitization
Solvent naphtha (petroleum),
light arom.
406 Skin
Sensitization
skin Guinea pig Not
sensitizing
-
Polyolefin alkyl phenol alkyl
amine (1)
406 Skin
Sensitization
skin Guinea pig Not
sensitizing
-
1,2,4-trimethylbenzene 406 Skin
Sensitization
skin Guinea pig Not
sensitizing
Based on data for a
similar substance.
mesitylene 406 Skin
Sensitization
skin Guinea pig Not
sensitizing
Based on data for a
similar substance.
xylene 429 Skin
Sensitization: Local
Lymph Node Assay
skin Mouse Not
sensitizing
-
cymene None available.skin Guinea pig Not
sensitizing
Based on data for a
similar substance.
cumene 406 Skin
Sensitization
skin Guinea pig Not
sensitizing
-
Product/ingredient name Route of
exposure
Species Result
Conclusion/Summary
Skin :
Respiratory :
Species Remarks
RemarksTest
Test
Not available.
May cause respiratory irritation.
Not available.
Causes skin irritation.
Not available.
Not available.
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Section 11. Toxicological information
Carcinogenicity
Mutagenicity
Solvent naphtha (petroleum),
light arom.
471 Bacterial Reverse
Mutation Test
Experiment: In vitro
Subject: Bacteria
Negative -
476 In vitro Mammalian
Cell Gene Mutation Test
Experiment: In vitro
Subject: Mammalian-Animal
Negative -
1,2,4-trimethylbenzene 471 Bacterial Reverse
Mutation Test
Experiment: In vitro
Subject: Bacteria
Negative -
476 In vitro Mammalian
Cell Gene Mutation Test
Experiment: In vitro
Subject: Mammalian-Animal
Negative Based on data for a
similar substance.
2-ethylhexanol 471 Bacterial Reverse
Mutation Test
Experiment: In vitro
Subject: Bacteria
Negative -
473 In vitro Mammalian
Chromosomal Aberration
Test
Experiment: In vitro
Subject: Mammalian-Animal
Negative -
mesitylene 471 Bacterial Reverse
Mutation Test
Experiment: In vitro
Subject: Bacteria
Negative -
476 In vitro Mammalian
Cell Gene Mutation Test
Experiment: In vitro
Subject: Mammalian-Animal
Negative Based on data for a
similar substance.
1,2,3-trimethylbenzene None available.Experiment: In vitro
Subject: Bacteria
Positive WOE does not
support
classification
None available.Experiment: In vitro
Subject: Bacteria
Negative -
None available.Experiment: In vitro
Subject: Mammalian-Animal
Equivocal -
None available.Experiment: In vivo
Subject: Mammalian-Animal
Positive WOE does not
support
classification
None available.Experiment: In vivo
Subject: Mammalian-Animal
Negative -
xylene 471 Bacterial Reverse
Mutation Test
Experiment: In vitro
Subject: Bacteria
Negative -
None available.Experiment: In vitro
Subject: Mammalian-Animal
Negative -
cymene 471 Bacterial Reverse
Mutation Test
Experiment: In vitro
Subject: Bacteria
Negative Based on data for a
similar substance.
476 In vitro Mammalian
Cell Gene Mutation Test
Experiment: In vitro
Subject: Mammalian-Animal
Negative Based on data for a
similar substance.
473 In vitro Mammalian
Chromosomal Aberration
Test
Experiment: In vitro
Subject: Mammalian-Human
Negative Based on data for a
similar substance.
cumene 471 Bacterial Reverse
Mutation Test
Experiment: In vitro
Subject: Bacteria
Negative -
None available.Experiment: In vitro
Subject: Mammalian-Animal
Negative -
474 Mammalian
Erythrocyte Micronucleus
Test
Experiment: In vivo
Subject: Mammalian-Animal
Equivocal -
Product/ingredient name Test Experiment Result
Conclusion/Summary :
Remarks
Not available.
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Section 11. Toxicological information
Solvent naphtha (petroleum),
light arom.
451 Carcinogenicity
Studies
Rat 113
months; 5
days per
week
Negative -
Inhalation -
NOAEL
-
2-ethylhexanol 451 Carcinogenicity
Studies
Mouse 18 months;
5 days per
week
Negative -
Oral -
NOAEL
-
451 Carcinogenicity
Studies
Rat 24 months;
5 days per
week
Negative -
Oral -
NOAEL
-
xylene None available.Rat 103 weeks;
5 days per
week
Negative -
Oral -
NOAEL
-
cumene 451 Carcinogenicity
Studies
Rat 105 weeks;
6 hours
per day
Positive -
Inhalation -
TC
-
Product/ingredient name Species Exposure
Conclusion/Summary :
Reproductive toxicity
Product/ingredient
name
Maternal
toxicity
Fertility Development
toxinSpecies
Conclusion/Summary :
Solvent naphtha
(petroleum), light arom.
None available.Inhalation Rat Negative Negative Negative -
Polyolefin alkyl phenol
alkyl amine (1)
421 Reproduction/
Developmental
Toxicity Screening
Test
Oral Rat Positive Negative Negative Based on
data for a
similar
substance.
1,2,4-trimethylbenzene 416 Two-
Generation
Reproduction
Toxicity Study
Inhalation Rat Positive Negative Negative Based on
data for a
similar
substance.
2-ethylhexanol 416 Two-
Generation
Reproduction
Toxicity Study
Oral Rat Negative Negative Negative -
mesitylene 416 Two-
Generation
Reproduction
Toxicity Study
Inhalation Rat Positive Negative Negative Based on
data for a
similar
substance.
1,2,3-trimethylbenzene None available.Inhalation Rat -Equivocal Equivocal -
xylene None available.Inhalation Rat -
Male
Positive Equivocal Negative WOE does
not support
classification
cymene 422 Combined
Repeated Dose
Toxicity Study with
the Reproduction/
Developmental
Toxicity Screening
Test
Oral Rat Positive Positive Positive Based on
data for a
similar
substance.
cumene 413 Subchronic
Inhalation Toxicity:
90-day Study
Inhalation Rat Positive Negative Negative -
Classification
xylene -3 -
cumene -2B Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Test Result Remarks
Test RemarksRoute of
exposure
Not available.
May cause cancer.
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Section 11. Toxicological information
Teratogenicity
Solvent naphtha (petroleum),
light arom.
None available.Rabbit Negative -
Inhalation
Based on data for a
similar substance.
None available.Rat Negative -
Inhalation
Based on data for a
similar substance.
1,2,4-trimethylbenzene 414 Prenatal Developmental
Toxicity Study
Rat Negative -
Inhalation
-
2-ethylhexanol 414 Prenatal Developmental
Toxicity Study
Rat Negative - Dermal -
414 Prenatal Developmental
Toxicity Study
Rat Negative -
Inhalation
-
414 Prenatal Developmental
Toxicity Study
Mouse Negative - Oral -
mesitylene 414 Prenatal Developmental
Toxicity Study
Rat Negative -
Inhalation
-
1,2,3-trimethylbenzene None available.Rat Equivocal -
Inhalation
Based on data for a
similar substance.
xylene 414 Prenatal Developmental
Toxicity Study
Rat Negative -
Inhalation
-
cumene 414 Prenatal Developmental
Toxicity Study
Rabbit Negative -
Inhalation
-
414 Prenatal Developmental
Toxicity Study
Rat Negative -
Inhalation
-
Product/ingredient name ResultSpecies
Conclusion/Summary :Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Solvent naphtha (petroleum), light arom.Category 3 -Respiratory tract
irritation
Category 3 Narcotic effects
1,2,4-trimethylbenzene Category 3 -Respiratory tract
irritation
2-ethylhexanol Category 3 -Respiratory tract
irritation
mesitylene Category 3 -Respiratory tract
irritation
1,2,3-trimethylbenzene Category 3 -Respiratory tract
irritation
Category 3 Narcotic effects
xylene Category 3 -Respiratory tract
irritation
cumene Category 3 -Respiratory tract
irritation
Name Category
Name Category
xylene Category 2 --
Aspiration hazard
Solvent naphtha (petroleum), light arom.ASPIRATION HAZARD - Category 1
1,2,4-trimethylbenzene ASPIRATION HAZARD - Category 1
mesitylene ASPIRATION HAZARD - Category 1
1,2,3-trimethylbenzene ASPIRATION HAZARD - Category 1
xylene ASPIRATION HAZARD - Category 1
cymene ASPIRATION HAZARD - Category 1
cumene ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
Test Remarks
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Section 11. Toxicological information
Solvent naphtha (petroleum),
light arom.
None available.Rat 353 ppm 13
weeks; 6
hours
per day
Sub-chronic
LOAEL
Inhalation
Vapor
-
408 Repeated Dose
90-Day Oral Toxicity
Study in Rodents
Rat 600 mg/kg -Sub-chronic
NOAEL Oral
Based on data
for a similar
substance.
452 Chronic Toxicity
Studies
Rat 900 mg/m³12
months;
6 hours
per day
Chronic
NOAEL
Inhalation
Vapor
-
Polyolefin alkyl phenol alkyl
amine (1)
421 Reproduction/
Developmental
Toxicity Screening
Test
Rat 100 mg/kg -Sub-acute
NOAEL Oral
Based on data
for a similar
substance.
1,2,4-trimethylbenzene 408 Repeated Dose
90-Day Oral Toxicity
Study in Rodents
Rat 600 mg/kg -Sub-chronic
NOAEL Oral
Based on data
for a similar
substance.
Product/ingredient name ResultSpeciesDoseExposure
Information on the likely
routes of exposure
Inhalation :Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.
:Ingestion
Skin contact :Causes skin irritation.
No known significant effects or critical hazards.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Adverse symptoms may include the following:
nausea or vomiting
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
:
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
Skin, Eyes, Ingestion, and Inhalation
RemarksTest
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Section 11. Toxicological information
452 Chronic Toxicity
Studies
Rat 1800 mg/
m³
12
months
Chronic
NOAEL
Inhalation
Vapor
Based on data
for a similar
substance.
2-ethylhexanol 408 Repeated Dose
90-Day Oral Toxicity
Study in Rodents
Rat 250 mg/kg -Sub-chronic
NOAEL Oral
-
413 Subchronic
Inhalation Toxicity:
90-day Study
Rat 640 mg/m³90 days Sub-chronic
NOAEL
Inhalation
Vapor
-
408 Repeated Dose
90-Day Oral Toxicity
Study in Rodents
Rat 125 mg/kg -Sub-chronic
NOEL Oral
-
mesitylene 408 Repeated Dose
90-Day Oral Toxicity
Study in Rodents
Rat 600 mg/kg -Sub-chronic
NOAEL Oral
-
413 Subchronic
Inhalation Toxicity:
90-day Study
Rat 1.23 mg/l 3 months Sub-chronic
NOAEL
Inhalation
Vapor
Based on data
for a similar
substance.
1,2,3-trimethylbenzene None available.Rat 25 ppm 4 weeks Sub-acute
LOAEL
Inhalation
Vapor
-
None available.Rat 30 mg/kg 28 days Sub-acute
NOAEL Oral
-
None available.Rat 123 mg/m³3 months Sub-chronic
NOAEL
Inhalation
Vapor
-
xylene 408 Repeated Dose
90-Day Oral Toxicity
Study in Rodents
Rat 150 mg/kg -Sub-chronic
LOAEL Oral
-
None available.Rat 3.5 mg/l 13 weeks Sub-chronic
NOAEL
Inhalation
Vapor
-
cymene 422 Combined
Repeated Dose
Toxicity Study with
the Reproduction/
Developmental
Toxicity Screening
Test
Rat 50 mg/kg -Sub-acute
NOAEL Oral
Based on data
for a similar
substance.
None available.Rat 1.23 mg/l 4 weeks;
6 hours
per day
Sub-acute
NOAEL
Inhalation
Vapor
Based on data
for a similar
substance.
cumene None available.Rat 535.8 mg/
kg
-Sub-chronic
NOAEL Oral
-
413 Subchronic
Inhalation Toxicity:
90-day Study
Rat 125 ppm 90 days Sub-chronic
NOAEL
Inhalation
Vapor
-
Conclusion/Summary :Not available.
No known significant effects or critical hazards.General :
May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
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Section 11. Toxicological information
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Section 12. Ecological information
Toxicity
Solvent naphtha (petroleum),
light arom.
Acute EL50 3.1 mg/l Algae - Raphidocelis subcapitata 72 hours -
Acute EL50 4.5 mg/l Daphnia - Daphnia magna 48 hours Based on data
for a similar
substance.
Acute LL50 8.2 mg/l Fish - Pimephales promelas 96 hours Based on data
for a similar
substance.
Chronic NOEC 0.4
mg/l
Daphnia - Daphnia magna 21 days Based on data
for a similar
substance.
Chronic NOEL 0.5
mg/l
Algae - Raphidocelis subcapitata 72 hours -
Chronic NOEL 2.6
mg/l
Fish - Pimephales promelas 14 days Based on data
for a similar
substance.
Polyolefin alkyl phenol alkyl
amine (1)
Acute EC50 5.4 mg/l Algae 96 hours Based on data
for a similar
substance.
Chronic NOEC 3.65
mg/l
Algae 96 hours Based on data
for a similar
substance.
Chronic NOEC 3.38
mg/l
Daphnia 21 days Based on data
for a similar
substance.
1,2,4-trimethylbenzene Acute LC50 3.6 mg/l Daphnia - Daphnia magna 48 hours -
Acute LC50 7.72 mg/l Fish - Pimephales promelas 96 hours -
2-ethylhexanol Acute EC50 39 mg/l Daphnia - Daphnia magna 48 hours -
Acute EL50 16.6 mg/l Algae - Desmodesmus
subspicatus
72 hours -
Acute LC50 17.1 mg/l Fish - Leuciscus idus melanotus 96 hours -
Chronic EL10 5.3 mg/
l
Algae - Desmodesmus
subspicatus
72 hours -
mesitylene Acute EC50 53 mg/l Algae - Desmodesmus
subspicatus
48 hours -
Acute LC50 6 mg/l Crustaceans - Daphnia magna 48 hours -
Acute LC50 12.52
mg/l
Fish - Carassius auratus 96 hours -
Chronic EC10 16 mg/
l
Algae - Desmodesmus
subspicatus
48 hours -
Chronic NOEC 0.4
mg/l
Crustaceans - Daphnia magna 21 days -
1,2,3-trimethylbenzene Acute EC50 4.4 mg/l Algae - Pseudokirchneriella
subcapitata
72 hours -
Acute EC50 2.7 mg/l Daphnia - Daphnia magna 48 hours -
Acute LC50 7.8 mg/l Fish - Oryzias latipes 96 hours -
Chronic NOEC 1.9
mg/l
Algae - Pseudokirchneriella
subcapitata
72 hours -
xylene EL50 >157 mg/l Micro-organism 3 hours Based on data
for a similar
substance.
Acute EC50 4.36 mg/l Algae - Raphidocelis subcapitata 73 hours Based on data
for a similar
substance.
Acute EC50 >3.4 mg/Crustaceans - Ceriodaphnia 48 hours Based on data
Product/ingredient name Result Exposure RemarksSpecies
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Section 12. Ecological information
l dubia for a similar
substance.
Acute LC50 2.6 mg/l Fish - Oncorhynchus mykiss 96 hours Based on data
for a similar
substance.
Chronic EC10 1.9
mg/l
Algae - Raphidocelis subcapitata 73 hours Based on data
for a similar
substance.
Chronic EC10 1.91
mg/l
Crustaceans - Daphnia magna 21 days Based on data
for a similar
substance.
Chronic NOEC 0.714
mg/l
Fish - Danio rerio 35 days Based on data
for a similar
substance.
cymene Acute EC50 5.8 mg/l Algae 72 hours Based upon data
for a similar
product.
Acute EC50 1.9 mg/l Daphnia 48 hours Based on data
for a similar
substance.
Acute LC50 2 mg/l Fish 96 hours Based on data
for a similar
substance.
Chronic NOEC 0.48
mg/l
Algae 72 hours Based on data
for a similar
substance.
Chronic NOEC 0.46
mg/l
Daphnia - Daphnia magna 21 days Based on data
for a similar
substance.
Chronic NOEC 0.69
mg/l
Fish -Based on data
for a similar
substance.
cumene EC50 >2000 mg/l Micro-organism 3 hours -
Acute EC50 2.01 mg/l Algae - Desmodesmus
subspicatus
72 hours -
Acute EC50 2.14 mg/l Crustaceans - Daphnia magna 48 hours -
Acute EC50 10.6 mg/
l Fresh water
Daphnia - Daphnia magna -
Neonate
48 hours -
Acute LC50 4.8 mg/l Fish - Oncorhynchus mykiss 96 hours -
Chronic EC10 1.35
mg/l
Algae - Desmodesmus
subspicatus
72 hours -
Chronic NOEC 0.35
mg/l
Crustaceans - Daphnia magna 21 days QSAR result.
Chronic NOEC 0.38
mg/l
Fish - D. rerio and P. promelas 28 days QSAR result.
Conclusion/Summary :
Persistence and degradability
2-ethylhexanol OECD 301C
Ready
Biodegradability -
Modified MITI
Test (I)
100 % - Readily - 14 days -
mesitylene -42 % - Not readily - 28 days -
1,2,3-trimethylbenzene -42 % - Not readily - 28 days Based on data for a similar
substance.
xylene OECD 301F
Ready
Biodegradability -
Manometric
Respirometry
87.8 % - Readily - 28 days Based on data for a similar
substance.
Product/ingredient name Test Result Remarks
Toxic to aquatic life with long lasting effects.
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
Solvent naphtha (petroleum),
light arom.
-10 to 2500 high
1,2,4-trimethylbenzene 3.63 243 low
2-ethylhexanol 2.9 25.33 low
mesitylene 3.42 161 low
1,2,3-trimethylbenzene 3.66 194.98 low
xylene 3.12 8.1 to 25.9 low
cymene 4.1 -high
cumene 3.55 35.48 low
Test
cumene -70 % - Readily - 20 days -
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
United States - RCRA Toxic hazardous waste "U" List
Xylene 1330-20-7 Listed U239
Ingredient CAS #Status Reference
number
Section 14. Transport information
3
III
3
III
Flammable liquid, n.o.
s. (Solvent naphtha,
Trimethylbenzenes)
UN1993
3
III
UN1993
TDG Classification IMDG IATA
UN number
UN proper
shipping name
Transport hazard
class(es)
Packing group
Environmental
hazards
Yes.Yes.Yes.
DOT Classification
Combustible liquid.
III
No.
Combustible liquid, n.
o.s. (Solvent naphtha,
Trimethylbenzenes)
Flammable liquid, n.o.
s. (Solvent naphtha,
Trimethylbenzenes)
Marine pollutant
NA1993 UN1993
Flammable liquid, n.o.
s. (Solvent naphtha,
Trimethylbenzenes)
Marine pollutant
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Section 14. Transport information
Notice to reader
Transport in bulk according
to IMO instruments
:Not available.
:
Special precautions for user :Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do
in the event of an accident or spillage.
The above transport information is provided to assist in the proper classification of
this product and may not be suitable for all shipping conditions.
Section 15. Regulatory information
SARA 302/304
SARA 304 RQ :16524548.1 lbs / 7502144.8 kg [2203042.5 gal / 8339422.9 L]
Composition/information on ingredients
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 3
SKIN IRRITATION - Category 2
CARCINOGENICITY - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
ASPIRATION HAZARD - Category 1
Composition/information on ingredients
TSCA 5(a)2 final significant new use rules
Polyalkenylalkylphenol P-99-0472 40 CFR 721.545
TSCA 5(a)2 proposed significant new use rules
None of the components are listed.
TSCA 5(e) substance consent order
None of the components are listed.
United States - TSCA 12(b) - Chemical export notification
StatusName on list Ref. number
Formaldehyde, reaction product with an alkylated phenol and an aliphatic amine One time notification P-01-0629
U.S. Federal regulations
CERCLA :CERCLA: Hazardous substances.: benzene: 10 lbs. (4.54 kg); cumene: 5000 lbs. (2270 kg); xylene: 100 lbs.
(45.4 kg); ethylbenzene: 1000 lbs. (454 kg); naphthalene: 100 lbs. (45.4 kg); potassium hydroxide: 1000 lbs.
(454 kg); 1-methylnaphthalene: No RQ is being assigned to the generic or broad class.; 2-methylnaphthalene:
No RQ is being assigned to the generic or broad class.; propylene oxide: 100 lbs. (45.4 kg); furan: 100 lbs.
(45.4 kg); acetaldehyde: 1000 lbs. (454 kg); o-cresol: 100 lbs. (45.4 kg); phenol: 1000 lbs. (454 kg);
o-cresol ≤0.001 Yes.1000 /
10000
-100 -
furan ≤0.001 Yes.500 64.1 100 12.8
propylene oxide ≤0.001 Yes.10000 1444.3 100 14.4
phenol ≤0.00001 Yes.500 / 10000 -1000 -
Name %EHS (lbs)(lbs)(gallons)(gallons)
SARA 302 TPQ SARA 304 RQ
None of the components are listed.
TSCA 6 final risk management
United States - TSCA Section 5
United States - TSCA Section 6
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Section 15. Regulatory information
SARA 313
Solvent naphtha (petroleum),
light arom.
≥35 - ≤45 FLAMMABLE LIQUIDS - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
ASPIRATION HAZARD - Category 1
HNOC - Static-accumulating flammable liquid
Polyolefin alkyl phenol alkyl
amine (1)
≥25 - ≤35 SKIN IRRITATION - Category 2
1,2,4-trimethylbenzene ≥10 - ≤15 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
ASPIRATION HAZARD - Category 1
2-ethylhexanol ≥5 - ≤7.3 FLAMMABLE LIQUIDS - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
mesitylene ≥5 - ≤7.1 FLAMMABLE LIQUIDS - Category 3
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
ASPIRATION HAZARD - Category 1
1,2,3-trimethylbenzene ≥1 - ≤1.7 FLAMMABLE LIQUIDS - Category 3
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
ASPIRATION HAZARD - Category 1
xylene ≥1 - ≤1.7 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
cymene ≥0.5 - <1 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 3
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
TOXIC TO REPRODUCTION - Category 2
ASPIRATION HAZARD - Category 1
cumene ≥0.3 - ≤0.5 FLAMMABLE LIQUIDS - Category 3
CARCINOGENICITY - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
ASPIRATION HAZARD - Category 1
Name %Classification
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Section 15. Regulatory information
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
1,2,4-trimethylbenzene 95-63-6 ≥10 - ≤15
xylene 1330-20-7 ≥1 - ≤1.7
cumene 98-82-8 ≥0.3 - ≤0.5
Form R - Reporting
requirements
International Inventory Status
Canadian regulations
State - California Prop. 65
Canada Significant New
Activity Notice
:None of the components are listed.
WARNING: This product contains a chemical known to the State of California to cause cancer.
WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects
or other reproductive harm.
The following components are listed: light aromatic solvent naphtha;
1,2,4-trimethylbenzene; xylene (all isomers)
Canadian NPRI :
CEPA Toxic
substances
:None of the components are listed.
cumene ≥0.3 - ≤0.5 Yes.No.--
Benzene <0.1 Yes.Yes.Yes.Yes.
Naphthalene ≤0.01 Yes.No.Yes.-
Ethylbenzene ≤0.01 Yes.No.Yes.-
Furan ≤0.001 Yes.No.--
Propylene oxide ≤0.001 Yes.No.--
acetaldehyde ≤0.0001 Yes.No.Yes.-
Ingredient name Cancer Reproductive No significant
risk level
Maximum
acceptable
dosage level
%
www.P65Warnings.ca.gov.
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
Europe (REACh):
Canada (DSL/NDSL):
Australia (AIIC):
China (IECSC):
For information on compliance with this regulation please contact your Afton representative
(EHS.CustomerVolumes@AftonChemical.com).
Japan (ENCS):
New Zealand (NZIoC):All components are listed or exempted.
Republic of Korea
(ECL)
:At least one component is not listed.
Philippines (PICCS):All components are listed or exempted.
Taiwan (TCSI):All components are listed or exempted.
United States Active
(TSCA)
:All components are active or exempted.
All components are listed or exempted.
Switzerland (SWISS):
Turkey (KKDIK):
United Kingdom (UK
REACh)
:
For information on compliance with this regulation please contact your Afton representative
(EHS.CustomerVolumes@AftonChemical.com).
For information on compliance with this regulation please contact your Afton representative
(EHS.CustomerVolumes@AftonChemical.com).
For information on compliance with this regulation please contact your Afton representative
(EHS.CustomerVolumes@AftonChemical.com).
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Section 16. Other information
History
Date of issue/Date of
revision
Prepared by
Notice to reader
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
WOE = Weight of Evidence
11/29/2023
This information and these recommendations are offered in good faith and believed to be correct as of the date hereof. Information and
recommendations are supplied upon the condition that the recipients will make their own decision as to safety and suitability for their purposes.
No representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose, or of any other nature, are
made with respect to the product or the information and recommendations. Afton makes no representation as to completeness or accuracy. In
no event will Afton be responsible for damages of any nature whatsoever resulting from the use or reliance upon the information and
recommendations.
EHS Department (Tel: +1 804 788 5800)