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DSHW-2010-046727 - 0901a068801d95e8
HAND DELIVERED NOV 0 3 20t0 UTAH DIVISION OF SOLID & HAZARDOUS WASTE ^010,O^H^"^ TOCDF Response to Division of Solid and Hazardous Waste (DSHW) Concerning Permit Modification Request TOCDF-DAVINCH-03-1117 (DSHW Tracking Number 2010 01938) REPLY TO ATTENTION OF DEPARTMENT OF THE ARMY US ARMY CHEMICALS MATERIAL AGENCY TOOELE CHEMICAL AGENT DISPOSAL FACILITY 11620 STARK ROAD STOCKTON, UT 84071 Tooele Chemical Agent Disposal Facility NOV 03 2010 HAND DELIVERED my 0 3 2010 UTAH DIVJSION OF SOLID & HAZARDOUS WASTE ^010.03^^8- PM0831-10 Mr Scott Anderson Director, Utah Department of Environmental Quality Division of Solid and Hazardous Waste PO Box 144880 195 North 1950 West Salt Lake City, Utah 841 14-4880 SUBJECT Tooele Chemical Agent Disposal Facility (TOCDF) Response to State of Utah Division of Solid and Hazardous Waste (DSHW) Concerning Permit Modification Request TOCDF-DAVINCH- 03-1 117 (DSHW TrackingNumber 2010 01938), EPA ID UT5210090002 Dear Mi Anderson Please find enclosed the response to comments received from DSHW concerning Permit Modificanon Request TOCDF-DAVINCH-03-11 17 which is titled "Install and Operate Explosive Destruction Technology Subpart X Unit in Aiea 10" Also enclosed is a compact disc containing electronic files of the TOCDF Resource Consei vation and Recovery Act Permit change pages, a redlined version of the Destruction Plan, which incorporates the comment responses, and Process and Instrumentation Drawings that have been reviewed by a Utah Certified Professional Engineei Note the following • TOCDF concurs with the DSHW recommendation to operate two Near Real Time Monitors in staggeied mode at the Detonation of Ammunition in a Vacuum Integrated Chambei (DAVINCH) Pollution Abatement System PMI sampling location, the monitoring location prior to the inlet of the Retention Tank • TOCDF intends to submit the analytical procedures listed in the response to DSHW comment # 11 These procedures will be submitted to DSHW for appioval by the Executive Secretary • The DSHW lettei dated September 7, 2010 that transmitted the comments to the TOCDF discussed the need to conduct stack testing Based on meetings held with DSHW, TOCDF proposes the following test format DAVINCH exhaust gas resulting from the detonation of single ovei packed 155iTim H Piojectiles will be analyzed foi concentrations of Caibon Dioxide, Cai bon Monoxide, Sulfur Dioxide, Nitrogen Oxides, Total Hydiocarbons, and Oxygen using an array of Continuous Emission Momtoiing Systems Exhaust gas concentrations of Volatile Oi game Compounds will be evaluated using a Fouriei Tiansfoim Infia Red Spectroscopy 155mm H Projectiles aie selected Recycled Paper PM0831-10 as the test case because it is duiing their processing when the maximum agent and explosive weights are present in the DAVINCH Detonation Chamber DAVINCH exhaust gas will be evaluated over the period of at least four separate detonations Samples of ash and condensate will be taken from the Detonation Chamber The solid samples will be analyzed for dioxins, explosives, and chloride content The liquid samples will be analyzed for explosives and chlorides A set of samples will be collected at the end of the day DAVINCH exhaust gas resulting from the detonation of overpacked 4 2-inch HD Mortars will be evaluated for Mercury (Hg) concentrations using the TOCDF Hg Process Monitor (MPM) which IS based on Environmental Protection Agency Reference Method 308 The MPM was used throughout the Mustard non-Baseline Ton Container Campaign to evaluate TOCDF incinerator Hg exhaust gas concentiatioiis Exhaust gas sample will be evaluated using the MPM for one day during the processing of the HD mortars HD mortars are selected because they contain the highest concentrations of Hg in their fill DAVINCH exhaust gas will be evaluated for a single day because the all the HD mortals that will be processed in the DAVINCH will be processed in one day Note HD mortars will be processed toward the end of DAVINCH operations at TOCDF to limit the amount of exhaust gas that will pass through the DAVINCH Pollution Abatement System sulfur impregnated carbon filter bed after it is exposed to Hg This sampling approach requires two separate sampling periods that will occur perhaps months apart (i e , one sampling period when processing 155min H Projectiles, and one period when processing 4 2-inch HD mortars) TOCDF will provide the DSHW will a test plan that will specify the sampling locations, test methods, and their associated quality objectives 60 days prior to the date of the first sampling period which is tentatively scheduled for early June or July of 2011 The points of contact in this matter are Ms Sheila R Vance at (435) 833-7577 or Mr Trace Salmon at (435) 833-7428 Sincerely, Elizabeth A Lowes EG&G Defense Materials, Inc "CERTIFICATION STATEMENT Thaddeus A Ryba, Jr TOCDF Site Project Manager "CERTIFICATION STATEMENT Enclosure • 1 CERTIFY UNDER PENALTY OF LAW THAT THIS DOCUMENT AND ALL ATTACHMENT S WERE I REPARED UNDER MY DIRECTION OR SUPERVISION IN ACCORDANCE WITH A S^ STEM DESIGNED TO ASSURE THA r QUALIFIED PERSONNEL PROPERLY GATHER AND EVALUATE THE INFORMATION SUBMl FTFD BASED ON MY INQUIRY OF THE PERSON OR PERSONS WHO MANAGE THE SYSTEM OR THOSE PERSONS DIRECTLY RESPONSIBLE FOR GATHERING THE INFORMATION THE INFORMATION SUBMITTED IS TO THE BEST OF MY KNOWLEDGE AND BELIEF TRUE ACCURATE AND COMPLETE I AM AWARE THAT THERE ARE SIGNIFICANT PENALTIES FOR SUBMITTING FALSE INFORMATION INCLUDING THE POSSIBILITY OF FINE AND IMPRISONMENT FOR KNOWING VIOLATIONS HAND DELIVERED DAVINCH EDT Modification Review Comments NOV 0 3 2010 fi*otu The Utah Division of Sohd and Hazardous Waste SOLIO^&'HAZI^DOUS^W^ 1 On page 6, midway through the paragraph, it states that wipe samples were taken off the munition fragments and the interior of the detonation chamber but it does not report the results Please provide the results of the sampling and analysis Please be aware that wipe sampling is currently not accepted by the Division as an appropriate method for verification of decontamination and an alternate method will need to be placed in all DAVINCH documents Please provide all available analytical data from past DAVINCH operations to support the statement that the DAVINCH is a proven technology such as analysis of residues and air monitoring data The wipe samples results were used to develop a Destruction Efficiency for the mustard surrogates used during the testing The data was provided with the permit modification request This information can be found on pages 33 through 47 of Attachment 2 to the permit modification request 2 On page 8, in the last paragraph, it states that detonation chamber off-gas is sampled both upstream and downstream from the cold plasma oxidizers How and where is the off-gas sampled and what constituents are being looked for in the samples'^ Is the post oxidizer agent monitor the PMI monitor shown on drawing DB31-EA101 just before the retention tank*^ How long does it take the off-gas to travel from the detonation chamber to PMl*^ How much air volume does the detonation chamber hold'' DB31-EA101 (Process Flow Diagram 1) shows that concentrations of hydrogen (H2) and carbon monoxide (CO) are monitored prior to the inlet of the Cold Plasma Oxidizers, and concentrations of CO, sulfur dioxide (SO2), hydrogen chloride (HCl), oxygen (O2), and nitrogen oxides (NOx) are monitored after the oxidizers The instrument used to determine the concentration of these constituents is a Gas Chromatograph equipped with a Thermal Conductive Detector (GC-TCD) Although agent monitor PMI is located near the Retention Tank, after the gases have been analyzed, they are directed though a duct for approximately 30 feet before they reach the inlet to the Retention Tank A calculation for the time it takes detonation gases to reach the PMI sampling location is not provided Rather, TOCDF has considered the recommendation of the State of Utah Division of Solid and Hazardous Waste (DSHW) and wall use staggered Near Real Time (NRT) momtors at the PMI sampling location (the location prior to the inlet of the Retention Tank) The use of staggered NRT at the PMI location will provide continuous agent monitoring at this location throughout each operational day The volume of the Detonation Chamber is 30 4 cubic meters or 1,073 cubic feet 3 On page 9, midway through the second paragraph, it states that if agent is detected in the off-gas, it IS re-circulated through the retention tank carbon filter and the retention tank until the agent concentration m the off-gas is less than 1 VSL Annex B Monitoring Plan indicates Page 1 of 45 that alarm levels are to be 0 5 VSL Please revise all areas of the modification documents to reflect that the alarm levels for all monitoring will be 0 5 VSL Will the recirculation be timed to ensure that the exhaust gas being sampled is representative'^ How many times will the gas be re- circulated'^ As a proactive measure, the Division may require the exhaust gas to be re-circulated at least once for every batch of exhaust gas no matter what the readings are on the agent monitor prior to the retention tank Would this be possible*^ Is there enough exhaust gas during the first treatment phase for this'' Would this negatively impact the operation of the unif The TOCDF concurs with establishing DAVINCH''"'^ agent emission limit of 0 5 Vapor Screening Limit (VSL) (VSL for mustard agents is 0 003 milligrams per cubic meter) The permit conditions in Module VIII are revised to specify an upper agent concentration limit to reflect this limit for DAVINCH™ exhaust gas The detonation gas is circulated through the carbon filter at least one time after which it is analyzed for agent concentration If the confirmed agent concentration in the gas is equal to or greater than 0 5 VSL, the gas will be sent through the carbon filter again Depending the results obtained during the initial detonation gas check, the valve downstream of the Retention Tank outlet will remain open or be closed, after which the remainder of the detonation will be transferred from the detonation chamber through the Cold Plasma Oxidizers The TOCDF does not recommend directing all treated detonation gas through the Retention Tank Carbon Filter The Pollution Abatement Systems (PASs) of other DAVINCHTM systems currently in operation in other parts of the world are not equipped with a Retention Tank Carbon Filter This filter was included in the DAVINCH™ PAS design at the request of TOCDF as a contingency should agent be detected by the agent monitor located downstream of the Cold Plasma Oxidizers and upstream of the Retention Tank inlet The DAVINCH^'^ systems have processed over 5,400 chemical munitions, and to date, there has not been an instance where chemical agent was detected downstream of the Detonation Chamber Therefore, based on this data, TOCDF does not expect that the Retention Tank Dedicated Carbon Filter will be used If each batch of detonation gas were to be directed through the Retention Tank Dedicated Carbon Filter, the number of detonations that could occur in a day would be reduced fi-om approximately six to an estimated five, which would extend the DAVINCH^"^ operations scope by approximately 18 percent Note that all detonation gases generated by the DAVFNCH'^'^ operation also pass through a sulfiir-impregnated activated carbon filter before being released to the environment Sulftir- impregnated activated carbon is effective in removing both mercury and organic compounds that are entrained in process gases 4 On page 10, the last sentence of the first paragraph states that the munitions will be delivered in overpacks Are these just the overpacks that the munitions are currently in, i e prop charge cans, or ONCs or something else'' The reference to overpacks was to the overpacks in which the munitions are packaged The type of overpacks used is shown in Table 7, page 25, of the permit modification request, under the column headed Overpack(s) Page 2 of 45 5 On page 11, the first paragraph discusses the closing and sealing of the door What indication do the operators use to know that the door is closed and sealed properly'' Proximity switches are used to indicate that the door clamps are in the correct position to seal the Detonation Chamber The status of the door and associated clamp position can be observed fi-om the Control Screens located in the Control Trailer 6 On page 12, the third full paragraph again mentions 1 VSL See comment 3 above Why aren't both Off-Gas Treatment 1 and Off-Gas Treatment 2 sampled for agent concentration'' The TOCDF concurs with the use of a 0 5 VSL limit for DAVINCH^M emission to the environment as a criterion for continued release of detonation gas past the Retention Tank outlet The TOCDF also concurs with the use of staggered NRT monitoring at this sampling location The monitors will operate continuously throughout the shift in staggered mode, therefore, detonation exhaust gas generated from both off-gas Treatments 1 and 2 will be sampled for agent concentration 7 On page 14, the first paragraph under the heading. Waste Analysis Plan, are listed the items to be treated by the DAVINCH This paragraph mentions HT and HD samples Please provide more information on these samples How are they configured'' Where did they come from*' Why it the DAVINCH be chosen as the treatment technology for them'' The mustard (HT and HD) samples were collected from past sample and analysis programs conducted by the Army to determine the rate of degradation of the Deseret Chemical Depot (DCD) chemical agent stockpile The mustard agent comprising the stockpile has been well characterized through past sampling/analysis efforts that have supported TOCDF mustard processing The samples were collected from ton containers and munitions, and analyzed for agent purity These samples are packaged with four sample containers to each overpack The samples are packaged in M2A1 overpacks There are 41 HT and 6 HD samples The volume of each HT sample is 825 milliliters The volume of each HD sample is 452 milliliters Table 7, on page 25 of the DAVNCH^"^ permit modification request, shows the number of samples in each overpack and their associated weights The DAVINCH^'^ is proposed to treat these agent samples because of the reduced handling requirement compared to what would be required to process the samples at the TOCDF There IS also the possibility that the some of the sample container may be damaged which would present a safety hazard for those having to unpack the samples Treatment in the DAVINCH does not require the un-packaging of any of the sample overpacks Additionally, the expense of operating the TOCDF to treat such a small amount of agent compared to the smaller expense of operating the DAVINCH^*^ is a consideration 8 At the bottom of page 15 and top of page 16, there is a discussion of the process for monitoring the drums of metal fragments The text states that a nitrogen purge is performed before agent monitoring How long is the purge'' Is the purge exhaust monitored for chemical agenf Why is the purge performed'' Page 3 of 45 The design of the DAVINCH^"^ munitions process allows for many contingencies to address unexpected occurrences The munitions fragments removed from the detonation are expected to be free of chemical agent contamination The procedure, which will be submitted to the DSHW for approval prior to the start of DAVINCH''''^ agent operations, requires the munition/overpack fragments to be placed in a drum The sealed drum is allowed to sit for a minimum of four hours at a temperature of 70 °F before the drum and its contents are "head- space" monitored If an unexpected result of greater than 0 5 VSL for solids and 1 0 VSL for PPE IS obtained from the head-space monitoring, rather than using the nitrogen purge (which is no longer included in the applicable procedure), the drum wall be opened near the inlets to the DAVrNCH'T'^ Environmental Enclosure Heating, Ventilating, and Air Conditioning (HVAC) System and vented into the DAVINCH HVAC system The HVAC system vents to the atmosphere through three activated carbon filter units After the lid on the drum in question is replaced the procedure require the sealed drum and its contents to sit for four hours at a temperature of 70 °F before the next head-space monitoring occurs 9 On page 16, the third full paragraph discusses the analysis of condensate and spent scrubber brines This is also discussed on page 40 of the Explosive Destruction Technology (EDT) Destruction Plan in the first paragraph on the page Please explain why the scrubber brines are not being analyzed for pH and specific gravity like the scrubber brines from the incinerator PAS The pH parameter is an analytical requirement to determine if the waste is Toxicity Characteristic for corrosivity, and this parameter has been added to the required list of parameter for analysis Specific gravity was not included as a parameter of analysis for this waste steams because it has no bearing on how the waste will be treated at the off-site Subtitle C Treatment, Storage, and Disposal Facility (TSDF) to which TOCDF will transfer the waste Specific gravity was selected as a parameter of analysis for TOCDF scrubber brines because there is also an incinerator operating parameter limit for maximum scrubber brine density 10 On page 16, the fourth full paragraph discusses the analysis of ash generated from several sources What is the filter media used to remove particulate from the detonation gas'' The last paragraph on the page discusses the analysis of spent carbon Carbon method validations will need to be submitted for review and approval and incorporation into the permit There are four places where ash accumulates and is removed from the DAVINCH™ system Ash accumulates in the Detonation Chamber, and the accumulation containers that support the inline Cyclone Filter F410, Screen Filter F420, and Screen Filter F320 (all filters are shown on drawing DB31-EA101, Sheet 1) Filter F320 is used to remove particulate from the detonation gas Filters F410 and F420 remove particulate from air that flows through the Detonation Chamber when the door to the chamber is open Filter F320 is comprised of stainless steel SA 213 TP213 filter mesh Filter 410 is an inline cyclone filter to remove large particulate Filter F420 is bonded material, 2 micrometers, 99 99 % filtration, backwash equipped Filters F320 and F420 are rated at greater than 99 97 % efficiency for removing particulate having a diameter greater than 2 microns Regarding the analysis of the activated carbon used in the DAVINCH^"^ PAS, TOCDF is developing a method to quantify the concentration of agent in activated carbon that is determined to be contaminated based on the agent monitoring results obtained during Page 4 of 45 operations The TOCDF is aware that agent-contaminated activated carbon cannot be transferred off site until a DSHW-approved analytical method is available that allows for the quantification of the agent concentration found in the carbon This method however is being developed programmatically and not specifically for the DAVINCH™ application To preclude the need to perform an agent extraction on spent activated carbon the DAVINCH™ subcontractor has decided to operate WPL DAAMS at the inlet to the Environmental Enclosure HVAC carbon filter units These DAAMS (which are identified in the revised Annex B to the Destruction Plan), will generate a historic record of the HVAC carbon's exposure to agent 11) Please provide all SOPS related to sampling and analysis including standard preparation, sample preparation, data management that will be used for the DAVINCH Also include revision identifier for SW-846 procedures Please provide matrix validation of the activated carbon for metals and organics The Laboratory Operating Procedures (LOPs) used to prepare monitonng and calibration standards, and to perform the agent analysis on waste residues, will be provided to DSWH for approval before agent operations begin The DAVINCH^"^ LOPs and Standard Operating Procedures (SOPs) that will be provided to DSHW for approval by the Executive Secretary are listed below PR-006 Detonation Chamber Decontamination PR-007 DAAMS Operation PR-008 MIN ICAMS Operation PR-010 Headspace Monitonng PR-016 Agent Analysis PR-017 Laboratory Quality Control Plan PR-022 DAAMS Analysis The data management for the DAVINCH in regards to the analytical QC review turn around time will be similar to that of the Chemical Assessment Laboratory (CAL) since ECBC is providing onsite QC personnel Regarding the activated carbon analysis, an analytical method to determine agent concentrations on activated carbon is being developed It is anticipated that the method developed by TOCDF will be used to analyze DAVINCH^'^-operations-generated spent carbon that IS suspected of being contaminated with mustard Any required metals analyses associated with the spent DAVINCH''''^ PAS impregnated carbon will be conducted by an off-site laboratory The samples of PAS carbon will be sent to an off-site laboratory after either an agent extraction has been perfonned or after review of monitoring data, if the data show that the carbon was not exposed to agent 12) On page 20, the sixth bullet states that there are two fixed-bed activated carbon filters but drawing DB31-EA102 shows three filters Which is correct'' What type of carbon is used m each of the carbon filters (HVAC and exhaust gas units)'' The Environmental Enclosure (EE) HVAC activated carbon filters are referenced in the sixth bullet on page 20 of the DAVINCH pennit modification request Initially, it was assumed two Page 5 of 45 of the three filters would be online at any time with one held in reserve However, the operator of the DAVINCH''"'^ intends to operate all three filter units simultaneously (i e , all three fihers will be online) when agent operations begin In summary, there are three HVAC filter units, and all of them will be online during agent operations A single filter may be taken offline if a carbon change out is required However, if a filter is taken offline, agent operations will be suspended until all three filters are placed online The type of activated carbon used in the HVAC filter units is standard activated carbon It is not impregnated with any metals, and its sole purpose is to control organic emissions 13) At several locations in the modification and plan an estimate of the number of 4 2 inch mortars to be treated in the DAVINCH is provided Now that all mustard projectile and mortar processing is complete the exact number of items to be treated in the DAVINCH should be known and the numbers at all locations throughout the modification and plans should be updated The table on page 25 of the modification, condition VIII H 5, Table 2 on page 4 of the Explosive Destruction Technology (EDT) Destruction Plan, Table 5 on page 35 of the Explosive Destruction Technology (EDT) Destruction Plan The only remaining energetic-configured munitions remaining in the DCD Chemical Stockpile are the 155-miIlimeter (mm) Projectiles and 4 2-inch Mortars that will be processed by the DAVINCH'^'** For this reason, the TOCDF Deactivation Furnace System (DFS) is no longer needed and has been shut down The TOCDF HD and HT Mortar Campaign contributed two additional HT mortar rejects to the number of munitions to be processed by the DAVINCH™ It was anticipated that there would be no more than 20 reject mortars from these campaigns Because the DFS has been shut down, plans are underway to remove the demilitarization machines that prepared its waste feed The Projectile and Mortar Disassembly Machines (PMDs) will be removed from the Explosive Containment Rooms (ECRs) During their removal and subsequent cleanup of the ECRs, it is possible that some explosive munition components or pieces of explosive may be found The TOCDF desires to process these components m the DAVINCH^M since it is not practical to relight the DFS to process the small amount of explosive that might be found, it is also not economically or environmentally practical to keep the DFS operable as it might not be used again, and it has large burners that require a lot of fuel to maintain temperature Therefore, the tables in Module VIII and the Explosive Destruction Technology (EDT) Destruction Plan are revised to specify that 117 HT mortars will be processed - rather than 115 - to account for the two additional HT mortar rejects generated during the TOCDF Mortar Campaign The tables are also revised to allow DAVrMCH^M treatment of ECR-closure- generated explosive wastes to replace the batches no longer needed to process the anticipated 18 reject mortars that were included as a contingency, but were never encountered Mortars are to be processed m the DAVINCH^M at a rate of three per batch Twenty mortars would have required seven batch treatments to destroy The two reject mortars added to the total will require one DAVINCH''"** treatment to destroy, leaving six batch treatments available to process ECR closure explosive waste This tally results m the same number of Page 6 of 45 DAVfKCH'^'^ batch treatments as proposed in the initial DAVrKCHi"** permit modification request The table m the Destruction Plan and Module VIII is revised as follows Page 7 of 45 DAVINCH^'^ Operation Limitations" 1 2 3 4 5 Munition OvernacWs) Agent No Munitions i& Samples Munitions/ Shot Shots/ Day' Aeent/ Shot m Total TNTea/ Shot Ob) 4 2" HT Mortar M13A2 HT 44^ 117 3 7 174 118 4 2" HD Mortar M13A2 HD 18 3 7 18 118 UD-er ^ '"' IS'lnH-nr" HT 2XJ 6-0 1 JTIUI Idl 3 111 V/ V7 V ECRExDiosive 9x41 or 7x27*' See See Note b 1 7 See 78 Wastes Note b Note b 155mm H Proio MI6A3 H 68 2 7 23 4 128 155mm H Proio 9x41 H 27 1 7 11 7 93 155mm H Proio M16A3/ M10A4 H 16 i 7 11 7 93 155mm H Proio PA37/ 12x56 H 8 1 7 11 7 119 155mm H Proio M16A3/ 12x56 H 79 1 7 11 7 119 HT Samoles M2A1 HT 4i 4 7 92 46 HD Samples M2A1 HD 6 4 7 5_L 46 Total • 386 "All values listed in columns 1 through 5 are maximums Either over-pack may be used for over packing ECR explosive waste mortars roicctod in the TOCDF Munitions Demilitarization Buildina during the This waste stream is limited to explosive or explosive munition components found during the closure of the ECR and Subpart X Treatment Unit within the ECRs The number of DAVINCH™ treatment shall not exceed 6 mertar campaign The 9x41 over-pack has approximately twice the mass as the 7x27 The Total TNTeq/shot associated with the treatment of mortars m either over-pack will not exceed the value shown Mertars may bo filled with HD or HT since this grouping represents anticipated mortar rejects from TOCDF mortar processing Does not include "Cleansing" shots when only explosives are added to Detonation Chamber to destroy residual agent Page 8 of 45 14) Please provide the materials of construction and design of the Environmental Enclosure The Enclosure fabric is made of reinforced polymer The supports are made of steel and aluminum The vendor makes enclosures having numerous commercial and military applications 15) Please describe how the HVAC filter units will be operated Drawing DB31-EA102 shows three monitors for each filter unit Annex B describes one NRT with three locations for each unit, but three stations for DAAMS in each unit In Annex B please clarify this narrative and explain each monitoring function at each location How many filter units will be operating at one time*^ All three EE HVAC filter units will be online during agent operations Each filter unit consists of a pre-filter, High Efficiency Particulate Air (HEPA) Filter followed by two activated carbon beds, which are followed by a second HEPA Filter Agent monitoring is provided for each filter unit Each unit has a dedicated MFNICAMS that is used to monitor agent concentration in the air exhausting through each filter between the first and second carbon bed Rather then using a "spider" assembly at the probe inlet, the MINICAMS sampling location cycles (i e , "spools") between the top, middle, and bottom section of the first carbon bed If agent is detected at the mid-bed location above the action level of the MFNICAMS, the sampling location is changed to the outlet of the filter unit (a location downstream of all three carbon beds and second HEPA Filter) Each carbon filter unit is also equipped with three Depot Area Air Monitoring System (DAAMS) A DAAMS samples the air as it passes through each carbon bed The DAAMS are used to confirm or refute a MINICAMS indication of agent in the air exhausting through the filter unit 16 ) Condition VIH A 1 h does not mention the samples The samples should be mcluded in this condition Condition VIIIA 1 h is revised to Condition VIII A 1 i (VIII A 1 h is marked "Reserved") and revised to read VIII A 1 1 One Detonation of Ammunition in a Vacuum Integrated Chamber (DAVFNCH) for the treatment of over-packed leaking munitions and agents, agent samples and ECR explosive waste specified in a DAVINCH Destruction Plan approved by the Executive Secretary 17 ) Condition VHI H 3 VHI H 6 , andVIII H 7 u See Comment 3 regarding 1 VSL The above reference conditions are revised to read VIII H 3 The Permittee shall orally report to the Executive Secretary any release of agent from the DAVINCH^'^ Environmental Enclosure or the DAVINCH^^M Environmental Enclosure HVAC Filter System Stack that exceeds the 4 0 5 Vapor Screening Limit for mustard (H/HT/HD) as specified in Table 1 of this Permit Page 9 of 45 VIII H 6 1 The Permittee shall release to the environment only those batches of detonation gas determined to have an agent concentration less than 4-0 0 5 Vapor Screening Limit (VSL) without application of Dilution Air Flow Controllers (DAFCs) at the PMI sampling location, or XX** VSL with application of DAFCs at the PMI samphng location using a dilution air to sample volume ratio of YY** Vlll H 6 11 The Permittee shall stop the flow of Detonation Off-Gas from the DAVINCH™ Pollution Abatement System (PAS) Retention Tank if the concentration of the gas entering the tank is equal to or greater than ^ 0 5 VSL without application of Dilution Air Flow Controllers (DAFCs) at the PMI sampling location, or XX** VSL with application of DAFCs at the PMI samphng location using a dilution air to sample volume ratio of YY** VIII H 6 III Detonation Off-Gas having an agent concentration equal to or greater than 4-0 0 5 VSL without application of Dilution Air Flow Controllers (DAFCs) at the PMI samphng location, or XX** VSL with application of DAFCs at the PMI sampling location using a dilution air to sample volume ratio of YY** shall be directed to the dedicated Retention Tank Carbon Filter and analyzed for agent concentration before being released to the Environment VIII H 7 11 The automatic valve located immediately downstream of the Retention Tank outlet closes if agent is detected in the Detonation OfF-Gas at a concentration equal to or greater than 4-0 0 5 VSL without application of Dilution Air Flow Controllers (DAFCs) at the PMI sampling location, or XX** VSL with application of DAFCs at the PMI sampling location using a dilution air to sample volume ratio of YY** **The dilution air to sample volume ratio is determined during systemization and validated during the 28-dav initial baseline study Place holders XX and YY to be specified and incorporated in this permit through a Class 1 Permit Modification Request prior to the start of Agent Operations Note upon further review of the process flow diagram it was determined that DAFC would be required at the PM1 sampling location (the location prior to the Retention Tank) because the exhaust gas will be saturated at that point in the process 18 ) Condition VIII H 4 will need to have a revision number and date associated with the destruction plan documents for configuration control purposes The TOCDF concurs with the need to associate a date and revision number, so the condition is revised to read VIII H 4 The Permittee shall comply with the waste analysis, inspection, preparedness and prevention, personnel training, agent monitoring, and closure requirements as specified in the DAVfNCH™ Destruction Plan and associated annexes, dated XXXX, Revision X Place holders for the dates and revision number of the Destruction Plan are provided with the intent of replacing them with the accurate information at the end of the permitting process when all required revisions to the plan are complete Page 10 of 45 19.) Condition VIII.H.5. Footnote "c" in the table mentions a "cleansing" shot used to destroy residual agent. Please explain this footnote. What is meant by residual agent? Where does it come from? How does the operator know it is there? Please provide more information on cleansing shots. The design of the DAVINCH™ munitions process allows for many contingencies to address unexpected occurrences. Reference to a cleansing shot in Condition VIII.H.5 is included to allow the operator to place and detonate an explosive charge in the chamber to destroy residual chemical agent. If used, a cleansing shot is comprised solely of donor (i.e., emulsion) explosive. No chemical agent or munitions are added to the Detonation Chamber during a cleansing shot. The cleansing shot is the typical method used to ensure that chemical agent concentrations within the Detonation Chamber are maintained below detectable levels. Cleansing shots are also used to decontaminate the Detonation Chamber when operations have been completed. A cleansing shot will be performed prior to DAVINCH™ system disassembly and transfer to an off-site location whose employees are trained to perform agent operations. The absence or presence of agent contamination within the Detonation Chamber is determined by monitoring the EE air that flows through the open chamber and into a portion of the DAVENCH^"^ PAS. The air is sampled for agent after the air passes through the cyclone style particulate filter. The contamination status of the Detonation Chamber is determined after each detonation to determine the Personnel Protective Equipment (PPE) necessary to enter the chamber. The photographs below show a comparison of the Detonation Chamber before and after a cleansing shot Inside Chamber before (Left) and after (Right) a Cleansing Shot 20. Condition VIII.H.7.i. and Condition VIII.H.7.ii. Since the residence time in the retention tank is 10 minutes and the MINICAMS cycle time is seven minutes, is it possible to complete two cycles of monitoring before the exhaust gas is released? Would it be possible to have staggered Page 11 of45 monitors for this monitoring location*^ Do both the valves before and after the retention tank close if agent is detected*^ Do the valves activate automatically or does an operator have to activate them*^ Do the valves close for an agent monitor malfunction or power failure or other upset conditions'^ Condition 7 ii should include monitor malfunction and power failure Is the retention time the same during Treatment 1 and Treatment 2 phases of treatment*^ Is the flow rate automatically controlled by the operating system or manually controlled by an operator*^ The TOCDF concurs with the suggestion to use staggered NRT monitors at the PMI sampling location In addition, TOCDF concurs with the need to stop the flow of detonation gas from the Retention Tank if either monitor at the PMI sampling location malfunctions or if there is a power loss This feature of the control system will be tested and documented during the Operational Readiness Review (ORR) The valve before (3901) and after (3902) the retention tank closes when agent is detected, a monitor malfianctions, or power fails The flow rate of the detonation gas is controlled by an operator 21) Will Versar/ECBC provide all analytical capabilities or will EG&G/TOCDF provide analytical support*^ The mobile laboratory will need to be audited and validated by the Division prior to commencement of analyses since Department of Health, Bureau of Laboratory Improvement does not certify mobile labs or specific methods (agent) What sample analysis will the mobile lab perform'' Will any off-site analysis be performed'^ The Versar©/ Edgewood Chemical and Biological Center (ECBC) mobile lab will prepare the Quality Plant (QP) sample used by the DAAMS, analyze the DAAMS tubes used at the DAVINCH^'** site, and prepare the Research, Development, Test, and Evaluation (RDTE) solutions used to challenge the MINICAMS The mobile laboratory will also perform the agent extraction analyses on the waste residues generated by DAVfNCH''"'^ operations Metals and organics analyses will be performed by an off-site laboratory certified by the bureau referenced above (i e , Department of Health, Bureau of Laboratory Improvement) The mobile laboratory will have fewer capabilities than the TOCDF Chemical Assessment Laboratory (CAL) as it will not be certified to perform metals, free liquid, or pH analyses 22) The Table of Contents in the Explosives Destruction Technology (EDT) Destruction Plan should be revised to include each of the Annexes t The EDT Destruction Plan Table of Contents references each of the annexes 23) On page v of the Explosive Destruction Technology (EDT) Destruction Plan in the second paragraph of the Executive Summary and on page 1 in the second paragraph of the Introduction, it states that 351 reject munitions will be treated The table in Permit Condition VIII H 5 lists 398 items to be treated Please clarify these discrepancies See comment 13 above regarding the exact count of items to be treated in the DAVINCH The Executive Summary identifies 351 reject munitions to be processed This number is derived from subtracting the number of samples to be processed (47), from the number of items to be processed (398) The total number of reject munitions to be processed included the Page 12 of 45 assumed 20 reject mortars that might have resulted from the TOCDF HD and HT Mortar Campaign, however, there were only 2 reject HT Mortars Therefore, the total number of mumtions to be treated by the DAVINCH^"^ is 333 However, the total number of items (i e , not just munitions) to be treated by the DAVINCH^M is 351-20+ 2 = 333, 333 +47 mustard samples + no more than 6 overpacks of ECR explosive waste total is 386 items The Executive Summary is revised accordingly 24) The fourth paragraph on page 1 of the Explosive Destruction Technology (EDT) Destruction Plan states, " leaking CWM are classified as hazardous waste in the State of Utah as described by Utah Hazardous Waste Code P999 " This statement should be modified to read, " CWM that are designated a waste destined for disposal are classified as hazardous waste in the State of Utah, see the Utah Hazardous Waste Rules R315-2-11(e)(1) " The Destruction Plan is revised to incorporate the suggested revision 25) The fifth paragraph on page 1 of the Explosive Destruction Technology (EDT) Destruction Plan states, "The destruction of CWM is permitted and regulated by the Resource Conservation and Recovery Act (RCRA) " This sentence should be revised to read, "The destruction of CWM in the State of Utah is permitted and regulated by the permit" The Destruction Plan is revised to incorporate the suggested revision 26) There is an extra period following "x-ray system" in the fourth line of paragraph 1 2 2 on page 2 of the Explosive Destruction Technology (EDT) Destruction Plan The Destruction Plan is revised to incorporate the suggested revision 27) There is an asterisk following M2A1 in the Designation column in Table 1 on page 3 of the Explosive Destruction Technology (EDT) Destruction Plan that does not appear to have any meaning If there is a missing reference, it should be added or the asterisk should be deleted The reference to the asterisk that reads "estimated number of process leaker" is deleted, the number of mortar rejects is now known because the TOCDF Mortar Campaigns have been completed The number 20 is deleted from the table, and the 2 actual HT mortar rejects are added to the number of HT mortars shown in the table (115 + 2=117) 28) The comments column of Table 1 on page 3 of the Explosive Destruction Technology (EDT) Destruction Plan is confusing The comments are broken up into rows when it appears that they should be grouped into one cell for each Munition Type Please clarify The formatting of Table 1 is revised to merge rows under the associated munition type specified in the first column of the table 29) On page 12 of the Explosive Destruction Technology (EDT) Destruction Plan, the word "prevent" in the next to last line of paragraph 1 6 2 4 should be "prevented " The Destruction Plan is revised to incorporate the suggested revision Page 13 of 45 30) The next to last sentence in paragraph 1 6 5 on page 13 should be revised to read, "A spill involves the release of a type or quantify of a hazardous waste or materials which, when spilled, become hazardous wastes, that poses a threat to human health or the environment, this includes an uncontrolled fire or explosion " The Destruction Plan is revised to incorporate the suggested revision 31) On page 14 of the Explosive Destruction Technology (EDT) Destruction Plan in paragraph 1 6 5 2 the acronym TOCDF is misspelled The Destruction Plan is revised to incorporate the suggested revision 32) On page 14 of the Explosive Destruction Technology (EDT) Destruction Plan in the first paragraph under 1 7 Monitoring, it states that the target agent for the monitoring plan is HD In paragraph 1 7 1, it states that HD and HT will be used as the target compounds Which statement is correct'' Please explain since H, HD, and HT will all be treated in the DAVINCH The target analyte of the MINICAMS and DAAMS is distilled mustard (HD) Paragraph 1 7 I is revised to remove the reference to HT 33) On pages 15 and 16 of the Explosive Destruction Technology (EDT) Destruction Plan are listed the EG&G, TOCDF and DCD support functions Please add the word "contractors" to the second bullet under 1 8 on page 15 Under paragraph 1 8 5, it states that EG&G and DCD will provide a temporary 90-day storage location Who will be in charge of waste management for the DAVINCH site including characterization, storage and shipment Somewhere in the plan should be language that explains how waste will be managed and who will be managing it The Destruction Plan is revised to incorporate the suggested revision Regarding the management of waste residues generated by DIVINCH'^'^ operations, it is the responsibility of VersarO/ECBC to • Arrange for waste containers and labels, containerize the waste, and manage wastes in satellite and 90-day storage areas while they remain at the DAVINCH'TM site It is also the responsibility of Versar©/ECBC to collect samples of the waste residues and to perform headspace monitoring The waste samples are analyzed by ECBC to determine their status relative to the mustard Waste Control Limit (WCL) • Collect samples of the waste and obtain associated waste analyses from off-site laboratories that are certified by the State of Utah (Versar©) • Arrange for the fransfer of the wastes to the TOCDF Waste Management organization Once the wastes are transferred from the DAVINCH'''^ site to TOCDF, TOCDF is responsible for them, as if the waste were generated by TOCDF (i e , TOCDF will store the wastes and arrange for their off-site treatment and disposal at a Subtitle C TSDF) The Destruction Plan was not revised to include this description Ultimately the waste manifest used to transfer the waste to an offsite Subtitle C TSDF will bear the DCD EPA ID number Page 14 of 45 34) On page 18 of the Explosive Destruction Technology (EDT) Destruction Plan midway through paragraph 2 2 1, the acronym "HDPE" is misspelled The Destruction Plan is revised to incorporate the suggested revision 35) Table 4 on page 20 of the Explosive Destruction Technology (EDT) Destruction Plan contains a row labeled 10-hrs/day Mode What is this*' Please explain this row The row labeled 10-hrs/day Mode is included to show the time devoted to preventative maintenance The planned DAVINCH'^'^ operational schedule for each week includes four days of processing and one day of maintenance The maintenance day is planned as a 10-hr work day The first column of the table shows that a visual inspection will occur each day of operation The second column shows the activities that will occur once a week on the day dedicated to maintenance and that those activities will require three operators two hours to complete (for a total of six man-hours) The third column shows the maintenance and inspection activities that will occur on a monthly basis and that it will take four operators the entire 10-hr day to complete (for a total of 40 man-hours) 36) On page 24 of the Explosive Destruction Technology (EDT) Destruction Plan in the last sentence of paragraph 2 5 5, the acronym DAVINCH is used twice The second occurrence appears to be an error The Destruction Plan is revised to incorporate the suggested correction 37) On page 26 of the Explosive Destruction Technology (EDT) Destruction Plan, the last sentence of the second paragraph refers to Figure 4 This reference should be Figure 5 On page 28, the first sentence under 3 5 1 refers to Figure 5 This reference should be Figure 6 Also on page 28, the first sentence in the paragraph following the bullet list under 3 5 1 refers to Figure 6 This reference should be Figure 7 On page 29, paragraph 3 5 5 refers to Figures 7 and 8 These references should be Figures 8 and 9 respectively On page 33, paragraph 3 5 5 1 references Figure 8 This reference should be Figure 9 On page 37, the second paragraph references Figures 9 and 10 These references should be Figures 10 and 11 respectively On page 46, the sentence at the top of the page refers to Figure 11 This should refer to Figure 12 On page 47, the first paragraph under 4 4 refers to Figure 12 This should refer to Figure 13 The Destruction Plan is revised to incorporate the suggested corrections 38) On page 27 of the Explosive Destruction Technology (EDT) Destruction Plan, Section 3 3 discusses systemization of the unit Please provide more details about the systemization and ORR process What surrogate chemicals will be used'' The TOCDF plans to test the DAVrNCH^M operation by detonating a series of over-packed Simulated Equipment Test Hardware (SETH) munitions after the Explosive portion of the Operational Readiness Review (ORR) is complete and before the beginning of the Agent ORR Both ORRs must be successfully completed before the DAVINCH^** will be allowed to process chemical munitions The overpacked SETH munitions are being processed to familiarize the operator with the Linear Shape Charge (LSC) and Donor Charge explosive configuration associated with each Page 15 of 45 munition/overpack combination that will be processed at the DAVINCH''^'^ In addition, these tests will be used to assure the operator that the system has been installed correctly and is operating as expected Surrogate testing was conducted in Japan The test results were provided with the initial permit modification request (See response to DSHW comment #1) 39) On page 29 of the Explosive Destruction Technology (EDT) Destruction Plan in paragraph 3 5 2 3, the word "resistances" in the middle of the fourth line should be "resistance " The Destruction Plan is revised to incorporate the suggested correction 40) On page 33 of the Explosive Destruction Technology (EDT) Destruction Plan paragraph 3 5 5 2 states, "This phase is accomplished by " What phase*' Please clarify this sentence The paragraph makes reference to the DAVINCH''"'*' process step titled Air Vacuum, during which the sealed Detonation Chamber is evacuated Paragraph 3 5 5 2 is revised to include the name of this process step 41) On page 33 of the Explosive Destruction Technology (EDT) Destruction Plan, paragraph 3 5 5 6 refers to paragraph 3 15 5 This paragraph does not exist in the plan Please correct this reference The correct reference is paragraph 3 5 5 5, and the plan is revised to correct the reference 42) On page 33 of the Explosive Destruction Technology (EDT) Destruction Plan, paragraph 3 5 5 8 mentions Electrostatically Charged Aerosol Decontamination solution Please provide more information on this solution What is if Is there an MSDS available'' If so, please provide a copy What is its purpose'' How is it used'' How often would this step be performed'' The term Electrostatically Charged Aerosol Decontamination (ECAD) solution refers to a method of apply decon solution Various solutions can be applied in this manner depending on whether the target contaminant is biological or chemical The following is from a report generated that investigated use of an ECAD application for remotely decontaminating a rail station (e g , subway) "The ECAD process produces an aerosol fog of electrically charged droplets of a liquid decontamination reagent These droplets repel one another and are attracted to surfaces and airborne particles in any orientation Thus, ECAD is a reagent delivery system that minimizes the amount of reagent used, thus potentially minimizing damage to materials and equipment (depending on the reagent used), while still achieving complete coverage of the area to be decontaminated " "The promise of hydrogen peroxide based formulations (e g , Decon Green) should be noted If the reactivity towards the treated materials is not of importance, bleach (or in general, active chlorine formulations) could be equally effective against chemical and biological agents " Page 16 of 45 TOCDF will be provided with an MSDS prior to the time the selected DAVINCH decon solution to be used in the ECAD arrives This MSDS will be made available to DSHW at that time 43) On page 36 of the Explosive Destruction Technology (EDT) Destruction Plan, Section 3 7 lists operating procedures for the EDT and highlights those that will have a Division approval role The EDT decontamination procedure is not highlighted but should be reviewed and approved Please add this procedure to the list of those needing approval The referenced procedure is marked to indicate that DSHW approval of the procedure is required prior to DAVINCH''"'^ hazardous waste operations 44) On page 36 of the Explosive Destruction Technology (EDT) Destruction Plan in the second paragraph under 3 9, there is a discussion about decontamination verification This discussion states that headspace monitoring at the STEL level for HD will be used for this purpose In the approved Closure Plan for the CAMDS facilify, the VSL and USACHPPM health-based screening levels are used A short term exposure limit does not seem to be appropriate for this Please explain why the STEL is to be used with the DAVINCH The decontamination clearance level for the DAVINCH™ equipment is revised to the Vapor Screening Limit (VSL) in both the Destruction Plan and in the revised Closure Plan Note • The DAVfNCH™ will not be discarded when the scope of the TOCDF applicafion is complete Rather, the DAVINCHT""^ and associated PAS will be moved to an off-site Federal facility and stored there until its services are contracted out again • The employees of the organization at the Federal facility that will store the DAVINCH™ equipment are trained chemical agent workers 45) On page 37 of the Explosive Destruction Technology (EDT) Destruction Plan, the last sentence of the first paragraph on the page does not make sense Please revise The last sentence is revised to read The system will be removed and transferred to a Federal installation and stored by an agency whose workers are trained in chemical agent operations The system will not be discarded upon completion of the TOCDF project, but stored for fijture operations Theroforo, the closure standard for components that are determined to be decontaminated through agent monitoring results is the mustard STEL rather than the Vapor Screen Limit (VSL) Note, the Closure Plan has been revised to reference the VSL rather than the STEL 46) On page 38 of the Explosive Destruction Technology (EDT) Destruction Plan, the first complete sentence in the first paragraph on the page states that hazardous waste will be removed by the operating contractor Is this referring to Versar, ECBC or EG&G'' Please clarify Page 17 of 45 The reference to the "operating contractor" is to Versar©/ECBC The waste will be containerized and transferred to the TOCDF Waste Management orgamzation Versar©/ECBC IS responsible for determining the decontamination status of the waste in regard to agent contamination and in characterizing the waste analysis by SW-846 method Note the SW-846 method analyses will be conducted by an off-site State of Utah certified laboratory The TOCDF will determine the applicable State and Federal waste codes to assign to the waste, and store and manifest the waste to an off-site Subtitle C TSDF 47) On page 38 of the Explosive Destruction Technology (EDT) Destruction Plan, the second paragraph under 3 10 states that the SSSP is located in Annex C This is incorrect Please correct this reference The sentence is revised to clearly explain that the annex referenced is an annex in the Site Specific Safety Plan (SSSP), and not that the SSSP is found in Annex C of the EDT Destruction Plan This sentence and others are revised as follows The PAED for the EDT maximum credible event (MCE) is defined in Armex D of the SSSP Annexe of the SSSP for the EDT Site defines the MCE for Establishing PAED as the detonation of 133 lb of TNTeq 48) On page 38 of the Explosive Destruction Technology (EDT) Destruction Plan, the first paragraph under 3 10 states that access within the PAED will be restricted to personnel directly involved with the chemical operations Inspectors from the Division will need access to all areas of the unit in order to perform their oversight duties and should be considered to be involved with the chemical operations If special training is required, this training will need to be provided The TOCDF acknowledges that the State of Utah Division of Environmental Quality (DEQ) Compliance Inspectors cannot be denied "nght of access" to the DAVINCH''''^ location as needed The only restriction, which is applicable to DAVrNCHT"^ operational persormel and EG&G persormel as well, is that personnel cannot be present within the Environmental Enclosure (EE) during a detonation All personnel are required to exit the EE prior to and during the Detonation step of the process Training regarding the unique hazards associated with the DAVrNCHT"^ operations will be provided to DSHW representatives if requested 49) On page 38 of the Explosive Destruction Technology (EDT) Destruction Plan, Section 3 11 discusses waste analysis and the characterization of the munitions and agent to be treated Is EG&G sure that the past sampling and analysis has properly characterized the waste to be treated'' Is there any concern that the actual mercury level in the waste munitions is higher than what has been reported in the pasf In light of the experience at TOCDF with the PFS, is there any concern that mercury will migrate through the carbon filter, F440, and become an emission problem*' Has this filter been sized properly for its intended purpose'' How will the filter be monitored to ensure that mercury does not migrate through the filter and become an emission problem'' Page 18 of 45 The TOCDF is confident that the wastes to be processed in the DAVINCH''''^ have been sufficiently characterized The TOCDF collected samples from 155-mm Projectiles throughout the munitions' campaign The concentration of metals in the sample did not present a concern in regards to metals emission rates These data were submitted to DSHW The TOCDF also collected liquid and solid samples from HT Mortars according to a sampling plan approved by DSHW The results of this sampling were provided to DSHW The metal of concern for mortars is mercury (Hg), and the analytical results did not show high concentrations of it However, the analysis of Metal Parts Furnace (MPF) exhaust gas samples collected during the processing of the drained HT mortars showed concentrations of Hg sufficiently high to prevent TOCDF from processing them at the desired rate until the MPF PAS Filtration System (PFS) became operational Solid and liquid samples were collected from HD mortars and analyzed The results are reported in the Parsons Engineering Design Study I Projectile Washout System (PWS) Testing, Vol 1 of 3, 14 August 2004 The liquid HD samples were found to contain minimal concentrations of Hg The solid samples (with solids comprising approximately half the fill of the mortars) were found to contain Hg at an average concentration of 766 parts per million A fiirther review of the above-referenced report shows that the drained and rmsed mortars were placed in a Metal Parts Treater (MPT) where they were heated The exhaust gas from the treatment was sampled, analyzed, and found to contain Hg The table below presents an estimate of the total Hg present in the mortars to be processed by the DAVINCH''"'^ based on the result determined from the available analyses previously described Page 19 of 45 DAVINCH Mercury (Hg) Emission Estimate Mortar Casing Hg Content' MPT^ Charge Interval (mm) 15 Mortars processed (no) 34 MPT Gas Flow Rate (cfm) 55 Exhaust Gas Hg Cone (ug/scm) 188 Total Hg m 34 mortars (mg) 14 9 Mortars m DAVINCH Scope (no ) 135 Hg to DAVINCH from Mortar Casmgs (lb) 0 13 HD Mortar Fill Hg Content^ Solid Heel Hg Content (mg/Kg) 768 Solid Heel wt Fraction (%) 16 HD Mortar Fill wt (lb) 60 DAVINCH HD Mortar Scope (no) 18 Hg to DAVINCH from HD Mortar Fill (lb) 0 013 HT Mortar Fill Hg Content"* HT Mortar Hg Content (mg/Kg) 197 Solid Heel wt Fraction (%) 5 HT Mortar Fill wt (lb) 5 8 Incidence of Solid Heel m HT Mortars (%) 33 DAVINCH HD Mortar Scope (no ) 117 Hg to DAVINCH from HT Mortar Fill (lb) 0 002 Total Hg to DAVINCH (lb) 0 15 DAVfNCH Fixed Bed Sulfur Impregnated Carbon 99 99 Hg Removal Efficiency (%) 99 99 Total DAVINCH Hg Emission (lb) 0 00001 'Estimate based on data taken from "Summary of Parsons Engmeenng Design Study I Projectile Washout System (PWS) TesUng Final Technical Report Volume I of III", 14 August 2003 ^MPT = Metal Parts Treater that was used by Parsons durmg the testmg, from which Hg exhaust gas samples were taken durmg operation ^Source is "Summary of Parsons Enigneermg Design Study I Projectile Washout System (PWS) Testmg", dated 14 August 2003, Tables 3-25 (liquid HD results) and 3-29 (solid HD results) ''Source is Table 6-37 of Summary cf Parsons Engmeermg Design Study I Projectile Washout System (PWS) Testmg, Vol 1 of 3, 14 August 2004 The TOCDF acknowledges that the mass of Hg in the munitions was imderreported in the past as demonstrated by the unexpected results of the MPF exhaust sampling conducted during the initial attempt to process HT mortars The information that the HT mortar casings contained Hg was available prior to the beginning of the initial HT Mortar Campaign based on the Page 20 of 45 exhaust gas sampling results generated from the Parsons MPT testmg The amount of Hg contained in the mortar casings is accounted for in the estimate above The TOCDF Pollution Abatement System (PAS) Filter Systems (PFSs) have been in operation for over a year They were installed to control the emissions from processing a subset of HD ton containers that were estimated to collectively contain over 1,200 pounds of Hg as compared to an estimated 0 15 poimds of Hg in the mortars to be processed in the DAVINCH™ The MPF processed approximately 1,000 non-Baseline ton containers and over 64,000 mortars The DAVINCH™ will operate for a total of approximately two months Of the two types of mortars (HT and HD), the solid heel contained in the HD mortars has been shown to contain Hg at an average concentration of 766 ppm There are 18 HD mortars to process in the DAVINCH''"'^, and this number can be processed in one day There are 117 HT mortars to process, and they can be processed in 6 5 days The sulfiar-impregnated activated carbon filter was sized based on residence time, however, the amount of Hg to which the filter will be exposed is very low Past operational experience has shown that the Hg contained in treated munitions remains in the Detonation Chamber and partitions to the ash Furthermore, the TOCDF experience with a fixed-bed sulfiir-impregnated activated carbon system has shown that the useful life of the carbon bed is influenced by the amount of Hg to which the bed is exposed and the amount of exhaust gas that flows through the bed Therefore, TOCDF has planned the order of munitions treatment in the DAVINCH'^'^ such that mortar processing will occur towards the end of DAVINCH''"'^ operations This "order of processing" will limit the amount of exhaust gas that flows through the sulfiir-impregnated activated carbon bed once the bed is exposed to Hg The Hg emissions from the DAVINCH^"^ are not a concern considenng the limited number of mortars to be processed therein, the short duration of the operation, the amovmt of Hg contained in the mortars to be processed, and the revised order of munition treatment Finally, the TOCDF is proposing to collect exhaust gas samples and analyze those samples for Hg during the time that HD mortars are processed These results will demonstrate the effectiveness of the DAVINCH and associated PAS in minimizing Hg emissions (see cover letter this comment response) 50) On page 39 the first full paragraph lists waste to be generated by the DAVINCH This list should also include monitoring wastes, spent decontamination solutions, PAS filters, HEPA filters, and dust/particulate and ash The paragraph is revised to read Waste generated by DAVrNCH'^'^ operations are metal munition and overpack fragments, condensate formed by the oxidation of the hydrogen contained in the chemical agent, munition burster and explosive LSCs and donor charges, spent scrubber solution, monitoring wastes, spent decontamination solution, particulate filters, ash, spent activated carbon, and discarded PPE Page 21 of 45 51) On page 39 of the Explosive Destruction Technology (EDT) Destruction Plan, the last paragraph on the page discusses re-monitoring of drums of metal fragments that have a first reading above 0 5VSL No contingency is discussed in the event that the contents of the drum are still above the acceptable level after a second round of monitoring Other areas of the modification documents mention the possibility of treating these metal fragments in the MPF Please provide language detailing how this will be handled The paragraph is revised to read If the monitoring results show a drum headspace result equal to or greater than 0 50 VSL,-_an additional air purge is performed and the headspace equalizing procedure is repeated (i e , four hours at 70 °F) the drum is moved underneath an intake vent to the Environmental Enclosure, opened and allowed to vent After venting the container is resealed and the -The container contents are then monitored again to determine the agent concentration relative to the 0 50 VSL If the drum headspace monitonng results continue to be above the 0 5 VSL limit for metal fragments and 1 0 VSL for PPE after venting, the drum and its contents will be transferred to the TOCDF and processed through the Metal Parts Furnace (MPF) Note the venting of the drums containing munition and overpack fragments that have been removed from the DAVINCH''"'^ Detonation Chamber is provided as a contingency Historical DAVINCH™ operations have shown the destruction of the chemical agent within the Detonation Chamber to the extent that chemical agent residues are not present on the residues removed from the chamber Use of the MPF to ftarther treat munition/overpack fragments that may fail headspace monitoring criterion is provided as a contingency to a contingency 52) On page 40 of the Explosive Destruction Technology (EDT) Destruction Plan, the word "steam" in the second sentence in the first paragraph and the first sentence in the third paragraph on the page should be "stream " The Destruction Plan is revised to incorporate the suggested corrections 53) On page 40 of the Explosive Destruction Technology (EDT) Destruction Plan, the second paragraph mentions that some of the over-packs may contain packing material and absorbent What will happen to these materials during the detonation process'' Will there be anything of significant size leff If there are significant amounts of these materials remaining, it may have to be segregated as a separate waste stream for sampling and analytical purposes During the overpack testing that was conducted by the manufacturer of the DAVINCH™ in Japan, SETH munitions were wrapped in plastic sheeting, inserted into overpacks, and detonated using the same explosive configurations that will be used during TOCDF DAVINCH''''^ operations The residues generated during these tests were of a consistent size, which will enable collection of a representative sample for waste characterization The component of the target munition with the most variability in size was the overpack Page 22 of 45 For pictures of target preparation and typical waste residues, see pages 50 through 61 of the Overpack Test Report that was submitted as Attachment 2 to the DAVINCH™ permit modification request 54) On page 40 and Table 8 of the Explosive Destruction Technology (EDT) Destruction Plan the analysis of spent scrubber brine and ash generated during operations of the DAVINCH is discussed The ash and brine need to be analyzed for explosives and perchlorate Is there any concern that all the explosives will not be consumed in the detonation and explosives residues will remain on the metal fragments and in the ash'' Because this is a small operation and the amount of waste generated is much less than that generated from the incinerators at TOCDF, each individual container should be sampled and analyzed without the samples being composited Agent and agent breakdown products should be added to the analysis Environmental Protection Agency (EPA) Method 8095 is applicable to the analysis of explosive in soils and water matrices The applicability of this method to ash samples is unknown Rather than add this analytical parameter to the associated Destruction Plan table, the TOCDF proposes to analyze the samples of ash and condensate for explosive that are collected during the testing that will occur at the beginning of the 155mm H projectile single overpack campaign (which is planned to be the first campaign) to determine if explosive is present in the waste residues at concentrations greater then the Land Disposal Restriction (LDR) limit If so TOCDF would continue to analyze spent brine and water for explosives The TOCDF does not concur with the need to analyze the waste residues for agent breakdown products since no other TOCDF-generated waste residue is analyzed for these constituents Additionally, it is the WCL that is the measure of compliance when determining whether the treatment process has sufficiently destroyed the chemical agent to a level that allows the transfer of waste residues to an offsite Subtitle C TSDF The WCL is based on the agent concentration in the residue, and for mustard the limit is less than 200 parts per billion The TOCDF does not concur with the suggestion to increase the sampling and analysis frequency of waste residues The number of samples proposed to be composited into one sample for analysis was determined by estimating the number of drums that would be generated during the treatment of each type of mumtion/overpack combination The number of drums proposed to be sampled during each sample/analysis event ensures the analysis of residues generated from each munition/overpack combination 55) Table 8 on page 42 has a footnote 5 reference in several of the columns but no footnote exists Please revise The footnote reference is deleted 56) Table 8 on page 42 lists a TOCDF procedure for agent analysis Will EG&G personnel be performing this analysis or will ECBC personnel be performing the analysis usmg the TOCDF procedure'' The agent screen conducted on waste residues will be conducted by Versar©/ECBC personnel at the Mobile Laboratory A procedure developed by ECBC will be used for this analysis Table 8 is corrected to show the applicable procedure Page 23 of 45 57) On page 43 under heading 3 12 2, the document states that leaking overpacks will be repacked, then shipped back to storage Please explain why they are sent back to storage and what will happen to them after that Overpacked munitions are delivered to the DAVINCH''"'^ in a box truck The sealed storage compartment is monitored for agent If the monitoring results are confirmed to be greater than 0 5 VSL the delivery is not accepted and the contents of the truck are returned to DCD to be overpacked and processed by the DAVINCH at a later date If the leak occurs after within the DAVfNCH'^'^ Environmental Enclosure the overpacked munition will be placed in a plastic bag to stop the release of agent vapors and prevent contamination and the bagged overpacked munition will be treated in the DAVINCH in the intended manner 58) Section 4 0 of the Explosive Destruction Technology (EDT) Destruction Plan discusses the organization for the EDT project How many operational/monitoring and lab teams are proposed for the DAVINCH Operations'' How often will they rotate'' Are there any QC personnel Please provide a list of each organization (CMA, EG&G, DCD, Versar, ECBC) and list exactly what the responsibilities of each organization are (e g, ECBC - air monitoring, waste analysis, DAVINCH operations) The data quality review will be conducted by ECBC personnel located on-site The number of personnel required to operate the DAVfNCH is currently being determined A organization chart is provided in Annex G, page 7, Figure 2 59) On page 47 of the Explosive Destruction Technology (EDT) Destruction Plan, the last two paragraphs on the page refer to Tables 8 and 9 These references should be to Tables 9 and 10 respectively The Destruction Plan is revised to incorporate the suggested corrections 60) On page 48 of the Explosive Destruction Technology (EDT) Destruction Plan in the Qualification/Experience column of Table 10, the acronym OSHA is misspelled Also, this table does not address qualifications for monitoring personnel Table 10 is revised to correct the misspelling and to include the qualifications for monitoring personnel 61) In Annex A, there is no definition of the acronym "CBARR" used on page 46 of the Explosive Destruction Technology (EDT) Destruction Plan Please provide this definition Please provide the definitions for "CEES" and "n-DBS" as well The acronyms CBARR, CEES, and n-DBS are added to Annex A 62) The following definitions in Annex A need to be corrected DAVINCH - Detonation of Ammunition in a Vacuum Integrated Chamber DSHW - Division of Solid and Hazardous Waste Page 24 of 45 OSHA - Occupational Safety and Health Administration The suggested corrections to Annex A are included 63) Annex B, page in, Table 9-1 is located on page 31 not page 32, Table 9-2 is located on page 32, not page 33, Table 11-1 is located on page 34, not page 35, Table 11-2 is located on page 35, not page 36, Table 11-3 is located on page 42, not page 43 The suggested corrections are made to the revised Annex B provided with this submission 64) Annex B, page 1, Section 1 0 Applicable Monitoring and Laboratory procedure/requirements should be at least as restrictive as TOCDF's Permit Specific procedural changes that are unique to this process should be addressed in this modification The personnel that will operate the DAVINCH'^'^ are provided by the ECBC They are experienced in the destruction of the chemical munitions that are not part of the national stockpile These personnel will adhere to requirements specified in a Laboratory Monitoring Quality Confrol Plan (LMQCP) that meets the requirements of the Chemical Materials Command (CMA) Laboratory Monitoring Quality Assurance Plan (LMQAP) and the Monitoring Concept Plan (MCP) 65) Annex B, page 1, in the first paragraph under 1 1, it states that 351 reject munitions will be treated The table m Permit Condition VIII H 5 lists 398 items to be treated Please clarify these discrepancies See comment 13 above regarding the exact count of items to be treated in the DAVINCH The total number of munitions to be processed by the DAVINCH''"'^ is corrected from 351 to 333 The total number of items to be processed by the DAVINCHT'^ IS now 333 munitions and 47 agent samples 66) Annex B, page 1, Section 1 1, Please justify an alternate baseline instead of the required 30 days The EDT project will perform standard initial (28-day) and continuing baseline studies 67) Annex B, page 2, Section 11, What is the frequency of agent challenge on the stack'' PMI4, the stack location NRT monitor, will be challenged at the instrument at the start and end of daily destruction operations Historical monitoring at the Worker Population Limit (WPL) will be performed on the stack This combination exceeds the monitoring requirements for a filter stack 68) Annex B, page 3, Section 1 5 states that unmasked workers should not exceed STEL and WPL limits but the agent monitoring plan has the monitoring for worker protection being done at the VSL level It appears that this should be STEL in most cases and possibly WPL in some Please review the entire monitoring plan with regards to the use of VSL and STEL and clarify this issue Page 25 of 45 Annex B was revised to remove STEL references The STEL is based on a time weighted concentration The NRT are managed to alarm at a concentration that is equal to the STEL 15 minute exposure (i e , the VSL) The NRT sample/analysis cycle used for this application however is less than 15 minutes 69) Annex B, page 5, the last sentence in the paragraph above Section 4 0 states that all monitoring devices used for CWM detection will satisfy the requirements in the CMA-LMQAP The TOCDF-LMQAP should be incorporated as an Annex to this plan and followed instead of the CMA document The ECBC will use their LMQCP, which meets the requirements of the CMA LMQAP and MCP The EDT project will perform standard initial (28-day) and continuing baseline studies 70) Annex B, page 8, Table 4-2 needs to be reformatted to show the information properly Is the value listed for the 12-hour WPL while using SCBA correcf This value decreased when all the others increased The table has been verified and corrected 71) Annex B, page 10 Please specify that the DAAMS tubes are TENAX for mustard As a reminder, all monitoring requirements specified must meet in the TOCDF LQCMP All DAAMS tubes used will contain Tenax® as the solid sorbent material 72) Annex B, page 10, Section 5 3 states that MINICAMS may be used to monitor at the STEL, WPL, VSL and IDLH concentrations Will they be used to monitor for WPL and IDLH at the DAVINCH site'' Paragraph 5 3 is corrected to state that NRT monitors are configured to detect agent at the VSL 73) Annex B, page 11, Section 5 4 references a Reporting Limit (RL) but does not provide one Please specify the reporting limit or make reference to the location in the plan where this is specified The RL for WPL DAAMS methods is 0 5 WPL The RL for NRT confirmation DAAMS samples is defined as a positive response based on a mimmum peak area which is determined during the method development This information will be provided to DSHW pnor to the beginning of agent operations 74) Annex B, page 11, Section 5 5 discusses dilution air flow controllers What is the ratio for the dilution air flow on these monitors'' A Dilution Air Flow Controllers (DAFC) will be required at the PMI sampling location The dilution ratio will be determined during systemization 75) Annex B, page 11, Section 5 6 The Stack and upstream retention tank monitoring location (PMI) are all critical for processing and will have continuous/staggered agent monitonng systems The HVAC monitor (PM13) will have a redundant monitor Page 26 of 45 Staggered NRT monitors will be placed on the PMI location (upstream of the Retention Tank) only There will be no redundant monitor at PMI 3 locations Considerations for this agent monitoring configuration are as follows • The source of agent is the Detonation Chamber The PMI location monitors Detonation Chamber exhaust gas agent concentrations prior to this exhaust gas mixing with EE ventilation air • Munitions are not stored in the EE continuously Only the numbers of munitions or agent samples that can be processed in one day are delivered to the DAVrNCH^"^ EE • DAAMS systems continuously sample the exhaust gas exiting the DAVINCH'^'^ and EE HVAC filter system Common Stack The DAAMS tubes collected from this location are analyzed to create a historical record of agent emission from DAVFNCH''^'^ operations 76) Annex B, Table 5-1 states that critical NRT monitors are equipped with UPS but Table 7- 1 indicates that ALL NRT monitors have UPS This statement appears again on page 17 in the first paragraph under 6 0 If it is true that all monitors have UPS, please delete these statements If not, please clarify which monitors are considered critical and will have UPS Table 5-1 also states that the size of the DAAMS tubes may vary depending on the agent operation Why should they vary on this project where only one agent is being monitored'' Please provide the DAAMS tube size and specifications Where are the specifications detailed'' Please explain what a chromosorb moisture detection disk is Table 5-1 is consistent with information included in Table 7-1 Table 5-1 reference shows that critical monitors are supported by Uninterruptible Power Supply (UPS) system Table 7-1 shows which monitoring systems are supported by the UPS Note not all monitoring systems are supported by the UPS Table 5-1 is further changed to indicate that 6-mm Tenax® tubes will be used The specifications for tube construction are in the ECBC DAAMS Internal Operating Procedure (lOP) The reference to a chromosorb moisture detection disc (indicator) relates to NOx filters The chromosorb reference is deleted, as ECBC will not be using the moisture indicator with their NOx filters 77) Annex B, Table 5-2 on page 16 lists Toxic gas mixtures under support gases Please list the toxic gas mixtures that will be used or delete those that will not be used The reference is deleted No toxic gas mixtures will be used on site 78) Annex B, page 17, Section 6 1 states that a qualitative method will be used for confirmation monitoring A qualitative method has not been approved A quantitative Class 1 method as defined in documents referenced in Attachment 3 to the TOCDF Part B Permit will need to be used Please revise this section accordingly Based on previous State approval for CMA Non-Stockpile operations (Dugway EDS), and in accordance with CMA guidance, ECBC uses a class III NRT confirmation method Although the method is officially qualitative, ECBC reports any detectable amount of agent m a confirmation method sample Page 27 of 45 79) Annex B, pages 20 through 22, Table 7-1 The header row of this table needs to be formatted so that it continues on each page The table has been reformatted 80) Annex B, page 20, Table 7-1 Monitors noted in Table 7-1, AM4 and AM5 used to point source monitor personnel should have a footnote describing this waste characterization process of the suits Any personnel monitoring performed in these airlocks does not serve as waste characterization of PPE Waste characterization of bagged or drummed PPE will occur in the post-treatment area 81) Annex B, page 20, Table 7-1 has two alarm levels for monitor AM7, 0 5 and 1 0 VSL This should only be 0 5 VSL similar to the MPF Discharge Airlock. The table has been revised to include the reporting limits of 0 2, 0 5, and 1 0 VSL, depending on the operatton being performed 82) Annex B, page 22, Table 7-1 shows the monitoring level for the Stack monitor PM14 to be VSL/WPL Shouldn't this be just VSL'' Please explain PMI4 will operate at the VSL In addition, there will be a historical DAAMS collected at the filter stack at the WPL concentration 83) Annex B, page 22, Table 7-1, footnote 4 should be revised to include NRT malfunction and power loss in the conditions that cause automatic activation of the recirculation loop This IS a fiinction of the Kobe DAVINCHTM control software, not the ME^ICAMS The Distributed Control System code will include commands to stop the flow of detonation gas past the Retention Tank if there is a loss of power or if one of the NRTs malfunctions 84) Annex B, page 22, Table 7-1, footnote 7 should state that the DAAMS tubes for the stack will be collected and analyzed every four hours Historical monitoring of the filter stack exhaust will be collected and analyzed every 8 hours durmg daily destruction operations There are two sets of DAAMS on the stack that exhaust the combined exhaust gas from the DAVfNCH'''** and the EE HVAC carbon filter system The WPL DAAMS will be collected and analyzed every 8 hours throughout agent operations 85) Annex B, page 22, Table 7-1 footnote 8 states that there is one MINICAMS spools between bed locations on each filter unit and that there is a separate DAAMS on each location Some explanation needs to be provided in the plan on how the spooling works and how the DAAMS tubes are set up and analyzed The QC also needs to be explained Section 7 1 11 is updated to include a description of the monitoring approach for filter units 86) Annex B, page 24, paragraph 717 Please notify the Division prior to smoking testing activities so a representative may be present to observe Page 28 of 45 A smoke testing demonstration will be scheduled and DSHW will be notified 87) Annex B, page 24, paragraph 7 1 10 2 All lab areas (monitoring/analytical) regardless of the agent standard level will require monitoring Any filter systems associated with the lab should also have monitoring Army safety regulations and CMA do not require monitoring of laboratory areas for non-surety operations, they also do not require monitoring of mobile laboratory filtration systems Monitoring is, however, provided in the laboratory using DAAMS only Agent monitoring is not provided on the carbon filter that supports laboratory operations since the laboratory will manage only RDTE solutions 88) Annex B, page 25, paragraph 7 1 12 states in the second sentence that first entry monitoring is one complete cycle First entry monitoring should be at least two complete cycles Please revise the sentence Section 7 112 will be changed to reflect that first entry monitoring (FEM) will be conducted using one complete cycle preceded by a purge cycle to ensure the sample line is filled with the intended sample The text will also be clarified as this paragraph pertains to FEM prior to personnel entry into the EE 89) Annex B, pages 25 and 26, paragraphs under 7 1 13 state that headspace monitoring is not being used to support disposition of material On page 15 and 16 of the modification document and again on page 39 of the Explosive Destruction Technology (EDT) Destruction Plan, it states that headspace monitoring will be used to evaluate metal munition and overpack fragments for agent contamination and make a waste determination These statements seem to be contradictory Please clarify The wording of 7 1 13 is revised Headspace results will be used to characterize wastes (PPE and metal fragments) 90) Annex B, page 26, first paragraph on the page states that headspace monitoring will be one complete sampling cycle A minimum of two complete cycles should be used Please revise the sentence The text is modified to indicate that one complete cycle preceded by a purge cycle will be performed to ensure the sample line is filled with the intended sample 91) Annex B, page 26, second paragraph states that headspace monitoring for the purposes of decontamination verification will follow the requirements of paragraph 4 4 of the CMA MCPO Documents that are not provided as part of the permit modification should not be referenced Please revise the text to include the requirements from paragraph 4 4 of the CMA MCPO Text IS added to clarify the referenced requirements 92) Annex B, page 26, paragraph 7 1 14 states that monitoring of the waste drum area will be done with a sample line hung less than two feet above the drums Which monitor is being used for this purpose'' Is this being done to determine if there is any agent contamination on the Page 29 of 45 outside of the drums'' If so, why are the drums not being tented in plastic and monitoring being performed as it is at other parts of the TOCDF facilify'' Will waste containers be stored in the environmental enclosure for longer than 24 hours'' The Momtonng Plan will be revised to clarify which MINICAMS will momtor the waste drum area The exterior of the drums will be tented and monitored in Airlock 2 Waste containers may be stored in the enclosure for more than 24 hours in designated 90-day storage locations 93) Annex B, page 26, Section 7 2 All historical monitors will need to be a quantitative method or Class 1 method If a DAAMS that is not a Class 2 or 3 method is used, then any area mass IS considered a confirmed alarm from the NRT Based on previous State approval for CMA Non-Stockpile operations (Dugway EDS) and in accordance with CMA guidance, ECBC uses a class III NRT confirmation method Although the method is officially qualitative, ECBC reports any detectable amount of agent in a confirmation method sample 94) Annex B, page 27, paragraph 7 2 6 1 states that laboratory work areas will be monitored at the STEL and WPL Is this correcf If so, please justify the use of the STEL for this type of monitoring The current Monitoring Plan identifies monitoring in the laboratory work area (MINICAMS at STEL level) Although Army safety regulations and CMA do not require monitoring for non- surety laboratory operations, the monitoring is being provided per the requirement of DAVINCH^** project management The monitor is calibrated to the STEL because the laboratory will mange only RDTE solutions, the sample containers of waste residues that the laboratory will receive are monitored for agent prior to being received at the lab, and the waste residue sample containers are opened, and the samples are prepared for analysis under a fume hood that vents to a carbon filter 95) Annex B, page 28, section 7 2 7 The Mobile Analytical Platform is not set up to vent through the EE's HVAC system What are the specifications for the Mobile Analytical Platform's laboratory ventilation system^ What happens if they get a hot tube'' Do they have carbon filters on their ventilation system'' If yes, will it be monitored'' The GC/MS instruments will be properly vented to protect laboratory operators Carbon filters are used on the laboratory filtration system, which wall not be monitored 96) Annex B, page 28, Section 7 2 7 Please substitute "quantitative confirmation" for "qualitative confirmation" in all subsections of 7 2 7 as only quantitative confirmation methods are allowed Based on previous State approval for CMA Non-Stockpile operations (Dugway EDS) and m accordance with CMA guidance, ECBC uses a class III NRT confirmation method Although the method is officially qualitative, ECBC reports any detectable amount of agent in a confirmation method sample 97) Annex B, page 28, Section 7 2 7 2 Please explain what "Chamber Discharge During Venting" is Page 30 of 45 The paragraph is revised to read During chamber venting, the door to the Detonation Chamber is open and EE air is drawing throug the chamber The DAAMS tubes will be used for qualitative confirmation analysis of chemical agents The sample inlet will be co-located with the MINICAMS™ HTSL distal end When the co-located MINICAMS^M alarms, the DAAMS tube wall be retrieved to confirm or refute the alarm 98) Annex B, page 28, Section 7 3 states that first entry monitoring is one complete cycle First entry monitoring should be at least two complete cycles Please revise the sentence Please explain in more detail how first entry monitoring is performed Is first entry monitoring done like it IS done for entering igloos at DCD'' How do you purge the sample line if you can't enter the area'' Please clarify The FEM for the EE will be conducted using one complete cycle preceded by a purge cycle to ensure the sample line is filled with the intended sample Personnel will also enter the Detonation Chamber to place the mumtions to be treated and, periodically, to remove ash and perform inspections FEM of the Detonation Chamber will also be conducted prior to personnel entering in the manner previously described The paragraph in question is redundant and will be deleted The FEM is covered in section 7 1 12 99) Annex B, page 29, Section 7 4 Please add the level, 0 5, that samples will be monitored to in the first sentence of the second paragraph Please delete the note about headspace monitoring for decontamination verification This should be discussed in decontamination plans Section 7 4 IS modified to reflect headspace monitormg is conducted using one complete cycle preceded by a purge cycle to ensure the sample line is filled with the intended sample Monitoring levels are addressed m Table 7-1 and depend on the item being monitored The sentence regarding headspace monitoring for decontamination verification was clanfied and verified for consistency with other sections 100) Annex B, page 29, Section 7 6 states that historical monitoring will operate only during agent operations This sentence seems to imply that historical monitoring can be stopped if agent munitions are not present Historical monitoring should be in operation shortly before the first munitions arrive until closure of the unit Please revise the sentence to make this clear Additionally, please clarify m the text that historical DAAMS tubes will be pulled and analyzed every 12 hours with the exception of the stack which will require tubes to be analyzed every four hours Section 7 6 IS designed to be an overview of historical monitonng Details for each histoncal location (including sampling frequency) are addressed in section 7 2, which is renamed DAAMS Monitoring Historical monitoring of the filter stack exhaust (i e , WPL DAAMS) wall be collected and analyzed every 8 hours dunng daily destruction operations 101) Annex B, page 29, Section 7 7 discusses vapor screening or samples prior to sending them to the on-site lab For off-site analytical such metals and organics, is an extraction procedure Page 31 of 45 performed prior to shipment off-site'' Which lab performs these analyses'' Please clarify in the last sentence that this vapor screening applies only to samples going to the site lab and not for waste characterization. Section 7 7 IS renamed for clarity The section addresses sample container monitoring Sample containers going to the site (mobile) lab will be headspace-monitored pnor to transport Regarding the samples themselves, all residues sent to off-site laboratories for fiirther analysis will be analyzed on site by the ECBC lab to verify that agent is not present above the WCL This analysis is performed via solvent extraction 102) Annex B, page 29, Section 7 7 states that vapor screening will be conducted in accordance with ECBC lOPs and DA PAM 385-61 Will these requirements be included in the analysis plans and SOPs referenced on page 36 of the Explosive Destruction Technology (EDT) Destruction Plan to be reviewed by the Division'' If not, the requirements should be spelled out in this section Additional information is added to section 7 7 103) Annex B, page 30, paragraph 8 0 states that ECBC Sample and Analytical Methods will be used to characterize waste Will these methods be provided m the Analysis Plan and Analysis SOPs listed on page 36 of the Explosive Destruction Technology (EDT) Destruction Plan'' If not, they need to be provided for review and approval Analytical methods will not be included in the Destruction Plan, but will be provided to the State 104) Annex B, page 30 paragraph 9 3 states that the EG&G Site Safety and Health Officer may be notified of NRT alarms Since EG&G is the operator responsible for all facility operations under the EG&G permit, this should state that EG&G will be notified of all NRT alarms no matter what the situation Paragraph 9 3 references Table 9-1 (NRT Notification Matrix) The EG&G Safety Office and TOCDF Environmental Shift Rep are required to be notified for all NRT alarms Upper EG&G management notification will be through the notified EG&G representatives 105) Annex B, page 30, Section 9 4 discusses who will be notified of DAAMS sample results All DAAMS sample data should be sent to an EG&G quality assurance person for verification of data regardless if agent was detected or not Please revise the paragraph Upon completion of ECBC internal quality review, data will be transmitted to EG&G for verification 106) Annex B, page 31, Table 9-1 In the Possible Action column of the table, only the first row lists Analyze DAAMS tubes as a possible action Is this because anything besides a single cycle alarm is being considered agent detection and does not need confirmation'' This could also imply that the DAAMS tubes are being pulled after the first cycle alarm The tubes should not be pulled until the NRT has stopped alarming Please clarify this language The DAAMS station sampling above the DAVINCH door should require a QP sample along with the air sample for Page 32 of 45 verification Please provide a narrative in the monitoring plan detailing when and where QP samples will be used This table will be modified to add "analyze DAAMS tubes" to each section Since ECBC will conduct a 28-day initial and continuing baseline studies, QPs will be rotated daily in accordance with continuing baseline study requirements 107) Annex B, page 31, Table 9-1 In the three alarms row, the possible action column, it states that filter system MINICAMS could be relocated to a post-bed location Isn't there already a monitor at that location, PM13'' Each individual filter system has a dedicated MINICAMS that can stream-select between mid- bed and post-bed for that filter system The standard operational configuration is to monitor the mid-bed of each filter 108) Annex B, page 32, Table 9-2 The table formatting needs to be fixed How many historical DAAMS stations are located in the EE and EE exhausf A review of Table 7-1 seems to show that they are all for confirmation Please clarify the information in the Quality Assurance Requirement row. The DAAMS tubes on this station should be sampled and analyzed every 12 hours The number and location of DAAMS samples in Table 7-1 will be updated to reflect all historical and confirmation locations There will be one historical DAAMS location in the EE and one at the filter stack The WPL tubes will be collected and analyzed for 8 hours Table 9- 2 will be revised All historical tubes are analyzed 109) Annex B, page 33, Section 9 5 mentions the Chemical Agent Worker Population Limit (WPL) Excursion Plan but does not provide any details Please provide the details of this plan in this section A WPL excursion plan will be provided prior to operations 110) Please provide a copy of the DA Memorandum Performance Standard for Monitoring Potentially Exposed Workers mentioned in paragraph 10 on page 33 of Annex B. Does EG&G currently follow this documenf Does this document meet or exceed the current requirements for EG&G'' The Department of the Army (DA) Memo is included with this submission The ECBC procedures meet the requirements of the DA memo See Enclosure AA 111) Will the ECBC LMQCP and the lOPs mentioned in paragraph 11 0 on page 33 of Annex B be part of the documents to be submitted for the Division review listed on page 36 of the Explosive Destruction Technology (EDT) Destruction Plan'' If not, they need to be provided for review and approval The documents referenced will not be included in the Destruction Plan, but will be provided to the State Page 33 of 45 112) Annex B, page 33, Section 111 Method validations will need to be approved by the Executive Secretary prior to implementation P&A studies will be in accordance with TOCDF procedures Class III methods are not approved at TOCDF unless justification is provided and approved Method validations will not be available until ECBC is on site, and method precision and accuracy studies are complete Based on previous State approval for CMA Non-Stockpile operations (Dugway EDS) and in accordance with CMA guidance, ECBC uses a class III NRT confirmation method Although the method is officially qualitative, ECBC reports any detectable amount of agent in a confirmation method sample 113) Annex B, Table 11-1, page 34 Please specify the limits of 60-140% for line challenges and 75-125% for calibration and instrument challenges Table 11-1 is revised to show an instrument calibrations and daily challenge tolerance range of 75 to 125% Paragraph 11 8 specifies a sample line challenge tolerance range of 60-140% 114) Table 11-2 on page 35 of Annex B needs to be reformatted to show the missing text in the Frequency column and the Corrective Action column The format is revised so that it is legible 115) Annex B, page 33, paragraph 111 and 1112 mention the use of mobile criteria which seems to provide the operator with a different set of certification criteria Please explain the difference and why mobile criteria would be applicable to the DAVINCH operations If mobile criteria are to be used, please specify which instruments it will apply to Any mobile criteria should follow procedures approved in TOCDF Permit Attachment 3 The reference to mobile criteria is deleted There are no plans for mobile NRT monitors 116) Annex B, page 33, Section 1112 discusses baseline method certification and validation and references the CMA LMQAP Initial alternate baseline study method certification requirements will need to follow the bolded sections of TOCDF's alternate baseline requirements of Attachment 3 to the TOCDF Part B Permit Please state which stations will use alternate baselines and which stations are defined as mobile stations These station definitions should not be a moving target Monitoring cessation greater than 60 days will require an alternate baseline to be conducted in accordance with TOCDF's procedures Monitoring cessation less than 60 days should follow procedures in Attachment 3 to the TOCDF Part B Permit The EDT project will perform standard initial (28-day) and continuing baseline studies 117) Annex B, the QC requirements in Tables 11-1 and 11-2 cannot be evaluated until the lOPs have been submitted for review The QP acceptance range of greater than 10% is not acceptable Some parts of Table 11-2 seem to be cut off Please reformat the table as needed Both Tables 11-1 and 11-2 have been reformatted 118) Annex B, page 36, Section 112 The calibration plans will need to be provided in specific procedures for review and approval or specifics will need to be documented in this plan Page 34 of 45 Calibration information for MINICAMS and GC/MSD systems will be added to section 112 119) Annex B, page 37, Section 11 2 1 The generic "may use" is not definitive Will the lab use performance charts for tracking performance'' If not, how will the performance be monitored'' Will ECBC provide a QC person onsite to review day-to-day data validation'' The use of performance charts is optional under the CMA and ECBC quality control programs, and the ECBC will not use them ECBC is providing onsite QC personnel, so the data QA/QC review will be conducted onsite 120) Annex B, page 37, Section 113 Please provide a site-specific table of the required QC for each procedure performed instead of the reference to the CMA LMQAP Section 11 3 IS updated, and references to the LMQAP have been removed 121) Please provide the sample frequency for NRT QP samples as mentioned in paragraph 11 3 1 on page 38 of Annex B Section 11 3 1 IS revised to read All NRT monitors methods used dunng operations will be challenged via OP samples immediately following calibration and at the end of daily operations If no operations occur on a given day, a challenge will be performed at least once during the day These challenges will be designated as continuing baseline challenges If two consecutive challenges fail to meet acceptance criteria, corrective action and data qualification is required for all readings above 0 25Z according to the frequency identified in the CMP LMQAP The QP challenge shall deliver agent to the instrument at 1 0 VSLZ 122) Annex B, page 40 Section 114 2, second paragraph discusses how corrections to errors will be documented Along with initialing the "cross out" the date of the correction should be included The paragraph is revised to read The sample identification system shall be documented, along with a method that relates the field data to the samples All documentation of the samples shall be performed in permanent ink If corrections are made to the data, the error will be crossed out once and initialed and dated by the person documenting the data All field notebooks shall become part of the project files 123) Annex B, page 40, Section 114 3 Samples will need to be analyzed for agent prior to shipping to an off-site laboratory Which laboratory will perform this analysis, TOCDF or ECBC All residues sent to off-site laboratories for any analysis will be analyzed on site by the ECBC lab to verify that agent is not present above the WCL This analysis is performed via solvent extraction Page 35 of 45 124) Annex B, page 41, Section 115 1 states that reports will be transmitted to EG&G on a monthly basis EG&G, as the operator responsible for the proper operation of this unit, should have access to this data on a daily basis Upon completion of ECBC internal quality review, data will be transmitted to EG&G for verification 125) Annex B, page 41, Section 115 2 discusses calibration curve data All calibration curve limits will need to be specified and approved prior to implementation Statistical analysis of calibration curve data will be addressed in the update of section 112 126) Annex B, page 41, Section 115 3 Data validation will need to be completed by an independent reviewer prior to waste being shipped off-site Will TOCDF QC personnel be the independent reviewer'' Upon completion of ECBC internal quality review, data will be transmitted to EG&G for verification 127) Annex B, page 43, Section 13 0 EDT personnel will need to meet the TOCDF requirements for those positions (e g, monitoring personnel, agent chemist, etc ) The ECBC will qualify and certify all monitoring and laboratory personnel in support of the EDT project 128) Additional comments for Annex B Narrative or conditions need to be added for the following a Please explain what operations will cease until DAAMS analysis information is available following an NRT alarm Operational issues are addressed in the Destruction Plan b All permit controlled agent monitors that are off line for more than 1 5 hours to have the DAAMS tubes analyzed as the primary monitor The ECBC can analyze NRT confirmation tubes for Resource Conservation and Recovery Act (RCRA) NRT stations that are offline for more than 1 5 hours AH data from confirmation tube analysis will be Class III data c All sample line challenges will need to be performed through the NOx filters The NOx filters will not be used for NRT sample lines, only DAAMS stations The DAAMS stations for this project do not have sample lines d Stack monitors need to be challenged at the distal end of the sample line Page 36 of 45 The TOCDF does not concur with the need to challenge the stack momtors at the distal end of the sample line The DAVINCH''"'^ is a batch process that will process up to 21 chemical munitions and a maximum of 164 pounds of agent per day during the day shift, four days a week A direct comparison of DAVINCH^"^ operations to a baseline incineration facility that operates 24 hours a day with a permitted capability of processing 58,000 pounds of agent per day is not pertinent Additionally, the TOCDF incinerator NRTs are configured with Dilution Air Flow Controllers (DAFC) because of the high moisture content of the exhaust gas The DAFC allows the NRTs used to monitor the incinerator exhaust ducts and the TOCDF Common Stack to be challenged at the distal end without removing the probe from the exhaust stack The DAFCs are used only at the PMI sampling location monitoring To perform a distal end challenge of the NRTs monitoring the stack, which combines the flows from the DAVINCH™ and DAVINCH™ EE HVAC carbon filters, would require the probes to be removed from the stack for each challenge since this monitor is not equipped with a DAFC Operational history for mustard agent monitoring has not shown a loss of probe and sample line performance in regards to agent transfer to the monitor over time when the sampled air IS clean The exhaust gas passing through the monitoring location in question (i e , the combined DAVINCH'^'^ and EE HVAC filter exhaust stack) is expected to be free of contaminants that could cause degradation of the NRT response due to sample transmission issues considering • The exhaust gas is primarily EE ventilation air, which is the breathing air for workers in the EE This air passes through carbon filter units equipped with HEPA filters before reaching the sampling location The exhaust gas passing the sampling location IS also primarily EE HVAC air (see flow rates shown on process diagrams in Aimex D of the Destruction Plan) The DAVFNCH''"'^ exhaust gas also passes through a HEPA-filter-equipped fixed- bed carbon filter before reaching the sampling location Note distil end challenge will be performed on the PMI monitors by virtue of the monitors being equipped with DAFCs e The change out frequency for NOx filters should not exceed seven days The NOx filters will be replaced with the frequency indicated in the ECBC DAAMS lOP, which has been shown to be adequate for experience f Calibration and challenge frequencies need to be spelled out and not make reference to additional documents that are not part of the permit or have not been provided as supporting documentation Calibration information for MINICAMS and GC/MSD systems will be added to section 11 2 Page 37 of 45 g All monitoring equipment exhaust will need to be vented to appropriate engineering controlled areas or through a carbon filter It IS ECBC practice to vent all monitoring equipment exhaust to engineering controls or to carbon filters h All DAAMS methods will need to be Class 1 methods or any peak in the agent retention time window will be considered a confirmed alarm Based on previous State approval for CMA Non-Stockpile operations (Dugway EDS) and in accordance with CMA guidance, ECBC uses a class III NRT confirmation method Although the method is officially qualitative, ECBC reports any detectable amount of agent in a confirmation method sample I Versar/ECBC will need to meet the requirements of the TOCDF monitoring plan and the TOCDF LMQAP References to CMA documents should be references to TOCDF documents or should be removed and specific requirements placed in the documents The ECBC will use their LMQCP, which meets the requirements of the CMA LMQAP and MCP The EDT project will perform standard initial (28-day) and continuing baseline studies J A corresponding QP will need to be sampled with all headspace monitoring of treatment Results of the QP must be between 75-125% All stack DAAMS samples will need to have a corresponding QP The NRT headspace monitoring will utilize at least one QP sample Since ECBC will conduct a 28-day initial and continuing baseline studies, QPs will be rotated daily in accordance with continuing baseline study requirements k Any NRT alarm on a monitor without a co-located DAAMS station for confirmation is considered a confirmed alarm This should be placed in the text of the monitoring plan All NRT stations will have co-located DAAMS confirmation 1 QP samples will need to be sampled and analyzed for all permitted stations daily with the corresponding DAAMS tubes, all NRT are required to be challenged daily or more frequently (every four hours) depending on location Since ECBC will conduct a 28-day imtial and continuing baseline studies, QPs will be rotated daily in accordance with continuing baseline study requirements m QL will need to bracket the sample analysis (beginning and end) and every 20 samples QL must meet the 85-115% recovery The ECBC will analyze QL samples as continuing calibration verification samples in accordance with Table 11-2 Page 38 of 45 129) Annex C, page C-2, paragraph 7 0 should be revised to read, "The inspection forms will be maintained on-site at the EDT for review access " The suggested change is mcluded m the revised Annex C mcluded with the submission 130) Annex C, Table C-1, page C-3, Item 1(c) Wouldn't the lid potentially sustain the same type of damage as the outer shell and inner liner'' Shouldn't it be inspected for the same things'' The inspection of the lid is added to the inspection critena 131) Annex C, Table C-1 There are several items in the table that do not belong as permitted inspections The following items typically are not listed in permit controlled inspection schedules Items 11,12,13,14,15, and 16 Please explain why these items are included in the schedule The referenced items are deleted from the inspection tables 132) Annex C, Table C-1, Item 31 Please clarify the challenges are performed daily or every four hours (stack) System verification such as heated lines, connection, gases may be inspected three times a week Stack monitor sample lines will be challenged at the same frequency as all other sample lines on site PMI4, the stack location NRT monitor, will be challenged at the instrument everyday at the start and end of daily destruction operations System verification checks will be performed weekly 133) The inspection forms will need to be reviewed and approved prior to being used but do not need to be incorporated into Annex C The inspection forms will be available for DSHW review pnor to the beginning of DAVINCH™ hazardous waste operations 134) Annex E, page E-4, first paragraph after the bullet list discusses decontamination solutions in general and references Army Field Manual 3-5 and Table 1 from 40 CFR 268 45 Because it is not the intention of EG&G and Versar to dispose of the DAVINCH, the criteria listed in Table 1 does not apply This paragraph should simply list the types of decontamination solutions that are to be used and why each is appropriate for chemical agent decontamination More detail should also be provided on cleansing shots and ECAD and their purposes A description of the purpose of cleansing shots is added to page E-4 A cleansing shot refers to the practice of placing donor explosives in the Detonation Chamber to remove contaminants from previous detonations of chemical munitions Chemical mimitions are not added to the chamber during a cleajising shot The entire energy of the explosive added is for the purpose of destroying any residual agent that may reside in the chamber as determined through agent monitoring Additionally, a cleansing shot may be used as a best practice for operators of Detonation Chambers The DAVINCH''''^ is only one type Detonation Chamber, there are others, and all use cleansing shots as a means of decontaminating their Detonation Chambers Page 39 of 45 135) Annex E, page E-5, first complete paragraph on the page and page E-10, first paragraph following the bullet list, top of page £-11, second paragraph on page E-12 These paragraphs mention wipe sampling as a means to determine if decontamination has been adequate See Comment 1 regarding this subject References to wipe sample have been removed from Annex E 136) Annex E, page E-5, Table E-1 The value, 0 003 mg/m^, shown in the table as the air monitoring performance standard is not an eight-hour TWA as stated in the table. This value is actually the STEL, which is a 15-minute exposure limit The value in Table E-1 has been revised and is now referenced as 1 VSL This value is chosen because the DAVINCH™ and associated equipment will not be disposed of upon completion of operations at the DCD Rather, the DAVINCH''"'^ will be disassembled and transported to a Federal installation whose workers are trained in chemical agent operations, particularly the operation of EDT systems It will be put in storage until another application for its use arises 137) Annex E The closure plan should specify the 10 step process as specified in the CAMDS closure procedures Please review the current CAMDS closure plan to ensure that closure of the DAVINCH follows a similar process Wipe sampling for verification of decontamination will not be accepted An approved decontamination plan will need to be used to accomplish closure of the unit The requirements included in the CAMDS closure plan are not applicable to the DAVINCH'^'^ since the DAVINCH™ and associated equipment will not be discarded after completion of the TOCDF project Rather, the DAVINCH^'^ will be decontaminated, disassembled, and transported to a Federal facility and stored by an organization whose personnel are trained chemical workers 138) Annex E, page E-6, Table E-2 In the first row in the Sampling Conditions column, the word "equal" between "to" and "equilibrium" should be changed to "reach " The suggested change is made to Table E-2 139) Annex E, page E-6, Table E-3 The SOPs and lOPs listed in the Analytical Methods column of this table should be submitted for review and approval as part of the documents listed on page 36 of the Explosive Destruction Technology (EDT) Destruction Plan See response to DSHW Comment 11 140) Annex E, page E-8, last paragraph This paragraph states that the Versar EDT Program Manager will certify closure This should state that the Versar EDT Program Manager and a qualified Professional Engineer will certify closure Additionally, EG&G and Versar should be aware that they must comply with Permit Condition IIJ 7 regarding notification of closure The requirement that a Professional Engineer Certified in the State of Utah will certify closure is included m the revised Annex E Page 40 of 45 141) Annex E, Appendix E-1 does not discuss the sampling procedures to be used to verify decontamination of the exhaust gas treatment equipment The procedure lists several methods for sample collection, catch/grab and wipes but does not specify anywhere in the procedure where they are used More detail is needed Appendix E-1 to Annex E was revised to provide more detail on how agent monitonng will be used during decontamination of equipment when operations are complete 142) Annex E, Appendix E-1 lists only one target analyte Additional target analytes should be listed including metals and organics to allow for proper closure of the unit Since the DAVINCH^"^ and associated equipment will not be discarded upon completion of operations at DCD, the equipment must be decontaminated to the point that it can be transferred to its intended storage location The waste residues generated during closure will be analyzed for the same analytes as those same waste residues that are generated during operations 143) Annex F, page F-2, Table F-1 states that TOCDF fire response will be dispatched in the event of a fire at the DAVINCH site Shouldn't this be DCD fire response since they are responsible for responding to all fires at TOCDF and TOCDF operated facilities'' Aimex F was revised to make reference to the DCD Fire Department 144) Annex F, page F-2, Table F-1 The acronym TOCDF is misspelled in the third column of the fourth row The suggested correction is included in the revised Annex 145) Annex F, page F-2, the last sentence on the page does not make sense and needs to be revised The sentence was revised as requested 146) Annex F, page F-3, the third and fourth paragraphs under 112 mention the TOCDF Fire Department Shouldn't this be the DCD Fire Departmenf Annex F was revised to make reference to the DCD Fire Department 147) Annex F, page F-4, the last bullet under 113 1 should be revised to read, "Placing absorbed or pumped material into DOT-approved containers and managing appropriately in accordance with all applicable permits and rules " The language as proposed would not allow any flexibility in management of the waste The bullet was revised to read • Placing absorbed or pumped material into DOT-approved containers and managing appropriately in accordance with applicable permits and rules Page 41 of 45 pertaining to hazardous waste management and spill reporting for hazardous material 148) Annex F, page F-4, the flfth bullet under 113 1 mentions following procedures from DA PAM 385-61 Please provide the details from this document in the narrative The bullet was revised to read • Decontaminating the release area using installation policies and DA Pam 385-61, including use of approved decontamination methods, including use of decontamination solutions, and post-decontamination monitoring via MINICAMS to the 1 0 VSL level, at 1 0 WPL, as needed 149) Annex F, page F-5, the last paragraph on this page deals with exposure to CWM Shouldn't this paragraph be located under 113 2 Events Involving CWM instead of under 113 4 Industrial Accidents and Medical Emergencies Assistance'' The section also addresses Medical Emergencies Assistance The paragraph remains in the same section as before, but was revised to read For medical emergencies involving CWM exposures, personnel shall follow the TOCDF Contingency Plan Additionally, procedures relative to medical monitoring and post-exposure results are established by the TOCDF Medical Director and will be adhered to in the event of individual exposure 150) Annex F, page F-6 and F-7, Sections 113 8 and 113 9 Please provide details that explain how EDT personnel would secure the unit in the event of an evacuation or severe weather event that occurs after a shot has been set up but not performed yet A paragraph was added to each section to describe how personnel secure DAVINCH''''^ operation if required due to evacuation or severe weather 151) Annex F, page F-7 and F-8, Section 1 1 3 12 should also state that approval of the Executive Secretary is required prior to the resumption of EDT operations The affected paragraph was revised to read Formal accident investigation will be conducted by the CMA/supporting safety office in accordance with procedures identified in AR 385-10 Should changes to EDT operations be required, those changes will be approved by CMA Risk Management Division (RMD), ECBC Risk Management Office (RMO), and the supporting safety office prior to resumption of EDT operations Approval of the Executive Secretary is required pnor to the resumption of EDT operations 152) Annex F, page F-8, Section 1 2 1 Please delete the words, "at TOCDF" at the end of the paragraph Page 42 of 45 The suggested change is incorporated into the revised Annex F 153) Annex F, page F-9, the final sentence on this page states that WPL excursions will be reviewed annually to determine any trends This project is short term. Excursions need to be analyzed more often to determine if there are any trends Please revise this with a term more appropriate to the time frame of this project such as weekly The paragraph is revised to read Investigations of all WPL excursions will be performed to determine the cause, control the source, and prevent fiiture occurrences of the excursion Techniques for controlling excursions might include conducting additional monitoring, reviewing operational procedures, evaluating engineering controls, and/or other procedures as determined by the SHO and EDT Site Manager All information relevant to the investigation wall be provided to the TOCDF Clinic Instances of excursions will be reviewed or analyzed at least monthly to determine any trends 154) Annex F needs to contain reporting requirements or make reference to the appropriate permit conditions similar to paragraphs 9 4111 and 9 8 found in Attachment 9 of the TOCDF Part B Permit The notification and reporting section of Annex F was revised to read 113 11 Notification and Reporting The primary responsibility for notification will he with the Crew Chief with assistance from all other field personnel Table F-1 (shown previously) provides information for the responsible person or agency notification In accordance with the appropriate Permit Conditions, the Executive Secretary shall be notified within 24 hours if there is a confirmed agent concentration in the DAVINCH"^** PAS and Environmental Enclosure Combined Stack that is equal to or greater than 1 Vapor Screening Limit (VSL) Required reports are made in accordance with R315-8-4 7(i) & (j) and TOCDF Part B Permit Conditions The operator must note in the operating record the time, date, and details of any incident that requires implementing the Contingency Plan For any emergency event requiring HAZMAT release reporting, the Control Room will notify the DCD EGG and the CMA Shift Engineer, and provide a copy of the event report All reporting to the Army, local. State, and Federal agencies will be handled by DGD 155) Annex F does not detail how personnel on site in the various buildings will be notified of an emergency Please provide this detail The DAVINCH site is equipped with an air horn that is used to notify the personnel in the different trailers of an emergency 156) Is there a process or contingency for retreating or handling material from a shot if there IS a mechanical failure or agent release problem'' Please explain Page 43 of 45 If chemical agent remains in the Detonation Chamber after the detonation (as determined by the NRT located at the PM2 sampling location (see Armex B or any Process Flow Diagram drawing) a cleansing shot will be used If there is visible explosive remaining in the chamber after a detonation an Ordinance Disposal (EOD) Team will be brought onsite to "render safe" the explosives before operations resume The DAVINCHi""^ system will undergo testing during the systemization and Operational Readiness Review (ORR) when SETH rounds will be overpacked in the configurations as the actual munitions to be processed, and detonated 157) Annex G, page 2, Section 1 1 in the second bullet the word TOCDF is misspelled the second time it occurs The suggested correction is incorporated into the revised Armex G 158) Annex G, page 2, Section 1 1 The list of applicable documents should include the Explosive Destruction Technology (EDT) Destruction Plan and Annexes and the plans hsted on page 36 of the Explosive Destruction Technology (EDT) Destruction Plan Please provide the Division with a copy of the Kobe Steel Training Plan listed under Section 1 2 The training of the operator is scheduled to be conducted in early February 2011 A copy of the training plan will be provided to DSHW when one is made available to TOCDF 159) Annex G, page 6, the fifth paragraph discusses the management of waste in a container following detonation and clean-up of the detonation chamber The satellite accumulation and 90 day area rules will apply to DAVINCH operations The TOCDF and DAVINCH™ operators intend to establish satellite and 90-day accumulation storage locations wathm the EE 160) Annex G, page 23 In the first line of the first paragraph, the word "began" should be "begin " The suggested correction is incorporated into the revised Annex G 161) Annex G Please provide clarification as to which of the training courses listed in Annex G will meet the requirements of R315-8-2 7(a) (3) The following has been added to the revised Annex G • The requirements in Utah R315-8-2 7(a) (3), which include 40-hour OSHA training and refresher training carried by all operators prior to arrival at the site, this includes, but is not limited to (i) Procedures for inspection, use, repair, and replacement of facility emergency and monitoring equipment (See Appendix 1, CBARR pre- deployment training), (ii) Communications or alarm systems (See Sec 3 13, Site Specific Training), Page 44 of 45 (ill) Key parameters for automatic waste feed cut-off systems (not applicable), (iv) Response to fires or explosions (See Sec 3 13, Site Specific Training), (v) Response to groundwater contamination incidents (See Appendix 1, CBARR pre-deployment training), (vi) Shutdown of operations (See Sec 2 3 1, EDT Operator Training) 162) Attachment 2, page 16 states that the remaining SETH and overpacks used in testing are in storage at both locations How many SETH and overpacks are available at DCD for systemization and testing of the equipment on site'' There are sufficient SETH and overpacks available to conduct systemization testing Prior to processing the overpacked agent-filled munitions, TOCDF intends to test the DAVINCHi""^ system using overpacked SETH munitions The SETH rounds will be overpacked in the same manner as the actual munitions, and will be prepared with donor and shape charges in the same configuration as the munition/overpack combination that they are intended to represent The DSHW will be notified as to the date and time of this testing so that they may be present This testing will occur toward the end of the ORR 163) None of the drawings in Attachments 3 or 4 have PE stamps Utah law requires that plans, specifications and reports prepared by or under the supervision of a professional engmeer must bear the seal of the engineer when files with public authorities Please have the most current revision of all drawings stamped as appropriate and re-submit them The Piping and Instrumentation Diagrams (P&IDs) have been reviewed by a Professional Engineer licensed in the State of Utah These drawings, bearing that seal, are included with this submission in electronic format Page 45 of 45 Enclosure AA Performance Standard for Monitoring Potentially Exposed Workers Memo EXPLOSIVE DESTRUCTION TECHNOLOGY (EDT) DESTRUCTION PLAN Submitted to: EG&G DM I. Inc/URS 11600 Stark Rd. Stockton, UT 84071 Subcontract DMB51843 Submitted by: (^VERSAR Versar, Inc.© 6850 Versar Center Springfield, VA 22151 X^ovemberJOlO Deleted: April 201011 TABLE OF CONTENTS LIST OF TABLES I\ LIST OF nGl^RES I\ EXEClTn E SITVIM \R\ \ 1.0 INTRODUCTION 1 1.1 1.2 1.2.1 I.:.: 1.3 1.4 1.5 /. /. /. /. /. /. 1.6 /. /. /. /. /. 1.- /. /. 1.8 /. /. /. /. /. /. /. PliRPOSE I ITEMS TO BE DESTRO^XD I Tiii'iifi MiiiiiiioiL, J Fill \ liiifiiiih 2 APPRO\ \L PROC ESS -I HISTORIC AL PRECEDENT FOR EDT ^ SITE DESC'RIPTION(LNC'HT)LNC SITE PREPARATION REOHREMEINTS) ^ Eyiiiiiii^ Piivfil 9 iiliiiiiiiiiriiiivf 9 EDTSiic 9 Siiiiiiiiii 9 iililiiioiiiil (jdii' 9 Rfiiiicifil iccfii 9 E^lERCENC'^ PLAMNINC ANDCoNTlNCElNC•^ OPERATIONS 9 Siif Spfcific Siiffiy Pluii 9 Pivvfiiiioii of Siiililfii Ri'li'dii'i lo ilif Ein iroiiiiii'iii 10 Fiir PiYVfiiiioii 12 <. oiiiiiiiiiiiciiiioii Sviii'iii /.•' S/Ji'll Ri'i/joiiii' /.•' MONITORING I-I Siiffiy Mr Moiiiioiiiiii / -I Moiiiioriiiii Poiim N EG&G. TOCDF. AND DCDSl'PPORT I-I Ei/iii/jiiii'iii Eiiciliiifi /.i L'liliiifi /.i SiTiiiiiy /.i Sill' PiYpiirniioii /.i 0/Ji'r<iiioiii Sii/j/jori /.i Pliiiiiiiiiii Pfniiiiiiiiii I6 EDT Ojjfruiioiis lb 2.0 S\ STEM DESCRIPTION 17 2.1 2.3 0\TiR\nEw r i.'oiicfpi of 0/Ji'r<iiioiii /' Sviii'iii Di'iii^ii Ri'i/iiiiviiii'iiii /' ENVIRONMENTAL ENCLOSIIRE(EE) DESCRIPTION IS D-117.V(. //TM f onuiimih-m /S EE Opfniiiiiii -Ircm Z*! MAINTEINANCT: REQI'IREMENTS 19 Moiiiioriiiii Emii^if Dniiuiiif 19 Pivvfiiiivf Miiiiiifiiiiiicf 19 Ei/iiipiiii'iii Miiiiiifiiiiiicf Sclifiliilf 19 TABLE OFCONTENTS (conlinued) 2.4 DESIGN PEATiTiES 2n J. 4.1 Dfioiiiiiioii <. Iiiiiiil'fy 20 2. -1.2 <. Iiiiiipiiiii Sviii'iii 21 2.-/.J MiiiiiiioiL, Hiiiiilliiiii liniiilliiiioii in i.'liiiiiil'fr 21 2. -I.-I i.'liiiiiil'fy Door \\<j\iil'lf Phil form 21 2.-/J 0(f-(J>i^ Eihcr 21 2.4.6 d(f-fJiii Hfiiifr 21 2.-I.' f'oolfi- 21 2.4. S 0(f-fJii!, .Sviifiii 21 2.4.9 V'liciiiiiii Piiiiipi 2.4.10 (. old Phiiimi OriJizfi- 22 2.4.11 f'oolfi- 22 2.4.12 Snubbcr 22 2.4.1 J SaOH Tank 22 2.4.14 0(f-iJ,i:, BloM fi- 22 2.4.1.^ Rfifiiiioii Tiiiik _V 2.4.16 Hfiiifr 2.^ 2.4.1' I. iirl'oii Eilifi-i 2J 2.4.1^ Eyiiiiiiii Mr Blow fi: 2J 2.5 OTHEIR SiippoRT EQI'IPMENT 23 3.0 EDT OPERATIONS 25 3.1. S^STE1M DELFV E1R^ 2^ J.I.I. Traiiiporidiioii mul Dflivfiy of Main i.'liiiiiil'fr mul iiiocinifil i.'oiiipoiifiin _V .•'./._''. Traiiiporidiioii mul Dflivfiy of Off-^Jiis TiYniiiifiii .Syni'iin _V .•'./..•'. Dflivfiy of.Siippori Ei/iiipiiu'iii _V 3.2. S^STE1M INSTALLATION 2^ 3.3. S^STEl^^z.ATlON 2" 3.4 OPEIRATIONAL READINESS RE\ [E\S 2" 3.5 OPEIRATIONS 2" / Opfrniioiiiil .Sii'pi 2^ 2 Donor i. 'luiriif J"i J <. Iiiiiiil'fr PiYpniiiiioii for Dfioiuiiioii 29 4 Implosion wiili Donor <. 'li<iri^i' 29 .i 0(f-(j<ii TiYiiiiiifni iiml Mr Plow P/jmci 29 3.6 THROIIGHPIIT 33 3." OPERATING PROCEDiTiES 3') 3.8 SCHElDliLE 3') 3.9 CLOSirRE 36 3.10 DESCRIPTION OFOc•cn'ANC'^ AND DESTRIICTION OF BnLDLNGS\MTHiN PifBLic-ACC ESS EXGLliSION DlSTANC E(PAED) 3S 3.11 W ASTE ANAL^SIS PLAN 3S 3.12 PEIRSONNEIL Li\nTS AND PROTECTr\x EQITPMENT "(S J. 12.1 Mrl'oriif EypoiniY Liinin i -\ELii '6 J. 12.2 EypoiniY Poinn '6 J. 12. J Pi'noiKil Proifciivf Ei/nipiiu'iii '6 TABLE OFCONTENTS (conlinued) 3.13 MITIGATION OF HAZ.ARDS (LNGLiTUNG CoNTLNGElNC•^ PLANS) J.I 4.0 4.1 4.2 4.3 4.4 (. oniiiiniiifni Siiffiy in EncloiuiY PPE Eii Tcsiiiiii Eini'rt^i'nry mulEvucuniion.... Eiiifriifncy Rf^ponsf ^riiom. .\ Ifiliciil Suppori ORGANIZATION 79 U.S. ARM> "9 STATE OF UTAH "9 CONTRACTORS Sn EDT SITE OPERATIONAL ORGANIZ^ATION Sn 5.0 REFERENCES. 82 III List ofTiibies Table 1 Table 2 Table 3 Table 4 Table 5 Table 6 Table 7 Table S Table 9 Table lo (Characteristics ol" DCD Munitions 3 Projectei-I DCD In\ entorA- ol"(!)\ eq")ack Types ani.1 Munitions lo be Processei.1 in ihe EDT 4 (!)\eq")ack SpeciUcalions 4 Schei-lule lor Pre\ enli\ e Maintenance 2() TOC'DF EDT Throughput 35 Estimated Waste Generated from DAMNGH'^" Operations 39 TOODF DAMNOH'T^' Waste .Analysis Summary (On-Site) 41 TOODF DAMNOH'T^' Waste .Analysis Summary- (Orf-Site) 42 Role ol" Each (!)perations Group 4S .lob ani.1 (Qualifications E.\perience 4S List of Figures F gure 1. F gure 2 F gure F gure 4. F gure F gure 6. F gure 1. F gure S. F gure 9. F gure lo F gure 1 1 F gure 12 F gure 13 Munitions to be Destroyed by D.AMNGH'^" 2 EDT Proposed Site Location at TOGDF cS EDT Site Location in .Area lo 7 EDT Site Oven iew S Installation ani.1 ("ommissioning Schetlule 2cS (\inceptual Steps of DA\"rNGHTM :S Total DAMNGHT^" System 2S DAMNGH'T^'OlT-GasTreatjnent Phases 31 EDT Block Flow Diagram 32 Insii.le Ghamber before ani.1 after Gleansing Shot 37 E(^AD Operation 37 TOGDF EDT Overall Organization 4cS EDT Site (!)peration (!)rganization 47 .Annexes .ANNEX .A. .Acronyms ani.1 .Abbre\ iations ANNEX B. Monitoring Plan .ANNEX G. Inspection Plan ANNEX D. DAMNGHTM Operational Mode Diagrams ANNEX E. Glosure Plan ANNEX F. TOGDF EDT Emergency Response Plan .ANNEX G. Training Plan EXECUTIVE SUMMARY The United States (U.S.) Army Chemical Materials Agency (CMA) is responsible for destroying U.S. chemical warfare materiel. The Project Manager - Chemical Stockpile Elimination (PM- CSE), established in 2006 by merging the Chemical Stockpile Disposal Project (CSDP) and the Alternative Technologies and Approaches Project (ATAP), manages the safe treatment and disposal of chemical agents and weapons stored at protected U.S. Army sites in Alabama, Arkansas, Oregon, and Utah. EG&G DMI, Inc., (EG&G) is contracted by the U.S. Army to operate the Tooele Chemical Agent Disposal Facility (TOCDF) located on the U.S. Army Deseret Chemical Depot (DCD) in Stockton, Utah. EG&G has a requirement for a technology to process^33 reject munitions that _,, - -[ Deleted; 351 have a high probability of exhibiting conditions that would not allow them to be processed using baseline practices. Due to the apparent condition of the bursters and burster wells - and more importantly, the high risks associated with destroying the problematic munitions with baseline technology - new safer processes have been evaluated. The TOCDF researched other technologies used to destroy chemical weapons and determined that Explosive Destruction Technology (EDT) is the preferred alternative. Therefore, the DAVINCIF'^ Detonation In a Vacuum-Integrated Chamber (DAVINCIF'^) technology will be used to destroy the target munitions at TOCDF. This Destruction Plan describes the process and procedures for destroying and treating over- packed/leaking 4.2-inch Mortars, 155-nim Projectiles, and 47 samples containing chemical agent (CA). This process will run in parallel to TOCDF's current baseline operations. EG&G has contracted for services to include a detonation chamber, exhaust gas filtration system, environmental enclosure with an engineered cascade ventilation system, and all necessary subsystems and operators as a complete package that will be delivered to, installed, systemized, staffed, operated, closed, and removed from the DCD. The agent fills to be treated consist of mustard (H), distilled sulfur mustard (HD), and thickened mustard (HT). This Destruction Plan is based on procedures used at two international sites: Kanda Harbor, Japan; and Poelkapelle, Belgium, where the DAVINCH™ has successfully and safely destroyed over 5,400 chemical munitions. The plan provides a description of the operations and sampling strategy for this operation. The procedures described herein will ensure that the operation is conducted in a safe, secure, and environmentally-sound manner. EG&G is the lead for permitting with the State of Utah Department of Environmental Quality, Divisions of Solid and Hazardous Waste (DSHW) and Air Quality (DAQ), which will provide environmental regulatory oversight of the TOCDF EDT operations. These operations will be permitted under a modification to the RCRA and CAA Title V Permits issued to the TOCDF by the DEQ. 1.0 INTRODUCTION The United States (U.S.) Army Chemical Materials Agency (CMA) is responsible for destroying U.S. chemical warfare materiel. The Project Manager - Chemical Stockpile Elimination (PM- CSE) manages the safe treatment and disposal of chemical agents and weapons stored at protected U.S. Army sites in Alabama, Arkansas, Oregon, and Utah. EG&G DMI, Inc., (EG&G) is contracted by the U.S. Army to operate the Tooele Chemical Agent Disposal Facility (TOCDF) located on the Deseret Chemical Depot (DCD) in Stockton, Utah. EG&G has a requirement for a technology to process 351 reject munitions that may be difficult or unsafe to process using baseline practices. The TOCDF researched other technologies used to destroy chemical weapons and determined that Explosive Destruction Technology (EDT) is the preferred alternative. Therefore, the Detonation In a Vacuum- Integrated Chamber (DAVINCH'^'^) technology will be used to destroy the target munitions at TOCDF. The DAVINCH'^'^ will support TOCDF as the approved chemical munitions disposal site for over-packed leaker/reject munitions and agent samples. The DAVINCH™ is designed for a maximum allowable explosive charge of approximately 133 pounds (lb) of net trinitrotoluene explosive equivalent (TNTeq). The Chemical Warfare Munitions (CWM) are classified as Hazard Division 1.2 in Department of Defense Standard 6055.9; therefore, associated Quantity- Distance (Q-D) arcs are quantified as such. Descriptions of adjacent facilities, work to be done, and operations are included in this submittal. Additionally, CWM that are designated a waste destined for disposal are classified as hazardous waste in the State of Utah, see the Utah Hazardous Waste Rules R315-2-1 l(e)(l)^ The DAVINCH™ is a type of EDT that treats the chemical agent and energetic components of CWM through controlled detonation facilitated by donor and Linear Shape Charges (LSCs) within a detonation chamber. Deleted: leaking CWM are classified as hazardous waste in the State of Utah as described by Utah Hazardous Waste Code P999 The destruction of CWM is permitted and regulated by the TCODF Resource Conservation and Recovery Act (RCRA) Permit. By these regulations the DAVINCH™ is classified as a Subpart X Miscellaneous Treatment Unit. 1.1 Purpose This Destruction Plan describes procedures for destroying and treating overpacked/leaking 4.2- inch Mortars, 155-mm Projectiles, and samples containing CA. 1.2 Items to be Destroyed Figure 1 shows pictures of the two munitions (i.e., projectiles and mortars) that are to be destroyed by the TOCDF DAVINCH™. TT 4.2-inch Mortar 155-mm Projectile Figure 1. Munitions to be Destroyed by DAVINdFi^ 1.2.1 Target Munitions The DAVINCH™ system's design will accommodate TOCDF processing of the items shown in Tables 1, 2 and 3. 1.2.2 Fill Materials Documentation from DCD confirms that the stockpile munitions in question are filled with mustard (H/HD/HT), as shown in Table 2. The over-packed items have been assessed using an x-ray system that was conducted at Area 10 to determine the content levels, interstitial materials, and configuration of the munitions targeted for destruction by EDT. Table 1. Chiiriiclerislics of DCD Munitions Designation Munition Type Fill Explosi\es Comments Igniter: M9 Fuze: PD MS Burster: M14 (•threai.lei.1 on fuze) Length: 21.ol inches ('1S inches w 0 ignition cartritlge) Wii-lth: 4.2 inches Total Wt: 24.CS7 lb ( 22 lb w o M2A1* 4.2-inch Mortar HT. 5.S lb HD. cS.o lb E.\plosi\e: Tetry l E.\plosi\e Wt: 0.14 lb Propellant: McS Propellant Wt: Length: 21.ol inches ('1S inches w 0 ignition cartritlge) Wii-lth: 4.2 inches Total Wt: 24.CS7 lb ( 22 lb w o E.\plosi\e: Tetry l E.\plosi\e Wt: 0.14 lb Propellant: McS Propellant Wt: ignition cartritlge ani.1 propellant charges) o.cS lb Primer: M2SA2 Ml 04 1 55-m m Projectiles HD: 11.7 lb Fuze: None Burster: McS E.\plosi\e: Tetrytol E.\plosi\ e Wt: .41 lb Length: 2cS.S inch Width: cS.oS2 inch Total Wt: 95.1 lb .Aluminum Bakelite Fuze Gup Fuze: None Burster: McS E.\plosi\e: Tetrytol E.\plosi\e Wt: .41 lbs Length: 2cS.S inches Ml lo 1 55-m m Projectiles HD. 1 1.7 lb Fuze: None Burster: McS E.\plosi\e: Tetrytol E.\plosi\e Wt: .41 lbs Width: cS.oS2 inches Total Wt: 94.59 lb .Aluminum Bakelite Fuze Gup Samples NA 452 ml HD NA NA Samples NA S25 ml HT NA NA Table 2. Projected DCD Inventory of Overpack Types and Munitions to be Processed in the EDT Munition Type Single Overpack Double Overpack Munition Type M2A1 M13 M16 9x41 or 7x27 M16/M10 PA37/2 x 56 M16/12 x 56 4.2-inch HT mortar ( Deleted: lis 4.2-inch HT mortar 117 4.2-inch HD mortar 18 T ( Deleted: 20* 155-mm H projectile 68 155-mm H projectile 27 155-mm H projectile 16 155-mm H projectile 8 79 HT SAMPLES 41 HD SAMPLES 6 Deleted: * Estimated number of process leakers.^f Table 3. Overpack Specifications Over Pack Type Exterior Length (inches) Flange Diameter (inches) Wall Thickness (inches) Tube Outside Diameter (inches) Empty Weight (lb) 7x27 27.625 10.4 0.134 7.12 52 lb 9X41 44.1 13.4 0.134 9.25 1001b MIO A4 55 3/8 9.75 0.055 8-61/64 38 lb M16 A3 42 21/32 8.5 0.055 6-7/8 33 lb 12X56 52.25 15.0 0.134 12.0 135 lb PA 37 32 3/4 8.5 0.055 6-7/8 171b M 13 A2 27 1/2 7.75 0.055 6-13/64 14.6 lb Length Width Height M2 Al 11 5-9/16 6-51/64 N/A 5.75 lb 1.3 Approval Process Plans for using EDT at TOCDF will be submitted to the State of Utah Department of Environmental Quality (DEQ) Division of Solid and Hazardous Waste (DSHW) for approval before destruction begins. In addition, TOCDF will coordinate with the DCD, Department of Defense Explosives Safety Board (DDESB), the U.S. Army Technical Center for Explosives Safety (USATCES), and CMA. Concurrence/approval by UDEQ, DCD, DDESB, and USATCES will be obtained before implementing this Destruction Plan. 1.4 Historical Precedent for EDT The EDTs evolved from an increasing need to safely destroy recovered chemical warfare material (RCWM), and they have safely destroyed RCWMs in Pine Bluff Arkansas; Waianae, Hawaii; Porton Down, England (United Kingdom); Poelkapelle, Belgium; and Munster, Germany. Riot control gas and various mustard agents, with and without energetics, have been safely destroyed in EDTs. The EDTs have also proven effective for destruction of conventional weapons. The EDT operations are currently conducted safely and in an environmentally-sound manner. The system uses explosives as the primary means of destroying the munition, overpacks, and chemical fill through extreme temperatures, and pressures and shock waves. As of October 30, 2009, the DAVINdF"^ EDT technology has destroyed over 5400 munitions worldwide. 1.5 Site Description (including Site Preparation Requirements) The TOCDF is a multi-incinerator hazardous waste treatment and storage facility located within the federally-owned DCD, which covers about 7,900 hectares. The DCD is located in Stockton, Utah [approximately 56 kilometers (35 miles) southwest of Salt Lake City]. The TOCDF was designed and constructed for the treatment of the chemical agents and munitions stockpile currently stored at the DCD Area 10 (i.e., the Chemical Munitions Storage Area). Area 10 is immediately adjacent and physically connected to the northem end of TOCDF. Area 10 is operated by DCD and has secure, surety-rated access control, perimeter monitoring, appropriate fencing, and an around-the-clock guard force. The EDT will be located in the northem end of the Open Storage area, between Road C and Road D. The permanently occupied areas of Area 10 include, but are not limited to, the administration and guard areas near the main gate on the south side. There are temporary activities ongoing in existing igloos near the EDT site. Design criteria used for the EDT site include: Altitude (above sea level) - 1557 m (5150 ft) Maximum Temperature - 37 °C (93 °F) (dry bulb) Mmimum Temperature - -17 °C (1.4 °F) Monthly Rainfall (max) and mo. -5.13 inches Rainfall in 1 hr - 0.94 inches Average Total Precipitation - 13 to 16 inches Relative Humidity - Maximum, 88 %; Minimum, 15 % Maximum Basic Wind Speed - 90 mph (40.2 m/s) Snow Load - 43 Ib/ft^ Wet-Bulb Temperature - 14 °C (58 °F) Seismic Zone (International Bldg. Code) - D The following three figures illustrate different drawings of the Area 10 location for the DAVNCH. Figure 2 shows the proposed site location in Area 10, at the northern end of the open storage area. Figure 3 depicts a notional diagram of the proposed EDT location in the Open Storage Area. Figure 4 shows an overview of the site plan, including the access roads, gates, and site layout. EDT SITE Figure 2. EDT Proposed Site Location at TOCDF Figure 3. EDT Site Location in Area 10 Formatted: Font: (Asian) Japanese DAVINCH SYSTEM TOEOT SERVICES General Plot Plan PF3400 100 DB41 -PROOSK Figure 4. EDT Site Overview .As shown in Figure 3. the EDT site will occupy approximately 75.()()() lr at the northem eni.1 ol" the (!)pen Storage area, atljacent to Buikling 1 S35. The site is a I'ormer storage area lor ton containers (TCs): it is currently occupiei.1 with abani.lonei.1 storage racks for the TCs. which consist of short sections of railroai.1 tracks ani.1 railroai.1 ties. This area will be grai.lei.1 after remo\al ofthe TC racks. The major sections ofthe site are i.liscussei.1 below. 1.5.1 Existing Pa\ e(.l .Area .At the northem eni.1 ofthe (!)pen Storage .Area there is an existing macai.lam roai.1 parking area. This area pro\ ii.les a solii.1 surface for parking ani.1 entry into the site. \ ia an existing gate along Road "D". 1.5.2 .Aelministrati\ e .Area Immei-liately atljacent to the Existing Pa\ ei.l .Area is the location for temporary trailers, which will house storage trailers, an office area, ani.1 the laboratory. This area will be grai.lei.1. compactei.1. ani.1 built up with gra\ el to sufficient tlepth to support the trailers, which will open to the parking area. a\ oii.ling the neei.1 for concrete or pa\ ei.l walkways. 1.5.3 EDT Site The EDT ani.1 enclosure will occupy an area roughly 1 oo ft x 1 oo ft. This section will be grai.lei.1. compactei.1. ani.1 built up abo\ e gratle using layerei.1 gra\ el to ensure i-lraining ani.1 pro\ ii.le a firm footing for the mobile D.AMNCH'^" unit. 1.5.4 Staging .Area .Ai-IJacent to the EDT site will be a 2()() ft x 2()() ft staging area, where utilities will be locatei.1. Generators, storage tanks for fuel ani.1 gases, ani.1 other temporary ei.|uipment will be locatei.1 here. This area will be grai.lei.1. compactei.1. ani.1 built up with gra\ el to a sufficient tlepth to support the ei.|uipment. During installation, components that are being stagei.1 for assembly will also be locatei.1 in this section. 1.5.5 .Additional Gate To pro\ ii.le a logical llow of materials through the site, ani.1 to facilitate i.leli\ ery of munitions, supplies, ani.1 other materials to the site, a new gate is proposei.1 for installation in the existing fence atljacent to Roai.1 D. approximately 3()() ft from the existing gate. This gate will pro\ ii.le ingress to ani.1 egress from the site. 1.5.6 Restricteel .Access .All fencing will be establishei.1 in accortlance with existing DCD access rei.|uirements. .An ai.klitional intemal fence will be usei.1 to i.li\ ii.le the (!)pen Storage .Area into a northem ( EDT) sector ani.1 a southem sector to pre\ ent access to unauthorizei.1 areas. 1.6 Emergency Planning and Contingency Operations 1.6.1 Site Specific Sal'et\' Plan .A Site Specific Safety Plan ( SSSP) contains infomiation regartling safety planning for the implementation ofthe EDT. The SSSP contains infomiation on support operations such as medical, fire, and emergency response at TOCDF and Area 10 for EDT operations. The SSSP will be approved by DDESB. 1.6.2 Prevention of Sudden Releases to the Environment The destruction of chemical agent munitions using the DAVINCH™ process is designed to minimize the potential of fire and sudden and non-sudden unexpected releases of hazardous waste to the environment. 1.6.2 .1 Minimized Handling The DAVINCH™ will process approximately 350 leaking and over-packed 155-mm H Projectiles, and 4.2-inch HD and HT Mortars. In addition, the DAVINCH^" will process approximately 50 HD and HT samples. The munitions and agent samples are processed in their over-packs as the DAVINCH™ process does not require the items to be removed from the over- packs prior to treatment. 1.6.2.2 C ontainnient The DAVINCH"^^ operations are conducted in an Environmental Enclosure (EE) that is equipped with airlocks and appropriate high-density polyethylene (HDPE) interlocking flooring, with a plastic floor liner under the HDPE panels, which interlock together to form a stable platform. The Environmental Enclosure is maintained under a negative pressure, and air circulating through the enclosure is vented to activated carbon filters. A damper system maintains flow during operations (See Section 2.2 for a more detailed description ofthe EE). 1.6.2 .3 Controlled Detonation The DAVINCH^"^ destroys the chemical munition agent fill and energetic components by controlled detonation, a mechanism whereby the steel munition components, agent fill, energetics, and overpacking are completely destroyed by the shock wave from the donor charge, intense heat, and extreme pressures generated microseconds after the initiation ofthe detonation. An explosive model of each detonation ensures the proper placement, size, and location of linear shaped charges (LSCs), which cut the walls ofthe overpack and munition, and a staged series of emulsion-type donor charges. The charges are attached to each munition based the munition type, type and number of overpacks (i.e., one or two overpacks are used to contain the munition), and on the position of the munition inside the overpack as determined by an x-ray assay. The donor charges are attached to the munitions in a preparation area within the Environmental Enclosure. Releases to the environment through an unplanned detonation of explosives are minimized by: • Minimization ofthe number of munitions and donor charges present at the DAVINCH'^'^ operational site. The number of munitions provided to the DAVINCIF^^ each day of operations is limited to the amount that can be processed in one day. The DAVINCH™ is a batch process system, and the schedule allows for a maximum of seven target treatment detonations per day, not including cleansing shots. The number of munitions processed in each batch is dependent on the type of munition: 155-mm H Projectiles are processed one or two per batch depending on the number of overpacks, and 4.2-inch Mortars are processed three per batch. 10 Storage of munitions in a separate location. The mimitions to be treated by the DAVINdF"^ for the day are stored within the Environmental Enclosure. The donor charges to be used for the day are stored in the Day Explosive Storage Units, which are located near to the Environmental Enclosure. The number of donor charges, and LSCs -at the DAVINCH™ site will not exceed the amount necessary for a day's operations. A separate Day Explosive Storage Unit is used to store detonators. Inherent Stability of Donor Charges. The donor and shape charges that are used are comprised of stable explosive formulations that require the use of a detonator. The detonator circuit is enabled only after the prepared munition is placed in the Detonation Chamber. Chamber Design. Sudden releases from the Detonation Chamber are prevented by the design of the chamber. The Detonation Chamber is comprised of an outer and inner chamber: The iimer chamber has a slightly smaller diameter than the outer chamber, which creates an interstitial space between the chambers. The inner chamber is sacrificial and is replaced after a designated number of shots. The Destruction Plan for TOCDF does not require replacement ofthe inner chamber, since the total number of shots for the inner chamber life is in the 2000 range, and the TOCDF plan requires only about a 300 shots for the duration ofthe campaign. The inner chamber is neither a pressure vessel nor an inipulsively-loaded vessel; it serves as the primary barrier against the heat, impulse, and fragments associated with the contained detonation. The interstitial space between the inner and outer chamber is open to the product gas. The outer chamber is a multi-layered steel chamber designed to contain the high temperatures and pressures generated by the confrolled detonation. The DAVINCH™ chamber will be manufactured at a factory in Japan that is an authorized manufacturer of ASME SEC VIII pressure vessels; this facility has the technology available to construct the multiple-layered-steel outer chamber. The system is designed in accordance with ASME Code Case 2564 (January 2008) on impulsively-loaded vessels, which is the first design guidance of this kind worldwide. The EDT subcontractor engineers participated in the Task Group ofthe Code Case and designed the DAVINCH™ chamber according to the design guidance. Leak-Before Burst Failure Mode. The design criteria for this chamber are based on numerical modeling. The multiple-layer design allows for the discontinuity between the layers to provide an arresting mechanism for small cracks that might occur in the chamber wall. In addition, the system is designed to prevent catastrophic failure even for loads well in excess of its rated design criteria for pressure and impulse loads. The design ensures that the failure mode ofthe vessel is "leak before burst," whereby the chamber will not catastrophically fail. If a failure occurs, any release of contamination from the DAVINCH™ will be captured by the EE. Near Real Time Strain Monitoring. Failure ofthe Outer Chamber is minimized by the system unique to the DAVINCIP^^ which is referred to as DESTINY. This near real time system uses strain gages to measure strain in the Outer Chamber metal fatigue at locations 11 that are based on numerical modeling and that have shown fatigue in previous DAVINCH™ operations. After each shot, an analysis is automatically run to show the accumulated stress/strain on the system, using the strain gage data. Over 5,400 munitions have been processed on similar systems with no structural failure, and those data are integrated into the design of the DAVINCH™ System. • Hold-Test-Release. Releases of agent from the DAVINCIP'^ stack are also prevented by the Hold-Test-Release concept of operations as allowed by the design ofthe system. After each shot, the off-gas is treated in a series of treatment trains, which incorporates a Retention Tank that is located downstream ofthe Cold Plasma Oxidizers. The Retention Tank provides a retention time of approximately 10 minutes, slowed by the baffles intemal to the tank. The gas residence time is longer than the cycle time of the agent monitor that is located upstream ofthe inlet to the Retention Tank. The pumps, blowers, and valves allowing off-gas to reach the CA monitor are timed to synchronize the release of off-gas to the sampling point with the sampling cycle ofthe MINICAMS'^'^ to ensure that detonation gas is sampled. If agent is detected in the detonation gases, the Retention Tank outlet valve is closed, and the gases are routed back through a dedicated activated carbon filter for additional treatment. • Carbon Filtration. Releases of agent from the DAVINCH™ stack are further prevented by passing treated detonation gases through a sulfur-impregnated activated carbon filter before they are released to the environment. Releases from the DAVINCH™ Environmental Enclosure to the ambient air are prevented by the supplied fixed bed activated carbon filters. 1.6.2.4 Prevention of Spills/Releases Releases of liquid hazardous waste to surface and ground water are prevented by processing all munitions and agent samples received at the DAVINCH™ operation site in the over-packs in which they arrive: this is because ofthe DAVINCH™ high TNTeq rating ofthe DAVINCH™ system Detonation Chamber. Releases of liquid hazardous wastes are further controlled by the use of an Environmental Enclosure that prevents the run-on and run-off of precipitation. The DAVINCH™ Detonation Chamber, Cold Plasma Oxidizers, and Retention Tank are located inside the Environmental Enclosure. The preparation ofthe munitions to be treated in the DAVINCIF^* occurs within the Environmental Enclosure. The DAVINCH™ Pollution Abatement System (PAS), which consists of a cyclone, 10- and 2-micron filter screens, wet scrubber, and fixed-bed carbon filter are housed in two shipping containers. Secondary containment is provided for the wet scrubber. Release of hazardous waste during the transfer of waste residues from the DAVINCH'^'^ Detonation Chamber, and particulate and wet scrubbers is prevented by conducting those activities inside the Environmental Enclosure and shipping container, which house some of the DAVINCH™ PAS components. 1.6.3 Fire Prevention Fire protection will be designed into the system. The trailers will be fire rated. Equipment and materials, piping, and electiical will be in accordance with National Fire Protection Association (NFPA) or underwriters [Underwriter's Laboratory (UL) Listed]. There will be a minimal amount of flammable materials in the EE, and housekeeping standards for all areas will be imposed to ensure that fire protection standards are met. Necessary equipment will be grounded. 12 and ground fault interruption will be applied to circuits that have a shock or fire hazard. No smoking or open flames will be allowed in the restiicted area of the site. 1.6.3.1 Fire extinguishers rated D by UL in accordance with UL/ANSI 711, local codes, and TOCDF requirements will be placed at designated locations throughout the EDT area of operations. 1.6.3.2 The DCD Fire Department will be the primary response team for any fire associated with the EDT operation. Contact with the TOCDF Control Room will be the primary method of reporting a possible fire, and response will be coordinated by TOCDF and DCD. 1.6.4 Communication System The DAVINCH'^'^ operations site is equipped with communication systems to alert employees to various site conditions, upset conditions, emergencies, and operations updated for TOCDF. 1.6.4.1 The Site Public Address (PA) announcements will be managed from the EDT Control Room. A feed from the TODCF site PA for overall TOCDF announcements will be provided. The PA speakers will be mounted at locations at the EDT site to allow all site personnel to hear announcements. 1.6.4.2 Cell phone use will be restricted during explosive operations. An exclusion area will be established based on Department ofthe Army Pamphlet (DA PAM) 385-64. Site security radios for DCD security will have the appropriate setbacks (i.e., defined areas where cell phones and radios are prohibited to prevent unintended initiation of electronic detonators) incorporated into the operation. 1.6.5 Spill Response The EDT site will have Standard Operating Procedures (SOPs) and signage associated with response to spills of hazardous materials. A spill involves the release of a type or quantity of a hazardous waste or materials which, when spilled, become hazardous wastes, that poses a threat to human health or the environment: this includes an uncontrolled fire or explosion^ 1.6.5.1 The EDT site will have pre-positioned spill control kits for response to minor spills, including but not limited to: • Absorbents Universal Spill Absorbent - 1:1:1 mixture of Flor-Dri (or unscented kitty litter), sodium bicarbonate, and sand. This all purpose absorbent is good for most chemical spills including solvents, acids, and bases. Acid Spill Neuttalizer - sodium bicarbonate, sodium carbonate, or calcium carbonate. Alkali (Base) Neuttalizer - sodium bisulfate. Solvents/Organic Liquid Absorbent - Inert absorbents such as vermiculite, clay, sand, Flor-Dri, and Oil-Dri. • Personal Protective Equipment (PPE) Goggles and face shield Heavy neoprene gloves Disposable PPE Deleted: A spiU response plaii will include response requirements for major spills, minor spills, chemical agent spills, and response plans in the event of a spill. A spill involves the release of a type or quantity of a chemical that poses an immediate risk to health; tliis includes an uncontrolled fire or explosion. 13 Plastic vinyl booties Dust mask/respirator • Clean-Up Material Plastic dust pan and scoop Plastic bags (30 gallon, 3-mil thickness) for contaminated PPE One plastic bucket (5-gallon polyethylene) with lid for spill and absorbent residues. 1.6.5.2 For all spills exceeding the category of minor spills, or any spill that involves CA, explosives, or Immediately Dangerous to Life or Health (IDLH), the J'OCDF HAZMAT Team will be the primary response organization. The EDT site SOPs will address administration of first aid, immediate response actions such as evacuation ofthe area and communication procedures. Deleted: TODCF 1.7 Monitoring Air monitoring will be performed in accordance with the EDT Monitoring Plan, Annex B to this Destruction Plan. Edgewood Chemical Biological Center (ECBC) and Versar will provide personnel and equipment for air monitoring for chemical agent. Air monitoring objectives include ensuring that worker and public safety and health are maintained by providing environmental monitoring in accordance with Army Regulation (AR) 385-10 and the U.S. Army Implementation Guidance Policy for Revised Airbome Exposure Limits. The target agent for the monitoring plan is HD. Agent monitoring is performed using MINICAMS™ and Depot Area Air Monitoring System (DAAMS) The EDT Monitoring Plan describes three types of monitoring used at the EDT site: Safety Monitoring/Personnel Safety; Process Monitoring, and Waste Monitoring. This monitoring shall be used to evaluate the overall effectiveness of engineering and administtative conttols, and when PPE is used, monitoring shall be in place to ensure that exposure levels are not exceeded. 1.7.1 Safetv Air Monitoring The MINICAMS™ near real time monitors will be used to monitor the enclosure for the presence of CA, using HD^s the target analysis compound^ The DAAMS tubes will be used to _ provide confirmation and historical monitoring documentation. 1.7.2 Monitoring Points Monitoring points will be located in the unpack area, the preparation area, the DAVINCH™ chamber area, airlocks, changing room, and waste areas. Monitoring points will also include first entry to the chamber after detonation, and mid-bed monitoring at the carbon filters. These monitoring points will address a first entry/check for the box truck that will be used to deliver munitions to the EDT site each day to confirm that no agent has leaked from the target munitions during ttansport from the igloo area to the EDT site. Deleted: andHT Deleted: s 1.8 EG«&G, TOCDF, and DCD Support 14 EG&G and DCD will provide site support services in Area 10 and at DCD during the EDT project. This includes oversight of EDT operations, which consists of ensuring: • A comprehensive evaluation of contractor work control practices, operation, maintenance and quality control procedures performed by TOCDF's Safety, Environmental, and Quality departments. • Vendor's and contractor's policies and procedures that meet or exceed TOCDF standards. • Discrepancy resolution and procedure revision to the satisfaction of EG&G and the vendor before any EDT operations commence. • X-ray data results based on x-ray Requirements (D-003). 1.8.1 Equipment/Facilities The TOCDF/DCD will provide the following equipment/facilities for the project: • Temporary personnel facilities including shower/locker ttailers and break room trailers. These facilities will be sized according to the number of user personnel identified by the vendor. • A bulk explosive storage building (storage igloo rated for Class 1.1 explosives) as applicable. • Communications system between the Detonation Chamber site, the TOCDF Control Room, and DCD Security. • Shower and break facilities for EDT operators. 1.8.2 Utilities The EDT is designed to be self-sustaining. EG&G will provide services to refill propane, diesel fuel and water tanks. 1.8.3 Security • DCD will provide round-the-clock security at Area 10 during setup, operations and demobilization. • Access conttol will be maintained at Area 10 through badging and escorts for non- Unrestricted Access badged personnel. EG&G will coordinate badging and escorting. Note that personnel with need for unrestricted access will be part ofthe DCD Unescorted Access Program (UAP). 1.8.4 Site Preparation EG&G will provide site preparation and civil consttuction for the site, including site preparation based on vendor-provided site specifications per Site Design (Deliverable D-002). 1.8.5 Operations Support EG&G and DCD will provide the following support during operations: • Hazmat and decontamination team support in the event of a hazardous waste event. • Fire suppression support (through DCD) in case of a fire at the EDT site • Site-specific ttaining for all EDT personnel (see Annex G, Training Plan). • Medical support via the TOCDF Clinic. 15 • Management and funding for the disposal of all hazardous waste generated. • A temporary 90-day storage location for hazardous waste. • Coveralls and cotton goods to be worn by operators during chemical weapons operations. • Toxicological Agent Protective (TAP) gear to include butyl boots, gloves, and M2A1 Aprons as required. • Masks issue for visitors to the site. 1.8.6 Planning/Permitting The operating contractor will provide the following: • The Destruction Plan Approval by DCD, CMA, DSHW, and other regulatory agencies. • The SSSP, which will be prepared and approval obtained by the U.S. Army Technical Center for Explosive Safety (USATCES) and DDESB. • Permitting, including necessary RCRA and CAA Permits, will be the responsibility of DCD, TOCDF, and the operating contractor, EG&G. 1.8.7 EDT Operations The EDT contractor will provide operations personnel, equipment, and consumables, including: • The crew, which will consist ofthe necessary trained operators; safety, monitoring, and laboratory personnel to conduct site setup, pre-operational checkout and acceptance, systemization, and the Operational Readiness Review as supported by CMA, DCD, TOCDF and EG&G). • Donor Explosives; movement ofthe explosives, conducted by trained personnel, from igloo storage to the day box will be coordinated with DCD and Area 10. • Consumables, which will include items necessary to conduct operations and maintain the system, including decontamination solutions, bottled gases, carbon and High Efficiency Particulate Air (HEPA) filters, and liquid and vapor sample containers. Note that munitions will be delivered by DCD/Area 10 personnel to the intake area at the EDT site. 16 2.0 SYSTEM DESCRIPTION 2.1 Overview The DAVINCH'^" system is designed to meet the requirements ofthe EDT project at TOCDF, including but not limited to: mobility; standalone capability; safety; environmental protection measures; EE containment while chemical agent is processed; process monitoring analysis of chemical composition; appropriate connection with chemical agent monitoring (i.e., process interlocks) and analysis: UPS backup; and appropriate redundancy to complete the ongoing destruction backup operations. 2 .1.1 Concept of Operations The explosive detonation system concept of operations is to destroy overpacked chemical munitions using specialized explosive donor charges in a vacuum-assisted, multiple-layered, armored-steel chamber capable of containing the explosion. The extteme pressures, temperatures, and shock waves generated by the donor charge destroys the overpack, the munition body, the explosives/burster charges contained in the munitions, and the chemical agent fill in microseconds. Operation will be controlled from a remote Control Room that contains all human-machine interface, process monitoring, closed-circuit television (CCTV), and communication equipment. The DAVINCIF^ model DV60 has the capacity to desttoy 133 lb (60 kg) of TNTeq of explosive and is capable of desfroying all the specified munitions listed in the specification without unpacking munitions or requiring other pre-treatment. This can be accomphshed in a 10 to 12-hour day/four-day week operation mode. The system's major subsystems include the: • DAVINCHTM Explosive Detonation Chamber; • Off-Gas Treatment System; • Control System; • Utility System; and • Ancillary Equipment. See Design Features, Section 2.6, for more details on these subsystems. 2.1.2 System Design Requirements The DAVINCH™ system is designed to meet the requirements ofthe EDT project at TOCDF. The DAVINCH™ DV60 has the capacity to desttoy 133 lb (60 kg) TNTeq of explosive and can desttoy all the specified munitions listed in Table 2 without unpacking or requiring other pre- freatment at a rate of seven detonations per day. The system is designed to be stand-alone. All utilities will be provided on-site, including electric power from two 600 kW diesel generators; storage for water, which will be refilled from the VA- inch line and spigot located in Area 10; and storage for gases and fuel, including propane and diesel. 17 The rack-mounted off-gas system will be designed to simplify installation of the entire system, to be completed in one month, at the TOCDF site. The DV60 main chamber will be tested under a 125 % load in Japan and brought to the U.S. for DDESB review and approval. The DV60 has a design life of 5,000 to 8,000 shots for the outer chamber; approximately 300 shots are required to fulfill the scope of this project. This DAVINCH™ will have the capability of desttoying the over-packed, mustard-filled 155-mm Projectiles and 4.2-inch Mortars with out removing from their over-packs. The over-packed munition is assembled with shaped and donor charges and placed (hung) in the chamber, where the detonation is activated in a partial vacuum. The emulsion explosive placed around the munition ensures an effective implosion process, thereby reducing the speed and the size of detonation fragments, and ensuring a longer life ofthe inner chamber. In the case of over-packed munitions, a shaped charge is added to the process to cut the overpack and detonate the burster. 2.2 Environmental Enclosure (EE) Description 2.2.1 DAVINCH™ Containment The "primary" containment for the munitions is the existing overpacks. The "secondary" or DAVINCH™ containment is the chamber itself. The detonation chamber lid has a space to capture escaping gas. The skid-mounted off-gas units are contained in 40-ft modular enclosures, which are ducted to the EE enclosure (described in paragraph 2.2.2). The DAVINCH™ will be located inside an EE comprised of a ceiling, sides, and flooring that will provide weather protection and interior environmental control for workers comfort and safety. The floor ofthe EE will be an^DPE interlocking floor, approximately 2 inches thick, underlain with , - - -( Deleted; HPDE impermeable plastic sheeting. The structure also provides secondary vapor containment during EDT operations in the event an unexpected release of chemical agent occurs while loading the items. The EE will have a continuously-operating air filtration system that maintains a negative pressure within the EE relative to the outside air; it will capture any chemical fill vapors resulting from operations. The air flow from in the EE containment is kept at negative pressure, -0.10 to - 0.5 in WC, through a cascade-type ventilation system, with carbon filtration to the outside atmosphere. The shelter meets the required wind load; the maximum criterion is 120 mph for a three-second gust. The EE will provide a seal with the ground to prevent outside water from entering and ensure air-tightness. 2.2.2 EE Operating Areas The munition receipt and preparation area, detonation chamber unit, waste handling area, are contained in separate sections ofthe EE. The off-gas tteatment equipment is housed in shipping containers positioned outside ofthe EE. The receiving area, and preparation room are air conditioned, and the shelter has local heaters and coolers for the operators. The exhaust air blower system maintains the required ventilation air changes per hour, and air is exhausted through a carbon filter. There are separate airlocks for personnel and material/equipment. The floor coating, consisting of interlocking HDPE panels, will meet the requirement for dust control, and provide a moisture barrier. Design load will be met; note that the slope coupled with the slippery membrane is designed to shed snow load. Under normal conditions, the aluminum frame has a 30-year design life, and the membrane has a two-year life. Humidity will be controlled by the ventilation system. Lightning protection is incorporated into the design. However, CWM will not be stored in the EE. 18 2.3 Maintenance Requirements Maintenance inclui.les periotlic inspections, ani.1 pre\enti\ e maintenance ani.1 correcti\ e maintenance. 2.3.1 Monitoring Fatigue Damage DESTINE' Real Time Fatigue Monitoring instrumentation system allows the fatigue i.lamage to be monitorei.1 (.luring e\ery shot. Inl'omiation regan.ling the prei.lictei.1 time of crack initiation is assessei.1 as the key ini.licator for long-temi maintenance. 2.3.2 Pre\ enti\ e Maintenance The pre\enti\ e maintenance is performei.1 as categorizei.1 in Table 4. This pre\ enti\ e maintenance program is basei.1 on actual operational perfomiance. Inspection is performei.1 in accori-lance with the Inspection Plan pro\'ii.lei.1 in .Annex C. 2.3.3 E(.|uipment Maintenance Scheelule The control system ani.1 its interface with an off-site system for performance (.lata collection (know as GRAND) offers the infomiation necessary for the ei.|uipment maintenance schetlule ani.1 supports operators in real-time. It estimates the maintenance tim ing basei.1 on the tlatabase. which incoqiorates statistical basei.1 estimation capabilities. The tlatabase is upi.latei.1 with operational result input from similar sites worklwitle. 19 Table 4. Schedule for Pre\enti\e Maintenance M.\1NTEN.\NCE T\PE DA1L\ \\T:EKI\ MONTHL\ Bl.\NNl'ALL\ Maintenance A B C D Le\el A B C D - Msual - Msual - Msual - Msual Inspection Inspection Inspection Inspection - Cleaning Chamber Inspection - Cleaning - Cleaning - Diameter Chamber Inspection - Diameter Measurement Measurement - NDE (MT.PT) - Crack remo\ al. if an\' - Daily check - Remo\ mg - Measurement - Cleaning of filter by list heavier i.lust check(hook elements - Check (e.g.. - Check opening, chain - Perioi-lic inspection Other Equipment Inspection (pump, cold plasma, off-gas filter) \ isual. noise. \ibration. temperature, llow rate, leakage) loosenei.1 bolts arouni.1 \ al\es near tletonation chamber i-liameter). perioi-lic inspection ('manufacturer's stani.lan.1) - Drain remo\ al of stack ('manufacturer's stani.lan.1) - .Acetone cleansing run of \ acuum pum ps - Change filter elements if necessary - Replacement repair as necessary Inclui.lei.1 in 10-hrs/day Mode the Daily (!)pe ration 2 Hours 1 Da\-3 Days Quantity of -, 4 S Personnel 4 S PPE ^es ^es ^es ^es NDE: Noil De-lniclioii Exaiiiiimlioii MT: Mnaielic Te-I PT: Liquid Peiielrnlioii Te-I 2.4 Design Features 2.4.1 Detonation Chamber The system inclutles two relati\ ely close-fitting \ essels. The D.AMNCH'''" tletonation chamber has i.listincti\ e features such as the i.louble-wallei.1 steel chamber with a replaceable inner \ essel that protects the outer chamber from explosion fragments: ani.1 the \ acuujn that is establishei.1 prior to tletonation ani.1 sei.|uential tletonation to retluce the impulsi\ e loai.1. souni.1 ani.1 \ ibration. ani.1 fatigue i.lamage. The i.louble-wallei.1 chamber tlesign is basei.1 on a " leak-before-burst" philosophy. It is cylini-lrical in shape, with hem ispherical eni.1 caps: the D\'6() chamber interior volume is appro.NJmately 1 So ff\ The maximum allowable explosive charge is 60 kg of TNTeq. or approximately 133 lb of explosi\ es. The chamber opening is closei.1 with a NLI that uses a hyi-lraulic clamping system ani.1 casketing to ensure pressure retention. The outer chamber is fixei.1 to the founi-lation \ ia satklles ani.1 is fabricatei.1 with laminatei.1. cylini-lrical. carbon-steel walls weklei.1 to monolithic carbon-steel top ani.1 bottom ellipsoii.lal heatls. The inner chamber consists of layerei.1 steel ani.1 is consii.lerei.1 a maintenance item - it is replaceable. The replaceable inner liner is also constructei.1 of special steel, ani.1 it is built up in layers to minimize the propagation of any cracks, which are arrestei.1 by the i-liscontinuity between the layers. 2.4.2 Clamping S\stem The "auto-clamping" NLI closure system was i.lesignei.1 untler recommeni-Lation by Lawrence Li\ ennore National Laboratory. The earlier D.A\TNCH'''" tlesign usei.1 two U-shapei.1 circum ferential clamps, ani.1 closure was accomplishei.1 by manually bolting the clamps together. The new system is constructei.1 using eight ini.lepeni.lent clamps, configurei.1 to allow optimal control ofthe access tloor. These clamps are i.lri\en by automatic hytlraulic or oil pressure. This pressure is monitorei.1 to ensure that all clamps are functional ani.1 supply the rei.|uirei.l closure pressure. 2.4.3 Munitioas Hanelling Installation in Chamber .A scissor-type lift is usei.1 to lift the configurei.1 munition to a position in the chamber that will allow personnel to hang the munition ani.1 explosi\ e using nylon web straps ( or other appro\ ei.l hanging materials) along an interior track at the top ofthe inner liner. The tletonation chain is set. ani.1 the automatic hytlraulic clamping system acti\ atei.l remotely to ensure a complete seal. 2.4.4 Chamber Door Mo\ able Platl'onn The hem ispherical chamber tloor is mountei.1 on an articulating mechanism that allows the tloor to mo\ e away from the chamber to pro\ ii.le access to the inner main chamber. The main chamber is accessei.1 by a mo\ able robotic access ramp that tloes not touch the inner chamber. 2.4.5 Off-Gas Filter .An inline filter is usei.1 to remo\ e particulates, with filtration specification of 2 micro-meter efficiency 99.97°o. The filter hasa backwash function. 2.4.6 Off-Gas Heater .A stainless-steel inline electric resistance heater is usei.1 to maintain process temperature. 2.4.7 Cooler .An inline gas cooler, using a gas air shell ani.1 tube configuration is usei.1 to nuxlulate temperature ofthe off-gas to maintain process temperature. 2.4.S Off-Gas Svstem The off-gas treatiiient system consists of a series of filttation banks ani.1 a "cokl plasma" gritl-arc oxii-lizer. followei.1 by carbon filttation. The Retention Tank pro\ii.les a retention time of up to lo m inutes. slowei.1 by the bafiles intemal to the tank: this allows sampling to occur prior to release. ani.1 rei-lirection ofthe off-gas to the treatiiient process shouki any C.A be i.letectei.1. 2.4.9 \"acuum Pumps Two rei.luni.lant. inline \ acuum pumps are usei.1 to e\ acuate the chamber. These are off-the-shelf units with: a capacity of 35o NlV'm in: suction of 1.45 psi: ani.1 tlischarge of o.2 psi. The i-letonation protluct gas is e.\nractei.l by a \ acuujn pump through an off-gas filter ani.1 then is sent to the off-gas treatment system. .A pretletemiinei.1 amount of o.\ygen is mixei.1 with the off-gas at the cokl plasma oxitlizer where the hytlrogen ani.1 carbon monoxii.le are o.Kii.lizei.1. .Any C.A remaining in the off-gas is i.lestroyei.1 by the cokl plasma o.^itlizer. 2.4.10 C^okl Plasma Oxidizer The cokl plasma oxitlizer unit is a unii.|ue piece of ei.|uipment. It is also callei.1 a Grii.l-.Arc Plasma ani.1 has been i.le\ elopei.l for refomi ing some lii.|uii.l fuels into synthetic gas or partial oxitlation of natural gas. ani.1 upgratling hytlrogen sullkle methyl-mercaptan. It is also now usei.1 as an oxii-lizer. The atk antages of the cokl plasma are low power consumption, compact size, rapii.1 startup time, ani.1 there is no neei.1 for pretreatiiient or catalyst. Howe\ er. the \ ital atk antage of the cokl plasma is the o.^itlation process. During the oxitlation process, the suppliei.1 o.\ygen is con\ertei.l too.\ygen ratlicals by high energy of electrons, ani.1 an oxitlation reaction with Hjani.1 CO is triggerei.1. which makes the cokl plasma oxii.lizer completely i-lifferent from a con\ entional seconi-lary combustion furnace. The i.letonation protluct gas is tlirectly mi.\ei.l with o.\ygen ani.1 injectei-l into the oxii.lizer as raw gas. The ratio of o.\ygen ani.1 i.letonation protluct gas is maintainei.1 so that excess o.\ygen remains after the reaction, to ensure complete oxitlation. The reaction temperature is controllei.1 by an appropriate ratio ani.1 llow rate ofthe i.letonation protluct gas ani.1 o.\ygen. The oxii.lizer is initially heatei.1 by introtlucing a mixture of LPG ani.1 air. Once the i.lesirei.1 temperature is reachei.1. the LPG llow is turnei.1 olTani.1 the raw gas is introi.lucei.1. The llow rate of o.\ygen ani.1 raw gas are ai.liustei.1 to maintain the i.lesirei.1 stoichiomettic ratio, while the total llow is ai.liustei.1 to maintain the oxii.lizer at the i.lesirei.1 temperature. The two units can operate in a fail-safe nuxle. where one unit can continue to operate if there is a failure ofthe other, albeit at a rei.lucei.1 llow rate. This ensures that any i.letonation gas will be tteatei.1 if either unit fails to operate. 2.4.1 1 Cooler The off-gas is coolei.1 after it passes through the cokl plasma oxii.lizer using an inline gas cooler with a gas air shell ani.1 tube conllguration that nuxlulates the temperature of the offgas to maintain process temperature. 2.4.12 Scrubber The off-gas is scrubbei.1 using an inline gas scrubber with a sotlium hyi.lroxii.le wash tlown. The coolei.1 gas is neutralizei.1 by the scrubber. The contlensate water generatei.1 in gas cooling is circulatei.1 through the insitle of the scrubber. 2.4.13 NaOH Tank This tank hokis the Na(!)H solution usei.1 for the scrubber. 2.4.14 Off-Gas Blower .An inline blower is usei.1 to maintain llow into the off-gas retention tank. Specification is 42ooo Nlr' hr at ambient pressure with a silencer. 2.4.15 Retention Tank .A miki steel off-gas retention tank is usei.1 to slow the llow ofthe off-gas such that the gas resilience time in the Retention Tank is longer than the upstream agent monitor's sample ani.1 analysis cycle time. 2.4.16 Heater .A stainless steel inline electric resistance heater is usei.1 to maintain process temperature. To exteni.1 the life of acti\ atei.l charcoal, the gas is heatei.1 to about 1 13 °F ('45 °C) before entering the filter unit. 2.4.17 Carbon Filters .A sulfur-impregnatei.1 carbon filter bank is usei.1 to filter the D.A\TNCH^" off-gas. with monitoring pro\ ii.lei.l i-lownstream of the filter's e.Khaust.. The air filtration system for the EE consists of pre filters. HEP.A filters, ani.1 carbon filters along with a monitor, port fan. ani.1 i-luctwork. .A series of nuxlular chem ical air filtration systems will be asei.1. ani.1 each system houses two banks of carbon filters, two banks of HEP.A filters, ani.1 one bank of prefliters. Each bank contains nine 1 S-inch first-time-use filters that ha\ e ne\ er been exposei.1 to chemical agent. .A smoke test will be coni.luctei.1 at the initial setup to certify the air filtration system ani.1 check airllow \ elocity to ensure that the EE is able to maintain negati\ e pressure insitle the sttucture relati\e to the outsitle air. The size ofthe carbon filtration unit is ai.lei.|uate to atlsorb any chemical agent that couki be releasei.1 from a leaking munition or item. 2.4. IS E.Khaust .Air Blower .An inline blower is usei.1 to maintain llow into the En\ ironjnental Enclosure H\'.AC fixei.l-bei.1 carbon filters. The specification is 126oooNlr' hr. 2.5 Other Support Equipment 2.5.1 EDT Control Room The EDT Conttol Room will consist of a rental ttailer ei.|uippei.l with appropriate \ entilation. This will be the location for the Disttibutei.1 Control System (DCS) control computers, communications conttol panel, safety system interfaces, ani.1 necessary manuals ani.1 SOPs. The EDT Control Room will ha\ e a security lock, ani.1 access will be limitei.1 to operators who are ttainei.1 to operate the system conttols. in accori-lance with the SOPs. The GRAND ani.1 DESTfN^' systems will be accessei.1 from the EDT Control Room. 2.5.2 Generators Rei.luni.Lant 6oo kW tliesel generators will be installei.1 to pro\ ii.le power to the entire site. .A nuxlular power i-listribution trailer will be usei.1 to tlisttibute power for the installation. 2.5.3 .Air Monitoring Shelter .Air monitoring ei.|uipment will be locatei.1 in a shelter, with sampling lines running to the \ arious monitoring locations at the EDT site. 2.5.4 Mobile Laboratory' A mobile chemical laboratory will be set up at the EDT site to provide air and liquid sample analysis services. 2.5.5 Explosive Storage/Day Boxes To minimize the quantity of explosive and CWM that will be onsite at any given time, deliveries of donor charges, detonation cord, LSCs, and detonators are limited to the number of munitions that can be processed in a single shift. The number of donor charge and LCSs is also limited to that required to treat the munitions delivered, which should only be enough for one day of operations. The Day Explosive Storage Box, which is used to store the donor charges and LSCs, is a modular system from an approved supplier of storage systems that meet or exceed the requirements of 6055.9-STD Department of Defense (DoD) Ammunition and Explosives Safety Standards (02-29-2008) and Bureau of Alcohol Tobacco and Firearms (ATF) requirements for Type 2 ATF high-explosive storage. A separate explosive storage box, separated by the distance specified in ARs will be used to store detonators. The boxes are outdoor rated, and are fire, theft, and weather resistant. The maximum number of donor charge, detonators, and shaped charges will be established for each ofthe DAVINCH'^'^ campaigns ^nd stored in accqrdance_\vith _ ,, - -{Deleted; DAVINCH™ regulation. 2.5.6 Storage of Munitions Pending Processing Munitions delivered for processing are placed in the preparation room and are under the continuous observation and control of operator personnel during preparation. Only the number of munitions planned for processing per shift will be delivered from the igloos in Area 10. Any munitions that are not processed during the shift are retumed to the storage igloo prior to site shutdown for the day. 2.5.7 Break Room/Crew Trailer A crew ttailer will be set up to allow breaks, rehydration, and rest area for the crew. 2.5.8 VIP Trailer An observation ttailer, equipped with CCTV, will be provided so the destruction process can be monitored without having to enter the exclusion zone. 2.5.9 Toilet Facilities The TOCDF will provide portable toilet facilities for on-site personnel. 2.5.10 Uninterruptible Power Supply (UPS) All monitoring equipment will be connected to an UPS. All other site equipment (including the air filttation system) will be powered by the backup generator. 24 3.0 EDT OPERATIONS The EDT will be operatei.1 in accori-lance with appro\ ei-l SOPs. .An operating ori-ler or scenario will be i-le\ elopei-l for each munition or item, basei-l on the Munitions .Assessment Re\ iew Boari-I ('MARB) i-lata from the x-ray campaign coni-luctei-l by DCD. Each operating ori-ler will be locatei-l in the EDT Control Room. 3.1. System Deli\ery The i-leli\ery ofthe system will be accomplishei-l in three phases: 3.1.1. Transportation ani-l Deli\ er\' of Main Chamber ani-l .Associatei-I Components The main chamber is the hea\iest component ofthe D.A\TNCH'''" system: it weighs approximately 75.ooo lb. ani-l is approximately lo feet in i-liameter. 1 1 feet high, ani-l 23 feet long. The major components of D.A\TNCH'''" ('main chamber, sai-klle. inner chamber. \ kl clamping system, entry gantty. ani-l associatei-l piping) will be packagei-l for shipment at the Kobe Steel. LILL. Takasago W orks, in Kobe. Japan. The system will be loai-lei-l into custom transportation sai-klles. sttuctures. ani-l packaging to minim ize i-lamage i-luring shipment. The chamber subsystem will be sea shippei-l \ ia a common carrier to a US port of entry. .At the port of entty. a rigging subcontractor will ttansfer the system to a rail ttansportation configuration. The system will be shippei-l from the coast by rail to a rail heai-l near DCD ( i.e.. to an ini-lustrial area near Tooele. Utah). .A i-|ualifiei-l hea\y loai-l contractor will transport the system component \ ia escortei-l ttuck from the rail heai-l to the DCD. .Arrangements will be mai-le with the State of Utah ani-l local authorities to ensure safe transport ani-l roai-l capacit}'. The same hea\y loai-l contractor will transport within DCD. ani-l ultimately, to the .Area 1 o EDT site. Special pro\ isions ani-l coori-lination with DCD will ensure that roai-l ani-l gate configuration meet the rei-|uirements ofthe shipper. The rigger will use an appropriate hea\ y crane to oflloai-l the unit onto the steel founi-Lation. which will be installei-l prior to i-leli\ ery. Steel plating ani-l certain reinforcements may be necessary to ensure roai-l i-lamage is pre\ entei-l. 3.1.2. Transportation ani-l Deli\ er\' ol'(!)lT-Gas Treatment S\stems The off-gas treatment systems will be assemblei-l in Salt Lake City ani-l ttuckei-l to the site o\ er state ani-l DCD roai-ls. The weights ani-l i-limensions ofthe off-gas systems are within the capability of a stani-lari-l 4o-foot ttailer. The off-gas system nuxlular components will be olT- loai-lei-l at the EDT site with a crane. 3.1.3. Deli\er\' ol'Support Ei-|uipment Support ei-|uipment. inclui-ling but not limitei-l to. the generators, conexes. containment structure, ai-lm inistrati\ e trailers, ani-l utility storage areas will be i-leli\ erei-l o\ er state ani-l DCD roai-ls. 3.2. System Installation The site will be preparei-l for installation ofthe D.AMNCH'''" in accori-lance with the ci\il i-lesign. which ai-klresses soil compaction rei-|uirements. grayling, i-lrainage. ani-l utilit}' locations. Layers of road base, gravel and rock will be placed on compacted soil to a sufficient depth to support the static and dynamic loading ofthe system. A heavy steel foundation will be assembled on site, with steel plating on its surface. The DAVINCH™ chamber saddle will be placed on the steel foundation, which will have steel penetrations into the soil and road base to ensure thrust blocking. The floor ofthe DAVINCH^'^ area will be 2-inch HDPE interlocking plastic modules, approximately 8 feet x 14 feet, leveled and attached to each other as necessary via clamping fasteners. The floor will be under-laid by non-conducting, reinforced plastic sheeting. The off-gas units are designed as trailer-mounted units in 40-ft containers to minimize the piping work on site. Field work will be continued on utilities while the tertiary containment structure is assembled. Pre-commissioning includes running tests for all the equipment to confirm that no damage occurred during transportation, and to validate proper connection of wiring and expected functions. Confnmation of piping connection air tightness and vacuum testing will also be conducted. Explosive tests will confirm the DAVINCIF^ chamber unit, off-gas unit, and utilities supply function as designed. Figure^ shows the phases of installation. Deleted: 4 Period 1st week 2nd week 3rd week Working day 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Control /Electrical Room-n^ Electricity Utility Utility Preparation ^Changing DAVINCH DAVINCH -Electrical Furnace Off gas skid Off gas skid Structure of sprung Covering over Equipment Structure of sprung Covering over Equipment Membrane of sprung Membrane of sprung Pipe Connection HVAC system ,s HVAC system p Wiring Wiring Commissioning Tes tfor each ur ver Supply lit 9 Pov tfor each ur ver Supply Figure 5. Installation and Commissioning Schedule The chamber is inspected and tested for pressure tightness; and the operating performance ofthe automatic clamping system, moving deck, and material handling equipment for munition handling at the assembling factory. The other auxiliary equipment (e.g., vacuum pumps, charcoal filters) will be purchased from U.S. suppliers, and Quality Assurance (QA) inspections are to be conducted at the manufacturing sites. The auxiliary equipment is designed as skid- mounted modules as much as possible and are shipped in regular ttansportation containers. The 26 main equipment, such as the cold plasma oxidizer, vacuum pumps, and charcoal filters will be manufactured independently and assembled in the 40-ft container units at a U.S. facility. 3.3. Systemization The systemization process will follow the approved Systemization Plan. The Systemization Plan will address the steps necessary to ensure that the system operates as designed, and that all components are fully operational and assembled correctly at the site. After the facility has been assembled at the TOCDF and commissioning is complete, acceptance testing will be performed. The records from assembly, pre-commissioning, and commissioning will be reviewed for completeness and accuracy. When assembly, pre-commissioning, and commissioning activities have been accepted, system acceptance testing will be performed to ensure all systems are working properly. Testing will be conducted using Simulation Equipment Test Hardware (SETH) munitions, overpack containers, and surrogate chemicals. Acceptance tests will be performed to confirm the following properties: Throughput, including handling (feeding), detonation, and off-gas treatment. Feeding system operability, including required time and safety. Waste handling operability, including required time and safety. Agent monitoring operation and management. Environmental emission control. Fatigue damage evaluation system (DESTINY) operation. 3.4 Operational Readiness Review System Operation Readiness Review (ORR), and approval by the ORR Team and an ORR Board, will be required prior to initiation of munitions operations at the EDT site. An ORR Board will be established by TOCDF and the operating contractor to implement the requirements of TOCDF ORR requirements per EG-073 R03 C03, Operational Readiness Review Guide. 3.5 Operations A 2-month campaign plan will be established to conduct munition destruction operations. The campaign will be set up to desttoy the categories of overpacked munitions previously identified in Table 2 of this plan. In the case of a 4-5 day/10 to 12 hour working schedule, 7 shots per day are required to maintain the schedule. A plan for the destruction process for each day's operation, based on the individual requirements of each munition type, will be established. Each day's target munitions will be delivered at the EDT entry point, the box truck first entry clearance conducted using a spooled MINICAMS'^" line, and the munitions/overpack container will be moved by forklift into the unpack area and then to the preparation area. Daily activity will also involve operators delivering donor charges to the day box from the Area 10 Storage Igloo. Appropriate system checks will begin prior to each shift. 27 3.5.1 Operational Steps Figure^ shows the foUowing cone detonation: • Installation of munitions with appropriate donor charge in the detonation chamber. • Evacuation ofthe air in the chamber and supply of minimum oxygen. • Activation ofthe controlled detonation explosion. • Evacuating the detonation product gas, sampling ofthe gas, and transferring it to the off-gas tteatment system. Deleted: 5 Figure 2 shows the DAVINCH™ deton^^ and the off-gas treatment y^stem. The cold plasma oxidizer is mainly for oxidizing the explosive products of CO and H2, and it is expected to provide additional agent Destruction Efficiency (DE) for back up. Deleted: 6 Munitions „HE) Donor cliarge Vacuuming Minimum oxygen supply Munitions (CAandHE) are destroyed Detonation off- gas (CO, H2, etc.; Clean off-gas (C02, H20, etc.; Off-gas treatment system DAVINCH detonation chamber open 0 Retention I Tank | ^•1 Solid wastes Cold Plasma Oxidizer Figure 6. Conceptual Steps of DAVINCH Figure 7. Total DAVINCH System 3.5.1.1 A quantity of over-packed munitions specific to the day's plan for detonation operations is delivered to the site via the access road. The over-packs are received and monitored for leakage of chemical agent. 3.5.1.2 The over-packed munitions (unloaded by a fork lift in the Unpack Area) are transferred by a hand lifter to the preparation area for setting the donor charge. The over-packs are moved on hand lifters by a hand crane for setting the donor charge. 3.5.2 Donor Charge Each munition has a specific placement and quantity identified for detonation based on the results of prior x-ray and analysis ofthe overpack/munition configuration. A quantity and placement plan is relayed to the operators in the preparation area for the munitions to be detonated. A shaped charge will be used in addition to the emulsion donor charge to cut the overpack and detonate the burster. The x-ray analysis from the MARB database will be used to identify the locations ofthe LSC charges, to ensure that the overpack and munition is 28 appropriately cut with the jet from the LSC. The emulsion donor charges are set in a circumferential configuration around the overpack or munition/sample container, and timed to initiate in a sequence designed to allow the explosive detonation pressure wave to implode the target evenly, ensuring complete destruction. The donor charges are "sausage-packed" emulsion explosive and are supplied in a pre-configured length and diameter by the explosive vendor. Donor charges will be delivered to the EDT site in shifts to address the daily plan for detonation. 3.5.2.1 The donor charge and LSC are picked up from the storage magazine, and assembled and transferred to the DoD- and ATF-rated modular Day Storage Box in the preparation container. They are moved from the day box to the preparation area as needed. The same plan will be used for the detonators, which are stored separately from the donor charges and LSCs. 3.5.2.2 The assembled donor charge is set aroimd the overpacks on the hand lifter by a trained operator. The overpack and donor charge are transferred from the preparation room to the detonation chamber through airlock by the hand lifter. The donor charges are manufactured and delivered in approximately 2-inch diameter by 2-to-3-foot "sausages" of explosive. These are taped into place using appropriate tape in accordance with the plan described above for each shot. The configured overpack, now surrounded by a donor charge, is placed (hung) on nylon webbed slings in the chamber by the material handling equipment. 3.5.2.3 In order to prevent improper operation and unintentional detonation, the detonation circuit shall be checked before detonation operation. An operator measures the electric resistance of detonation circuit after connecting the circuit to the switchbox, and then shorts the outlet in the chamber. After confirming the resistance is correct, the switch box, plug, and outlet near the firing device in the chamber are shorted to prevent improper operation. The operator will connect the detonators after he exits the chamber. All the explosive operations shall be done using the "buddy system" (two-man rule). 3.5.3 Chamber Preparation for Detonation 3.5.3.1 The unit's lid is robotically closed using the hydraulic clamping system, which has specialized gaskets to prevent leakage. 3.5.3.2 The chamber is evacuated using a vacuum pump, and oxygen is introduced into the chamber prior to detonation. 3.5.4 Implosion with Donor Charge The detonation process creates an exttemely hot fireball and Shockwave that destroys the chemical agent and the metal munition bodies, over-packs, and other parts, which are reduced to shards of scrap. The emulsion explosive placed aroimd the munition ensures an effective implosion process, reducing the speed and size of detonation fragments, and ensures a longer life ofthe inner chamber. 3.5.5 Off-Gas Treatment and Air Flow Phases The off-gas treatment process treats the detonation product off-gas on a batch-wise basis. Figure il shq^vs thej)re-detonatio phases pf thej)rocess. Figure^ Deleted: s Deleted: 7 Deleted: 8 29 shows the four basic irealmenl units, consisting of the H\'.AC unit lo tlraw a continuous llow of air from the EE: Treatment Unit .A. which consists of the pre-filler ani.1 \ acuum pujnp: Treatment Unit B. which consists of the Cokl Plasma (;)xii.lizer ani.1 its associalei.1 heal exchanger cooler ani.1 blower: Treatment Unit C. which consists ofthe retention lank, carbon filler bypass ani.1 C.A monitor: ani.1 Treatment Unit D. which consists of an inline charcoal filler ani.1 blower. .A utility system allows gases lo be inlroi.lucei.1 into the chamber or system. During operation, \ arious nuxles are usei.1 lo ensure negali\ e air llow when the chamber is open, ani.1 lo balance the airllow lo ensure EE negali\ e pressure. .A clamper is usei.1 lo conttol this balance of air llow. .Annex D contains more i.lelailei.1 llow i-liagrams showing the \ arious nuxles i.lescribei.1 in this section, inclut-line llow rales. 30 DAVINCH Operational Phase Treatment Phase Preparation Pre- Detonation Detonation Post- Detonation Utility Management Preparation Vacuum Extraction Oxygen injection Detonation Off-Gas Treatment-1 Off-Gas Treatment-2 Off-Gas Treatment-3 Fragment Recovery Figure 8. DAVINCH Off-Gas Treatment Phases 31 HEPA Charcoal Filter Filter Stack HVAC Damper ^-r^ Detonation Chamber Containment Filter Charcoal Filter Blower Cha rcoal Filter Retention Tank 3 UnltD Unite Vacuum LI,, ^ Pump Unit A 3xidize^»|cooie^»^lowe^- Unit B Utility Figure 9. EDT Block Flow Diagram 3.5.5.1 During pre-detonation, the off-gas system extracts air from the chamber, exhausting that air through the carbon filter bed. The detonation chamber lid is open in this configuration. The exhaust air from the HVAC System (reference Figure^, HVAC) is maintained at a constant flow rate. The air is fed through Unit D during this mode of operation. During this phase, munitions are himg, detonators set, and processing activity can occur within the chamber. The damper is used in all phases to equalize air flow and maintain negative EE pressure with respect to the exterior. Deleted: 3.5.5.2 jrhe_ Air Vacuum phase (Le... evacuation of the chamber) is accomplished by activating the vacuum pump, and extracting air from the sealed chamber through Units A and D. When the appropriate vacuum is established, the chamber is isolated. 3.5.5.3 A stream of oxygen is fed to the evacuated chamber from the Utility area through the exit of the chamber. The oxygen is used to combine with the detonation product gas and to optimize the detonation. 3.5.5.4 During detonation, only the HVAC exhausting air from the EE is operational. The chamber and other components are isolated. 3.5.5.5 After cool down, a preliminary test quantity of the detonation product gas is extracted by the vacuum pump through Units A, B, and C. If CA is detected at the monitoring point M, the system re-routes the gas, stops the flow of gas to the DAVINCH exhaust stack and directs the gas through the Retention Tank Carbon Filter F392 located in Unit C2, The chamber lid remains closed during this sequence. 3.5.5.6 After the preliminary CA check in 3 5.5, the system operates at full extraction, _ processing all ofthe detonation gas through units A, B, and C, and through the final, exterior carbon beds. Deleted: Tliis Deleted: back througli Unit B for fiirther treatment in tlie cold plasma oxidizer. Deleted: 1 3.5.5.7 The chamber lid is opened when all ofthe chamber off-gas is processed in Treatment Phase 2. Air flow continues through units A, B, and C, and through the final, exterior carbon beds. 3.5.5.8 There is a possible mode where the chamber lid is closed, and Electtostatically Charged Aerosol Decontamination (ECAD) solution is introduced into the chamber from an outside port. The chamber is isolated during that process. During this mode, the retention tank is purged through its associated carbon filter. After the chamber is deconned, the system is exhausted once again through Units A, B, and C. 3.5.5.9 The system reverts to the pre-detonation configuration where the exhaust gas is removed as in the pre-detonation mode. Fragments are removed by electtomagnet and by hand, if large enough. 3.6 Throughput 33 Table 5 shows the expeclei.1 throughput for each munition type, in a single or tlouble o\ erpack. ani.1 samples. This throughput expectation is basei.1 upon the operational experience of 5 years of operations in Japan ani.1 one year of operation in Belgium. Impro\ements on automatei.1 fragment hani-lling ani.1 a larger capacity of off-gas treatment are incoqioratei.1 into this tlesign. Three 4.2- inch HT Motor rouni.ls in M13.A2 single o\ er-packs can be i.letonatei.1 in a single shot, ani.1 a I 55- mm H Projectile in M I6.A3 1 2.\56 tlouble o\ er-packs can be i.letonatei.1 by one shot, using a total amount of explosi\ es of approximately I 1 S lb ( 53.6 kg) TNTei.|. 34 Table 5. TOCDF EDT Throughput IiuiitiDii Ovei^i:ifk(s) Agent Number of Muniiioiis & Samples MiuiitiDns/ Package Packages/ Shot Miuiitioiis/ Sliot Shots/ Day Number/ Day Days Weeks' Shots Agent/ Shot (lb) PEP/ Shot (lb TNTeq) Donor/ Shot (lb) Donor/ Shot (lb TNTeq) LSC/ Shot (lb TNTeq) Total TNTeq/ Shot (lb) 4 2" I TMortiB-M13A2 HT 117 1 3 3 7 21 6 1.5 39 17.4 2.55c 87.6 88.8 26.2 117.6 4.2" I-D Mortar M13A2 KD 18 1 3 3 7 21 1 0.3 6 18 2.55c 87.6 88.8 26.2 117.6 ECR Wasti vloftars* iKplosve 3x41 or 7x27 ED orHT See Note a 1 1 1 7 7 2 0.5 7 6.0 2.55c 65.7 66.6 8.7 77.9 155m. n H Projectile M16A3 H 68 1 2 2 7 14 5 1.3 34 23.4 0 86 102.2 103.6 23.3 127.8 155m. n H Projectile 3x41 H 27 1 1 1 7 7 4 1.0 27 11.7 043 76.6 77.7 14.6 92.7 155m n H Projectile M16A3/M10A4 H 16 1 1 1 7 7 3 0.8 16 11.7 043 76.6 77.7 14.6 92.7 155m n H Projectile PA37/12x56 H 8 1 1 1 7 7 2 0.5 S 11.7 043 102.2 103.6 14.6 118.6 155m n H Projectile M16A3/12x56 H 79 1 1 1 7 7 12 3.0 79 11.7 043 102.2 103.6 14.6 118.6 HI S i mples M2A1 HT 41 4 1 4 7 28 2 0 5 11 9 2 0 45.4 46 46 0 HD S imples M2A1 HD 6 4 1 4 7 28 1 0.3 2 5.1 0 45.4 46 46.0 1 Totnl Totals •> 58 <) 5 Either with tht s the 7x27. The Total TbTTeq/shot associated ver-pack may be used for /"aste mortars rejected in the TOCDF MDB during the mortar campaign. The 9xA 1 over pack has approjamately twice the r tteatment of mortars iti either over pack will not exceed the value shown. Mortars may be filled with HD or HT since this grouping repressent aniticipated mortar rejects from TOCDF mortar processing. •ste sfream is limitc- >.rce ofthe ECR an. C Treatment Unit within the ECRs. The number of DAVTtTCH This Wi tteatme it shall not exceed 6. T T 'Eased ^PEPw )n anticipated Four days per week munition processing ^ight included propellant. Note only one over-packed mortar is known to be cotifigured ^mtli propellent. 35 3.7 Operating Procedures All operating procedures will be provided for review and approval by EG&G. They will include, but not be limited to: EDT Control System Operations EDT Explosive Operations EDT Off-Gas Operations EDT Contingency Plan EDT Delivery, Assembly, and Checkout EDT Decontamination* EDT Monitoring And Control Operations EDT Air Monitoring Plan and Operations* Analysis Plan and Analysis SOPs* Waste Management Operations Material Handling Operations Maintenance Operations Metal Fragment Drum Headspace Monitoring Operations* (The * indicates required approval by DSHW prior to operations.) 3.8 Schedule The schedule for the EDT program is based on the following assumptions: • EDT equipment delivery date is on or about November 2010. • Permitting will be required to be in place prior to any operations; however a temporary generator may be used during installation until the air permitting process is completed which will allow for the use ofthe generators that support DAVINCIFM operations. • Completion of Installation and Systemization is anticipated to occur the first quarter of Calendar Year (CY) 2011. • The ORR will take place after histallation and Systemization. • The operational phase will be completed in approximately 2 months, including maintenance. • Decommissioning and Removal is anticipated to occur the Second Quarter of CY2011. 3.9 Closure Annex E provides the Closure Plan for the EDT. Once the munition campaigns have concluded, the site will be shifted to a decontamination and removal process. Then, when site closure has been conducted with respect to decontamination levels, the system will be packaged for shipment and removal. Minimal demolition will be required, and will be limited to a few minor system components that are not part of the main systems. Decommissioning is designed into the DAVINCH™ system. A site closure plan will guide the process of ensuring that the system is completely decontaminated using headspace monitoring to the Vapor Screen Lunit (VSL) for HD. All components will be decontaminated to the levels , - - { Deleted: short Term Exposure Limit [ (STEL) 36 specified in the closure plan. The system will be removed and transferred to a federal installation and stored bv an agency whose workers are trained in chemical agent operations. The svstem will not be discarded upon completion ofthe TOCDF project, but stored for future operations. Components will be removed and enclosed in an approved enclosure (e.g., plastic film), and monitoring will be conducted to demonstrate that the headspace ^VSL is met._ The system is self-cleaning to a large extent, simplifying the decommissioning process. A combination of cleansing shots and ECAD are used for decontamination ofthe equipment/ piping. Necessary ports are pre-installed in the equipment and piping to provide an insert point for the nozzle ofthe ECAD decon wands. As DAVINCH™ has no expansion tank, there is no concern about accumulation of carbon dust with CA or heavy metals from the munitions paint residue in the tank. Figure JJ) shows the effect of cleansing shots and Figure JL1, an illustration of ECAD. Deleted: Tlie system will be removed to a site where plant workers are trained and use the appropriate procedures for chemical operations; therefore the closure standard for instances where agent monitoiing is used on the STEL for HD. Deleted: STEL Deleted: 9 Deleted: 10 1 I.-Ml ^h..t Figure 10. Inside Chamber before (Left) and after (Right) Cleansing Shot Figure 11. ECAD Operation The EDT will use TOCDF-approved decontamination solutions (such as caustic) for equipment if decontamination is required. The SOPs for decontamination of personnel are based on the latest Material Safety Data Sheet (MSDS) for HD and HT. The decontaminating solution that will be used for personnel will be consistent with the Emergency and First Aid Procedures that are addressed in the MSDS for HD (revised: 5 March 2009), published by the ECBC. The primary decontaminating solution for a liquid exposure to HD is warm or hot water with liquid soap. Sterile saline or water will be used for any eye contact with HD. Decontaminating solution is collected in the washdown pan in the change out area. Any heavy metals are expected to remain within the chamber and will be removed using decontamination procedures based on the type of metal. Heavy metals in the PAS ducting will also be removed. 37 The chamber and lid systems will be placed on the shipping pads that were used to deliver the components. A reversal ofthe process will be conducted to ship the system off-site. The off-gas treatment systems, modular buildings, storage boxes, and utility components will be trucked off- site. Any hazardous waste will be removed by the operating contractor in accordance with the TOCDF Waste Management Plan. All general waste will be placed in approved roll-offs for final disposition. The site will be cleared of debris and returned to Area 10 control after removal of intemal fencing, wood, or other packing items. 3.10 Description of Occupancy and Destruction of Buildings within Public Access Exclusion Distance (PAED) The PAED is defined as the longest distance ofthe hazardous fragment distance (HFD), Inhabited Building Distance (IBD) for overpressure, or the One Percent Lethality Distance. For siting purposes, the PAED is analogous to the IBD for explosives; therefore, personnel not directly associated with the chemical operations are not to be allowed within the PAED. The PAED for the EDT maximum credible event (MCE) is defined in Annex D of the SSSP^ There are no occupied facilities in Area 10 within the PAED distance arc. Site access controls will be used to prevent entry into the PAED area during explosive operations by blocking off the adjacent roads as necessary. Annexe ofthe SSSP for the EDT Sit^ defines the MCE for Establishing PAED as the detonati^on of lYs'lb of TNTeq' the MCE^ as~deYme~d"in DA PAMy85-6l7is"theVoteW^ for an accident or incident to occur and cause agent release. For chemical munitions that have explosive components assembled in them, the MCE will be based on the functioning of the most disruptive component that would produce the maximum release of agent. The explosive safety quantity distance for the DAVINCH™ site is based on the accidental detonation of 133 lb of TNTeq, Hazard Division 1.2, and will be documented in accordance with the DoD Standard 6055.9. Deleted: Aimex D Deleted: Tlie Deleted: (Aimex C) 3.11 Waste Analysis Plan The DAVINCH™ will treat wastes that were previously characterized by TOCDF, and the DAVINCH™ will generate wastes that are similar to waste currently generated by TOCDF incinerator operations. H Projectiles were characterized throughout the 155-mm H Projectile Campaign as different lots were processed in the Metal Parts Fumace (MPF). Both liquid H and solid heel samples were collected and analyzed. This waste stream has therefore been thoroughly characterized, and no further characterization is required. The HT mortars were characterized during the Parsons Engineering Design Study I Projectile Washout System (PWS) Testing (Reference 3). Volume 1 (of 3) of this test report, dated 14 August 2004, provides the analytical results ofthe HT liquid agent and HT paste found in HT mortars, and the liquid HD and solid HD heels found in HD mortars. The TOCDF additionally collected liquid HT samples directly from mortars prior to feeding them to MPF and from the Agent Collection Tank to which the drained HT from mortars was transferred. The mortars have 38 been sufficiently characterized by these previously sampling and analysis efforts for their treatment in the DAVINCH™ considering that the issues with mortar characterization is the presence of mercury. The DAVINCIF'^ PAS is equipped with sulfur-impregnated activated carbon filter to control mercury emissions. Waste generated by DAVINCH™ operation are metal munition and overpack fragments, condensate formed by the oxidation ofthe hydrogen contained in the chemical agent, munition burster and explosive LSCs and donor charges, spent scrubber solution, monitormg waste, spent decontamination solution, particulate filters, ash, spent activated carbon, and discarded PPE. The estimated quantities of waste to be generated from the DAVINCH™ operation described in this plan are provided in Table 6. Table 6. Estimated Waste Generated from DAVINCH Operations Waste Description Overpack Configuration Wastes Generated Waste Description Overpack Overpack Metal Fragments Ash Condensate^ Waste Description Overpack Overpack (lb/Blast) (lb/Blast) (lb/Blast) 4.2" HT Mortar M13A2 98.3 0.55 32 4.2" HD Mortar M13A2 97.7 0.55 30 4.2" HD Mortar 9X41 or 7X27 182.5 0.55 39 155mm H Projectile M16A3 213.3 0.55 37 155mm H Projectile 9X41 117.9 0.55 34 155mm H Projectile M16A3 M10A4 137.5 0.55 33 155mm H Projectile PA37 12X56 234.8 0.55 42 155mm H Projectile M16A3 12X56 250.7 0.55 42 HT Samples M2A1 46.1 0.55 44 HD Samples M2A1 46.1 0.55 38 Totals (lb) • 42,988 133 9,126 ^Condensate is the combination of scrubber brine and condensate generated from the oxidation of hydrogen contained in the agent and explosives. Metal munition and overpack fragments removed from the Detonation Chamber will be verified to less than 0.50 VSL based on headspace monitoring results. The fragments will be placed into barrels that are equipped with both an inlet and outlet valve. The procedure requires an air purge, introduced into the sealed container using the inlet valve and vented to the Enclosure HVAC Carbon Filter System through the headspace monitoring drum's outlet valve. The air purge is then stopped and the valves closed. The contents ofthe seal container are allowed to equilibrate for four hours at 70 °F before an agent monitor is attached to the outlet valve and the contents sampled. If the monitoring results show the agent concentration in the drum to be less than 0.50 VSL, the contents ofthe drum are transferred to a roll-off or DOT-approved shipping container for disposal at a Subtitle C Treatment, Storage, and Disposal Facility (TSDF). If the monitoring results show a drum headspace result equal to or greater than 0.50 VSL,, the drum is moved underneath an intake vent to the Environmental Enclosure, opened and allowed to vent. After venting the container is resealed and th^ container contents are then monitored again to determine the agent concentration relative to the 0.50 VSL. . If the Formatted: Indent: Left: 0 pt Deleted: an additional air pmge is perfonned and tlie headspace equalizing procedure is repeated (i.e., four lioiiis at 70 °F). Deleted: The 39 drum headspace monitoring results continue to be above the 0.5 \'SL limit for metal fragments and 1.0 VSL for PPE after venting, the drum and its contents will be transferred to the TOCDF and processed through the Metal Parts Fumace (MPF). Condensate from the oxidation of hydrogen in the explosives and agent is combined with _,, - -(Deleted: t scrubber brine. The waste stream exiting the liquid scrubber will be analyzed for agent content, TCLP metals and TCLP organics. This waste stream will be transferred to an off-site Subtitle C TSDF provided the agent analytical results show that the agent content is below the Waste Control Limit (WCL), which for mustard agents is 200 parts per billion (ppb). Ash is generated in the DAVINCIF'^ Detonation Chamber; the filters are used to remove particulate from the Detonation Gas, and the cyclone filter is used to remove particulate from the Detonation Chamber Ventilation air. The munitions to be processed in the DAVINCH™ were over-packed either because the agent cavity was breached so that an agent sample could be collected from the munition or because the munitions developed a leak while in storage. It is possible that some ofthe over-packs contain packing material and absorbents that were added to prevent the munition from moving inside the over-pack. The absorbents used were cloth rags and vermiculite. This waste steam is anticipated to contain metals in parts per million (ppm) concentrations and will be sampled and analyzed for agent, TCLP metals, and TCLP organics. This waste stream will be transferred to an off-site Subtitle C TSDF provided the agent analytical results show that the agent content is below the WCL, which for mustard agents is 200 ppb. Spent activated carbon generated from the DAVINCH™ PAS fixed-bed carbon filter will be sampled and analyzed for agent, TCLP metals, total metals, and TCLP organics. This waste stream will be transferred to an off-site Subtitle C TSDF provided the agent anal3^ical results show that the agent content is below the WCL, which for mustard agents is 200 ppb. Tables 7 and 8 summarize the sampling and analysis requirements for the wastes previously discussed. 40 Table 7. TOCDF DAVINCIFM WASTE ANALYSIS SUMMARY (On-Site) WASTES REQUIRING ON-SITE TREATMENT WASTE STREAM TREATMENT UNIT(S) ANALYTICAL PARAMETERS, PREPARATION and ANALYTICAL FREQUENC Y OF ANALYSIS, SAMPLING - - METHOBL WASTE STREAM TREATMENT UNIT(S) METHODS, CEstablisli Profile) ________ _ _~ Over-Packed 155-mm H Projectiles DAVINCH™ Not Applicable; metals and organics previously characterized during TOCDF 155-mm H Projectile Campaign; data provided to DSHW Not Applicable Not Applicable Not Applicable Over-Packed 4.2-inch HT Mortars DAVINCHTM Not Applicable; metals and organics previously characterized during TOCDF HT Mortar Campaign; data provided to DSHW Not Applicable Not Applicable Not Applicable Over-Packed 4.2-mch HD Mortars DAVINCH™ Not Applicable; HD mortar metals and organics characterized during Projectile Washout System Testing; data provided to DSHW. Not Applicable Not Applicable Not Applicable Over-Packed HT and HD Samples DAVINCH™ Not Applicable; metals and organics characterized during TOCDF Ton Container, HT, and Mortar Campaigns. HD mortars characterized during Projectile Washout System Testing; data provided to DSHW. Not Applicable Not Applicable Not Applicable [ Deleted: •I Deleted: '( Deleted: i Deleted: 41 Table 8. TOCDF DAVINCIFM WASTE ANALYSIS SUMMARY (Off-Site) WASTES REQUIRING OFF-SITE TREATMENT/DISPOSAL WASTE STREAM GENERATION SOURCE ANALYTICAL PARAMETERS^ PREPARATION and ANALYTICAL METHODS FREQUENCY OF ANALYSIS, SAMPLING METHOD Munition and Oveipack Metal Fragments DAVINCH™ Container Headspace Agent Monitoring PR-010 -Each-Drum Genaated - Headspace Monitoring method; ensuie iiepresentative - - sample analyzed by MINICAMS™ Spent Scmbber Brine and Condensate DAVINCH™ Agent HD TCLP Metals TCLP Organics ^R-016 Spent Scmbber Brine and Condensate DAVINCH™ Agent HD TCLP Metals TCLP Organics 1311 and 6010 or 6020 and 7470 or 7471 1311 and 8260 and 8270 ^040 One sample from each of 3 containers generated; composited into one sample set for analysis Coliwasa Spent Scmbber Brine and Condensate DAVINCH™ Agent HD TCLP Metals TCLP Organics Detonation Chamber and PAS Particulate Filter Ash/Over-Pack Packing Material DAVINCH™ Agent HD TCLP Metals TCLP Organics ^R-016 Detonation Chamber and PAS Particulate Filter Ash/Over-Pack Packing Material DAVINCH™ Agent HD TCLP Metals TCLP Organics 1311 and 6010 or 6020 and 7470 or 7471 1311 and 8260 and 8270 One sample rrom each i of 4 containers generated; composited into one sample set for analysis Trier or coring device Spent DAVINCH™ PAS Activated Carbon DAVINCH™ Agent HD TCLP Metals Total Metals TCLP Organics ^ee Note 1 Spent DAVINCH™ PAS Activated Carbon DAVINCH™ Agent HD TCLP Metals Total Metals TCLP Organics 1311 and 6010 or 6020 and 7470 or 7471 3050 or 3051 and 6010 or 6020 and 7470 or 7471 1311 and 8260 and 8270 Core sample from each container generated duiing change out; composited into one sample set for analysis Trier or coring • device Deleted: Deleted: ^ Deleted:' J "I Deleted: See Monitoring Plan ] -( Deleted: TE-LOP-57211 ] "{ Formatted; Font: Not Bold ] -{ Formatted; Font: Not Bold -( Deleted: TE-LOP-57211 Deleted: Procedure cuixently under review "( Formatted Table 42 Spent Enviionmental Enclosiue HVAC Svstem Enviromnental Eiiclosuie Carbon Aeent HD See Note 2 Core sample from eacii container generated during change out; Trier or coring device Carbon Filter Units composited into one sample set for analysis Trier or coring device -{ Formatted; Left "I Formatted; Centered Notes: 1 Four digit number refer to SW-846 methods, most recent version. 2 Agent monitoring results may be used to demonstrate spent carbon is not contaminated with agent in lieu of performing an analysis for chemical agent. If required, spent carbon will be place in storage until an DSHW approved method is available for analysis of agent on an activated carbon matrix. 43 3.12 Personnel Limits and Protective Equipment 3.12.1 Airbome Exposure Limits (AELs) The Centers for Disease Control and Prevention (CDC) promulgates airbome exposure limits (AELs) for chemical nerve agents tabun (GA), sarin (GB), VX, and blister agent sulfur mustard (including H, HT, and HD) for demilitarization workers and the general public (Reference 4). Exposure criteria include short-term exposure limits (STELs) and immediately dangerous to life or health (IDLH) values. These new criteria augment revised long-term criteria, which include Worker Population Limits (WPLs) and General Population Limits (GPLs). The criteria were revised using various risk assessment approaches, including reference concentration (RfC), relative potency, categorical regression (CatReg), carcinogenicity potency, and the CDC/National Institute for Occupational Safety and Health (NIOSH) IDLH methods. The CDC believes the revised criteria meet the goal of protecting workers and the public at potential airbome concentration levels below those that would result in adverse health effects from acute exposure, and further protecting against risk for effects from long-term exposure. For HD and HT, the AELs are: • IDLH: 0.7mg/m^ • STEL: 0.003 mg/m^ • VSL: 0.003 mgW . WPL(8hr): 0.0004 mg/m^ • GPL: 0.0001 mg/m^ 3.12.2 Exposure Points The DAVINCH™ process potential exposure points are: • Leaking Overpack/at Delivery .QY^rpacked munitions are delivered to the DAVfflCH™ in a box truck. The sealed storage compartment is monitored for agent. If the monitoring results are confirmed to be greater than 0.5 VSL the delivery is not accepted and the contents of the tmck are retumed to DCD to be overpacked and processed by the DAVINCH at a later date. • Leaking^fter Receipt from DCD ^ICthg^I^^^QF^H^J^ft-fl^tjiin the_DAVIIsOP^_ Environmental Enclosure the overpacked munition will be placed in a plastic bag to stop the release of agent vapors and prevent contamination and the bagged overpacked munition will be treated in the DAVINCH m the intended maimer. • Leaking after Entry into Chamber - If agent is detected in the chamber after hanging the mimition, the DAVINCH™ process will continue. Personnel decontamination may be necessary, which will follow established procedures. • Exposure after Detonation - While potential for this scenario is low, any alarms after the detonation will be investigated. Personnel will back out ofthe area for decontamination, and the control system will place the system in the fail-safe mode. Established procedures will be used to isolate, decontaminate, and address the cause of the leak. It should be noted that after nearly 6,000 shots, no exposure has been detected at any of the DAVINCIP^ sites. 3.12.3 Personal Protective Equipment Deleted: The oveipacked iiiimitions will be checked prior to placement in the transfer truck. If, after transport, the munitions are leaking, vapor or Mquid exposure could result in the Unpack Area. The Unpack Area is equipped with near real time monitoring, and if a leaking overpack is identified, established procedures will be used to isolate, decontaminate, and repack tlie item, after wlrich it will be removed from the site and retimied to DCD storage Deleted: during Placement of Donor Charges Deleted; If the monitoring alarm soiuids during donor charge placement, pereonnel will back out, and response procedures will be implemented. Tlie explosives will be stabilized and decontaminated accordiug to estabhslied procedures to isolate, decontamuiate, and repack the item after which it will be removed from the site and retumed to ' storage. Formatted: Font: Bold 44 The PPE for the operator crews will consist of supplied PPE, including but not limited to coveralls and cotton goods to be worn by operators during chemical weapons operations, and Toxicological Agent Protective (TAP) gear to include butyl boots, gloves, and M2A1 Aprons as required. Respiratory protection will be through M40 masks with approved activated carbon canisters. The M40 mask combines the protective mechanisms of a charcoal filter against CWA vapors (especially nerve agent and vesicant). 3.13 Mitigation of Hazards (including Contingency Plans) Annex F provides the TOCDF EDT Emergency Response Plan, which will be the guiding document for contingency planning for EDT operations. 3.13.1 Containment The DAVINCH'^'^ containment systems are based on the following levels of containment/ engineering controls. The "primary" containment for the munitions are the existing overpacks. The "secondary" or DAVINCH™ containment is the chamber itself The detonation chamber lid has a space to capture escaping gas, and the skid-mounted off-gas units are contained in 40-ft containers, ducted to the EE enclosure. The whole process of receipt and preparation of munitions, the detonation chamber imit, waste handling, and the off-gas treatment are contained in a temporary plastic-film (with aluminum- or steel-framed) shelters acting as the EE containment stmcture. The airflow from the EE containment provides a design negative pressure -0.10to-0.5inWC. 3.13.2 Safety in Enclosure Safety systems included in the enclosure have explosion mitigation barriers in accordance with DoD 6055.9-STD, DoD Ammunition and Explosives Safety Standards (02-29-2008). In addition, worker safety will be ensured through a lockout/tagout program, a PA system for notification, CCTV observation. Occupational Safety and Health Administration (OSHA) safety markings and exclusion area markings within the facility, railings and buffer zones, and waming or informational signage. Training will also be conducted to ensure safe operations in the enclosure. 3.13.3 PPE Fit Testing All operators will be responsible for ensuring that their PPE is fit for use, properly wom, and checked on a periodic basis. 3.13.4 Emergency and Evacuation In the event of an upset condition, mimitions operators, site workers, and site control system operators will be notified by the PA system. Evacuation will then occur in accordance with the SOP for response to upset conditions requiring evacuation. The operators will report to a designated location and will be checked against the site occupancy sign-off list for the day to ensure that all are safely evacuated. 3.13.5 Emergency Response Actions 45 The TOCDF and DCD have in place assets, programs, and plans for emergency response. The TODCF will provide response to any EDT incident requiring emergency response. The EDT operation will have a direct line to the TOCDF operations center for notification of upset or emergency situations, such as a chemical event. 3.13.6 Medical Support The TOCDF has a Medical Clinic available for handling medical emergencies, including exposure to toxic agents, decontamination, and triage. 46 4.0 ORGANIZATION The overall organization for the EDT Project at TOCDF is shown in Figure j. 2. Deleted: 11 Chemical Materials Agency Site Manager Deseret Chemical Depot 1 TOCDF Site Manager EDT Subcontractor Figure 12. TODCF EDT Overall Organization 4.1 U.S. Army The principal US Army organizations involved in implementing this Plan include the Chemical Materials Agency (CMA), the Tooele Chemical Agent Destmction Facility (TOCDF), the Deseret Chemical Depot (DCD), and Edgewood Chemical Biological Center (ECBC). CMA provides oversight for the operation through its on-site representative. DCD provides operations support in Area 10, munition transportation within Area 10, security, surety and logistics support. TOCDF provides the assets including emergency response, firefighting, and chemical/hazardous materials response. ECBC provides the assets of CBARR, for trained CPRP- and explosive- certified operators, monitoring equipment, and mobile laboratory support. 4.2 State of Utah The UDEQ will provide environmental regulatory oversight of the DAVINCIP^ operation at TOCDF. The DAVINCIFM operation at TOCDF will be conducted under a Modification to the RCRA and CAA permits for TOCDF and DCD, respectively. 47 4.3 Contractors The TOCDF Operatmg Contractor, EG&G DMI (URS) will provide oversight ofthe EDT subcontractor, Versar, Inc. 4.4 EDT Site Operational Organization The EDT Site Operational Organization is shown in Figure The EDT Subconttactor w provide the EDT equipment, and will control operations to ensure that destmction is conducted in a safe and environmentally acceptable manner. The total mmiber of people on the operations team is approximately 18. The operation team consists of one supervisor, one safety manager, two technical specialists, two analysts, five groups of two persons each for operation (using the two-man mle buddy system) and 2 persons for monitoring on night shifts and weekends. Deleted: 12 Site Supervisor Site Heaitli and Safety Site Engineering Chemical And Explosive Operators Monitoring Staff Figure 13. EDT Site Operation Organization Table ^ shows the role of each group for e_yery^ shot. Groups A, B, C, and D change the role for every shot to reduce the total time of work in PPE. Group E operates DCS at the control room without PPE; therefore. Groups A, B, C, and D are required to be EOD and mechanics, while members of Group E should be engineers/chemical process operators. Table shows the job and related qualification/e?^ for the personnel comprising the groups. Groups A, B, C, and D should have the same qualifications/experience and perform the same jobs alternatively in the field. The job of Group E is completely different from A through D. Group E's job is to control the plant operation at the control room and no field work is necessary. The Training Plan, Annex G, describes the type, frequency and requirements for operator training for the TOCDF EDT. Deleted: Deleted: 9 48 DEPARTMENT OF THE ARMY us ARMY CHEMICAL MATERIALS AGENCY (PROVISIONAL) PROGRAM MANAGER FOR THE ELIMINATION OF CHEMICAL WEAPONS 4585 HOADLEY ROAD ABERDEEN PROVING GROUND, MARYLAND 21010-4005 REPLY TO ATTENTION OF: SFAE-CD-S 1 ^ 2003 MEMORANDUM FOR SEE DISTRIBUTION SUBJECT: Performance Standard for Monitoring Potentially Contaminated Workers References a. Memorandum, Office of the Assistant Secretary of the Army, Installations and Environment, 10 Jun 03, subject: Interim Guidance on Nerve and Mustard Agent Decontamination and Medical Services in Industrial Activities. b. Memorandum, US Army Chemical Materials Agency (CMA), AMSCM-D, 10 Jun 03, subject: Performance Standard for Monitoring Potentially Contaminated Workers. 2. This memorandum clarifies procedures and monitoring levels for evaluating contaminated workers and supersedes guidance published in reference 1b. Clarified guidance is enclosed. 3. CMA verify decontamination of agent contaminated workers using near real time monitors set to the certified reporting limit before the worker leaves the accident site. At any time during the decontamination procedure, medical or supervisory personnel may decide to transport the contaminated worker to the health clinic or begin life saving medical care. 4. Referenced lb Performance Standard was prepared by an interdisciplinary team composed of representatives from the Program Manager for Chemical Demilitarization, the US Army Edgewood Chemical Biological Center; the US Army Soldier and Biological Chemical Command (SBCCOM), Stockpile, Industrial, Remediation, and Restoration Enterprise, and the US Army Center for Health Promotion and Preventive Medicine which was formed to develop guidance for point source monitoring from currently available instruments. It has been modified based on input from users. This guidance addresses monitoring levels to be achieved, required monitoring times, identifies levels to determine when re-decontamination is required and establishes the information on the material safety data sheet (MSDS) as the standard for decontamination procedures. SFAE-CD-S SUBJECT: Performance Standard for Monitoring Potentially Contaminated Workers 5. Points of contact for further information are LTC Alan Cushen, SBCCOM Risk Manager, (410) 436-4985 or Mr. Steve Blunk, Chief, CMA Safety Office, (410) 436- 1435/3325. End MICHAEL A. PARKER Director DISTRIBUTION: AMSSB-OAN-CO (LTC Robert E. Jones) AMSSB-OBG-CO (LTC Dennis M. Cantwell) AMSSB-OCD-CO (COL Peter C. Cooper) AMSSB-OEC-CO (LTC Gerald L. Gladney) AMSSB-ONC-CO (LTC Joseph F. Marquart) AMSSB-OPB-CO (COL Thomas Woloszyn) AMSSB-OPA-CO (LTC James Bayha) AMSSB-OPC-CO (LTC John A. Becker) AMSSB-OUM-CO (LTC David Holliday) SFAE-CD-CO-A (Timothy Garrett) SFAE-CD-CO-T (Dale Ormond) SFAE-CD-CO-P (Randy Long) SFAE-CD-CO-U (Don Barclay) SFAE-CD-AA (Joseph Lovrich) SFAE-CD-AN (Jeffrey Brubaker) SFAE-CD-N (LTC James P. Fletcher) CF: AMSSB-OAN-CO (Mary Snyder) AMSSB-OBG-RD (Richard Hancock) AMSSB-OCD-RM (Walt Levi) AMSSB-OEC-DO (Paul Lemeshka)' AMSSB-ONC-CO (Michael Orn) AMSSB-OPB-RRS (Mark Lumpkin) AMSSB-OPA-RM (Tony Poole) AMSSB-OPC-RM (Pat Steranka) AMSSB-OUM-IRM (Mervin Beck) SAILE-ESOH (Jim Patton) AMCPE-SF (Don Pittenger) AMSSB-OSM (Trooper Studdert) SFAE-CD^S (Gregory St. Pierre) SFAE-CD-S SUBJECT: Performance Standard for Monitoring Potentially Contaminated Workers CF (Cont'd): AMSSB-RCB-R (George Collins) MCHB-TS-OFS (Stephan Graham) PMATA PMCSD PMCSD (Tim Thomas) PROCEDURES FOR NEAR REALTIME MONITORING OF AGENT CONTAMINATED WORKERS Chemical sites and operations involving chemical agent will implement the following procedures when workers are contaminated with chemical agent (e.g., potentially exposed workers, ref 1). At any time during the decontamination procedure, medical or supervisory personnel may decide to transport the contaminated worker to the health clinic or begin life saving medical care. As new technologies become available, they may also be used as long as the technology meets the following performance standard: "Chemical Materials Agency will verify decontamination of agent contaminated workers using near real time monitors set to the certified reporting limit before the worker leaves the accident site." a. The primary type of jnstrument to determine if a worker is contaminated is near real time chemical agent monitor (NRT monitor). The Automatic Continuous Air Agent Monitoring System (ACAMS), the Miniature Chemical Agent Monitor (MINICAMS®), or other low level near real time monitor is acceptable for this purpose. Regardless of which instrument a site uses, trained personnel must properly maintain, calibrate, and operate the low level NRT monitor. Site personnel must retrain the workforce on the proper utilization ofthe existing low level NRT monitor hand-held probe using these procedures. b. To be effective, site personnel must pass the low level NRT monitor probe slowly and deliberately over the contaminated worker for one full low level NRT monitor sampling cycle. The probe must remain within one to two inches from the contaminated worker's body. Properly protected personnel will screen the contaminated worker's body by quadrant starting at the head. To achieve a slow and deliberate screening of a contaminated worker, the low level NRT monitor operator will coach the worker handling the probe on when to move to the next quadrant. One- fourth ofthe low level NRT monitor sampling cycle will be spent on each quadrant of the contaminated worker's body. As an example, for a low level NRT monitor running on a two-minute cycle, thirty (30) seconds will be spent screening the face, chest, and abdomen; thirty (30) seconds screening the head, arms (including each hand) and back; thirty (30) seconds screening the pelvic region and front ofthe legs; and thirty (30) seconds screening the back ofthe legs, feet, and buttocks. The low level NRT monitor operator will verbally tell the worker with the probe how far they have progressed in each cycle. Low level NRT monitor operators and probe operators must practice this screening procedure at least quarterly. c. For chemical sites and operations that do not have low-level NRT monitors, the site safety plan must address the decontamination and screening of contaminated workers to ensure workers are adequately protected. d. The site will base the level of decontamination on the extent ofthe worker's injuries. If after the initial decontamination, the NRT monitor operator still receives reading above the certified reportable limit, the worker will be re-decontaminated if the medical situation permits. At any time during the decontamination procedure, medical or supervisory personnel may decide to transport the contaminated worker to the health clinic or begin life saving medical care. e. Site personnel will decontaminate all contaminated individuals according to the emergency and first aid procedures listed on the agent material safety data sheet. EDT DESTRUCTION PLAN ANNEX A - ACRONYMS AND ABBREVIATIONS November 2010 Formatted: Font: 14 pt Formatted: Font: (Default) Times New Roman, 14 pt .\NIVE\ .\ - .\CRONMVlS .\ND .\BBRE\l.\TIONS This .\nne.\ presents the .Acronyms and .Abbre\ iations used in the TOCDF EDT Destruction Plan ani.1 .-\rine.\es. .A-1 ACRONYM/ABBREVIATION ANSI AR ASME ATAP ATF CA CAA CBARR CCTV CDSP CEES CMA CWM DA PAM DAAMS DAVINCH n-DBS DCD DDESB DEQ DESTINY DSHW DOT DV60 ECAD ECBC EDT EE EG&G DMI GC/MS GRAND H HAZMAT HD DEFINITION American National Standards Institute Army Regulation American Society of Mechanical Engineers Altemative Technologies and Approaches Program Bureau of Alcohol, Tobacco and Firearms Chemical Agent Clean Air Act, as amended Chemical Biological Applications & Risk Reduction Closed Circuit Television Chemical Stockpile Disposal Program Chloroethylethyl Sulfide Chemical Materials Agency Chemical Warfare Mimitions Department ofthe Amiy Pamphlet Depot Area Air Monitoring System ^Detonation of Ammunition in a Vacuum Integrated Chamber di-Butvl Sulfide Deseret Chemical Depot Department of Defense Explosive Safety Board Department of Environmental Quality Damage Evaluation System - Time? Not Yet!, as in real time damage assessment system for DAVINCH jPiyision of Solid and Hazardous Waste Department of Transportation DAVINCH EDT Chamber, 60 kg TnT Net Equivalent Capacity Electrostatically Charged Aerosol Decontamination Edgewood Chemical Biological Center Explosive Detonation Technology Environmental Enclosure EG&G Defense Materials, Inc., Operating Contractor, TOCDF Gas Chromatography/Mass Spectrometry Global Rapid Assistance Network of DAVINCH Mustard agent Hazardous Materials (as in response team) Mustard agent Deleted: Detonation in a Vacuum Integrated Chamber I Deleted: Department A-2 ACRONYM/ABBREVIATION DEFINITION HEPA High efficiency particle arresting HFD Hazardous Fragment Distances HT Mustard agent HVAC Heating, Ventilation, and Air Conditioning, as in system IBD Inhabited Building Distance IDLH Immediate Danger to Life and Health lOP Intemal Operating Procedure, ECBC LPG Liquified Propane Gas LSC Linear Shaped Charges, explosives MARB Material Assessment Review Board MINICAMS Miniature Chemical Agent Monitoring System MPF Metal Parts Fumace MSDS Material Safety Data Sheet NaOH Sodium Hydroxide NFPA National Fire Protection Association pSHA Occupational ^afetv and Health Administration ORR Operational Readiness Review PA Public Address System PAED Public Access Exclusion Distance PAS Pollution Abatement System PM-CSE Program Manager, Chemical Stockpile Elimination PPE Personal Protective Equipment PWS Projectile Washout System QA Quality Assurance Q-D Quantity-Distance (arcs) RCRA Resource Conservation and Recovery Act RCWM Recovered Chemical Warfare Munitions SETH Simulated Equipment Test Hardware, as in simulated munition bodies SOP Standard Operating Procedure(s) SSSP Site Specific Safety Plan TAP Toxicological Agent Protective, as in gear TC Ton Container TCLP Toxic Characteristic Leaching Procedure (EPA requirement) TNTeq TnT Equivalent, explosives TOCDF Tooele Chemical Agent Destruction Facility TSDF Treatment Storage Disposal Facility UAP Unescorted Access Program UL Underwriters Laboratory A-3 Deleted: OHSA -\ Deleted: Health and ACROINr\M/ABBRE\ lATION DEFIIMTION L^PS UninletTuplei.1 power suppl\' US.ATCES US .Arm\' Technical Center for E.\plosi\ es Saret\- \'SL \'apor Screening Le\el W'C Inches of water column, as in pressure (.iilTerenlia! WCL Waste Control Limit WPL Worker Population Limit .\-4 EDT DESTRUCTION PLAN ANNEX B MONITORING PLAN rRev. 1) November 2010 SITE-SPECIFIC MONITORING PLAN (Rev. 1) 155-mm Leaker Campaign Explosive Destruction Technology (EDT) Operations Deseret Chemical Depot (DCD) Submitted to: A niibhH ur EG&G Defense Materials, Inc. A Division of URS, Inc. 11600 Stark Rd. Stockton, UT 84071 Submitted by: VERSAR Versar, Inc. 6850 Versar Center Springfield, VA 22151 ^ { Deleted: August 23,2010 • - -[ Formatted; Indent: Rrst line: 0 pt j^ovember 2010,__ /^.^ Deleted-.^ 11 TABLE OF CONTENTS TABLE OF CONTENTS i .\PPEIVDICES ii LIST OF TABLES iiii LISTOFnClTiES iiii 1.0 INTRODUCTION l 1.1 B\CKGROLiND 1 1.2 PlfRPOSE 2 1.3 SCOPE 2 1.4 CiiiAiK .\i, .\GEiNTS Ol-CONCERN 2 1.5 MONITORINC ()B.|i:(TI\ ES 3 2.0 ORGANIZATION AND NL\NAGEMENT RESPONSIBILITIES 3 2.1 CMA 3 2.2 CMA-MoNiTORiNG OFFICE 4 2.3 ECBC 4 3.0 MONITORING CONCEPT 4 4.0 MONITORING ST.\ND.\RDS .\ND CONTROL LIMITS 5 4.1 AELs FOR CHEMIC.\L AGENTS 5 4.2 .\ELDEFIJNITIOINS 6 5.0 MONITORING .\ND S.\MPLING EQllPMENT 10 5.1 MEMCXMS"^" EQUIPMENT DESCRIPTION lo 5.2 DAAMS S.\MPLiNG EQii|p\[ENT DESCRIPTION lo 5.3 NE.\R-RE.\L-TIME MONITORS lo 5.4 DEPOT ARE.\ AIR MONITORING S^ STEM 11 5.5 DILUTION AIR FLOW CONTROLLERS(DAFC) 11 5.6 B.\CKUP EQUIPMENT 11 5.7 MoNiTORiNG.\ND AN.\L^Tlc.\L EQUIPMENT OPER\TIONS.\NDNL\INTEN.\NCE (O&M) REQUIRE\ENTS 11 6.0 MONITORING OPER.\TIONS/STR.\TEGIES l" 6.1 .\RT/(:ONFIR\I.\TION 1 7 6.2 I IlSTORIC.\iy(\)NFIRMVnON 1 7 7.0 MONITORING S\ STEMS 18 7.1 NRT MoiviTORLNG 25 7.2 CONFIRM.vnoN MONITORLNC 2S 7.3 FIRST ENTR^• 3o 7.4 HE.\DSP.\CE 31 7.5 PERSONNEL DECONT.\MIN.\TION ST.\TION (PDS) 31 7.6 HISTORIC.^, MONITORING 31 1 TABLE OF CONTENTS (continued) 7.7 \'.\poR SCREENING 31 8.0 S.\MPLE AND .\N.\L\ TIC.\L METHODS 32 9.0 .\L.\RM RESPONSE/REPORTING POSITIN E CHENOCAL M\TERIEL RESPONSES 32 9.1 MOIVITORUNG LE\ ELS 32 9.2 MIN1CAMST"AL.\RM SETPOINTS 32 9.3 NRT .NOTIFIC.VTIONS 32 9.4 CONFIRAUTION .\ND HLSTORIC.\L NOTIFIC.\TIONS 33 9.5 W PL EXCURSIONS 36 10.0 MONITORING OF POTENTIALL\ EXPOSED W ORKERS 36 11.0 Ql'ALIT\ CONTROL REQI'IREMENTS 36 11.1 CFRTIFK ATioN REQUIREMENTS 36 11.2 C.\LIBR.\TION .\NDTEST METHODS 39 11.3 QCS.\MPLING 40 11.4 S.\MPLE R\NDLING .\ND ST0R.\GE 42 11.5 ST.VHSTK AL N'ALIDATION 44 11.6 QC OF DAAMS TUBES 45 11.7 TUBE CONDITIONING 45 12.0 DOCnVIENT.\TION 46 12.1 GENER.\L MONITORING DOCUMENT.\TION 46 12.2 EQUIPMENT DOCUMENTATION 46 12.3 REFERENCE STANDARDS 46 13.0 TRAINING REQI'IREMENTS 46 .\PPENDICES .\PPENDL\ 1 .ACRON^TvlS .\BBRE\"LATI(:)NS TERMS 45 .\PPENDL\2 REFERENCES 49 LIST OF TABLES 4-1 H"HD HT .AELs 7 4- 2 H HD HT .AELs S 5- 1 Description ani.1 Rei.|uiremenls I'or Monitoring ani.1 Sampling Ei.|uipment 1 2 5- 2 Support Gases Ei.|uipment Rei.|uirements 16 6- 1 Monitoring .Application ani.1 Monitor Type IS 7- 1 Summary- of Monitoring Strategv for D.AMNCH'^" DCD EDT Operations 2o 9-1 NRT No'tification Matri.x '7.'. 32 9-2 D.AAMS Tube .Analysis Matrix 33 I 1-1 (^C Requirements for lOP Nrr-o2 35 I 1-2 (^C Requirements for lOP NTT-Li 36 I 1-3 Samples Sizes lor Normal Inspection I'or Ma.\imum ol" 2.5 Percent Nonconlbnnance..43 USTOFFIGlTiES 7-1 Monitoring Locations ani.1 Diagram of D.A\TNCH'''" S\stem 19 1.0 INTRODl'CTION This i-locument presents a site-specific plan for air ani.1 waste monitoring at the site ofthe Detonation of .Ammunition in a \'acuum Integratei.1 Chamber ( D.A\TNCH''''^) E.\plosi\ e Destruction Technology (EDT) System at the Deseret Chemical Depot ( DCD). Stockton. Utah. This plan atklresses the monitoring rei.|uirements as specifiei.1 in the U.S. .Army Chem ical Materials .Agency ('CMA) Progrummutic Monitoring Concept Plan (MCP). the CMA Progrummutic Luhorutoiy an J Monitoring Quality- .Assurance Plan (LNK^.AP). ani.1 the Ei.lge\vooi.l Chemical Biological Center ( ECBC) En\ ironment Monitoring Laboratory. Lahoratoiy anJMonitoring Quality- Control Plan (L\ IQCP) Jbr Chemical Materials .-\genc\- (CM.-i) anJJbr Chemical .-\gent StanJarJ .Analytical Reference Material (CAS.ARM). 1.1 B;ickground EG&G DND. a contractor to the U.S. .Army ani.1 operator ofthe Tooele Chem ical Demilitarization Facility (T(!)CDF). Iocatei.1 on the DCD. has a rei.|uirement for a technology to process 351 reject munitions that either e.Khibitei.1 or ha\e a high probability of exhibiting contlitions that LIO not allow them to be processei.1 using baseline practices. The T(!)CDF researchei.1 other technologies usei.1 to i-lestroy leaking ani.1 ON eqiacketl chemical weapons, inclutling E.\plosi\ e Destruction Technology (EDT) that has been or is currently being usei.1 in the Unitei.1 States. Unitei.1 kingtlom. Belgium, ani.1 Germany. E.\plosi\ e Destruction Technology e\ ol\ ei.l from an increasing neei.1 to safely tlestroy reco\ erei.l chemical warfare material (RCWM). The EDTs ha\ e safely i.lestroyei.1 RCWMs in Pine Bluff. .Arkansas: Waianae. Hawaii: Porton Down. Unitei.1 kingtlom: Poelkapelle. Belgium: ani.1 Munster. Gemiany. Riot control ani.1 \ arious mustan.1 agents (with ani.1 without energetics) ha\ e also been safely i.lestroyei.1 by EDTs. These EDTs ha\ e also pro\ en elTecti\ e for tlestruction of con\ entional weapons. EG&G DND has subcontractei.1 with \'ersar. Inc.. to pro\' itle EDT ser\ ices to inclutle a i.letonation chamber. e.Khaust gas filtration system. en\ ironmental enclosure with engineerei.1 cascatle \ entilation system, all necessary subsystems ani.1 operators as a complete package: this package will be i.leli\ erei.l to. installei.1. systemizei.1. operatei.1. closei.1. ani.1 remo\ ei.l from the DCD in Stockton. Utah. The EDT system to be provided by \ ersar ( i.e.. D.A\TNCH'r". model D\'6o ) will process the chem ical warfare material ('CWM) in\ entory of 1 55-mm Projectiles ani.1 4.2-inch Mortars ( leakers ani.1 rejects) ani.1 agent samples storei.1 at the T(!)CDF ani.1 ii.lentifiei.1 for e.\plosi\ e system tlestruction tlisposal by the Munitions .Assessment Re\ iew Boan.1 (NLARB). The chemical agent of concern for these munitions is mustan.1. The EDT process at DCD is to run parallel to T(!)CDF"s current baseline schetlule so as not to impact T(!)CDF mission completion by the CWC treaty i.late. The E.\plosi\e Detonation System concept of operations is to tlestroy o\erpackei.l chemical munitions using specializei.1 e.\plosi\ e tlonor charges in a \ acuum-assistei.l. multiple-layerei.1. annorei.1 steel chamber capable of containing the explosion. The extreme pressures, temperatures, ani.1 shock wa\ esgeneratei.1 by the tlonor charge tlestroy the o\ erpack. munition boi.ly. e.\plosi\ es burster charges containei.1 in the munitions, ani.1 chemical agent fill in microseconi.ls. (!)perations will be controllei.1 from a remote control room that contains all human- machine interface, process monitoring. CCT\'. ani.1 communication ei.|uipment. The D\'6o has the capacity to tlestroy 1 33 lb (60 kg of TNT ei.|ui\alent) of e.\plosi\es ani.1 all ofthe specifiei.1 1 munitions listed in the REP without unpacking or other pre-treatment, in a lO-hour-day/4-day- per-week operation mode. The system's major subsystems include: DAVINCHTM Explosive Detonation Chamber; Off-Gas Treatment System; Control System; Utility System; and Ancillary Equipment The general personal protective equipment (PPE) to be wom during EDT System operations will be Level C. However, all monitoring will be performed at levels required for unmasked workers, designated as "no respiratory protection" in airbome exposure limit (AEL) tables. A typical operational day will be 10 to 12 hours. All MINICAMS™ monitoring systems will operate continuously under normal baseline and, therefore, will be challenged during non- operational hours. However, if mobile criteria are used, challenges may occur periodically in accordance with LMQAP. Chemical agent products are not intended to be stored on-site in the Environmental Enclosure (EE) during non-operational hours. 1.2 Purpose The purpose of this plan is to provide the strategy to monitor for potential airbome vapor concentrations and generated waste products for the chemicals of concem during operation ofthe DAVINCH™ System at the DCD EDT site. The monitoring equipment will serve to provide agent detection, worker and general population protection at the site, and to indicate whether or not EDT operations are in control. 1.3 Scope This plan establishes monitoring objectives, procedures, and responsibilities for the execution of a monitoring program at the DCD EDT site. Monitoring strategies used to support operations at the site are based on the following assumptions: • The chemical material contents of each munition/item have been identified. • Items will be processed based on a predetermined quantity per day. • The EDT unit will be located in an EE. 1.4 Chemical Agents of Concern The DAVINCIF'** EDT System will be used to destroy munitions/items filled with the following chemical agents: • Levinstein mustard (H), or bis(2-chloroethyl) sulfide. Mustard produced by 2 the levinstein process contains about 30 percent sulfur impurities. The H is monitored as distilled mustard (HD). • Distilled mustard (HD), or bis(2-chloroethyl) sulfide, CAS number 505-60-2. The HD is H that has been purified by washing and vacuum distillation to reduce sulfur impurities. • HT, or a lethal vesicant composed of approximately 60 percent HD [bis(2- chloroethyl) sulfide] and 40 percent agent T {bis[2-(2-chloroethylthio)ethyl]ether}. Both HD and T are alkylating agents. The HT is monitored as HD. 1.5 Monitoring Objectives Monitoring during DAVINCH^'^ EDT operations will be performed to ensure that chemical material destmction operations are being safely conducted, and to detect any conditions that may cause a release of chemical material. Monitoring of the DCD EDT site during treatment activities will: • Provide worker protection. • Protect the environment from a potential chemical agent release. • Provide early waming to decision-makers for implementation of corrective action(s). • Verify that treatment activities are complete. • Verify that cleanup activities satisfy necessary performance/compliance standards. For the chemical agents of concem, exposure limits are based on maximum concentration values that are not to be exceeded for a given period of time, depending on the level of protection wom by personnel. In general, unmasked workers should not exceed established unmasked worker time/concentration Short-Term Exposure Limits (STEL) and/or Worker Population Limits (WPL). 2.0 ORGANIZATION AND MANAGEMENT RESPONSIBILITIES The EDT operations at DCD will require collaborative efforts between several govemment agencies. 2.1 CMA CMA is responsible for: • Developing and coordinating all plans and procedures required for EDT operations. • Ensuring that appropriate review/approval of EDT procedures is obtained from the Department ofthe Army (DA) and outside agencies. • Implementing a quality assurance (QA) program. • Ensuring that Occupational Safety and Health Administration (OSHA) and DA health and safety requirements are met • Overseeing agent treatment and certifying that treatment is complete. 2.2 CMA-Monitoring Office The CMA-Monitoring Office is responsible for: Notifying outside agencies such as the Department of Health and Human Services (DHHS) of monitoring results. Defining laboratory and monitoring QA requirements for monitoring activities. Advising on laboratory-related quality assurance/quahty control (QA/QC) practices. Recoiumending QA/QC practices for use in supporting the EDT monitoring activities. Monitoring the effective implementation of this SSMP at the DCD EDT site. Reviewing QC data and recommending remediation, as required. 2.3 ECBC Monitoring operations will be conducted by the ECBC Monitoring Branch. ECBC will: Collect md retain all monitoring data and monitoring QC data generated during the project. Provide guidance for monitoring operations conducted on-site. Provide trained and certified personnel to set up, calibrate, and challenge monitoring equipment; and collect monitoring and waste screening samples. Provide calibration and challenge research development, test, and evaluation (RDT&E) standards for chemicals of concem. Perform monitoring procedures outlined in this plan. Provide an operational Mobile Analytical Platform (MAP) configured with instrumentation capable of analyzing Depot Area Air Monitoring System (DAAMS) tubes. 3.0 MONITORING CONCEPT Monitoring for toxic chemicals is a critical element for the effective implementation of the U.S. Army's cardinal principle, which is defined as follows: "The cardinal principle to be observed in any location or operation involving explosives, ammunition, or toxic chemical agents is to limit the potential exposure to a minimum number ofpersonnel, for a minimum period of time, and to a minimum amount of the hazardous material consistent with safe and efficient operations. " (DA Pam 385-61, March 2002, Parag}~aph 6-1). To effectively implement the cardinal principle, engineering controls, administrative controls, and PPE are used in combination, and each play a critical support role. Engineering and administrative controls shall be implemented, when practical, to minimize: • Number of personnel involved in operations; • Persormel exposure time; and • Toxic chemical concentrations. Use of engineering and administrative controls shall be implemented to the extent possible to reduce the PPE level of protection. When engineering and administrative controls are not practical or are determined to be insufficient, PPE shall be considered for effective mitigation of potential exposure. Monitoring shall be used to evaluate the overall effectiveness of engineering and administrative controls, and when PPE is used, monitoring shall be used to ensure that levels, as defined in section 4.0, are not exceeded. Placement of each monitoring/sampling point shall be based on potential chemical migration points, and designated monitoring points shall be verified via the use of sulfur hexafluoride (SF6) or smoke tests. When monitoring supports personnel protection, monitoring locations should be located in close proximity to personnel work activities. All monitoring devices used for CWM detection shall satisfy the certification and performance requirements specified in the CMA-LMQAP, most current revision. 4.0 MONITORING STANDARDS AND CONTROL LIMITS Airborne Exposure Limits (AELs) for H, HD, HT, at the STEL, WPL, General Population Limit (GPL), Vapor Screening Limit (VSL), and Source Emission Limit (SEE) are listed in Tables 4-1 and 4-2. 4.1 AELs for Chemical Agents Values identified in Table 4-1 are final CDC recommendations for H/HD/HT AELs. Values identified in Table 4-2 are time-and-concentration derived values. Table 4-2 provides maximum concentration values not to be exceeded for a given period of time, depending on the level of protection wom by personnel. The STEL values are short-term exposure limits. Occurrences above these short-term concentrations require immediate egress and re-entry in increased level of protection. The WPL values are long-term exposure limits. If a worker is in an area for 8 hours, the average concentration in the area for the 8-hour period should not exceed the S-hour WPL exposure Mm it for the le\el of protection worn by the worker. If the exposure limit is e.\ceei.lei.L implementation of correcti\e actions is rei.|uirei.l. 4.2 .\ELDerinilions 4.2.1 Genenil Population Limit (GPL) The GPL is an allow able 72-hour. time-\\ eightei.l-a\ erage concentration for the general population. The limit applies to the entire jiopulation. inclui.ling all ages ani.1 medical contlitions. The 12-hour GPL for HD is 2 .x Kr mg m". 4.2.2 \\ orker Population Limit (\\ PL) The WPL is the a\ erage allow able concentration that an unmaskei.1 worker coukl be e.xposei-l to for an S- to 1 2-hour w orki.la\'. 4() hours per w eek for 3() \ ears. w ithout atk erse etlects. The WPL for the DCD EDT Site has been ai.ljustei.1 to rellect a 1 o- to 1 2-hour work shift. How e\ er. since operators will not speni.1 more than S hours untlergoing tlestruction operations, the S-hour WPL for HD (i.e. 4 .x lo~^ mg m"') will be asei.!.. 4.2.3 Short-Term Exposure Limit (STEL) The STEL is the ma.ximum concentration to w hich unprotectei.1 chemical agent w orkers ma\' be e.xposei-l to for up to 1 5 minutes, continuous!}'. The STEL for mustan.1 agent is 3 .x lo""' mg m"\ Only one e.xposure i.lail\' is allowei.1 at the STEL for mustan.1. 4.2.4 \':ipor Screening Limit (\'SL) The \'SL is a \ apor concentration term that is ini.lepeni.lent of time. It ma\' be usei.1 to (.lefine the le\ el to w hich an item is monitorei.1 to tletermine the agent contamination le\ el. The \'SL for mustan.1 agent is 3 .x 1 o""" mg m"\ 4.2.5 Immediately Dnngerousto Life :uid Henlth (EDLH) The EDLH is the ma.ximum concentration, in the e\ent of respirator failure, w here a person coukl escape w ithin 3o minutes w ithout a respirator ani.1 w ithout e.xperiencing an\' escape-impairing (e.g.. se\ ere e\ e irritation) or irre\ ersible health effects. The IDLH le\ el is o.7 mg m" for mustan.1 aeent. Table 4-1. H/HD/HT AELs" Sulfiir Mustard (H, HD, HT) ^ Criteria GPL WPL STEL'^ IDLH*^ Exposure Level (mg/m3) 0.00002 0.0004 0.003 0.7 Averaging Time 12 hours 8 hours <15 minutes <30 minutes Recoimnended Monitoring Method Historical^ Historical^ or Ne^-real-Near-real-time Near real-time Although the Centers for Disease Conti'ol and Prevention (CDC) do not specifically recommend additional reduction factors for statistical assurance of action at the exposure limit, exposm^es to sulfur mustard should be minimized given the uncertainties in risk assessment, particularly as related to characterizing carcinogenic potency. The toxicity data for agent T is inadequate for setting exposure limits. The very low vapor pressure for agent T precludes its classification as a vapor hazai'd under normal ambieiit conditions. For suMir mustard and T mixtures, air monitoring for sulfui' mustard alone should be sufficient, under most circumstances, to prevent exposure to T. To be evaluated with a near-real-time instrument using shortest practicable analytic cycle time. No more than one exposure per work-shift. The mustard IDLH is based only on non-carcinogenic effects. No IDLH has been established for carcinogens. Historical monitoring typically is used for tmie-weighted-average (TWA) monitoring where the sample analyzed represents an extended time period, for example, 8 or 12 hom^s. Results ai^e not known until laboratory analysis is completed after the sampling event. The AELs using historical monitoring are set at levels at which health effects are not expected to occur for most workers. Exposures above the WPL-8, but below the STEL, likewise, are not expected to result in significant health effects unless such exposures occur continuously for lor^ time periods. Table 4-2. H/HD/HT AELs Averaging l Time (mg/m^^ GPL WPL WPL WPL WPL STEL'' H/HD/HT (12 hours) (12 hours) (8 hours) (4 hours) (2 hours) (15 minutes) Variable General 2 X 10"^ Population No Respiratory Protection 2.7 X 10"^ 4 X 10"^ 1.6 X 10"^ 3 X 10"^ Air-Purifying Respirator For sulfur mustards, air-puriiy ing respirators are for escape purposes only. Supplied-Air Respirator w/o 0.27 0.4 0.8 1.6 3.0 Escape Bottle Self-Contained Breathing Apparatus or 2.0 X 10'^ 4.0 8.0 16.0 30.0 Supplied-Air Respirator with Escape Bottle Demilitarization Protective Ensemble lOO.O" Deleted: Deleted: Vapor Screening Limit (VSL) Source Emissbn Limit (SEL) 3x 10' 3 X 10" iln\ iiicli .\jiiie\ B iiioiiiloriii2 |)laji Himl ve\ I .iloc E.\|)Or:iirer: ill I lie STEL r:|iiill occiir iiol more IIKUI one I line |)er ihn . The ("eiilerr: lor Dir:eiir:e ("oiilrol ami Pre\ eiilioii (("D(") |)iil>Ur:li ii|)iliileil iimiil>err:. liii|)leiiieiileil ii.-: a ceiliiie \aliie. Nole;:: .\irl>onie e.\|)Or:iire liiiiil?: (.AEL;;) iire lakeii Iroiii .Anii\ Reeiilalioii .iS'^-Ol ( 1 2 ()clol>er 01 ) ami O'-) FR 2'-) 1 (1-1-2'-) 1 oS (0.^ Ma\ 0-1). .All .AEL;: are coiiceiilralioii ami lime \ ill lie?:, iiol coiiceiilralioii oiJ\ \ aliie?:. .Ailiiiiiur:lrali \ e coiilrolr: iiia\ l>e iir:eil lo liinil |)oleiilial e.\|)Or:iire lo vv orker?:. Hovve\ er. l>ecaiir:e ailiiiiiur:lrali \ e coiilrolr: camiol l>e iir:eil lo limil Uie iliiralioii or|)oleiilial |)iil>lic e.\|)Or:iire. oiiK I he vv orker |)0|)iilalioii limil (\^'PL) |)rolecli \ e acdoii le\ el ir: r:ieiiillcaiill\ alVecleil In ailiiiiiur:lrali \ e coiilrol;:. vv lucli lunil die il lira don or|)oleiilial e.\|)Or:iire. The II lii-M Ilium iir:e coiicei Ural ion ir: die |)roihii.i ofllie .A EL ami I he ar:r:ieiieil |)rolecdoii liiclor lor die rer:|)iralor. The iir:r:ieiieil |)rolei.iioii liiclorr: iir:eil in ilur: lal>le are liikeii Iroiii oS FR .'^-lO.Vi-.'^-l I h). o Jime 200.V The mi.xmre HT r:liiill l>e iiioiuloreil a?: H D. The r:oiirce eiiiir:r:ioii lunil war: |)re\ iour:l\ kjiovv II a?: llie allovval>le r:lack coiiceiilralioii (.AS("). 5.0 MONITORING AND SAMPLING EQUIPMENT The chemicals of concem at the DCD EDT site will be monitored using the following equipment: • MINICAMS™; and • DAAMS tube sample collection followed by analysis with GC/MS or GC/FPD. The MINICAMS'^'^ is considered a Near-Real-Time (NRT) agent monitor. The DAAMS is used as a historical method and for confirmation of NRT alarms and historical concentrations greater than the reportable limit(s). The following paragraphs describe the monitoring equipment in more detail. 5.1 MENICAMSTM Equipment Description The MINICAMS™ is an automated gas chromatograph (GC) that operates by altemating between sampling and analysis cycles. During the sampling cycle, a vacuum system pulls an air sample into the MINICAMS™ via a heat-traced sample line (HTSL). 5.1.1 MINICAMS™ Configuration/Operation The air sample enters the MINICAMS™ and concentrates on a solid sorbent tube (i.e., a pre- concentrator tube). The sorbent tube is maintained at a temperature that will prevent condensation from forming on the tube. During sample analysis, the solid sorbent tube is heated to thermally desorb the analytes, while nitrogen flows into the sorbent tube to sweep the analytes into the capillary column for analytical separation. Analytes undergo chromatographic separation and are carried to the detector for sample analysis. 5.2 DAAMS Sampling Equipment Description The DAAMS tubes are used to confirm agent MINICAMS™ alarms and to provide historical monitoring at WPL. The DAAMS stations are comprised of solid sorbent DAAMS tubes, sample manifolds, sequencers, pumps, and flow control devices. Air monitoring with DAAMS employs air aspiration through the DAAMS tube for a predetermined period of time at a controlled airflow rate. Contaminants in the air are adsorbed on the solid sorbent. Aspirated DAAMS samples are then analyzed in the laboratory to detect chemical material at the prescribed monitoring levels. Laboratory analysis uses thermal desorption ofthe analytes from the sorbent tubes into a GC/MS or GC/FPD. 5.3 Near-Real-Time Monitors The Near-Real-Time (NRT) Monitors are configured to monitor the chemical agents being processed at the Site. These NRT monitors are used to monitor the operational areas, filters, and stacks. They may monitor at th^ WPL, VSL, and IDLH co , ^ - -{ Deleted; STEL mustard chemical agents. 10 5.4 Depot Area Air Monitoring System Depot .Area .-\ir Monitoring S\ stem (•D.-\.-\MS) collects air samples to tletect chemical agents, for conllrmation of NRT monitor alarms, .-\nal\ sis of D.-\.-\MS samples pro\ ii.les conllrmation of agent if concentrations are at or abo\ e the i.lelmei.1 Reporting Limit ( RL). Instrumentation usei.1 liir agent conllrmation are the Gas Chmmatograph}' Flame Photometric Detector ( GC FPD) ( D.AAMS) orGC-Mass Selecti\ e Detector (GC-MSD). 5.5 Dilution Air Flow Controllers (DAFC) Both the NRT monitor ani.1 D.-\.AAIS use tlilution airllow contmllers. The puqiose ofthe tlilution llow controllers is to inject i.lr\- air into the sample stream to pre\ ent the lii.|uii.l in the sample Irom coni-lensing in the sampling ei.|uipment. keeping the sample abo\ e the i.lew point. The tlilution llow contmllers are i.lesignei.1 such that the llow contml i.le\ ice has a feetlback signal to a How meter. This feetlback signal causes the ratio ofthe sample llow to sta\' constant once the t\\ o are lockei.1 together. Therefore, the unit compensates for an\' interruptions in the sample llow ani.1 maintains the correct ratio. The agent concentration in the D.A-\MS tubes is calculatei.1 using the \olume of sample air. not the tlilution air. The same theor\- of operation hokIs true w ith the NRT monitors. The NRT monitors are calibratei.1 regartlless ofthe i.|uantit\' of i.lilution air. The i-lilution air can be consii.lerei.1 a carrier for the sample. The agent concentration is basei.1 on the \olume ofthe sample. 5.6 Backup Equipment The function ofthe NRT monitor is to rapitlk tletect agent. Shouki a neei.lei.1 instrument fail, the l1rst response is to tmubleshoot ani.1 repair it in place. Shouki the estimatei.1 repair time be in e.xcess of 1' j hours the NRT monitor shall be replacei.1 w ith an NRT monitor Irom the contingency'. 5. 7 Monitoring and Analytical Equipment Operations and M:iintenance (0«&M) Requirements This section summarizes the sampling ani.1 analytical ei.|uipment rei.|uirei.l for N erilying control of agent m igration in air ani.1 in process eflluents for DCD EDT site acti\' ities. .All hartlware associatei.1 with air monitoring ani.1 laboratory ei.|uipment will be maintainei.1 in accon.lance with the manufacturers" operations ani.1 maintenance (•(!)^&M) manual recommeni-lations ani.1 ECBC associatei.1 \OPs. Table .^-1 pro\ ii.les general tlescriptions. operational rei.|uirements. ani.1 pre\ enti\e maintenance rei.|uirements. Table .^-2 pro\' itles ei.|uipment rei.|uirements for support gases. 11 Monitoring NRT Monitors: MINICAMS > XSD Operational Components Operational Components • Preconcentrator Tubes/Sample Tubes • Sample Loops • Capillarv Columns • Mass Flow Controller Support Gases: • Purifiers (optional) • Leak Detectors • Compressed Gas Regulators Manufaqturer Specifications Electrical Requirements; • Critical NRT monitors equipped with UPS • Power is provided m accordance with manufacturer specifications. Temperature: • Use operational performance characteristics to determine if the NRT is operating within control. • Doors to environmentally controlled NRT monitor shelter must remain closed at all time, except during personnel entrv/egress. • Condensation shall be minimized and if obser\'ed, corrective actions will be taken immediatelv. Minimum Operational Requirements Routine Calibration • Daily Challenges • Calibration of mass flow meter • The sample exhaust must be filtered, retumed to the sampling point, or vented to appropriated engineering controls. Preventive • PCT is replaced as needed, based upon challenge performance. Deleted: Table 5-1: Description and Requirements for Monitoring and Sampling Equipment^ Monitoring Equipment ... [1] "I Formatted; Bullets and Numbering 'I Formatted; Bullets and Numbering 'I Formatted; Bullets and Numbering ~( Formatted; Bullets and Numbering "I Formatted; Bullets and Numbering TABLE 5-1: Description and Requirements for Monitormg and Sampling Equipment 12 Deleted: ^End of Section"==«= Table 5-1: Description and Requirements for Monitoring and Sampling Equipment (Continued)f Monitoring Equipment | p21 \ I Formatted Table r Formatted: Left 13 TABLE 5-1: Description and Requirements for Monitoring and Sampling Equipment (continued) T. DAAMS Manufacturer Minimum Operational Monitoring Operational Components Specifications Requirements Preventive Depot Area Air DAAMS Tubes: Power Requirements: • The sample • Daily checking Monitoring • Size mav varv • Power is provided exhaust must be filtered. of flow rates, critical System depending on agent in accordance with retumed to the sampling orifices, fittings, and (DAAMS) operations. manufacturer point, or vented to fermles. specifications. appropriate engineering • Vacuum pump. Sequencers: • Critical DAAMS controls. sequencer, and sample • Director and control equipped with UPS. transfer line preventive flow pattern Vacuum Pumps: maintenance will be Temperature: • Used in perfonned in accordance DAAMS Manifold: • Temperamre is coniunction with a flow with manufacturer • Provides stable maintained to minimize control device or critical specifications. support svstem. condensate formation. orifice. • Require air. • Designed to provide • Should maintain nitrogen, or other inert a directional sample flow Manifold: critical ratio of inlet to gas flow through tube patter and distribute the • Fabricated from outlet vacuum across the and thermal desorption sample flow. stainless steel orifice. of tube for conditioning. NOx Filter: Hoses: • Change-out • Used to connect frequency is based on a site-sequencer sample ports specific basis. to the DAAMS manifold • Silastic tubing must not be used upstream of the DAAMS tube. • Units that demonstrate detectable leaks, poor flow rates, or broken sections are repaired or replaced. ••-^ 'l^i'J Deleted: t \\\ Deleted: End of Section Table 5-1: Description and Requirements for Monitoring and Sampling Equipment (Continued)f Monitoring Equipment |'3j 'I Formatted Table ^ iM Formatted Table , V \ \ s '[ Formatted; Bullets and Numbering \ \ \ ^ [ Formatted: Bullets and Numbering y \ [ Formatted; Bullets and Numbering \ \ j Formatted: Bullets and Numbering" \ I Formatted; Bullets and Numbering" I Formatted: Bullets and Numbering 'I Formatted; Bullets and Numbering [ Formatted; Bullets and Numbering ~[ Formatted; Bullets and Numbering I Formatted: Bullets and Numbering 14 Formatted: Left TABLE5-1: Description and Requirements for Monitoring and Sampling Equipment (continued) Monitoring GC Analytical Systems: • FPD • MSD XSD Operational Components Operational: • Sample inlet • Capillary column • Colunm switching system Support gases Integration system Thermal transfer system Exhaust Cryofocusing Roughing pump Manufacturer Specifications Power Requirements: • Power is provided in accordance with manufacturer specifications. • Confirmation monitoring is equipped with UPS^ • Power board is 120 volts altemating current. Room Temperature: • Between 68° and 80°F during operational periods. May be exceeded if instrument performance is acceptable. In accordance with manufacmrer specifications Minimum Operational Requirements • Exhaust is vented to appropriate engineering controls if required by safety analysis. • Temperature flow rate, and desorption time shall be optimized on a site-specific bases. In accordance with manufacmrer specifications Preventive • Performed on an ''as-needed basis" in accordance with the O&M Manuals. • Roughing pump oil is exchanged to maintain vacuum efficiency. Formatted: Bullets and Numbering Formatted: Bullets and Numbering Formatted; Bullets and Numbering Formatted: Bullets and Numbering Formatted: Bullets and Numbering Deleted: NOx Filters ^ Formatted: Bullets and Numbering " The unintermptible power supply (UPS) must have brown-out protection and constant voltage output and must operate the instruments for at least 15 minutes during a power failure. ^ Mass selective detector (MSD) only Deleted: Table 5-1: Description and Requirements for Monitoring and Sampling Equipment (Continued)^ Monitoring Equipment ['5"[ Formatted Table 15 TABLE 5-2: Support Gases Equipment Requirements Support Gases Purifiers Leak Detectors Compressed Gas Regulators Compressed Gas Line May Include: Moisture and May Include: • Will be tAvo-• Will be pre- • Air Hydrocarbon Traps j • Simple soap solution stage regulators or cleaned tubing. •• • Nitrogen • Frequency of • Electronic leak equivalent • All fittings will •• • Helium change-outs are identified detector be Swagelok fittings in the Site-Specific Oualitv or equivalent. Cryofocusing requires Control Plan Utilization: liquid nitrogen or • UseJ^ased on • Completed in carbon dioxide. instmmentation performance. accordance with manufacturer specifications Support gases are and requirements. handled and stored m accordance with the Site Chemical Hvaiene Plan, which mcoriDorates: • The CGA Pamphlet P-1; AR 700-68 • CGA Pamphlet S-1.1-1963 and 1965 addendum and S-1.2- 1963 • 29 CFR 1910.101 Formatted: Bullets and Numbering Deleted: (if recommended bv manufacturer or vendorl [Formatted: Bullets and Numbering ^ I Formatted; Bullets and Numbering ~^ -{ Deleted: B ) 'I Formatted; Bullets and Numbering ~^ Formatted; Bullets and Numbering *Gas generators will be operated in accordance with manufacmrer specifications. 16 6.0 MONITORING OPERATIONS/STRATEGIES Placement of each monitoring location is based on potential chemical migration points, and designated monitoring points shall be verified via the use of a smoke test. When monitoring supports personnel protection, monitoring locations should be located in close proximity to personnel and preferably at the breathing zone height. Heat-traced sample lines (HTSLs) will be no more than the length that allows agent recovery in one sampling cycle. All critical NRT monitoring equipment will be connected to an unintermptible power supply (UPS). During DCD EDT operations, monitoring will be conducted based on the agent being destroyed (i.e, HD). The NRT monitoring for HD^ will be conducted with MINICAMS™ units equipped with^alqgen selectiye detectors (XSDs}. A.dditiqnally, confiimation DAAMS tiibes will be co-located at each NRT monitoring location.^ Historical DAAMS samples will be collected in locations with the most likely potential for exposure for individuals with no respiratory protection. Table 6-1 specifies the monitoring application and type of monitor to support each application. The monitoring types discussed in the following paragraphs will be employed during DCD EDT operations. 6.1 NRT/Confirmation The NRT/confirmation locations shall consist of an instmment that satisfies the monitoring requirement identified for NRT monitors and incorporate a confirmation monitoring method. At a minimum, confirmation monitoring shall consist of a qualitative method as defined in the CMA MCP and LMQAP. The confirmation method shall be capable of confirming a single cycle NRT alarm response. When NRT monitoring is coupled with a confirmation method, and chemical materiel is confirmed, the NRT measured concentration shall be the value of record. Formatted: Left: 70.55 pt, Top: 76.3 pt, Bottom: 30.95 pt, Header distance from edge: 36.7 pt. Footer distance from edge: 35.3 pt Deleted; f Table 5-2: Support Gases Equipment Requirements f Support Gases ["s] Deleted: flame photometric detectors (FPDs) or 6.2 Historical/Confirmation Historical monitoring will be performed by DAAMS sampling and subsequent analysis by gas chromatograph/mass spectrometer (GC/MS)^ A separate confimation me when GC/MS is employed. When class III methods are used for NRT confirmation samples, any positi\"e response will be considered a confirmed detection. Deleted: or gas chromatogiaph flame photometric detector (GC/FPD) 17 HT will be monitored as HD. ^ When collecting DAAMS tubes for HD detection, a nitrogen oxide (NOx) filter will be installed at the distal end of each sampling location. Table 6-1. Monitoring Application and Monitor Type Analyte Monitor/Equipment Notes NRT Monitoring HD/HT MIMCAM^®con%uredwi1h_a_rc^ Confirmation of NRT Alarm and Historical Monitoring HD DAAMS; GC/MS_Qualitative confirmation ofthe MINICAMS®^larm and quantitative historical DAAMS Historical Monitoring HD DAAMS; GC/MS.Quantitative analysis Deleted: Deleted: MINICAMS™ Deleted: or FPD \ Deleted: Deleted: or GC/FPD ^ Deleted: or GC/FPD HT will be monitored as HD. Notes: DAAMS = Depot Area Air Monitoring Systen^ GC/MS = Gas Chromatograph/Mass Spectrometer HD = DistiUed Sulfiir Mustard (Bis(2-Chloroethyl) Sulfide) HT = ({Bis[2-(2-Chloroethylthio)ethyl]Ether}) NRT = Near- Real-Time PCT = Preconcentrator Tube XSD = Halogen Selective Detector Deleted: ^ FPD = Flame Photometric Detector Formatted: Tabs: 54 pt, Right + Not at -76.5 pt + 49.5 pt + 197 pt 7.0 MONITORING SYSTEMS The following paragraphs describe the monitoring systems that wiU be employed during DCD EDT operations. Monitoring locations during chemical agent operations are illustrated in Figure 7-1. A summary of the monitoring systems is provided in Table 7-1. Detailed discussions of the monitoring systems and locations are provided in the following paragraphs. 18 SCft 1"* l*M7| [6M*i [121*11 1 Cx-imj \ s s= o s s B o o h-1 en s 'C Q •«-> d o CXI TableJ-l: Summary of Monitoring Strategy for DAVINCHT^^^ EDT Qperations Deleted: Station # MINICAMS^ AMI AM2 AM3 AM4 No. 1 No. 2 No. 3 No. 4 DAAMS N/A NO. 1 NO. 2 N/A Instrument Location Monitoring Trailer Monitoring Trailer Monitoring Trailer Monitoring Trailer Area Monitored Delivery Van UPA Area Preparation Area Changing Room Power Source UPS UPS UPS UPS Monitoring Level VSL VSL VSL VSL Alarm Level 0.5 0.5 0.5 0.5 DAAMS Mode N/A MINICAMS TM Confirmation MINICAMS TM Confirmation N/A RCRA Station.s No No No No Smoke Test Requir'd No Yes Yes No Formatted Table Comment Not&„-H Deleted: l Deleted: Note 3 Note Deleted; 2 AM5 No. 5 N/A Monitoring Trailer Air Shower Room UPS VSL 0.5 N/A No No Note Deleted; 2 AM6 AM7 No. 6 No. 1 NO. 3 Monitoring Trailer Detonation Chamber Area (DOOR) UPS VSL 0.5 MINICAMS TM Confirmation No No Note 4 N/A Monitoring Trailer Jleadspace UPS VSL 0.2 0.5 1.0 N/A Yes No Note. 2 ,^ Deleted; Post Treatment ) AMl^ No. 1 N/A Monitoring Trailer Note 2,3 Airlock 2 UPS VSL 0.5 N/A No No Deleted; 7-S Deleted: Note 10 20 Station # MINICAMST>« AMll No. 1 AM13 No. 1 AM8 No.7 AM9 No. 8 DAAMS N/A N/A No. 4 NO. 5 Instrument Location Monitoring Trailer Monitoring Trailer Monitoring Trailer Monitoring Trailer Area Monitored UnitG Davinch Lid Shroud Airlock 1 j^qntainment Room Power Source UPS UPS UPS UPS Monitoring Level VSL VSL VSL VSL/WPL Alarm Level 0.5 0.5 0.5 0.5 DAAMS Mode confirmation ronfirmation MINICAMS TM Confirmation MINICAMS TM Confirmation RCRA Stations No No No No Smoke Test Requir'd No No Yes Yes Formatted Table Comment Note 1.2 Note 2 Deleted; Mobile Analytical Platform Deleted; Note 8 ] AM12 N/A NO. 20 N/A Mobile Laboratory N/A WPL 0.5 Historical No No PMI No. 9/No. 17 NO. 6 Monitoring Trailer Upstream of Retention Tank UPS VSL 0.5 MINICAMS TM Confirmation Yes No Note 5,13 PM2 No. 10 NO. 7 Monitoring Trailer Chamber Discharge during venting UPS VSL 0.5 MINICAMS TM Confirmation No No Note 6 PM3 No. 11 NO. 8 Monitoring Trailer Process Discharge UPS VSL 0.5 MINICAMS TM Confirmation Yes No PM4 No. 12 NO. 9 Monitoring Trailer Mid bed of HVAC Filter El UPS VSL 0.5 MINICAMS TM Confirmation Yes No Note 9 21 Smoke Station Instrument Power Monitoring Alarm RCRA Test # MINICAMST^i DAAMS Location Area Monitored Source Level Level DAAMS Mode Stations Requir'd Comment Mid bed of MINICAMS Monitoring HVAC Filter TM PM5 No. 12 NO. 10 Trailer El UPS VSL 0.5 Confirmation Yes No Note 9 Mid bed of MINICAMS Monitoring HVAC Filter TM PM6 No. 12 NO. 11 Trailer El UPS VSL 0.5 Confirmation Yes No Note 9 Mid bed of MINICAMS Monitoring HVAC Filter TM PM7 No. 13 NO. 12 Trailer E2 UPS VSL 0.5 Confirmation Yes No Note 9 Mid bed of MINICAMS Monitoring HVAC Filter TM PM8 No. 13 NO. 13 Trailer E2 UPS VSL 0.5 Confirmation Yes No Note9 Mid bed of MINICAMS Monitoring HVAC Filter TM PM9 No. 13 NO. 14 Trailer E2 UPS VSL 0.5 Confirmation Yes No Note 9 Mid bed of MINICAMS Monitoring HVAC Filter TM PMIO No. 14 NO. 15 Trailer E3 UPS VSL 0.5 Confirmation Yes No Note 9 Mid bed of MINICAMS Monitoring HVAC Filter TM PMI I No. 14 NO. 16 Trailer E3 UPS VSL 0.5 Confirmation Yes No Note 9 Mid bed of MINICAMS Monitoring HVAC Filter TM PM12 No. 14 NO. 17 Trailer E3 UPS VSL 0.5 Confirmation Yes No Note 9 MINICAMS Monitoring HVAC TM PM13 No. 15 NO. 18 Trailer Discharge UPS VSL 0.5 Confirmation Yes No Note 7 Formatted Table 22 Station # PMi4 PMI 5 PM16 PM17 MINICAMST>« No. 16 N/A N/A N/A DAAMS NO. 19 NO. 21 NO. 22 NO. 23 Instrument Location Monitoring Trailer N/A N/A N/A Area Monitored Stack PrefilterEl Prefilter E2 Prefilter E3 Power Source UPS N/A N/A N/A Monitoring Level VSL/WPL VSL VSL VSL Alarm Level 0.5 N/A N/A N/A DAAMS Mode MINICAMS TM Confirmation process process process RCRA Stations Yes No No No Smoke Test Requir'd No No No No Formatted Table Comment Note 8 ,£ntigal| Formatted; Font: 10 pt DAAMS Note 11 Note 11 Note 11 jNlotes: _ _ L With DAAMS capability,^ 2. iSpooled loj:ation_ _ 3. Headspace monitoring (4 hours @70°Fy Clearance levels are 0.2 VSL for exterior of diimis. 0.5 VSL for chamber solid waste inside dnmis. and 1.0 VSL for other (PPE) dmimned waste. 4. No smoke test required; will position according to proximity to chamber opening/door. For daily entry clearance/maintenance this station may be used with DAAMS for WPL monitoiing. 5. Controls the release of detonation gas to synq^witliMC cyclg. Iii the event of aim g^tiyates^ 6. Peisoimel entiy chamber cleaiance spooled based on chamber status. 7. Upstream of process discharge. 8. WPL DAAMS station must be collected and analyzed on a daily basis for this station. 9. One MINICAMS™ spools between bed locations on each filter unit. Separate DAAMS on each location. Also has ability to spool to post-filter location if necessaiT to deteiiniiie if breaktluough has occmTed in final stage of filter. 10. j'ersonnel poiiit sourc^ I._ These process sa^npl^g jL^Jo j^teiimiie if ag^nt is^bdng loa^^ onto caibon filters^ .Qfigg. ^gg^tjg. j^?Pl^j^il9_ft^dll^" jopBi^Q-^fflj_ requiied. 12. Stations not supporting operations mav be taken offline and carbon traps placed on the inlet. ^71 Formatted: Font: 10 pt Deleted: Deleted: Also Spools to AM7 and AM 7-S Deleted: Personnel point source. Deleted; h ' Deleted; Spools from Post Treatment to Airlock 2. Deleted; t 13. If the process stream contains too much moiNtme. a DAFC mav be used. The detection limit for this location will be increased based on dilution ratios. 14. NRT confiimation based on comparison of results obtained from differently configured NRTs aboard Real Time Analytical Platform (RTAP) provided by DCD. RTAP monitor sample the same sample since sample is contained in box tnick's storage compaitmeiit. 23 Formatted: Left: 70.55 pt, Top: 76.3 pt, Bottom: 30.95 pt, Section start: New page 7.1 NRT Monitoring The NRT monitoring is online monitoring, conducted in areas where contamination is likely or possible, to determine an airbome chemical concentration in the shortest amount of time at the monitoring level commensurate with engineering controls and worker protection. This monitoring will take place at the locations discussed in the following paragraphs. Table 6-1 details the MINICAMS™ configurations for monitoring chemical agents. All NRT stations will be configured with un-interruptible power supplies. 7.1.1 Worlcspace Process Area (Delivery Van) The NRT monitoring ofthe Delivery Van will be performed using an HTSL interfaced with a MINICAMS™ located in the Monitoring Container/Station. The monitoring at this location will be performed at the VSL. 7.1.2 Workspace Process Area (Unpack Area (UPA)) The NRT monitoring ofthe Unpack Area will be performed using an HTSL interfaced with a MINICAMS™ located in the Monitoring Container/Station. The monitoring at this location will be performed at the VSL 7.1.3 Workspace Process Area (Preparation Area) The NRT monitoring of the Preparation Area will be performed using an HTSL interfaced with a MINICAMS™ located in the Monitoring Container/Station. The monitoring at this location will be performed at the VSL 7.1.4 Workspace Process Area (Aii'lock 1) The NRT monitoring of Airlock 1 will be performed using an HTSL interfaced with a MINICAMS™ located in the Monitoring Container/Station. The monitoring at this location will be performed at the VSL. 7.1.5 Facility Support Area (Changing Room) The NRT monitoring ofthe Changing Room will be performed using an HTSL interfaced with a MINICAMS™ located in the Monitoring Container/Station. The monitoring at this location will be performed at the VSL. 7.1.6 Facility Support Area (Air Shower Room) The NRT monitoring ofthe Air Shower Room will be performed using an HTSL interfaced with a MINICAMS™ located in the Monitoring Container/Station. The monitoring at this location will be performed at the VSL. 25 7.1.7 Process Area (Detonation Chamber Door) Deleted: Coutainment Area The NRT monitoring ofthe Detonation Chamber/Containment Area will be performed using an HTSL interfaced with a MINICAMS™ located in the Monitoring Container/Station. The HTSL will be coiled and hung over the Detonation Chamber Containment Vessel such that it is less than 2 feet above and slightly in front of the Detonation Chamber door. The monitoring at this location will be performed at the VSL. A DAAMS may be used at this location optionally to provide clearance for maintenance or entry using a WPL clearance level. 7.1.8 Workspace Process Area (Post Treatment Area) The NRT Headspace Monitoring ofthe firagments in the Post Treatment Area will be performed using an HTSL interfaced with a MINICAMS™ located in the Monitoring Container/Station. The Headspace Monitoring at this location will be performed at the VSL. 7.1.9 Workspace Process Area (Airlock 2) The NRT monitoring of Airlock 2 will be performed using an HTSL interfaced with a MINICAMS'^'^ (spooled) located in the Monitoring Container/Station. The monitoring at this location will be performed at the VSL. 7.1.10 Laboratory Work Area/Mobile Analytical Platform ^Laboratory areas ^vhere the RDT&E diliite levels are not exceeded do not require NRT monitoring. 7.1.11 Ventilation Exhaust Filter System The ventilation exhaust filter system includes the facility's ventilation system exhaust where CWM is processed for demilitarization. It does not include the laboratory ventilation system or other buildings in the facility where CWM is not processed. 7.1.11.1 Upstream of Retention Tank The NRT monitoring will be performed upstream from the Retention Tank. Monitoring will be performed using an HTSL interfaced with a MINICAMS™. The monitoring will be performed at this location at the VSL. 7.1.11.2 Chamber Discharge during Venting The NRT monitoring ofthe Chamber Discharge during venting will be performed using an HTSL interfaced with a MINICAMS™. The monitoring will be performed at this location at the VSL during operations. This location will also be used to perform fust entry monitoring into the 26 Deleted: Laboratory work areas are where chemical agent standards are prepared or used and/or where samples are analyzed that may contain chemical agent. Chemical agent contamination is not expected, but because ofthe nature of the operations being performed in these areas, tliere is a potential for contamination.^ 7.1.10.1 Operations with Chemical Agent Above RDT&E Dilute Level. ^ The process areas include laboratory areas where operations with chemical agent above RDT&E dilute level are conducted or where samples expected to contain chemical agent above RDT&E dilute level are analyzed. Tliese laboratory work areas require NRT monitoring at the STEL and liistorical monitoring at the WPL during chemical agent operations. The monitoring level will be selected in accordance with PPE level and administrative controls, but as a standard requir ement, the STEL and the WPL (consistent with the site-defmed work shift) for unmasked woiicers shall be utilized. Confinnation monitoring is required for botli the NRT and liistorical monitoring.il 7.1.10.2 Dilute RDT&E Operations.^ Davinch chamber. 7.1.11.3 Process Disc ha rge The NRT monitoring of the Process Discharge will be performed using an HTSL interfaced with a MINICAMS™. The monitoring will be performed at this location at the VSL. 7.1.11.4 Midbed ofHVA C Filter The NRT monitoring will be performed at the midbed location ofthe air filtration unit using an HTSL interfaced with a MINICAMS™. The monitoring will be performed at this location at the VSL. 7.1.11.5 HVAC Discharge The NRT monitoring will be performed at the HVAC Discharge ofthe air filtration unit using an HTSL interfaced with a MINICAMS™. The monitoring will be performed at this location at the VSL. 7.1.11.6 Stack The NRT monitoring will be performed at the Stack location ofthe air filtration unit using an HTSL interfaced with a MINICAMS™. The monitoring will be performed at this location at the ^ -(Deleted; andwPL VSI^ ~ 7.1.12 First Entiy First entry monitoring will be conducted, prior to persormel entry, to determine the potential contamination of an enclosed area that was previously contaminated or has not been under continuous monitoring. First entries require NRT monitoring at the VSL for one complete sampling cycle ofthe NRT. Prior to monitoring for one complete sampling cycle, the sample line should be purged to ensure that a clean representative sample is taken. The monitoring level will be selected in accordance with the PPE level of personnel making the entry. Confirmation monitoring is not immediately required but can be performed after the NRT response indicates possible chemical agent contamination. 7.1.13 Headspace Headspace monitoring may be used to screen samples to determine such information as operational constraints, PPE requirements, and handling precautions. Headspace monitoring shall be performed jn accordance with table 7-1 on solid samples that _ ^ - - \ Deleted; at o.s of the VSL have been bagged or contained in an agent-tight barrier of sufficient volume to permit sample air to be withdrawn while minimizing dilution with incoming air. Headspace monitoring requires one complete sampling cycle ofthe NRT. Prior to monitoring for one complete sampling cycle, the sample line should be purged to ensure that a clean representative sample is taken. Historical monitoring can be performed instead of NRT monitoring. Liquid samples may not be headspace analvzed to support the disposition ofthe liquid. Liquid waste samples must be 27 cleared by extraction and meet project waste control limits. ^_ JHeadspace monitoring for the piirpose of decontamina^^^ shall include the followin^;^^ - the item has been surface decontaminated by locally approved procedures - the item has been bagged or contained in an agent-tight barrier of sufficient volume to -"^^ permit sample air to be withdrawn while minimizing dilution with in-coming air - the Item shall be allowed to off-gas for a minimum of 4 hours at temperatures at or above 70 degrees Farenheit 7.1.14^aste Prums / J^RT monitoring 9^ waste dmmj, bej)erform^^ a _ MINICAMS™ (spooled) located in the Monitoring Container/Station. ^TTie monitoring at this location will be performed at the VSL. Waste drums will be cleared to 0.2 VSL at the exterior of "^v the drum by headspace monitoring, before removal from the EE. 7.1.15 Decontamination Area/Air Shower In the event of a potentially exposed worker, MINICAMS™ will be available to conduct NRT monitoring in the Air Shower Room. The monitoring at this location will be at the VSL. 7.1.16 UnitG NRT monitoring will be performed at Unit G using an HTSL interfaced with a MINICAMS^^' (spooled) located in the Monitoring Container/Station. The monitoring at this location will be performed at the \"SL.. Deleted: One complete sampling cycle of the NRT monitor is required. Historical monitoring can be perfonned instead of NRT monitoring. " Deleted; Note that these results may not be used to support disposition of material that requires decontamination. Deleted: the requirements Deleted: described in paragraph 4.4 of the CMA MCPO. Formatted: Indent: Left: 36 pt Deleted: Above Deleted: Tlie Deleted: the Deleted: Deleted: Tlie HTSL will be coiled and hung over the waste dnuns such that it is less than 2 feet above the dnmis. 7.2 Confirmation and Historical Monitoring Confirmation monitoring is performed to validate or invalidate a positive measurement from another monitoring system, either an NRT method or historical method. Sampling is accomplished by the collection of an air sample in the immediate vicinity of the NRT monitor or historical sampling location, and subsequent analysis is conducted offline at the site laboratory. Confirmation monitoring is used for informational and qualitative data reporting purposes in the event of a chemical material release. The confirmation sample, if required, shall be analyzed by a method different from the principal method (NRT or historical) to increase the likelihood of detecting interferences and only upon a principal method (NRT or historical) positive response. Confirmation monitoring samples shall be given priority over all routine samples. For class III confirmation samples, a positn e response shall be considered a confirmed detection. Confirmation DAAMS tubes are continually aspirated throughout the work day. In the event of 28 an NRT alarm, the DAAMS tubes co-located with the alarming MINICAMS'^'^ are collected and analyzed. Note that when using a DAAMS GC/MS historical method, a separate confirmation method is not required. 7.2.1 Workspace Process Area (Delivery Van) The DAAMS tubes samples will be used for qualitative confirmation analysis of chemical agents. The sample inlet will be co-located with the MINICAMS™ HTSL distal end. When the co- located MINICAMS™ alarms, the DAAMS tube will be retrieved to confirm or refute the alarm. 7.2.2 Workspace Process Area [Unpack Area (UPA)] The DAAMS tubes will be used for qualitative confirmation analysis of chemical agents. The sample inlet will be co-located with the MINICAMS™ HTSL distal end. When the co-located MINICAMS™ alarms, the DAAMS tube will be retrieved to confirm or refute the alarm. 7.2.3 Workspace Process Area (Preparation Area) The DAAMS tubes will be used for qualitative confirmation analysis of chemical agents. The sample inlet will be co-located with the MINICAMS™ HTSL distal end. When the co-located MINICAMS™ alarms, the DAAMS tube will be retrieved to confirm or refute the alarm. 7.2.4 Workspace Process Area (Au'lock 1) The DAAMS tubes will be used for qualitative confirmation analysis of chemical agents. The sample inlet will be co-located with the MINICAMS™ HTSL distal end. When the co-located MINICAMS™ alarms, the DAAMS tube will be retrieved to confirm or refute the alarm. 7.2.5 Process Area (Detonation Chamber/Containment Area) The DAAMS tubes will be used for qualitative confirmation analysis of chemical agents. The sample inlet will be co-located with the MINICAMS™ HTSL distal end. When the co-located MINICAMS™ alarms, the DAAMS tube will be retrieved to confirm or refute the alarm. 7.2.6 Laboratory Work Area/Mobile Analytical Platform J^aj3oratory areas where the RDT&E dilute levels are not exceeded do not require moni^^ However, the ECBC laboratorv will be monitored using historical DAAMS. J.2.7 Ventilation Exhaust Filter The ventilation exhaust filter system includes the facility's ventilation system exhaust where CWM is processed for demilitarization. It does not include the laboratory ventilation system or other buildings in the facility where CWM is not processed. 29 Deleted: Laboratoiy work areas are areas where chemical agent standards are prepared or used and/or areas where samples are analyzed that may contain chemical agent. Chemical agent contamination is not expected, but because of tlie nature ofthe operations being performed in these areas, there is a potential for contamination.^ 7.2.6.1 Operations with Chemical Agent Above RDT&E Dilute Level. ^ The process areas include laboratory areas where operations with chemical agent above RDT&E dilute level are conducted or where samples expected to contain chemical agent above RDT&E dilute level are analyzed. Tliese laboratoiy work areas require NRT monitoring at the STEL and liistorical monitoring at the WPL during chemical agent operations. The monitoring level will be selected in accordance with PPE level and administrative controls, but as a standard requiiement, the STEL and the WPL (consistent with the site-defined work shift) for umnasked workers shall be utilized. Confirmation monitoring is required for both the NRT and liistorical monitoring.1 7.2.6.2 Dilute RDT&E Operations.^ Deleted: 11 7.2.7.1 Upstream of Retention Tank The DAAMS tubes will be used for qualitative confirmation analysis of chemical agents. The sample inlet will be co-located with the MINICAMS™ HTSL distal end. When the co-located MINICAMS™ alarms, the DAAMS tube will be retrieved to confirm or refute the alarm. 7.2.7.2 Chamber Discharge During Venting During chamber venting, the door to the Detonation Chamber is open and EE air is drawing throug the chamber. The DAAMS tubes will be used for qualitative confirmation analysis of chemical agents. The sample inlet will be co-located with the MINICAMS™ HTSL distal end. When the co-located MINICAMS™ alarms, the DAAMS mbe will be retrieved to confirm or refute the alarm. 7.2.7.3 Process Discharge The DAAMS tubes will be used for qualitative confirmation analysis of chemical agents. The sample inlet will be co-located with the MINICAMS™ HTSL distal end. When the co-located MINICAMS™ alarms, the DAAMS tube will be retrieved to confirm or refute the alarm. 7.2.7.4 Midbed of HVAC Filter The DAAMS tubes will be used for qualitative confirmation analysis of chemical agents. The sample inlet will be co-located with the MINICAMS™ HTSL distal end. When the co-located MINICAMS™ alarms, the DAAMS tube will be retrieved to confirm or refute the alarm. 7.2.7.5 HVAC Discharge The DAAMS tubes will be used for qualitative confirmation analysis of chemical agents. The sample inlet will be co-located with the MINICAMS™ HTSL distal end. When the co-located MINICAMS™ alarms, the DAAMS tube will be retrieved to confirm or refute the alarm. 7.2.7.6 Stack ^The stack shall be monitored for NRT alaim confirmation and for historical dtU DAAMS \ Deleted; uie tubes will be used for qualitative confirmation of NRT alarms and jbr historical monitoring to | Deleted: daily the WPIy The DAAMS NRT confinnation sample inlet will be co-located with the _ , , -{Deleted; analysis of chemical agents MINICAMS™ HTSL distafend.' When the co-located MINICAMS™ alarms, the confirmation " DAAMS tube will be retrieved to confirm or refute the alarm. 7.3 First Entry First entry monitoring will be conducted, prior to personnel entry, to determine the potential contamination of an enclosed area that was previously contaminated or has not been under continuous monitoring. First entries require NRT monitoring at the VSL for one complete sampling cycle ofthe NRT. Prior to monitoring for one complete sampling cycle, the sample line should be purged to ensure a clean representative sample is taken. The monitoring level will be selected in accordance with PPE level of personnel making the entry. Confirmation 30 monitoring is not immediately required but can be performed after the NRT response indicates possible chemical agent contamination. 7.4 Headspace Headspace monitoring may be used to perform things like screen samples to determine operational constraints, PPE requirements, and handling precautions. Headspace monitoring shall be performed m accordance with table 7-1 on solid samples that have been bagged or contained in an agent-tight barrier of sufficient volume to permit sample air to be withdrawn while minimizing dilution with incoming air. Headspace monitoring is required for one complete sampling cvcle ofthe NRT. Prior to monitoring for one complete sampling cycle, the sample line should be ]?urged to ensure that a clean representatn'e sample is taken. Historical monitoring can be perfonned instead of NRT monitoring. Liquid samples may not be headspace analyzed to support the disposition ofthe liquid. Liquid waste samples must be cleared by extraction and meet applicable waste control limits. Headspace monitoring for the purpose of decontamination verification shall include the following: - the item has been surface decontaminated by locally approved procedures - the item has been bagged or contained in an agent-tight barrier of sufficient volume to permit sample air to be withdrawn while minimizing dilution with in-coming air - the Item shall be allowed to off-gas for a mmiimim of 4 hours at temperatures at or above 70 degrees Farenheit ^.5 ^Personnel Decqntaminafion Station (^ In the event of a potentially exposed worker, MINICAMS™ will be available to conduct NRT monitoring in the Air Shower/Changing Rooms. The monitoring at this location will be at the VSL. 7.6 Historical Monitoring Historical monitoring is performed to measure very low concentrations of airborne analytes at the WPL, where contamination is unlikely or workers are operating without PPE. Sampling is accomplished by the collection of an air sample over an extended period of time (usually the duration of a workday), and subsequent analysis is conducted offline at the site laboratory. Historical monitoring is designed to trigger activities to investigate the source of contamination that may be found below the alarm level ofthe NRT system. All historical DAAMS samples must be analyzed within 72 hours of sampling termination. During agent operations (whenever unmasked workers are in the EE), historical DAAMS stations will be employed. 7.7 Vapor Screening of Sample Containers As a minimum, headspace monitoring shall be implemented on all solid process sample 3f Formatted: Indent: Left: 36 pt Deleted: Headspace monitoiing shall be perfonned at the VSL on samples tliat have been bagged or contained in an agent-tight barrier of sufficient voliune to pennit sample air to be withdrawn while niininiizing dilution with incoming air. One complete sampling cycle of tlie NRT monitor is required. Historical monitoring can be perfonned instead of NRT monitoring.^ Note: Tliese results may not be used to support disposition of material that requires decontamination. Headspace monitoring for the purpose of decontamination verification shall follow the requirements described in paragraph 4.4. ofCMA'sMCP.t Formatted: Right: 1.55 pt contamers, and any liquid process sample containers j?rior to jransfer to the laboratory (i.e., _ Mobile Analytical Platform). The purpose of this screening is to provide evidence that contamination is not present on the sample container prior to the container leaving the environmental enclosure. , Vapor screening will be performed on items that have been bagged or contained in an agent-tight banier of sufficient volume to permit sample air to be withdrawn while minimizing dilution with incoming air. Vapor screening can be performed with either MINICAMS™ or DAAMS tubes. If results provide a concentration greater than 0.5 VSL, conective actions shall be implemented (e.g., confirmation, repeat decontamination process, and re-monitor). ^•9 SAMPLE AND ANALYTICA^^ METHODS The ECBC Sample and Analytical Methods will be used to characterize the waste prior to shipment of waste off-site. Deleted: Deleted: shipment Deleted: Vapor screening will be conducted in accordance with ECBC lOPs and Department ofthe Army Pamphlet (DA Pam) 385-61.1[ Formatted: Expanded by 0.15 pt Deleted: ^ 9.0 ALARM RESPONSE/REPORTING POSITIVE CHEMICAL MATERIEL RESPONSES All worker and environmental protection MINICAMS'^'^ alarms will require confirmation analysis. The MINICAMS™ alarm confirmation will be performed by collection and analysis of a DAAMS tube sample. 9.1 Monitoring Levels Monitoring at the VSL will be performed in areas where worker protection monitoring is required. If the NRT sampling and analysis cycle time is less than 15 minutes (the STEL), excursion is manually calculated using the concentration reported by the NRT monitor. The VSL is intended for applications and/or locations that require monitoring for an environmental release, engineering controls (e.g., filters), process upset condition, or vapor decontamination classification monitoring. The VSL is a concentration-only value and does not consider the analysis method's sampling duration other than to determine the volume of air sampled to calculate the anal5^e concentration. 9.2 MINICAMSTM Alarm Setpoints During EDT operations at DCD, the following alarm levels will be used: • 0.5 Z will be used in all areas where worker protection is being performed (all locations inside the EE and the PDS). 9.3 • 0.5 Z will be used in all process monitoring areas (within the air filtration units). NRT Notifications 32 In the event of an alarm, the MINICAMS™ operator will notify the Versar EDT Site Manager and ECBC Site Supervisor. In addition, the EG&G Site Safety and Health Officer (SSHO) may be notified, depending on the situation. Table 9-1 lists several possible scenarios, persons to be ^ -{Deleted; notified, ^Qotified and possible actions to be taken. ^ -' 9.4 Confirmation and Historical Notifications The support laboratory will notify the Versar EDT Site Manager ofthe results of all DAAMS tube analyses. If the samples were confirmation samples, the Versar EDT Site Manager will notify the EG&G Safety Office ofthe results. If the samples were analyzed only for historical purposes, the Versar EDT Site Manager will notify the EG&G Safety Office only if agent was detected. The EG&G Project Manager will be notified of all detections and confirmed detections of chemical agent. Table 9-2 is the DAAMS tube analysis matrix. 33 Table 9-1: NRT Notification Matrix Situation Notification Possible Action* Single NRT Alarm • Versar EDT Site Manager and ECBC Site • Await result of next MINICAMS™ cvcle Single NRT Alarm Supervisor • ECBC SSHO • EG&G Safetv Office • TOCDF Environmental Shift Rep • Evaluate non-essential personnel • Evaluate PPE • Analvze DAAMS tubes * - Two Consecutive NRT Alarms • Versar EDT Site Manager and ECBC Site • Await result of next -^-^ MINICAMS™ cvcle Supervisor • EG&G Safetv Office • ECBC SSHO • TOCDF Environmetnal Shift Rep • Evaluate PPE • Determine source of contamination • Analvze DAAMS tubes Three Consecutive NRT Alarms • Versar EDT Site Manager and ECBC Site Supervisor • EG&G Safetv Office • ECBC SSHO • Determine source of contamination • Analvze DAAMS tubes • Relocate filtration svstem MINICAMS™ sample point fi:om Three Consecutive NRT Alarms • TOCDF Environmental Shift Rep midbed location to post-bed * - location " \ Formatted: Bullets and Numbering I Formatted: Bullets and Numbering Formatted: Bullets and Numbering Formatted: Bullets and Numbering Formatted: Bullets and Numbering Formatted: Bullets and Numbering Formatted: Bullets and Numbering Formatted: Bullets and Numbering Formatted: Bullets and Numbering *This table is based on detection of chemical warfare materiel (CWM) at the alarm set point- Decision on actual actions taken will reside with the Versar ETD Site Manager. Actions may varv, depending on the actual concentration of CWM detected. Notes: DAAMS - Depot Area Air Monitoring System DCD - Deseret Chemical Depot EDT - Explosive Destruction Technology PPE - Personal Protective Equipment Deleted: \ Table 9-1. NRT Notification Matilxf situation |^3'j Formatted Table Formatted Table 34 Table 9-2: DAAMS Tube Analysis Matrix Response to Location/Scenario DAAMS Tube Analysis Sites NRT Alarm EE Co-located confirmation DAAMS Tubes NRT Alarm Midbed carbon filter position in EE air handlina unit Co-located confirmation DAAMS Tubes Continaency Visually observe item leaking inside EE All historical DAAMS stations in EE and EE exhaust filtration system Contingency Failure of engineerina controls in EE All historical DAAMS stations in EE and EE exhaust filtration system Oualitv Assurance Requirement Each day of destruction operations at least one - OP DAAMS tubejor each method Notes: DAAMS - Depot Area Monitoring System EDT - Explosive Destruction Technology EED - Environmental Enclosure "I' If "• H lit / Deleted: from above the door of the EDT vesel Deleted: Table 9-2. DAAMS Tube Analysis Matrix^ Response To Location/Scenario DAAMS Tube Analysis Sites^f Deleted: MINICAMS™® Deleted: NRT EE Co-located confirmation DAAMS tubes^l Alarm^l Deleted: MINICAMS^ Deleted: NRT^j Alarm Midbed carbon filter Co- located confirmation DAAMS tubes^f position in EE air^ handling unit^ Contingency Visually observe item All historical DAAMS stations in EE and EE exhaust^l leaking inside EE filtration system^l Deleted: (outside of EDTt vessel)! Deleted: Contingency Failure of engineering All historical DAAMS stations in EE and EE exhaust^! controls in EE filfration system^l Quality Assurance Each day of destruction operations at least one -f Requirement • DAAMS tube from above the door of the EDT^I vessel!! Notes:f DAAMS = Depot Area Air Monitoring System^! EDT = Explosive Destruction TechnologyTI EE = Environmental Enclosure!! Formatted: Expanded by 0.1 pt 35 9.5 WPL Excursions In the event of a WPL excursion, the Chemical Agent Worker Population Limit (WPL) Excursion Plan for the DCD EDT System at Tooele, developed by ECBC, will be implemented. 10.0 MONITORING OF POTENTIALLY EXPOSED WORKERS Monitoring of potentially exposed workers will be conducted in accordance with the DA Memorandum: Performance Standard for Monitoring Potentially Exposed Workers, 13^eptember 2007^ 11.0 QUALITY CONTROL REQUIREMENTS All monitoring operations will be conducted in accordance with the ECBC LMQCP, the CMA LMQAP, and apphcable lOPs. The ECBC will incorporate the data generated into the monitoring 40-year data storage program, should access to additional information be required. The QC requirements for applicable ECBC lOPs ^lOP MT-6^ and lOP MT-13) are proyided in Tables 11-1 and 11-2, respectively. 11.1 Certification Requirements The laboratory shall perform a certification and validation process for operators, instruments, and methods to confirm that analytical processes are suitable for use. Method certification will require completion of a successfiil precision and accuracy (P&A) study and initial baseline study. JVIethod certfication will be required before the method can be used in support o£operations. Method validation will be demonstrated through the continuing^ baseline study. 11.1.1 Precision and Accuracy (P&A) Method Certification All NRT and historical agent methods will be certified as Class I methods via P&A studies in accordance with the LMQAP. Confirmation methods will be certified as Class IE methods.. Class in method results that yield a positive response will be considered confirmed detections . The P&A studies will be performed on-site j)rior to thepre-operatiqnal survey for data evaluation by the CMA Monitoring Office. Deleted: Deleted: lOP MT-16, Deleted: 02 Deleted: However, if mobile criteria are used, challenges may occur periodically in accordance witli CMA LMQAP Table 12-1. Deleted: Deleted: via P&A studies Deleted: at DCD 11.1.2 Baseline Method Certification and Validation All methods shall successfully satisfy the regular initial j^aseline study method certification requirements as shown in Table 13-3^qf the CMA LMQAP before tl^^ support operations. , Deleted: alternate Deleted: 4 Deleted: However, if mobile criteria are used, challenges may occur periodically in accordance witli CMA LMQAP Table 13-3. 36 Deleted: 02 Table 11-1: OC Requirements for lOP MT-6e Deleted:, HT Deleted: Initial 37 QC Sample Frequency Acceptance Limits Corrective Action Sampling Flow Rate Measurements During Calibration HD; 400± lOOmL/min Adjust and recheck before Sampling Flow Rate Measurements During Calibration starting calibration and analysis ^CalibrationjChallenge (1.0 Z^^ ^ollowma calibration miections 0.7.\to 1.25,4 Investigate and perform corrective action. Repeat calibration^ if required. JDailv challenge After the end of daily p. 75 to 1.254 Investigate and correct cause. operations or if no operations occur, at least 12 hours after c a 11 b r a 110 n c h a 11 e n 2 e Recalibrate if necessary. Note on data forms and qualify data. Deleted: (ICAL) l High Level Deleted: VSL Deleted: Started of each operational day or after failing midday challenge Deleted: 60 Deleted: 40 Deleted: VSL Deleted: correct i Deleted: ICAL ^ Operafion and Maintenance Procedures for Fixed Site MNICAMS™ r Note: \ \>t HD - distilled sulfur mustard \ >f ,piL/min - milliliter per minute ^ ' OC - quality control \ T ^ X T Table 11-2: OC Requirements for lOP MT-IS" Deleted: Continuing Cahbration Verification (CCV ) - Also Called Challenge 1 Low-level Challenge (0.25 VSL)*" Deleted: Afler every 4 to 5 hours of operation and at the end of operational date Deleted: VSL Deleted: Repeat ICAL if failure is for midday challenge. No action if fai _ ^ ["g"! Deleted:''Distal end line clialh p^Qi Deleted: HT - {bis[2-(2-...[11] Deleted: VSL - Vapor Screening Limits Deleted: J Formatted: Left Formatted: Left Formatted: Left Formatted: Left Deleted; ° Operation and Main [131 ^ Formatted: Left QC Sample Sampling Flow Rate Measurments Five Point Initial Calibration (ICAL) Initial Calibration Verification (ICV} Continuing Calibration Verification (CCV) Method Blank Quality Process (QP) - Similar to Matrix Spike Frequency Before and after sample collection When instrument parameters change. After Preparation of new standards At the start of each day of analysis. After ICAL At the end of a sample run or every 12 hours, whichever is shorter At least one before analyzing samples 1 each per batch of 20 or fewer samples. Acceptance Limits Starting and ending flow rates within 10% ofthe average flow rate. R2>0.99 Each target analyte ±15% of true value Each target analyte ±15% of true value. Absence of target analytes and interferences Recovery >10% (Note: Agent- specific limits are currently under development) Corrective Action Repeat sampling unless samples are one of a kind. If one of a kind, flag data. Investigate and correct the cause. Repeat ICAL. Recalibrate. If results >115% of true value, recalibrate. Sample results may be reported. If results <85% of true value, recalibrate. Analyze second sample tube for each sample analyzed since. Investigate and correct. Repeat method blank to verify acceptable performance. Verify spiking solutions. Analyze second QP tube. If results are confirmed spike and analyze second sample tube from location where QP was taken. ^Analysis of Chemical Warfare Agents and Degradation Products on DAAMS Tubes using a Gas Chromatography System Coupled with a Mass Selective Detector •^gi^jl _ _ Q^ajitY Control 38 Deleted: f Formatted: Left Deleted: Table 11-2: QC Requirements for TOP MT-13"' Deleted: <sp>Table 11-2. QC Requirements for lOP MT-13"f QC Sample Frequency Acceptance Limits Corrective Actionf Sampling Flow Rate Measurements Before and after sample Starting and ending flow Repeat sampling unless samples are one ofK collection rates within 10% of the a kind. If one of a kind, flag data.^^ average flow ratef <sp>l Five Point Initial Calibration (ICAL) Wlien instmmentK parameters changef After preparation of new standards!! When ICV or CCV fails [-141 During the initial baseline studies, all sampling and analysis operations shall be performed exactly as set forth in the applicable analytical procedures under similar operating conditions for instruments shown to be in control. The^initial baseline study^shall be cpniposed of _ challenges performed at the end of each operational day for not less than 20 days. The continuing baseline study will be conducted to validate long-term performance ofthe monitoring systems. The continuing baseline study begins immediately after successful completion ofthe initial baseline and will be conducted in accordance with table 13-3 of the CMA LMOAP. ^or monitoring cessation of less than 60 days, NR^pietliod re-certification^h^an b^ accordance with CMA LMQAP, table li-5V//////////////_ _ _____ 11.2 Calibration and Test Methods The laboratory shall have an established calibration program. Air monitoring methods shall undergo calibration in accordance with ECBC lOPs. This plan shall define the calibration requirements for chemical materiel methods, including physical measurement equipment or other laboratory equipment that validates a measurement. The calibration plan shall have documented instmctions on using and operating all relevant equipment, handling and preparing calibration items, and calibrating equipment. All up-to-date instmctions, standards, manuals, and reference data relevant to the monitoring or laboratory operation shall be maintained and be readily available to staff and auditors. The laboratory and monitoring staff shall use documented procedures and legally defensible statistical techniques to select representative samples for analysis, where applicable. All calculations and data transfer performed in support of solution preparation, calibration, and sample analysis shall be documented on a calculation sheet, signed and checked by a separate person. The validator shall sign the calculation sheet once it is deemed accurate. Where computers or other automated equipment are used to capture, process, manipulate, record, report, and/or store or retrieve calibration or test data, the laboratory shall ensure that: • The computer software is documented, fully tested, and adequate for use. • Computer and automated equipment is maintained to ensure proper functioning and is provided with the environmental and operating conditions necessary to maintain its integrity. • Procedures are implemented to protect data integrity. • Appropriate and up-to-date virus protection is in use. Deleted: alternate Deleted: will consist of one challenge event, the beginning of the operational workday, tlien not less than three challenge events per station per day with a challenge event every 2 to 3 hours. The alternate baseline will be conducted for 3 consecutive days. If necessary, mobile criteria may be used in heu of the alternate baseline. Deleted: Tlie mobile baseline study will consist of one cliallenge event at the start ofthe work day or operation, a challenge every 4 to 5 hours, and at the end ofthe workday or operation, each day of operations.^ For monitoring cessation greater tlian 60 days, tliree 1-day imtial and continuing baselines will be repeated. Deleted: baselines Deleted: 0 • Previous releases of software packages are maintained if data reprocessing is required. EDT personnel shall establish and implement appropriate procedures for the maintenance and 39 security of data, including the prevention of unauthorized access to and amendment of computer records. 11.2.1 .Calibration of Near Real Time Instruments NRT systems used to support class I air monitoring methods shall be calibrated using a minimum of two injections at the l.OZ level. Calibration will be considered acceptable if a challenge sample yields acceptable per cent recovery and carry over is less than 0.2 Z as compared to a blank cycle. ai.2.2 Calibration of GC/MS Systems GC MSD s\'stems used to analyze class I air samples shall be calibrated using a minimum three point calibration curve with masses covering the analytical range for each chemical to analyzed. At least one mass equivalent will be at or below the lowest l.OZ monitoring level. Cahbration regression lines shall provide a correlation coefficient value of 0.990 or greater. 11.3 QC Sampling All instmments used for the analysis of chemical agents shall be subject to periodic QC sample analysis to check the process from sample collection through analysis. The QC samples are also used to: • Evaluate the accuracy and precision of analytical data to establish the quality ofthe data. • Provide an indication of the need for corrective actions. • Determine the effectiveness of corrective actions when they are implemented. The laboratory and monitoring staff that supports EDT operations uses numerous types of QC samples to inspect the measurement process. The QC samples provide data that can validate the results of the analysis of an actual sample. The following types of QC samples are used by the laboratory staff during EDT operations: • Blanks; • Replicates; • Calibration checks; • Matrix spikes (MSs); • Field spikes [quahty plant (QP)]; and • Laboratory spikes [quality laboratory (QL)]. 40 Deleted: Performance Charts Deleted: Tlie laboratory may use performance charts for intemal QC tracking. A perfomiance chart is a graphical plot of challenge results with respect to time or sequence of challenges, with limits drawn witliin wliich results are expected to lie when the analytical scheme is in a state of "performance control." In addition to identifying methods or instrumentation that are out of "perfomiance control," tlie chart discloses any trending.^! Formatted: Font: Bold Formatted: Font: Bold Detailed definitions and descriptions of QC samples are available in the CMA LMQAP. , 11.3.1 NRT Methods All NRT monitors ^will be challenged via QP samples immediately following calibration and at the end of daily operations. If no operations occur on a given day, a challenge will be performed at least once during the day. These challenges will be designated as continuing baseline challenges. If two consecutive challenges fail to meet acceptance criteria, corrective action and data ciiialification is reciuired for all readings above 0.25Z. J'he QP challenge shall deliver agent to the instmment at 10^. Deleted: Limiting Conditions of operation (LCOs) can also be found in the LMQAP. Deleted: metliods used during operations 11.3.2 Historical/Confirmation Methods • QP Samples. All historical/confirmation methods will be challenged via QP samples in accordance with the CMA LMQAP, Table 13-4 and table 7-1. Confirmation QP samples must be analyzed within 72 hours of sample termination. A QP sample challenge failure will require corrective action and additional daily QP challenges until the problem is resolved. These QP challenges will not be included in the baseline studies, but will be included in the corrective action report. • QL Samples. All laboratory instmments used for analysis as part of historical or confirmation methods shall be challenged with QL samples [initial calibration verification (ICV) or continuous calibration verification (CCV) samples] to assess the laboratory's cross-contamination and bias. 11.3.3 In-Control Criteria and Notification The term in-control is used to indicate that the laboratory and monitoring analytical activities are within the pre-established statistical control limits and meet baseline study requirements. When instmmental methods are in-control, the analytes are detected and accurately quantitated if present in a sample. To protect personnel at the site, the monitoring equipment must be operating and in control before operations start each day and remain in control for the operational period. The EDT personnel report to the Versar EDT Site Manager the status ofthe monitoring and analytical instmmentation on a daily basis. The ECBC will record the control status ofthe laboratory and monitoring equipment in a daily operational log. If the laboratory or monitoring equipment is determined to be out of control, or if control status is questionable, then the Versar EDT Site Manager will be notified immediately. This ensures that agent concentrations above or equal to the MINICAMS™ alarm set_point at sampling locations will be properly detected and quantitated, and laboratory equipment will provide unqualified analyses. 11.3.3.1 Monitoring Equipment In-Control Critena/LCOs The EDT monitoring equipment is in-control if the following criteria are met: • The MINICAMS™ alarm systems have successfully passed their daily initial baseline challenge. • The alarm confimiation and historical sample stations are online and operating. 41 Deleted: according to tlie frequency identifled in tlie CMA LMQAP. ~ H Deleted: VSL The QC sample results reported back to the site from the laboratory are acceptable. • The monitoring teams have qualified personnel onsite to maintain monitoring operations in accordance with this SSMP. 11.3.3.2 Laboratory In-Control Criteria/LCOs The laboratory is in-control if the following criteria are met: • The instruments that will be used for sample analysis have been calibrated and challenged, and meet all performance criteria. • The samples can be received, stored, prepared, and analyzed in accordance with approved SOPs and this monitoring plan. • The laboratory is staffed with qualified personnel to prepare samples, perform sample analysis, document and report sample analysis results, and maintain monitoring operations in accordance with this SSMP. The in-control status of the laboratory will be recorded in the instrument data sheets on a daily basis prior to sample analysis. Traceability will include calibration of analytical instmments and qualifications of the operators. 11.3.3.3 Corrective Action If a QL result is outside the acceptable limits, then the method being checked is considered out of control. Another QL sample that duplicates the initial QL sample conditions will be mn as soon as possible. Immediate corrective actions will be taken to identify the source ofthe out-of- control condition. The Versar EDT Site Manager or designee will be notified if the laboratory cannot be retumed to an in-control status. 11.4 Sample Handling and Storage All laboratory and monitoring work performed during EDT operations shall follow strict COC procedures. The maintenance of records on the samples collected, received, and analyzed is a critical part of the monitoring program. The laboratory and monitoring personnel are required to ensure that COC is properly conducted. The recei'ving chemist will monitor the receipt of samples and compliance with preservation and holding time specifications. Specific procedures will be established by the laboratory and monitoring teams and ECBC under guidelines provided in the following paragraphs. 11.4.1 Shipping Containers and Custody Seals for Nonagent Analysis Cleaned sample bottles will be sent to the field in shipping containers that will be used for return of samples to the laboratory. Each sample container will contain packing material to protect the 42 samples from movement during shipment. Individuals collecting samples will follow published U.S. Environmental Protection Agency (USEPA)-approved procedures (SW-846) and site- specific SOPs, as approved by state agencies. The sample collection record will contain, as a minimum: Sample identification (ID); Date and time; Start and stop flow rates or collection times; Start and stop times of sampling period; Volume of sample; Sample location; Operator's ID Agent and monitoring level; Sample type; and Preservative, if any. Deviations from SOPs, security, and unusual environmental conditions shall also be included in the sample collection record. 11.4.2 Sample Identification A unique sample ID number will be affixed to the sample or sample container. To ensure traceability and uniqueness ofthe sample identification, the sample ID number should incorporate the sample type, date, and time that the sample was collected. Any deviations from standard procedures shall be noted in the comments section ofthe sample COC form. The sample identification system shall be documented, along with a method that relates the field data to the samples. All documentation ofthe samples shall be performed in permanent ink. If corrections are made to the data, the error will be crossed out once and initialed and dated by the person documenting the data. All field notebooks shall become part ofthe project files. 11.4.3 Sample COC Documentation The COC documentation will be strictly maintained. Evidence of sample custody shall be traceable from the time the samples are collected until the samples are disposed of after sample analysis. After samples are collected, the COC form will be completed, and the original will be placed in a plastic bag inside the secured sample transport container. Samples identified for analysis by the Organization for the Prohibition of Chemical Weapons will require a custody seal to be affixed to each sample container. A COC form will be forwarded with the samples as they are stored, prepared, analyzed, and finally disposed of in the laboratory. Receipts from post offices, copies of bills of lading, and airbills will be retained as part ofthe COC documentation for samples 43 that have been shipped off-site. 11.4.4 Sample Storage The laboratory shall be responsible for the documentation, security, and maintenance of storage conditions for sample storage. 11.5 Statistical Validation Statistical validation will be documented in reports including QC data, statistical analysis, and corrective actions. The laboratory will submit the QC data to the CMA mandated statistical program from baseline through closure at https://home.cma.armv.mil/qcdrs. 11.5.1 Routine Statistical Reports Raw data will be submitted to the operating contractor for data treatment. Reports shall be transmitted via the web-based statistical software to EG&G and CMA-Monitoring Office representatives on a monthly basis. These reports will contain information regarding the initial and continuing baseline studies. The laboratory will use the software to produce statistically valid and defensible reports. 11.5.2 Statistical Analysis of Cahbration Cui've Data Calibration curve data for the analj^ical equipment used in the sample measurement process will be analyzed statistically. Once the laboratory has defined the calibration method for an instmment, acceptance criteria for the calibration curve data will also be developed. The chemical material raw calibration data shall be generated from the laboratory specified calibration curves. Algorithms used for calibration curves shall satisfy the calibration requirements specified for each analytical method. 11.5.3 Data Vahdation Data validation of laboratory and monitoring data shall be performed routinely to ensure all data are used effectively and in accordance with the approved QC plan. Validation may be performed more frequently when data integrity has been or is suspected to have been compromised. Data captured that do not satisfy applicable data quality objectives (DQOs) will be deemed compromised data. Compromised data must be qualified appropriately and corrective actions shall be implemented to ensure that future data have the capability of satisfying applicable DQOs. The laboratory will define and document proper site validation procedures. To validate analytical and monitoring data, all equations and calculations must be validated during internal audits of the laboratory and monitoring teams. The internal data validation review will be documented in the laboratory or monitoring files, whichever is appropriate. If the internal data validation identifies an error, the CMA-Monitoring Office or designee will be notified. All actions taken to correct the error shall be documented. 44 11.6 QC of DAAMS Tubes New DAAMS tubes shall be subjected to the following test^ The nimber of tubers to bej)ulled for testing is provided in Table 11-3 Sampling/acceptance and inspection requirements consist of: • The Sample number, which is in accordance with American National Standards Institute (ANSI)/American Society for Quahty Control (ASQC) Z1.4, acceptable quality level of 2.5 percent nonconformance. • Visual inspection for loose packing, warped tube ends, and loose sorbent material • A pressure-drop test to ensure sufficient airflow through the mbe. For DAAMS 6-mm tube Tenax® TA, the pressure drop may not exceed 15 inches of mercury (Hg). Deleted: , or the manufacturer shall supply documentation with each lot purchased, attesting that the lot of DAAMS tubes have been subjected to these tests and meets all requirements Table 11-3. Samples Sizes for Normal Inspection for Maximum of 2.5 Percent Nonconformance Lot or Batch Size General Inspection Level 1, Number of Samples Rejection Number" 2 to 8 2 1 9 to 15 2 1 16 to 25 3 1 26 to 50 5 1 51 to 90 5 1 91 to 150 8 1 151 to 280 13 2 281 to 500 20 2 501 to 1,200 32 3 Reject the entiie lot if this number of samples is found to be defective. 11.7 Tube Conditioning After the representative mbes from a lot pass visual inspection and pressure drop testing, they will be conditioned in a flow of nitrogen at 290 °C for 20 minutes, followed by a 5-niinute cooling period. All mbes must be conditioned before agent recovery testing. 11.8 Heated Sample Lines Heated sample lines will be challenged at the distal end every 60 days for all locations except the stack. Heated sample lines used for stack NRT monitors will be challenged every 45 two weeks. Heated sample lines used for headspace monitoring will be challenged at the distal end before and after each analysis batch. All sample line challenges will be performed at l.OZ and will demonstrate recovery of 0.60 to 1.40Z. 12.0 DOCUMENTATION 12.1 General Monitoring Documentation During operations, ECBC personnel will maintain documentation of all monitoring activities. The documentation will include activity information on daily air monitoring, sample records, chain- of-custody (COC) forms or transfer of possession, sample analysis records, equipment calibration, equipment maintenance records, agent response, and Standing Operating Procedures (SOPs) and/or Intemal Operating Procedures (lOPs) for air monitoring and laboratory analysis. 12.2 Equipment Documentation All support laboratory analytical equipment infomiation will be documented by ECBC support laboratory persormel. The laboratory will document and maintain all acceptance test results for the equipment. Information regarding each instrument is documented in logbooks, an electronic database, or other applicable format. 12.3 Reference Standards The RDT&E dilute CASARM solutions will be used. Agent standards received by the agent custodian or designated alternates will be accounted for, undamaged, and properly labeled at all times. ^ •{ Formatted; Font: Bold ^12.4 Laboratorv Wastes ..^'^ Waste generated by air monitoring operations will be managed in accordance with local mles and regulations. 13.0 TRAINING REQUIREMENTS All EDT monitoring personnel are required to meet the minimum training requirements outlined in the OSHA standard 29 Code of Federal Regulations (CFR) 1910.120 covering Hazardous Waste Operations and Emergency Response (HAZWOPER). The ECBC personnel will perform all monitoring and analytical operations at the site. All monitoring personnel must also meet the training criteria detailed in the ECBC LMQCP. 46 APPENDIX 1. ACRON\MS/ABBRE\ lATlONS/TERMS -17 APPEIVDIX 1. ACRON\MS/ABBRE\ lATlONS/TERMS •AEL airbome e.\posure limit •ANSI .American National Slani.lan.ls Inslilule •ASC .Allowable Slack Concenlralion .\SQC .American Society lor (Quality Control C. AS.ARM Chemical .Agent Slani.lan.1 .Analytical Rel'erence Material CC\' continuous calibration \ eril1calion CDC Center for Disease Control CFR Cotle ol"Fei.leral Regulations CMA U.S. .Army Chemical Materials .Agency COC Chain ol'Cuslotly D. A Department ol'lhe .Army D.A Pam Department ol" the .Army Pamphlet D.AAMS Depot .Area .Air Monitoring System DCD Deseret Chemical Depot DHHS Department ol" Health ani.1 Human Ser\' ices DQO (.lata i.|ualily obiecli\ e -!« ECBC Ei.lge\vooi.l Chemical Biological Center EE En\ ironmenlal Enclosure FPD llame photometric (.leleclor G. A la bun GB sarin GC gas chromatograph GC FPD gas chromatograph llame photometric (.leleclor GC MS gas chromatograph mass spectrometer GD soman H. AZ\\'(!)PER Hazartlous W aste (!)peralions ani.1 Emergency Response HD i.lislillei.1 sulfur muslan.1 ('Bis('2-chloroelh\ 1) sullkle) Hg mercuiy HT !bis[2-('2-chloroelhylthio)elhyl]elher; HTSL heal-tracei.1 sample transfer line IC.AL Initial Calibration 1C\' initial calibration \ erificalion ID klenlificalion IDLH ImmetlialeK' Dangerous to Life ani.1 Health \0P intemal (!)peraling Procetlure LCO limiting contlilion ol"operation LNK^.AP Laboratoiy ani.1 Monitoring (^ualit\' .Assurance Plan LMC^CP Laboratoiy ani.1 Monitoring (Quality Control Plan ( for Chemical Materials .Ai:enc\' ('CMA ianLl for Chemical .Aeenl Slani.lan.1 .AnaKlical Reference Material (•(^AS.ARM)) MAP Mobile .Analytical Platform MARB Materiel .Assessment Re\ ie\v Boan.1 MCP Monitoring Concept Plan MS Mairi.\ Spike -19 MS Mass Speclrophotomeliy NRT near-real lime OSHA '•!)ccupalional Safely ani.1 Health .Ai.lministralion PA A precision ani.1 accuracy PCT Pre-Concenlralor Tube PDS Personnel Decontamination Station PMNSCM Project Manager for Non-Stockpile Chem ical Materiel PPE personal prolecli\ e ei.|uipmenl QA '.(ualily n.s.surnnce QA (^c '.|ualily assurance i.|ualily control QC '.|ualit\' control QL '.|ualily laboratoiy QP '.|ualily plant RDTAE research i.le\ elopmenl. lest, antl e\ alualion RT.AP Real-Time .Analytical Plalfomi SOP Slantling (!)peraling Procetlure SSHO Site Safet}- and Health Officer SSMP Site-Specific Monitoring Plan SEL Source Emission Limil STEL short-lemi e.\posure limil TWA rime W'eighlei.1 .A\ erage USEPA U.S. En\ ironmenlal Protection .Agency \"SL \'apor Screening Le\ el \'X '•:)-ethyl S-('2-diisopropylaminoethyl)melhylphosphonolhioale WPL worker population limil .\SD haloeen selecli\e (.leleclor 50 Formatted: Left: 70.55 pt, Right: 72 pt, Top: 76.3 pt. Bottom: 30.95 pt APPENDIX 2. REFERENCES Formatted: Left: 70.55 pt, Top: 76.3 pt. Bottom: 30.95 pt APPENDIX 2. REFERENCES ANNEXE Site-Specific Monitoring Plan for the Explosive Destruction System at Dugway Proving Ground, U.S. Army Chemical Materials Agency Project Manager for Non- Stockpile Chemical Materiel Site-Specific Monitoring Plan for the Explosive Destruction System at Dugway Proving Ground, Final Revision 2, March 2009. CMA, Programmatic Monitoring Concept Plan, most recent version. Department ofthe Army (DA), Implementation Guidance Policyfor Revised Airbome Exposure Limits for GB, GA, GD, GF, VX,H,HD, andHT, 18 June 2004. DA, Interim AMC Supplement to the Implementation Guidance Policy for Revised Airbome Exposure Limits for GB, GA, GD, GF, VX,H,HD, andHT, 14 December 2004. DA, Memorandum, Subject: Performance Standard for Monitoring Potentially Exposed Workers, 13 September 2007. DA Pamphlet 385-61, Toxic Chemical Agent Safety Standards, 17 December 2008. U.S. Army Chemical Materials Agency (CMA), Programmatic Laboratoiy and Monitoring Quality Assurance Plan, most recent version. U.S. Environmental Protection Agency, Test Methods for Evaluating Solid Wastes, Physical/ Chemical Methods, SW-846, current version. 52 Page 12: [1] Deleted arlita.privett 10/20/2010 6:14:00 AM Table 5-1: Description and Requirements for Monitoring and Sampling Equipment Manufacturer Minimum Operational Monitoring Operational Components Specifications Requirements Preventive NRT Monitors: MINICAMSTM^ NRT Detectors: FPD XSD PFPD Operational Components: Preconcentrator Tubes/Sample Tubes Sample Loops Capillary Columns Mass Flow Controller Support Gases: Purifiers Leak Detectors Compressed Gas Regulators Electrical Requirements: Critical NRT monitors equipped with UPS^ Power is provided in accordance with manufacturer specifications. Temperature: Use operational performance characteristics to determine if the NRT is operating within control. Doors to enviroimientally controlled NRT monitor shelter must remain closed at all times, except during personnel entry/egress. Condensation shall be minimized and if observed, corrective actions will be taken immediately. Routine Calibration Daily Challenges Calibration of mass flow meter The sample exhaust must be filtered, retumed to the sampling point, or vented to appropriate engineering controls. PCT is replaced as needed, based upon challenge performance. Page 13: [2] Deleted arlita.privett =End of Section= 10/20/2010 6:15:00 AM Table 5-1: Description and Requirements for Monitoring and Sampling Equipment (Continued) Monitoring Operational Manufacturer Specifications Minimum Operational Requirements Preventive Depot Area Air Monitoring System (DAAMS) DAAMS Operational Components: DAAMS Tubes: Size may vary depending on agent operation. Sequencers: Direct and control flow patterns DAAMS Manifold: Provides stable support system Power Requirements: Power is provided in accordance with manufacturer specifications. Critical DAAMS equipped with UPS' Temperature: Temperature is maintained to minimize condensate formation. The sample exhaust must be filtered, retumed to the sampling point, or vented to appropriate engineering controls. Vacuum Pumps: Used in conjunction with a flow control device or critical orifice Should maintain critical ratio of inlet to outlet vacuum across the orifice Daily checking of flow rates, critical orifices, fittings, and ferrules Vacuum pump, sequencer, and sample transfer line preventive maintenance will be performed in accordance with manufacturer specifications. Require air, nitrogen, or other inert gas flow through tube and thermal desorption of tube for conditioning Page 14: [3] Deleted arlita.privett Section Break (Next Page) 10/20/2010 6:15:00 AM Table 5-1: Description and Requirements for Monitoring and Sampling Equipment (Continued) Monitoring Equipment Operational Components Manufacturer Specifications Minimum Operational Requirements Pre Fabricated from stainless steel Page 14: [4] Deleted arlita.privett Changeout frequency site-specific basis. 10/20/2010 6:18:00 AM Stainless steel demonstrate detectable leaks, poor flow rates, or broken sections are repaired or replaced. Page 15: [5] Deleted arlita.privett 10/20/2010 6:31:00 AM Table 5-1: Description and Requirements for Monitoring and Sampling Equipment (Continued) Monitoring Operational Manufacturer Specifications Minimum Operational Requirements Pre' GC Analvtical Systems: Operational Power Requirements: Exhaust is vented to FPD MSD XSD Sample inlet Capillary column Column switching system Support gases Integration system Thermal transfer system Exhaust Cryofocusing Roughing pump'' Power is provided in accordance with manufacturer specifications. Confirmation monitor is equipped with UPS.' Power board is 120 volts altemating current. Room Temperature: Between 68 and 80 F during operational periods NOx Filters N/A In accordance with manufacturer specifications In accordance with manufacturer specifications The imintermptible power supply (UPS) must have brown-out protection and constant voltage output and must operate the instmments for at least 15 minutes during a power failure. Mass selective detector (MSD) only Page 17: [6] Deleted arlita.privett 10/20/2010 6:32:00 AM Table 5-2: Support Gases Equipment Requirements Compressed Gas Support Gases Purifiers Leak Detectors [Regulators Con May include: Moisture and Hydrocarbon May include: Will be Hydrogen Traps(if recommended by Simple soap solution two-stage regulators or equivalent Air manufacturer or vendor): Electronic leak detector two-stage regulators or equivalent Nitrogen Helium Frequency of change-outs Utilization: Use of toxic chemical are: approved Completed in accordance with nianufacturer specitlcations ;ind requirenients * Gas generators will be operatei.1 in accori-lance with manul'acturer specil'ications. Section Break (Next Page) Page 23: [7] Deleted arlita.privett 10/20/2010 3:49:00 PM With DAAMS capability. Also Spools to AM7 and AM 7-S. Personnel point source. Headspace monitoring (4 hours @ 70 °F). Clearance levels are 0.2 VSL for exterior of dmms, 0.5 VSL for chamber solid waste inside dmms, and 1.0 VSL for other (PPE) dmmmed waste. No smoke test required; will position according to proximity to chamber opening/door. For daily entry clearance/maintenance this station may be used with DAAMS for WPL monitoring. Controls the release of detonation gas to synch with MC cycle. In the event of alarm, recirculation loop automatically activates. Personnel entry chamber clearance spooled based on chamber stams. Upstream of process discharge. WPL DAAMS station must be collected and analyzed on a daily basis for this station. One MINICAMS™ spools between bed locations on each filter unit. Separate DAAMS on each location. Also has ability to spool to post-filter location if necessary to determine if breakthrough has occurred in final stage of filter. Spools from Post Treatment to Airlock 2. 11 These process samples are to determine if agent is being loaded onto carbon filters. Once agent is detected, no further monitoring is required. Page 34: [8] Deleted arlita.privett Table 9-1. NRT Notification Matrix Situation Notification Possible Action^ Single NRT Alarm • Versar EDT Site • Manager and ECBC • Site Supervisor • ECBC SSHO • EG&G Safety Await resuh of next MINICAMS™ cycle Evacuate non-essential oersonnel Evaluate PPE Analvze DAAMS tubes Two Consecutive MINICAMSTM • Versar EDT Site Manager and ECBC • Site Supervisor • . EG&G Safety Office • ECBC SSHO Await resuh of next MINICAMS™ cycle Evaluate PPE Determine source of contamination Analyze DAAMS tubes 10/20/2010 6:42:00 AM Three Consecutive Versar EDT Site Determine source of contamination MINIC AMSTMNR Manager and ECBC • Analyze DAAMS tubes T Alarms Site Supervisor Relocate filtration system MINICAMS™ sample point from prefilter midbed location to post-bed location EG&G Safety (if alarm occurs at the prefilter and the Office midbed • ECBC SSHO MINICAMS™ and/or a confiimed midbed alarm occurs) ^ This table is based on detection of chemical warfare materiel (CWM) at the alarm setpoint. Decision on actual actions taken will reside with the Versar EDT Site Manager. Actions may vary, depending on the actual concentration of CWM detected. Notes: DAAMS = Depot Area Air Monitoring System DCD = Deseret Chemical Depot EDT = Explosive Destmction Technology PPE = Personal Protective Equipment Page 37: [9] Deleted michael.knudsen 10/20/2010 9:59:00 AM Repeat ICAL if failure is for midday challenge. No action if failure is at the end of the day. Page 37: [10] Deleted michael.knudsen 10/21/2010 9:49:00 AM ^ Distal end line challenges will be performed on a weekly basis. Acceptance limits will be 0.60 to 1.40 VSL. Method is for one-of-a-kind, near-real-time samples. Reanalysis is not possible for QC failures. Page 37: [11] Deleted michael.knudsen 10/20/2010 10:01:00 AM HT - {bis[2-(2-chloroethylthio)ethyl]ether} Page 37: [12] Deleted arlita.privett 10/20/2010 6:46:00 AM Table 11-1. QC Requirements for lOP MT-02'' QC Sample Frequency Acceptance Limits Corrective Action Sampling Flow Rate Measurements During calibration HD, HT: 400 ±100 mL/minAdjust and recheck before starting calibration and analysis. Initial Calibration (ICAL) 1 High-level Challenge (1.0 VSL) Start of each operational day or after failing midday challenge 0.60 to 1.40 VSL Investigate and correct cause. Repeat ICAL if required. Continuing Calibration Verification (CCV) - Also Called Challenge 1 Low-level Challenge (0.25 VSL)*" After every 4 to 5 hours of operation and at the end of operational day Low: 0.75 to 1.25 VSL Investigate and correct cause. Repeat ICAL if failure is for midday challenge. No action if failure is at the end of the day. Note on data forms. arlita.privett 10/20/2010 6:44:00 AM Page 37: [13] Deleted " Operation and Maintenance Procedures for Fixed Site MINICAMS™. ^ Distal end line challenges will be performed on a weekly basis. Acceptance limits will be 0.60 to 1.40 VSL. Method is for one-of-a-kind, near-real-time samples. Reanalysis not possible for QC failures. Notes: HD HT mL/min =QC STEL = distilled sulfur mustard = {bis[2-(2-chloroethylthio)ethyl]ether} = milliliter per minute = quality control = short-term exposure limit Page 38: [14] Deleted arlita.privett 10/20/2010 6:46:00 AM Table 11-2. QC Requirements for lOP MT-IS" QC Sample Frequency Acceptance Limits Corre Sampling Flow Rate Measurements flow samples are one of Before and after sample Starting and ending Repeat sampling unless collection rates within 10% of the a kind. If one of a average flow rate Five Point Initial Calibration (ICAL) When instmment parameters change After preparation of new standards R2 >0.99 Investigate and c< ICAL. Initial Calibration Verification (ICV) At the start of each day of ±15% Recalibrate. analysis After ICAL Each target analyte of tme value Continuing Calibration Verification (CCV) At the end of a sample mn or every 12 hours, whichever is shorter Each target analyte ±15% of tme value Ifresult>115%. recalibrate. Sam] reported. If result <85' recalibrate. Ana tube for each si Method Blank At least one before analyzing samples Absence of target analytes Investigate and coi and interferences blank to verify acc( Quality Process (QP) - Similar to Matrix Spike 1 each per batch of 20 or fewer samples Recovery >10% (Note: Agent-specific limits are currently under development.) Verify spiking second QP tube spike and analyz from location w ^ Analysis of Chemical Warfare Agents and Degradation Products on DAAMS Tubes using a Gas Chromatography System Coupled with a Mass Selective Detector Notes: QC quality control REVISION 1 EDT DESTRUCTION PLAN ANNEX C INSPECTION PLAN November 2010 REVISIONS 1) Page C-2. p;u\igraph 7.0 re\ ised to read. "Tlie inspection tbrnis \\ ill be maintained on-site at the EDT for re\ iew access." 2) Table C-1. page C-3. item 1(c). .Add: "and inspect inner lid liner for e\idence of physical diiniage such as cracks, gouges, and dimples, beyond e.\pected depth" 3) Table C-1. Note added to Table C-1: items 11. 12. 13. 14. 15. and 16 are intemal inspections and not part ofthe pennit requirements. Tliese lia\e been included to ensure safe operations". 4) Table C-1. item 31. Table C-1 niodiHed to clarify that the 3.\ per week inspections are o\er and abo\e the daily calibration challenges. .Added clariUcation at the end ofthe last sentence in the last block of item 31: "records. (Regular MINICAMS challenges are not part of this inspection)." 5) Page C-2. Section 7.0. added "The fomis will be re\ iewed and appro\ed prior to use". EDT Destruction Plan .Anne.\ C Inspection Plan TABLE OF CONTENTS TABLE OF C ONTENTS C -i LIST OF TABLES C-i 1.0 INTRODICTION C-1 2.0 GENERAL INSPEC TION REQI IREMENTS C -1 3.0 SCOPE C-1 4.0 TYPES OF PROBLEMS TO BE IDENTIFIED C -2 5.0 FREQI ENCA OF INSPEC TION C -2 6.0 CORRECTI\ FACTIONS C-2 7.0 INSPEC TION FORMS AND INSPEC TION DOC I'MENTATION C -2 LIST OF TABLES Table C -1. Inspection Items for the TOOELE DAMNC H EDT C -3 C-i EDT Destmction Plan Annex C Inspection Plan 1.0 INTRODUCTION The Detonation of Ammunition in a Vacuum Integrated Chamber (DAVINCH™) Explosive Destmction Technology (EDT) treatment operation at Tooele Chemical Agent Destmction Facility (TOCDF) will be permitted by a TOCDF Resource Conservation and Recovery Act (RCRA) Permit modification issued by the State of Utah Division of Solid and Hazardous Waste (DSHW). This EDT Inspection Plan has been prepared to meet the inspection requirements for RCRA Permit Subpart X, Treatment Units. 2.0 GENERAL INSPECTION REQUIREMENTS The EDT site will be inspected according to a prescribed inspection schedule designed to detect equipment deterioration and prevent potential equipment malfunctions that could cause a release of hazardous wastes or otherwise pose a threat to human health and the environment. The inspection schedule document and inspection logs will be located in the EDT Control Room (at the EDT site). At a minimum, the inspection program will include inspections of the equipment items listed in Table C-1. Various forms are necessary to address the inspections required. 3.0 SCOPE This inspection plan addresses the RCRA requirement for Subpart X Treatment Units to conduct periodic inspections. The inspection criteria is based on good industrial practices of operation. Items to be inspected include: • EDT Chamber and components; • Off-gas treatment system; • Environmental Enclosure (EE) and the Heating, Ventilating, and Air Conditioning (HVAC) system; • Air monitoring equipment; • Less-than-90-day waste storage areas; • EDT loading/unloading areas; • Processing areas; • Fire protection, safety equipment (to include but not limited to spill kits, shovels, brooms, portable decon sprayers, and eye washes); • Communication items and equipment; C-1 EDT Destmction Plan Annex C Inspection Plan • Security fencing and signs; and • Emergency backup power. 4.0 TYPES OF PROBLEMS TO BE IDENTIFIED The types of problems that may be identified during inspections are listed in Table C-1 (below). 5.0 FREQUENCY OF INSPECTION The inspections listed in Table C-1 will be conducted at the specified frequency to identify and correct problems before they cause harm to human health or the environment. Inspection frequencies of individual items may vary, but are based upon the rate of possible deterioration of the equipment and the probability of an environmental or human health incident if a problem remains undetected during inspection. 6.0 CORRECTIVE ACTIONS Corrective actions are measures taken to address and resolve any issues discovered during inspection to prevent a malfimction or deteriorated/defective equipment from potentially causing a release of hazardous materials or otherwise posing a threat to human health and the environment. Corrective actions may include necessary repairs or further investigation of potential problems. All corrective actions are recorded and described on the inspection forms; these forms are dated and signed by the inspector, who also follows up on the corrective actions to ensure implementation and success 7.0 INSPECTION FORMS AND INSPECTION DOCUMENTATION The inspection forms will be maintained on-site at the EDT for review access. C-2 EDT Destruction Plan .Anne.\ C Inspection Plan Table C -1. Inspection Items for TOOELE DAMNC H EDT Item Number Item Description Inspection Frequency Types of Problems (Inspection Criteri;i) Detonation Chamber ani.1 Interior Ei.|uipment 1(a) Main Chamber (!)uter Shell Daily when in use Msually inspect e.\terior inclutling tubing, hoses, ani.1 \ al\es lor e\ii.lence ofcorrosion ani.1 leakage: this inclutles other physical i-lamage such as tears, stresses, gouges, i-limples. rips, cracks, ani.1 fasteners. 1(b) Main Chamber Inner Liner Daily when in use Msually inspect interior for e\ ii.lence of physical i.Lamage such as cracks, gouges. ani.1 i-limples. beyoni.1 e.\pectei.l tlepth 1(c) Main Chamber Lii.1 Daily when in use Coni-luct inspection ani.1 cleaning of sealing surfaces, .n-^.i m |-.'. I mn>-¥ lul ini-T I - .r 2 Pass-through lor Detonation Daily when in use Coni-luct high-potential test through open \ essel i.loor: coni.luct continuity check of feei.l-through ani.1 tletonator terminal blocks for proper functioning. (!)IT-Gas Treatment Systems EDT (!)IT-Gas Treatment Container Unit A Daily when in use Msually inspect for e\ ii.lence of corrosion, leakage, or other physical i.lamage such as cracks, gaps, or holes. 4 EDT Process \'entilation Unit B Daily when in use Msually inspect for e\ ii.lence of corrosion, leakage, or other physical i.lamage such as cracks, gaps, or holes. EDT Process \'entilation UnitsCl and C2 Daily when in use Msually inspect for e\ ii.lence of corrosion, leakage, or other physical i.lamage such as cracks, gaps, or holes. 6 EDT (!)IT-Gas Treatment Container Unit D Daily Msually inspect for e\ ii.lence of corrosion, leakage, or other physical i.lamage such as C-3 EDT Destmction Plan Annex C Inspection Plan Item Number Item Description Inspection Frequency Types of Problems (Inspection Criteria) when ni use cracks, gaps, or holes. Ventilation System 7(a) Carbon Filter Unit El Daily Visually inspect for evidence of corrosion, leakage, or other physical damage such as cracks, gaps, or holes. 7(b) Carbon Filter Unit E2 Daily Visually inspect for evidence of corrosion, leakage, or other physical damage such as cracks, gaps, or holes. 7(c) Carbon Filter Unit E3 Daily Visually inspect for evidence of corrosion, leakage, or other physical damage such as cracks, gaps, or holes. 8 Ventilation Blower/HVAC Blower Daily Visually inspect for any evidence of malfunction, blockage, or maintenance issues. 9 Stack Daily Visually inspect for any evidence of malfunction. Unpack Area (UPA) 10 Unpack Area Daily Inspect for evidence of spills, leakage, or damage to area. i_ Preparation Area -I T T T T » T » • T Utilities T J Deleted: ; Deleted: M210 Deleted: /'( I'l' r Deleted: comiection I'l' ,1/' I'l' Deleted: I'l' ,1/' I'l' Deleted: M141 Deleted: fi'i'i I'l'i'i i'l' I'l' Deleted: comiection iVi'i' Deleted: Deleted: M130 /^'|" Deleted: /^'|" Deleted: comiection S|i|i|'i' / i Ih'i 1 Deleted: S|i|i|'i' / i Ih'i 1 Deleted: MHO Deleted: ft'/' hi' i' 1' ''''I',' Deleted: comiection 1 ' r /'' ' ' 1'!' // Deleted: 1 ' r /'' ' ' 1'!' // Deleted: M170 i I , f'/// Deleted: i I , f'/// Deleted: comiection Deleted: Deleted: Unit F Deleted: Deleted: C-4 EDT Destmction Plan Annex C Inspection Plan Item Number Item Description Inspection Frequency Types of Problems (Inspection Criteria) 17 Generators Weekly Inspect for spills, proper operation, electrical output, fuel consumption abnormalities 18 UPS Weekly Check for battery life and indicators, correct voltage; check for leaks/corrosion in battery area. Communications 19 Link to TOCDF Control Room Daily Ensure link working to TODCF Control Room. 20 PA Daily Test PA. 21 Alarm Panels Weekly Check function of alarms. 22 Alarm Horns Weekly Check function of homs. 23 CCTV Weekly Check for operability, visual clarity; pan and zoom if applicable. 24 Radios/Cell Phones Daily Check for operability. Security 26 Fences Weekly Check for integrity, obstmction, gaps. 27 Lighting Weekly Check for operability. 28 Waming Signs Weekly Check for presence and legibility. Fire Protection/Safety Equipment 28 Fire Extinguishers Weekly Check pressure, general condition, and service date. 29 Personnel Decontamination Station Weekly Check for availability of decon solution, access, and operability. 30 Spill Kits Fire Extinauishers Safetv Equipment Weekly Check for inventory, condition, and expiration dates. C-5 EDT Destruction Plan •Annex C Inspection Plan Item Number Item Description Inspection Frequency Types of Problems (Inspection Criteri;i) •Air Monitoring 31 Chemical .Agent Monitors (MINK^AMST^'. DA.AMS) 3x AVeek Msual inspection for integrity, tliagnostic ini-licator check, sample lines ani.1 connections, heat traces, \ entilation for e.Khaust. ani.1 calibration i h.:jui.fi En\ ironmental Enclosure Weekly Check for breaches, weatheri-lamage. leakage, ani.1 air monitoring integrity C-6 Page 4: [1] Deleted drew papadakis 11/2/2010 11:41:00 AM Inspect for damage, labeling, potential damage, proper stowage of gas cylinders. REVISION 1 EDT DESTRUCTION PLAN ANNEX E - CLOSURE PLAN November 2010 REVISIONS 1) Annex E, page E-4, first paragraph after the bullet. 2) Page E-5, Change sentence to read: "Once the EDT unit is certified clean-closed to 1 VSL';^ 3) Changes 1.2. Closure Strategy, last paragraph, to read as follows^ FormaUed: Font color: Auto Formatted: Font color: Auto Formatted; Bullets and Numbering Formatted: Indent: Left: 18 pt Formatted: Indent: Left Formatted: Indent: Left 36 pt 54 pt, Tabs: 72 pt, List tab + Not at 54 pt Tenting and/or closing areas off and conducting head space nionitoruig using MINICAMS to 1 VSL for HD for two successive MINICAMS cvcles. 1) Disassembling components ofthe chamber and chamber door, decontaminating • components (e.g.. 0-ring. blast shield, and covers), and manuallv cleaning/decontaminating these components if headspace monitoring is identified. 2) Conducting "cleansing shots" which are explosive detonations without munitions to clean the interior ofthe chamber, and use the detonation process to remove any contaminants. Formatted: Bullets and Numbering Deleted: Aiuiex E, page E-5, first complete paragraph on the page and page E-10, first paragraph following the bullet list, top of page E-11, second paragraph on page E-12. These paragraphs mention wipe sampling as a means to determine if decontamination has been adequate. See Comment 1 regarding this subject. 31 4) Clearing sample and drain lines. Cleaning contact surfaces (electrical panels, debris pan, spill containment trays, railings, and other operator-contacted surfaces). 4) ^Wipe sampling has been deleted from the approach^ Formatted: Bullets and Numbering Deleted: Annex E, page E-5, Table E-1. The value, 0.003 mg/m', shown in tlie table as the air monitoring perfonnance standard is not an eight-hour TWA as stated in the table. Uiis value is actually the STEL, wliich is a 15-minute exposure limit. Formatted: Bullets and Numbering 6) Annex E, page E-6, Table E-2. ,"equal" between "to" and "equilibrium" Jias been changed^to "reach/'_ _ 7) Annex E, page E-8, last paragraph, .^dd "and a qualified Professional Engineer wih certify closure". ^ _ Deleted: <#>Annex E. Tlie closure plan should specify the 10 step process as specified in the CAMDS closure procedures. Please review the current CAMDS closure plan to ensure tliat closure ofthe DAVINCH follows a similar process. Wipe sampling for verification of decontamination will not be accepted. An approved decontamination plan will need to be used to acconq^hsh closm e of the unit^ \ \\ 1 Deleted: In tlie fnst row in the Deleted: should be Deleted: Deleted: t <#>Annex E, page E-6, Table E-3. The SOPs and lOPs listed in the Analytical Methods colimin of tliis table should be submitted for review and approval as part of the documents listed on page 36 ofthe Explosive Destruction Technology (EDT) Destruction Plan.^ Formatted: Bullets and Numbering Deleted: Tliis paragraph states that the Versar EDT Program Manager will certify closure. This should state that tlie Versar EDT Program Manager Deleted: Additionally, EG&G and [ Versar should be aware that they n ... ["!] Deleted: <#>Annex E, Appendix E-1 does not discuss the sanyling proc \^ ['2] TABLE OF CONTENTS T.\BLE: OF CONTENTS E i LIST OF FIGURES E ii LIST OF T.\BLES E ii LIST OF .\PPENDICES E ii 1.0 INTRODUCTION El 1.1 GEMER_\L DESCTilPTION E-1 1.2 CLOS^lRESTRATEC^ E-1 2.0 CLOSURE PERFORM\NCE ST.\ND.\RDS E 5 3.0 DISPOS.\LOR DECONT.\MIN.\TION OF EQUIPMENT. STRUCTURE. .\ND \\.\STE E " 4.0 CLOSURE SCHEDULE OF .\CTI\ ITIES E " 5.0 CONFIRM\TION .\CTI\ IT^ E 8 E-i List of Figures Fieure E-1. Overv iew of Closure Slraleev for D.AMNCH'r^' EDT E-3 List ofTiibles Table E-1. Closure Standards for D.A\TNCH'r^' EDT E-> Table E-2. .Air Monitoring Sampling Rei.|uirements E-6 Table E-3. Sampling ani.1 .Analysis Methotls E-6 Table E-4. Closure Schetlule (!)\ er\ ie\v E-7 List of Appendices .APPENDIX E-1. EDT S.AMPLFNG PROCEDirRES E-9 E-i 1.0 INTRODUCTION This Closure Strategy describes performance standards and procedures to clean-close the DAVINCIF'^ Explosive Detonation Technology (EDT) for reuse. This plan presents methods to identify contaminated system equipment; decontaminate contaminated system equipment; dispose of all wastes and contaminated materials; perform verification sampling to confirm successful decontamination; and certify closure. After the system operations are completed, the DAVINCH'^'^ will be transported to a storage facility at a Govemment site where qualified plant workers using appropriate procedures will operate the system. The DAVINCH'^'^ will remain under Government control (expected to be the Edgewood Chemical Biological Center in Edgewood, Maryland); therefore, the standard for decontamination of the equipment for removal is "3X" or VSL for HP. ,- \ Deleted: i VSL for HD~ 1.1 General Description The EDT will be located in Area 10 at DCD. It will be used to destroy overpacked chemical munitions and various samples from the Deseret Chemical Depot (DCD) Chemical Stockpile. Operational waste will be handled in accordance with the TOCDF Waste Management Plan and Chapter 3.11 of the Destmction Plan. 1.2 Closure Strategy Figure E-1 presents the general process for ensuring that the EDT site is closed in accordance with applicable standards. The EDT and associated equipment addressed in this strategy includes the DAVINCH™ main chamber, the off-gas treatment systems, the Environmental Enclosure (EE), and associated equipment that may have been in contact with chemical agent (CA) as determined by agent monitoring results and a review of DAVINCH™ operational history. No hazardous waste residue will remain on the EDT site after closure. Per Utah R315-8-7, Closure and Post-Closure (that incorporates by reference 40 CFR 264.111), an owner or operator must close a permitted hazardous waste management unit in a manner that minimizes the need for further maintenance and controls; minimizes or eliminates, to the extent necessary to protect human health and the environment, post-closure escape of hazardous waste, hazardous constiments, leachate, contaminated mn-off, or hazardous waste decomposition products to the groundwater, surface waters, or the atmosphere. All EDT operations are performed in a manner designed to control and eliminate the escape of hazardous waste and hazardous constituents into the environment. The EDT operations at TODCF will take place inside an EE comprised of a ceiling, sides, and flooring that will protect the hazardous waste management unit from precipitation and mn-on as well as prevent the creation of any contaminated mnoff Engineering and administrative controls are in place to control, minimize, or eliminate the possibility of contamination to groundwater, surface waters, or the atmosphere from EDT operations; they include: • An air filtration system with carbon filtration; E-1 Trained explosive handling and chemical operators in appropriate Personal Protective Equipment (PPE); Approved work procedures; and Prohibition of open flames, cutting, welding, smoking, and radiant heat inside the EE. E-2 Assess EDT Equipment' Decontaminate Equipment with ECAD, Cleansing Shot, Hot Soapy Water Clean Closure Achieved"' Determined through air monitoring, surface wipes, sampling, operational log review. Air monitoring via MINICAMST" and DAAMS, and analysis of surface wipes/samples. Rinse water will be samples and analyzed. Results compared to closure standards (See Table E-1). EDT or component can be removed from EE and removed from site Figure E-1. Oven iew ofClosure Str:iteg> for DA\ INCFF" EDT E-3 Decontamination procedures involve: • Tenting and/or closing areas off and conducting head space monitoring using MINICAMS to 1 VSL for HD for two successive MINICAMS cycles. 5) disassembling components ofthe chamber and chamber door, decontaminating components (e.g., 0-ring, blast shield, and covers), and manually cleaning/decontaminating these components if headspace monitoring is identified. 6} Conducting "cleansing shots" which are explosive detonations without munitions to clean the interior ofthe chamber, and use the detonation process to remove any contaminants. 7) Clearing sample and drain lines. 8) Cleaning contact surfaces (electrical panels, debris pan, spill containment trays, railings, and other operator-contacted surfaces). • Monitoring, and if necessary, cleaning the EE. • Collecting disposable components (i.e., plastic film shielding and other items considered consumable/not reusable), and placing them in waste containers for disposal. • Performing air monitoring, sampling, and pertinent assessments to confirm that the standards for removal are met; these assessments include, but are not lunited to, rinsate sampling, filter media sampling, visual assessment of system condition to ensure that no visible residue remains m the chamber or piping. re\ae\\' of monitoring records to detennine potential for system intemal contamination and headspace monitoring. • Reassembling and packing the EDT and subsystems for shipment off-site. Cleaning/decontaminating solutions may include hot soapy water/general detergent or other appropriate decontaminant; technique is referenced in United States (U.S.) Army Field Manual (FM) 3-5 or identified in Table 1, Alternative Treatment Standards for Hazardous Debris (40 CFR 268.45). The U.S. Environmental Protection Agency (EPA) recommends and approves the use of the Table 1 alternate treatment standards for Resource Conservation and Recovery Act (RCRA) closure purposes. For example, sodium hypochlorite (NaOCl), a standard decontaminant for chemical agent, is identified as a suitable decontaminant under the chemical destmction technology category. The decontamination/cleaning solutions are generally applied manually with a spray device or by wiping down with cloth or paper towels and wipes. Prior to initiating closure and verification activities to confirm successful EDT decontamination, the previously-described decontamination procedures will have been conducted and air monitoring results recorded; and all EDT process and cleaning wastes collected, containerized, and removed from the EE. Wastes will be properly characterized as outlined in the Waste Management Plan (Section 3.11 ofthe EDT Destmction Plan) and temporarily stored in a less- than-90-day waste storage area pending shipment off-site for further treatment or disposal. Air monitoring results will be compared to the closure performance standards listed in Table E-1. If results do not meet the closure performance standards, then decontamination will be repeated until the closure performance standards are met. The sampling method, EDT components, and areas for de-ionized water rinsate sampling, if necessary, are identified in Appendix E-1. Monitoring results will be compared against the closure performance standard values listed in Table E-1; if monitoring analytical results do not meet the closure performance standards in Deleted: <#>If MINICAMS readings exceed 1.0 VSL, then decontamination actions are executed including, but not limited to tlie following: % <#>Pei"forming decontamination ofthe chamber and chamber door tlirough Electrostatically Charged Aerosol Decontamination (ECAD), which uses a proprietary method of applying decontamination fluids to tlie chamber and its ulterior passages. Tlie ECAD uses a statically charged particle generator to ensuie that decon solution adheres to the imier surface of the chamber and the imier liiier(s) for the chamber and lids. H Formatted: Bullets and Numbering E-4 Table E-1, equipment will be decontaminated until they are met. The EDT will be deemed clean-closed when air monitoring, and if necessary, liquid sampling results meet the closure performance standards identified in Table E-1. The EE air filtration system will continue to operate and monitoring conducted until air monitoring and rinse water sample results are received. The EE will be decontaminated to the 1.0 VSL level for retum to ECBC. Once the EDT unit is certified clean-closed to 1.0 VSL, the EDT and EE will be demobilized. Demobilization will involve packing and removing the EDT equipment from the enclosure and then dismantling the enclosure. If, during demobilization, equipment or areas are discovered to be still contaminated, these areas/equipment will be decontaminated and decontamination verified as previously described. The types of wastes expected to be generated from closure activities include spent decontamination solutions/rinse waters; used PPE; and wipes, rags, and other absorbent and cleaning materials used to conduct decontamination. If the carbon filters from the air filtration system cannot be reused, they will be removed and managed as State of Utah waste code P999 hazardous waste. Rinse waters will be managed as State of Utah waste code F999. Table E-1. Closure Standards for DAVINCIFM EDT Media and Parameter Performance Standard Equipment - Mustard (HD/HT) US ARMY 3X -1 VSL headspace air monitoring Liquid Waste - Mustard (HD/HT) 200 ppb 2.0 CLOSURE PERFORMANCE STANDARDS Clean-closure ofthe EDT unit and associated equipment will be deemed complete when air monitoring and rinsewater sampling results meet the closure performance standards identified in Table E-1, for movement to a government facility. Air will be monitored for specific periods as detailed in Table E- 2. Closure performance standards for air monitoring of chemical agents are based on headspace vapor sampling and analysis and are established as the "3X" level, or screening to 1 VSL. Sampling conducted to determine decontamination and clean-closure is summarized in Table E-3. E-5 Table E-2. Air Monitoring Sampling Requirements Item Sampling Conditions Equipment Isolate potentially contaminated equipment by enclosing in plastic and allowing headspace in the enclosure to.jeach equilibrium for 4 hours at or Equipment above 70°F before monitoring. Fixed Equipment 4 hours at or above 70°F before monitoring Portable Equipment 4 horns at or above 70°F before monitoring ® After the conditions listed in this table are established, MINICAMS or Depot Area Air Monitoring System (DAAMS) samples will be collected. MINICAMS alanns will be confinned using DAAMS. If results meet closure perft)nnance standards in Table E-1, the stmcture or equipment is considered "clean-closed". Deleted: equal Table E-3. Sampling and Analysis Methods' Sample Source Headspace Gas Sample of EE and EDT Equipment Rinse Waters Number of Samples Two sampling cycles for each equipment or space Two Sampling Method/ Equipment^ Low-level air monitor/using MINICAMS™ or DAAMS Grab Analytical Parameters Chemical Agents Chemical Agents Analytical Method j:DT-TOCDF: PROO^-ECBC lOP MT-11 D.\_\MS TUBE MONITORMG EDT-TOCDF- PR008 MINICAM EDT-TOCDF-PR- 022. ANALYSIS OF CWM ON DAAMS. ^DT-TOpCF-PROl 6-_ _ K:BC.IOPMTrOS- " ANALYSIS PLAN AND ANALYSIS SOP. Sample Holding Time N/A N/A Formatted: Font: 9 pt Formatted: Bullets and Numbering Formatted: Font: 9 pt Deleted: ECBC lOP MT-02 (MINICAMS), MT-11 (DAAMS), and MT-13 (GC/MS) Formatted: Font: 9 pt, Not Bold Mobile laboratoiy will perfonn confirmation agent analysis for all wastes, using state-approved analytical methods. ^ DAAMS will be used to confirm MINICAMS™ alann. Mustard, HT will be measured. HT will be measmed as HD. ^ SPS/IOP's are Internal Operating Piocedures from Edgewood Chemical Biological Center and adopted for EDT. Copies will be provided prior to initiation of operations. Deleted: ECBC SOP Number CNG- 044 lOP MT-8 Formatted: Font: 9 pt E-6 Upon closure ol'lhe EDT unit ani.1 associalei.1 ei.|uipmenl. there will be no hazartlous wastes or hazari-lous waste constituents, inclutling i-lecontamination wastes, remaining. Prior to beginning closure, all irealmenl resitlues ani.1 relalei.1 wastes will be remo\ ei.l iVom the EDT site. .All wastes generalei.1 (.luring closure acli\ ilies. such as spent i-leconlaminalion solutions ani.1 rinse waters, will be conlainerizei.1. samplei.1. analyzei.1. characlerizei.1. ani.1 managei.1 appropriately, basei.1 on waste classiUcalion ani.1 in accori-lance with applicable regulatory rei.|uiremenls. Spent i-leconlam inalion solutions ani.1 rinse waters will be managei.1 as F999 hazartlous waste. Closure wastes will be placei.1 in a less-lhan-9()-i.lay waste storage area pentling shipment to a pemiilled TSDF. During closure acli\ ilies. personnel will use appropriate personal prolecli\ e clothing ani.1 ei.|uipmenl as i.lelenn inei.1 by the EDT Site Salely ani.1 Health (!)lTicer. In general. Department ol" the .Army Pamphlet (D.A Pam) 3S5-61. Toxic Chemical.-igenl Sajet}- Standards, will be Ibllowei-I. as well as (!)ccupalional Safely ani.1 Health .Ai.lminislralion ((!)SH.A) safely slani.lan.ls. 3.0 DISPOSAL OR DECONTAMINATION OF EQllPMENT, STRI CTI^RE, AND \\ ASTE Soil remo\ al shouki not be necessary (.luring closure because the EDT operations are enclosei.1 (the enclosure consists of ceiling, sitles. grouni.1 co\ er. ani.1 llooring) ani.1 coni.luclei.1 on a closei.1- olT-gas irealmenl system with secontLaty containment. .Any incitlenls in\ ol\ mg chemical agent release or hazartlous waste (.luring operations wouki be manage(.l un(.ler Emergency Response an(.l Contingency .Actions. oulline(.l in the site-specific SSSP. 4.0 CLOSIRRE SCHEDULE OF ACTIMTIES Table E-4 presents the notional sche(.lule of closure actions by (.lay Table E-4. Closure Schedule 0\en lew lleiii Da> Coiiipleled liuiiiiie Cio-^iire .\cii\iiie-; Dm n Coinliici Decoiiiiuiu Mill ion Dii\ ^ ()\er-^2lii iuni Re\ievv Dm Piick EDT eiiiu|)iiieiii Dii\ 6 EG.tG Reiiio\iiJ iiil vvii-;ie iVoiii EDT Siie Dii\ S Coiii|)leie Cio-^iire Dii\ Ml E-7 5.0 CONFIRMATION ACTIVITY The Versar© Program Manager, EDT, will ensure that confirmation activities have been accomplished. These activities inclu(ie confirming that: • Spills, releases, and cleanup activities were noted and evaluating them. • The EDT procedures for closeout (servicing, cleaning/decontaminating, and preparing the EDT and associated equipment for reuse and demobilization) were followed. • The EDT was air monitored to verify adequacy of cleaning/decontamination. • Air monitoring results were documented and the recorded values met the closure performance standards. • Decon rinsate and anv de-ionized water rinsate sampling results met the closure performance j Deleted: oe-ionized water rinsate QtnnflnrH« sampling and analysis were conducted SldnUdrus. according to procedure, t • Wastes generated from closure activities were transferred to a less-than-90-day waste storage ^ area pending shipment off-site. When the closure performance standards for air monitoring and decon rinsate sampling have been met, the Versar© EDT Program Manager will certify in writing that the EDT was clean- closed in accordance with the approved closure strategy and all applicable regulations. A licensed UT Professional Engineer will review and sign the closure certification. This certification shall be provided to EG&G for further submittal to TOCDF, DCD, and the Utah DEQ as required. Additionally, all activity will be consistent and comply with Permit Condition II.J.7. regarding notification of closure. E-8 APPENDIX E-1. EDT S AMPLING PROCEDIRRES E-9 APPENDIX E-1 EDT SAMPLING PROCEDURES Purpose: Sampling will be conducted to validate clean-closure of the EDT and associated equipment in accordance with this procedure. Objectives: Headspace monitoring will be conducted to determine the 1.0 VSL screening limit for the following equipment: • EDT Main chamber inside walls; • EDT Main chamber door/lid; • Hose and lines; • Personnel decontamination station; • Mobile Laboratory; • Monitoring Enclosure; and • EE. Any areas that require additional decontamination will be treated with rinsate/decon solution. Once the decon /insate samples have been collected from the previously-listed EDT components/areas, the rinsate wastes can be commingled into a single container for easier management. If required, the Operating Subcontractor (Le..jVersar) wilL^P^ggt^^^, _ characterization sample(s) from the rinsate waste container once the container has been transferred to the less-than-90-day waste storage area. , Target Analytes: Target analytes are listed in Table E-1 (i.e.. Mustard [H/HD/HT). Laboratories: Utah-certified chemical laboratory, on-site laboratory, and surety laboratory as required. Participants: EDT operators and subcontractor (Versar) personnel. Observers: Versar Chemical Safety Manager. Formatted: Underline, Font color: Red Deleted: C Deleted: URS Deleted: Additional wipe samples may be used in the chamber interior. E-10 Sampling Method: MINICAMS headspace monitoring PPE: Level D. Decontamination/Rinse Equipment: Garden-type plastic sprayers (2); Squeeze bottles (polyethylene) (4); 2- gallons of deionized water; Plastic film and catch basins to catch and transfer rinsates; Paper towels; Waste containers; 5-gallon pails; and ECAD spray device. Sample Prep and Shipment: 1-liter sample bottles (24 bottles); Sample labels; Floor and wall squeegee; Chain(s) of custody forms; Clear packing tape for positive closure of sample jars; Sample coolers approved for Department of Transportation (DOT) shipment; Ice for sample preservation; Plastic "bubble wrap" for packaging samples in coolers; Adequate rubber bands to secure bubble wrap around sample jars; DOT Labels (if required) and address labels for shipping coolers (if required); Box tape; Razor knife; and Shipping labels, and shipment or pickup by an appropriate ovemight carrier (if required). Sampling Procedures: Inner Chamber The inner chamber will be tented using visqueen. The chamber will be allowed to stabilize for 4 hours at 70 degrees F. Two consecutive MINICAMS readings will be taken to determine if the inner chamber is contaminated above the 1.0 VSL screening limit. If the interior of the chamber is deemed contaminated, additional decon will take place based on the procedures in the closure plan. E-U Chamber Lid/Door Containment/Floor Area/Mobile Laboratory/Monitoring Enclosure The mam area ofthe enclosure will be sealed off and the H\'AC shut down. The enckisure will be allowed to stabilize for 4 hours at 70 degrees F. Two consecutive MINICAMS readings will be taken in the interior ofthe enclosure to detemiine if the area contains residual agent, or is contaminated above the 1.0 VSL screening limit. If the enclosure is deemed contaminated, additional decon will take place based on the procedures in the closure plan. T Waste Processing Area The waste processing area will be sealed off and the HVAC shut down. The enclosure will be allowed to stabilize for 4 hours at 70 degrees T. Two consecutn'e MINICAMS readings will be taken in the interior ofthe enclosure to determine if the area contains residual agent, or is contaminated above the 1.0 VSL screening limit. If the waste processing area is deemed contaminated, additional decon will take place based on the procedures in the closure plan. T Sampling Lines An EDT technician will use a garden sprayer or other spray source (e.g., a squirt bottle) filled with de-ionized water to spray into sampling lines, allowing water to pass through the lines and be collected into a plastic catch pan at the opposite end. Sampling personnel will collect the samples from the plastic catch pan, and remaining rinsate will be placed into the designated rinsate waste container. Waste Management and RCRA Characterization All excess rinsates will be placed in a DOT-approved container (possibly a 5-gallon plastic, closed-top pail for liquids). The container will be labeled as hazardous waste pending RCRA characterization. The waste container will be transferred to Operating Subgontractqrj?ery>nnel for management. ' Deleted: One EDT samphng teclmician will place a clean plastic pan on tlie floor in a position to allow capture of spray water beneath the lid/door. The teclmician will then proceed to use the de-ionized water-filled garden sprayer to rinse all areas on tlie inner side ofthe lid/door. The rinsate produced will be captured in the plastic catch pan. Spraying will continue until the entire area has been sprayed. Sampling personnel will collect the samples fiom the plastic catch pan. Remaining rinsate will be placed into the designated rinsate waste container. ^ Deleted: An operator will spray over the entire contaimiient area: floor, bottom, and sides. Spray activity will continue until the entire floor ofthe containment pan has been sprayed. The second teclmician will collect the containment rinsate using a squeegee and place it in a plastic pan of an adequate size to hold the rinsate generated from at least one pass across the containment area. Sampling personnel will collect the samples from the plastic catch pan, and remaining rinsate wiU be placed into the designated rinsate waste container. One wipe sample per 100 fp will be taken from tlie interior of tlie EE. K Deleted: Tlie dmm area, including the spill control pallets, will be sampled. Tlie spill pallet will be elevated and laid on its side in a maimer that will allow the placement of a plastic catch pan undemeatli the opening of a pallet to catch the rinsate as it exits the pallet. Sampling personnel will collect the samples from the plastic catch pan. Remaining rinsate will be placed into the designated rinsate waste container. ^ Deleted: C E-12 Page 2: [1] Deleted PKendall 10/6/2010 7:00:00 PM Additionally, EG&G and Versar should be aware that they must comply with Permit Condition II.J.7. regarding notification of closure. Page 2: [2] Deleted PKendall 10/6/2010 6:59:00 PM Annex E, Appendix E-1 does not discuss the sampling procedures to be used to verify decontamination of the exhaust gas treatment equipment. The procedure lists several methods for sample collection, catch/grab and wipes but does not specify anywhere in the procedure where they are used. More detail is needed. REVISION 1 EDT DESTRUCTION PLAN ANNEXE TOCDF EDT EMERGENCY RESPONSE PLAN November 2010 REMSIONS 1) Paee F-:. Table F-1. Chanee "TOCDF" to "DCD". .Added to last line of Table F-1 Noli Ik'iiiioii ol'i )ilier FiiL'iliiie-; BiiUiliiis-; iii E\eiii ol' Eiiier2eik'\ T( )DCF Coiiirol Room The TOCDF Coiiirol Room -liiiJI lie re-;|)oii-;il>le I'or iioii l\ iiig oilier I'iiL'Uii ie-; biiUiUiis-; ol'EDT eiiiergeik'ie-;. lo iiiclmle. l>iii iioi l>e Uiiuieilio. .AiilOL-liive. D\ SD\ SSR iuiil .ATL IC |)er-;oiuiel 2) Page F-2. Table F-1. Corrected spelling of "TOCDF" in Table F-1. 3) Page F-2. the last sentence changei.1 to reai.1: "Use ol"controllei.1 access ( i.e.. the personnel i-lecontamination station airlock to the en\ ironmental enclosure must be passei.1 through by personnel as they enter)". 4) The thiri-l ani.1 I'ourth paragraphs untler 1.1.2: Change "T(!)CDF" to "DCD" The last bullet untler 1.1.3.1 re\ isei.l to reai.1. "Placing absorbei.1 or pumpei.1 material into DOJ- appro\ ei.l containers ani.1 managing appropriately in accon.lance with all applicable pemiits ani.1 rules." 6) Page F-4. ai.klei.1 to bullet: "inclutling use ol"appro\ei.l i-lecontamination methotls. inclutling use ol'i-lecontamination solutions, ani.1 post-tlecontamination monitoring \ ia NITNIC.AMS to the 1.0 \"SL level, at l.o \"SL" 7) Page F-.^. ai.klei.1 this phrase to the the last paragraph on this page - "metlical emergencies in\ ol\ ing" to clarily that metlical emergencies may in\ ol\ e chemical agent." S) Page F-6 ani.1 F-7. Sections 1.1.3.Sani.l 1.1.3.9. .Ai.klei.1 this paragraph to Section I.I.3.S. .Any munitions in o\ erpacks that are on site in the e\ ent ol'an e\ acuation or work stoppage ol" operations tlue to se\ ere weather contlitions will be securei.1 in the enclosure. I fcN acuation is not callei.1 for. then CPRP members will monitor the status ofthe munitions. If munitions o\erpacks are set up with e.\plosi\ es ani.1 not yet placei.1 in the chamber, the e.\plosi\ es operator will remo\ e any tletonators ani.1 rentier the item safe before e\ acuation. or. (.luring se\ ere weather. If the munition ON eqiack is in the chamber, the chamber tloor will be closei.1 ani.1 securei.1 by the DCS. In all cases, health ani.1 safet\' conceras will o\ errii.le an\' actions taken to secure munitions. 9) Page F-6. .Atkl to the eni.1 of Section 1.1.3..^: "I fa shot is i.leterminei.1 to be a partial tletonation. SOP procei-lures will be followei.1. In the e\ ent that such a partial tletonation occurs, procetlures ani.1 risk assessments are in place to enter the chamber ani.1 atklress the issue. It is not consii.lerei.1 an emergency contlition unless a release or e.\plosi\ e hazan.1 e.Kists. which will be ai.klressei.1 as part of this plan. The Hazan.1 .Assessment has i.letenn inei.1 that this is an unlikely occurrence." lU) Page F-S. Seclioii 1.1.3.1 1 . .Added "In accoiclaiice \\ illi llie appiopiiale Peniiil CondiIIOIL-^. The E.\ecuti\e Secretary shall be notifiei.1 within 24-hour if there is a confirmei.1 agent concentration in the D.A\TN("H P.AS ani.1 En\ ironmental Enclosure ("ombinei.1 Stack that is ei.|ual or greater than 1 \'apor Screening Limit (A'SL). Re(|iiiied lepoiis are made in accordance wiili R313-S-l.7( i) (J) aiid TOCDF Pail B Peniiil Coiidilioiis. The operator must note in the operating recon.1 the time. i.late. ani.1 tletails of any incipient that rei.|uires implementing the Contingency Plan. For any emergency e\ ent rei.|uiring H.AZMAT release reporting, the control room will notify the DCD EOC ani.1 the CMA Shift Engineer ani.1 pro\ii.le a copy ofthe e\ent report. .All reporting to the .Army, local. State, ani.1 Fetleral agencies will be handled by DCD." 1 1) Page F-7 ani.1 F-S. Section 1.1.3.1 2 has been nuxlifiei-l to state that ".Appro\ al of The E.\ecuti\ e Secretaiy is rei.|uirei.l prior to the resumption of EDT operations. 12) Page F-S. Section 1.2.1. "at T(!)CDF" i.leletei.1 at the eni.1 ofthe paragraph. LV) Paee F-9. Revised to"monthlv". TABLE OF CONTENTS T.\BLE: OF CONTENTS F i LIST OF T.\BLES F N LIST OF .\PPENDICES F N 1.0 INTRODUCTION F i 1.1 SPECIFIC-Co^mNCElNC•^ PL\NS F-2 /././ PiYVfiiiiiiivf Mi'diiiin F-J 1.1.2 EiiiiTi^i'iiry Plmiiiiiiii F-.^ /./..i Ri'i/joiiii' ^nioiii f-V 1.2 WORKZR POPliLATION Ll\nT(\\ PL) EXCliRSION PL\N F-9 1.2.1 Purpose of n PL F\runion Plan F-9 I.:.: Tfi-iiii F-9 Opfniiiiiii Prori'diiin F-9 F-i List of Tables Table F-1. Emergency Notifications F-2 List of Appendices APPENDIX F-1. Example Notice of WPL Notification F-10 APPENDIX F-2 Emergency Response Equipment Locations and Evacuation Routes F-15 F-ii • ( Formatted 1.0 INTRODUCTION This Emergency Response Plan describes the emergency response and contingency actions that will be followed in the event of a fire, explosion, or any unexpected, implanned release of hazardous materials, hazardous waste, or hazardous waste constituents during operations ofthe Explosive Detonation Technology (EDT) at TOCDF. These actions pertain to all operations ofthe EDT at TOCDF, and they apply to all site personnel, visitors, contractors, and external support personnel. The EDT will be located in Area 10 ofthe Deseret Chemical Depot (DCD). The system will be used to destroy overpacked chemical mimitions and samples from the DCD Chemical Stockpile. The operational waste will be handled in accordance with the TOCDF Waste Management Plan and Chapter 3.11 ofthe Destruction Plan. The EDT Site Manager or Safety and Health Officer (SHO) will be responsible for ensuring that the appropriate procedures are followed. The TOCDF Control Room will be notified if any emergency or release condition occurs. Table F-1 lists the organizations to be contacted when emergencies or releases occur. A copy of this plan will be maintained at the TOCDF EDT Control Room at the site. All EDT operations are performed in a manner designed to control and eliminate escape of hazardous waste and hazardous constituents into the environment. EDT operations at TODCF will take place inside an Environmental Enclosure (EE) comprised of a ceiling, sides, and flooring that will protect the hazardous waste management unit from precipitation and run-on as well as prevent the creation of any contaminated runoff. All EDT operations are performed in a manner designed to control and eliminate escape of hazardous waste and hazardous constituents into the environment. The EDT operations at TODCF will take place inside an EE comprised of a ceiling, sides, and flooring that will protect the hazardous waste management unit from precipitation and nm-on as well as prevent the creation of any contaminated runoff. Engineering and administrative controls are in place to control, minimize, or eliminate the possibility of contamination to groundwater, surface waters, or the atmosphere from EDT operations; they include: • An air filtration system with carbon filtration; • Trained explosive handling and chemical operators; • Appropriate Personal Protective Equipment (PPE); • Approved work procedures; and • Prohibition of open flames, cutting, welding, smoking, and radiant heat inside the EE. Formatted: Centered, Space After: 6 pt F-1 Table F-1. Emergency Notifications Formatted: Font: Bold Event Reporting Comments Fire TOCDF Control Room (435-833-7700) DCD Fire Response dispatched Medical TOCDF Control Room DCD Ambulance dispatched Chemical Release TOCDF Control Room TOCDF HAZMAT response team dispatched Chemical Spill of Industrial Compoimds TOCDF Control Room TOCDF HAZMAT response team dispatched if required All Other Emergencies TOCDF Control Room TOCDF Emergency Response will assist in deteimining response level EDT Site Manager EDT SHO Notify as soon as possible after accident or illness occms. Do not Accident Reporting Operating Contractor PM Operating Contiactor SHO delay emergency assistance to make notifications; reporting shall be made TOCDF Control Room by EDT Site Manager EDT Site Manager EDT SHO Operating Contractor PM Operating Contiactor SHO TOCDF Control Room Do not delay emergency assistance to make notifications. Notification of Chemical Event EDT Site Manager EDT SHO Operating Contractor PM Operating Contiactor SHO TOCDF Control Room reportable spills must be made even when cleanup is handled by EDT operations personnel; reporting shall be made by EDT Site Manager Non-Emergency Change in PPE level EDT Site Manager EDT SHO Operating Contractor PM Operating Contractor SHO Approval of change must be received before operations resume. Notification shall be made by EDT Site Manager Daily Start of Operations Daily End of Operations TOCDF Control Room Daily Reporting The TOCDF Control Room shall be Notification of Other responsible for notifymg other facilities/buildings of EDT emergencies to include, but not be limited to, Autoclave, DVS/DVSSR and ATLIC persoimel. * Facilities/Buildings in Event of TODCF Coiitiol Room responsible for notifymg other facilities/buildings of EDT emergencies to include, but not be limited to, Autoclave, DVS/DVSSR and ATLIC persoimel. * Emergency responsible for notifymg other facilities/buildings of EDT emergencies to include, but not be limited to, Autoclave, DVS/DVSSR and ATLIC persoimel. * .* For additional notification requirements, see Section 1.1.3.11. <^ A 1.1 Specific Contingency Plans Contingency plans for the site include measures to prevent emergencies or, if any emergency occurs, to limit the negative impact. The major aspects of these plans are: • Preventive Measures - Measures that should prevent or limit an emergency incident. • Response Actions - Specific actions to be taken in an emergency situation. • Notification - Response organizations or personnel to be notified in case of emergency. I.I.I Preventative Measures The following measures will be implemented to prevent or limit an emergency incident: • Strictly adhering to the Standard Operating Procedures (SOPs), including use of PPE '( Formatted; Space Before: 3 pt •{ Formatted; Font: Not Bold { Formatted: Normal F-2 during all EDT site activities Use of controlled access (i.e., the personnel decontamination station airlock to the environmental enclosure must be passed through by personnel as they enter the enclosure). Determining the evacuation route and rallying point, and communicating it to workers during the daily safety briefing. Keeping standard absorbent materials, shovels, and overpacks on-site to contain a spill or leak. A review ofthe EDT consumable list and verification checklist will be used to ensure appropriate inventories of these materials. Discontinuing operations when inclement/hazardous weather conditions pose a threat to the safe working environment. Some ofthe items to be considered prior to determining if work should continue are heat stress; severe weather conditions, such as high wind, fog, and heavy rain; and potential for electrical storms. 1.1.2 Emergency Planning Response actions by EDT at TOCDF personnel for spills or releases will depend on whether the release occurs within or outside of engineering control, it can be safely managed using EDT site persoimel and resources on hand, and the release involves chemical agent. Any spills or releases will be immediately assessed by the EDT Site Manager or designee to determine the following information: • Material(s) involved; • Exact source of release; • Quantity of release; and • Release classification: Release to the environment (not wholly contained in the EE) or release contained; extent of any materials released to the environment and extent of injuries. Releases or spills occurring within engineering controls or for an incident at the EDT site that can be managed using available EDT site supplies and resources will be managed by EDT site persoimel. The TOCDF Control Room will be notified if any emergency condition occurs and of all spill of hazardous materials or hazardous wastes. Spills beyond the management capability ofthe EDT Site Manager will be managed by TOCDF personnel under their emergency response procedures. Spills or releases outside of EDT engineering controls or those that cannot be managed using EDT site personnel and resources will be handled in accordance with the TOCDF Emergency Response Plan. The TOCDF and DCD emergency responders, including fire and medical personnel, will be on duty during EDT operations. The DCD Fire Department and the TOCDF Clinic will provide the emergency and medical response to the TOCDF EDT at the request of the EDT Site Manager through the TOCDF Control Room office. If the incident is beyond the capabilities of TOCDF response personnel, the EDT Site Manager or designee will contact the TOCDF Control Room. Emergency responders may be reached by calling the DCD Fire Department via the TOCDF Control Room (435 F-3 '[ Formatted; Font: Bold Formatted: Font: (Default) Times New Roman, Not Bold 833-7700) as indicated in Table F-1 (see previous). 1.1.2.1 Amendment of Emergency Response and Contingency Action These emergency response and contingency actions will be reviewed and amended, if necessary, when: • Applicable regulations are revised. • Actions fail in an emergency. • Facility changes in its design, construction, operation, maintenance, or other circumstances in a way that materially increases potential for fires, explosions, or release of hazardous materials or hazardous waste/constituents, or changes response necessary in an emergency. • List of emergency equipment changes. j^ote: Revisions to this Emergency Response Plan constitute a revision to the TOCDF RCRA Permit and must be done through permit modification procedures specified in Title 40 ofthe Code of Federal Regulation (CFR), Part 270.42, Appendix I, B^6. ^ ^ -- -fFoi^atted; Font: Not Bold 1.1.2.2 Emergency Equipment at EDT Site at TOCDF Spill kits will be located inside the EE and the decontamination stations. The spill kit will contain spill pillows and assorted items to facilitate the containment and reduction of liquid spills. Additionally, shovels, brooms, portable decontamination sprayers, and other such equipment will be located at the EDT site to further aid in the containment of any liquid spills. Other emergency equipment will be provided on an as-needed basis by TOCDF emergency response services. 1.1.3 Response Actions This section describes response actions that will be used for incidents or events requiring some action by EDT site personnel, visitors, contractors, and external support personnel for the following categories: events involving Chemical Warfare Material (CWM); events involving non-CWM; medical assistance; fire/explosion; severe weather; and external arsenal events. 1.1.3.1 General Spill or Release Response The following actions will be followed for spills or releases that occur within engineering controls and/or that can be reasonably handled using EDT site personnel and resources on hand: • Notify the TOCDF Control Room • Wearing appropriate protective clothing per the direction of Site Safety and Health Officer. • Containing the spill in the smallest area possible using absorbent socks, berms, or other means. • Repairing or plugging the leak, if possible. • Decontaminating the release area using installation policies and DA Pam 385-61, including use of approved decontamination methods, including use of decontamination solutions, and post-decontamination monitoring via MINICAMS to the 1.0 VSL level, at 1.0 WPL, /is needed. , . - \ Deleted; F-4 • For container spills, placing containers in overpack or removing container contents, if necessary, using a portable pump, and transferring material to a new container. If the material was released to secondary containment (for contents released from a container), released material either will be pumped out ofthe containment area using a portable pump or absorbed using compatible absorbent materials such as pillows, socks, or granules. • Decontaminating equipment and clothing as directed by the EDT Site Manager as applicable. • Managing spent chemical agent decontamination solutions and other waste decontamination solutions as hazardous waste. • Placing absorbed or pumped material into DOT-approved containers and managing appropriately in accordance with applicable permits and rules pertaining to hazardous waste management and spill reporting for hazardous material. 1.1.3.2 Events Involving CWM If exposure to chemical agent is suspected, or symptoms of agent exposure develop, operators will hold their breaths and immediately don escape masks, sound the air horn (one long blast) or give verbal waming (if workspace alarm has not soimded), and report to the Personnel Decontamination Station area or rally point. The Crew Chief/SHO will notify the TOCDF Control Room of the suspected or known release and of any casualty requiring immediate medical attention. Casualties will be processed through the Personnel Decontamination Station, and decontamination will not be delayed until the arrival of medical personnel imless physical injuries prevent safe movement ofthe casualty. Operators not showing symptoms of agent exposure will be processed through the Personnel Decontamination Station and will stand by for further instruction. The EE provides engineering control so that personnel outside the EE will not be exposed to hazardous concentrations of chemical agent vapors. Under no circumstances will incoming personnel or visitors be allowed to proceed into the Chemical Response Zone (CRZ) once the emergency signal has been given unless authorized. Further emergency response to chemical agent release and injuries will be directed by the TOCDF Control Room. 1.1.3.3 Events Involving Non-CWM Materials When an incident occurs involving non-chemical agent hazardous materials (for example, chemical reagents, industrial solvents, decontamination agents, fuels) in a quantity that cannot be managed by EDT site personnel and resources on hand, the EDT Site Manager will contact the TOCDF Control Room that assistance is required. Otherwise, the TOCDF Control Room will be notified that a spill occurred and the EDT operators will respond using materials contained in the spill kits and follow the general spill or release response steps. Typical responses to chemical exposure emergencies shall include: • Inhalation - Move to fresh air and call for emergency assistance as indicated in the subsequent paragraphs. F-5 • Sldn Contact - Use copious amounts of soap and water. Wash and rinse affected area thoroughly, and then provide appropriate medical attention. An eye wash will be provided at the EDT personnel decontamination station. Eyes should be rinsed for 15 minutes upon exposure. Drenching, if required, will be performed at the personnel decontamination station. • Ingestion - Call for emergency assistance and process through the personnel decontamination station immediately. • Puncture Wound or Laceration - Call for emergency assistance as indicated in the subsequent paragraphs. If chemical materials are involved, process through the Personnel Decontamination Station immediately. If no chemical materials are involved, processing through the Personnel Decontamination Station is not required. 1.1.3.4 Industrial Accidents and Medical Emergencies Assistance If a worker is injured or becomes ill on the job, trained co-workers will implement first aid/CPR if necessary. Emergency medical guidance and assistance will be provided by the TOCDF emergency services. The DCD Fire Department will be contacted at (435- 833-7700) (landline) through the TOCDF Control Room. For medical emergencies involving CWM exposures, personnel shall follow the TOCDF Contingency Plan. Additionally, procedures relative to medical monitoring and post- exposure results are established by the TOCDF Medical Director and will be adhered to in the event of individual exposure. 1.1.3.5 Potential or Actual Fire or Explosion Evacuation diagrams will be posted conspicuously throughout the EDT at TOCDF site. A common rally point shall also be identified. The EDT has been designed to minimize the possibility of a fire associated with the system. The EDT uses electrically-powered equipment, combustible liquids, and compressed gas in various operations. When a fire is spotted by a team member, he or she will soimd an alarm (i.e., an air hom). The operator must inform the EDT Site Manager ofthe size and location ofthe fire. If the fire is small, the operators may attempt to extinguish it using a portable fire extinguisher. If this attempt is successful, the crew member will inform the EDT Site Manager ofthe fire status. If the fire is large, involves materials that present an increased hazard to the crew member, or the first attempt to control the fire is unsuccessful, the crew members will evacuate the area and inform the EDT Site Manager. The EDT Site Manager will contact the TOCDF Control Room and request assistance. This contact should include a description ofthe type and size of the fire, the location of the fire, and the method for contacting the EDT Site Manager. The EDT Site Manager will account for all personnel, including visitors, on the site. Regardless ofthe size of the fire, the TOCDF Control Room will be called. They will be informed ofthe nature ofthe fire and whether or not items containing chemical agents are involved. F-6 I.I.3.CS PPE Failure U"an\' site worker e.\periences a PPE failure that alTecls the pn')tecli\e abiliU' ofthe ei.|uipmenl. that person \\ ill immei.lialel\' irUorm the ("rew ("hiefani-l report to the Personnel Decontamination Station for assistance. Re-entr\' to the EDT operations area will not be permittei.1 until the ei.|uipment has been repairei.1 or replacei.1 ani.1 the EDT ("rew ("hief has grantei.1 permission. 1. 1.3.7 Ph\ sical Iniur\' Emergenc\' first aii.1 shall be appliei.1 onsite as necessar\'. A l1rst-aii.l kit is a\ ailable at the Personnel Decontamination Station. For minor non-emergenc\' ph\sical injuries rei.|uiring metlical treatment be\oni.l on-site l1rst aii.1. the casualt>' will be transportei.1 to the nearest healthcare racilit>'. The T(!)("DF Control Room will be notil1ei.l ofall injuries. I.I.3.S Se\ere Weather The T(!)CDF Control Room will irUorm the EDT Control Room ofweather atkisories such as se\ere w eat her watches or w amings. The EDT Site Manager ani.1 SHO will consii-ler this information ani.1 make motlifications to the work schetlule as appropriate to ensure worker saret>'. During se\ere w eat her. w hen notil1ei.l. all personnel e.\posei.l to the elements will report to the i.lesignatei.1 safe location. WTien lightning is i.letectei.1. all EDT operation acti\ ities will cease. The EDT Site Manager w ill i.le\elop a list orke\' personnel ani.1 ensure employee awareness. In the e\ent that T(!)CDF is closei.1 ulue to se\ere weather), the EDT Site Manager will notily ke\' personnel to report to the site to ensure continuei.1 saret>' oran\' CWM ani.1 ensure that critical ei.|uipment (such as monitoring ei.|uipment ani.1 \entilation ei.|uipment) is maintainei.1. These personnel will be on hani.1 once the on.ler to reopen the base is gi\ en. so acti\ ities at the EDT site can proceei.1 w ith a minimum of interruption. 1. 1.3.9 E.\ternal TOCDF Emergencies The potential e.\ists that an accitlent or incipient somewhere else on T(!)CDF w ill rei.|uire e\acuation ofthe EDT site. The T(!)CDF Control Room will irUorm the EDT Control F-7 Room of such emergencies should they occur. 1.1.3.10 Evacuation Plan Personnel assigned to the EDT site will be instructed in evacuation signals, procedures, and routes from the EDT site. An evacuation route from the EDT site will be determined prior to operations. Evacuation procedures are as follows: • The EDT Site Manager or designee will make the decision to evacuate. • Upon direction to evacuate, the EDT Site Manager or designee will notify all personnel in the area of an evacuation by an audible alarm/or vocal command. • If an incident occurs inside the EE, non-essential personnel (as defined by the EDT Site Manager) will don protective masks and proceed outside to an upwind assembly point. All essential personnel will don protective masks (unless already in higher- level PPE) and will rally at the Personnel Decontamination Station to prepare for decontaminating the affected area. • If the incident has occurred outside the EE, the same procedure will be followed and all non-essential personnel will be evacuated from the assembly point to a safe distance, upwind ofthe incident. Windsocks located at the site will indicate wind direction. • The EDT Site Manager will identify the evacuation route from the EDT site based on the type of incident and prevailing wind. • The EDT Site Manager or designee will contact the TOCDF Control Room by phone or radio and will indicate the number of personnel requiring transportation from the assembly point as necessary. • If required, transportation will be provided for all personnel at the designated assembly point. Personnel who are injured or may have been exposed to hazardous chemicals or chemical agents will be decontaminated in the EDT Personnel Decontamination Station, and then will be taken immediately to the TOCDF Medical Clinic. 1. 1.3.11 Notification and Reporting The primary responsibility for notification will lie with the Crew Chief with assistance from all other field personnel. Table F-1 (shown previously) provides infonnation for the responsible person or agency notification, hi accordance with the appropriate Pennit Conditions, The Executive Secretary shall be notified within 24-hour if there is a confirmed agent concentration in the DAVINCH PAS and Environmental Enclosure Combined Stack that is equal or greater than 0.5 Vapor Screening Limit (VSL). Requued reports are made in accordance with R315-8-4.7(i) & (j) and TOCDF Part B Permit Conditions. The operator must note in the operating record the time, date, and details of any incident that requires implementing the Contingency Plan. For any emergency event requiring HAZMAT release reporting, the operator will notify the TOCDF Control Room. The TOCDF Contiol Room will notify the DCD EOC and the CMA Shift Engineer and provide a copy of the event report. All reporting to the Aimy, local. State, and Federal agencies will be handled by TOCDF. 1. 1.3.12 Critique of Response and Follow-up F-8 Formal accident investigation will be conducted by the CMA/supporting safety office in accordance with procedures identified in AR 385-10. Should changes to EDT operations be required, those changes will be approved by CMA Risk Management Division (RMD), ECBC Risk Management Office (RMO), and the supporting safety office prior to resumption of EDT operations. Approval of The Executive Secretary is required prior to the resumption of EDT operations. 1.2 Worker Population Limit (WPL) Excursion Plan 1.2.1 Purpose of WPL Excursion Plan The purpose of this plan is to provide information that will be used to investigate, identify, and control sources of identified excursions of chemical agents above the worker population limit (WPL) in areas where excursions are not expected during EDT operations. 1.2.2 Terms • Worker Population Limit (WPL). The WPL is the maximum allowable 8-hour time- weighted-average concentration of chemical agent that an unmasked worker could be exposed to for an 8-hour workday and 40-hour week for 30 years without adverse effect. The agent of concem at the site is mustard (HD). The WPL for HD and HT, the agents of interest at TOCDF EDT, is 0.0004 mg/ml • WPL Excursion. A WPL excursion is defined as readings above 1.0 WPL that do not coincide with near real-time (NRT) monitoring greater than or equal to the NRT alarm level. • WPL Excursion Response. This is defined primarily as a medical response when an airbome concentration of chemical agent is greater than the established WPL. It does not necessitate emergency response or an immediate threat to life, but will result in direction given by a competent medical authority (TOCDF Clinic or other appropriate medical support) to determine any health risks or potential adverse effects. However, a WPL excursion greater than the STEL is considered a chemical agent event and requires that the appropriate emergency response be initiated. 1.2.3 Operating Procedures 1.2.3.1 Notice of WPL/Emergency Response If air monitoring results indicate an excursion of chemical agent above the WPL in a location where an excursion was not expected (that is, outside of engineering controls), the following steps will be followed: • The monitoring team leader will immediately notify the SHO ofthe WPL excirrsion. • The SHO will ensure that the area(s) involved in the excursion will be promptly restricted, transients will be limited, and PPE levels will be increased until the cause is evaluated and corrected. See Appendix F-1 for an example of a Notice of Restriction. • The SHO will notify the EDT Site Manager and provide the: Location of excursion; Period of time for excursion; F-9 Name ofagent in\oKei.k WTL in mg m"': .Amount ore.\cess in mg m"\ Proposes actions to pre\ent future e.\cursions: Salet>' POC ani.1 telephone number: Mei-lical POC ani.1 contact plan \ ia T(!)CDF Control Room: ani.1 Statement concerning health impact ani.1 concurrence of competent metlical authorit>'. Appeni.li.\ F-1 shows an e.\ample of a Notice of E.\cursion 1.2.3.2 ln\ estigation of WTL E.\cursions ln\estigations ofall WPL e.\cursions will be pertormei.1 to tletermine the cause, control the source ofthe e.\cursion. ani.1 pre\ent future occurrences. Technii.|ues for controlling e.\cursions might inclutle contlucting atklitional monitoring. re\ iew ing operational procei-lures. e\aluating engineering controls, ani.1 or other procei-lures as i.leterminei.1 by the SHO ani.1 EDT Site Manager. All irUormation rele\ant to the in\estigation w ill be pro\ii.lei.l to the T(!)CDF Clinic. Instances of e.\cursions will be re\iewei.l or anal\zei.l at least \u- hihlv to (.letermine an\' trentls. F-|() APPENDIX F-1 NOTIC E OF WPL EXC I RSION F-1 I APPENDIX F-2 EMERGENCY RESPONSE EQUIPMENT LOCATIONS AND EVACUATION ROUTES * ( Formatted; Left F-13 The EDT Site evacuation routes are shown in Figure F-2-1. The figure shows three separate potential pathways for egress from the site. The TOCDF Emergency response/evacuation plan will be used to guide the EDT operations persoimel from Area 10 to a safe haven- Figure F-2-2 shows the escape pathways for the environmental enclosure. There are four separate egress points from the enclosure, and the doors swing in the appropriate direction to ensure a quick exit. The diagram also shows the location of fire extinguishers. Figure F-2-3 shows the evacuation route for DCD to included Area 10. Area 10 evacuation routes are determined at the time of the incident and are directed by the TOCDF Control Room or DCD Emergency Operations Center (EOC) F-14 Primary ^ ^ F~15 Fire Extinguisher Locations Q Spill Kit Location Emergency Exit Routes ~( Formatted; Space Before: 2 pt Figure F-2-3. Evacuation Pathways for EDT Environmental Enclosure F-16 Formatted: Font: Not Bold figure ZZ. Evacuation Route for DCD Including Area 10 -[ Formatted; Font: Bold 'I Formatted; Centered F-17 REVISION 1 EDT DESTRUCTION PLAN ANNEX G OPERATOR TRAINING PLAN November 2010 OPERATOR TRAINING PLAN Subcontract No: DMB51843 Submitted to: EG&G Defense Materials, Inc/URS 11600 Stark Rd. Stockton, UT 84071 Submitted by: (^VERSAR Versar, Inc.© 6850 Versar© Center Springfield, VA 22151 jNFoyember 2010 Deleted: May 10. 2010 REMSIONS 1) Page 2. Section I.I. The list ol" applicable i-locuments has been nuxlil1ei.l to inclutle the I'ollowing i-locuments: a. EDT Destruction Plan ani.1 .Annexes b. EDT-TOCDF-PRool - EDT Conlrol System Operations c. EDT-TODCT-PRoo: - EDT E.\plosive'Operations d. EDT-T0CDF-PR()()3-EDT OFFGAS Operations e. EDT-T0D(T-PR()()4-C0NT1NGENC^' (\intingency Plan f EDT-T0CDF-PR()()5-Delivery. Assembly, and Checkout g. EDT-T0CDF-PR()()6- EDT Decontamination h. EDT-T0CDF-PR()()7- ECBC lOP MT-I I D.AAMS TUBE MONITORING i. EDT-TOCDF-PR()()S_^[TNI(^AMS .i. EDT-TOD(T-PR()kS-ECBC lOP MT-oS- .AN.AL^ SIS PL.AN .AND .AN.AL^ SIS SOP k. EDT-TOCDF-PRooO - Waste Management Operations I. EDT-TOCDF-PR()i:- Material Handling Operations m. EDT-T0DCF-PR()13 - Maintenance Operations n. EDT-T(!)CDF-PR|() - Metal Fragment Drum Heatlspace Monitoring (!)perations 2) .Appeni.li.\. .A copy ol'the Kobe Steel Training Plan has been ai.klei.1 as .Appeni.li.\ 3. 3) .Anne.\ G. page 6. the lH'th paragraph. Changei.1 to reai.1: The SONLI waste will be heatlspace screenei.1 to 0.5 \'SL in accori-lance with procei-lures. The waste storage area ol'the En\ ironmental Enclosure will be managei-l in accori-Lance with 9() i-lay storage area rei-|uirements. (!)perators will screen the exterior ofthe waste containers to a o. 1 \'SL le\ el. ani-l use a forklift to mo\ e the waste: once clearei-l. to the exterior of the enclosure for pickup by T(!)CDF W aste Management operations. . The waste will then be turnei-l o\ er to T(!)CDF W aste Management personnel who will arrange for any ai-klitional analyses rei-|uirei-l ani-l for off-site i-lisposal. 4) .Annex G. page 23. Change "began" to "begin. •Annex G. Section I .o. Ai-kl: The rei-|uirements in Utah R31 5-S-2.7( a) ('3). which inclui-les 4()-hour (!)SH.A training ani-l refresher training carriei-l by all operators prior to arri\ al at the site: inclui-ling. but not liiuitei-l to: ( i) Procei-lures for inspection, use. repair, ani-l replacement of facility emergency ani-l monitoring ei-|uipment ( See .Appeni-li.x I. CB.ARR pre-i-leployment training) ( ii) Communications or alann systems: ( See Sec. 3.1.3. Site Specific Training) (iii) key parameters for automatic waste feei-l cut-off systems: (not applicable) Cw) Response to fires or explosions: ( See Sec. 3.1.3. Site Specific Training) (A) Response to grouni-lwater contain ination incii-lents: (See .Appeni-li.x I. CB.ARR pre- i-leployinent training) (A i) Shuti-lown of operations ( See Sec. 2.3.1. EDT (!)perator Training) TABLE OF CONTENTS TABLE OF CONTENTS I LIST OF TABLES II LISTOEHGirRES II LISTOF ACRON\VIS II 1.0 OPERATOR TRAINING 0\ ER\1E\\ l 1.1 .\PPLIC.\BLE: DociMKMS : 1.2 REFERENCES 3 2.0 EDT-SPECmC TRAINING REQllREMENTS 3 2.1 EDT PROCESS TR.\IJNHNG 2. /. / Statement of Purpose •! 2.1.2 Process Ovenueiv and Training Objectives < 2.2 JOB TITLES .\M)I)I TIES 6 2.3 EDT-SPECIFICTR.\HNHNG CONTENT, FREQLIEINC^ , .\IVDTECI-IJNIQLIES 9 2.3.1 Classroom Training Modules 9 2.3.2 EDT On-Site OJT 10 2.4 EDT-Si'ECN K TR.VIMV; M.\TERI.\I,S m 2.5 TR.\IJNHNG ST.\FF i-i 3.0 SITE-SPECIFIC TRAINING REQllREMENTS 15 3.1 CHEMIC.\L SITE-SPECIFICTR.\HNIJNG REQLIIREMEINTS i^ 3.1.1 CEA Door Guard Training Course /.i" 3.1.2 Escort Training Course /.i" 3.1.3 Site-Specific Briefings lo 3.2 OTHER SITE-REQI IRED TR.VIMNC I6 4.0 IMPLEMENT ATION OF THE TR AINING PROGRAM 24 APPENDIX 1 25 APPENDIX 2 2- .\i'i'LNDi\5 r List of Tables Table I Table 2 Table 3 Table 4 Table 5 EDT Site (!)perational Training (!)biecti\ es Training Le\ els. Training Curriculum for Classroom Lectures Training Curriculum for Site-Specific Training Training Materials Site-Specific Training Rei-|uireinents \6 List of Figures Figure I. Process (!)\ er\ iew ani-l Training (!)biecti\ es for (!)perators Figure 2. EDT (!)perational (!)rganization List of Acroiivms (^AIRA Chemical .Accii-lent or Incipient Response ani-l .Assistance CB.ARR Chemical Biological .Applications Risk Rei-luction Business Unit CEA Chemical E.xclusion .Area CL.\ Chemical Limitei-l .Area CPRP Chemical Personnel Reliability Program CSM Chemical Surety Materiel DA\TNCHT^' Detonation of .Ammunition in \'acuuin Integratei-I Chamber DCD Deseret Chemical Depot DCS Dislributei-I Control System DESTINE' Near Real Time Strain Monitoring System ECBC Ei-lgewooi-l Chemical Biological Center EDT E.xplosi\ e Detonation Technology EGSiG Defense Materials. Inc. IT^S GRAND Global DA\TNCH'r^' EDT Data System HSiS Health and Safety LSC Linear Shapei-I Charges OSHA (!)ccupational Health ani-l Safety .Ai-lininistration O.IT On the .lob Training PPE Personal Protection Ei-|uipinent RCRA Resource Conser\ ation ani-l Reco\eiy .Act T-CEA Temporaiy- CE.A TOCDF Tooele Chemical .Agent Destruction Facilit}' 1.0 OPERATOR TRAINING OVERVIEW The Explosive Destruction Technology (EDT) Statement of Work (SOW), paragraph 3.17, requires that the contractor provide an operation, maintenance, monitoring, and engineering Training Plan for operators ofthe EDT. The contractor must also ensure that the EDT is operated in a manner that protects human health and the environment. This plan addresses the specifics ofthe training program for EDT operators at TOCDF. Versar© proposes using qualified, trained operators from the Edgewood Chemical Biological Center (ECBC) Chemical Biological Applications & Risk Reduction (CBARR) operators, supported by Versar© personnel. A memorandum of imderstanding between the Deseret Chemical Depot (DCD) and the ECBC organizations will define the Chemical Personnel Reliability Program (CPRP) requirements associated with assignment of ECBC personnel. In addition, a list of personnel, training certifications, and Competent Person Training will be provided before deployment. A Training Supervisor will be assigned to coordinate and manage the training program for the EDT Team. This individual will also participate in the hands-on training provided under this plan. This training plan addresses the baseline training requirements for EDT operations personnel, which are: • EDT-specific training, described in this Operator Training Plan; • DCD- and TOCDF-required training, including site-specific training required by the operating contractor [i..e. Site Visitor Orientation Traimng (SVOT)]: chemical exclusion area , - - 4 Formatted: Font: (Default) Times operations; SOW Appendix B, Badging and Site Access; and Appendix E, Traming and ^ ^ New Roman, 12 pt, Not Bold Certification Requirements, including site-specific training. • CBARR-provided training in CPRP, including Chemical Surety under Army Regulation (AR) 50-6, Chemical Safety and Chemical Handling; explosive safety training under AR 385-64; Department ofthe Army Pamphlet (DA Pam) 385-64, Ammunition and Explosives Safety Standard; and other CBARR-required training programs as described in Appendix 1, CBARR Training Requirements. • The requirements in Utah R315-8-2.7(a) (3), which includes 40-hour OSHA training and refresher training carried by all operators prior to arrival at the site; including, but not limited to: (i) Procedures for inspection, use, repair, and replacement of facility emergency and monitoring equipment (See Appendix 1, CBARR pre-deployment training) (ii) Communications or alarm systems; (See Sec. 3.1.3, Site Specific Training) (iii) Key parameters for automatic waste feed cut-off systems; (not applicable) (iv) Response to fires or explosions; (See Sec. 3.1.3, Site Specific Training) (v) Response to groundwater contamination incidents; (See Appendix 1, CBARR pre- deployment training) (vi) Shutdown of operations (See Sec. 2.3.1, EDT Operator Training) The operator training program described in this plan will address the first two bullets above. 1.1 Applicable Documents Applicable Documents include: SOW for EDT at TOCDF, EG«feG, which includes Appendices B and E. TOCDF Trainmg Plan, Attachment 7, TOCDF (May 2009), 29 Code of Federal Regulations I9I0. Occupational Safety and Health Administration (OSHA) Standards, Subparts D, E, G, H, I, J, L, M, O, and S. Department of Defense (DoD) 6055.9-Std., Department of Defense Ammunition and Explosives Safety Standards, 29 February 2008; Chapters 4, 5, 6, 7, 8, 9 and 11. DA Pam 385-64, Ammunition and Explosives Safety Standards, 15 December 1999, Chapters 4, 5, 6, 7, 8, 9, and 11, and Appendices B, C, D, and F. DA Pam 385-61, Toxic Chemical Agent Safety Standards, 17 December 2008, Chapters 3, 4, 5, 6, 7, 8, and 12, and Appendices E, F, G, and H. DA Pam 385-173, Occupational Health Guidelines for the Evaluation and Control of Occupational Exposure for Mustard Agents H, HD, and HT, 3 June 2003, Chapter 2. DA Pam 385-65, Explosive and Chemical Site Plan Development and Submission, 1 February 2008. Explosive Site Safety Plan Developer's Guide, February 2006, Sections 5, 6, 11, and 12, and Appendices A and B. AR 415-15, Army Military Construction Program Development and Execution, Paragraph 2- 16. DA Pam 385-65, Explosive and Chemical Site Plan Development and Submission, 1 February 2008. Technical Manual (TM) 5 -1300, Stmctures to Resist the Effects of Accidental Explosions, 1999. Military Standard (MIL-STD)-882D, Standard Practice for System Safety, 10 February 2000 DA Pam 385-16, System Safety Management Guide, 13 November 2008. EDT Destruction Plan and Annexes EDT-TOCDF-PROOl - EDT Control System Operations EDT-TODCF-PR002 - EDT Explosive Operations EDT-TOCDF-PR003-EDT OFFGAS Operations EDT-TODCF-PR004-CONTnsfGENCY Contingency Plan EDT-TOCDF-PR005-Delivery, Assembly, and Checkout EDT-TOCDF-PR006- EDT Decontamination EDT-TOCDF-PR007- ECBC lOP MT-11 DAAMS TUBE MONITORING EDT-TOCDF-PR008_MINICAMS EDT-TODCF-PR016-ECBC lOP MT-08- ANALYSIS PLAN AND ANALYSIS SOP EDT-TOCDF-PR009 - Waste Management Operations EDT-TOCDF-PR012- Material Handling Operations EDT-TODCF-PR013 - Maintenance Operations EDT-TOCDF-PRIO - Metal Fragment Drum Headspace Monitoring Operations 1.2 References Kobe Steel Ref \'()() D\'l l-PR-ol Training Plan. .lanuaiA-. 2()()9 2.0 EDT-SPECIFIC TRAINING REQUIREMENTS The training program is designed to train experienced EDT operations personnel, site supervisory personnel, and other site staff in the specific operational characteristics, processes, maintenance, and systems management necessary to conduct safe and secure Detonation of Ammunition in a Vacuum Integrated Chamber (DAVINCIP'^) EDT operations in a chemical surety program. This will be completed using a combination of classroom instruction and closely supervised on-the-job training (OJT). The program provides for initial training for the operators; it does not address recurring training, since the project is expected to be of short duration. However, this plan can be modified to include post-processing review training and ongoing training requirements if, after the initial scope of work is completed, additional processing becomes necessary. The EDT-specific training locations will be at the existing ECBC CBARR training facility in Edgewood, Maryland, at the TOCDF EDT site, and at contractor-provided classroom areas, which will be provided by EG&G. Included in the training are assessments of each individual's skill and knowledge to determine that the training program objectives have been met. In addition, this training plan provides for the recording and documentation of training to meet vendor EDT requirements. The plan and subcontractor training records are maintained and available at the EDT Control Room on the DCD EDT site. 2.1 EDT Process Training 2.1.1 Statement of Purpose The purpose of this traimng is to instruct operations supervisors, engineering and maintenance personnel, and system operators in the operating principles ofthe DAVINCIF^ and the specific procedures for its safe and efficient operation. General areas covered include operation, maintenance, monitoring, and engineering concepts related to the operators. The DAVINCH'^'" controlled detonation chamber system is sufficiently different from other systems with which operators may have had some experience, so an understanding of operational principles and salient differences is important. The DAVINCH™ System is extensively monitored in real time for chamber and system mechanical integrity, emission of detonation product gases, and destruction removal efficiency of chemical warfare agents. As safety is of paramount concern, part of the training will be dedicated to understanding and interpreting any indication of an upset condition and instructing how to respond quickly and efficiently to such indicators. 2.1.2 Process Overview and Training Objectives The DAVINCH^" system operation is staffed with operators, monitoring technicians, and supervisory personnel. Objectives are identified as: • D - DCD specific training, OSHA, and site access training; • C - CPRP Training; • A - Ammunition and Explosives Handling; and • O - Operations-ZD AVINCH™-specific training, as noted on Figure 1. Overpacked chemical munitions (CSM) are received at the Unpack Area of the EDT site. Trained operators will establish a Temporary Chemical Exclusion Area (T-CEA), clear the box tmck used to transport the munitions using a Miniature Chemical Agent Monitoring System (MINICAMS'^") to ensure safe first entry into the truck. A forklift-trained operator with ammunition training, CPRP certifications, and OSHA training, wearing appropriate Personal Protective Equipment (PPE), moves the pallet or box containing the overpacked munitions (or samples) to the Unpack Area. There, a team of two operators, one operating the forklift and the other a safety/surety observer, will move the overpacked munitions to the Preparation Area. This will require that these operators have site-specific safety training, CPRP, OSHA, and ammunition-handling/explosives training, as well as training on the specifics of installing the charges. In the preparation area, munitions will be removed from the transport box by a lifter. The two operators will install the linear shaped charges (LSC), donor charges, detonators, and detonation cord on the munition. These operators will be required to have site-specific safety training, CPRP, OSHA, and ammunition-handling/explosives training, as well as training on the specifics of installing the charges. After configuring the munition with the charges, operators will move it to the EDT containment area on a cart. The operators will then raise the explosive-configured munition to the level ofthe movable platform. This will require that these operators have site-specific safety training, CPRP, OSHA, and ammunition handling/explosives training, as well as training on the specifics of lifting the configured munition. The entry into the chamber will be a confined-space entry, so OSHA confined-space entry requirements for training will be met. Two operators will enter the chamber, after the exhaust of the chamber downstream from the particle filter has been monitored clear by MINICAMS™, for safe first entry. The lifting cart will be positioned on the movable platform by the operators. Three operators will participate in the entry process: two for entry and one for safety monitoring during the confined space entry. One operator will operate the movable platform in full view of the two operators standing adjacent to the platform at the level of the chamber entrance. Once the munition and lifting cart have been moved into the chamber, the operator will lift the configured munition until it is horizontally level within the chamber near the top. At that point, an operator will hand-configure the hanging slings to allow the munition to hang in place. Specific training will be required for that process. Mine CiP Miiiiilioii- lo Proi;e--iiie .\ren T<y. D. .\.L. <i lii-lall LSC ainl Donor Cliaree TO: D. .A. L. n Fir-1 Eiilr\ Clearance vv i MINlC.\MSTw T<y. D.L.ii Mo\e Donor cTiaree ainl LSC from Da\ Box T<y. D. .A. L. <i Mo\ e Donor- con lien reil EDT |)rocer:r:ine iireii T<1: D. .A. L.il Sel ilelonalor vv irins T<y. D. .\.L. <i Li|)erale D.WINCHTw Cliaiiil>er TCI: D. .\. C. Ci E-lal>li-li TE.\. Conlrol Room CT)eralion- T<y. D. .A. L. <i LT)en Cliaiiil>er Door Renio\e Scra|) (Maenel) T<y. D. .A. ( Fir-1 Enlr\ Clearance vv iili MINlC.\MSTw ainl Conllneil S|)ace Ci\er-ielil T<y. D.L.ii Mo\e Scra|) lo Wa-le Proce--ine .\rea T<y. D.L.ii Traii-I'er Scra|) lo Wa-le Drum- T<y. D.L.ii Wa-1e Clearance vv iili \nNlC.\MSTw T<1: D.L.ii Per-onnel Deconlaininalion T<y. D. .A. L. <i Training (!)biecti\es D- DCD site training. OSH.A. ani-l baseline training .A- .Ammunition E.xpli')si\e C- CPRP O- Operations DA\TNCHTM Figure 1. Process Overview and Training Objectives for Operators •After hanging the munition in the chamber, a trainei-l operator will test the continuity' of the i-letonation cable pass-through, ani-l ensure that the leai-ls are shortei-l at the EDT Control Room. W hen coinpletei-l. a public ai-klress system (P.A) will be usei-l to relay this infonnation to the EDT Control Room. Once that is \ alii-latei-l as safe, the operator will connect the i-letonation cori-l chain to the leai-ls at the pass-through ani-l then e.xit the chamber. The ino\ able platfonn will be wilhi-lrawn by the operators. These operators will obser\e the closure ofthe chamber \k\ ani-l then e.xit the En\ ironinental Enclosure through the personnel i-lecontain ination area. The operators in the Control Room will \ alii-Late that the chamber is clear of personnel ani-l ei-|uipinent prior to closing the lii-l. Once the \k\ is closei-l. the Temporaiy E.xclusion .Area (TE.A) is inaintainei-l at the perimeter ofthe main enclosure, ani-l i-loor guari-ls are postei-l at the control- point i-loor. The EDT will then cycle through its process of e\acuation. stabilization, ani-l correct pressure \ acuuin setting, .lust prior to i-letonation sei-|uencing. the EDT control operators will test the continuity ofthe e.xplosi\e leai-l circuit ani-l attach the i-letonation trigger mechanism. Once clear, the EDT operators will initiate the i-letonation sei-|uence. ensuring safe position ani-l accountability for all operators. obser\ ers. ani-l other staff. The EDT Control Room will perfonn the necessaiy pre-i-letonation checks. Once all checks ha\ e been clearei-l. the EDT Site Manager or i-lesignee will then ini-licate that the i-letonation will occur. The P.A system will be usei-l to pro\ ii-le \ arious warnings, followei-l by a counti-lown ani-l i-letonation. Once the chamber has completely cyclei-l through its process, three operators will enter the EDT containment area in PPE. .A magnet system will be usei-l to reino\ e ferrous metal fragments. Two more operators will then enter the chamber after the interior ofthe chamber has been i-letenninei-l to be safe to enter basei-l on MTNIC.AMS'''" results obtainei-l from a sampling location that is i-lownstreain from the particle filter These operators will manually reino\ e any remaining waste that might be iinpeeling the operation. Waste materials will be transferrei-l by operators in PPE to the waste container in the chamber area, ani-l a trainei-l operator will ino\ e the waste container to the W aste Processing .Area for heai-Lspace analysis in i-lruins i-lesignei-l for that purpose, i lie !e •v:il he ^i-raJ (•Jh.-r •All personnel will then e.xit \ ia the conlrol point, ani-l the system can either be shut i-lown for maintenance, or the process can begin for the ne.xt shot. .A ina.xiinuin of se\ en shots per i-Lay can be accoinplishei-l. 2.2 Job Titles and Dulles Training courses are to be hekl for the following i-lifferent le\ els of personnel, basei-l on their assignments ani-l responsibilities, as notei-l in the following paragraphs ani-l Figure 2. The on-site organization and training objectives will consist of categories identified in Table Ijpelow. As shown in the table, the plan includes four leye^^ the different assignments of personnel as follows. • Supervisor Course for the supervisory and engineering personnel, including the Site Manager, and Health and Safety (H&S)/Explosive Safety Manager. • EDT Operator Course for the ECBC CPRP Site Supervisor, ECBC CPRP operators, and ECBC CPRP Control Room Operators. • EDT Familiarization Course for Monitoring personnel and site personnel who do not handle munitions, operate controls, or perform chemical duties. Deleted: above EG&G Project Manager (Versar) *High Level *High Level Safety Manager (Explosive, Environmental) /Vers| *TT: -1. T f Site Manager (Kobe Steel) Shift Supervisor (Kobe Steel) Site Manager (ECBC) *MediumLevel CPRP Control Room Safety (E GB C) *Mediiim Level A (ECBC) B (ECBC) C (ECBC) Analysis/Monitoring Sampling *Mediiim Level Same personal as site manager and safety (ECBC) *Low Level Each team consists of two persons *Analysis Specialist (ECBC) Figure 2. EDT Operational Organization Site-Specific Training for all on-site personnel as described in Section 3.0. Licluded will be site- 7 specific training for the unique aspects ofthe EDT as implemented on the TOCDF site, including chemical-area-specific training, door guarding, escorting, RCRA Class III Permit modification and Air Pennit modification instruction, and training on hazardous waste management requirements unique to the State of Utah in regards to the treatment of chemical agents. This training will be developed by EG&G. Table 1. EDT Site Operational Training Objectives/Training Levels Organizational Element Role EDT Training Objective Site Manager Responsible for site operations, management of on-site activity, and liaison with EG&G operations • EDT Supervisor Course • Site-Specific Training • D,0 H&S/Explosive Safety Manager Responsible for implementing H&S plan, chemical safety, and explosive safety oversight; liaison with Versar© and Kobe Steel site personnel • EDT Supervisor Course • Site-Specific Training • D, A, 0 ECBC Site Supervisor (CPRP) Responsible for operations mgmt for EDT, supervises operators, ensures safety. Liaison with Versar© and Kobe Steel site personnel • EDT Supervisor Course • EDT Operator Course • Site-Specific Training • Escort Training • D, A, C, 0 ECBC Site Safety Supervisor (CPRP) Oversees and supervises operational safety of EDT operations process • EDT Operator Course • Site-Specific Training • Escort Training • D, A, C, 0 ECBC Operators (CPRP) Munitions handling, explosive placement, waste removal, maintenance support, control room ops • EDT Operator Course • Site-Specific Training • Escort Training • D, A, C, 0 ECBCJVIonitoring • EDT Familiarization Course Personnel (CPRP) Monitormg" • "Site-Specifio Training | • Escort Training • D,0 Training Objectives D- DCD site training, OSHA, baseline training A- Ammunition/Explosive C-CPRP O- Operations/DAVINCH™ Deleted: and Contractor ^s slKmpi in Table 1 . the plan includes three kyels of jraming. each optimized for the different assignments of personnel as follows. • High level course for the engineering personnel: two persons (Versar; project manager and safetv manager). • Medium level course for supervising personnel: two persons (site manager and safety) • Low level course for operating personnel: 6 persons-ff)T operators _ • Monitoring and analyst personnel: Monitoring personnel are assumed to have sampling and analysis training and experience will be assigned, therefore, no additional fomial training is necessarv beyond baseline TOCDF/DCD site training requirements, and proficiency on the instmmentation and processes used during monitoring. Site Specific Training: Section 3.0 identifies site-specific training requirements for all on-site personnel. 2.3 EDT-Specific Training Content, Frequency, and Techniques 2.3.1 Classroom Training Modules The content ofthe Supervisor, EDT Operator, and Familiarization classroom training modules is presented in Table 2. These are the currently contemplated subject areas for instruction, but may be augmented as the scheduled training draws nearer. Formatted: Font: (Default) Times New Roman Formatted: Bullets and Numbering Formatted: Font: (Default) Times New Roman Table 2 - Training Curriculum for Classroom Lectures Course Curriculum Material/Duration • Supervisory • Familiarization General • Equipment • Plant Layout • Operational Overview • General Safety and Surety Overview Design Documents (High: 2 days. Medium: 1 day) • Supervisory Safety Management • Controlled Area • Safety Analysis • Risk Assessment • Donor Explosive Characteristics Design Documents (1 day) MAXAM brief • Supervisory • EDT Operators Operation Procedures • Division of Work on Site • Standard Operation Procedures • Starmp and Shutdown • DCS • DESTEslY • GRAND User Manual (1 day) Course Curriculum Material/Duration EDT Safety • Hazards of Chemical Agent (Area) User Manual (Iday) • EDT Operators • Hazards of Explosion/Gas Leaks • Donor Explosive Handling and Storage User Manual (Iday) Maintenance • EDT Operators • Where and how to check the EDT conditions/PM schedule • Dust and Liquid/Drain Removal Design Documents (Iday) • Supervisory • EDT Operators • Familiarization Course • Agent Analysis & Monitoring • Request for Analysis & Monitoring Sampling Method Paper (Iday) 2.3 .1.1 Classroom Training Duration The Supervisor Course will require 1.5 weeks for completion, and the medium-level course duration is 1 week. The training will include classroom lectures augmented by audio/visual aids of actual ongoing operations at DAVINCff'^ operational sites at Kanda Harbor, Japan, and Poelkapelle, Belgium. Additionally, the trainees will be introduced to the real-time network of shared experience documentation from the Kanda and Poelkapelle operations, available through the intemet [Distributed Control System (DCS), DESTINY, GRAND]. 2.3 .1.2 Classroom Training Location A fiilly-equipped classroom is available at the CBARR facility in Edgewood, Maryland. The classroom has audio-visual and presentation support, and it is adjacent to the CBARR warehouse and storage areas for hands-on demonstration. Kobe Steel and Versar© instructors will travel to ECBC to conduct the initial training for high, medium, and low classroom modules. A similar requirement for classroom training will be coordinated as needed at TOCDF to augment the initial training. 2.3.2 EDT On-Site/OJT Supervised OFT will follow the classroom training modules at ECBC. For this requirement, the curriculum items in Table 3 will be used for the training process. The EDT Operator course will require two weeks for completion during system familiarization/systemization. Versar© and Kobe Steel instructors will travel to TOCDF to conduct the initial OJT. A suitable classroom will be available for lectures. The OJT will take place at the EDT site in Area 10. 2.4 EDT-Specific Training Materials The training staff from Versar© and Kobe Steel will develop, produce, and deliver training materials and documentation as shown in Table 4. These materials will consist of presentations 10 in PowerPoint; video presentations of specific operational overviews from the operational sites at Kanda Harbor, Japan, and Poelkapelle, Belgium; engineering documentation and manuals: flow charts and process flow diagrams; plans and procedures; and related materials. These materials will be distributed to the operators as necessary, and copies ofthe material will also be retained on-site in the Control Room/break room areas for easy reference. The site will also be the repository for the training certifications and required forms and, for TOCDF access, the required training proficiency forms and training materials described below. All of the training materials will be reviewed and approved by the technical staff of Kobe Steel, and will be provided to EG&G for review and approval. This will ensure integration with the EG&G Training Manager's ongoing programs. Any proposed modification to the training curriculum will be reviewed and approved by EG&G before implementation. Table 3 Training Curriculum for On-Site Training Course OJT Curriculum Material/Duration • Supervisory • EDT Operator • Familiarization General (Lecture) • General Information of System • Introduction Videos • Layout/Process/Equipment Design Documents (0.3 day) • Supervisory • EDT Operator • Familiarization EDT Specific Site Safety (Lecture) Paper (0.3 day) • Supervisory • EDT Operator • Familiarization Site Tour (Site) (0.3 day) • Supervisory • EDT Operator Operation Procedure (Lecture) • Work of Low-Level Operator • Safety Education for Explosive • Key Points of HE/CA Destruction • Key Points of Donor Charge Setting Paper (0.5 day) • EDT Operator In-Service Training (Time Trial with PPE, Site) • Preparation for Donor Charge • Setting Donor Charge on Overpack Overpacks and simulated donor charge (3.5 days) • EDT Operator On site Training (Site) • Off-Controlled Area Preparation • Controlled Area Preparation • Handling System Operation (3 days) 11 Course OJT Curriculum Material/Duration • Daily Check/Maintenance All Joint Training with other operating levels (Site) (2 days) 12 Table 4 - Training Materials Item Course Operators and Trainers Presentation • Supervisory • EDT Operator • Familiarization Kanda Video • Supervisory • EDT Operator • Familiarization Belgium Video • Supervisory • EDT Operator • Familiarization Process Flow Diagram • Supervisory • EDT Operator • Familiarization Assembly Drawing of EDT • Supervisory • EDT Operator • Familiarization General Plot Plan • Supervisory • EDT Operator • Familiarization Operation Flow Chart • Supervisory • EDT Operator User Manual • Supervisory • EDT Operator User Manual for DCS • Supervisory • EDT Operator Piping & Instrumentation Diagram • Supervisory • EDT Operator Key Points • Supervisory • EDT Operator Troubleshooting Guide • EDT Operator User Manual for DESTINY • EDT Operator User Manual for GRAND • EDT Operator Maintenance Manual • EDT Operator Daily Check List • Supervisory • EDT Operator Procedure of Startup and Shutdown • Supervisory • EDT Operator Understanding the Donor Explosive/MSDS • Supervisory • EDT Operator • Familiarization 13 2.5 Trahiiiig Staff •A Training Super\ isor. will be assignei.1 lo coori-linale ani.1 manage the training program lor the EDT Team. The Training slalT will inclutle engineering ani.1 operational specialists with experience al both Kantla Harbor, .lapan. ani.1 Poelkapelle. Belgium. These trainers will ha\ e an e.\cellenl commani.1 ol" English lo minimize any communication issues between trainers ani.1 slui-lenls. The training slalThas experience in i.le\ eloping ani.1 implementing training for operators from the Belgian Minisliy of Defense ani.1 for the Kobe Steel slalT in .lapan. These e.\periencei.l trainers will be a\ ailable (.luring the training process for ini.li\ ii.lual consultation ani.1 coaching shouki that be necessary. E.\ample resumes ofthe training staff are pro\ii.lei.l in .Appeni.li.\ 2. The sample resumes ii.lenlify the type ani.1 le\ el of personnel a\ ailable from \'ersariCi ani.1 Kobe Steel lo contlucl the training process. 14 3.0 SITE-SPECIFIC TRAINING REQllREMENTS The training program for EDT will be reviewed with the TOCDF Training Manager to ensure that site conditions, requirements for site-specific training, and permit requirements are met. Versar© will ensure that all operators and on-site personnel complete required training at TOCDF in accordance with the SOW Appendix E, Training and Certification Requirements. The Versar© Training Supervisor will perform an analysis of each employee's training status. This will ensure that any gaps in training are identified and scheduled to ensure operations are not affected. 3.1 Chemical Site-Specific Training Requirements In addition to the EDT-specific training described in Section 2.0, all site personnel must be trained in requirements listed in the following documents: • AR 190-59, Chemical Agent Security Program; • AR 50-6, Chemical Surety; • System Contractor Surety Project Regulatory Procedure (PRP-SR)-002; • PRP-SE-006, Chemical Personnel Reliability & UAP [i.e., Unescorted Access] Program; • Chemical Limited Area (CLA) and Chemical Exclusion Area (CEA) Access Controls and Management PRP-MG-24, TOCDF Badging Process; and • The draft Memorandum of Agreement (MOA) or equivalent for maintaining CPRP compliance with AR50-6. The site contractor Surety department will provide the training for the areas listed below, subsequent to DCD in-processing. Two days will be required for this training, which will be provided on-site at TOCDF/DCD. 3.1.1 CEA Door Guard Training Course This course provides the trainee with information for performance as a CEA Door Guard. Upon completion of this training, the trainee will be able to: • Discuss key words and definitions. • Describe the Duress System, including the rules, and how and when it is used. • Describe the general and special CEA Door Guard requirements and responsibilities. • Describe the process for maintaining security of a CEA Door in "Access" during an emergency/exercise. • Discuss previous CEA Door Guard violations and noncompliances 3.1.2 Escort Training Course Upon completion of this presentation, the trainee will be able to: . Differentiate between a CLA, CEA, and T-CEA. • Describe the Duress System and how to use it. 15 • Identify the level of authorization indicated by a proximity badge (CLA, CEA, T-CEA, escort/no-escort required). • Identify the basic elements ofthe escort process for UA and CPRP. • Describe the steps in preparing, entering/exiting, and managing escorted person(s) in a CLA, CEA and T-CEA. • Understand the requirements ofthe "Checklist for Escorting" and Lessons Learned. 3.1.3 Site-Specific Briefings These briefings will address: • Specific security protocol for entering the Area 10 CLA and conducting operations during and after normal operating hours. Tour Area 10 as required. • MOA or equivalent for CPRP-certified workers. • CPRP medical support. • Specific requirements associated with the TOCDF RCRA and Air Pemiit requirements. _ , - j Deleted: EDTRCRA CLASS m This will include: Penmt modification • A discussion on the State of Utah hazardous waste codes unique to chemical agent and their treatment residues, P999 and F999, respectively. • A discussion on what the reportable spill quantity is for agent (any spill) and agent treatment residues (1 kilogram). • A discussion on what the different alarm tones mean, and the muster points and evacuation routes applicable to the DAVINCH™ site. • Operator familiarization with hazardous waste generator waste management requirements (e.g., satellite accumulation points, 90-day storage) from OSHA and RCRA training. 3.2 Other Site-Required Training Table 5 provides an overview ofthe Site Training Program for the personnel assigned to the EDT program. The requirements for each position will be analyzed for applicability ofthe following courses, specifically, those involved with Competent Person training. As stated above, the gap analysis conducted by the Training Supervisor will establish training requirements for individual staff members prior to operations. Exhibits 1 and 2 to Appendix E are presented below. Each employee will have the appropriate training documented on these forms, which will be provided to EG&G prior to operations. These forms will be used to document and substantiate the training for the EDT team. 16 Table 5 - Site-Specific Training No. Req'int Training EDT Training Objecti\ e T-: :9CFR1 910.1:()( q X6Xi) OSHA RCRA .Aw areness Training: .A certificate of completion from a i.|ualifiei.l course for each \'ersar:0 Team employee. .As statei.1 in .Appeni.li.\ C. all \'ersar:0 Team personnel recei\ ing (!)ne-\ear Temporar\' or Permanent batlges must complete an S-hour training class to fulfill the rei.|uirements of 29CFR1 91 (). 1 2()(pXSXiii) and (qX^^Ki)- This OSH.A .Awareness le\el training may be accompiishei.1 \ia an\' training course which satisfies the specifiei.1 (!)SH.A regulations. \'ersar:0 Team personnel shall submit tlocumentation which shows the\' ha\e hai.1 the rei.|uirei.l training w ithin the last 1 2 months. The Subcontractor shall take refresher training as rei.|uirei.l (.luring the performance of this contract to ensure that a 12 month perio(.l (.loes not lapse since the Subcontractor last complete(.l the training class. Personnel who (.lo not ha\e this training will be enrolled in EG&G HAZCOM CPRFA. and or SORT-R T-3 29CFR1 910.12()( pX^Xi) OSHA RCRA (!)perations Training: .A certificate of completion from a (.|ualiJle(.l course for each \'ersar:0 Team emplo\ee. In accor(.lance w ith 29CFR1 91 o. 1 2o(p)(7)(i). emplo\ ees e.\pose(.l to health hazar(.ls or hazar(.lous substances must recei\ e 24 hours of training to enable them to perform their assigne(.l (.luties an(.l functions in a safe an(.l healthful manner so as not to en(.langer themsekes or other emplo\ ees. This (!)SH.A (!)perations le\el training ma\' be accomplishe(.l \ ia an\' training course w hich satisfies the specil1e(.l (!)SH.A regulations. \'ersar:0 Team personnel shall submit (.locumentation w hich show s the\' ha\ e ha(.l the re(.|uire(.l training w ithin the last 1 2 months. The Personnel shall take refresher training as re(.|uire(.l (.luring the performance of this contract to ensure that a 1 2 month perio(.l (.loes not lapse since the Personnel last complete(.l the training class. EG&G S(!)RT-(!) ma\' be use(.l for this training. T-4 29CFR1 910. 29CFR1 926 Competent Person: .A complete(.l Competent Person Form (Training .Appen(.li.\ E.\hibit 1) for each in(.li\i(.lual (.lesignate(.l by the Subcontractor to perform the specil'ie(.l acti\ ities. (!)SH.A regulations re(.|uire that the Subcontractor ha\ e a "Competent Person" perform \arious acti\ities relate(.l to the safe e.\ecution of work acti\ities. \'ersar:0 w ill complete an(.l submit a complete(.l Competent Persons Form (•E.\hibit 1 to the S(!)\\' .Appen(.li.\ E) for each person w ho is (.lesignate(.l the Competent Person for the specifie(.l acti\ it>'. \'ersar:0 w ill pro\ i(.le competent or (.lesignate(.l persons as re(.|uire(.l by all (!)SH.A regulations but as a minimum shall pro\i(.le competent persons for the follow ing areas of competence as re(.|uire(.l by the Tasking: a. Asbestos - 1926.1 lol b. Oanes - 191o.l79. 191o.lSo: 1926.550: 1926.753 c. Material Personnel Hoists - 1926.552 d. Demolition - 1926.S5o. S52. S5S. S59 1 7 No. Req'int Training EDT Training Objecti\e m. n. o. P- Scaffolding - 1926.45o. 451. 454 Electrical - 1926.4o4 Ladders - 1926.1o53. 1 060 Fall Protection - 1926.5oo. 5o2. 5o3. 1 060 Slings & Rigging - 191o. 1S4: 1926.251 Lead - 1926.rS2^ Welding Cutting - 1910.253. 2.^4. 255: 1926.354 E.\ca\ ations Trenches - 1926.65o. 651. 652 Compressed .Air - 1926.So3 Ionizing Radiation - 1926.53: 191o. 1()96 Cadmium - 1926.1 127 General Health & Saler\- - 1926.2o T-5 29C 910, 0 FRl Hazards Communication: .A complete(.l Training Form (Training .Appen(.li.\ E.\hibit 2) for each Subcontractor an(.l Sub-tier Subcontractor emplo\ee. 29CFR1 91 o. 1 2oo man(.lates that the Subcontractor estabi ish a comprehensi\ e Hazar(.l Communication Program, w hich inclu(.les container labeling an(.l other forms of w arning. material salet>' (.lata sheets an(.l emplo\ee training. \'ersar:0 w ill submit a complete(.l Subcontractor Training Form ( E.xhibit 2) for each Subcontractor an(.l Sub-tier Subcontractor emplo\ ee. T-6 29C 910. 29C 926. •)('6) FRl 146. FRl 21(b Conlme(.l Space Training: .A complete(.l Subcontractor Training Form (Training .Appen(.li.\ E.\hibit 2) for each applicable Subcontractor an(.l Sub-tier OSLLA regulations 29(TR 191 o. 146 and 29(TR 1926.21 ( bX6) require that all emplovees re(.|uire(.l to enter into corUlne(.l or enclose(.l spaces shall be instructe(.l as to the nature ofthe hazar(.ls in\dKe(.l. the necessar\' precautions to be taken. an(.l in the use of protecti\ e an(.l emergenc\' e(.|uipment re(.|uire(.l. The Subcontractor shall submit a complete(.l Subcontractor Training form (•E.\hibit 2 to this .Appen(.li.\) for each Subcontractor an(.l Sub- tier Subcontractor emplo\ ee re(.|uire(.l to ha\e this training. The CorUlne(.l Space course olTere(.l by EG&G w ill be use(.l to accomplish this re(.|uirement for operators not \ et certifie(.l. No. Req'int Training EDT Training Objecti\e Subcontractor emplo\ee. T-7 29(TR 1 91o.l7S( Forklift Training: .A complete(.l Subcontractor Training Form (Training .Appen(.li.\ E.\hibit 2) for each applicable Subcontractor an(.l Sub-tier Subcontractor emplo\ee. OSH.A regulation 29CFR 191o. 1 7S(I) requires that ihc Subcontractor shall ensure that each powere(.l in(.lustrial truck operator is competent to operate a powere(.l in(.lustrial truck safelw as (.lemonstrate(.l by the successful completion ofthe training an(.l e\aluation specifie(.l. The Subcontractor shall maintain recor(.ls w hich (.locument the training for each in(.li\ i(.lual (.lesignate(.l to operate a forklift. The Subcontractor shall submit a complete(.l Subcontractor Training form ( E.xhibit 2 to this .Appen(.li.\) for each Subcontractor an(.l Sub-tier Subcontractor emplo\ ee re(.|uire(.l to ha\e this training. The Forklift Training course olTere(.l by EG&G w ill be use(.l to accomplish this re(.|uirement for operators not \ et certifie(.l. T-S 29(TR 1 910.147 Lockout Tagout Training: .A complete(.l Subcontractor Training Form (Training .Appen(.li.\ E.\hibit 2) for each applicable Subcontractor an(.l Sub-tier Subcontractor emplo\ee. (!)SH.A regulation 29CFR 191 o. 147 re(.|uires Subcontractors to establish a program an(.l utilize proce(.lures for airi.\ing appropriate lockout (.le\ ices or tagout (.le\ ices to energ\' isolating (.le\ ices. an(.l to otherw ise (.lisable machines or e(.|uipment to pre\ent une.\pecte(.l energization, start-up or release of store(.l energ\' in or(.ler to pre\ ent injurx' to emplo\ ees. It further re(.|uires that the Subcontractor shall pro\ i(.le training to ensure that the puqiose an(.l function ofthe energ\' control program are un(.lerstoo(.l by emplo\ees an(.l that the know le(.lge an(.l skills re(.|uire(.l for the safe application, usage. an(.l remo\al ofthe energ\' controls are ac(.|uire(.l by emplo\ ees. The Subcontractor shall maintain recor(.ls w hich (.locument the training for each in(.li\ i(.lual (.lesignate(.l to perform these acti\ ities. The Subcontractor shall submit a complete(.l Subcontractor Training form ( E.xhibit 2 to this .Appen(.li.\) for each Subcontractor an(.l Sub-tier Subcontractor emplo\ ee re(.|uire(.l to ha\e this training. The Lockout Tagout course oirere(.l by EG&G w ill be use(.l to accomplish this re(.|uirement for operators not \ et certil'ie(.l. T-9 29(TR 1 926.503 Fall Protection Training: .A complete(.l Subcontractor Training Form (Training .Appen(.li.\ (!)SH.A regulation 29CFR 1926.5o3 re(.|uires that the Subcontractor shall pro\ i(.le a training program for each emplo\ ee w ho might be e.\pose(.l to fall hazar(.ls. The program shall enable each emplo\ ee to recognize the hazar(.ls of falling an(.l shall train each emplo\ ee in the proce(.lures to be followe(.l in or(.ler to minimize these hazar(.ls. The Subcontractor shall maintain recor(.ls w hich (.locument the training for each in(.li\ i(.lual (.lesignate(.l to perform these acti\ ities. The Subcontractor shall submit a complete(.l Subcontractor Training form No. Req^int Training EDT Training Objecti\e E.\hibit 2) for each applicable Subcontractor an(.l Sub-tier Subcontractor emplo\ee. (•E.\hibit 2 to this .Appen(.li.\) for each Subcontractor an(.l Sub-tier Subcontractor emplo\ee re(.|uire(.l to ha\e this training. The EG&G Fall Protection Course w ill be use(.l to accomplish this re(.|uirement for operators not\ et certifie(.l. T-1 1 29(TR 1 910.134 Respirator\' Protection: .A complete(.l Subcontractor Training Form (Training .Appen(.li.\ E.\hibit 2) for each applicable Subcontractor an(.l Sub-tier Subcontractor emplo\ee. 29CFR1 91 o. 134 man(.lates that emplo\ers re(.|uiring their emplo\ees to wear respirator\' protection (.le\elop an(.l establish a written Respirator\' Protection Program. The program shall inclu(.le me(.lical screening. pulmonar\' function test (PFT). training. an(.l fit testing. The Subcontractor is re(.|uire(.l to maintain recor(.ls which (.locument all (!)SH.A re(.|uire(.l acti\ities. The Subcontractor shall submit a complete(.l Subcontractor Training form (E.xhibit 2 to this .Appen(.li.\) for each Subcontractor an(.l Sub-tier Subcontractor emplo\ee re(.|uire(.l to ha\e this training. Subcontractors performing tasks w hich re(.|uire respirator\' protection shall suppl\' respirators for their personnel. T-1 2 29(TR 1 910.332 Electrical Training: .A complete(.l Subcontractor Training Form (Training .Appen(.li.\ E.\hibit 2) for each applicable Subcontractor an(.l Sub-tier Subcontractor emplo\ee. 29CFR1 91 0.332 re(.|uires emplo\ ees shall be traine(.l in an(.l familiar w ith the salet> -relate(.l work practices required by 191o.331 through 1910.335 and NFP.A 7oE. "Electrical Salet>- Re(.|uirements for Emplo\ ee Workplaces" that pertain to their respecti\ e job assignments. The Subcontractor shall ensure that all Subcontractor an(.l Sub-tier Subcontractor emplo\ ees ha\ e ha(.l the re(.|uire(.l training. The Subcontractor shall submit a complete(.l Subcontractor Training form (•E.\hibit 2 to this .Appen(.li.\) for each Subcontractor an(.l Sub- tier Subcontractor emplo\ ee re(.|uire(.l to ha\e this training. T-13 29(TR 1 926.1 lo .A complete(.l Subcontractor Training Form 29CFR1 926.1 lol re(.|uires that emplo\ees shall be traine(.l in an(.l familiar w ith the hazar(.ls associate(.l with asbestos an(.l the specific proce(.lures implemente(.l to protect emplo\ees from e.\posure to asbestos, such as appropriate work practices. emergenc\' an(.l clean-up No. Req'int Training EDT Training Objecti\e (Training .Appen(.li.\ E.\hibit 2) for each applicable Subcontractor an(.l Sub-tier Subcontractor emplo\ee. proce(.lures. an(.l personal protecti\e e(.|uipment to be use(.l. The Subcontractor shall ensure that all Subcontractor an(.l Sub-tier Subcontractor emplo\ees ha\e ha(.l the re(.|uire(.l training. The Subcontractor shall submit a complete(.l Subcontractor Training form (E.xhibit 2 to this .Appen(.li.\) for each Subcontractor an(.l Sub-tier Subcontractor emplo\ee re(.|uire(.l to ha\e this training. Tniiiiiiig .Appendix Exiiibit 1 C'oiiipeteiit/Designiited Pei'soii .Ackiio>vledgeiiieiit Foi'iii Definition .A (;'oiii|)eleiil or De-ieimled Per-oii i- n per-oii vvlio lin- llie nhilih. niid Irniiiiiie lo recoaiize liaznrd- niid llie nulliorih. lo correcl llieiii. Responsibility The de-iainled (;'oiii|)eleiil De-ieimled Per-oii i- re-poii-ihle I'or recoeiiiziiie niid correcl iiie -;il'el> liaznrd-. Tlii- per-oii I in- llie nulliorih. lo -lop vvork in llie e\eiil ol'mii. poleiMini -nl'eh. concern on llie.ioh -ile. Tlii- rei)re-eiilnli\e i- coii-idered llie coiilnci per-oii I'or EG.^G Mniineeiiieiil on -nl'eh.-relnled i"Ue- mid -I ml I he on—ile vvlieiie\er llie .Aren or(;'oiii|)eleiic\ i- iii\ol\ ed vviili llie proiecl. Tlii- I'onii iiiu-l he coiiipleled h\ llie Suhcoiilrnclor niid llie Suhcoiilrnclor"- de-ieiinled (;'oiii|)eleiil Per-oiii-1. Where n Suhcoiilrnclor i- re-poii-ihie I'or -uh-lier Suhcoiilrnclor-. il i- iiece"nn. lo iiiniiilniii nddilioiinl de-ieiinled (;'oiii|)eleiil Per-oii- mid Ton 11- I'or encli nddilioiinl I ier. &ncli Suhcoiilrnclor iiiu-l -uhiiiil llii- coiiipleled I'onii prior I o heeiiuiiiie mi\ vvork on llie proiecl niid iiiii-l iipdnle il mi> lime lliere i- n dim ice in llie de-i&iinled repre-eiilnli\ e(-i. Supervisor Acknowledgement repre-eiiliiie lin\ e n"ieiied llie helovv li-ied per-oiuiel Io he llie (;'oiiipeleiil De-ieiinled Per-oiii-i iii llie nren- iiidicnied. I nckiiovv ledee llinl II iiidi\ idiinl I in- heeii lliorouelil\ Imiiied ni id i- experienced in I inznrd recoaiil ion. He -he I in- nulliorih. lo -lop vvork mid correcl linznrd- in llie e\eiil ol'n poleiilinll> linznrdoii- -iliinlioii- or iiiuiiiiieiil dmicer Competent/Designated Person(s) Acknowledgement livvei. llie 111ider-ialed iiidi\ idunli-i. nckiiovv ledee llinl livvei lin\ e heeii ihoroueliK Irniiied mid lin\e experience Io perl'onii llie dulie- n- n (;'oiiipeleiil De-ieiinled Per-oii in llie nreni-i iiidicnied helovv. Iivvei uiider-lmid llinl livvei lin\ e llie re-poii-ihilih. niid nulliorih. lo correcl linznrd- mid -lop vvork iii llie e\ eiil orpoleiilinll\ linznrdou- -ilunlioii- or iiiuiiiiieiil dniieer: -IJVI; of i.'oiiipfifiicy n. .A-he-lo-|c:().l liil 1. SliiiQ- Ricciiic icMi.m: ic:().:.';i h. (;'rmie-ICMi.rc: ICMi.lSii. 1 1. ic:().".';.^ i. Lend ic: ().(>: c. Mnlerinl Per-oiuiel Hoi-I-k. Weldiiie (;'ulliiie ichi.i'^.vi'^-i.:.';.';: ic:()..v';-i d. Deiiiolilioii ic:().s.';(i. s.'^:. s.'^s. s.'^c 1. Excn\nlioii- Treiiclie-|c:().().';(i. h.'^l. (1^2 e. ScniVoldiiie IcZh.-l.'^ii.-l.'^l. -I.'^-I III. (;'oiiipre"ed .Air ic:().S( i.i r. Eleclricnl ic:().-hM II. loiiiziiic Rndinlioii ic:()..';.v ichi.hi% e. Lndder-1 (iZh. 1 n.";.;. i(i()(i 0. (^'ndiiiiiuii ic:(). 112" li. Fnll Proleclioii 1 <'2()..''n(i. ^{\2. .''H.v |(i()(i p. GeiiernI Snl'el\ Henllli ic:().:(i C'oiiipeleiil Person (SieiiHliire) C'oiiipelPiil Person (Priiil Naiiie) .\reH(s) orC'oiiipeleiio (eiiler leller iiiclicHliiic compeleiio) DHle Tniiiiiiig .Appendix Exiiibit 2 Tnilniiis .Acknowledgement Form Requirement The (iccupniioiinl Snl'eh. mid Henllli .Adiiiiiii-lrnlioii K iSKA i reeulnlioii- require llinl eiiiplo\ ee- he Imiiied lo perl'onii cerlniu ncli\ ilie-. Tlii- Irniiline \nrie- dei)eiidiiie on llie ncli\ ih. Soiiieliiiie- n vvrilleii proermii. vvliicli coiiiplelel\ deliiienle- llie proce—e- mid procedure- lo he u-ed I'or llie Irniiline niid le-liiie. i- required. In oilier cn-e-. llie required Irniiiiiie i- luideliiied mid iiin\ -iiiipl\ he \erhnl iii-lniclioii or eii-uriiie llinl vvrilleii iii-lniclioii- lin\ e heeii rend. In -oiiie cn-e-. lliere nre requireiiieiil- lo pro\ ide rel're-her Irniiiiiie iu-unll\ muiunlK i. Responsibility The Suhcoiilrnclor lin- llie re-poii-ihilih. lo he nvvnre ol'nll npplicnhle Irniiiiiie requireiiieiil- -pecilled h\ (iSKA. Furllieniiore. llie Suhcoiilrnclor lin- llie re-poii-ihilih. lo eii-ure llinl llieir eiiiplo\ee- nre nvvnre ol'llie required Irniiiiiie. Iin\e recei\ ed nil ol'lhe required Imiiiiiie. Tlii- include- eii-iiriiie Uml llie Irniiiiiie i- curreiil niid dociuiieiilnlioii ol'lhe Irniiiiiie i- iiiniiilniiied n- required h> llie npplicnhle reeulnlioii. Tlie employee SIIHU IIOI be Hllo»ecl lo per Tor in HII> Hc1i\il> Tor »liicli llie> Imve iiol IIHCI Uie required IrHiiiiiic HIICI IIIHI IrHiiiiiic iiiiisl be nirreiil. Tlii- I'onii iiiu-l he coiiipleled h\ llie Suhcoiilrnclor mid llie Suhcoiilrnclor"- eiiiplo\ee- vvlio vvill he perl'onnine llie ncli\ ilie- I'or vvliicli (iSKA—pecilled Irniiiiiie i- required. Wliere n Suhcoiilrnclor i- re-poii-ihie I'or -uh-lier Suhcoiilrnclor-. llie Suhcoiilrnclor -linll eii-ure llinl nil -ucli -uh-lier Suhcoiilrnclor- mid llieir eiiiplo\ee- coiiiplele llii- I'onii. Encli Suhcoiilrnclor iiiu-l -uhiiiil llii- coiiipleled I'onii prior Io heeiiiiiiiie nin. vvork on llie proiecl: he -he iiiii-l iipdnle il mn. lime lliere i- n climiee in llie per-oiiiiel n"ieiied lo perl'onii llie de-ieiinled In-k-. Supervisor Acknowledgement rei)re-eiiliiie lin\ e n"ieiied llie rollovviiie per-oiiiiel lo perl'onii ncli\ ilie- llinl require -pecilk (iSKA Irniiiiiie in llie nren- iiidicnied. I nckiiovvledee llinl llii- iiidi\ idiinl lin- heeii lliorouelil\ Irniiied in nccordmice vviili Uie requireiiieiil - ol'lhe npplicnhle (iSKA reeulnlioii-. Employee(s) Acknowledgement I ivvei. llie luider-ieiied iiidi\ idunli-i. ncknovv ledee llinl I ivvei lin\e heeii lliorouelil\ Irniiied mid lin\e experience Io perl'onii llie dulie- in llie nren(-i iiidicnied hehm: ^ir<i of Truiiiiiiv Hnznrd- (;'oiiuiiiuiicnlioii |Chi. i:("i T-l 1 Re-pirnlor\ Proleclioii 1 c h 1.1 .^-1 T-() (;'oiiruied Spnce-|CMi.l-l(). |c:().:iihii()i T-i: Eleclricnl |Chi..vi: T--Forklill (ipernlion icMi.rsih. ic:().()(i: T-I.i .A-he-lo-|c:().l Mil T-S Lockoul Tneoul 1 c h 1.1 -1" T-N Lend ic :().(>: T-O Fnll Proleclioii ic:()..';(i.^ T-l.'; (^'ndiiiiiiiii ic:().i 12" T-hi Fir-I .Aid ichi. i.'^i. 1 (':()..';(1 T-U) Povvder (ipernled Tool-i'':()..i(i:ieii 11 Trniiied Per-oii iSieiinlurei Trniiied Per-oii iPriiil Nniiiei .Areni-i orTrniiiiiie ili-l npplicnhleT =-i Dnie 4.0 IMPLEMENTATION OF THE TRAINING PROGRAM Training operations for the EDT project will begin prior to systemization, continue through it, and end when site operations commence. The Training Supervisor will schedule and manage training activity prior to and during site activity. Any replacement personnel will be required to 'catch up' with the staff on-site via a similar gap analysis and tailored plan. All EDT site personnel will be required to meet the minimum site access standards required in the EDT SOW, including the elements of site-specific training required by SOW Appendix B, Badging and Site Access; and Appendix E, Training and Certification Requirements. Operators, site supervisors, and site management personnel will be required to complete the initial phases of the training program prior to systemization. The following information and documents shall be maintained and available on-site at the EDT Control Room: • Job title for each position at the EDT facility. • Roster showing the names ofthe employees filling each job. • A written job description for each job title. • A written description of the type and amount of EDT, site access, and other training given to each person named. • Records that document the successful completion ofthe training and experience required for each person named. • The training records and documents shall be kept at least until closure ofthe facility. • Training records on former employees shall be kept at least three years from the date the employee last worked at the facility. Copies will be held by Versar© as directed. Some records may require longer retention times. • The Training Plan shall be maintained, and made available for access, by the EDT subcontractor after closure. 24 .\PPEIVDI\ 1 CB.\RR TR.\IN1NG REQl IREMENTS CBARR TRAINING REQUIREMENTS Chemical Biological Applications & Risk Reduction (CBARR) operations at Edgewood Chemical Biological Center (ECBC) provides in-house training as a baseline for deployment of certified chemical and explosive operators to work sites in the continental United States (CONUS) and outside (OCONUS). The CBARR provides staffing of Chemical Personnel Reliability Program (CPRP)-certified personnel with training in chemical agent handling, safety and health, explosive operations, and other tailored training modules depending on the need. Each certified operator will have the following basic coursework documented prior to the commencement of DAVINCH™ EDT operator training: • PRP-specific training, hi accordance with AR 50-6, all CPRP personnel will have completed core safety, security, and emergency training, which will be documented per local Standard Operating Procedures, plans, and regulations, including requirements of 2-16, Technical Proficiency; and 10-2, CAIRA Exercises, as appropriate. • Agent-handling training and certification. • OSHA 40-hour training and annual certification. • Explosive training, including Anmiunition, Arms, and Explosives (AA&E). • Related traimng in the any areas of technical proficiency as required (e.g., forklifi: operations). • Site-Specific Training per Section 3. Prior to deployment, the training records, curriculum plan, and traimng certifications issued by instructors for the CPRP elements of the proposed operators and supervisors will be reviewed by Versar© and forwarded to EG&G for approval. 26 .\PPEIVDI\ 2 S.UIPLE EDT TR\INER RESITVIES 27 PROPOSED TITLE/POSITION: Trainer. Supervisor and Chemical Operations Supen isor Name: E(.lucation (^ualiUcations: B.S.. Chemistry. South Carolina State Uni\ersity. 1967 MS.. E(.lucatiorL South Carolina State Uni\ ersit\' US .Amiy Training Courses (chemical surety. US .Army Ranger Course. NBC training) Present Position in (!)lTeror's Com pany: \'ice Presi(.lent. Chemical (!)perations Rele\ ant E.\perience: Mr. o\ ersees all chem ical surety operations at \ERS.ARiCi. inclu(.ling the in-house surety laboratoiy. operations in\ ol\ ing kSL EDT o\erseas. operations at Dugway Pro\ing Groun(.l an(.l Non-Stockpile (.lemil programs. He pro\i(.les training to in-house an(.l contractor personnel. .A(.l(.litional (.luties inclu(.le lor o\ ersight ol" the training an(.l super\ ision of technicians in the han(.lling of materials an(.l samples e.\pose(.l to chem ical an(.l biological agents. an(.l monitoring of all laboratoiy operations for compliance with local, state an(.l re(.leral regulations. The following is a partial list of the supporte(.l key projects. Tooele Cheinic;il .\geiil Desl ruction FiiciliK EDT Project. Responsible for chemical operations, monitoring planning an(.l technical support to the EDT program. K;iiid;i Hiirbor Cheinic;il Destruction Progriim. Responsible for o\ ersight of MTNIC.AMS operations, training personnel for operations at kan(.La in\ol\ ing monitoring. an(.l management ofthe project. Cheinic;il Deinilit;iriz;itioii on the Non-Stockpile Cheinic;il M;iteriel Progriim. for which GE(!)MET was responsible for mobile analytical laboratory operations, air monitoring. associate(.l chemical surety materiel acti\ ities. an(.l other rele\ ant laboratoiy ser\ ices: Iinpro\ed To\icologic;il .\gent Protecti\e Suit Progriim an(.l STEPO Program-Natick: Non-Stockpile Progriim - Chemical agent analysis of en\ ironmental samples from Spring \'alley site in Washington. DC an(.l biological agent analysis of samples from a site at Ft. Detrick. US.ACE N'lirious .\ssigninents, US .\rmy Cheinic;il Corps. During ser\ ice in the .Army. ac(.|uire(.l more than 23 years of experience in NBC matters inclu(.ling a wi(.le range of chemical surety relate(.l training programs. .As Chief. Chem ical-Biological Di\ ision. U.S. .Army Chem ical School. super\ise(.l an instructor staff of S.^ with responsibility for training sokliers in chemical warfare an(.l chem ical an(.l biological (.lelease: (.lirectly super\ ise(.l the training of chemical laboratory specialists in the 2S school's chem ical laboratoiy. .A(.lm inistere(.l the establishment an(.l monitoring of NBC contain ination sur\ i\ ability criteria for the Department of the .Army to ensure the incoqioration of NBC materiel sur\ i\abilit\' criteria in the (.lesign. ac(.|uisition an(.l procurement process for new items of .Army materiel: an(.l to ensure the e\ aluation of non-NBC sur\ i\ able fiel(.le(.l e(.|uipment for retrofit of sur\ i\ ability characteristics. Personally e\aluate(.l an(.l formulate(.l solutions for high \ isibility DoD problems pertaining to chem ical stockpile (.lem ilitarization. chem ical stockpile retrogra(.le. preparation of supplemental en\ ironmental impact statement which supporte(.l the (.lecision to buiki binaiy chem ical pro(.luction plants at Pine Bluff .Arsenal, preparation an(.l submission of the presi(.lential certification to the congress for pro(.luction of the 1 .^.^ mm binary artillery projectile. an(.l G.\0 (.|uestions about the binaiy chemical program. PROPOSED TITLE/POSITION: Trainer. D.A\TNCHT^' Operations Name: E(.lucation (Qualifications: Msiting Student 1991 St.Catherine's (\illege. CKford M.S. 19S9 Mechanical Engineering Kyoto Uni\ ersity. .lapan B.S. 19S7 Mechanical Engineering Kyoto Uni\ersity. .lapan First Class E.\plosi\ es Control (!)lTicer Present Position in (!)lTeror's Com pany: Rele\ ant E.\perience: Manager at Engineering Department. Nuclear an(.l CWT) business unit Mr. ^^^^1 has o\er 1.^ years of experience with hea\y engineering associate(.l with (.letonation chambers, (.lonor e.\plosi\e charge analysis, structural engineering, research an(.l (.le\elopment for fatigue an(.l (.lamage evaluation ofthe EDT system, test and evaluation ofthe D.A\TNCH'r"^" system for (.letonation an(.l simulant surrogate testing, (.lonor charge (.lesign. an(.l acti\ate(.l carbon filtration. He is also a First Class E.\plosi\es Control (!)lTicer (Japan). an(.l hokIs a Master's Degree in mechanical engineering from k\oto Uni\ersit\'. .lapan. He trains operators an(.l engineers in D.AMNCHT" technology. .liipiinese Cheinic;il \\ eiipons Destruction Project, K;ind;i, .J;ip;in - Mr. ^^^^1 ser\ es a lea(.l applications engineer for the EDT system at kan(.la. The system has safely an(.l successfully (.lestroye(.l appro.\imately 600 chemical munitions containing HD an(.l L using \acuum-assiste(.l (.letonation. The munitions were reco\ere(.l from the sea using a container system (.lesigne(.l to keep the munition at the appropriate pressure an(.l temperature to ensure that they are stable when brought to the surface. Mr. (.lesigne(.l an(.l impro\ e(.l (.lonor charge using gel-base(.l e.\plosi\ es to (.lestroy chemical bombs by controlle(.l (.letonation. He was also in charge of nuxlelineand ensuring that the technical aspects of (.letonation were applie(.l. Mr. ^^^^1 also manage(.l (.letonation tests on \arious chemical munitions using control le(.l (.letonation technology. He also (.lirecte(.l the D.AMNCH"^"^" R&D work on detonation chamber, including fatigue (.lamage e\ aluation using strain measurement an(.l finite element analysis of the structure. Incinenitors ;ind melting furiKices ;ind R&D: Mr. pro\ i(.le(.l (.lesign an(.l R&D engineering for (.le\elopment of a sewage slu(.lge incinerator an(.l melting fumace. R&D work inclu(.ling acti\ ate(.l carbon filter technology to remo\ al of (.lio.xins from e.Khaust gas. an(.l ultrasonic heat treatment for sewage slu(.lge. En\'ironinent;il R&D: Mr. pro\'i(.le(.l engineering an(.l technical support for projects rele\ ant to en\ ironment reco\ ery. He also set up training re(.|uirements an(.l coursework for personnel for better perfomiance in R&D. 30 PROPOSED TITLE/POSITION: Tminine Engineer. D.A\TNCHT" Name: E(.lucation (Qualifications: M.S. 19S4 Mechanical Engineering Tokashima Uni\ ersity. .lapan Thermal Energy Manager First Class E.\plosi\ es Control (!)lTicer Present Position in (!)lTeror's Com pany: Rele\ ant E.\perience: Manager at Engineering Department. Nuclear an(.l CWT) business unit Mr. ^^^^^ has playe(.l a significant role in (.lesigning an(.l constructing power plants an(.l heating an(.l cooling plants as a project engineer an(.l manager. He has been in charge of (.lesign process at the Chemical Weapons Destruction Project in kan(.la. .lapan. He was instrumental in traasfeming the technology an(.l training at Poelkapelle. Belgium. Cheinic;il \\ eiipons Destruction Project, K;ind;i, .J;ip;in. As a Process Designer. Mr. is in charge of process (.lesign. He is re\ iewing new e(.|uipment for the off-gas treatment facility being (.lesigne(.l for TH.ALES. (•SEC(!)I.A Project) an(.l con(.lucting research on the possible miniaturization an(.l simplification of the off-gas treatment process by applying a Cokl Plasma Furnace. R&D of Orr-G;is Tre;itinent. Mr. playe(.l a key role in the 1st test off-gas treatment test of Cokl Plasma at US.A an(.l the 2n(.l test Chem ical agent (.lestruction test of Cokl Plasma at GE(!)MET. Mr. ^^^^^1 manage(.l the off-gas treatment test on new technology using Cokl Plasma. He checke(.l the (.lecomposition rate of Cokl Plasma fumace by mL\e(.l gas of Mustar(.l (HD) an(.l Lewisite (L). He also (.lesigne(.l compact an(.l simplification ofthe off-gas system. Cogener;ition Fiicilit> \\ ork for Diiiiin Pliint, D;ii;in, .J;ip;in. As Project Manager Designer. Mr. is responsible for playing numerous roles, from in\ol\ement in preliminaiy (.lesign to the construction, commissioning an(.l maintenance of a cogeneration facility for a plant, as well as (.lealing with the plant licensing with go\ ernment authorities. Rese;irch Connected to Co;il FK .\sh, Kobe, .J;ip;in. Mr. was a Researcher with responsibility for engaging in R&D in the manufacturing of an artificial an(.l lightweight aggregate from coal lly ash: stu(.lying ways to promote the elTecti\ e use of coal lly ash in concrete an(.l tiles \ ia electrostatic separation: an(.l (.lecarbonizing coal lly ash by electrostatic separation an(.l assessing those mo(.lifie(.l coal lly ash. Development of ii Sewiige Giis Pretreiitment Unit, Kobe, .J;ip;in. Mr. ^^^^^1 ser\'e(.l as a Researcher Project Engineerwith responsibility for establishing a sustainable, stable operation for cogeneration using gas engine: (.le\ eloping a sewage gas pretreatment unit to remo\e minute amounts of hazar(.lous elements in sewage gas: an(.l (.lemonstrating the operation of cogeneration technology. PROPOSED TITLE/POSITION: EDT Safetv Conlrol Manager Name: E(.lucation (Qualifications: Tottori Prefectural High School in ^'onago Diploma of In(.lustrial Chemistry E.\plosi\ e Control (!)lTicer Special In(.lustrial W aste Manager Recei\e(.l training an(.l practice with respect to the OCW (.lestruction con(.lucte(.l bv (.IstI ( Defence Science an(.l Technoloi:\' Laboratory' Present Position in (!)lTeror's Com pany: Rele\ ant E.\perience: Safety Control Manager for Chem ical W eapon. Kobe Steel Mr. ^^^1 is an E.\plosi\ es Control (!)lTicer with more than 4.^ years experience in the fiekl. He has recei\ e(.l training from an(.l perfonne(.l OCW (.lestruction in accor(.lance with practices establishe(.l by the Defence Science an(.l Technology Laboratoiy. His career highlights inclu(.le (.lirecting an(.l controlling the safet\' of (.lestruction operations at CWT) facilit}' an(.l marine operations. Chemiciil \\ eiipons Destruction Project, K;ind;i, .J;ip;in. On this project. Mr. ^^^1 (.lirecte(.l an(.l controlle(.l the safety aspects of (.lestruction operations at a CW'D facility an(.l marine operations unco\ering an(.l reco\ering appro.\imately 600 okl chemical weapons. His (.luties also inclu(.le(.l (.lirecting the transport ofthe bombs to CWT) facilit}' an(.l interacting with (.lomestic officers. He also assiste(.l in the transportation of okl chemical weapons foun(.l at kan(.la port to Sasebo Maritime Self-Defense Force for in\ estigation of munitions. Beer Bottled Chemic;il .\gent Reco\er\7Destruction ;ind Contiiminiited Soil Decont;imin;ition Project, S;imuk;iw;i, .J;ip;in. Mr. was (.lesignate(.l Project Manager an(.l Safety Control Manager, with responsibility for reco\ering an(.l (.lestroying appro.\imately Soo of beer bottle(.l chemical agent foun(.l un(.lergroun(.l. He also (.lecontaminate(.l soil contaminate(.l by chemical warfare agent (.le\ elope(.l by Imperial .lapanese .Army. Inspection of .\b;indoned Chemic;il \\ eiipons, \\ ulnin, Chiini. Mr. ^^^1 inspecte(.l aban(.lone(.l chemical weapons in China an(.l con(.lucte(.l seale(.l packaging for those munitions. Chemic;il \\ eiipons Destruction Project, Luke Kussh;iro, .liipiin. As (.lesignate(.l Safety Control Manager for the chemical weapon. Mr. monitore(.l the safe an(.l successful (.lestruction of 26 chem ical munitions. Fertilizer Plant in se\ eral foreign countries. (!)\ erseas. During a posting in Zambia. supporte(.l the construction an(.l operation of a fertilizer plant. .Also ser\ e(.l as Section Chief in Singapore for the construction of polypropylene plant. Employment Histoiy 2()().';-Present: CWT) Project in kan(.La 2001-200.';: Kobe Steel. Ltd. Nuclear and CW D Business Units 196S-2000: Kobe Steel. Ltd. Industrial Machineiy Plant Department (Oerseas) 1964-1967: Kobe Steel. Lt(.l. Engineering Department 1961-19cS3: Kobe Steel. Ltd. Industrial Machineiy Plant Department (•(!)\erseas) .\PPENDI\ 3 KOBE STEEL TR\IN1NG PL.\N FOR EDT 34 SRD ANGI£ PROJECTION i3 # nnaioN NOTE vm TTJA NONE _ Projects Department Engineering Section 0. MO. 1-09630620 CWD PROJECTS DEPARTMENT THE DliAWIKG(S) AND THE INFORMATION CONTAINED HEREIN ARE THE PROPERTY OF KOBE STnULTD. THEY SHAU. NOT BE DISCL0SED,REPRODUCED OR USED.IN ANY MANNER WrTHOUT THE PRIOR WRfTTEN CONSEHT OF KOBE STEELLTD. DAVINCH SYSTEM TOEDT SERVICES Process Flow Diagram (l) (Main Process) PF3400 100 I I DB31 -EA101<S> -I I I I I I L 1/1 0 I ' I I ' I ' I I I I I I I I I I I I I I I I I I/a 0 s 10 IB 111111111111111111111 1/5 0 « 10 IS to 3RD ANGLE PROJECTION A it (PM4)(PM5)(^ CA CA CA Al Al Al 5201A 5202A 5203A HVAC M520A Unit E3r CA CA CA Unit CI Unit C2 Unit D Detonation Containment (2066 m^) *2 Unit A Al Al Al 5201C 5202C 5203C —i— HVAC M520C Ventilation -0.1—0.5 inchAq (-2.54—12.7 mmAq) Process ^ "cA Al 5204 PMI^ CA Al 5401 <§) <§) Stack S540 CWD PROJECTS DEPARTMENT mmto CWD PROJECTS DEPARTMENT THE DRAWING(S] AND THE INFORMATION CONTAINED HEREIN ARE THE PROPERTY OF KOBE STEEULTD. THEY SHAU. NOT BE DISCLOSED.REPRODUCED OR USED.IN ANY MANNER WTTHOUT THE PRIOR WRIHEN CONSENT OF KOBE STEELLTD. nnsioMxon ENGINIKBING DCPARTMENT NONE _ rejects Department Engineering Section 0. HO. 1-09630620 DAVINCH SYSTEM TOEDT SERVICES Process Flow Diagram (2) (Ventilation) JOB NO. PF3400 AREA 100 DRATHNG NO. ML DB31 -EA102<^ 1/1 0 I ' I ' I ' I ' I ' I 1/3 0 I I I j I I I 10 j 111111111 j 111111 1/5 0 5 10 15 3RD ANGLE PROJECTION Valve and Attachment Synnbo Symbol Name (PM) Process Monitoring Point (so) Samp inq Point .^^Area^Jyl^jnltorlng Flexible Tube TFX) ) (Rubber Hose) (HS) j Glove Valve (T) Check Valve (C) Ball Valve (B) Butterfly Valve (W) Relief Valve (R) 03 Ferrule (FE) Control Valve (FV,TV) ON-OFF Valve (HV) Pressure Reducing Valve (PV) Regulator (RG) Y—Type Strainer (SR) m \M Solenoid Valve (SO) Silencer (SL) FC(orFa"^NC) FC:Air Fail Closes Power Fail Close FO:Air Fail Opens Power Fail Open NC:Air Fail Locks Power Fail Close / Air Intake Filter (AF) Converter (SC) Flexible Pipe (FP) Pressure Relief Damper (PRD) \ \ -EE-Cuplo (CP) ] O Field Indication Control Room Indication(DCS) e Field Panel Indication INV Inverter Note) Open and close limit switches are applied for each ON-OFF valve. ^ ft Piping Symbo Exemplar 1"-OG-001-CS1-H3 Piping Size—Fluid Symbol—Serial Nunnber—Piping Class—Insulation Class Fluid Synnbo Symbol Name OC Off-Gas VT Ventilation WW Waste Water DR Drain GO Oxygen ON Nitrogen lA Instrument Air CW(S or R) Cooling Water(S:Service , R:Return) PC Propane Gas IW Industrial Water CA Cooling Air PA Process Air ,Intake Air NOH NaOH Piping Class Symbol Name CS1 ASME B36.10 ,A53 typeF ,A53 Gr.A typeE CS2 ASME B36.10 ,A53 typeF(GLV) ,A53 Gr.A typeE(GLV) CS3 ASME B36.10 ,A53 typeF(GLV) .Galvanized Steel Sheet (Spiral Duct) CS4 ASME B36.10,A135 Gr.A CSS ASME B36.10.A135 Gr.A CS6 ASME B36.10 ,A53 typeF ,A135 Gr.A + Epoxy Lining ANSI 150LB SCH 10 RJ CS7 ASME B36.ro ,A53 typeF ,A135 Gr.A + Epoxy Lining ANSI 600LB SGH 40 RJ S2 ASME B36.10 .A312 Gr.TP304 for Oxygen Line S3 ASMEB36.10,A312Gr.TP316L nsu ation C ass Symbol Name H1 Thernnal Insulation (Below 100 degrees centigrade) H2 Thermal Insulation (Below 150 degrees centigrade) H3 Thermal Insulation (Below 200 degrees centigrade) H4 Thermal Insulation (Below 250 degrees centigrade) H5 Thermal Insulation (Below 300 degrees centigrade) PP Personal Protection C1 Prevention of Freeze & Dew Gondensation SP Noise Reduction :Hazardous Area » Preparation Container (GlassIDivl) " Preparation Area (ClassIDiv2) ° Detonation Containment (Class! Div2) ° Off—Gas Treatment Area (GlassIDiv2) Unit / / / / Design Progress 7/ 8 2010 Iwasaki fB Ueda /^ ^tayams Hayashi Ueda Hayashi <i> Design Progress 5/21 2010 Iwasaki 5/ /21 Ueda [atayame Hayashi Ueda 5/ /21 Hayashi <s> Design Progress 4/2 2010 Iwasaki 4/ /2 Ueda % [atayams Hayashi % Ueda Hayashi First issue 2/25 2010 Sasaki /25 Iwasaki /25 Ueda /25 Hayashi /25 Ueda /25 Hayashi BEV. NO. REVISION NOTE DESIGNED CHECKED APPROVED REVIEWED BEV. NO. REVISION NOTE ENGINEERING DEPARTlfENT sous NONE S^Prqjects Department Engineering Section NAME 0. NO. 1-09630620 T.NO. •1013 Technology Park Dr. Qlen Allen. Virginia 23069 Phone: (804) 262-6600 ANDAttOClATiS FaX: (804) 262-1048 CWD PROJECTS DEPARTMENT THE DRAWING(S) AND THE INFORMATION CONTAINED HEREIN ARE THE PROPERTY OF KOBE STEEULTD. THEY SHALL NOT BE DISCLOSED.REPRODUCED OR USED.IN ANY MANNER WITHOUT THE PRIOR WRIHEN CONSENT OF KOBE STEELLTD. TITLE DAVINCH SYSTEM TOEDT SERVICES Pipe & Instruments Diagram(1) P&ID Explanatory notes JOB NO. PF3400 J L AREA 100 I 1—. DRAlflNG NO. DB33 -EA001<^ J 1 I I I I L I ' I M M • I ' I I I I I t I I I I I I I I M I |nn|iin|nn|nn| SRD ANGLE PROJECTION - - t-H - - 'p 141 Handlifter B x2 170 Cylinder Cart Ml40 Handlifter A x3 Changing Room * IS ^ it <8> <S> REV. NO. Design Progress Design Progress First issue REVISION NOTE 5/21 2010 4/2 2010 2/25 2010 Iwasaki Iwasaki Sasaki DESIGNED CHE(XED ^^21 ^25 Ueda Ueda Iwasaki ^25 2 [atayama /2 Ueda 21 [atayami ^i Hayashi ^25 Hayashi Hayashi APPROVED ENGINEERING DEPARTMENT ^21 ^25 Ueda Ueda Ueda '^21 ^25 Hayashi Hayashi Hayashi REVIEWED SCALE NONE ^(^^Projects Department Engineering Section NAME 0. NO. 1-09630620 T. NO. 1013 Technology Park Dr. Qlen Allen, Virginia 23069 Phone: (804) 262-6600 ANDAtfOCIATIt Fax: (804) 262-1048 CWD PROJECTS DEPARTMENT THE DRAWING(S) AND THE INFORMATION CONTAINED HEREIN ARE THE PROPERTY OF KOBE STEEULTD. THEY SHALL NOT BE DISCLOSED.REPRODUCED OR USED.IN ANY MANNER WITHOUT THE PRIOR WRITTEN CONSENT OF KOBE STEELLTD. TITLE DAVINCH SYSTEM TOEDT SERVICES Pipe & Instruments Diagram(2) Area 10 Pre Treatment JOB NO. PF3400 ' ' ' • ' AREA 100 DRAWING NO. DB33 -EA002<|> I ' I ' I 1/10 1 2 1/S 0 II I I I I M I I ( M I I 5 10 15 |n(l|MII|MM|MII 1/5 0 5 IG i5 r SRD ANGLE PROJECTION It strain Monitoring System DESTINY M230 M231 GRAND M232 Networi< Detonation Containnnent Lid and Deck Operation Unit E CAD M211 M250 Hand Lifter A MUO Dust Capture Recipient M240 Hydraulic Punnp P211 Waste Handling Eorklift M216 - o ppg o Drum Porter M215 F410 Sheet (7) F320 Sheet (5) C810 Sheet(9) Z850 Sheet(9) Z870 Sheet(9) Ventilation Sheet (8) Air Shower Room (AMS) koKo^ Forklift M120 Air Shower M160 REV. NO. Design Progress Design Progress Design Progress Design Progress First issue REVISION NOTE 7/ 8 2010 6/14 2010 5/21 2010 4/2 2010 2/25 2010 Iwasaki Iwasaki Iwasaki Iwasaki Sasaki DESIGNED CHECKED ^21 '25 Ueda Ueda Ueda Ueda Iwasaki 8 [atayams 14 [atayama '25 21 [atayam8/2i Ueda Hayashi Hayashi 2 [atayama / 2 Hayashi Hayashi 25|Hayashi APPROVED ENGINEERING DEPARTMENT '21 '25 Ueda Ueda Ueda Ueda Ueda '21 '25 Hayashi Hayashi Hayashi Hayashi Hayashi REVIEWED SCALE NONE Projects Department Engineering Section NAME 0. NO. 1-09630620 T. NO. •1013 Technology Park Dr. H H M Qlen Allen, Virginia 23069 • Phone: (804) 262-6500 ANDAfSOCIATiS Fax: (804) 262-1048 CWD PROJECTS DEPARTMENT THE DRAWING(S) AND THE INFORMATION CONTAINED HEREIN ARE THE PROPERTY OF KOBE STEEULTD. THEY SHALL NOT BE DISCLOSED.REPRODUCED OR USEDJN ANY MANNER WITHOUT THE PRIOR WRITTEN CONSENT OF KOBE STEELLTD. TITLE DAVINCH SYSTEM TOEDT SERVICES Pipe & Instruments Diagram(3) Area 20 Detonation JOB NO. PF3400 I L_J ' ' AREA 100 DRAWING NO. DB33 -EA003^ J I J I I L 1/1 0 I ' I ' I ' I I ' I 4 5 I 111 I I i/3 0 6 I 10 15 I IIII I I II I I II II I II II I i/5 0 6 10 20 1/S 0 III1111IIIIIII11II11 l/fi 0 6 10 le 20 SRD ANGLE PROJECTION ^ ft Unit B C810 > 5/4"-IA-8Q9-CS2 *1 csj 1/2"-IA-809-CS2 Sheet(9) B348 -Dech-BVC01 CNI Z860 oo D-3/8"-IA-5Q4-CS2 12"-CA-314-CS4-PP 12"-CA-306-CS4-PP 'ATM 'ATM NOx CO O2 SOx HCL Dust Al 3801 Al 3802 Al 3803 Al 3804 Al 3805 Al 4501 Sheet(9) P33QA/B >ll^ Sheet(5) Z870 Sheet(9) AT-4501 Sheet(7) Sheet(7) <8> <3> <8> REV. NO. Design Progress Design Progress Design Progress Design Progress First issue REVISION NOTE 7/ 8 2010 6/14 2010 5/21 2010 4/2 2010 2/25 2010 Iwasaki Iwasaki Iwasaki Iwasaki Sasaki DESIGNED CHECKED '21 '25 Ueda Ueda Ueda Ueda Iwasaki ^atayama 14 [atayama '25 21 [atayama [atayama Ueda '25 Hayashi Hayashi 21 Hayashi Hayashi Hayashi APPROVED ENGINEERING DEPARTMENT '14 '21 '25 Ueda Ueda Ueda Ueda Ueda '21 '25 Hayashi Hayashi Hayashi Hayashi REVIEWED SCALE NONE BY rejects Departnnent Engineering Section NAME 0. NO. 1-09630620 T. NO. 1013 Technology Park Dr. Qlen Allen. Virginia 23069 Phone: (804) 262-6600 ANDAffOClATif Fax: (804) 262-1048 CWD PROJECTS DEPARTMENT THE DRAWING(S) AND THE INFORMATION CONTAINED HEREIN ARE THE PROPERTY OF KOBE STEEULTD. THEY SHALL NOT BE DISCLOSED.REPRODUCED OR USEDJN ANY MANNER WITHOUT THE PRIOR WRIHEN CONSENT OF KOBE STEELLTD. TITLE DAVINCH SYSTEM TOEDT SERVICES Pipe & Instruments Diagram(6) Area 30 Off Gas Treatment(2) JOB NO. PF3400 I I I I I AREA 100 DRAWING NO. mm DB33 -EA006<§> I ' I i/i 0 i 1/3 0 I I I i I I I I I I I I I I 3 Id 1/6 I I I I I 11 I I I 11 I I I I 30 15 "I SO I ll ' I ' 1/1G 1 2 I I I I I I I I I I I I I I I i/3 Q 5 10 15 I I I I I I I I I I I I i I I I I I I I 1/5 0 5 in m m 3RD ANGLE PROJECTION ^ if B450 HS 01 Sheet(7) 10"-Vr-516-CS3 18"-\Ar-502-CS3-H1 18"-Vr-503-CS3-H1 18"-Vr-504-CS3-H1 <S> REV. NO. Design Progress Design Progress Design Progress Design Progress First issue REVISION NOTE 7/ 8 2010 6/14 2010 5/21 2010 4/2 2010 2/25 2010 Iwasaki Iwasaki Iwasaki Iwasaki Sasaki DESIGNED CHECKED '14 '21 '25 Ueda Ueda Ueda Ueda Iwasaki 8 [atayama / B Hayashi / B '14 [atayama '25 21 [atayama 2 [atayama Ueda '25 Hayashi 21 Hayashi Hayashi Hayashi APPROVED ENGINEERING DEPARTMENT '21 '25 Ueda Ueda Ueda Ueda Ueda '21 '25 Hayashi Hayashi Hayashi Hayashi Hayashi REVIEWED SCALE NONE Projects Department Engineering Section NAME O.NO. 1-09630620 T.NO. 12"-Vr-405-CS3 o o LO (PMI 3) CA Al 5204 "1 (PM14) CA Al 5401 B541 CP-501 BVCOli 3/8"-( 4". B542 CP-502. 4" B543 CP-503/ 1"-CS1 Stack S540 •1013 Technology Park Dr. H H B Allen, Virginia 23069 • Phone: (804) 262-6500 ANDAfSOCIATIf Fsx: (804) 262-1048 CWD PROJECTS DEPARTMENT THE DRAWING(S) AND THE INFORMATION CONTAINED HEREIN ARE THE PROPERTY OF KOBE STEEULTD. THEY SHALL NOT BE DISCL0SED,REPR0DUCED OR USEDJN ANY MANNER WITHOUT THE PRIOR WRITTEN CONSENT OF KOBE STEELLTD. TITLE DAVINCH SYSTEM TOEDT SERVICES Pipe & Instruments Diagram(8) Area 50 Containment & Ventilation JOB NO. PF3400 I I I I AREA 100 DRAWING NO. DB33 -EA008<^ J L 1/1 0 I M M • I M 1 S 3 4 5 I I I I I I I I I I I I I I I I 1/3 0 5 10 15 1/5 0 I I I I I I I I I I I I I I I I I 5 10 m so 1"-IW-835-CS2 SRD ANGLE PROJECTION ^ it Tank Truck Area"CHAMBER Sheet(3) Csl 1 1/2"-IW-831-CS2 ^ —^ 1X1- For the chamber and floor cleaninq BVC01 Unit 0 l"-IW-834-CS2 F270 Make-Up B83Sf!vCP-815 2"-G0-873-S2 l"-GN-854-CS2 R220 1"-IA-804-CS2 R220 1/2--IA-805-CS2 ,^3^^ BVC01 1"-IA-813-CS2 1"-GN-857-CS2 M260 1"-IW-836-CS2 B837 BVC01 /floor cleaning Unit A Sheet(5) 1/2"-GN-855-CS2 P330 A/B 1/2"-GN-856-CS2 1 1/2"-CWR-305-CS2 1 1/2"-CWS-822-CS2 F320 P330 A/B P330 A/B 1 "-IA-806-CS2 1/2"-IA-807-CS2 P330 A/B 1/2--IA-808-CS2 B^9^^^ ^^^^^ F320 BVC01 Unit B Sheet(6) 1"-G0-874-S2 1"-PG-861-CS5 R360 A/B 1/2"-IA-809-CS2 R360 A/B 1/4"-IA-814-CS2 R360 A/B 1/2"-IA-815-CS2 g^OpQ D373 1"-IW-833-CS2 B836 BVCOI,^ ~"'^BVC01 <§> D373,V363 •• ke-Up Unit C2 1/2"-IA-810-CS2 Sheet! FOR INST. BVCOl Unit D Sheet(7) Air Connpressor Unit C810 (110mVhx0.69MPa) / nstrument Air Storage Tank V812 1/2"-IA-811-CS2 F420 1/2--IA-812-CS2 g^^pQp INST. BVC01 Plastic Drum Plastic Drum Plastic Drum <s> REV. NO. Design Progress Design Progress Design Progress Design Progress First issue BEVISIONNOTE 7/ 8 2010 6/14 2010 5/21 2010 4/2 2010 2/25 2010 Iwasaki Iwasaki Iwasaki Iwasaki Sasaki DESIGNED CHECKED 6 14 ^21 '25 Ueda Ueda Ueda Ueda Iwasaki 8 [atayams 14 [atayami "25 21 [atayama/21 2 [atayama Ueda 14 ^25 Hayashi / B Hayashi Hayashi Hayashi Hayashi APPROVED ENGINEERING DEPARTMENT '21 '25 Ueda Ueda Ueda Ueda Ueda 14 '21 '25 Hayashi Hayashi REVIEWED SCAI£ NONE Projects Department Engineering Section NAME 0. NO. 1-09630620 T. NO. 1013 Technology Park Dr. Qlen Allen. Virginia 23069 Phone: (804) 262-6600 ANDAStOClATif Fax: (804) 262-1048 CWD PROJECTS DEPARTMENT THE DRAWIN6(S) AND THE INFORMATION CONTAINED HEREIN ARE THE PROPERTY OF KOBE STEEULTD. THEY SHALL NOT BE DISCLOSED.REPRODUCED OR USEDJN ANY MANNER WITHOUT THE PRIOR WRIHEN CONSENT OF KOBE STEELLTD. TITLE DAVINCH SYSTEM TOEDT SERVICES Pipe & Instruments Diagram(9) Area 80 Utility JOB NO. PF3400 I I I I I AREA 100 DRAWING NO. DB33 -EA009<^ 1 L I I I M M I I I M M I M iiiiliiMiiininii SRD ANGLE PROJECTION SLIDING DECK TRANSFER SYSTEM HYDRAULIC CYLINDER Press: 7MPa Dia:32mm Stroke:720mnn HYDRAULIC CYLINDER Press: 7MPa Dia:50mm Stroke:880mm CHAMBER CLAMP HYDRAULIC LOCK SYSTEM CHAMBER LID TRANSFER SYSTEM ^zsYzs_ .35 A36. MOTOR FOR SLIDING DECK MOTOR P0WER:1.5kw R.P.M: 1800/15 REDUCING: 1/120 HYDRAULIC CYLINDER Press: 21 MPa Dia:140mm Stroke: 100mm QTY:16sets HIGH PRESS. HOSE^ HYDRAULIC CYLINDER ^ Press: 7MPa Dia :100mm Stroke:360mm HIGH PRESS. HOSE ltd UUL LIFER Press: 3MPa Dia: mm Stroke:500mm A V LID OPNE/CLOSE LID MOVING MOTOR FOR SLIDING DECK MOTOR POWER: 1.5k w R.P.M: 1800/15 REDUCING; 1/120 019.2/012.7 LOW PRESS. HOSE Rcl/2 t HYDRAULIC CYLINDER Press: 7MPa Dia:110-80mm Stroke:3900mm HYDRAULIC CYLINDER Press: 7MPa Dia:80mm Stroke: 1300mm 026.8/019 LOW PRESS. HOSE Rc3/4 m o 019.2/012.7 LOW PRESS.HOSE Rcl/2 t SET 1~7MPa t 01 013,2/06.3 LOW PRESS. HOSE Rc 1/2 013,2/06.3 LOW PRESS. HOSE Rc 1/2 m MAGNET 013.2/06.3 LOW PRESS.HOSE Rcl/2 t ELECTRIC&INSTRUMENT LIST ROLL CURTAIN SYSTEM HYDRAULIC POWER UNIT SYMBOL M01 M02,M05 HT01 S0L1-S0L11 ZS01-ZS16 ZS21-ZS41 PS01'-PS04 3WV01 MG01 M04 S0L11 ZS42'-ZS45 NAME OIL POMP MOTOR SLIDING DECK MOTOR OIL TANK HEATER SOLENOID VALVE (OIL) SWITCH (FOR CLAMP) SWITCH (FOR CHAMBER LID) SWITCHfFOR SLIDING DECK) OIL PRESS. SWITCH 3-WAY VALVE MAGNET ROLL CURTAIN MOTOR SOLENOID VALVE (AIR) SWITCH (FOR ROLL CURTAIN) SPECIFICATION 1 5kw, 4P, AC480/440V,60Hz, 1. 5kw. 4P, AC480/440V.60HZ.1/12Q 2kw. AC480/440V DC24V DC24V DC24V DC24V DC24V DC 180V 0. 2kw, 4P. AC480/440V.60HZ.1/4Q DC24V DC24V QTY 2 1 1 1 6 4 2 1 4 4 REV. NO. Design Progress First issue BEVISIONNOTE 5/21 2010 2/25 2010 Takeda Sasaki DESIGNED CHECKED '21 ^^25 Ueda Iwasaki '25 21 [atayama Ueda '21 Hayashi 25 Hayashi APPROVED ENGINEERING DEPABTIIENT '21 '25 Ueda Ueda '21 '25 REVIEWED SCALE NONE Projects Department Engineering Section NAME O.NO. 1-09630620 T. NO. SYMBOL : MOTOR HYDRAULIC PUMP (PISTON PUMP) ? ? m cz 1 in: J-L 3-POSITION VALVE(4-PORT) (WITH SOLENOID VALVE) 2-POSITION VALVE(4-PORT) (WITH SOLENOID VALVE) : 3-PORT VALVE • 2-POSITION VALVE (4-PORT) )( 3-POSITION VALVE (4-PORT) FLOW CONTROL VALVE : PILOT CHECK VALVE : RELIEF VALVE : CHECK VALVE : PRESSURE GAUGE : OIL HEATER : AIR BREATHER OIL FILTER OIL LEVEL GAUGE T2 P Tl SOL 1 1 AIR SUPPLY (INSTRUMENT AIR) •1013 Technology Park Dr. mm ^ Qlen Allen, Virginia 23069 •%# Phone: (804) 262-6600 ANDAffOClATif Fax: (804) 262-1048 S>-KOBH CWD PROJECTS DEPARTMENT THE DRAWING(S) AND THE INFORMATION CONTAINED HEREIN ARE THE PROPERTY OF KOBE STEEULTD. THEY SHALL NOT BE DISCLOSED.REPRODUCED OR USEDJN ANY MANNER WITHOUT THE PRIOR WRIHEN CONSENT OF KOBE STEELLTD. TITUS DAVINCH SYSTEM TOEDT SERVICES Pipe & Instruments Diagram(10) Lid And Deck Operation Unit JOB NO. PF3400 I I I I I AREA 100 DRAWING NO. DB33 -EA010<J> J I I L 1/1 0 I ' I ' I ' I ' I ' I 4 I I II 1/S 0 I I I I I I I II II I fi IQ 15 I I I I I I I I I II I I I I I I 1 I /5 G & 10 15 20